EP0927427B1 - Method of manufacturing an electromechanical relay - Google Patents

Method of manufacturing an electromechanical relay Download PDF

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Publication number
EP0927427B1
EP0927427B1 EP97940680A EP97940680A EP0927427B1 EP 0927427 B1 EP0927427 B1 EP 0927427B1 EP 97940680 A EP97940680 A EP 97940680A EP 97940680 A EP97940680 A EP 97940680A EP 0927427 B1 EP0927427 B1 EP 0927427B1
Authority
EP
European Patent Office
Prior art keywords
contact
contact pieces
hole
metal blade
brazing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97940680A
Other languages
German (de)
French (fr)
Other versions
EP0927427A1 (en
Inventor
William G. Welsh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TE Connectivity Corp
Original Assignee
Tyco Electronics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tyco Electronics Corp filed Critical Tyco Electronics Corp
Publication of EP0927427A1 publication Critical patent/EP0927427A1/en
Application granted granted Critical
Publication of EP0927427B1 publication Critical patent/EP0927427B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H45/00Details of relays
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H11/00Apparatus or processes specially adapted for the manufacture of electric switches
    • H01H11/04Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
    • H01H11/041Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by bonding of a contact marking face to a contact body portion
    • H01H11/043Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by bonding of a contact marking face to a contact body portion by resistance welding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H11/00Apparatus or processes specially adapted for the manufacture of electric switches
    • H01H11/04Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
    • H01H11/041Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by bonding of a contact marking face to a contact body portion
    • H01H11/045Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by bonding of a contact marking face to a contact body portion with the help of an intermediate layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H11/00Apparatus or processes specially adapted for the manufacture of electric switches
    • H01H11/04Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
    • H01H11/041Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by bonding of a contact marking face to a contact body portion
    • H01H2011/047Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by bonding of a contact marking face to a contact body portion on both sides of the contact body portion

Definitions

  • the present invention relates to an electromechanical switching device, such as, a relay. More particularly, the invention relates to an electromechanical switching device with an electrical contact arm having contact pieces on both sides thereof, which is used, for example, as a moveable contact arm.
  • rivet style contacts are commonly used in the making of the electrical contact arms.
  • a contact configuration having a center contact arm that needs contacts on both sides e.g. SPDT, Break-Make, Form C
  • a rivet contact for this arm has to be preformed, then staked through a hole in the arm and deformed again in order to achieve a matching contact surface on both sides of the contact arm.
  • This known method of making a contact arm requires expensive manufacturing of the contact rivets. Further, the resulting contact arm structure does not pass some harsh application life requirements for particular switching applications.
  • British Patent Specification No. GB-A-1,158,119 describes a spring blade assembly, and a method of manufacturing same, having a plurality of superimposed spring blades that are clamped together via connected contact pieces located on either side of the plurality of spring blades.
  • the spring blades have aligned apertures formed therethrough, a head contact overlying the apertures on one side of the plurality of spring blades and a backing member overlying the apertures on the other side.
  • the head contact and the backing member are connected to each other by means of soldering or welding.
  • the contact pieces Due to the plurality of superimposed spring blades, the contact pieces have to be connected with good conductivity within the aligned apertures. This requires each contact piece to have a connecting member extending from the head contact and/or backing member into the respective aperture for joining to the other contact piece.
  • the contact pieces have rivet shapes and require expensive manufacturing similar to the rivet contacts described above.
  • an electromagnetic switch that includes:
  • the present invention also provides an electrical contact arm, comprising a metal blade having a through-hole formed therethrough, and a pair of contact pieces, each having a planar bottom surface, said contact pieces being joined with the bottom surface to the metal blade so as to cover the through-hole from both sides and said through-hole being filled at least partially with excess joining material.
  • the present invention provides a method of manufacturing an electrical contact arm, comprising the steps of:
  • a contact tape 1 which is normally contained on a spool 2.
  • the contact tape 1 has a specified thickness and width.
  • a cutting mechanism 4 is shown only schematically and may be any type of known or conventional cutting mechanism.
  • the contact tape 1 is comprised of contact material and is coated on one side with a braze alloy backing.
  • the contact tape 1 and the contact pieces 3 are comprised of three bonded layers: a precious metal mating surface 31, a silver intermediate 32 and a braze alloy backing 33, which layers are shown in the enlarged cross section.
  • a metal blade 5 is provided with a through-hole 6 at the desired contact position.
  • the metal blade 5 may be made of any material suitable for the desired application, for example, copper alloy.
  • a pair of cut contact pieces 3A, 3B are centered over both sides of the through-hole 6 with the braze backing 33 placed against the blade 5.
  • Each contact piece 3A, 3B is larger in cross-sectional area than the through-hole 6 so that the through-hole 6 is completely covered on both sides of the metal blade 5 and the contact pieces 3A, 3B contact the respective surrounding surfaces of the metal blade 5.
  • a pair of electrodes 7, 8 are brought to the mating surfaces 31 of the contact pieces 3A, 3B.
  • the electrodes 7, 8 exert a force on the contact pieces 3A, 3B to keep the pieces in position and to ensure acceptable electrical contact with the blade 5.
  • a current is then passed through the first electrode 7, through the blade and contacts assembly 3A, 5 and 3B, to the other electrode 8 for a sufficient amount of time to melt the braze alloy backing 33 on both contact pieces 3A, 3B.
  • the amount of current applied is dependent upon the compositions and other physical characteristics of the various elements.
  • the electrodes 7, 8 stay in place for a sufficient amount of time so the braze alloy can solidify. This method results in braze bonding each of the contact pieces 3A, 3B directly to the blade 5 and any excess braze material 34 flowing into the through-hole 6 which serves as a "braze reservoir". Once the braze has solidified, the electrodes 7, 8 are removed, as shown in FIG 3.
  • the method can also result in bonding the contact pieces 3A, 3B to one another. This can be accomplished by having the excess braze material 34 fill the through-hole 6 completely (as shown in FIG 3) or having the excess braze material 34 from each contact piece sufficiently join with one another in the through-hole 6.
  • a moveable contact arm for a relay was made using the method of the present invention having the following dimensions:
  • FIG 4 shows a relay 40 of the present invention.
  • the relay 40 comprises a base 41, a coil assembly 42 that connects to the base 41, an armature 43, stationary contact members 44, 45 and a moveable contact arm 46 that is actuated by the armature 43 to contact the stationary contacts 44, 45.
  • the moveable contact arm 46 is shown in more detail in FIG 5.
  • the moveable contact arm 46 comprises a metal blade 46a having a through-hole 46b formed therethrough and a pair of contact pieces 46c, 46d that are joined to the metal blade 46a.
  • the through-hole 46b acts as a reservoir to contain any excess joining material used to join the contact pieces 46c, 46d to the blade 46a.
  • the relay 40, and the moveable contact arm 46 may be constructed by the method of the present invention.
  • the embodiments described herein are merely illustrative of the principles of the present invention. Various modifications may be made thereto by persons ordinarily skilled in the art, without departing from the scope or spirit of the invention.
  • the contact tape 1 may be in the form of single strips rather than on a spool 2.
  • the contact pieces 3A, 3B may be cut from the tape 1 in different shapes, for example, in rectangular or circular shapes.
  • the braze alloy backing 33 may consist of any known or conventional brazing material.
  • braze alloy backing 33 may be melted by another mechanism other than via the use of the electrodes 7, 8 and the application of current therebetween, for example, via the use of a heat chamber. Further, the electrodes 7, 8 may be replaced or supplemented by another mechanism to press and hold the contact pieces 3A, 3B against the metal blade 5.
  • contact pieces may also be joined to the blade via any known or conventional metallurgical joining process, other than via brazing, such as, soldering or welding, using a suitable solder or joining material.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Manufacture Of Switches (AREA)
  • Contacts (AREA)
  • Electromagnets (AREA)

Abstract

An electromechanical relay, in particular, a moveable contact arm for a relay. The contact arm is manufactured by brazing a pair of contact pieces from both sides to a metal blade. In order to avoid excess brazing material contaminating the contact surfaces, the metal blade is provided with a through-hole over which the contact pieces are centered from both sides. The through-hole serves as a braze reservoir. Thus, excess brazing material flows into the hole which in turn limits braze flow up the contact edges which would result in contamination of the contact surfaces.

Description

    FIELD OF THE INVENTION
  • The present invention relates to an electromechanical switching device, such as, a relay. More particularly, the invention relates to an electromechanical switching device with an electrical contact arm having contact pieces on both sides thereof, which is used, for example, as a moveable contact arm.
  • BACKGROUND OF THE INVENTION
  • In relays and other electromechanical switching devices for switching higher currents, rivet style contacts are commonly used in the making of the electrical contact arms. For example, for a contact configuration having a center contact arm that needs contacts on both sides (e.g. SPDT, Break-Make, Form C), a rivet contact for this arm has to be preformed, then staked through a hole in the arm and deformed again in order to achieve a matching contact surface on both sides of the contact arm. This known method of making a contact arm requires expensive manufacturing of the contact rivets. Further, the resulting contact arm structure does not pass some harsh application life requirements for particular switching applications.
  • British Patent Specification No. GB-A-1,158,119 describes a spring blade assembly, and a method of manufacturing same, having a plurality of superimposed spring blades that are clamped together via connected contact pieces located on either side of the plurality of spring blades. Specifically, the spring blades have aligned apertures formed therethrough, a head contact overlying the apertures on one side of the plurality of spring blades and a backing member overlying the apertures on the other side. The head contact and the backing member are connected to each other by means of soldering or welding. Due to the plurality of superimposed spring blades, the contact pieces have to be connected with good conductivity within the aligned apertures. This requires each contact piece to have a connecting member extending from the head contact and/or backing member into the respective aperture for joining to the other contact piece. As a consequence, the contact pieces have rivet shapes and require expensive manufacturing similar to the rivet contacts described above.
  • It is also known to cut contact pieces from a contact tape and metallurgically join, such as by resistance brazing, the contact pieces to the surfaces of electrical contact arms as desired. No holes need to be formed through the contact arms' surfaces. Such a contact piece typically has a braze alloy backing layer on one side which is used for brazing the contact piece to a planar surface of a contact arm or a blade spring. Contact arms made with brazed contact tape pieces routinely pass harsh application life requirements.
  • However, during the joining/brazing process, excess molten brazing material flows high up the sides of a contact piece and may in some cases flow onto the surface of the contact piece. This is due, in part, to electrodes used in the brazing process which exert a force on the contact pieces to keep them in position and to ensure acceptable electrical contact with the contact arms. This condition can result in contacts welding during operation of the contact arm as well as in shortening the resistance brazing process electrode life. Disadvantageously, the amount or thickness of the braze alloy coating cannot be reduced sufficiently because of limitations in the manufacturing process of the contact tape, i.e., such a braze alloy coating can be achieved only with a specified minimum thickness on the tape.
  • It is thus an object of the present invention to overcome the disadvantages of the existing art.
  • In particular, it is an object of the present invention to provide an electromechanical switch having an electrical contact arm using cheap contact pieces with a simple shape and a planar bottom surface, which contact pieces can be brazed on both sides of a metal blade without excess brazing material affecting the contact surfaces.
  • It is a further object of the invention to provide an electromechanical switch having an electrical contact arm in which a pair of contact pieces are cut from a contact tape having a braze alloy backing.
  • It is still a further object of the present invention to provide an electromechanical switch having an electrical contact arm in which a pair of contact pieces are brazed to respective sides of a metal blade and the contacts are pressed against the metal blade to achieve a predetermined overall thickness between the contact surfaces without a need of removing excess brazing material.
  • SUMMARY OF THE INVENTION
  • The aforementioned problems are obviated by the present invention which provides an electromagnetic switch that includes:
  • a coil assembly having a magnetic core, a coil wound around the core, and a frame that holds the coil and core;
  • a contact assembly having (a) a pair of stationary contact arms arranged opposite one another and with the respective contacts facing one another; and (b) a moveable contact arm arranged between the pair of stationary contact arms and having a metal blade with a through-hole formed therethrough and a pair of contact pieces, each having a planar bottom surface, said contact pieces being brazed with the bottom surface to the metal blade so as to cover the through-hole from both sides and said through-hole being filled at least partially with excess braze material; and
  • means for actuating the moveable contact arm upon energization and de-energization of the coil.
  • The present invention also provides an electrical contact arm, comprising a metal blade having a through-hole formed therethrough, and a pair of contact pieces, each having a planar bottom surface, said contact pieces being joined with the bottom surface to the metal blade so as to cover the through-hole from both sides and said through-hole being filled at least partially with excess joining material.
  • Further, the present invention provides a method of manufacturing an electrical contact arm, comprising the steps of:
  • providing a metal blade having a through-hole formed therein;
  • providing a pair of contact pieces each having a planar bottom surface greater than the through-hole in said blade, each of said bottom surfaces being coated with a layer of joining material;
  • positioning one of said contact pieces on either side of said blade so as to cover said through-hole from either side;
  • joining the contact pieces to the blade by applying heat for melting said layers of joining material while pressing said contact pieces from either side against said blade, the through-hole serving as a reservoir where excess molten joining material flows in; and
  • solidifying the joining material.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • For a better understanding of the invention, reference is made to the following description of an exemplary embodiment thereof, and to the accompanying drawings, wherein:
  • FIG 1 is a schematic illustration of the method of the present invention showing contact pieces being cut from a tape and being centered over both sides of a metal blade, the illustration using different scales;
  • FIG 2 is an enlarged sectional view of an electrical contact arm of the present invention with the contact pieces at the beginning of the brazing process;
  • FIG 3 is a sectional view of the contact arm of FIG 2 with the contact pieces after brazing;
  • FIG 4 is an exploded view of a relay of the present invention; and
  • FIG 5 is the moveable contact arm of the relay of FIG 4.
  • DETAILED DESCRIPTION
  • Referring now to FIG 1, there is shown a contact tape 1 which is normally contained on a spool 2. The contact tape 1 has a specified thickness and width. For manufacturing an electrical contact arm, the tape 1 is cut into single contact pieces 3. A cutting mechanism 4 is shown only schematically and may be any type of known or conventional cutting mechanism. The contact tape 1 is comprised of contact material and is coated on one side with a braze alloy backing. For example, as shown in the drawing, the contact tape 1 and the contact pieces 3 are comprised of three bonded layers: a precious metal mating surface 31, a silver intermediate 32 and a braze alloy backing 33, which layers are shown in the enlarged cross section.
  • In order to manufacture an electrical contact arm with contacts on both sides, which can be used, for example, as a moveable contact arm for a relay, a metal blade 5 is provided with a through-hole 6 at the desired contact position. The metal blade 5 may be made of any material suitable for the desired application, for example, copper alloy. Then, a pair of cut contact pieces 3A, 3B are centered over both sides of the through-hole 6 with the braze backing 33 placed against the blade 5. Each contact piece 3A, 3B is larger in cross-sectional area than the through-hole 6 so that the through-hole 6 is completely covered on both sides of the metal blade 5 and the contact pieces 3A, 3B contact the respective surrounding surfaces of the metal blade 5.
  • As shown in FIG 2, a pair of electrodes 7, 8 are brought to the mating surfaces 31 of the contact pieces 3A, 3B. The electrodes 7, 8 exert a force on the contact pieces 3A, 3B to keep the pieces in position and to ensure acceptable electrical contact with the blade 5. A current is then passed through the first electrode 7, through the blade and contacts assembly 3A, 5 and 3B, to the other electrode 8 for a sufficient amount of time to melt the braze alloy backing 33 on both contact pieces 3A, 3B. The amount of current applied is dependent upon the compositions and other physical characteristics of the various elements.
  • After the current is stopped, the electrodes 7, 8 stay in place for a sufficient amount of time so the braze alloy can solidify. This method results in braze bonding each of the contact pieces 3A, 3B directly to the blade 5 and any excess braze material 34 flowing into the through-hole 6 which serves as a "braze reservoir". Once the braze has solidified, the electrodes 7, 8 are removed, as shown in FIG 3.
  • If desired, the method can also result in bonding the contact pieces 3A, 3B to one another. This can be accomplished by having the excess braze material 34 fill the through-hole 6 completely (as shown in FIG 3) or having the excess braze material 34 from each contact piece sufficiently join with one another in the through-hole 6.
  • As an example, a moveable contact arm for a relay was made using the method of the present invention having the following dimensions:
  • Contact pieces 3A, 3B: length and width 3.5 mm;
  • thickness of precious metal mating surface 31: 0.46mm(minimum);
  • thickness of silver intermediate layer 32: 0.12mm(maximum);
  • thickness of braze alloy backing 33: 0.02 mm to 0.04 mm;
  • thickness of contact arm blade 5: 0.127 mm;
  • diameter of through-hole 6: 2.39 mm.
  • The braze alloy backing 33 consisted of a common braze alloy composition, for example 15% Ag, 80% Cu and 5% P.
  • FIG 4 shows a relay 40 of the present invention. The relay 40 comprises a base 41, a coil assembly 42 that connects to the base 41, an armature 43, stationary contact members 44, 45 and a moveable contact arm 46 that is actuated by the armature 43 to contact the stationary contacts 44, 45. The moveable contact arm 46 is shown in more detail in FIG 5. The moveable contact arm 46 comprises a metal blade 46a having a through-hole 46b formed therethrough and a pair of contact pieces 46c, 46d that are joined to the metal blade 46a. The through-hole 46b acts as a reservoir to contain any excess joining material used to join the contact pieces 46c, 46d to the blade 46a. The relay 40, and the moveable contact arm 46, may be constructed by the method of the present invention. The embodiments described herein are merely illustrative of the principles of the present invention. Various modifications may be made thereto by persons ordinarily skilled in the art, without departing from the scope or spirit of the invention.
  • For example, the contact tape 1 may be in the form of single strips rather than on a spool 2. Also, the contact pieces 3A, 3B may be cut from the tape 1 in different shapes, for example, in rectangular or circular shapes. Also, the braze alloy backing 33 may consist of any known or conventional brazing material.
  • Further, the braze alloy backing 33 may be melted by another mechanism other than via the use of the electrodes 7, 8 and the application of current therebetween, for example, via the use of a heat chamber. Further, the electrodes 7, 8 may be replaced or supplemented by another mechanism to press and hold the contact pieces 3A, 3B against the metal blade 5.
  • Still further, the contact pieces may also be joined to the blade via any known or conventional metallurgical joining process, other than via brazing, such as, soldering or welding, using a suitable solder or joining material.

Claims (7)

  1. A method of manufacturing an electrical contact arm, comprising the steps of:
    providing a metal blade (3; 46a) having a through-hole (6; 46b) therein:
    providing a pair of contact pieces (3; 46c; 46d) each having a planar bottom surface greater than the through-hole (6; 46b) in said metal blade (3; 46a), each of said bottom surfaces being coated with a layer of joining material (33);
    positioning one of said contact pieces (3; 46c, 46d) on either side of said metal blade (3, 46a) so as to cover said through-hole (6; 46b) from either side;
    joining the contact pieces (3; 46c, 46d) to the metal blade (3; 46a) by applying heat for melting said layers of joining material (33) while pressing said contact pieces (3; 46c, 46d) from either side against said metal blade (3; 46a), the through-hole (6; 46b) serving as a reservoir where excess molten joining material (34) flows in; and
    solidifying the joining material.
  2. The method of claim 1, wherein the joining material comprises brazing material (33) and the step of joining the contact pieces (3; 46c, 46d) comprises brazing the contact pieces (3; 46c, 46d).
  3. The method of claim 2, further comprising the step of cutting said contact pieces (3; 46c, 46d) from a tape (1) consisting of contact material (31) that is coated on one side with said brazing material (33).
  4. The method of claim 2, wherein the step of brazing comprises resistance heating by applying a pair of electrodes (7, 8) to said contact pieces (3; 46c, 46d) and passing current therebetween.
  5. The method of claim 4, wherein the electrodes (7, 8) are arranged so as to press and hold the contact pieces (3; 46c, 46d) against said metal blade (3; 46a) until the brazing material (33) has solidified.
  6. The method of claim 1, wherein the step of solidifying comprises cooling the contact pieces (3; 46c, 46d).
  7. The method of claim 2, wherein the step of brazing comprises melting the layers of brazing material (33) until there is sufficient excess molten brazing material (34) in the through-hole (6; 46b) to braze the contact pieces (3; 46c, 46d) to one another.
EP97940680A 1996-09-19 1997-08-28 Method of manufacturing an electromechanical relay Expired - Lifetime EP0927427B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US71612296A 1996-09-19 1996-09-19
US716122 1996-09-19
PCT/US1997/015210 WO1998012723A1 (en) 1996-09-19 1997-08-28 An electromechanical relay and method of manufacturing same

Publications (2)

Publication Number Publication Date
EP0927427A1 EP0927427A1 (en) 1999-07-07
EP0927427B1 true EP0927427B1 (en) 2001-01-31

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP97940680A Expired - Lifetime EP0927427B1 (en) 1996-09-19 1997-08-28 Method of manufacturing an electromechanical relay

Country Status (7)

Country Link
EP (1) EP0927427B1 (en)
JP (1) JP3818393B2 (en)
KR (1) KR100473425B1 (en)
CN (1) CN1075235C (en)
DE (1) DE69704025T2 (en)
TW (1) TW357374B (en)
WO (1) WO1998012723A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT411157B (en) * 2002-02-21 2003-10-27 Stanzbiegetechnik Ges M B H METHOD FOR WELDING ELECTRICAL CONTACTS
CN102513678A (en) * 2011-12-13 2012-06-27 温州兴机电器有限公司 Multilayer metal plate stitch welding process

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2759074A (en) * 1952-10-16 1956-08-14 Square D Co Electric contact mounting
US3339048A (en) * 1965-10-14 1967-08-29 Texas Instruments Inc Switch having improved multiple blade assembly
DE4139998A1 (en) * 1991-12-04 1993-06-09 Siemens Ag, 8000 Muenchen, De CONTACT PIECE WITH A SILVER CONTACT PAD AND METHOD FOR ITS PRODUCTION

Also Published As

Publication number Publication date
TW357374B (en) 1999-05-01
DE69704025T2 (en) 2001-07-19
CN1075235C (en) 2001-11-21
EP0927427A1 (en) 1999-07-07
DE69704025D1 (en) 2001-03-08
WO1998012723A1 (en) 1998-03-26
KR20000048484A (en) 2000-07-25
JP2001500664A (en) 2001-01-16
JP3818393B2 (en) 2006-09-06
CN1231058A (en) 1999-10-06
KR100473425B1 (en) 2005-03-07

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