EP0903435B1

EP0903435B1 - Waterproofing membrane and the method for its manufacture

Info

Publication number: EP0903435B1
Application number: EP19980117400
Authority: EP
Inventors: Giorgio Pasetto; Giuseppe Modena
Original assignee: Pluvitec SpA
Current assignee: Pluvitec SpA
Priority date: 1997-09-17
Filing date: 1998-09-14
Publication date: 2004-02-25
Anticipated expiration: 2018-09-14
Also published as: IT1296530B1; EP0903435A3; EP0903435A2; ITVR970085A1; DE69821847D1

Description

This invention relates to a bitumen-polymer-based waterproofing membrane which is particularly suitable for the protection of buildings and civil engineering works in general from rainwater or groundwater, as well as for the containment of water, e.g. in water catchment tanks for irrigation, and a new process for the manufacture of that membrane.
Bitumen-polymer-based waterproofing membranes have been produced for many years and can be found on the market e.g. in the form of rolls ready for application to the surfaces of structures which require waterproofing. In general these membranes comprise:

a bituminous waterproofing material based on "distilled" or "oxidised" bitumen, appropriately mixed with thermoplastic polymers to modify its strength properties at high and low temperatures, and
one or more "cores" or mechanical reinforcements intended to provide the final membrane with the required properties of resistance to the stresses to which the membrane is likely to be subjected when in use.

The following are currently used as cores: glass fleece, non-woven materials and synthetic fibre, plastics films, metal sheets, glass nets and fabrics, cardboard, paper and many others.
Surface finishing materials are also used on one or both sides of the membrane, and these may have various functions, e.g. an aesthetic function as in the case of the "self-protected" membranes, i.e. coated on the top side or on the surface intended to remain visible, e.g. with slate chippings or metal sheeting, or a functional function, as in the case of membranes lined with films of a textile nature in order to improve their paintability or the application of adhesives or also membranes coated with anti-adherent materials which make them easier and more convenient to lay, preventing sticking between the various turns of the membrane when it is wound in a roll.
The thermoplastic polymers used to modify the bitumen to obtain waterproofing membranes are those of the polyolefin series and the styrene-butadiene series.
Bituminous membranes containing modifying agents of the polyolefin series are described as BPP membranes (bitumen - polymer plastomer) or also in some cases "bitumen-APP membranes", as the first modifying agent historically introduced for modifying bitumen for obtaining plastomer waterproofing materials was in fact APP (atactic polypropylene). These membranes are more resistant to high temperatures and are plastomers, i.e.they have a plastic behaviour, that is under the effect of an induced deformation the waterproofing material follows the deformation without offering any constant resilient elasticity.
On the other hand bituminous membranes containing modifying agents of the styrene-butadiene copolymer series are described as BPE membranes (bitumen-polymer-elastomer) or bitumen-SBS membranes, in that the main modifying agent is in fact styrene-butadiene-styrene. These have better resistance to low temperatures and are elastically resilient, that is under the effect of an induced deformation the waterproofing material tends to return to its original dimensions. In addition to this, waterproofing materials of the BPE type have a greater tear strength.
To sum up, the advantages and the corresponding limitations of waterproofing materials of the BPP type and the BPE type are, in the case of the former, greater resistance to heat and solar radiation, and in particular UV radiation, and plasticity, while in the case of the latter, better resistance to low temperatures, better bonding to the substrate and elasticity.
In general waterproofing membranes are manufactured by impregnating the core with the waterproofing material. The core or mechanical support is coated on one or both sides with a waterproofing material previously prepared in suitable heated mixers in which the bitumen has suitable polymers and other additives added to it. The bituminous material is then cooled, surface treated and finally rolled into rolls of predetermined length.
impregnation, both by immersion and by spreading, is a difficult operation in that the desired thickness has to be imparted to the membrane and reinforcing material, especially when porous products, such as for example polyester non-wovens, have to be perfectly impregnated to ensure absolute uniformity in the finished product.
In addition to this, the impregnating operation tends to set up tension in the membrane as it is being formed, which is subjected to a variable amount of elongation. This elongation is "frozen" by the immediately subsequent cooling of the membrane and constitutes an important parameter for the quality of the finished product. An assessment of the magnitude of this effect may be made by measuring "dimensional stability" on the finished product, that is the free shrinkage which the membrane exhibits when after heating it is left free to recover the elongation imparted at the time of its manufacture. The greater the shrinkage the less will be the stability of the membrane.
US-A-2 893 889 discloses a membrane used as building-covering which comprises a base sheet of cellulosic fibers saturated with asphalt or bitumen on which three layers are applied, namely a first layer of thermoplastic bituminous composition containing glass filaments or inorganic filler, a second layer of asphalt and a third layer of roofing granules. The main object of this known prior art is to provide a bituminous composition having enhanced fire-resistant qualities with respect to the other prior art of the same general character, with no provision of dimensional stability and long lasting protection.
US-A-4 055 453 relates to a process for manufacturing a laminated bituminous composition comprising a base sheet of ordinary bituminous membrane including a fibre fabric or similar material impregnated with a first layer molten bitumen, coated on all part of both or one face with a second layer of bitumen in turn laminated with a third layer of denaturated bitumen compound including natural or synthetic rubber blended with synthetic resin. Thanks to such arrangement, the composition is particularly suitable to impart high tackiness at ambient temperature while avoiding pouring of molten bitumen common to conventional process. Optionally, the membrane may be covered with a release sheet laid over the whole surface of the compound bitumen layer.
US-A-4 755 409 teaches a waterproof laminate comprising a reinforcing core sheet with three superposed layers secured to the core on opposite side thereof, including a first layer of bitumen, a second compound bitumen containing a material selected from the group of synthetic or natural rubber, and natural or synthetic resin secured to the first one, a third layer consisting of an elastomeric sheet, and a release sheet secured to the second compound bitumen. Such known waterproof laminate is mainly directed to resist penetration of water and vapour therethrough and to facilitate installation thereof but has no provision for enhancing dimensional stability of the overall membrane.
The principal object of this invention is to provide waterproofing membranes with enhanced dimensional stability which are therefore suitable for providing lasting and effective protection over a long period of time.
Another object of this invention is to provide a process for the manufacture of bituminous waterproofing membranes which in addition to yielding membranes with a high degree of dimensional stability is easy to implement and does not require any major investment in plant.
According to a first aspect of this invention, a waterproofing membrane is provided which, in accordance with claim 1, comprises a core and three different layers of waterproofing material secured to said core, in which one of the layers is impregnating the core, characterised in that the first layer saturating said core comprises a waterproofing material based on bitumen modified with polymers of low molecular weight of a partly polar nature having stabilising and compatibility-enhancing properties, the second layer at one side or both sides of the first layer comprises a waterproofing material different from that of the first layer and based on both elastomer and plastomer, the third layer at one side of said second layer comprises a waterproofing material including compatibility-enhancing polymers of low molecular weight.
According to another aspect of this invention, a process is provided for the manufacture of waterproofing membranes which, in accordance with claim 4, comprises three successive steps, namely a first step of application to the core of a first layer of waterproofing material based on bitumen modified with thermoplastic polymers of low molecular weight having a partly polar nature and having stabilising and compatibility-enhancing properties until the core becomes saturated, a second step of application to at least one of the surfaces of the core saturated with the waterproofing material of a second layer of elastomer or plastomer-based waterproofing material which is different from that applied in the first step, a third step of application to one side of the membrane treated in the second step of a third layer of a waterproofing material modified with compatibility-enhancing polymers of low molecular weight.
According to a third aspect of this invention, a plant is provided for the production of waterproofing membrane in three layers characterised in that it comprises a first station in which a core is immersed in a bath of waterproofing mass or material having stabilising and compatibility-enhancing characteristics with respect to the two materials subsequently applied to the core, until saturation, a second station in which the core saturated with waterproofing material has a layer of waterproofing material based on both elastomer and plastomer applied to at least one side, and a third station in which a layer of waterproofing material including compatibility-enhancing materials is spread onto the core from the said second station.
The plant according to this invention will be further described below with reference to the appended drawings, in which:
The sole Figure shows a diagrammatical lateral elevation view of a three station plant according to the invention.
The waterproofing material applied to the core is based on bitumen modified with low molecular weight polymers of a partly polar nature, e.g. EVA (ethylene vinyl acetate), low molecular weight acrylic copolymers and others capable of performing the same bonding function between waterproofing materials.
This modification is effective from the chemical point of view in that it confers stability and compatibility with the materials subsequently applied to the core. The quantity of waterproofing material applied must in practice be limited to saturation of the core, and the latter may be of any suitable type.
Three examples are provided below by way of non-limiting indicative examples of compositions which can be used to provide the waterproofing/compatibility-enhancing material.

Example 1

Type 180/200 distilled bitumen 85%

EVA 10%

Polyethylene wax 5%

Example 2

Type 180/200 distilled bitumen 80%

Isotactic polypropylene copolymer 300,000 cps 10%

EVA 10%

Example 3

Type 85/25 oxidised bitumen 80%

Radial SBS type elastomer 5%

Polypropylene homopolymer 10%

Filler with a "10,000 mesh" particle size 5%
As will be seen in the drawing, the operation of applying this compatibility-enhancing material can be performed by immersing core 1 through use of a suitable immersion roll 2, which can be adjustably set at various levels with respect to a trough 3 containing the bath of waterproofing/compatibility-enhancing material in a first treatment station 4. The immersion operation is performed in combination with a rolling operation performed by a squeezing roller diagrammatically represented by a pair of cylinders 5 and 6 controlled by a balance lever mechanism to exert a maximum pressure of 60 kg/cm² on core 1.
Core 1 is therefore saturated at station 4, and the limitation on the quantity of waterproofing material must in practice be limited to saturation of the core otherwise the compatibility-enhancing effect may be compromised.
It is important that core 1 is not subjected to any kind of tension, and as a result the operation of applying the waterproofing/compatibility-enhancing material and that of rolling must be controlled electronically so that they take place under closely controlled conditions. Core 1 is therefore carefully "monitored" to avoid stretching during application.
As a rule the passage through second treatment station 7 should take place at a predetermined distance from first station 4 so the saturated core can cool in ambient air with a temperature drop of approximately 30°C.
At second station 7 the second type of waterproofing material, for example one with a plastomer or elastomer base, respectively, and therefore of the BPP or BPE type, is applied. The type of waterproofing material is different from that present at station 4 and is therefore prepared and delivered independently by separate pipes (not shown).
At station 7 the waterproofing material can be applied to the upper or lower side or both sides according to the nature of the final membrane which it is desired to obtain.
The cooling of core 1, which would have an adverse effect on the bonding of subsequent layers when the compatibility-enhancing material was not present, provides the additional benefit of improving the dimensional stability of the membrane because it confers sufficient rigidity upon the core, even if weakly impregnated or, better, saturated with waterproofing material, to withstand the tensions subsequently induced during the manufacturing process.
At second station 7 there is provided for example an immersion roller 8 which is preferably interfaced electronically with a drive motor which is capable of controlling the tension on the core between station 4 and station 7 and an inking roller 9 as well as two pairs of calendering rollers 10, 11 and 12, 13.
At a third station 14 there is provided an inking roller 15 and a spreading roller 16, which apply a further layer of waterproofing material which is different from the previous materials and is therefore likewise produced and delivered in a totally independent way to one side of the membrane being formed. The waterproofing material in this third station comprises bitumen suitably modified with appropriate compatibility-enhancing agents similar to those used at station 4, that is with polymers of the EVA (ethylene vinyl acetate) and low molecular weight acrylic type.
The advantages resulting from this invention are that membranes having improved dimensional stability are obtained by virtue of the process of manufacture in three passes, all of which are controlled electronically, and in that more cohesive composite membranes are obtained without any danger of detachment between the layers. In addition to this, the use of chemical modifying agents as described above further ensures compatibility between the layers so as to ensure the required uniformity in the composite membrane.
These advantages are particularly apparent in membranes intended for roofing purposes, which bond better to the substrate and are therefore able to take advantage of the benefits due to the different waterproofing materials, such as strong bonding on the underside in contact with the substrate and high resistance to radiation on the upper face directly exposed to atmospheric agents.

Claims

A waterproofing membrane comprising a core and three different layers of waterproofing material secured to said core, in which one of the layers is impregnating the core, characterised in that the first layer saturating said core comprises a waterproofing material based on bitumen modified with polymers of low molecular weight of a partly polar nature having stabilising and compatibility-enhancing properties, the second layer at one side or both sides of the first layer comprises a waterproofing material different from that of the first layer and based on both elastomer and plastomer, the third layer at one side of said second layer comprises a waterproofing material including compatibility-enhancing polymers of low molecular weight.
Membrane according to claim 1, characterised in that the said low molecular weight polymers of a partly polar nature comprise EVA (ethylene vinyl acetate) and low molecular weight acrylic copolymers.
Membrane according to claim 2, characterised in that said waterproofing material including compatibility-enhancing products based on low molecular weight polymers comprises bitumen modified with polymers such as EVA (ethylene vinyl acetate) and low molecular weight acrylic polymers.
Process for the manufacture of a waterproofing membrane, said membrane having a core and three layers, the process comprising three steps, namely:

a first step of application to the core of a first layer of waterproofing material based on bitumen modified with thermoplastic polymers of low molecular weight having a partly polar nature and having stabilising and compatibility-enhancing properties until the core becomes saturated,

a second step of application to at least one of the surfaces of the core saturated with the waterproofing material of a second layer of elastomer or plastomer-based waterproofing material which is different from that applied in the first step;

a third step of application to one side of the membrane treated in the second step of a third layer of a waterproofing material modified with compatibility-enhancing polymers of low molecular weight.
Process according to claim 4, characterised in that the said core saturated with waterproofing material is allowed to cool between the first and the second step so that it acquires sufficient rigidity to withstand subsequent induced tensions and therefore improved dimensional stability.
Process according to claim 4 or 5, characterised in that the said operation of applying the said compatibility-enhancing material takes place by immersing the core in a bath of waterproofing/compatibility-enhancing material for saturating the said core.
Process according to claim 6, characterised in that the said immersion operation is performed in combination with a calendering operation.
Process according to any one of claims 4 to 7, characterised in that the said operation of applying the waterproofing/compatibility-enhancing material and calendering are controlled electronically so that they are carried out under strictly controlled conditions.
Process according to any one of claims 4 to 8, characterised in that after the operation of applying the waterproofing/compatibility-enhancing material a stage of cooling the core is provided.
Process according to claim 8 or 9, characterised in that plastomer or elastomer-based waterproofing material is applied to at least one side of the said core saturated with waterproofing/compatibility-enhancing material.
Process according to claim 10, characterised in that a further layer of waterproofing material which is different from the foregoing, comprising bitumen modified with compatibility-enhancing agents selected from polymers of the EVA (ethylene vinyl acetate) and low molecular weight acrylic type, is applied to only one side of the membrane being formed.
Plant for the production of a waterproofing membrane in three layers according to any claims 1 to 3, characterised in that it comprises a first station (4) in which a core is immersed in a bath of waterproofing mass or material having stabilising and compatibility-enhancing characteristics with respect to the two materials subsequently applied to the core, until saturation, a second station (7) in which the core saturated with waterproofing material has a layer of waterproofing material based on both elastomer and plastomer applied to at least one side, and a third station (14) in which a layer of waterproofing material including compatibility-enhancing materials is spread onto the core from the said second station.
Plant in accordance with claim 12, characterised in that the said first station (4) comprises a bath of waterproofing/compatibility-enhancing material, at least one immersion cylinder or roller (2) which can be adjustably set at different levels with respect to the bath, and at least one pair of calendering rollers (5, 6).
Plant according to claim 12 or 13, characterised in that the said second station (7) comprises a bath of waterproofing material, at least one immersion cylinder or roller (8) which can be adjustably set at different levels with respect to the said bath, an inking roller (9) and at least one pair of squeezing rollers (10, 11 and 12, 13).
Plant according to claim 14, characterised in that the said third station (14) comprises a bath of waterproofing material, an inking roller (15) and a spreading roller (16), which apply a further layer of waterproofing material which is different from the foregoing to one side of the membrane being formed.
Plant according to any one of claims 13 to 15, characterised in that it comprises electronic control means for both the operation of applying the waterproofing/compatibility-enhancing material and the calendering operation.