EP0890803A1 - Wassererhitzer mit doppelter Kammer zur direkten Wärmeübertragung - Google Patents
Wassererhitzer mit doppelter Kammer zur direkten Wärmeübertragung Download PDFInfo
- Publication number
- EP0890803A1 EP0890803A1 EP97401618A EP97401618A EP0890803A1 EP 0890803 A1 EP0890803 A1 EP 0890803A1 EP 97401618 A EP97401618 A EP 97401618A EP 97401618 A EP97401618 A EP 97401618A EP 0890803 A1 EP0890803 A1 EP 0890803A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- housing
- burner
- tank
- lining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/10—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium
- F24H1/107—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium using fluid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/06—Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour
Definitions
- the present invention relates to a direct contact water heater and more particularly a double section water heater comprising two hot springs; a first source of water at high temperature and a second source of hot water at a lower temperature.
- a single or multiple burner or a single source of heat e.g. flue gases
- One aspect of the invention is to provide a contact water heater direct with double sections of hot water tank, water in said tanks being heated by a single burner or burners multiple and / or external heat sources (including hot gases from other devices).
- Another aspect of the present invention is to provide a direct contact water heater with double tank sections hot water, the water in it being at different temperatures, characterized in that each of the sections is placed side by side to obtain a compact water heater housing.
- Another aspect of the present invention is to provide a direct contact heater with double tank sections hot water stacked vertically on top of each other and ensuring efficient cooling with combustion gases which rise through the sections before exiting at the top of the housing.
- Another aspect of the present invention is to provide a direct contact water heater with double tank sections hot water and using a submerged burner housing, which is used as a unique heat source to heat water that infiltrates through the linings associated with each section of the water heater.
- Another aspect of the present invention is to provide a direct contact water heater with double sections of water tank hot, having a second source of hot gases from a system external, connected to the first or second section of the water heater.
- Another aspect of the present invention is to provide a direct contact water heater with double tank sections hot water producing two hot water sources at temperatures different, characterized in that the efficiency of the water heater increases clearly depending on the temperature of the intake water supplied to sections connected in a closed loop or an open loop provided with external heat exchange devices.
- the present invention provides a direct contact water heater comprising a housing comprising a first water spray nozzle disposed in the housing so as to spray the water to be heated towards descending on a first lining of heat exchange elements retained in a housing region by a support means.
- a exhaust pipe communicates with an upper part of the housing.
- a burner is connected to the lower part of the housing and is arranged to heat the water in a first water tank placed inside the housing.
- a second lining of heat exchange elements is kept apart above the first water tank by some other means of support.
- a second water spray nozzle is provided in the housing above the second packing for spraying water down on the second packing.
- An intermediate hot water tank is provided in the housing in a space located under the first lining.
- a way passage is provided for the passage of hot gases through the second packing so as to direct them towards a space situated above the intermediate tank.
- a pump means is associated respectively with the first and second water tanks so as to circulate the hot water from these to respective external exchange devices heat, connected respectively to a closed circuit, and using the burner unique.
- the water heater 10 includes a housing 11 comprising a first water spray nozzle 12 placed above a first lining 13 of heat exchange elements, not illustrated but obvious to those skilled in the art, maintained in an upper section or second B, identified by the reference number 14, of the housing.
- the lining 13 is retained in this section at a location predetermined by a support means 15, in particular an appropriate grid fixed all around of the inner surface of the circular wall 11 'of the housing.
- An exhaust gas line 16 is located at the end of the upper part B of the housing to allow hot gases to escape cooled produced by a burner 17 located at the lower part A illustrated by the reference number 18, and constituting the high temperature portion of the water heater 10.
- the burner 17 is connected to the wall 11 'of the housing 11 and is arranged to heat the water in a first water tank 19 of the lower part A of the housing 11.
- the burner 17 produces a flame 17 'in a region 20 of the lower part 18, above of the first tank 19.
- the burner 17, as illustrated, is a burner with natural gas capable of heating the water seeping into the lower part of the first tank 19, at temperatures sufficient for use in heating systems of large buildings, especially hotels, hospitals, etc.
- a second lining 21 of heat exchange elements is placed above the first water tank 19 and is further maintained in this place by a support means 22.
- the lower part 18, or at least the part containing the burner 17, can be constructed with a double wall such as illustrated in 23 to constitute a water cooling jacket around the burner compartment 10.
- a water spray nozzle 24 is also fixed above the second lining 21 to spray the water towards the low on the second lining 21 so as to heat the water by contact with the heat exchange elements and with the ascending hot gases produced by the flame 17 '.
- a second water tank 25 is associated with the upper part B and consists of an intermediate wall 26 fixed so circumferential on the internal surface of the wall 11 '. It has a central pipe 27 and a cap 28 which is arranged spaced above of line 27 so as to allow hot gases to rise from the part A which rise through the second water tank 25 of part B to heat the water which circulates through the lining 13 and which is sprayed by the spray nozzle 12.
- the cap 28 prevents water flowing by gravity through the upper packing 13, to enter the part hot lower part of the burner.
- the gases which rise from the hot part A, illustrated by the arrows 29, are in the form of hot vapor which condenses as it rises through the lining 13 and through the cooler water (less hot) sprayed from the upper nozzle 12.
- this hot steam condenses and flows from below to the second tank 25. Consequently, the water present in the lower tank 19 is at a temperature much higher than that of the water in the upper tank 25 because the single source of heat is arranged in the lower part A of the housing and cools down as it rises through the lower lining 21 and the upper lining 13, same as through the water sprayed through the spray nozzles.
- the water sprayed in the hot part particularly by the spray nozzle 24 may be at a temperature of around 60 ° C, while the water entering the upper part through the nozzle 12 can be at a temperature of around 6 ° C.
- the gases that exit through the line 16 are cooled to a temperature below about 38 ° C (37.7 ° C in particular), thus ensuring very efficient operation.
- the water present in the hot part 18 and in the first tank 19 can be used for applications industrial and, as illustrated, this hot water recirculates in a circuit closed 30 through a heat exchange device 31 by means of a pump 32 connected to the closed circuit 30.
- a pump 32 connected to the closed circuit 30.
- the water is cooled by heat exchange with the fluid which enters the heat exchange device 31 through an inlet 33.
- This cooled hot water comes out of outlet 34 directly connected to the nozzle of water spray 24 where it is sprayed and heated to a temperature upper as it flows through the packing, the hot gases ascending and the flame 17 '.
- the water entering the heat exchange device 31 can be at a temperature of about 74 ° C and heats up in the heat exchange device 31 thanks to the water from the hot water tank 19 for leaving said heat exchange device, at an outlet 35, at a temperature of about 85 ° C.
- the water from the tank 25 also recirculates by means of a pump 32 'in a closed circuit 36 through a heat exchange device 37, and returns to the nozzle of spraying 12 through line 34 '.
- This water is at a temperature lower and can be used as a heat source to heat water domesticated.
- domestic water can be kept in a tank (not shown).
- Hot water from the tank enters the exchanger heat 37 at an inlet 38 at a temperature of about 10 ° C and will come out at an outlet 39 at a temperature of about 60 ° C.
- the hot water of the circuit closed 36 which leaves the heat exchange device 37 is sent to the spray nozzle 12 and is typically found at a temperature about 15.5 ° C. This cooled water is sufficient to cool the gases hot which rise through the lining 13, this allowing the water heater 10 double section to obtain an efficiency of about 95% using a single burner or multiple burners 17.
- the fresh water supplied by the city illustrated in 25 'can also be supplied to the spray nozzle 12 by closing a 25 '' valve and opening a valve 26 '. Hot water can then be sent to the pipe outlet 36 'by opening a 36' 'valve, and be used for applications industrial or commercial.
- the contact water heater 10 direct and to two sections of the present invention can also be connected to a secondary heat source 45.
- a secondary heat source 45 In the present case of FIGS. 2a and 2b, it this is a kettle located in a remote location, so as to recover hot gases from the kettle which are normally at temperatures about 315.5 ° C, and reinsert them into double water heaters section.
- an outlet 46 for recovering gas hot is provided in the wall 11 'of the housing 11 and communicates with a space 47 located above the water tank 25 and under the first lining 13.
- the hot gases rising through this space 47 and produced by burner 17 are at a temperature of about 77 ° C and saturated in water vapor. Therefore, the secondary source of hot gases will cause so that the temperature of the water flowing through the packing 13 will rise and cause the temperature of the water in tank 25 to rise upper part B.
- an outlet 46 'for recovering gases hot is provided in the wall 11 'of the housing 11 and communicates with a space 47 'located above the water tank 19 and under the lining 21.
- Figure 3 is another version of the external system recovery of hot gases according to which the gas inlet 46 is illustrated here as being connected to the wall 11 'of the housing 11 but communicates with a space 20 above the first water tank 19 of the lower part A.
- FIG 4 we illustrate another construction of the housing 111 of the water heater 10 in direct contact with the present invention.
- the two parts 114 and 118 are arranged side by side so that the height of the housing 111 is reduced by considerably. This may be desirable depending on the location in which accommodation must be provided.
- the lower part of the first part 114 constitutes the water tank 125 placed under a lining 113.
- the spray nozzle 112 is placed above the packing 113 and under an exhaust pipe 116.
- a passage communicating 48 is provided between region 49 located above reservoir 125 and the end upper 50 of the second part 118 in the vicinity of the nozzle of water spray 124.
- the water tank 119 in part 118 is located at the base of part 118 and under lining 121.
- a burner housing 120 is introduced into the tank 119 and we immerse it at least partially in the latter. As illustrated in Figures 5 and 6, the burner 117 produces a flame 117 'inside the housing 120 for heating the water surrounding housing 120.
- the burner housing 120 is provided with an outlet exhaust 54 located above the high water level present a the interior of the tank 119, allowing the discharge of hot gases to from the burner chamber 120, as illustrated by the arrows 55.
- the output exhaust 54 is formed at one end of a vertical section 57 of duct of the housing 120, the exhaust orifice 54 being in the form a side opening located opposite the open region 58 above the water present in the tank 119. Because the gases discharged through the orifice exhaust 54 are very hot, it is necessary to cool the section vertical pipe 57 and deflecting the rising gases towards the droplets of water which escape by gravity from the lining 121. Consequently, one thus obtains a gas cooling structure.
- the gas cooling structure is provided by the wall upper 59 of the vertical pipe defining an open basin 60 at its upper part and extending in 60 'around the walls to accumulate the water droplets 63 which flow downwards from the lining 121 to cool the top wall 59.
- deflection plates 61 and 62 are placed so as to direct the escaping hot gases, as this is represented by the arrow 55, upwards towards the second lining, to cool these hot gases by heat exchange with the water droplets 63 which come from the lining 121.
- the deflection plate 62 is arched and more narrower than the exhaust port 54 to deflect the gases upward and next to.
- Another deflection plate 64 is provided on each side of the base of the plate 62 to ensure another deflection of the hot gases towards the up and to the sides.
- These deflection plates 62 and 64 are fixed to the housing 120 of the burner, as illustrated in FIG. 6.
- the deflection plate 62 is fixed along the upper edge of the outlet orifice 54 to send the hot gases against the deflection plate 62 in order to disperse the gases, as shown by arrow 55.
- part A is the part producing high temperature water and using a gas burner to give the energy necessary for the production of water at high temperature.
- the part B is used to recover the energy present in the gases which rise from part A and this produces hot water which is sufficient for constitute a source of hot water capable of heating the tap water supplied by the municipality in proportion to the energy available in the gases warm, and keep them inside the tank 25 of part B.
- the energy available in part B is a function of the gas temperature of conduct.
- FIG 7 shows the efficiency curve 70 of the double section water heater of the present invention compared with that of a direct contact water heater with single hot water tank 71.
- the efficiency curve 72 of the hot part A of the double burner we have also shown the efficiency curve 72 of the hot part A of the double burner and we can note that the effectiveness of this part A considered independently falls quickly once the temperature of the inlet water, i.e. the water to the spray nozzle 24, is above 60 ° C.
- the combination with part B allows the water heater to increase its efficiency above 90% with the parameters illustrated in table 1.
- the water heater 10 when it is in "summer", does not require high temperature water from the lower part A to heat buildings.
- the water in tank 19 can recirculate directly to the spray nozzle 24, through the circuit 30 'diversion, to produce saturated hot gases which will rise to through part B to give heat to the hot spring domesticated.
- the same effect could be achieved by simply closing the fluid circulation on the secondary side of the heat exchanger 31 (entry 33 and exit 35).
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Heat-Pump Type And Storage Water Heaters (AREA)
- Instantaneous Water Boilers, Portable Hot-Water Supply Apparatuses, And Control Of Portable Hot-Water Supply Apparatuses (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/655,609 US5765546A (en) | 1996-05-30 | 1996-05-30 | Direct contact water heater with dual water heating chambers |
FR9613417A FR2749376B1 (fr) | 1996-05-30 | 1996-11-04 | Chauffe-eau a contact direct a double chambre |
DK97401618T DK0890803T3 (da) | 1996-05-30 | 1997-07-07 | Vandvarmer med dobbeltkammer med direkte varmeoverføring |
EP97401618A EP0890803B1 (de) | 1996-05-30 | 1997-07-07 | Wassererhitzer mit doppelter Kammer zur direkten Wärmeübertragung |
DE69708076T DE69708076T2 (de) | 1996-05-30 | 1997-07-07 | Wassererhitzer mit doppelter Kammer zur direkten Wärmeübertragung |
CZ19972208A CZ292754B6 (cs) | 1996-05-30 | 1997-07-11 | Kotel pro ohřev vody s přímým dotykem |
HU9701836A HU219323B (en) | 1996-05-30 | 1997-11-05 | Direct water heating apparatus with two chambers |
CA002229671A CA2229671C (en) | 1996-05-30 | 1998-02-16 | Direct contact water heater with dual water heating chambers |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/655,609 US5765546A (en) | 1996-05-30 | 1996-05-30 | Direct contact water heater with dual water heating chambers |
EP97401618A EP0890803B1 (de) | 1996-05-30 | 1997-07-07 | Wassererhitzer mit doppelter Kammer zur direkten Wärmeübertragung |
CZ19972208A CZ292754B6 (cs) | 1996-05-30 | 1997-07-11 | Kotel pro ohřev vody s přímým dotykem |
CA002229671A CA2229671C (en) | 1996-05-30 | 1998-02-16 | Direct contact water heater with dual water heating chambers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0890803A1 true EP0890803A1 (de) | 1999-01-13 |
EP0890803B1 EP0890803B1 (de) | 2001-11-07 |
Family
ID=31950578
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97401618A Expired - Lifetime EP0890803B1 (de) | 1996-05-30 | 1997-07-07 | Wassererhitzer mit doppelter Kammer zur direkten Wärmeübertragung |
Country Status (8)
Country | Link |
---|---|
US (1) | US5765546A (de) |
EP (1) | EP0890803B1 (de) |
CA (1) | CA2229671C (de) |
CZ (1) | CZ292754B6 (de) |
DE (1) | DE69708076T2 (de) |
DK (1) | DK0890803T3 (de) |
FR (1) | FR2749376B1 (de) |
HU (1) | HU219323B (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016123536A1 (en) | 2015-01-30 | 2016-08-04 | Schneider Electric USA, Inc. | Interior comfort hvac user-feedback control system and apparatus |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6427638B1 (en) * | 2001-03-09 | 2002-08-06 | Chris Kolbusz | Water heater apparatus |
CN100455947C (zh) * | 2002-12-19 | 2009-01-28 | 胡晓平 | 直燃式双效热力机 |
US20090215375A1 (en) * | 2003-03-06 | 2009-08-27 | Greenvex | Fan Assemblies, Mechanical Draft Systems and Methods |
US20070209653A1 (en) * | 2003-03-06 | 2007-09-13 | Exhausto, Inc. | Pressure Controller for a Mechanical Draft System |
DE10316874B4 (de) * | 2003-04-11 | 2008-04-03 | Thermoselect Ag | Verfahren zur Schockkühlung von Hochtemperaturgasen |
WO2005005893A1 (en) * | 2003-07-11 | 2005-01-20 | Houle Andre | Multicompartment hot water tank |
US6971335B2 (en) * | 2003-08-20 | 2005-12-06 | Paloma Industries, Limited | Water heater |
CN100359237C (zh) * | 2005-08-16 | 2008-01-02 | 江苏双良锅炉有限公司 | 气液气——高效锅炉排烟热能回收装置 |
US7258080B2 (en) * | 2005-09-08 | 2007-08-21 | Rheem Manufacturing Company | Fuel-fired dual tank water heater having dual pass condensing type heat exchanger |
US20070072138A1 (en) * | 2005-09-23 | 2007-03-29 | Exhausto, Inc. | Atmosphere-control-system design programs and methods |
US7644686B2 (en) * | 2006-07-19 | 2010-01-12 | Aos Holding Company | Water heating distribution system |
US20080178866A1 (en) * | 2007-01-30 | 2008-07-31 | Trevor Davies | Snow melting system and method with direct-contact water heater |
WO2010108281A1 (en) * | 2009-03-26 | 2010-09-30 | Fadi Eldabbagh | System to lower emissions and improve energy efficiency on fossil fuels and bio-fuels combustion systems |
US8986430B2 (en) | 2009-08-03 | 2015-03-24 | Fluor Technologies Corporation | Low-energy waste gas cooling using direct contact condenser |
US8844471B2 (en) | 2010-06-14 | 2014-09-30 | Gas Technology Institute | Integrated contact condensing water heater |
CA2797554C (en) | 2011-11-30 | 2018-12-11 | Energy Heating Llc | Mobile water heating apparatus |
US9683428B2 (en) | 2012-04-13 | 2017-06-20 | Enservco Corporation | System and method for providing heated water for well related activities |
US9328591B2 (en) | 2012-08-23 | 2016-05-03 | Enservco Corporation | Air release assembly for use with providing heated water for well related activities |
RU2522716C2 (ru) * | 2012-09-21 | 2014-07-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Астраханский государственный университет" | Контактный водонагреватель |
WO2016135764A1 (en) * | 2015-02-27 | 2016-09-01 | Barbagli Francesco | Heat exchanger |
US10323200B2 (en) | 2016-04-12 | 2019-06-18 | Enservco Corporation | System and method for providing separation of natural gas from oil and gas well fluids |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2838135A (en) * | 1954-01-26 | 1958-06-10 | Pilo Claes Wilhelm | Process for the recovery of heat from hot gases |
FR2244968A1 (de) * | 1973-09-25 | 1975-04-18 | Hanrez Sa J Atel | |
EP0172660A2 (de) * | 1984-07-20 | 1986-02-26 | I. Krüger A/S | Verfahren und Vorrichtung zur Ausnutzung der Kondensationswärme des im Abgas enthaltenen Wassers |
EP0181248A1 (de) * | 1984-10-16 | 1986-05-14 | Gaz De France | Verfahren zum Erhitzen einer Flüssigkeit mittels Tauchverbrennung und Anlage zum Durchführen dieses Verfahrens |
US5293861A (en) | 1993-01-25 | 1994-03-15 | Sofame Inc. | Direct contact water heater with hybrid heat source |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1527740A (en) * | 1924-02-09 | 1925-02-24 | Jacob A Lipshitz | Water heater |
US3204629A (en) * | 1963-06-14 | 1965-09-07 | Jr Robert P Newton | Water heater |
US3386436A (en) * | 1965-10-28 | 1968-06-04 | Miyahara Kingo | Water heaters |
US4753220A (en) * | 1987-02-05 | 1988-06-28 | Ludell Manufacturing Company | Direct contact water heater |
GB8905969D0 (en) * | 1989-03-15 | 1989-04-26 | British Gas Plc | Water heater |
US5305735A (en) * | 1993-03-29 | 1994-04-26 | Welden David P | Direct fired hot water generator with more than one heat exchange zone |
-
1996
- 1996-05-30 US US08/655,609 patent/US5765546A/en not_active Expired - Lifetime
- 1996-11-04 FR FR9613417A patent/FR2749376B1/fr not_active Expired - Lifetime
-
1997
- 1997-07-07 EP EP97401618A patent/EP0890803B1/de not_active Expired - Lifetime
- 1997-07-07 DK DK97401618T patent/DK0890803T3/da active
- 1997-07-07 DE DE69708076T patent/DE69708076T2/de not_active Expired - Fee Related
- 1997-07-11 CZ CZ19972208A patent/CZ292754B6/cs not_active IP Right Cessation
- 1997-11-05 HU HU9701836A patent/HU219323B/hu not_active IP Right Cessation
-
1998
- 1998-02-16 CA CA002229671A patent/CA2229671C/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2838135A (en) * | 1954-01-26 | 1958-06-10 | Pilo Claes Wilhelm | Process for the recovery of heat from hot gases |
FR2244968A1 (de) * | 1973-09-25 | 1975-04-18 | Hanrez Sa J Atel | |
EP0172660A2 (de) * | 1984-07-20 | 1986-02-26 | I. Krüger A/S | Verfahren und Vorrichtung zur Ausnutzung der Kondensationswärme des im Abgas enthaltenen Wassers |
EP0181248A1 (de) * | 1984-10-16 | 1986-05-14 | Gaz De France | Verfahren zum Erhitzen einer Flüssigkeit mittels Tauchverbrennung und Anlage zum Durchführen dieses Verfahrens |
US5293861A (en) | 1993-01-25 | 1994-03-15 | Sofame Inc. | Direct contact water heater with hybrid heat source |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016123536A1 (en) | 2015-01-30 | 2016-08-04 | Schneider Electric USA, Inc. | Interior comfort hvac user-feedback control system and apparatus |
Also Published As
Publication number | Publication date |
---|---|
HU9701836D0 (en) | 1997-12-29 |
DE69708076T2 (de) | 2002-03-14 |
DK0890803T3 (da) | 2002-02-18 |
HU219323B (en) | 2001-03-28 |
HUP9701836A1 (hu) | 1999-03-29 |
FR2749376A1 (fr) | 1997-12-05 |
EP0890803B1 (de) | 2001-11-07 |
FR2749376B1 (fr) | 1998-07-17 |
US5765546A (en) | 1998-06-16 |
CA2229671A1 (en) | 1999-08-16 |
DE69708076D1 (de) | 2001-12-13 |
CZ292754B6 (cs) | 2003-12-17 |
CZ220897A3 (cs) | 1999-02-17 |
CA2229671C (en) | 2005-11-22 |
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