EP0890671A2 - Use of modified fatty amines for preventing deposition of low molecular weight by-products on textile materials - Google Patents

Use of modified fatty amines for preventing deposition of low molecular weight by-products on textile materials Download PDF

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Publication number
EP0890671A2
EP0890671A2 EP98810611A EP98810611A EP0890671A2 EP 0890671 A2 EP0890671 A2 EP 0890671A2 EP 98810611 A EP98810611 A EP 98810611A EP 98810611 A EP98810611 A EP 98810611A EP 0890671 A2 EP0890671 A2 EP 0890671A2
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EP
European Patent Office
Prior art keywords
alkyl
weight
products
polyester
und
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP98810611A
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German (de)
French (fr)
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EP0890671A3 (en
Inventor
Claudius Brinkmann
Alfred Keller
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Novartis AG
BASF Schweiz AG
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Ciba Geigy AG
Ciba Spezialitaetenchemie Holding AG
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Publication of EP0890671A3 publication Critical patent/EP0890671A3/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/06—After-treatment with organic compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/622—Sulfonic acids or their salts
    • D06P1/625—Aromatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/667—Organo-phosphorus compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/93—Pretreatment before dyeing

Definitions

  • the present invention relates to the use of modified fatty amines to reduce or prevent deposits of low molecular weight by-products arising during the manufacturing process of a polyester fiber material textile materials consisting of polyester fibers or these fibers in a mixture with others Contain fibers.
  • the resulting in the manufacturing process of polyester fibers and on or in the fibers adhering low molecular weight by-products cause in textile finishing processes, such as. Dyeing or finishing, unpleasant disturbances, e.g. Unegality, nuance shift, Color strength reduction or staining. You can also by these deposits increasingly occur during yarn processing.
  • the amines of the formula (1) are known or can be prepared by known methods become.
  • the modified fatty amine of formula (1) can on the polyester-containing textile material in the Equipment commonly used in the textile finishing industry after one in the textile finishing industry usual method, e.g. from a pretreatment liquor or before, or preferably are applied from the dye bath during a dyeing process.
  • the modified fatty amine of the formula (1) is advantageously used in the tree and jet dyeing processes used.
  • suitable solvents may be mentioned e.g. Ethylene glycol, diethylene glycol, mono-, di- and tri-butyl glycol, diethylene glycol methyl ether, diethylene glycol ethyl ether Diethylene glycol propyl ether, 1,2-dimethyl-2,4-pentadiol, polyethylene propylene glycol ether, Dipropylene glycol methyl ether, dipropylene glycol butyl ether, hexylene glycol, Polyethylene glycols with 6 to 25 ethylene oxide units, isopropanol and n-butanol.
  • Ethylene glycol diethylene glycol, mono-, di- and tri-butyl glycol
  • diethylene glycol methyl ether diethylene glycol ethyl ether
  • Diethylene glycol propyl ether 1,2-dimethyl-2,4-pentadiol
  • polyethylene propylene glycol ether Dipropylene glycol methyl ether
  • the modified fatty amine of formula (1) is in the pretreatment liquor or in the dye bath in an amount of 0.03 to 5 g / l, preferably 0.15 to 2 g / l.
  • the modified fatty amine of formula (1) is preferably in the form of a suitable preparation applied.
  • a preparation containing as component (A) 3 to 30% by weight of a compound is preferred of the formula (1) and as component (B) 2 to 10% by weight of dodecylbenzenesulfonic acid, as well as other components if necessary.
  • the dodecylbenzenesulfonic acid used as component (B) is used as such, or advantageously in the form of salts, e.g. Ammonium salt or monoethanolammonium salt used.
  • An aqueous preparation containing as component (A) is preferably 3 to 50% by weight, preferably 3 to 30% by weight of a compound of the formula (1) and as component (B) 2 up to 10% by weight of dodecylbenzenesulfonic acid, and optionally further components.
  • the preparation according to the invention advantageously contains 5 to 50 as component (C) % By weight, preferably 10 to 50% by weight, in particular 20 to 40% by weight, of a compound from the group of monohydric and polyhydric alcohols, ethylene, polyethylene, propylene and polypropylene glycols, adducts of 4 to 100 moles of ethylene and / or Propylene oxide to monohydric and polyhydric alcohols, ethylene, polyethylene, propylene and Polypropylene glycols, which are optionally sulfated or phosphated and preferably can be used in the form of soluble salts.
  • component (C) % By weight, preferably 10 to 50% by weight, in particular 20 to 40% by weight, of a compound from the group of monohydric and polyhydric alcohols, ethylene, polyethylene, propylene and polypropylene glycols, adducts of 4 to 100 moles of ethylene and / or Propylene oxide to monohydric and polyhydric alcohols, ethylene, poly
  • Examples of such compounds include ethylene glycol, diethylene glycol, mono-, di- and tri-butyl glycol, diethylene glycol methyl ether, diethylene glycol ethyl ether Diethylene glycol propyl ether, 1,2-dimethyl-2,4-pentadiol, polyethylene propylene glycol ether, dipropylene glycol methyl ether, Dipropylene glycol butyl ether, hexylene glycol, polyethylene glycols with 6 to 25 ethylene oxide units, isopropanol and n-butanol.
  • As component (C) are sulfated or phosphated addition products from 4 to 100 Mol ethylene and / or propylene oxide to polyhydric alcohols preferred.
  • the preparation according to the invention can also contain dispersants, e.g. the previous described dispersants, solubilizers, such as alkyl sulfonates, such as e.g. 2-ethylhexyl sulfonate, Alkylarylsulfonates such as e.g. Cumene sulfonate, such as ethylated vegetable oils e.g. Soybean oil, castor oil or coconut fat ethoxylates with 20 to 50 ethylene oxide units or Mono- or dialkylated diphenyloxide mono or disulfonic acid, preservatives, such as formaldehyde donors, e.g.
  • Paraformaldehyde and trioxane especially aqueous, about 30 to 40 weight percent formaldehyde solutions, carriers such as e.g. Alkylbenzene, Biphenyl compounds, alkyl benzoates, halogenated aromatics such as e.g. Trichlorobenzene or Alkyl phthalates, wetting agents, leveling agents, anti-foaming agents, lubricants, such as e.g. Polyether polymers, Phosphoric acid esters or polyglycol fatty acid esters or UV stabilizers, such as e.g. Benzophenone, benzotriazole or s-triazine UV absorbers, as well as others, in the textile finishing industry usual tools included.
  • carriers such as e.g. Alkylbenzene, Biphenyl compounds, alkyl benzoates, halogenated aromatics such as e.g. Trichlorobenzene or Alkyl phthalates, wetting agents, leveling agents, anti
  • the preparations according to the invention are generally produced by simple mixing of the individual components, advantageously with an increased Temperature, e.g. between 30 and 60 ° C.
  • Another object of the present invention is the method for reducing, or prevention of deposits of low molecular weight by-products on polyester-containing textile fiber materials, which is characterized in that the Preparation used according to the invention.
  • the preparations according to the invention can be added to those containing polyester or polyester textile fiber materials are applied before, during or after a finishing process, e.g. expediently before, during or after a dyeing process. Applications during and especially before the actual dyeing process are preferred.
  • the preparation according to the invention can be used in those customarily used in the textile finishing industry Apparatus, advantageously used in the tree and jet dyeing processes become.
  • the preparations according to the invention can be applied to the fiber material by methods customary in the textile finishing industry. An application according to the pull-out method is preferred.
  • the preparations according to the invention are usually applied in an exhaust dyeing process in a temperature range from 80 to 145 ° C. and at a pH from 4 to 12, preferably from 4 to 6.
  • the liquor ratio can be selected within a wide range, for example from 1: 5 to 1:40, preferably from 1: 8 to 1:25.
  • the preparations according to the invention are in the liquor in an amount of 0.1 to 10 g / l, preferably 0.5 to 5 g / l.
  • a preferred embodiment of the method according to the invention is that e.g. the polyester fiber material to be dyed first with the inventive one Preparation e.g. Treated for 5 to 10 minutes at 50 to 70 ° C and in the same bath after addition of the dye at temperatures up to 140 ° C. At the end the bath is cooled and finished the dyed fiber material as usual.
  • Preparation e.g. Treated for 5 to 10 minutes at 50 to 70 ° C and in the same bath after addition of the dye at temperatures up to 140 ° C. At the end the bath is cooled and finished the dyed fiber material as usual.
  • the dyes used in a dyeing process are suitable for the dye according to the invention
  • Process such dyes which are included in the Color Index, 3rd edition (3rd revision 1987 inclusive Additions and amendments to No. 85) are described under "Disperse Dyes”. It are, for example, carboxylic acid and / or sulfonic acid group-free nitro, amino, amino ketone, Ketoneimine, methine, polymethine, diphenylamine, quinoline, benzimidazole, xanthene, Oxazine or coumarin dyes and especially anthraquinone and azo dyes such as mono- or disazo dyes.
  • Example 7 The procedure is as described in Example 7, but uses 40% instead of 0.2 g Solution of a tallow fatty amine reacted with 8 moles of ethylene oxide 0.3 g of that given in Example 5 Formulation, you also get a level blue strong coloring, the shows no or only a trace of deposits.
  • Example 7 The procedure is as described in Example 7, but uses 40% instead of 0.2 g Solution of a tallow fatty amine reacted with 8 moles of ethylene oxide 0.4 g of that given in Example 6 Formulation, you also get a level blue strong coloring, the shows no or only a trace of deposits.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Abstract

The use of modified fatty amines for reducing or preventing the deposition of low-mol. wt. by-products from polyester fibre production on textile materials made of polyester fibres or mixtures of these with other fibres is claimed. These amines have the formula R-NR3-(R1-O)n-R2 (I), in which R = 9-24C alkyl or acyl; R1 = 2-4C alkylene; R2 = H, or 1-4C alkyl or acyl; R3 = H or (R1-O)m; n, m = 2-100; the groups (R1-O) can be the same or different in (R1-O)n and in (R1-O)m. Also claimed is (i) a preparation containing (A) 3-50 wt% compound (1), (B) 2-10 wt% dodecylbenzene-sulphonic acid, and optionally other components; (ii) a method for reducing or preventing the deposition of low- mol. wt. by-products as above on polyester-containing fibre material, by using a preparation as in (i).

Description

Gegenstand der vorliegenden Erfindung ist die Verwendung von modifizierten Fettaminen zur Verringerung, bzw. Verhinderung von Ablagerungen von niedermolekularen Nebenprodukten entstehend während des Herstellungsprozesses eines Polyester-Fasermaterials, auf textilen Materialien, die aus Polyesterfasern bestehen oder diese Fasern im Gemisch mit anderen Fasern enthalten.The present invention relates to the use of modified fatty amines to reduce or prevent deposits of low molecular weight by-products arising during the manufacturing process of a polyester fiber material textile materials consisting of polyester fibers or these fibers in a mixture with others Contain fibers.

Die im Herstellungsprozess von Polyesterfasern entstehenden und an oder in den Fasern haftenden niedermolekularen Nebenprodukte verursachen bei den Textilveredelungsprozessen, wie z.B. Färben oder Ausrüsten, unangenehme Störungen, wie z.B. Unegalität, Nuanceverschiebung, Färbestärkeverminderung oder Fleckenbildung. Ausserdem können durch diese Ablagerungen bei einer Garnverarbeitung vermehrt Fadenbrüche auftreten.The resulting in the manufacturing process of polyester fibers and on or in the fibers adhering low molecular weight by-products cause in textile finishing processes, such as. Dyeing or finishing, unpleasant disturbances, e.g. Unegality, nuance shift, Color strength reduction or staining. You can also by these deposits increasingly occur during yarn processing.

Es besteht darum ein Bedürfnis die durch die Ablagerungen von niedermolekularen Nebenprodukten bedingten Störungen zu verhindern.There is a need, therefore, for the deposits of low molecular weight by-products prevent conditional interference.

Es hat sich überraschenderweise gezeigt, dass durch die erfindungsgemässe Verwendung der modifizierten Fettamine die Ablagerungen von den unerwünschten niedermolekularen Nebenprodukten stark verringert, bzw. vollständig verhindert werden können.Surprisingly, it has been shown that the use according to the invention the modified fatty amine deposits from undesirable low molecular weight By-products can be greatly reduced or completely prevented.

Gegenstand der vorliegenden Erfindung ist somit die Verwendung eines modifizierten Fettamines der Formel R - NR3 - (R1 - O)n - R2 worin

  • R C9-C24-Alkyl oder Acyl, R1 C2-C4-Alkylen, R2 Wasserstoff, C1-C4-Alkyl oder Acyl, R3 Wasserstoff oder (R1-O)m sind, n und m unabhängig voneinander eine ganze Zahl von 2 bis 100 bedeuten und (R1-O)n für n gleiche oder verschiedene Reste (R1-O) und (R1-O)m für m gleiche oder verschiedene Reste (R1-O) steht,
  • zur Verringerung, bzw. Verhinderung von Ablagerungen von niedermolekularen Nebenprodukten entstehend während des Herstellungsprozesses eines Polyester-Fasermaterials, auf textilen Materialien, die aus Polyesterfasern bestehen oder diese Fasern im Gemisch mit anderen Fasern enthalten.
    In der Formel (1) ist:
  • als R ein C14-C20-Alkyl bevorzugt;
  • als R1 Propylen und insbesondere Ethylen bevorzugt;
  • als R2 C1-C4-Alkyl und insbesondere Wasserstoff bevorzugt;
  • als n eine Zahl zwischen 2 und 25, insbesondere zwischen 4 und 25, vor allem zwischen 4 und 12, bevorzugt; ganz besonders wichtig is n eine Zahl zwischen 4 und 8;
  • als m eine Zahl zwischen 2 und 25, insbesondere zwischen 4 und 25, vor allem zwischen 4 und 12, bevorzugt; ganz besonders wichtig is m eine Zahl zwischen 4 und 8;
  • die Summe m+n 4 bis 50, insbesondere 4 bis 16, vor allem 4 bis 8 bevorzugt.
    • The present invention thus relates to the use of a modified fatty amine of the formula R - NR 3 - (R 1 - O) n - R 2 wherein
  • RC 9 -C 24 alkyl or acyl, R 1 C 2 -C 4 alkylene, R 2 hydrogen, C 1 -C 4 alkyl or acyl, R 3 are hydrogen or (R 1 -O) m , n and m independently represent an integer from 2 to 100 and (R 1 -O) n for n identical or different radicals (R 1 -O) and (R 1 -O) m for m identical or different radicals (R 1 -O) stands,
  • to reduce or prevent deposits of low molecular weight by-products formed during the manufacturing process of a polyester fiber material, on textile materials consisting of polyester fibers or containing these fibers in a mixture with other fibers.
    In formula (1):
  • preferred as R is a C 14 -C 20 alkyl;
  • preferred as R 1 is propylene and especially ethylene;
  • preferred as R 2 C 1 -C 4 alkyl and in particular hydrogen;
  • as n a number between 2 and 25, in particular between 4 and 25, especially between 4 and 12, is preferred; a number between 4 and 8 is particularly important;
  • as m a number between 2 and 25, in particular between 4 and 25, especially between 4 and 12, is preferred; a number between 4 and 8 is particularly important;
  • the sum m + n 4 to 50, in particular 4 to 16, especially 4 to 8 is preferred.

    • Die Amine der Formel (1) sind bekannt oder können nach bekannten Methoden hergestellt werden.The amines of the formula (1) are known or can be prepared by known methods become.

    Das modifizierte Fettamin der Formel (1) kann auf das polyesterhaltige textile Material in den in der Textilveredlungsindustrie üblich verwendeten Apparaturen nach einer in der Textilveredlungsindustrie üblichen Methode, z.B. aus einer Vorbehandlungsflotte oder vor, oder vorzugsweise während eines Färbeprozesses aus dem Färbebad aufgebracht werden. Vorteilhafterweise wird das modifizierte Fettamin der Formel (1) bei der Baum- und Jet-Färbeprozessen verwendet.The modified fatty amine of formula (1) can on the polyester-containing textile material in the Equipment commonly used in the textile finishing industry after one in the textile finishing industry usual method, e.g. from a pretreatment liquor or before, or preferably are applied from the dye bath during a dyeing process. The modified fatty amine of the formula (1) is advantageously used in the tree and jet dyeing processes used.

    Das modifizierte Fettamin der Formel (1) kann auf das polyesterhaltige textile Material z.B. als Lösung, insbesondere eine 10 bis 50%-ige, gegebenenfalls lösungsmittelhaltige wässrige Lösung, oder eine 10 bis 50%-ige wasserfreie Lösung, oder in Form einer Dispersion appliziert werden.
    Für die Herstellung solcher Dispersionen sind die üblichen für die Dispergierung von Fettaminen verwendeten Dispergiermittel, vorzugsweise nichtionogene Dispergiermittel, geeignet.
    Als nichtionogene Dispergiermittel eignen sich insbesondere Verbindungen, welche aus der Gruppe der

  • (ca) Alkylenoxidaddukte der Formel
    Figure 00030001
    worin
  • Y1 C1-C12-Alkyl, Aryl oder Aralkyl bedeutet,
  • "Alkylen" für den Ethylenrest oder Propylenrest steht und
  • m1 1 bis 4 und n1 4 bis 50 sind,
  • (cb) Alkylenoxidaddukte an gesättigte oder ungesättigte 1-6-wertige aliphatische Alkohole, Fettsäuren, Fettamine, Fettamide, Diamine oder Sorbitanester,
  • (cc) Alkylenoxid-Kondensationsprodukte (Blockpolymerisate)
  • (cd) Polymerisate von Vinylpyrrolidon, Vinylacetat oder Vinylalkohol und
  • (ce) Co- oder Ter-polymere von Vinylpyrrolidon mit Vinylacetat und/oder Vinylalkohol, ausgewählt sind.
    • The modified fatty amine of formula (1) can be applied to the polyester-containing textile material, for example as a solution, in particular a 10 to 50%, optionally solvent-containing, aqueous solution, or a 10 to 50% anhydrous solution, or in the form of a dispersion .
    For the preparation of such dispersions, the customary dispersants used for the dispersion of fatty amines, preferably nonionic dispersants, are suitable.
    Particularly suitable nonionic dispersants are compounds which belong to the group of
  • (ca) alkylene oxide adducts of the formula
    Figure 00030001
    wherein
  • Y 1 is C 1 -C 12 alkyl, aryl or aralkyl,
  • "Alkylene" stands for the ethylene radical or propylene radical and
  • m 1 are 1 to 4 and n 1 4 to 50,
  • (cb) alkylene oxide adducts with saturated or unsaturated 1-6-valent aliphatic alcohols, fatty acids, fatty amines, fatty amides, diamines or sorbitan esters,
  • (cc) alkylene oxide condensation products (block polymers)
  • (cd) polymers of vinyl pyrrolidone, vinyl acetate or vinyl alcohol and
  • (ce) copolymers or terpolymers of vinylpyrrolidone with vinyl acetate and / or vinyl alcohol.

    • Als für die Herstellung einer wasserfreien oder gegebenenfalls lösungsmittelhaltigen Lösung des modifizierten Fettamines der Formel (1) geeigneten Lösungsmittel seien genannt z.B. Ethylenglykol, Diethylenglykol, mono-, di- und tri-Butylglykol, Diethylenglykolmethylether, Diethylenglykolethylether Diethylenglykolpropylether, 1,2-Dimethyl-2,4-pentadiol, Polyethylenpropylenglykolether, Dipropylenglykolmethylether, Dipropylenglykolbutylether, Hexylenglykol, Polyethylenglykole mit 6 bis 25 Ethylenoxideinheiten, lsopropanol und n-Butanol.As for the preparation of an anhydrous or, if appropriate, solvent-containing solution of the modified fatty amine of formula (1) suitable solvents may be mentioned e.g. Ethylene glycol, diethylene glycol, mono-, di- and tri-butyl glycol, diethylene glycol methyl ether, diethylene glycol ethyl ether Diethylene glycol propyl ether, 1,2-dimethyl-2,4-pentadiol, polyethylene propylene glycol ether, Dipropylene glycol methyl ether, dipropylene glycol butyl ether, hexylene glycol, Polyethylene glycols with 6 to 25 ethylene oxide units, isopropanol and n-butanol.

    Das modifizierte Fettamin der Formel (1) wird in der Vorbehandlungsflotte oder im Färbebad in einer Menge von 0,03 bis 5 g/l, vorzugsweise 0,15 bis 2 g/l eingesetzt.The modified fatty amine of formula (1) is in the pretreatment liquor or in the dye bath in an amount of 0.03 to 5 g / l, preferably 0.15 to 2 g / l.

    Vorzugsweise wird das modifizierte Fettamin der Formel (1) in Form einer geeigneten Zubereitung appliziert.The modified fatty amine of formula (1) is preferably in the form of a suitable preparation applied.

    Einen weiteren Gegenstand der vorliegenden Erfindung stellt eine Zubereitung, enthaltend als Komponente (A)
    3 bis 50 Gew.-% einer Verbindung der Formel R - NR3 - (R1 - O)n - R2 worin

  • R C9-C24-Alkyl oder Acyl, R1 C2-C4-Alkylen, R2 Wasserstoff, C1-C4-Alkyl oder Acyl, R3 Wasserstoff oder (R1-O)m sind, n und m unabhängig voneinander eine ganze Zahl von 2 bis 100 bedeuten und (R1-O)n für n gleiche oder verschiedene Reste (R1-O) und (R1-O)m für m gleiche oder verschiedene Reste (R1-O) steht und für R, R1, R2 R3 ,n und m die oben angegebenen Bevorzugungen gelten, und
  • als Komponente (B)
  • 2 bis 10 Gew.-% Dodecylbenzolsulfonsäure,
  • sowie gegebenenfalls weitere Komponenten, dar.
    • The present invention further provides a preparation comprising as component (A)
    3 to 50% by weight of a compound of the formula R - NO 3rd - (R 1 - O) n - R 2nd wherein
  • RC 9 -C 24 alkyl or acyl, R 1 C 2 -C 4 alkylene, R 2 hydrogen, C 1 -C 4 alkyl or acyl, R 3 are hydrogen or (R 1 -O) m , n and m independently represent an integer from 2 to 100 and (R 1 -O) n for n identical or different radicals (R 1 -O) and (R 1 -O) m for m identical or different radicals (R 1 -O) stands for R, R 1 , R 2 R 3 , n and m the preferences given above apply, and
  • as component (B)
  • 2 to 10% by weight of dodecylbenzenesulfonic acid,
  • and optionally further components.

    • Bevorzugt ist eine Zubereitung enthaltend als Komponente (A) 3 bis 30 Gew.-% einer Verbindung der Formel (1) und als Komponente (B) 2 bis 10 Gew.-% Dodecylbenzolsulfonsäure, sowie gegebenenfalls weitere Komponenten.A preparation containing as component (A) 3 to 30% by weight of a compound is preferred of the formula (1) and as component (B) 2 to 10% by weight of dodecylbenzenesulfonic acid, as well as other components if necessary.

    Für die Komponente (A) gelten die vorgängig angegebenen Bevorzugungen.The preferences given above apply to component (A).

    Die als Komponente (B) verwendete Dodecylbenzolsulfonsäure wird als solche, oder vorteilhafterweise in Form von Salzen, wie z.B. Ammoniumsalz oder Monoethanolammoniumsalz verwendet.The dodecylbenzenesulfonic acid used as component (B) is used as such, or advantageously in the form of salts, e.g. Ammonium salt or monoethanolammonium salt used.

    Bevorzugt wird eine wässrige Zubereitung enthaltend als Komponente (A) 3 bis 50 Gew.-%, vorzugsweise 3 bis 30 Gew.-%, einer Verbindung der Formel (1), und als Komponente (B) 2 bis 10 Gew.-% Dodecylbenzolsulfonsäure, sowie gegebenenfalls weitere Komponenten.An aqueous preparation containing as component (A) is preferably 3 to 50% by weight, preferably 3 to 30% by weight of a compound of the formula (1) and as component (B) 2 up to 10% by weight of dodecylbenzenesulfonic acid, and optionally further components.

    Vorteilhafterweise enthält die erfindungsgemässe Zubereitung als Komponente (C) 5 bis 50 Gew.-%, vorzugsweise 10 bis 50 Gew.-%, insbesondere 20 bis 40 Gew.-% einer Verbindung aus der Gruppe der einwertigen und mehrwertigen Alkohole, Ethylen-, Polyethylen-, Propylen- und Polypropylenglykole, Anlagerungsprodukte von 4 bis 100 Mol Ethylen- und/oder Propylenoxid an einwertige und mehrwertige Alkohole, Ethylen-, Polyethylen-, Propylen- und Polypropylenglykole, welche gegebenenfalls sulfatiert oder phosphatiert sind und vorzugsweise in Form von löslichen Salzen eingesetzt werden.The preparation according to the invention advantageously contains 5 to 50 as component (C) % By weight, preferably 10 to 50% by weight, in particular 20 to 40% by weight, of a compound from the group of monohydric and polyhydric alcohols, ethylene, polyethylene, propylene and polypropylene glycols, adducts of 4 to 100 moles of ethylene and / or Propylene oxide to monohydric and polyhydric alcohols, ethylene, polyethylene, propylene and Polypropylene glycols, which are optionally sulfated or phosphated and preferably can be used in the form of soluble salts.

    Als Beispiele solcher Verbindungen seien genannt unter anderem Ethylenglykol, Diethylenglykol, mono-, di- und tri-Butylglykol, Diethylenglykolmethylether, Diethylenglykolethylether Diethylenglykolpropylether, 1,2-Dimethyl-2,4-pentadiol, Polyethylenpropylenglykolether, Dipropylenglykolmethylether, Dipropylenglykolbutylether, Hexylenglykol, Polyethylenglykole mit 6 bis 25 Ethylenoxideinheiten, Isopropanol und n-Butanol.Examples of such compounds include ethylene glycol, diethylene glycol, mono-, di- and tri-butyl glycol, diethylene glycol methyl ether, diethylene glycol ethyl ether Diethylene glycol propyl ether, 1,2-dimethyl-2,4-pentadiol, polyethylene propylene glycol ether, dipropylene glycol methyl ether, Dipropylene glycol butyl ether, hexylene glycol, polyethylene glycols with 6 to 25 ethylene oxide units, isopropanol and n-butanol.

    Als Komponente (C) sind sulfatierte oder phosphatierte Anlagerungsprodukte von 4 bis 100 Mol Ethylen- und/oder Propylenoxid an mehrwertige Alkohole bevorzugt.As component (C) are sulfated or phosphated addition products from 4 to 100 Mol ethylene and / or propylene oxide to polyhydric alcohols preferred.

    Die erfindungsmässige Zubereitung kann weiter Dispergiermittel, wie z.B. die vorgängig beschriebenen Dispergiermittel, Lösungsvermittler, wie z.B.Alkylsulfonate, wie z.B. 2-Ethylhexylsulfonat, Alkylarylsulfonate, wie z.B. Cumolsulfonat, oxethylierte pflanzliche Öle wie z.B. Sojaöl- Ricinusöl- oder Kokosfettethoxylate mit 20 bis 50 Ethylenoxideinheiten oder Mono- oder dialkylierte Diphenyloxid-mono oder Disulfonsäure, Konservierungsmittel, wie formaldehydabgebende Mittel, wie z.B. Paraformaldehyd und Trioxan, vor allem wässrige, etwa 30 bis 40-gewichtsprozentige Formaldehydlösungen, Carrier, wie z.B. Alkylbenzol, Biphenylverbindungen, Alkylbenzoate, halogenierte Aromate wie z.B. Trichlorbenzol oder Alkylphthalate, Netzmittel, Egalisiermittel, Antischaummittel, Gleitmittel, wie z.B. Polyetherpolymere, Phosphorsäureester oder Polyglykolfettsäureester oder UV-Stabilisatoren, wie z.B. Benzophenon-, Benzotriazol- oder s-Triazin-UV-Absorber, sowie andere, in der Textilveredlungsindustrie übliche Hilfsmittel, enthalten.The preparation according to the invention can also contain dispersants, e.g. the previous described dispersants, solubilizers, such as alkyl sulfonates, such as e.g. 2-ethylhexyl sulfonate, Alkylarylsulfonates such as e.g. Cumene sulfonate, such as ethylated vegetable oils e.g. Soybean oil, castor oil or coconut fat ethoxylates with 20 to 50 ethylene oxide units or Mono- or dialkylated diphenyloxide mono or disulfonic acid, preservatives, such as formaldehyde donors, e.g. Paraformaldehyde and trioxane, especially aqueous, about 30 to 40 weight percent formaldehyde solutions, carriers such as e.g. Alkylbenzene, Biphenyl compounds, alkyl benzoates, halogenated aromatics such as e.g. Trichlorobenzene or Alkyl phthalates, wetting agents, leveling agents, anti-foaming agents, lubricants, such as e.g. Polyether polymers, Phosphoric acid esters or polyglycol fatty acid esters or UV stabilizers, such as e.g. Benzophenone, benzotriazole or s-triazine UV absorbers, as well as others, in the textile finishing industry usual tools included.

    Die Herstellung der erfindungsgemässen Zubereitungen geschieht im allgemeinen durch einfaches Zusammenmischen der einzelnen Komponenten, vorteilhafterweise bei einer erhöhten Temperatur, z.B. zwischen 30 und 60° C.The preparations according to the invention are generally produced by simple mixing of the individual components, advantageously with an increased Temperature, e.g. between 30 and 60 ° C.

    Einen weiteren Gegenstand der vorliegenden Erfindung stellt das Verfahren zur Verringerung, bzw. Verhinderung von Ablagerungen von niedermolekularen Nebenprodukten an polyesterhaltigen textilen Fasermaterialien, welches dadurch gekennzeichnet ist, dass man die erfindungsgemässe Zubereitung verwendet.Another object of the present invention is the method for reducing, or prevention of deposits of low molecular weight by-products on polyester-containing textile fiber materials, which is characterized in that the Preparation used according to the invention.

    Die erfindungsgemässen Zubereitungen können an die Polyester- oder polyesterhaltigen textilen Fasermaterialien vor, während oder nach einem Veredlungsprocess appliziert werden, z.B. zweckmässigerweise vor, während oder nach einem Färbeverfahren. Applikationen während und insbesondere vor dem eigentlichen Färbeprozess werden bevorzugt. The preparations according to the invention can be added to those containing polyester or polyester textile fiber materials are applied before, during or after a finishing process, e.g. expediently before, during or after a dyeing process. Applications during and especially before the actual dyeing process are preferred.

    Die erfindungsgemässe Zubereitung kann in den in der Textilveredlungsindustrie üblich verwendeten Apparaturen, vorteilhafterweise bei den Baum- und Jet-Färbeprozessen verwendet werden.The preparation according to the invention can be used in those customarily used in the textile finishing industry Apparatus, advantageously used in the tree and jet dyeing processes become.

    Das Aufbringen der erfindungsmässigen Zubereitungen auf das Fasermaterial kann nach in der Textilveredlungsindustrie üblichen Methoden geschehen. Bevorzugt wird eine Applikation nach dem Ausziehverfahren.
    Die Applikation der erfindungsmässigen Zubereitungen in einem Ausziehfärbeverfahren erfolgt üblicherweise in einem Temperaturbereich von 80 bis 145° C und bei einem pH von 4 bis 12, vorzugsweise von 4 bis 6.
    Das Flottenverhältnis kann innerhalb eines weiten Bereichs gewählt werden, z.B. von 1:5 bis 1:40, vorzugsweise von 1:8 bis 1:25.    The preparations according to the invention can be applied to the fiber material by methods customary in the textile finishing industry. An application according to the pull-out method is preferred.
    The preparations according to the invention are usually applied in an exhaust dyeing process in a temperature range from 80 to 145 ° C. and at a pH from 4 to 12, preferably from 4 to 6.
    The liquor ratio can be selected within a wide range, for example from 1: 5 to 1:40, preferably from 1: 8 to 1:25.

    Die erfindungsgemässen Zubereitungen werden in der Flotte in einer Menge von 0,1 bis 10 g/l, vorzugsweise 0,5 bis 5 g/l eingesetzt.The preparations according to the invention are in the liquor in an amount of 0.1 to 10 g / l, preferably 0.5 to 5 g / l.

    Eine bevorzugte Ausführungsform des erfindungsgemässen Verfahrens besteht darin, dass man z.B. das zu färbende polyesterhaltige Fasermaterial zuerst mit der erfindungsgemässen Zubereitung z.B. 5 bis 10 Minuten bei 50 bis 70° C behandelt und im gleichen Bad nach Zugabe des Farbstoffes bei Temperaturen bis 140° C färbt. Am Schluss wird das Bad abgekühlt und das gefärbte Fasermaterial wie üblich fertiggestellt.A preferred embodiment of the method according to the invention is that e.g. the polyester fiber material to be dyed first with the inventive one Preparation e.g. Treated for 5 to 10 minutes at 50 to 70 ° C and in the same bath after addition of the dye at temperatures up to 140 ° C. At the end the bath is cooled and finished the dyed fiber material as usual.

    Als die bei einem Färbeverfahren verwendeten Farbstoffe eignen sich für das erfindungsgemässe Verfahren solche Farbstoffe, welche im Colour Index, 3. Auflage (3. Revision 1987 inclusive Additions and Amendments bis No. 85) unter "Disperse Dyes" beschrieben sind. Es sind beispielsweise carbonsäure- und/oder sulfosäuregruppenfreie Nitro-, Amino-, Aminoketon-, Ketonimin-, Methin-, Polymethin-, Diphenylamin-, Chinolin-, Benzimidazol-, Xanthen-, Oxazin- oder Cumarinfarbstoffe und insbesondere Anthrachinon- und Azofarbstoffe, wie Mono- oder Disazofarbstoffe.The dyes used in a dyeing process are suitable for the dye according to the invention Process such dyes, which are included in the Color Index, 3rd edition (3rd revision 1987 inclusive Additions and amendments to No. 85) are described under "Disperse Dyes". It are, for example, carboxylic acid and / or sulfonic acid group-free nitro, amino, amino ketone, Ketoneimine, methine, polymethine, diphenylamine, quinoline, benzimidazole, xanthene, Oxazine or coumarin dyes and especially anthraquinone and azo dyes such as mono- or disazo dyes.

    Die nachfolgende Beispiele dienen der Erläuterung der Erfindung. Die Temperaturen sind in Celsiusgraden angegeben, Teile sind Gewichtsteile, und Prozentangaben beziehen sich auf Gew.-%, sofern nicht anders vermerkt. Gewichtsteile stehen zu Volumenteilen im Verhältnis von Kilogramm zu Liter. The following examples serve to explain the invention. The temperatures are in Celsius degrees, parts are parts by weight, and percentages relate to % By weight, unless stated otherwise. Parts by weight are in relation to parts by volume from kilogram to liter.

    Beispiel 1:Example 1:

    In einem mit einem Rührer versehenen Reaktionskolben werden

  • 40,0 Gewichtsteile Ölsäureethylester vorgelegt. Danach werden unter ständigem Rühren nacheinander
  • 15,0 Gewichtsteile eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins,
  • 6,0 Gewichtsteile Dodecylbenzolsulfosäure und
  • 39,0 Gewichtsteile Wasser
    • zugegeben und homogen verrührt. Anschliessend wird der pH-Wert der Mischung mit Ammoniak auf einen Wert zwischen 7 bis 8 eingestellt.In a reaction flask equipped with a stirrer
  • 40.0 parts by weight of oleic acid ethyl ester submitted. After that, stirring in succession
  • 15.0 parts by weight of a tallow fatty amine reacted with 8 moles of ethylene oxide,
  • 6.0 parts by weight of dodecylbenzenesulfonic acid and
  • 39.0 parts by weight of water
    • added and stirred homogeneously. The pH of the mixture is then adjusted to a value between 7 and 8 with ammonia.

    Beispiel 2:Example 2:

    In einem mit einem Rührer versehenen Reaktionskolben werden

  • 36,0 Gewichtsteile eines mit 36 Mol Ethylenoxid umgesetzten Ricinusöl vorgelegt. Der Kolbeninhalt wird anschliessend auf 50° C aufgeheizt und es werden unter ständigem Rühren nacheinander
  • 1,5 Gewichtsteile Natriumsalz eines mit 2 Mol Ethylenoxid umgesetzen, sulfatierten Nonylphenol,
  • 10,0 Gewichtsteile Polypropylenglykol 600,
  • 0,5 Gewichtsteile Ethylendiamintetraessigsäure-Na-Salz,
  • 5,0 Gewichtsteile Dodecylbenzolsulfosäure,
  • 7,0 Gewichtsteile eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins, und
  • 40,0 Gewichtsteile Wasser
    • zugegeben, homogen verrührt und auf die Raumtemperatur abgekühlt. Danach wird der pH-Wert der Mischung mit Ammoniak auf einen Wert zwischen 7 bis 8 eingestellt.In a reaction flask equipped with a stirrer
  • 36.0 parts by weight of a castor oil reacted with 36 mol of ethylene oxide. The contents of the flask are then heated to 50 ° C and are stirred one after the other with constant stirring
  • 1.5 parts by weight of sodium salt of a sulfated nonylphenol reacted with 2 mol of ethylene oxide,
  • 10.0 parts by weight of polypropylene glycol 600,
  • 0.5 parts by weight of ethylenediaminetetraacetic acid sodium salt,
  • 5.0 parts by weight of dodecylbenzenesulfonic acid,
  • 7.0 parts by weight of a tallow fatty amine reacted with 8 moles of ethylene oxide, and
  • 40.0 parts by weight of water
    • added, stirred homogeneously and cooled to room temperature. The pH of the mixture is then adjusted to a value between 7 and 8 with ammonia.

    Beispiel 3:Example 3:

    In einem mit einem Rührer versehenen Reaktionskolben werden

  • 20,0 Gewichtsteile des Natriumsalzes eines ethoxilierten 1,4-Butandiol-sulfatesters mit mittleren Molmasse von 2000 vorgelegt. Der Kolbeninhalt wird anschliessend auf 60° C aufgeheizt und es werden unter ständigem Rühren nacheinander
  • 6,0 Gewichtsteile Dodecylbenzolsulfosäure,
  • 25,0 Gewichtsteile eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins, und
  • 49,0 Gewichtsteile Wasser
    • zugegeben, homogen verrührt und auf die Raumtemperatur abgekühlt. Danach wird der pH-Wert der Mischung mit Ammoniak auf einen Wert zwischen 7 bis 8 eingestellt.In a reaction flask equipped with a stirrer
  • 20.0 parts by weight of the sodium salt of an ethoxylated 1,4-butanediol sulfate ester with average molecular weight of 2000 presented. The contents of the flask are then heated to 60 ° C and are stirred one after the other with constant stirring
  • 6.0 parts by weight of dodecylbenzenesulfonic acid,
  • 25.0 parts by weight of a tallow fatty amine reacted with 8 moles of ethylene oxide, and
  • 49.0 parts by weight of water
    • added, stirred homogeneously and cooled to room temperature. The pH of the mixture is then adjusted to a value between 7 and 8 with ammonia.

    Beispiel 4:Example 4:

    In einem mit einem Rührer versehenen Reaktionskolben werden

  • 20,0 Gewichtsteile Polyethylenglykol 400, und
  • 10,0 Gewichtsteile Polypropylenglykol 400
  • vorgelegt. Der Kolbeninhalt wird anschliessend auf 50° C aufgeheizt und es werden unter ständigem Rühren nacheinander
  • 1,0 Gewichtsteile Ethylendiamintetraessigsäure-Na-Salz,
  • 2,0 Gewichtsteile Dodecylbenzolsulfosäure,
  • 30,0 Gewichtsteile eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins, und
  • 37,0 Gewichtsteile Wasser
    • zugegeben, homogen verrührt und auf die Raumtemperatur abgekühlt. Danach wird der pH-Wert der Mischung mit Ammoniak auf einen Wert zwischen 7 bis 8 eingestellt.In a reaction flask equipped with a stirrer
  • 20.0 parts by weight of polyethylene glycol 400, and
  • 10.0 parts by weight of polypropylene glycol 400
  • submitted. The contents of the flask are then heated to 50 ° C and are stirred one after the other with constant stirring
  • 1.0 part by weight of ethylenediaminetetraacetic acid sodium salt,
  • 2.0 parts by weight of dodecylbenzenesulfonic acid,
  • 30.0 parts by weight of a tallow fatty amine reacted with 8 moles of ethylene oxide, and
  • 37.0 parts by weight of water
    • added, stirred homogeneously and cooled to room temperature. The pH of the mixture is then adjusted to a value between 7 and 8 with ammonia.

    Beispiel 5:Example 5:

    In einem mit einem Rührer versehenen Reaktionskolben werden

  • 50,0 Gewichtsteile Hexylenglykol
  • 30,0 Gewichtsteile eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins, und
  • 20,0 Gewichtsteile Wasser
    • vorgelegt. Der Kolbeninhalt wird anschliessend auf 50° C aufgeheizt ,homogen verrührt und auf die Raumtemperatur abgekühlt.In a reaction flask equipped with a stirrer
  • 50.0 parts by weight of hexylene glycol
  • 30.0 parts by weight of a tallow fatty amine reacted with 8 moles of ethylene oxide, and
  • 20.0 parts by weight of water
    • submitted. The contents of the flask are then heated to 50 ° C, stirred until homogeneous and cooled to room temperature.

    Beispiel 6:Example 6:

    In einem mit einem Rührer versehenen Reaktionskolben werden

  • 80,0 Gewichtsteile Dipropylenglykol und
  • 20,0 Gewichtsteile eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins
    • vorgelegt. Der Kolbeninhalt wird anschliessend auf 30° C aufgeheizt ,homogen verrührt und auf die Raumtemperatur abgekühlt.In a reaction flask equipped with a stirrer
  • 80.0 parts by weight of dipropylene glycol and
  • 20.0 parts by weight of a tallow fatty amine reacted with 8 moles of ethylene oxide
    • submitted. The contents of the flask are then heated to 30 ° C, stirred until homogeneous and cooled to room temperature.

    Beispiel 7:Example 7:

    Ein Stück von 25 g eines Polyestergewebes werden in einer Laborfärbeapparatur bei einem Flottenverhältnis 1:14 mit einer Flotte, enthaltend pro 1 l der Flotte

  • 2 g Ammoniumsulfat,
  • 4 g eines handelsüblichen Carriers, und
  • 2 g der Zubereitung aus Beispiel 3
    • welche mit Ameisensäure auf den pH-Wert von 5,5 eingestellt ist, bei einer Temperatur von 60° C für 5 Minuten behandelt.
    Anschliessend werden der Flotte 25 ml einer 3%-igen Lösung des Farbstofffes der Formel
    Figure 00090001
    zugesetzt.
    Nach 5 Minuten erhöht man die Temperatur der Flotte innerhalb von 40 Minuten auf 135° C und behandelt das Polyestergewebe 60 Minuten bei dieser Temperatur. Anschliessend wird die Flotte auf 60° C abgekühlt, und das gefärbte Polyestergewebe mit kaltem Wasser gespült und getrocknet.
    Man erhält eine egale blaue farbstarke Färbung, die keine oder nur eine Spur Ablagerungen zeigt.A piece of 25 g of a polyester fabric is in a laboratory dyeing machine at a 1:14 liquor ratio with a liquor containing 1 liter of the liquor
  • 2 g ammonium sulfate,
  • 4 g of a commercially available carrier, and
  • 2 g of the preparation from Example 3
    • which is adjusted to pH 5.5 with formic acid, treated at a temperature of 60 ° C. for 5 minutes.
    The liquor is then 25 ml of a 3% solution of the dye of the formula
    Figure 00090001
    added.
    After 5 minutes, the temperature of the liquor is raised to 135 ° C. in the course of 40 minutes and the polyester fabric is treated at this temperature for 60 minutes. The liquor is then cooled to 60 ° C., and the dyed polyester fabric is rinsed with cold water and dried.
    A level blue coloration is obtained which shows no or only a trace of deposits.

    Beispiel 8:Example 8:

    Ein Stück von 25 g eines Polyestergewebes werden in einer Laborfärbeapparatur bei einem Flottenverhältnis 1:14 mit einer Flotte, enthaltend pro 1 l der Flotte

  • 2 g Ammoniumsulfat und
  • 0,2 g einer 40%-igen wässrigen Lösung eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins,
    • welche mit Ameisensäure auf den pH-Wert von 5,5 eingestellt ist, bei einer Temperatur von 60° C für 5 Minuten behandelt.
    Anschliessend werden der Flotte 25 ml einer 3%-igen Lösung des Farbstofffes der Formel (4) zugesetzt.
    Nach 5 Minuten erhöht man die Temperatur der Flotte innerhalb von 40 Minuten auf 135° C und behandelt das Polyestergewebe 60 Minuten bei dieser Temperatur. Anschliessend wird die Flotte auf 60° C abgekühlt, und das gefärbte Polyestergewebe mit kaltem Wasser gespült und getrocknet. Man erhält eine egale blaue farbstarke Färbung , die keine oder nur eine Spur Ablagerungen zeigt. A piece of 25 g of a polyester fabric is in a laboratory dyeing machine at a 1:14 liquor ratio with a liquor containing 1 liter of the liquor
  • 2 g of ammonium sulfate and
  • 0.2 g of a 40% aqueous solution of a tallow fatty amine reacted with 8 moles of ethylene oxide,
    • which is adjusted to pH 5.5 with formic acid, treated at a temperature of 60 ° C. for 5 minutes.
    25 ml of a 3% solution of the dye of the formula (4) are then added to the liquor.
    After 5 minutes, the temperature of the liquor is raised to 135 ° C. in the course of 40 minutes and the polyester fabric is treated at this temperature for 60 minutes. The liquor is then cooled to 60 ° C., and the dyed polyester fabric is rinsed with cold water and dried. A level blue coloration is obtained which shows no or only a trace of deposits.

    Beispiel 9:Example 9:

    Verfährt man wie im Beispiel 7 angegeben, verwendet aber anstatt 0,2 g einer 40%-igen Lösung eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins 0,3 g der im Beispiel 5 angegebenen Formulierung, erhält man ebenfalls eine egale blaue farbstarke Färbung , die keine oder nur eine Spur Ablagerungen zeigt.The procedure is as described in Example 7, but uses 40% instead of 0.2 g Solution of a tallow fatty amine reacted with 8 moles of ethylene oxide 0.3 g of that given in Example 5 Formulation, you also get a level blue strong coloring, the shows no or only a trace of deposits.

    Beispiel 10:Example 10:

    Verfährt man wie im Beispiel 7 angegeben, verwendet aber anstatt 0,2 g einer 40%-igen Lösung eines mit 8 Mol Ethylenoxid umgesetzten Talgfettamins 0,4 g der im Beispiel 6 angegebenen Formulierung, erhält man ebenfalls eine egale blaue farbstarke Färbung , die keine oder nur eine Spur Ablagerungen zeigt.The procedure is as described in Example 7, but uses 40% instead of 0.2 g Solution of a tallow fatty amine reacted with 8 moles of ethylene oxide 0.4 g of that given in Example 6 Formulation, you also get a level blue strong coloring, the shows no or only a trace of deposits.

    Claims (9)

    Verwendung eines modifizierten Fettamines der Formel R - NR3 - (R1 - O)n - R2 worin R C9-C24-Alkyl oder Acyl, R1 C2-C4-Alkylen, R2 Wasserstoff, C1-C4-Alkyl oder Acyl, R3 Wasserstoff oder (R1-O)m sind, n und m unabhängig voneinander eine ganze Zahl von 2 bis 100 bedeuten und (R1-O)n für n gleiche oder verschiedene Reste (R1-O) und (R1-O)m für m gleiche oder verschiedene Reste (R1-O) steht, zur Verringerung, bzw. Verhinderung von Ablagerungen von niedermolekularen Nebenprodukten entstehend während des Herstellungsprozesses eines Polyester-Fasermaterials, auf textilen Materialien, die aus Polyesterfasern bestehen oder diese Fasern im Gemisch mit anderen Fasern enthalten. Use of a modified fatty amine of the formula R - NR 3 - (R 1 - O) n - R 2 wherein RC 9 -C 24 alkyl or acyl, R 1 C 2 -C 4 alkylene, R 2 hydrogen, C 1 -C 4 alkyl or acyl, R 3 are hydrogen or (R 1 -O) m , n and m independently represent an integer from 2 to 100 and (R 1 -O) n for n identical or different radicals (R 1 -O) and (R 1 -O) m for m identical or different radicals (R 1 -O) stands, to reduce or prevent deposits of low molecular weight by-products formed during the manufacturing process of a polyester fiber material, on textile materials consisting of polyester fibers or containing these fibers in a mixture with other fibers. Verwendung gemäss Anspruch 1, dadurch gekennzeichnet, dass R C14-C20-Alkyl ist.Use according to claim 1, characterized in that RC 14 -C 20 alkyl. Verwendung gemäss einem der Ansprüche 1 und 2, dadurch gekennzeichnet, dass R1 Ethylen ist.Use according to one of claims 1 and 2, characterized in that R 1 is ethylene. Verwendung gemäss einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass R2 Wasserstoff ist.Use according to one of claims 1 to 3, characterized in that R 2 is hydrogen. Zubereitung, enthaltend als Komponente (A) 3 bis 50 Gew.-% einer Verbindung der Formel R - NR3 - (R1 - O)n - R2 worin R C9-C24-Alkyl oder Acyl, R1 C2-C4-Alkylen, R2 Wasserstoff, C1-C4-Alkyl oder Acyl, R3 Wasserstoff oder (R1-O)m sind, n und m unabhängig voneinander eine ganze Zahl von 2 bis 100 bedeuten und (R1-O)n für n gleiche oder verschiedene Reste (R1-O) und (R1-O)m für m gleiche oder verschiedene Reste (R1-O) steht, und als Komponente (B) 2 bis 10 Gew.-% Dodecylbenzolsulfonsäure, sowie gegebenenfalls weitere Komponenten. Preparation containing as component (A) 3 to 50% by weight of a compound of the formula R - NR 3 - (R 1 - O) n - R 2 wherein RC 9 -C 24 alkyl or acyl, R 1 C 2 -C 4 alkylene, R 2 hydrogen, C 1 -C 4 alkyl or acyl, R 3 are hydrogen or (R 1 -O) m , n and m independently represent an integer from 2 to 100 and (R 1 -O) n for n identical or different radicals (R 1 -O) and (R 1 -O) m for m identical or different radicals (R 1 -O) stands, and as component (B) 2 to 10% by weight of dodecylbenzenesulfonic acid, as well as other components if necessary. Zubereitung gemäss Anspruch 5, dadurch gekennzeichnet, dass sie als Komponente (A) 3 bis 30 Gew.-% einer Verbindung der Formel (1) enthält.Preparation according to claim 5, characterized in that it is used as component (A) Contains 3 to 30 wt .-% of a compound of formula (1). Zubereitung gemäss einem der Ansprüche 5 und 6, dadurch gekennzeichnet, dass sie als weitere Komponente (C) 5 bis 50 Gew.-% einer Verbindung aus der Gruppe der einwertigen und mehrwertigen Alkohole, Ethylen-, Polyethylen-, Propylen- und Polypropylenglykole, Anlagerungsprodukte von 4 bis 100 Mol Ethylen- und/oder Propylenoxid an einwertige und mehrwertige Alkohole, Ethylen-, Polyethylen-, Propylen- und Polypropylenglykole welche gegebenenfalls sulfatiert oder phosphatiert sind und vorzugsweise in Form von löslichen Salzen eingesetzt werden, enthalten.Preparation according to one of claims 5 and 6, characterized in that it as further component (C) 5 to 50 wt .-% of a compound from the group of monovalent and polyhydric alcohols, ethylene, polyethylene, propylene and polypropylene glycols, addition products from 4 to 100 moles of ethylene and / or propylene oxide to monovalent and polyhydric alcohols, ethylene, polyethylene, propylene and polypropylene glycols which, if appropriate are sulfated or phosphated and preferably in the form of soluble salts are used included. Verfahren zur Verringerung, bzw. Verhinderung von Ablagerungen von niedermolekularen Nebenprodukten auf polyesterhaltigem Fasermaterial, dadurch gekennzeichnet, dass man die Zubereitung gemäss einem der Ansprüche 5 bis 7 verwendet.Process for reducing or preventing deposits of low molecular weight By-products on polyester-containing fiber material, characterized in that one the preparation according to one of claims 5 to 7 is used. Verwendung der Zubereitung gemäss einem der Ansprüche 5 bis 7 zur Verhinderung von Ablagerungen von niedermolekularen Nebenprodukten auf polyesterhaltigem Fasermaterial.Use of the preparation according to one of claims 5 to 7 for the prevention of Deposits of low molecular weight by-products on polyester-containing fiber material.
    EP98810611A 1997-07-10 1998-07-01 Use of modified fatty amines for preventing deposition of low molecular weight by-products on textile materials Withdrawn EP0890671A3 (en)

    Applications Claiming Priority (3)

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    CH168897 1997-07-10

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    CN101798391B (en) * 2010-03-29 2012-03-21 东莞市良展有机硅科技有限公司 Process for preparing modified textile silica gel and product thereof
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    US2861949A (en) * 1956-09-10 1958-11-25 Willis C Ware Fur glazing composition and method for preparing same
    US3519561A (en) * 1966-06-23 1970-07-07 Gaf Corp Alkoxylated tertiary amine antistatic composition
    DE1619058A1 (en) * 1967-12-01 1971-01-28 Hoechst Ag Preparations for treating textiles
    FR2153434A1 (en) * 1971-09-23 1973-05-04 Kao Corp
    US4233164A (en) * 1979-06-05 1980-11-11 The Proctor & Gamble Company Liquid fabric softener
    EP0056695A2 (en) * 1981-01-16 1982-07-28 THE PROCTER & GAMBLE COMPANY Textile treatment compositions

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    Publication number Priority date Publication date Assignee Title
    US4054716A (en) * 1975-05-06 1977-10-18 Ciba-Geigy Corporation Preparations of reaction products obtained from epoxides, fatty amines and reaction products which contain carboxyl groups, process for their manufacture and their use
    CH611107B (en) * 1977-08-25 Ciba Geigy Ag PROCESS FOR THE REMOVAL OF OLIGOMER PRECISIONS FROM DYED TEXTILE MATERIAL CONTAINING POLYESTER FIBERS.

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    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US2861949A (en) * 1956-09-10 1958-11-25 Willis C Ware Fur glazing composition and method for preparing same
    US3519561A (en) * 1966-06-23 1970-07-07 Gaf Corp Alkoxylated tertiary amine antistatic composition
    DE1619058A1 (en) * 1967-12-01 1971-01-28 Hoechst Ag Preparations for treating textiles
    FR2153434A1 (en) * 1971-09-23 1973-05-04 Kao Corp
    US4233164A (en) * 1979-06-05 1980-11-11 The Proctor & Gamble Company Liquid fabric softener
    EP0056695A2 (en) * 1981-01-16 1982-07-28 THE PROCTER & GAMBLE COMPANY Textile treatment compositions

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