EP0884415B1 - Method of washing pulp in connection with bleaching - Google Patents

Method of washing pulp in connection with bleaching Download PDF

Info

Publication number
EP0884415B1
EP0884415B1 EP98113684A EP98113684A EP0884415B1 EP 0884415 B1 EP0884415 B1 EP 0884415B1 EP 98113684 A EP98113684 A EP 98113684A EP 98113684 A EP98113684 A EP 98113684A EP 0884415 B1 EP0884415 B1 EP 0884415B1
Authority
EP
European Patent Office
Prior art keywords
washer
bleaching
stage
pulp
recited
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98113684A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0884415A1 (en
Inventor
Kaj Henricson
Bertil Stromberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Andritz Oy
Original Assignee
Andritz Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8537491&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0884415(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Andritz Oy filed Critical Andritz Oy
Publication of EP0884415A1 publication Critical patent/EP0884415A1/en
Application granted granted Critical
Publication of EP0884415B1 publication Critical patent/EP0884415B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1026—Other features in bleaching processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/02—Washing ; Displacing cooking or pulp-treating liquors contained in the pulp by fluids, e.g. wash water or other pulp-treating agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1026—Other features in bleaching processes
    • D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1026—Other features in bleaching processes
    • D21C9/1042—Use of chelating agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
    • D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/16—Bleaching ; Apparatus therefor with per compounds
    • D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides

Definitions

  • the present invention relates to a method of washing pulp in connection with bleaching.
  • the invention is especially related to ozone bleaching of pulp without preceding removal of heavy metals.
  • Typical bleaching sequences by which pulp has earlier been bleached are, for example, OOAZEZPZ, OAZEZPZ, OOAZEZP and OAZEZP. These sequences thus include one or more oxygen bleaching stages (O), an A-stage (acid washing), an ozone stage (Z), an extraction stage (E), a second ozone stage (Z) and a peroxide stage (P), and possibly a third ozone stage (Z).
  • the extraction stage (E) may be an oxidizing peroxide extraction stage or a conventional oxidizing extraction stage.
  • the ozone bleaching stages are preferably carried out with pulp having the consistency of about 5-18%.
  • washing stages in other words bleaching stages alternate with washing stages, i.e. washers, by which the chemicals separated from the fibers as reaction products or otherwise in each bleaching stage are removed from the suspension. Since the washers form a considerable part of the investment costs in a bleaching plant, the number of the washers should, of course, be limited as much as possible, if it is only possible without risking the quality of the final product.
  • EP-A-0 426 652 discloses several bleaching sequences where ozone has been used in combination with peroxide and oxygen. For instance, sequences like EOP-Z-PE-Z-PE, EOP-Z-PE, O-Z-EO-Z-P, O-Z-EOP-Z-P and O-Z-EO-Z-D were discussed. However, the publication does not take into account the presence of heavy metals in the pulp in spite of the fact that at least one of the examples discusses bleaching of kraft pulp by means of a peroxide containing compound.
  • EP-A-0 512 978 discloses a multi-stage bleaching process using both ozone and peroxide for bleaching pulp. The document does not pay any attention to the removal of heavy metals from pulp before bleaching with peroxide.
  • EP-A-0 402 335 discloses a process for bleaching lignocellulose-containing pulps by means of peroxide containing substance.
  • the main teaching of the document is to alter the trace metal profile of the pulp by means of a separate treatment with a complexing agent.
  • the document teaches the importance of treating pulp prior to a peroxide stage in a separate metal removing stage.
  • the treatment comprises a washing stage between the treatment with complex formers and the peroxide stage.
  • US-A-4 310 384 describes ozone bleaching with stages before and after it. The pulp is washed after each stage with counterflow of the wash filtrate.
  • a conventional bleaching + screening plant has thus included four or five bleaching stages and one screening and/or vortex cleaning stage, which the washing stage separates from each other.
  • the present invention compresses these five to six stages into three stages and thus almost halves the investment costs of a bleaching plant and a screening plant.
  • the method in accordance with the present invention involves that pulp is bleached with a sequence beginning with ozone and without the removal of heavy metals preceding the ozone stage.
  • a bleaching sequence is provided using a high consistency pulp tower 10, from which pulp is discharged and fed, for example, with an MC® (i.e. fluidizing) pump 12 into an ozone reactor 14, from which pulp is preferably discharged by means of a gas separator 16 into a first reaction tower 18.
  • Pulp is preferably discharged from tower 18 into a washer 22 by means of an MC® pump 20.
  • the washer may be a conventional DRUM DISPLACERTM washer or a conventional pressure diffuser. Pulp is preferably pumped from washer 22 by an MC® pump 24 into an oxygen reactor 26, and from reactor 26 into a second reaction tower 28.
  • a second washer 32 preferably a DRUM DISPLACERTM washer
  • ozone in a carrier gas
  • oxygen may be mixed prior to the oxygen reactor 26 with mixer 62 and the mixture of ozone and carrier gas prior to the second ozone reactor 36.
  • the mixers 60, 62, 64 are preferably AHLMIXERTM type fluidizing mixers, which are able to mix very large amounts of gas into fiber suspensions, including medium consistency suspensions.
  • Fig. 1 teaches how, in order to adjust the pH value of the pulp for the first ozone stage and the removal of heavy metals subsequent thereto, acid may be supplied into the pulp, for example, in the pump 12.
  • complex formers such as EDTA, and/or alkali may be added to the pulp. If too much magnesium is removed from the pulp by washer 22, it may be added, for example, with the alkali either in pump 24 and/or in the discharge from the oxygen reactor 26, or in any other appropriate way.
  • Another possibility to adjust the pH of the pulp for the second ozone treatment is to feed acid subsequent to the second washer 32 in pump 34 or in some other suitable way.
  • peroxide and/or magnesium may be added into the pulp, as illustrated in Fig. 1.
  • All the reaction towers 18, 28 and 40 in Fig. 1 are shown as of the down flow type. Alternatively, they may be of the up flow type, as is shown in Fig. 2.
  • the only significant difference between Figs. 1 and 2 is the flow direction of the reaction towers.
  • components functionally equivalent to or the same as the components in the Fig. 1 embodiment are illustrated by the same reference numeral, only preceded by a "1".
  • pumps 20, 30 and 42 of Fig. 1 are replaced by pumps 120', 130' and 142' of Fig.2, because they have been relocated at the other side of the reaction tower, in other words instead of feeding washers 22, 32 and 44 as illustrated in Fig. 1 they feed pulp to the reaction towers 118, 128 and 140 in the embodiments of Fig. 2.
  • pulp is cooked, for example with a continuous EMCC digester, sold by Kamyr Inc., of Glens Falls, New York, to a low kappa number, whereafter the kappa number is further decreased by oxygen bleaching to a value of about 14 or below.
  • a continuous EMCC digester sold by Kamyr Inc., of Glens Falls, New York
  • oxygen bleaching to a value of about 14 or below.
  • hot alkali extraction and oxygen bleaching a kappa range of 14 - 5 is obtained both with soft wood and birch.
  • a kappa number of 14 is sufficient in order to carry out the final bleaching with chlorine-free bleaching chemicals and yet reach a full brightness defined by ISO 86 (preferably ISO 88).
  • ISO 86 preferably ISO 88
  • the kraft pulp is bleached subsequent to the pulp washing and according to the invention without a separate removal of heavy metals, for example, with a sequence in accordance with Fig. 1, which is described more in detail below.
  • Pulp may be treated, if so required, with enzymes prior to the sequence in accordance with the present invention.
  • Pulp is brought from the high consistency pulp tower 10 to the first bleaching stage, which is a (ZT) stage.
  • the first bleaching stage which is a (ZT) stage.
  • pulp is bleached with ozone, the dosing being about 2-10 kg/adt, pH about 2- 7, and temperature about 40-70°C.
  • the pH value of pulp is adjusted by adding acid to the bottom of the high consistency tower 10, pump 12 (or the discharge to pump 12 as seen in Fig. 1), or chemical mixer 60.
  • the ozone having reacted, the residual gas is removed from the pulp preferably in a gas separator 16 and the treatment of heavy metals begins in the first reaction tower 18 in the T portion
  • the T portion of the (ZT) stage may be carried out, for example, in the following ways.
  • the first alternative is to allow the pH value of the pulp to decrease to the range of 2 - 4, whereby the majority of the heavy metals are dissolved into the filtrate phase and may be washed off in the thickener or washer 22 following that stage.
  • the disadvantage here is that the majority of the magnesium (Mg) is also discharged, so that it is possible that magnesium must be added to the pulp, mostly in the form of magnesium sulphate, for the oxygen and/or peroxide stages following later on in the sequence.
  • T portion of the (ZT) stage Another way to carry out the T portion of the (ZT) stage is to use complex formers, for example, EDTA.
  • the T portion of the (ZT) stage is then carried out in the pH range of about 4-7 and it is advantageous also to have the pH of Z portion of the (ZT) stage preceding T portion above 4.
  • manganese which is harmful in the oxygen stages
  • Filtrate S 1 of the washer 22 subsequent to the (ZT) stage may be brought to pulp washing prior to the (ZT) stage, or passed to the sewer or to the recovery of cooking chemicals.
  • the (ZT) stage is followed in Fig. 1 by an (EOP) stage.
  • the oxygen dose is about 2-6 kg/adt and the peroxide dose about 10-20 kg/adt. In some special cases it is possible to run the process completely without oxygen.
  • Temperature in the (EOP) stage is about 60-95°C, pH about 9-12, and the duration is about 2-8 hours. If required, magnesium may be added as a protective chemical.
  • the (EOP) stage is followed by washing, which gives filtrate S 2 .
  • the filtrate S 2 may be taken to pulp washing prior to or subsequent to the (ZT) stage, to sewer, or to recovery of chemicals.
  • the (EOP) stage is followed in Fig. 1 by a second ozone bleaching stage, i.e. an (ZP) stage.
  • the ozone portion of the (ZP) stage is normally carried out in the processes in accordance with the prior art in cold, acid conditions in order to have the ozone react properly.
  • the P portion of the (ZP) stage is carried out according to the teachings of the prior art in hot, alkali conditions in order to have the peroxide react properly.
  • the combination thereof in an economically advantageous way according to the present concepts is conventionally considered impossible.
  • the ozone dose is small, below 3 kg/adt and the purpose of the ozone is only to activate. Although disadvantageous conditions are used and a part of the ozone reacts poorly, this is insignificant, because the dose is small. Ozone is thus mainly used for the activation of the bleaching stage.
  • the temperature in the ozone stage may be 50-80°C, preferably, for example, 60-70°C.
  • the pH is 4-10, preferably about 6- 10.
  • the dose in the P portion of the (ZP) stage is also small, usually less than 10 kg/adt. Normally about 3-7 kg/adt is sufficient.
  • the temperature in the peroxide stage may be dropped to the range of 60-80°C, preferably to 70-80°C.
  • the pH is 9-11, preferably about 10.
  • the duration is about 1-6 hours.
  • the pulp is washed and a filtrate S 3 is obtained.
  • the filtrate S 3 may be used for the washing of pulp in connection with the earlier bleaching stages, discharged to the sewer, or led to the recovery of cooking chemicals.
  • a vortex cleaner 66 and/or a screening plant may be added according to Fig. 3 to the last stage of the bleaching plant to precede the thickener/washer 68, which in this case does not have to be an MC® washer, as in the earlier embodiments.
  • Pulp is diluted to the consistency range of about 0.5-1.5 % after the P-tower 140, when vortex cleaning or screening with a slotted screen is used. On the other hand, when screening with a perforated screen, a dilution to about 2-4% is usually sufficient.
  • the pulp is thickened and washed - usually with a suction filter 68. Previously pulp had to be diluted after washing to a screening consistency and thickened again after screening to a medium consistency.
  • FIG. 5 illustrates an oxygen delignification stage 80, which is followed by a two-stage washing 82. Pulp is transferred from the washing stage to the (ZT) stage 83, and from there via washing 84 to (EOP) stage 85, and from there via washing 86 to the (ZP) stage 87, which is followed by a washing stage 88.
  • the amount of effluent, which is brought to the effluent clarification, discharge channel 90, is 0-5 m3/adt. Part of the effluent may alternatively be transferred to the manufacture of cooking chemicals, via discharge channel 92, to be used instead of fresh water. Thus the amount of effluent that must be treated is minimized.
  • Fig. 5 may further be intensified by dividing the filtrates from the washer into two fractions with different pH according to Fig. 6.
  • Fig. 6 utilizes the reference numbers of Fig. 5 with a preceding "1".
  • the washers used in Fig. 6 are manufactured and marketed by A. Ahlstrom Corporation, and known as DRUM DISPLACERTM washers.
  • the pulp for the last washer 188 comes from the alkali (ZP) stage.
  • ZP alkali
  • the first outwashed filtrate 1881 is clearly alkaline and the filtrate 1882 coming out later is less alkaline or even neutral, because water 1880 flowing to the last washer 188 is generally neutral or slightly acid.
  • the pH of the filtrates may also be adjusted by adding acid or alkali to them before they are used again. In some cases it may, for example, be necessary to add alkali to the filtrates prior to their being brought to the brown stock washing or it may be necessary to add acid in order to maintain the pH low during the removal of the metals in the (ZT) stage (point 1840). It is possible that heavy metals are thickened again and attach to the fibers, if the pH increases during washing. Thus heavy metals are entrained to the P portion of the (ZP) stage following the Z portion and disturb the peroxide stage. Preferably the pH value is maintained less than 4, or at least maintained at 4, during the removal of heavy metals.
  • the pH values of the filtrates are close to the respective pH values of the entering and exiting pulp, preferably closer to these than to each other.
  • the present invention also includes a new method of arranging the screening subsequent to the pulp bleaching in such a way that a separate washing between the last washing stage and screening/vortex cleaning is unnecessary, but only dilution to screening/cleaning consistency is needed.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Paper (AREA)
  • Detergent Compositions (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP98113684A 1993-03-03 1993-05-25 Method of washing pulp in connection with bleaching Expired - Lifetime EP0884415B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI930954A FI93232C (fi) 1993-03-03 1993-03-03 Menetelmä massan valkaisemiseksi kloorivapailla kemikaaleilla
FI930954 1993-03-03
EP93910051A EP0687321B1 (en) 1993-03-03 1993-05-25 Method of bleaching pulp with chlorine-free chemicals

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP93910051A Division EP0687321B1 (en) 1993-03-03 1993-05-25 Method of bleaching pulp with chlorine-free chemicals

Publications (2)

Publication Number Publication Date
EP0884415A1 EP0884415A1 (en) 1998-12-16
EP0884415B1 true EP0884415B1 (en) 2002-11-20

Family

ID=8537491

Family Applications (2)

Application Number Title Priority Date Filing Date
EP98113684A Expired - Lifetime EP0884415B1 (en) 1993-03-03 1993-05-25 Method of washing pulp in connection with bleaching
EP93910051A Expired - Lifetime EP0687321B1 (en) 1993-03-03 1993-05-25 Method of bleaching pulp with chlorine-free chemicals

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP93910051A Expired - Lifetime EP0687321B1 (en) 1993-03-03 1993-05-25 Method of bleaching pulp with chlorine-free chemicals

Country Status (13)

Country Link
EP (2) EP0884415B1 (ru)
JP (1) JP3276083B2 (ru)
AT (2) ATE228181T1 (ru)
AU (1) AU5370594A (ru)
BR (1) BR9307858A (ru)
CA (1) CA2157109C (ru)
DE (2) DE69323566T2 (ru)
ES (2) ES2130260T3 (ru)
FI (3) FI93232C (ru)
NO (1) NO953444L (ru)
PT (1) PT884415E (ru)
RU (1) RU2126471C1 (ru)
WO (1) WO1994020673A1 (ru)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI89516B (fi) 1989-05-10 1993-06-30 Ahlstroem Oy Foerfarande foer blekning av cellulosamassa med otson
FI103818B1 (fi) * 1995-02-21 1999-09-30 Ahlstrom Machinery Oy Menetelmä massan valkaisemiseksi
US20080110584A1 (en) * 2006-11-15 2008-05-15 Caifang Yin Bleaching process with at least one extraction stage
FR2910027B1 (fr) * 2006-12-13 2009-11-06 Itt Mfg Enterprises Inc Procede de blanchiment des pates papeteries chimiques par traitement final a l'ozone a haute temperature
BRPI1012052A2 (pt) 2009-05-28 2017-12-26 Gp Cellulose Gmbh fibras kraft hidrolisadas e quimicamente modificadas e métodos de produção e de branqueamento de fibras kraft
MX353539B (es) 2011-05-23 2018-01-17 Gp Cellulose Gmbh Star Fibra kraft de madera blanda que tiene blancura y brillo mejorados, y metodos para preparala y usarla.
CN104302831A (zh) 2012-01-12 2015-01-21 Gp纤维素股份有限公司 具有降低的黄变特性的低粘性牛皮纸纤维及其制造和使用方法
CN106968127B (zh) 2012-04-18 2019-03-01 Gp纤维素股份有限公司 用于粘胶溶液的针叶木牛皮纸浆
JP6472758B2 (ja) 2013-02-08 2019-02-20 ゲーペー ツェルローゼ ゲーエムベーハー 改善されたα−セルロース含量を有する軟材クラフト繊維およびその化学セルロース製品の生産における使用
BR112015019882A2 (pt) 2013-03-14 2017-07-18 Gp Cellulose Gmbh fibra kraft clareada oxidada e métodos para fazer polpa kraft e fibra kraft de madeira macia e para clarear polpa kraft de celulose em sequência de branqueamento de multi-estágios
BR112015020000A2 (pt) 2013-03-15 2017-07-18 Gp Cellulose Gmbh fibra kraft quimicamente modificada e métodos de fabricação da mesma
FR3007044B1 (fr) * 2013-06-13 2016-01-15 Air Liquide Procede de traitement des pates papetieres chimiques par traitement a l'ozone en presence d'ions magnesium
AT515152B1 (de) * 2013-11-26 2015-12-15 Chemiefaser Lenzing Ag Verfahren zum Vorbehandeln von rückgewonnenen Baumwollfasern zur Verwendung bei der Herstellung von Formkörpern aus regenerierter Cellulose
EP3541849B1 (en) 2016-11-16 2023-11-15 GP Cellulose GmbH Modified cellulose from chemical fiber and methods of making and using the same
SE545759C2 (en) * 2022-06-20 2024-01-02 Valmet Oy Method for bleaching pulp from recycled textile material

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO144711C (no) * 1978-04-04 1981-10-21 Myrens Verksted As Fremgangsmaate til bleking av oksygendelignifiserte celluloseholdige masser med ozon
US4310384A (en) * 1979-01-11 1982-01-12 Weyerhaeuser Company Reducing chemical transfer between treatment stages
FI74752C (fi) * 1986-03-20 1992-12-01 Ahlstroem Oy Foerfarande och anordning foer tvaettning av cellulosa
DE69004492T3 (de) * 1989-06-06 2001-11-15 Eka Nobel Ab, Bohus Verfahren zum Bleichen von Lignocellulose enthaltenden Zellstoffen.
AU636173B2 (en) * 1989-10-30 1993-04-22 Lenzing Aktiengesellschaft Method for the chlorine-free bleaching of pulps
US5567262A (en) * 1991-04-16 1996-10-22 Ahlstrom Machinery Inc. Two stage pressure diffuser
SE468355B (sv) * 1991-04-30 1992-12-21 Eka Nobel Ab Blekning av kemisk massa genom behandling med komplexbildare och ozon
AT400153B (de) * 1991-05-02 1995-10-25 Voest Alpine Ind Anlagen Verfahren zum bleichen von xylan- und lignocellulosehältigen materialien

Also Published As

Publication number Publication date
AU5370594A (en) 1994-09-26
FI934036A0 (fi) 1993-09-15
CA2157109A1 (en) 1994-09-15
PT884415E (pt) 2003-03-31
RU2126471C1 (ru) 1999-02-20
DE69332508D1 (de) 2003-01-02
BR9307858A (pt) 1996-02-27
DE69323566T2 (de) 1999-07-15
CA2157109C (en) 2002-09-03
FI93232B (fi) 1994-11-30
EP0884415A1 (en) 1998-12-16
FI930954A (fi) 1994-09-04
FI934036A (fi) 1994-09-04
ATE228181T1 (de) 2002-12-15
FI98223B (fi) 1997-01-31
EP0687321B1 (en) 1999-02-17
DE69323566D1 (de) 1999-03-25
DE69332508T2 (de) 2003-07-03
ES2186948T3 (es) 2003-05-16
FI93232C (fi) 1995-03-10
FI954093A (fi) 1995-10-17
FI930954A0 (fi) 1993-03-03
FI954093A0 (fi) 1995-08-30
ES2130260T3 (es) 1999-07-01
EP0687321A1 (en) 1995-12-20
JPH08509781A (ja) 1996-10-15
JP3276083B2 (ja) 2002-04-22
ATE176808T1 (de) 1999-03-15
NO953444D0 (no) 1995-09-01
WO1994020673A1 (en) 1994-09-15
NO953444L (no) 1995-10-19

Similar Documents

Publication Publication Date Title
US6010594A (en) Method of bleaching pulp with chlorine-free chemicals wherein a complexing agent is added immediately after an ozone bleach stage
EP0884415B1 (en) Method of washing pulp in connection with bleaching
AU670659B2 (en) Process for delignification of lignocellulose-containing pulp
AU4096793A (en) A process for bleaching pulp without using chlorine-containing chemicals
EP0650541B1 (en) Process for bleaching pulp in conjunction with adsorption of metals
RU2148118C1 (ru) Двустадийная делигнификация лигноцеллюлозной массы кислородом
CA2031848C (en) Method of bleaching pulp
WO1995009945A1 (en) Method of treating chemical paper pulp without using chlorine-containing chemicals
RU95122814A (ru) Способ производства целлюлозы без применения хлорных химикатов
AU665461B2 (en) Method of treating process water
EP1644574B1 (en) Method for treating pulp in connection with the bleaching of chemical pulp
EP0846199B1 (en) Treatment of pulp with chelating agent in at least two mixing steps without intermediate washing
US6375797B1 (en) Bleaching chemical pulp in a PkDQ-Po Sequence
WO1995008021A1 (en) Eop stage for chlorine free bleaching
EP0951599B1 (en) Treatment of pulp with a chelating agent without using a bleaching tower
WO1998014657A1 (en) Oxidation of disturbing metal ions in bleaching processes
CA2179700A1 (en) Method and apparatus for treating pulp

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19980722

AC Divisional application: reference to earlier application

Ref document number: 687321

Country of ref document: EP

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT DE ES FR PT SE

RIN1 Information on inventor provided before grant (corrected)

Inventor name: STROMBERG, BERTIL

Inventor name: HENRICSON, KAJ

17Q First examination report despatched

Effective date: 20010502

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: ANDRITZ-AHLSTROM OY

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: ANDRITZ OY

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AC Divisional application: reference to earlier application

Ref document number: 687321

Country of ref document: EP

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT DE ES FR PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20021120

REF Corresponds to:

Ref document number: 228181

Country of ref document: AT

Date of ref document: 20021215

Kind code of ref document: T

REF Corresponds to:

Ref document number: 69332508

Country of ref document: DE

Date of ref document: 20030102

ET Fr: translation filed
REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20030206

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20030411

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20030507

Year of fee payment: 11

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2186948

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20030821

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20040510

Year of fee payment: 12

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050131

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Effective date: 20041125

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050526

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20050526

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20080425

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20080421

Year of fee payment: 16

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090526