EP0884152A1 - A slab of stone material with multiple layer paper and phenolic resin-based backing, and method for making slab - Google Patents

A slab of stone material with multiple layer paper and phenolic resin-based backing, and method for making slab Download PDF

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Publication number
EP0884152A1
EP0884152A1 EP98110541A EP98110541A EP0884152A1 EP 0884152 A1 EP0884152 A1 EP 0884152A1 EP 98110541 A EP98110541 A EP 98110541A EP 98110541 A EP98110541 A EP 98110541A EP 0884152 A1 EP0884152 A1 EP 0884152A1
Authority
EP
European Patent Office
Prior art keywords
backing
slab
marble
block
stone material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98110541A
Other languages
German (de)
French (fr)
Inventor
Oreste Apolloni
Maria Stella Firori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NTM Nuove Tecnologie Marmifere Srl
Original Assignee
NTM Nuove Tecnologie Marmifere Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NTM Nuove Tecnologie Marmifere Srl filed Critical NTM Nuove Tecnologie Marmifere Srl
Publication of EP0884152A1 publication Critical patent/EP0884152A1/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D1/00Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor
    • B28D1/005Cutting sheet laminae in planes between faces
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups

Definitions

  • the invention relates to the field of marble processing to produce so-called marble-chip floor tiles or marble tiles, or generally slabs of marble, granite or stone, or stone material in general.
  • marble-chip floor tiles or marble tiles or generally slabs of marble, granite or stone, or stone material in general.
  • stone material in general, including stone, granites, etc. as well as marble.
  • slabs or tiles without distinction, it being understood that the invention applies to one and the other without limitations of size.
  • fibreglass is sprayed on top of a liquid resin applied to the back of the tile.
  • the results obtained are not satisfactory and besides the working environment is made hazardous by the harmful microparticles which are dispersed into the air.
  • a further object is to make the tiles stronger over time, that is, to ensure that the tiles do not suffer structural or cosmetic changes once applied either due to the application materials or due to environmental factors.
  • a further object is to obtain the preceding objects at a cost compatible with the market.
  • the new product comprises a layer of marble coupled, by gluing on the back, to a single layer or a multilayer of kraft paper impregnated with phenolic resin.
  • a laminate known as LPR - a registered trademark of LIRI Industriale - or FORMICA - a registered trademark of the FORMICA CORPORATION - without the outer layer of melamine resin can be used as the backing.
  • a block of marble is coupled on its two larger surfaces with respective backing sheets as stated above, by means of gluing and then it is divided or separated, that is, cut in half parallel to the larger surfaces, so as to obtain two slabs, which are then cut to the desired shape and size.
  • the new tile with a backing according to the invention has numerous advantages.
  • the perfect adhesion of the backing to the marble and its characteristic of elasticity mean that, besides stability, flexibility and tensile stress are increased. Consequently there is less waste during processing and a greater yield, and in addition the covering with the tiles lasts longer and is stronger.
  • the consistency obtained makes it possible to create tiles with smaller thicknesses than those currently on the market, which allows them to be used for tiling in sectors where greater lightness is particularly necessary (tiling of ships, lifts, skyscrapers, etc.) and with a considerable saving on the raw material used.
  • the reduction in specific weight is about 10% or even more. This also results in a reduction in transport costs.
  • a further advantage is that the material can be set in place using normal glues, without having to use specific products to make it adhere walls and without the colour of the glue appearing on the visible surface of the tile.
  • a further advantage consists in the fact that, once the slab or tile has been set in place, the supporting sheet forms a barrier against damp rising from the wall to the marble, and thus the inherent problems such as stains or cracks are eliminated.
  • the new tile 10 comprises a layer of marble 11 and a backing sheet 12 glued to the layer of marble on the back thereof.
  • the backing according to the invention comprises a single layer or a multilayer of kraft paper impregnated with phenolic resins.
  • a laminated product known as LPR, or FORMICA, preferably deprived of the melamine layer, can be used.
  • a block of marble with a thickness more than double the final thickness that is to be obtained for the tiles is first cut; said block is indicated by reference numeral 20.
  • two backing sheets 21, 22 in a single layer or a multilayer of craft paper soaked in phenolic resins are applied. These backing sheets are applied by gluing.
  • the block is then left to dry.
  • the block is then divided or sawn roughly in half, or in any case in an intermediate position with respect to the thickness, along a plane p parallel to the planes of the larger faces, so as to obtain two strips 20a, 20b that each have an exposed marble surface and the backing.
  • the two strips are then processed as desired on the surface on view and cut to the desired final shape and size of the tiles.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Mining & Mineral Resources (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Finishing Walls (AREA)

Abstract

A marble, granite or stone tile for building uses has on the surface not on view a glued kraft paper or phenolic resin-based backing, preferably a multilayer of kraft paper and phenolic resins, as used in manufacturing plastic laminates.
The procedure provides that after obtaining a chunk or square block of marble (20), each of the two surfaces thereof undergo application of the backing (21,22) as stated above and then the block is divided in two along a plane (p) parallel to the largest surfaces, to obtain slabs or blocks (20a,20b) of the desired thickness, which are then cut to the desired shape and size.

Description

The invention relates to the field of marble processing to produce so-called marble-chip floor tiles or marble tiles, or generally slabs of marble, granite or stone, or stone material in general. For simplicity's sake reference will be made hereunder to marble; it is understood, however, that the invention applies to stone material in general, including stone, granites, etc. as well as marble. Reference will also be made to slabs or tiles without distinction, it being understood that the invention applies to one and the other without limitations of size.
Some precious marbles have fractures or microfractures that compromise their consistency and therefore they cannot be processed by normal procedures, or, at least, the usual procedures give rise to considerable waste (up to 80% of the initial raw material). Various solutions to this problem have been studied. For example, use has been made of liquid resins applied to give consistency to the product, but without appreciable results.
Another prior art solution to the problem consists in applying a nylon net to the back of the tile as a support. However, this solution does not give the tile satisfactory stability and there are quite a few breakages during polishing, with consequent slowing of the automatic production lines.
According to another procedure known to the art, fibreglass is sprayed on top of a liquid resin applied to the back of the tile. However, in this case also the results obtained are not satisfactory and besides the working environment is made hazardous by the harmful microparticles which are dispersed into the air.
Some companies in the field have made use of a marble backing as a base layer for working such friable materials; this procedure is quite successful, but has a very high cost, due both the somewhat complex application procedure and to the cost of the material used as a backing.
Having examined the products and procedures of the prior art, the applicant set out to achieve stability of the material during processing even for relatively small thicknesses of material and thus obtain a considerable reduction in production waste. A further object is to make the tiles stronger over time, that is, to ensure that the tiles do not suffer structural or cosmetic changes once applied either due to the application materials or due to environmental factors.
A further object is to obtain the preceding objects at a cost compatible with the market.
These objects have been achieved with a product as claimed in claim 1 and a procedure as claimed in claim 4.
The new product comprises a layer of marble coupled, by gluing on the back, to a single layer or a multilayer of kraft paper impregnated with phenolic resin.
A laminate known as LPR - a registered trademark of LIRI Industriale - or FORMICA - a registered trademark of the FORMICA CORPORATION - without the outer layer of melamine resin can be used as the backing.
According to the procedure, a block of marble is coupled on its two larger surfaces with respective backing sheets as stated above, by means of gluing and then it is divided or separated, that is, cut in half parallel to the larger surfaces, so as to obtain two slabs, which are then cut to the desired shape and size.
The new tile with a backing according to the invention has numerous advantages. the perfect adhesion of the backing to the marble and its characteristic of elasticity mean that, besides stability, flexibility and tensile stress are increased. Consequently there is less waste during processing and a greater yield, and in addition the covering with the tiles lasts longer and is stronger.
The consistency obtained makes it possible to create tiles with smaller thicknesses than those currently on the market, which allows them to be used for tiling in sectors where greater lightness is particularly necessary (tiling of ships, lifts, skyscrapers, etc.) and with a considerable saving on the raw material used. The reduction in specific weight is about 10% or even more. This also results in a reduction in transport costs.
A further advantage is that the material can be set in place using normal glues, without having to use specific products to make it adhere walls and without the colour of the glue appearing on the visible surface of the tile.
A further advantage consists in the fact that, once the slab or tile has been set in place, the supporting sheet forms a barrier against damp rising from the wall to the marble, and thus the inherent problems such as stains or cracks are eliminated.
The product and the procedure forming the subject matter of the invention will be described in greater detail below with reference to the attached drawings, in which:
  • Figure 1 represents a perspective view of the tile according to the invention, with a part removed to show the supporting sheet;
  • Figure 2 is a view in profile of the tile
  • Figures 3, 4, 5 diagrammatically show the procedure of the invention.
  • With reference first to Figure 1, the new tile 10 according to the invention comprises a layer of marble 11 and a backing sheet 12 glued to the layer of marble on the back thereof. The backing according to the invention comprises a single layer or a multilayer of kraft paper impregnated with phenolic resins. For example, a laminated product known as LPR, or FORMICA, preferably deprived of the melamine layer, can be used.
    This backing lends the tile flexural strangth whether it bends with the marble surface on the extrados or with the support on the extrados (something which was not possible with prior systems).
    With reference now to Figures 3-5, according to the procedure a block of marble with a thickness more than double the final thickness that is to be obtained for the tiles, is first cut; said block is indicated by reference numeral 20. On the opposite larger faces of the block 20 two backing sheets 21, 22 in a single layer or a multilayer of craft paper soaked in phenolic resins are applied. These backing sheets are applied by gluing. The block is then left to dry. The block is then divided or sawn roughly in half, or in any case in an intermediate position with respect to the thickness, along a plane p parallel to the planes of the larger faces, so as to obtain two strips 20a, 20b that each have an exposed marble surface and the backing. The two strips are then processed as desired on the surface on view and cut to the desired final shape and size of the tiles.

    Claims (6)

    1. A slab of stone material, such as marble, granite or stone, for coverings comprising a layer of stone material (11) and a backing integral with each other, characterized in that said backing (12) comprises at least a sheet of paper or paper material impregnated with phenolic resins.
    2. A slab according to claim 1 characterized in that said backing is multilayer kraft paper impregnated with phenolic resins.
    3. A slab according to claim 1 characterized in that said support (12) is a plastic laminate comprising a base of kraft paper soaked in phenolic resins and layers of melamine resin, at least partially deprived of the melamine resin part.
    4. A procedure to obtain a slab according to claim 1 characterized in that it comprises the following steps:
      creating a block of stone material, substantially with flat surfaces with a thickness greater than double the final thickness desired for the tiles;
      applicating a backing by gluing on the two opposite larger surfaces of the block, said backing comprising a layer of kraft paper impregnated with phenolic resins;
      dividing the block along a plane (p) parallel to the larger surfaces of the block so as to obtain two slabs each having a marble surface on view and said backing on the back.
    5. A procedure according to claim 4 comprising the further step of: finishing the slabs thus obtained to obtain tiles.
    6. A procedure according to claim 5 characterized in that said finishing step comprises cutting to define the single tiles.
    EP98110541A 1997-06-12 1998-06-09 A slab of stone material with multiple layer paper and phenolic resin-based backing, and method for making slab Withdrawn EP0884152A1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    ITMI971393 1997-06-12
    IT97MI001393A IT1292150B1 (en) 1997-06-12 1997-06-12 SLABS IN STONE MATERIAL WITH MULTILAYER SUPPORT BASED ON PAPER AND PHENOLIC RESINS AND PROCEDURE

    Publications (1)

    Publication Number Publication Date
    EP0884152A1 true EP0884152A1 (en) 1998-12-16

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    EP98110541A Withdrawn EP0884152A1 (en) 1997-06-12 1998-06-09 A slab of stone material with multiple layer paper and phenolic resin-based backing, and method for making slab

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    EP (1) EP0884152A1 (en)
    IT (1) IT1292150B1 (en)

    Cited By (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    ES2172394A1 (en) * 2000-05-19 2002-09-16 Navarro Vicente Marti Fabrication of marble building slabs consists of application of polyurethane sheets to a quarried and cut slab, for subdivision into two identical structure slabs
    ES2190332A1 (en) * 2001-04-04 2003-07-16 Politek Plant S L Millimetric dissection of e.g. marble consists of unilateral coating with polyurethane prior to cutting parallel with this keying layer
    WO2003064128A1 (en) * 2002-01-31 2003-08-07 Esteve & Mañez Marmoles, S.A. Method of obtaining slabs of petrous materials comprising two layers of materials having different aesthetic qualities and the slabs thus obtained
    ES2312283A1 (en) * 2007-08-06 2009-02-16 Camilo Piedras De Galicia, S.L. Method for obtaining slabs of natural stone for use in decoration
    EP2184422A2 (en) * 2008-11-06 2010-05-12 Azteca Sergrup, S.L. Modular flooring

    Citations (2)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4063982A (en) * 1972-09-04 1977-12-20 Bourke Patrick T Method of making a composite surface elements of stone and lightweight sheet material
    EP0344619A1 (en) * 1988-06-01 1989-12-06 TECNOMAIERA S.r.l. A method for the production of reinforced panels from a block of building material, such as stone

    Patent Citations (2)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4063982A (en) * 1972-09-04 1977-12-20 Bourke Patrick T Method of making a composite surface elements of stone and lightweight sheet material
    EP0344619A1 (en) * 1988-06-01 1989-12-06 TECNOMAIERA S.r.l. A method for the production of reinforced panels from a block of building material, such as stone

    Cited By (8)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    ES2172394A1 (en) * 2000-05-19 2002-09-16 Navarro Vicente Marti Fabrication of marble building slabs consists of application of polyurethane sheets to a quarried and cut slab, for subdivision into two identical structure slabs
    ES2190332A1 (en) * 2001-04-04 2003-07-16 Politek Plant S L Millimetric dissection of e.g. marble consists of unilateral coating with polyurethane prior to cutting parallel with this keying layer
    WO2003064128A1 (en) * 2002-01-31 2003-08-07 Esteve & Mañez Marmoles, S.A. Method of obtaining slabs of petrous materials comprising two layers of materials having different aesthetic qualities and the slabs thus obtained
    ES2197795A1 (en) * 2002-01-31 2004-01-01 Esteve & Manez Marmoles S A Method of obtaining slabs of petrous materials comprising two layers of materials having different aesthetic qualities and the slabs thus obtained
    ES2312283A1 (en) * 2007-08-06 2009-02-16 Camilo Piedras De Galicia, S.L. Method for obtaining slabs of natural stone for use in decoration
    WO2009027567A1 (en) * 2007-08-06 2009-03-05 Camilo Piedras De Galicia, S.L. Method for obtaining slabs of natural stone for use in decoration
    EP2184422A2 (en) * 2008-11-06 2010-05-12 Azteca Sergrup, S.L. Modular flooring
    EP2184422A3 (en) * 2008-11-06 2012-01-11 Azteca Sergrup, S.L. Modular flooring

    Also Published As

    Publication number Publication date
    ITMI971393A1 (en) 1998-12-12
    ITMI971393A0 (en) 1997-06-12
    IT1292150B1 (en) 1999-01-25

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