EP0883663A4 - Selective hydrodesulfurization catalyst and process - Google Patents

Selective hydrodesulfurization catalyst and process

Info

Publication number
EP0883663A4
EP0883663A4 EP97905697A EP97905697A EP0883663A4 EP 0883663 A4 EP0883663 A4 EP 0883663A4 EP 97905697 A EP97905697 A EP 97905697A EP 97905697 A EP97905697 A EP 97905697A EP 0883663 A4 EP0883663 A4 EP 0883663A4
Authority
EP
European Patent Office
Prior art keywords
hydrodesulfurization catalyst
selective hydrodesulfurization
selective
catalyst
hydrodesulfurization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97905697A
Other languages
German (de)
French (fr)
Other versions
EP0883663A1 (en
Inventor
Mark P Lapinski
Kenneth L Riley
Thomas R Halbert
William Lasko
Jeffrey L Kaufman
Clyde L Aldridge
Michele S Touvelle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/583,725 external-priority patent/US6126814A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of EP0883663A1 publication Critical patent/EP0883663A1/en
Publication of EP0883663A4 publication Critical patent/EP0883663A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EP97905697A 1996-02-02 1997-01-30 Selective hydrodesulfurization catalyst and process Withdrawn EP0883663A4 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US601274 1995-07-20
US60127496A 1996-02-02 1996-02-02
US583725 1996-02-02
US08/583,725 US6126814A (en) 1996-02-02 1996-02-02 Selective hydrodesulfurization process (HEN-9601)
PCT/US1997/001594 WO1997040120A1 (en) 1996-02-02 1997-01-30 Selective hydrodesulfurization catalyst and process

Publications (2)

Publication Number Publication Date
EP0883663A1 EP0883663A1 (en) 1998-12-16
EP0883663A4 true EP0883663A4 (en) 1999-12-29

Family

ID=27078881

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97905697A Withdrawn EP0883663A4 (en) 1996-02-02 1997-01-30 Selective hydrodesulfurization catalyst and process

Country Status (5)

Country Link
EP (1) EP0883663A4 (en)
JP (1) JP3955096B2 (en)
AU (1) AU2252797A (en)
CA (1) CA2244374C (en)
WO (1) WO1997040120A1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7513989B1 (en) 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
US7288182B1 (en) * 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US5985136A (en) * 1998-06-18 1999-11-16 Exxon Research And Engineering Co. Two stage hydrodesulfurization process
US6413413B1 (en) 1998-12-31 2002-07-02 Catalytic Distillation Technologies Hydrogenation process
US6596157B2 (en) * 2000-04-04 2003-07-22 Exxonmobil Research And Engineering Company Staged hydrotreating method for naphtha desulfurization
US6673237B2 (en) 2001-11-28 2004-01-06 Corning Incorporated High performance monolith treater for gasoline upgrade
US6867338B2 (en) 2002-03-15 2005-03-15 Catalytic Distillation Technologies Selective hydrogenation of acetylenes and dienes in a hydrocarbon stream
US7220352B2 (en) * 2002-04-02 2007-05-22 Exxonmobil Research And Engineering Company Selective hydrodesulfurization of naphtha streams
US7776784B2 (en) 2003-07-14 2010-08-17 Nippon Oil Corporation Hydrodesulfurization catalyst and hydrodesulfurization process for gasoline fractions
JP4486329B2 (en) * 2003-07-14 2010-06-23 財団法人石油産業活性化センター Hydrodesulfurization catalyst and hydrodesulfurization method for gasoline fraction
JP4486330B2 (en) * 2003-07-14 2010-06-23 財団法人石油産業活性化センター Hydrodesulfurization catalyst and hydrodesulfurization method for gasoline fraction
JP2007501104A (en) * 2003-08-01 2007-01-25 エクソンモービル　リサーチ　アンド　エンジニアリング　カンパニー Catalyst system and its use in producing low sulfur fuel
AU2003289799A1 (en) * 2003-12-23 2005-07-14 China Petroleum And Chemical Corporation A process for reducing sulfur and olefin contents in gasoline
US7629289B2 (en) * 2004-06-23 2009-12-08 Uop Llc Selective naphtha desulfurization process and catalyst
CN101152631B (en) * 2006-09-29 2011-04-20 中国石油化工股份有限公司 Selective hydrogenation desulfurizing catalyzer and method of producing the same
JP5123635B2 (en) 2007-10-12 2013-01-23 Ｊｘ日鉱日石エネルギー株式会社 Method for producing gasoline base material and gasoline
JP5330056B2 (en) * 2009-03-30 2013-10-30 一般財団法人石油エネルギー技術センター Method for producing monocyclic aromatic hydrocarbons
JP4929311B2 (en) * 2009-04-27 2012-05-09 一般財団法人石油エネルギー技術センター Hydrodesulfurization catalyst and hydrodesulfurization method for gasoline fraction

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4013547A (en) * 1976-01-22 1977-03-22 Union Oil Company Of California Desulfurization of residual petroleum oils with a catalyst calcined at higher temperatures
US4016108A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
US4328127A (en) * 1980-09-16 1982-05-04 Mobil Oil Corporation Residua demetalation/desulfurization catalyst
US4717705A (en) * 1986-10-28 1988-01-05 Shell Oil Company Hydrotreating catalysts prepared from hydrogels
EP0349223A1 (en) * 1988-06-29 1990-01-03 Union Oil Company Of California Hydroprocessing catalytic composition and the preparation and use thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4132632A (en) * 1978-03-31 1979-01-02 Standard Oil Company (Indiana) Selective hydrodesulfurization of cracked naphtha
US4600703A (en) * 1983-12-19 1986-07-15 Intevep, S.A. Catalyst for the hydrocracking of heavy vacuum gas oils, method of preparation of catalyst and process for use thereof in the mild hydrocracking of heavy vacuum gas oils
US5266188A (en) * 1991-04-22 1993-11-30 Amoco Corporation Selective hydrotreating
US5169822A (en) * 1991-06-17 1992-12-08 Texaco Inc. Catalysts for removal of impurities by the hydroprocessing of hydrocarbons
US5275994A (en) * 1991-06-17 1994-01-04 Texaco Inc. Process for preparing a catalyst for removal of hydroprocessing impurities

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016108A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
US4013547A (en) * 1976-01-22 1977-03-22 Union Oil Company Of California Desulfurization of residual petroleum oils with a catalyst calcined at higher temperatures
US4328127A (en) * 1980-09-16 1982-05-04 Mobil Oil Corporation Residua demetalation/desulfurization catalyst
US4717705A (en) * 1986-10-28 1988-01-05 Shell Oil Company Hydrotreating catalysts prepared from hydrogels
EP0349223A1 (en) * 1988-06-29 1990-01-03 Union Oil Company Of California Hydroprocessing catalytic composition and the preparation and use thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO9740120A1 *

Also Published As

Publication number Publication date
JP3955096B2 (en) 2007-08-08
EP0883663A1 (en) 1998-12-16
WO1997040120A1 (en) 1997-10-30
JP2000505358A (en) 2000-05-09
CA2244374C (en) 2005-04-12
CA2244374A1 (en) 1997-10-30
AU2252797A (en) 1997-11-12

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PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

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Inventor name: TOUVELLE, MICHELE, S.

Inventor name: ALDRIDGE, CLYDE, L.

Inventor name: KAUFMAN, JEFFREY, L.

Inventor name: LASKO, WILLIAM

Inventor name: HALBERT, THOMAS, R.

Inventor name: RILEY, KENNETH, L.

Inventor name: LAPINSKI, MARK, P.

A4 Supplementary search report drawn up and despatched

Effective date: 19991111

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