EP0865534B1 - Multiple zone limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby - Google Patents
Multiple zone limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby Download PDFInfo
- Publication number
- EP0865534B1 EP0865534B1 EP96918490A EP96918490A EP0865534B1 EP 0865534 B1 EP0865534 B1 EP 0865534B1 EP 96918490 A EP96918490 A EP 96918490A EP 96918490 A EP96918490 A EP 96918490A EP 0865534 B1 EP0865534 B1 EP 0865534B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- zone
- embryonic web
- web
- less
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000001035 drying Methods 0.000 title description 40
- 238000007605 air drying Methods 0.000 claims abstract description 22
- 230000002745 absorbent Effects 0.000 claims abstract description 13
- 239000002250 absorbent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 15
- 238000009826 distribution Methods 0.000 claims description 5
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 6
- 230000007704 transition Effects 0.000 description 4
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B13/00—Machines and apparatus for drying fabrics, fibres, yarns, or other materials in long lengths, with progressive movement
- F26B13/10—Arrangements for feeding, heating or supporting materials; Controlling movement, tension or position of materials
- F26B13/101—Supporting materials without tension, e.g. on or between foraminous belts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F5/00—Dryer section of machines for making continuous webs of paper
- D21F5/18—Drying webs by hot air
- D21F5/182—Drying webs by hot air through perforated cylinders
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F5/00—Dryer section of machines for making continuous webs of paper
- D21F5/02—Drying on cylinders
- D21F5/021—Construction of the cylinders
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F5/00—Dryer section of machines for making continuous webs of paper
- D21F5/14—Drying webs by applying vacuum
- D21F5/143—Drying webs by applying vacuum through perforated cylinders
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B13/00—Machines and apparatus for drying fabrics, fibres, yarns, or other materials in long lengths, with progressive movement
- F26B13/10—Arrangements for feeding, heating or supporting materials; Controlling movement, tension or position of materials
- F26B13/14—Rollers, drums, cylinders; Arrangement of drives, supports, bearings, cleaning
- F26B13/16—Rollers, drums, cylinders; Arrangement of drives, supports, bearings, cleaning perforated in combination with hot air blowing or suction devices, e.g. sieve drum dryers
Definitions
- the present invention relates to absorbent embryonic webs which are through air dried, and particularly to cellulosic fibrous structures which are through air dried.
- Absorbent embryonic webs are a staple of everyday life.
- Absorbent embryonic webs include cellulosic fibrous structures, absorbent foams, etc.
- Cellulosic fibrous structures have become a staple of everyday life.
- Cellulosic fibrous structures are found in facial tissues, toilet tissues and paper toweling.
- a wet embryonic web of cellulosic fibers dispersed in a liquid carrier is deposited onto a forming wire.
- the wet embryonic web may be dried by any one of or combinations of several known means, each of which drying means will affect the properties of the resulting cellulosic fibrous structure.
- the drying means and process can influence the softness, caliper, tensile strength, and absorbency of the resulting cellulosic fibrous structure.
- the means and process used to dry the cellulosic fibrous structure affects the rate at which it can be manufactured, without being rate limited by such drying means and process.
- Felt drying belts have long been used to dewater an embryonic cellulosic fibrous structure through capillary flow of the liquid carrier into a permeable felt medium held in contact with the embryonic web.
- dewatering a cellulosic fibrous structure into and by using a felt belt results in overall uniform compression and compaction of the embryonic cellulosic fibrous structure web to be dried.
- Felt belt drying may be assisted by a vacuum, or may be assisted by opposed press rolls.
- the press rolls maximize the mechanical compression of the felt against the cellulosic fibrous structure. Examples of felt belt drying are illustrated in U.S. Patent 4,329,201 issued May 11, 1982 to Bolton and U.S. Patent 4,888,096 issued December 19, 1989 to Cowan et al.
- Drying cellulosic fibrous structures through vacuum dewatering, without the aid of felt belts is known in the art.
- Vacuum dewatering of the cellulosic fibrous structure mechanically removes moisture from the cellulosic fibrous structure while the moisture is in the liquid form. Furthermore, the vacuum deflects discrete regions of the cellulosic fibrous structure into the deflection conduits of the drying belts and strongly contributes to having different amounts of moisture in the various regions of the cellulosic fibrous structure.
- drying a cellulosic fibrous structure through a vacuum assisted capillary flow, using a porous cylinder having preferential pore sizes is known in the art as well. Examples of such vacuum driven drying techniques are illustrated in commonly assigned U.S. Patent 4,556,450 issued December 3, 1985 to Chuang et al. and U.S. Patent 4,973,385 issued November 27, 1990 to Jean et al.
- the air permeable belt may be made with a high open area (at least forty percent).
- the belt may be made to have reduced air permeability. Reduced air permeability may be accomplished by applying a resinous mixture to obturate the interstices between woven yarns in the belt.
- the drying belt may be impregnated with metallic particles to increase its thermal conductivity and reduce its emissivity or, alternatively, the drying belt may be constructed from a photosensitive resin comprising a continuous network.
- the drying belt may be specially adapted for high temperature airflows, of up to about 815 degrees C. (1500 degrees F). Examples of such through-air drying technology are found in U.S.
- Patent Re. 28,459 reissued July 1, 1975 to Cole et al.; U.S. Patent 4,172,910 issued October 30, 1979 to Rotar; U.S. Patent 4,251,928 issued February 24, 1981 to Rotar et al.; commonly assigned U.S. Patent 4,528,239 issued July 9, 1985 to Trokhan; and U.S. Patent 4,921,750 issued May 1, 1990 to Todd.
- a first region of the cellulosic fibrous structure having a lesser absolute moisture, density or basis weight than a second region, will typically have relatively greater airflow therethrough than the second region. This relatively greater airflow occurs because the first region of lesser absolute moisture, density or basis weight presents a proportionately lesser flow resistance to the air passing through such region.
- the production rate of the cellulosic fibrous structure must be slowed, to compensate for the greater moisture in the high density or high basis weight region.
- the Yankee hood air temperature must be decreased and the residence time of the cellulosic fibrous structure in the Yankee hood must be increased, slowing the production rate.
- the limiting orifice through-air-drying apparatus of the Ensign et al. patent teaches having one or more zones with either a subatmospheric pressure or a positive pressure to promote airflow in either direction.
- this patent (8:17-26) also teaches that as the basis weight of the embryonic web increased, greater residence time on the micropore medium would be necessary, as logic would dictate. Specifically, it taught a common tissue paper basis weight 20 g/m 2 (12 pounds per 3,000 square feet) would require a residence time of at least about 250 milliseconds on the micropore medium.
- Applicants have unexpectedly found that the necessary residence time in the first zone can be reduced, providing the limiting orifice through-air drying apparatus is divided into plural zones. Furthermore, it has unexpectedly been found that the overall energy consumption of the apparatus can be reduced utilizing proper zones. Specifically, less fan horsepower (or kW) is required if the zones are properly sized and selected. Fan horsepower (or kW) reductions of up to 10 to 15 percent over the original apparatus disclosed in the aforementioned Ensign et al. patent can be by utilizing the present invention. At an advertised annual operating cost of $200 to $250 per horsepower per year the potential savings can be significant.
- an object of this invention to provide a limiting orifice through-air drying apparatus having a micropore medium which can be used in conjunction with through-air drying to produce cellulosic fibrous structures. It is, furthermore, an object of this invention to provide a limiting orifice through-air drying apparatus which reduces the necessary residence time and requires less energy than had previously been thought in the prior art.
- the invention comprises a limiting orifice through-air-drying apparatus in combination with an absorbent embryonic web having moisture distributed therein.
- the embryonic web may comprise a cellulosic fibrous structure.
- the embryonic web may have a consistency of at least 18 percent.
- the apparatus comprises a limiting orifice for airflow through the embryonic web.
- the apparatus further comprises a plurality of distinct zones, in order, at least a first zone and a second zone. The zones have mutually different differential pressures relative to the atmospheric pressure.
- the first zone is maintained at a pressure less than the breakthrough pressure of the apparatus.
- the apparatus has a water removal rate in the second zone of at least 5 kg of water per kg (5 pounds of water per pound) of embryonic web per second.
- the apparatus has a water removal rate in the second zone at least 0.10 times as great as the water removal rate in the first zone, while the water removal rate in the second zone is at least 5 kg per kg (5 pounds of water per pound) of embryonic web per second.
- the apparatus has a residence time in the first zone of less than about 35 milliseconds.
- Another aspect of the present invention is a process for limiting orifice through-air drying a cellulosic fibrous structure, said process comprising the steps of:
- Figure 1 is a schematic side elevational view of a micropore medium according to the present invention embodied on a pervious cylinder and having a subatmospheric internal pressure.
- Figure 2 is a graphical representation of relationship between consistency and residence time on an apparatus according to the present invention.
- Figure 3 is a graphical representation of energy consumption and water removal as a function of time for the present invention (CC), a prior art micropore medium drying apparatus (BB) and a prior art apparatus made according to commonly assigned U.S. Patent 4,556,450 issued December 3, 1985 to Chuang et al. (AA).
- the present invention comprises a limiting orifice though-air-drying apparatus 20 in conjunction with a micropore medium 30.
- the apparatus 20 and medium 30 may be made according to the aforementioned U.S. Patent 5,274,930, the disclosure of which is incorporated herein by reference.
- the apparatus 20 comprises a pervious cylinder 32 and the micropore medium 30 circumscribing such a pervious cylinder 32.
- This circular segment 40 may be subdivided into multiple zones 41, 42 having mutually different differential pressures relative to the atmospheric pressure.
- the apparatus 20 may comprise a partitioned vacuum slot or an endless belt . The apparatus 20 removes moisture from an embryonic web.
- the limiting orifice through-air-drying apparatus 20 may particularly be divided into a plurality of zones.
- a preferred apparatus 20 has two zones, a first zone 41 and a second zone 42.
- the embryonic web encounters, in order, the first zone 41, then the second zone 42, then subsequent zone(s), if any.
- the first zone 41 is maintained at a pressure less than the breakthrough pressure of the apparatus 20.
- the second zone 42 is maintained at a pressure greater than the breakthrough pressure of the apparatus 20.
- the breakthrough pressure is found according to the Society of Automotive Engineers' Aerospace Recommended Practice 901 issued March 1, 1968, and entitled Bubble Point Test Method, and modified to use a 50 millimeter immersion depth, and which Practice is incorporated herein by reference.
- first and second zones 41, 42 may subtend an arc from about 180 to 270 degrees, more preferably 210 to 240 degrees.
- the first zone 41 may comprise up to 60 degrees of the total arc subtended by the first and second zones 41, 42 and more preferably 20 to 30 degrees.
- the support member 28 transports the absorbent embryonic web relative to the apparatus 20 and across the zones 41, 42 at a rate providing the embryonic web a residence time in the first zone 41 of less than 35 milliseconds, preferably less than 25 milliseconds, more preferably less than 15 milliseconds.
- the residence time in the second zone 42 should be at least 125 and preferably at least 175 milliseconds.
- an "absorbent embryonic web” comprises a cellulosic fibrous structure, or any other web which is deposited wet and must have the water removed to be in a dry state to be functional.
- a web is considered “absorbent” if it can hold and retain water, or remove water from a surface.
- “cellulosic fibrous structures” refer to structures, such as paper, comprising at least fifty percent cellulosic fibers, and a balance of synthetic fibers, organic fillers, inorganic fillers, foams etc. Suitable cellulosic fibrous structures for use with the present invention can be found in commonly assigned U.S. Patent 5,245,025 issued September 14, 1993 to Trokhan et al., which patent is incorporated herein by reference.
- the apparatus 20 has a water removal rate in the second zone 42 of at least 5, and preferably at least 7 kg of water per kg (pounds of water per pound) of embryonic web per second.
- the proper transition point between the first and second zones 41, 42 is that point at which the water removal rate of the second zone 42 exceeds the water removal rate of the first zone 41.
- the actual transition point is where the differential pressure through the apparatus 20, relative to atmospheric, goes from less than the breakthrough pressure to greater than the breakthrough pressure.
- the system is optimized when the actual and the proper transition points are coincident. It is recognized that the exact transition point will depend upon the porosity and drainage capabilities of the absorbent embryonic web, the flow characteristics and size of the orifices in the micropore medium, and perhaps other factors as well.
- the second zone 42 may be partitioned into one or more subzones, each having a dedicated fan or may be maintained without a partition and have a single large fan as desired.
- a single zone 41 or 42 may have its differential pressure generated by two or more fans.
- the fans may be arranged in series or in parallel. It is generally believed that the horsepower requirements of two smaller fans or one larger fan, having the same total horsepower (or kW), are very similar as used in conjunction with the present invention.
- the first zone 41 Since the first zone 41 is run at less than breakthrough pressure, it does not require a fan and may work well with a vacuum pump. Thus, the first zone 41 consumes only minimal energy in the apparatus 20 according to the claimed invention.
- the unit horsepower (or kW) refers only to the horsepower (or kW) necessary to create the differential pressure in the apparatus 20, and does not include horsepower (or kW) necessary to transport the embryonic web relative to the apparatus 20.
- the ratio of the drying rate of the second zone 42 to the drying rate of the first zone 41 is at least 0.10 times as great, and preferably at least 0.12 times as great. Of course this ratio can be artificially inflated by running an inefficient first zone 41.
- the first zone has a water removal rate of at least 40 kg of water per kg (pounds of water per pound) of embryonic web per second. There is minimal horsepower (or kW) involved in the water removal rate of the first zone 41, since the first zone 41 relies upon capillary dewatering which occurs below the breakthrough pressure, and does not rely upon a fan to create airflow above the breakthrough pressure.
- Pulp filtration resistance is measured according to the procedure set forth in commonly assigned U.S. Patent 5,228,954 issued July 20, 1993 to Vinson et al.
- the optimum residence time on the apparatus 20 is directly proportional to the pulp filtration resistance.
- the incoming embryonic web has a consistency of at least 18 percent, and possibly at least 19 percent.
- the apparatus 20 according to the present invention has a greater water removal capability for a given PFR than is obtainable with prior art porous cylinders which dry the web by capillary attraction and are maintained at less than breakthrough, as illustrated in commonly assigned U.S. Patent 4,556,450 issued December 3, 1985 to Chuang et al., prior art woven support members 28, and prior art photosensitive resin support members 28.
- the water removal rate is ascertained by measuring the consistencies of the embryonic web before and after the zone 41, 42 in question using gravimetric weighing and convective drying to achieve a bone-dry baseline.
- the residence time can be easily calculated knowing the path length of the zone 41, 42 and the velocity of the embryonic web.
- the apparatus 20 according to the present invention has a water removal rate of at least 5 kg of water per kg (pounds of water per pound) of embryonic web per second, and more preferably at least 7 kg of water per kg (pounds of water per pound) of embryonic web per second in the second zone 42 .
- the apparatus 20 according to the present invention has a water removal rate of at least 40 kg of water per kg (pounds of water per pound) of embryonic web per second, and more preferably at least 50 kg of water per kg (pounds of water per pound) of embryonic web per second in the first zone 41.
- the apparatus 20 according to the present invention has a power consumption of less than 39.6, and preferably less than 31.7 kW/m 2 (less than 5, and preferably less than 4 horsepower per square foot) of web area subjected to the process in the first zone 41.
- the apparatus 20 according to the present invention has a power consumption of less than 158.3, preferably less than 142.5, and more preferably less than 126.7, kW/m 2 (less than 20, preferably less than 18, and more preferably less than 16 horsepower per square foot) of web area subjected to the process in the second zone 41.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Paper (AREA)
- Drying Of Solid Materials (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US484734 | 1995-06-07 | ||
US486874 | 1995-06-07 | ||
US08/475,284 US5584128A (en) | 1995-06-07 | 1995-06-07 | Multiple zone limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby |
US08/486,874 US5581906A (en) | 1995-06-07 | 1995-06-07 | Multiple zone limiting orifice drying of cellulosic fibrous structures apparatus therefor, and cellulosic fibrous structures produced thereby |
US08/484,734 US5539996A (en) | 1995-06-07 | 1995-06-07 | Multiple zone limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby |
US475284 | 1995-06-07 | ||
PCT/US1996/010303 WO1996041053A1 (en) | 1995-06-07 | 1996-06-03 | Multiple zone limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0865534A1 EP0865534A1 (en) | 1998-09-23 |
EP0865534B1 true EP0865534B1 (en) | 2000-11-02 |
Family
ID=27413317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96918490A Expired - Lifetime EP0865534B1 (en) | 1995-06-07 | 1996-06-03 | Multiple zone limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby |
Country Status (17)
Country | Link |
---|---|
EP (1) | EP0865534B1 (ko) |
JP (1) | JPH11507417A (ko) |
KR (1) | KR100291880B1 (ko) |
CN (1) | CN1101872C (ko) |
AT (1) | ATE197330T1 (ko) |
AU (1) | AU721236B2 (ko) |
BR (1) | BR9609010A (ko) |
CA (1) | CA2223773C (ko) |
CZ (1) | CZ9703964A3 (ko) |
DE (1) | DE69610855T2 (ko) |
ES (1) | ES2151169T3 (ko) |
HU (1) | HUP9901098A3 (ko) |
MX (1) | MX9709814A (ko) |
NO (1) | NO975658L (ko) |
NZ (1) | NZ310350A (ko) |
TR (1) | TR199701564T1 (ko) |
WO (1) | WO1996041053A1 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1785523A3 (en) * | 2001-08-14 | 2007-05-30 | The Procter and Gamble Company | Through-air drying apparatus having decreasing wet flow resistance in the machine direction and process of drying a web therewith |
DE102011113837A1 (de) * | 2011-09-21 | 2013-03-21 | Trützschler Nonwovens Gmbh | Heizsystem zum Erwärmen eines gasförmigen Behandlungsmediums für einen Trockner |
CN103954110A (zh) * | 2014-03-28 | 2014-07-30 | 吴江龙升纺织有限公司 | 纺织品穿透式烘干装置 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1334777A (fr) * | 1961-10-02 | 1963-08-09 | Fleissner Gmbh | Procédé et dispositif pour le traitement de matières mouillées ou humides, notamment en vue de leur séchage |
US3265559A (en) * | 1965-05-03 | 1966-08-09 | Time Inc | Paper press section |
USRE28459E (en) * | 1966-06-07 | 1975-07-01 | Transpiration drying and embossing of wet paper webs | |
US4074441A (en) * | 1976-03-08 | 1978-02-21 | Frederick D. Helversen | Rotary through dryer having multiple vacuum chambers and associated heaters |
DE3141460A1 (de) * | 1981-10-19 | 1983-05-05 | Brückner-Apparatebau GmbH, 6120 Erbach | Siebtrommel |
US4556450A (en) * | 1982-12-30 | 1985-12-03 | The Procter & Gamble Company | Method of and apparatus for removing liquid for webs of porous material |
US5274930A (en) * | 1992-06-30 | 1994-01-04 | The Procter & Gamble Company | Limiting orifice drying of cellulosic fibrous structures, apparatus therefor, and cellulosic fibrous structures produced thereby |
-
1996
- 1996-06-03 AU AU61134/96A patent/AU721236B2/en not_active Ceased
- 1996-06-03 JP JP9502276A patent/JPH11507417A/ja not_active Withdrawn
- 1996-06-03 CA CA002223773A patent/CA2223773C/en not_active Expired - Fee Related
- 1996-06-03 HU HU9901098A patent/HUP9901098A3/hu unknown
- 1996-06-03 NZ NZ310350A patent/NZ310350A/xx unknown
- 1996-06-03 BR BR9609010A patent/BR9609010A/pt not_active IP Right Cessation
- 1996-06-03 EP EP96918490A patent/EP0865534B1/en not_active Expired - Lifetime
- 1996-06-03 WO PCT/US1996/010303 patent/WO1996041053A1/en not_active Application Discontinuation
- 1996-06-03 KR KR1019970709086A patent/KR100291880B1/ko not_active IP Right Cessation
- 1996-06-03 TR TR97/01564T patent/TR199701564T1/xx unknown
- 1996-06-03 AT AT96918490T patent/ATE197330T1/de not_active IP Right Cessation
- 1996-06-03 CZ CZ19973964A patent/CZ9703964A3/cs unknown
- 1996-06-03 ES ES96918490T patent/ES2151169T3/es not_active Expired - Lifetime
- 1996-06-03 DE DE69610855T patent/DE69610855T2/de not_active Expired - Lifetime
- 1996-06-03 CN CN96195746A patent/CN1101872C/zh not_active Expired - Fee Related
-
1997
- 1997-12-05 NO NO975658A patent/NO975658L/no not_active Application Discontinuation
- 1997-12-05 MX MX9709814A patent/MX9709814A/es active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
NZ310350A (en) | 2000-03-27 |
BR9609010A (pt) | 1999-06-29 |
ATE197330T1 (de) | 2000-11-15 |
NO975658D0 (no) | 1997-12-05 |
TR199701564T1 (xx) | 1998-03-21 |
DE69610855T2 (de) | 2001-05-10 |
NO975658L (no) | 1998-02-09 |
KR19990022605A (ko) | 1999-03-25 |
AU721236B2 (en) | 2000-06-29 |
CA2223773C (en) | 2001-10-16 |
KR100291880B1 (ko) | 2001-06-01 |
MX9709814A (es) | 1998-08-30 |
EP0865534A1 (en) | 1998-09-23 |
CN1101872C (zh) | 2003-02-19 |
DE69610855D1 (de) | 2000-12-07 |
JPH11507417A (ja) | 1999-06-29 |
AU6113496A (en) | 1996-12-30 |
CA2223773A1 (en) | 1996-12-19 |
CZ9703964A3 (cs) | 2001-11-14 |
HUP9901098A2 (hu) | 1999-07-28 |
ES2151169T3 (es) | 2000-12-16 |
HUP9901098A3 (en) | 1999-11-29 |
CN1192255A (zh) | 1998-09-02 |
WO1996041053A1 (en) | 1996-12-19 |
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