EP0855440A1

EP0855440A1 - Antibacterial liquid dishwashing detergent compositions

Info

Publication number: EP0855440A1
Application number: EP97870119A
Authority: EP
Inventors: Michael Jakob Reynen; Nikipad Aryana
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 1997-01-24
Filing date: 1997-08-14
Publication date: 1998-07-29
Also published as: EP0971995A4; JP2002511110A; WO1998032821A1; IL130956A0; CN1255156A; AR011430A1; PL336995A1; BR9807005A; AU5917198A; KR20000070247A; TR199901727T2; EP0971995A1

Abstract

Liquid dishwashing compositions are disclosed, which have antibacterial properties. The compositions comprise a surfactant or hydrotrope from selected classes and an unsaturated aliphatic terpene alcohol or derivative.

Description

Technical Field

The invention relates to liquid dishwashing detergent compositions. The compositions have antibacterial properties.

Background

Liquid dishwashing compositions are much desired by consumers and can be used neat or diluted. In diluted mode, a composition is diluted in water to form a wash liquor in which the dishes to be cleaned are immersed. In neat mode, a composition is directly applied neat onto dishes, and in this mode a dish implement is often use. Specifically, the composition is applied onto the implement, usually a sponge or a dishcloth, which is in turn contacted with the dishes to be cleaned.

A problem arises that dish implements are left humid most of the time, and so they provide a good medium for bacterial growth. The contaminated implement which is used to clean dishes will in turn contaminate those dishes.

We have now found that certain dishwashing compositions can fulfill the further purpose of reducing or eliminating bacterial growth on dish implements.

Summary of the Invention

The compositions of the present invention are liquid dishwashing compositions comprising :

a surfactant,
a hydrotrope selected from the group consisting of salts of cumene sulfonate, toluene sulfonate, xylene sulfonate, benzene sulfonate or mixtures thereof; and
an unsaturated aliphatic terpene alcohol or derivative.

The invention further encompasses a method of washing dishes with these compositions. Without wishing to be bound by theory, it is believed that the anti bacterial efficacy of said formulations is mainly driven by a synergy between the hydrotrope(s) and the unsaturated aliphatic terpene alcohol(s) or derivative.

Detailed Description of the Invention

The compositions of the invention are aqueous liquid compositions. They typically comprise from 30% to 90% by weight of the total composition of water, preferably 40% to 85%.

The compositions herein are liquid and so they typically have a viscosity of from 5 cps to 2000 cps, preferably 5 cps to 400 cps, most preferably 5 cps to 350 cops, measured with a Brookfield Viscometer, with a No. 18 spindle, at 20°C.

Surfactants

The compositions of the present invention comprise, as an essential ingredient, one or several of the following surfactants. Suitable for use herein are amine oxides according to the formula :

wherein R₂ represents a straight or branched alkyl or alkenyl group having 10 to 16 carbon atoms, and R₃ and R₄ represent a C₁ to C₄ hydrocarbon chain, preferably a methyl group or an ethyl group. Generally, when the number of carbon atoms in R₂ is less than 10, the detergency of the composition is lowered, while if it exceeds 16, the stability of the composition at low temperatures deteriorates.

Also suitable for use herein are alkyl alkoxylated sulfates of the formula R₁O(A)_nSO₃M, wherein R₁ is an alkyl or alkenyl group having 9 to 15 carbon atoms, A is an alkoxy group, preferably ethoxy or propoxy, most preferably ethoxy, n represents 0.5 to 7 of real number in average, and M is an alkalimetal, alkali earth metal, ammonium or alkanolammonium group.

The use of alkyl alkoxylated sulfates with lower values for n, on an equal weight basis, typically when n is below 1.0, improves the performance of the composition on grease removal and sudsing due to the corresponding increase in moles of anionic but results in an increase in the total amount of unalkoxylated alkyl sulphate, and this seems to make the low temperature instability issue more acute. If different alkyl alkoxylated sulfates are used which have different n values, the resulting average n value of the alkyl alkoxylated sulfate in the composition will be the weighted molar average n value of the individual n values of the different alkyl alkoxylated sulfates used in the composition.

If the average n value is less than 0.5, the stimulus to skin increases and this is not desirable. On the other hand, if the average n value is more than 3, the detergency deteriorates.

Concerning R₁, if the average number of carbon atoms in R₁ is less than 9, the detergency is insufficient, while if it is more than 16, the stability at low temperature deteriorates.

Suitable alkyl alkoxylated material for use herein can be straight or branched materials. By branched material, it is meant that R₁ is branched, while the position of the branching, and the length of the branched group is as determined by the position of the CH2-OH functional group in the parent alcohol. The increase in the proportion of branched material can improve the physical stability of the composition at low temperature.

In this respect, it is important that the branched alkyl alkoxylated sulfate material should not represent more than 60%, by weight, of the total alkyl alkoxylated sulfate (branched plus linear), otherwise the sudsing performance of the product deteriorates unacceptably. At the other end of the range, there should be enough branched alkyl alkoxylated sulfate to achieve a suitable low temperature stability. This minimum value depends on the specific needs, and can be evaluated by plotting the stability of a given matrix at the desired temperature, as a function of the proportion of branched material. Generally, branched alkyl alkoxylated sulfates should be present in amounts of up to 60%, preferably from 10% to 55%, most preferably 10% to 50%.

Alkyl alkoxylated sulfates are commercially available with a variety of chain lengths, degrees of alkoxylation and degrees of branching under the trade names Empicol® ESA 70 (AE1S) or Empicol® ESB 70 (AE2S) by Albright & Wilson, with C12/14 carbon chain length distribution which are derived from natural alcohols and are 100% linear, Empimin® KSL68/A - AE1S and Empimin® KSN70/LA - AE3S by Albright & Wilson with C12/13 chain length distribution and about 60% branching, Dobanol® 23 ethoxylated sulphates from Shell with C12/13 chain length distribution and about 18% branching, Lial® 123 ethoxylated sulphates from Condea Augusta with C12/13 chain length distribution and about 60% branching and Isalchem® 123 alkoxylated sulphates with C12/13 chain length distribution and about 95% branching.

Also, suitable alkyl alkoxylated sulfates can be prepared by alkoxylating and sulfating the appropriate alcohols, as described in "Surfactants in Consumer Products" by J.Falbe and "Fatty oxo-alcohols : Relation between their alkyl chain structure and the performance of the derived AE,AS,AES" submitted to the 4th World Surfactants, Barcelona, 3-7 VI 1996 Congress by Condea Augusta. Commercial oxo-alcohols are a mixture of primary alcohols containing several isomers and homologues. Industrial processes allow one to separate these isomers hence resulting in alcohols with linear isomer content ranging from 5-10% to upto 95%. Examples of available alcohols for alkoxylation and sulfation are Lial® alcohols by Condea Augusta (60% branched), Isalchem® alcohols by Condea Augusta (95% branched), Dobanol® alcohols by Shell (18% linear).

Other suitable surfactants for use herein are :

Alkyl benzene sulfonates in which the alkyl group contains from 9 to 15 carbon atoms, preferably 11 to 40 carbon atoms in straight chain or branched chain configuration. An especially preferred linear alkyl benzene sulfonate contains about 12 carbon atoms. U.S. Pat. Nos. 2,220,099 and 2,477,383 describe these surfactants in detail.
Alkyl sulfates obtained by sulfating an alcohol having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. The alkyl sulfates have the formula ROSO₃ ^-M⁺ where R is the C_8-22 alkyl group and M is a mono- and/or divalent cation.
Paraffin sulfonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms, in the alkyl moiety. These surfactants are commercially available as Hostapur SAS from Hoechst Celanese.
Olefin sufonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. U.S. Pat. No. 3,332,880 contains a description of suitable olefin sulfonates.
Alkyl glyceryl ether sulfonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms, in the alkyl moiety.
Fatty acid ester sulfonates of the formula : R₁ - CH(SO₃ ^-M⁺)CO₂R₂ wherein R₁ is straight or branched alkyl from about C₈ to C₁₈, preferably C₁₂ to C₁₆, and R₂ is straight or branched alkyl from about C₁ to C₆, preferably primarily C₁, and M⁺ represents a mono- or divalent cation.
Secondary alcohol sulfates having 6 to 18, preferably 8 to 16 carbon atoms.

Other suitable co-surfactants herein are

Fatty acid amide surfactants having the formula :
wherein R⁶ is an alkyl group containing from 7 to 21, preferably from 9 to 17, carbon atoms and each R⁷ is selected from the group consisting of hydrogen, C₁-C₄ alkyl, C₁-C₄ hydroxyalkyl, and -(C₂H₄O)_xH where x varies from 1 to about 3.
Polyhydroxy fatty acid amide surfactant of the structural formula :
wherein R¹ is H, C₁-C₄ hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl, or a mixture thereof, preferably C₁-C₄ alkyl, more preferably C₁ or C₂ alkyl, most preferably C₁ alkyl (i.e., methyl); and R² is a C₅-C₃₁ hydrocarbyl, preferably straight chain C₇-C₁₉ alkyl or alkenyl, more preferably straight chain C₉-C₁₇ alkyl or alkenyl, most preferably straight chain C₁₁-C₁₇ alkyl or alkenyl, or mixtures thereof; and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z preferably will be derived from a reducing sugar in a reductive amination reaction; more preferably Z is a glycityl. Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, mannose, and xylose. Z preferably will be selected from the group consisting of -CH₂-(CHOH)_n-CH₂OH, -CH(CH₂OH)-(CHOH)_n-1-CH₂OH, -CH₂-(CHOH)₂(CHOR')(CHOH)-CH₂OH, where n is an integer from 3 to 5, inclusive, and R' is H or a cyclic or aliphatic monosaccharide, and alkoxylated derivatives thereof. Most preferred are glycityls wherein n is 4, particularly -CH₂-(CHOH)₄-CH₂OH. In formula (I), R¹ can be, for example, N-methyl, N-ethyl, N-propyl, N-isopropyl, N-butyl, N-2-hydroxy ethyl, or N-2-hydroxy propyl.R²-CO-N< can be, for example, cocamide, stearamide, oleamide, lauramide, myristamide, capricamide, palmitamide, tallowamide, etc.Z can be 1-deoxyglucityl, 2-deoxyfructityl, 1-deoxymaltityl, 1-deoxylactityl, 1-deoxygalactityl, 1-deoxymannityl, 1-deoxymaltotriotityl, etc.
Betaine detergent surfactants having the general formula : R - N⁽⁺⁾(R¹)₂ - R²COO^(-) wherein R is a hydrophobic group selected from the group consisting of alkyl groups containing from 10 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, alkyl aryl and aryl alkyl groups containing a similar number of carbon atoms with a benzene ring being treated as equivalent to about 2 carbon atoms, and similar structures interrupted by amide or ether linkages; each R¹ is an alkyl group containing from 1 to about 3 carbon atoms; and R² is an alkylene group containing from 1 to about 6 carbon atoms.
Ethylene oxide condensates, which can be broadly defined as compounds produced by the condensation of ethylene oxide groups (hydrophilic in nature) with an organic hydrophobic compound, which can be aliphatic or alkyl aromatic in nature. The length of the hydrophilic or polyoxyalkylene radical which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired balance between hydrophilic and hydrophobic elements. Examples of such ethylene oxide condensates suitable as suds stabilizers are the condensation products of aliphatic alcohols with ethylene oxide. The alkyl chain of the aliphatic alcohol can either be straight or branched and generally contains from about 8 to about 18, preferably from about 8 to about 14, carbon atoms for best performance as suds stabilizers, the ethylene oxide being present in amounts of from about 8 moles to about 30, preferably from about 8 to about 14 moles of ethylene oxide per mole of alcohol.
Cationic quaternary ammonium surfactants of the formula : [R¹(OR²)_y][R³(OR²)_y]₂R⁴N⁺X^- or amine surfactants of the formula : [R¹(OR²)_y][R³(OR²)_y]R⁴N wherein R¹ is an alkyl or alkyl benzyl group having from about 6 to about 16 carbon atoms in the alkyl chain; each R² is selected from the group consisting of -CH₂CH₂-, -CH₂CH(CH₃)-, -CH₂CH(CH₂OH)-, -CH₂CH₂CH₂-, and mixtures thereof; each R³ is selected from the group consisting of C₁-C₄ alkyl, C₁-C₄ hydroxyalkyl, benzyl, and hydrogen when y is not 0; R⁴ is the same as R³ or is an alkyl chain wherein the total number of carbon atoms of R¹ plus R⁴ is from about 8 to about 16, each y is from about 0 to about 10, and the sum of the y values is from about 0 to about 15; and X is any compatible anion. The compositions herein typically comprise from 10% to 60% by weight of the total composition of a surfactant, or mixtures thereof, preferably from 10% to 55%, most preferably from 10% to 50%.

Hydrotropes

As a second essential ingredient, the compositions herein comprise a hydrotrope selected from the group consisting of salts of cumene sulfonate, toluene sulfonate, xylene sulfonate, benzene sulfonate or mixtures thereof. Preferred salts are ammonium and sodium salts.

The compositions herein typically comprise from 1% to 15% by weight of the total composition of said hydrotropes, preferably 1% to 10%, most preferably 2% to 6%.

Unsaturated aliphatic terpene alcohol or derivative

As a third essential ingredient, the compositions herein comprise an unsaturated aliphatic terpene alcohol or derivates thereof (i.e unsaturated aliphatic terpene alcohols where the alcohol group is functionalized, e.g. into acetate, formate, propionate, or the like) or mixtures thereof. Suitable such alcohols or derivatives for use herein include geraniol, nerol, citronellol, linalool, citronellyl acetate, geranyl acetate, linalyl acetate, citronellyl formate, geranyl formate, linalyl formate, citronellyl propionate, geranyl propionate and linalyl propionate.

Most preferred for use herein is geraniol.

The compositions herein typically comprise from 0.1% to 3% by weight of the total composition of said unsaturated aliphatic terpene alcohol, preferably 0.2% to 2.5%, most preferably 0.4% to 2%.

Optionals

The compositions herein can comprise a number of other, optional ingredients, as follows :

A first optional, but preferred ingredient is a phenolic compound according to the formula

wherein R, R1, R2, R3, R4 are independently H, a linear or branched, saturated or unsaturated hydrocarbon chain having from 1 to 20 carbon atoms, preferably from 1 to 10, more preferably from 1 to 4, an alkoxylated hydrocarbon chain according to the formula Ra(A)_n wherein Ra is a linear or branched, saturated or unsaturated hydrocarbon chain having from 1 to 20 carbon atoms, preferably from 1 to 10, more preferably from 1 to 4, wherein A is butoxy, propoxy and/or ethoxy, and n is an integer of 1 to 4, preferably from 1 to 3, or an aryl chain having from 1 to 20 carbon atoms, preferably from 1 to 10 and more preferably from 1 to 4, or mixtures thereof. Highly preferred from that class of ingredients are Eugenol and Thymol.

The compositions herein can comprise from 0.1% to 4%, preferably from 0.2% to 1.5% by weight of the total composition of such a phenolic compound or mixtures thereof.

Magnesium ions :

The compositions herein preferably comprise from 0% to 2.0%, preferably 0.1% to 1.5%, most preferably from 0.2% to 1% by weight of the composition, of magnesium ions which may be added to the liquid detergent compositions of the invention for improved product stability, as well as improved sudsing and skin mildness.

It is preferred that the magnesium ions are introduced by neutalization of the acid form of alkylethoxy surfactants with a magnesium oxide or magnesium hydroxide slurry in water. Normally, this method is limited by the amount of anionic surfactants in the composition. An alternative method is to use MgCl2, MgSO4 or other inorganic Mg salts. These materials are less desirable because they can cause corrosivity problems (chloride salts), decrease the solubility of the formulations, or cause formulatibility/stability problems in the compositions. It is desirable for these reasons to iimit the addition of inorganic salts to less than 2%, preferably less than 1% by weight of the anionic inorganic counterion.

Anti-gelling polymer :

As another optional component, the compositions of the invention comprise an anti-gelling polymer which improves the compositions' resistance to gelling. Suitable polymers for use herein have a molecular weight of at least 500, preferably from 500 to 20000, more preferably 1000 to 5000, most preferably 1000 to 3000.

The required amount of anti-gelling polymer can easily be determined by trial and error, but generally, the compositions herein comprise from 0.5% to 6% by weight of the total composition of an anti-gelling polymer, or mixtures thereof, preferably 0.5% to 4%, most preferably 1.5% to 3%.

Suitable polymers for use herein include :

polyalkylene glycols, preferably polyethylene glycol and polypropylene glycol;
polyamines; Particularly suitable polyamine polymer for use herein are alkoxylated or polyalkoxylated polyamines. Such materials can conveniently be represented as molecules of the empirical structures with repeating units :
wherein R is a hydrocarbyl group, usually of 2-6 carbon atoms; R¹ may be a C₁-C₂₀ hydrocarbon; the alkoxy groups are ethoxy, propoxy, and the like, and y is 2-30, most preferably from 10-20; n is an integer of at least 2, preferably from 2-20, most preferably 3-5; and X^- is an anion such as halide or methylsulfate, resulting from the quaternization reaction. The most highly preferred polyamines for use herein are the so-called ethoxylated polyethylene amines, i.e., the polymerized reaction product of ethylene oxide with ethyleneimine, having the general formula :
when y = 2-30. Particularly preferred for use herein is an ethoxylated polyethylene amine, in particular ethoxylated tetraethylenepentamine, and quaternized ethoxylated hexamethylene diamine.
Terephtalate-based polymers; Suitable terephtalate polymers for use herein include polymers having the formula :
wherein each R¹ is a 1,4-phenylene moiety; the R² are essentially 1,2-propylene moieties; the R³ are esssntially the polyoxyethylene moiety - (CH₂H₂O)_q-CH₂-CH₂-; each X is ethyl or preferably methyl; each n is from about 12 to about 45; q is from about 12 to about 90; the average value of u is from about 5 to about 20; the average value of v is from about 1 to about 10; the average value of u+v is from about 6 to about 30; the ratio u to v is from about 1 to about 6.

Hihgly preferred polymers for use herein are polymers of the formula :

in which X can be any suitable capping group, with each X being selected from the group consisting of H, and alkyl or acyl groups containing from 1 to about 4 carbon atoms, preferably 1 to 2 carbon atoms, most preferably alkyl. Furthermore, the alkyl group may contain anionic, cationic or nonionic substituents such as sulphonate, sulphato, ammonium, hydroxy etc. groups. n is selected for water solubility and is a range of values which generally averages from about 10 to about 50, preferably from about 10 to about 25. There should be very little material, preferably less than about 10 mol %, more preferably less than 5 mol %, most preferably less than 1 mol %, in which u is greater than 5. Furthermore there should be at least 20 mol %, preferably at least 40 mol %, of material in which u ranges from 3 to 5.

The R¹ moieties are essentially 1,4-phenylene moieties. As used herein, the term "the R¹ moieties are essentially 1,4-phenylene moieties" refers to compounds where the R¹ moieties consist entirely of 1,4-phenylene moieties, or are partially substituted with other arylene or alkarylene moieties, alkylene moieties, alkenylene moieties, or mixtures thereof. Arylene and alkarylene moieties which can be partially substituted for 1,4-phenylene include 1,3-phenylene, 1,2-phenylene, 1,8-naphthylene, 1,4-naphthylene, 2,2-biphenylene, 4,4'-biphenylene and mixtures thereof. Alkylene and alkenylene moieties which can be partially substituted include ethylene, 1,2-propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexamethylene, 1,7-heptamethylene, 1,8-octamethylene, 1,4-cyclohexylene, and mixtures thereof.

Preferably, the R¹ moieties consist entirely of (i.e., comprise 100%) 1,4-phenylene moieties, i.e. each R¹ moiety is 1,4-phenylene.

For the R² moieties, suitable ethylene or substituted ethylene moieties include ethylene, 1,2-propylene, 1,2-butylene, 1,2-hexylene, 3-methoxy-1,2-propylene and mixtures thereof. Preferably, the R² moieties are essentially ethylene moieties, or, preferably, 1,2-propylene moieties or mixtures thereof. Preferably, from about 75% to about 100%, more preferably from about 90% to about 100% of the R² moieties are 1,2-propylene moieties.

The value for n averages at least about 10, but a distribution of n values is present. The value of each n usually ranges from about 10 to about 50 Preferably, the value for each n averages in the range of from about 10 to about 25.

The most preferred polymers for use herein are polymers according to the formula :

wherein X is methyl, n is 16, R¹ is 1,4-phenylene moiety, R² is 1,2-propylene moiety and u is essentially between 3 and 5.

Solvent :

As another optional component, the compositions of the invention can comprise a solvent in an effective amount so as to reach the desired viscosity.

Suitable solvents for use herein include low molecular weight alcohols such as C₁-C₁₀, preferably C₁-C₄ mono- and dihydric alcohols, preferably ethyl alcohol, isopropyl alcohol, propylene glycol and hexylene glycol.

The compositions herein typically comprise from 3% to 20% by weight of the total composition of an alcohol, or mixtures thereof, preferably 3% to 15%, most preferably 5% to 10%.

Preferably, the compositions herein are formulated as clear liquid compositions. By "clear" it is meant isotropic, stable and transparent. In order to achieve isotropic compositions, the use of solvents and hydrotropes is well known to those familiar with the art of dishwashing formulations. Those clear compositions are preferably packaged in transparent containers, which can typically be made out of plastic or glass.

In addition to the optional ingredients described hereinbefore, the compositions can contain other optional components suitable for use in liquid dishwashing compositions such as perfume, dye, opacifiers, enzymes, builders and chelants and pH buffering means so that the compositions herein generally have a pH of from 5 to 11, preferably 6.0 to 10.0, most preferably 7 to 9 measured at a 10% solution in water.

Method :

In the method aspect of this invention, soiled dishes are contacted with an effective amount, typically from about 0.5 ml. to about 20 ml. (per 25 dishes being treated), preferably from about 3 ml. to about 10 ml., of the detergent composition of the present invention. The actual amount of liquid detergent composition used will be based on the judgement of user, and will typically depend upon factors such as the particular product formulation of the composition, including the concentration of active ingredients in the compositon, the number of soiled dishes to be cleaned, the degree of soiling on the dishes, and the like.

The particular product formulation, in turn, will depend upon a number of factors, such as the intended market (i.e., U.S., Europe, Japan, etc.) for the composition product.

In the method herein, the soiled dishes are preferably immersed into a water bath with or without a liquid dishwashing detergent as described herein. A dish implement, i.e. a device suitable for absorbing a liquid dishwashing detergent such as a sponge or a dishcloth, is placed directly onto or contacted with a separate quantity of undiluted liquid dishwashing composition as described herein for a period of time typically ranging from about 3 to about 10 seconds. The absorbing device, and consequently the undiluted liquid dishwashing composition, is then contacted individually to the surface of each of the soiled dishes to remove said soiling. The absorbing device is typically contacted with each dish surface for a period of time ranging from about 5 to about 30 seconds, although the actual time of application will be dependent upon factors such as the degree of soiling of the dish. The contacting of the absorbing device to the dish surface is preferably accompanied by concurrent scrubbing.

After all the dishes to be cleaned have been cleaned, the dish implement is preferably contacted, e.g. soaked with neat product and left to dry. There is little or no bacterial growth in the dish implements used according to the method herein even over extended usage, and contaminated dish implements (i.e. dish implements contaminated by previous uses with other compositions) also recover after one or several uses in a method according to the present invention.

Examples

The following compositions, which illustrate the invention, are made by mixing together the listed ingredients in the listed proportions.

Example 1		Example 2
Alcoholethoxylate (2.2) sulfate	22	Alcoholethoxylate (2.2) sulfate	22
Amine oxide	3	Amine oxide	3
Nonionic	7	Nonionic	7
Glucose amide	5	Glucose amide	5
Betaine	2	Betaine	2
Mg++	0.5	Mg++	0.5
Ethanol	7	Ethanol	7
Sodium cumene sulfonate	5	Sodium toluene sulfonate	5
Polypropylene glycol (2000)	2.00	Polypropylene glycol (2000)	2.00
Propylene glycol	1.00	Propylene glycol	1.00
Geraniol	0.60	Geraniol	0.25
Water	balance	Thymol	0.25
		Eugenol	0.25
		Water	balance

pH (10% water)	7.8	pH (10% water)	7.8

Example 3		Example 4
Alcoholethoxylate (3.0) sulfate	19	Alcoholethoxylate (3.0) sulfate	11
Alcyl polyglycoside	2	Nonionic	6
Nonionic	13	Amide	2 DEA
Amide	2 DEA	Amine oxide	7
Amine oxide	6	Mg++	0.04
Mg++	0.02	Sodium toluene sulfonate	8.00
Ethanol	3	Geraniol	0.30
Sodium toluene sulfonate	5	Thymol	0.30
Nacitrate	3	Eugenol	0.30
Geraniol	0.60	Water	balance
Water	balance

pH (10% water)	6.4	pH (10% water)	6.8

Example 5		Example 6
Alcoholethoxylate (0.6) sulfate	26	Alcoholethoxylate (0.6) sulfate	26
Amine oxide	2	Amine oxide	2
Betaine	2	Betaine	2
Glucose amide	1.5	Glucose amide	1.5
Nonionic	5	Nonionic	5
Mg++	0.50	Mg++	0.50
Ethanol	7	Ethanol	7
Sodium cumene sulfonate	3	Sodium xylene sulfonate	5
Geraniol	0.60	Geraniol	0.20
Water	balance	Thymol	0.20
		Eugenol	0.20
		Water	balance

pH (10% water)	7.8	pH (10% water)	7.8

Example 7		Example 8
Alcoholethoxylate (2.2) sulfate	27	Sodium parafinesulfate	7
Amine oxide	6	Alcoholethoxylate (2.0) sulfate	22
Nonionic	4	Nonionic	0.50
GS-base	6	Amide	0.3 DEA
Ethanol	6	Betaine	0.50
Calcium xylene sulfonate	4	Ethanol	0.60
Geraniol	0.60	Sodium toluene sulfonate	5
Triclosan	0.25	Water	balance
Water	balance

pH (10% water)	7.80	pH (10% water)	6.30

Example 9		Example 10
Alcoholethoxylate (0.6) sulfate	13	Alcoholethoxylate (0.6) sulfate	13
Amine oxide	0.8	Amine oxide	0.8
Betaine	0.8	Betaine	0.8
Glucose Amide	0.6	Glucose Amide	0.6
Nonionic	2	Nonionic	2
Magnesium	0.2	Magnesium	0.2
SCS -Sodium Cumen Sulfonate	2.5	SCS -Sodium Cumen Sulfonate	2.0
PEG 4000	-	PEG 4000	-
Geraniol	0.6	Geraniol	2.0
BHT	0.02	BHT	0.02
Ethanol	-	Ethanol	-

Viscosity (cps)	280	Viscosity (cps)	380
pH (10% water)	7.0	pH (10% water)	7.8

Example 11
Alcoholethoxylate (0.6) sulfate	13
Amine oxide	0.8
Betaine	0.8
Glucose Amide	0.6
Nonionic	2
Magnesium	0.2
SCS -Sodium Cumen Sulfonate	6.0
PEG 4000	-
Geraniol	0.6
BHT	0.02
Ethanol	-

Viscosity (cps)	5
pH (10% water)	7-7.8

Claims

An aqueous liquid dishwashing composition comprising

a surfactant,

a hydrotropic selected from the group consisting of salts of cumene sulfonate, toluene sulfonate, xylene sulfonate, benzene sulfonate or mixtures thereof; and

an unsaturated aliphatic terpene alcohol or derivative.
A composition according to claim 1 which comprises from 10% to 60% by weight of the total composition of said surfactant, from 1% to 15% by weight of the total composition of said hydrotrope, and from 0.1% to 3% by weight of the total composition of said unsaturated aliphatic terpene alcohol or derivative.
A composition according to claim 2 which comprises from 10% to 55% by weight of the total composition of said surfactant, from 1% to 10% by weight of the total composition of said hydrotrope, and from 0.2% to 2.5% by weight of the total composition of said unsaturated aliphatic terpene alcohol.
A composition according to the preceding claims wherein said salts of cumene sulfonate, toluene sulfonate, xylene sulfonate and benzene sulfonate is the sodium salt.
A composition according to the preceding claims wherein said unsaturated aliphatic terpene alcohol is geraniol.
A composition according to the preceding claims which additionally comprises a phenolic compound of the formula
wherein R, R1, R2, R3, R4 are independently H, a linear or branched, saturated or unsaturated hydrocarbon chain having from 1 to 20 carbon atoms, preferably from 1 to 10, more preferably from 1 to 4, an alkoxylated hydrocarbon chain according to the formula Ra(A)_n wherein Ra is a linear or branched, saturated or unsaturated hydrocarbon chain having from 1 to 20 carbon atoms, preferably from 1 to 10, more preferably from 1 to 4, wherein A is butoxy, propoxy and/or ethoxy, and n is an integer of 1 to 4, preferably from 1 to 3, or an aryl chain having from 1 to 20 carbon atoms, preferably from 1 to 10 and more preferably from 1 to 4, or mixtures thereof.
A composition according to claim 6, wherein said phenolic compound is eugenol or thymol, or mixtures thereof.
A composition according to claims 6 and 7 which comprises from 0.1% to 4% by weight of the total composition of said phenolic compound, or mixtures thereof.
A method of washing dishes, wherein an effective amount of the composition according to claims 1-8 is applied onto a dish implement, and said dish implement is then contacted with dishes to be cleaned.