EP0845294A3 - Catalyst for dimethyl ether, method of producing catalyst and method of producing dimethyl ether - Google Patents

Catalyst for dimethyl ether, method of producing catalyst and method of producing dimethyl ether Download PDF

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Publication number
EP0845294A3
EP0845294A3 EP97107540A EP97107540A EP0845294A3 EP 0845294 A3 EP0845294 A3 EP 0845294A3 EP 97107540 A EP97107540 A EP 97107540A EP 97107540 A EP97107540 A EP 97107540A EP 0845294 A3 EP0845294 A3 EP 0845294A3
Authority
EP
European Patent Office
Prior art keywords
catalyst
dimethyl ether
producing
alumina particles
methanol synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97107540A
Other languages
German (de)
French (fr)
Other versions
EP0845294B1 (en
EP0845294B8 (en
EP0845294A2 (en
Inventor
Tsutomu Int. Prop. Dept. NKK Corp. Shikada
Yotaro Int. Prop. Dept. NKK Corp. Ohno
Takashi Int. Prop. Dept. NKK Corp. Ogawa
Masatsugu Int. Prop. Dept. NKK Corp. Mizuguchi
Masami Int. Prop. Dept. NKK Corp. Ono
Kaoru Fujimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Holdings Inc
Original Assignee
NKK Corp
Nippon Kokan Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP8117243A external-priority patent/JPH09301907A/en
Priority claimed from JP12478096A external-priority patent/JP3421901B2/en
Priority claimed from JP12537096A external-priority patent/JP3865148B2/en
Priority claimed from JP12666996A external-priority patent/JP3421902B2/en
Priority claimed from JP33975896A external-priority patent/JP3341808B2/en
Priority to EP01122577A priority Critical patent/EP1174408B1/en
Application filed by NKK Corp, Nippon Kokan Ltd filed Critical NKK Corp
Publication of EP0845294A2 publication Critical patent/EP0845294A2/en
Publication of EP0845294A3 publication Critical patent/EP0845294A3/en
Publication of EP0845294B1 publication Critical patent/EP0845294B1/en
Publication of EP0845294B8 publication Critical patent/EP0845294B8/en
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A catalyst suitable for producing dimethyl ether comprises alumina particles having an average size of 200 µm or less and a methanol synthesis catalyst layer formed around each of the alumina particles. The methanol synthesis catalyst has a weight ratio of 0.05 to 5 to a weight of the alumina particles. The catalyst is produced by forming a layer comprising a methanol synthesis catalyst around each of alumina particles. The dimethyl ether is produced by the method of foming a slurry by introducing the catalyst into a solvent and introducing a mixed gas comprising carbon monoxide and hydrogen into the slurry.
EP97107540A 1996-05-13 1997-05-07 Catalyst for dimethyl ether, method of producing catalyst and method of producing dimethyl ether Expired - Lifetime EP0845294B8 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP01122577A EP1174408B1 (en) 1996-05-13 1997-05-07 Catalyst for the preparation of dimethyl ether, method of producing catalyst and method of producing dimethyl ether

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
JP117243/96 1996-05-13
JP11724396 1996-05-13
JP8117243A JPH09301907A (en) 1996-05-13 1996-05-13 Dimethyl ether synthesizer
JP124780/96 1996-05-20
JP12478096 1996-05-20
JP12478096A JP3421901B2 (en) 1996-05-20 1996-05-20 Method for producing dimethyl ether
JP125370/96 1996-05-21
JP12537096A JP3865148B2 (en) 1996-05-21 1996-05-21 Reactor for synthesis of dimethyl ether
JP12537096 1996-05-21
JP12666996A JP3421902B2 (en) 1996-05-22 1996-05-22 Method for producing dimethyl ether
JP12666996 1996-05-22
JP126669/96 1996-05-22
JP33975896 1996-12-19
JP339758/96 1996-12-19
JP33975896A JP3341808B2 (en) 1996-12-19 1996-12-19 Catalyst for producing dimethyl ether and method for producing dimethyl ether

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP01122577A Division EP1174408B1 (en) 1996-05-13 1997-05-07 Catalyst for the preparation of dimethyl ether, method of producing catalyst and method of producing dimethyl ether

Publications (4)

Publication Number Publication Date
EP0845294A2 EP0845294A2 (en) 1998-06-03
EP0845294A3 true EP0845294A3 (en) 1998-12-09
EP0845294B1 EP0845294B1 (en) 2003-05-14
EP0845294B8 EP0845294B8 (en) 2003-08-06

Family

ID=27526759

Family Applications (2)

Application Number Title Priority Date Filing Date
EP97107540A Expired - Lifetime EP0845294B8 (en) 1996-05-13 1997-05-07 Catalyst for dimethyl ether, method of producing catalyst and method of producing dimethyl ether
EP01122577A Expired - Lifetime EP1174408B1 (en) 1996-05-13 1997-05-07 Catalyst for the preparation of dimethyl ether, method of producing catalyst and method of producing dimethyl ether

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP01122577A Expired - Lifetime EP1174408B1 (en) 1996-05-13 1997-05-07 Catalyst for the preparation of dimethyl ether, method of producing catalyst and method of producing dimethyl ether

Country Status (5)

Country Link
US (2) US6147125A (en)
EP (2) EP0845294B8 (en)
AU (1) AU701666B2 (en)
DE (2) DE69731496T2 (en)
ID (1) ID17203A (en)

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WO2001037990A1 (en) * 1999-11-03 2001-05-31 Plug Power Inc Thermal regulating catalyst composition
US6458856B1 (en) 2001-11-07 2002-10-01 Air Products And Chemicals, Inc. Separation process for one-step production of dimethyl ether from synthesis gas
US6608114B1 (en) * 2002-03-13 2003-08-19 Air Products And Chemicals, Inc. Process to produce DME
US6693057B1 (en) 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
US6638892B1 (en) * 2002-04-18 2003-10-28 Conocophillips Company Syngas conversion and catalyst system employed therefor
JP3951127B2 (en) * 2003-02-28 2007-08-01 国立大学法人静岡大学 Dimethyl ether steam reforming catalyst and method for producing the same
US8747805B2 (en) * 2004-02-11 2014-06-10 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction using microchannel technology
CN1318138C (en) * 2004-02-18 2007-05-30 中国石油化工股份有限公司 Catalyst used for preparing dimethyl ether directly from synthetic gas
CN1314491C (en) * 2004-09-18 2007-05-09 太原理工大学 Catalyst for sizing bed and its preparation
JP2006241319A (en) * 2005-03-03 2006-09-14 Shimadzu Corp Method and installation for removing co2 in mixture gas such as biogas
US7749376B2 (en) * 2005-08-15 2010-07-06 Sud-Chemie Inc. Process for sulfur adsorption using copper-containing catalyst
US8957259B2 (en) * 2005-09-30 2015-02-17 Battelle Memorial Institute Dimethyl ether production from methanol and/or syngas
US20070212271A1 (en) * 2006-02-17 2007-09-13 Kennedy Paul E Process air desulfurization for syngas production
CN100556538C (en) * 2006-12-14 2009-11-04 太原理工大学 A kind of slurried catalyst and preparation method thereof
CN101274879B (en) * 2007-03-30 2011-08-10 中国石油化工股份有限公司 Fluidizer for producing dimethyl ether by methanol dehydration
EP2028173B1 (en) * 2007-08-23 2011-06-29 Haldor Topsoe A/S Process for the preparation of dimethyl ether
DE102009036203A1 (en) * 2009-08-05 2011-02-17 Süd-Chemie AG Process for the preparation of a fracture-resistant catalyst for the desulfurization of gases
US8835517B2 (en) 2012-05-30 2014-09-16 Cool Planet Energy Systems, Inc. Method for producing dimethyl ether using a separator
CN103949258B (en) * 2014-04-08 2016-08-17 太原理工大学 Methods and applications for slurry bed system synthesis gas catalyst for producing dimethyl ether
CN104492411B (en) * 2014-12-16 2016-06-29 华东师范大学 A kind of ZnO/SiO2-γ-Al2O3Catalyzing hydrolysis Celfume prepares the method for methanol and dimethyl ether
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
WO2019122075A1 (en) * 2017-12-20 2019-06-27 Basf Se Catalyst and process for preparing dimethyl ether
CA3086707A1 (en) * 2017-12-20 2019-06-27 Basf Se Catalyst system and process for preparing dimethyl ether
CN113677655B (en) * 2019-02-22 2024-03-19 英国石油有限公司 Production method of dimethyl ether
WO2020168539A1 (en) * 2019-02-22 2020-08-27 Bp P.L.C. Process
US11045793B1 (en) * 2020-07-24 2021-06-29 Qatar University Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis
CN112264025B (en) * 2020-11-18 2021-10-15 西南化工研究设计院有限公司 Simple, energy-saving and environment-friendly preparation method of methanol synthesis catalyst

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US4098809A (en) * 1972-12-20 1978-07-04 Snamprogetti S.P.A. Process for the production of dimethyl ether
GB2093365A (en) * 1981-02-20 1982-09-02 Mobil Oil Corp Catalyst and method for synthesis of dimethyl ether
US4375424A (en) * 1981-10-21 1983-03-01 Shell Oil Company Catalyst for the preparation of dimethyl ether
EP0324475A1 (en) * 1988-01-14 1989-07-19 Air Products And Chemicals, Inc. One-step process for dimethyl ether synthesis utilizing a liquid phase reactor system
EP0404408A1 (en) * 1989-06-23 1990-12-27 The Standard Oil Company Use of coated catalysts for the hydrogenation of maleic anhydride to tetrahydrofuran and gammabutyrolactone
EP0409086A1 (en) * 1989-07-18 1991-01-23 Air Products And Chemicals, Inc. One-step liquid phase process for dimethyl ether synthesis
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WO1993010069A1 (en) * 1991-11-11 1993-05-27 Nkk Corporation Process for producing dimethyl ether

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US4098809A (en) * 1972-12-20 1978-07-04 Snamprogetti S.P.A. Process for the production of dimethyl ether
GB2093365A (en) * 1981-02-20 1982-09-02 Mobil Oil Corp Catalyst and method for synthesis of dimethyl ether
US4375424A (en) * 1981-10-21 1983-03-01 Shell Oil Company Catalyst for the preparation of dimethyl ether
EP0324475A1 (en) * 1988-01-14 1989-07-19 Air Products And Chemicals, Inc. One-step process for dimethyl ether synthesis utilizing a liquid phase reactor system
JPH029833A (en) * 1988-01-14 1990-01-12 Air Prod And Chem Inc Method for direct synthesis and electric production of dimethyl ether and methonol byproducts from a synthetic gas
EP0404408A1 (en) * 1989-06-23 1990-12-27 The Standard Oil Company Use of coated catalysts for the hydrogenation of maleic anhydride to tetrahydrofuran and gammabutyrolactone
EP0409086A1 (en) * 1989-07-18 1991-01-23 Air Products And Chemicals, Inc. One-step liquid phase process for dimethyl ether synthesis
JPH0352835A (en) * 1989-07-18 1991-03-07 Air Prod And Chem Inc Direct synthesis of dimethyl ether from synthetic gas and extending of stock fuel by means of cycle plant
US5070058A (en) * 1990-01-22 1991-12-03 Texaco, Inc. Method for making a catalyst composition used in the production of lower aliphatic alcohols
EP0483609A1 (en) * 1990-10-24 1992-05-06 Air Products And Chemicals, Inc. Liquid phase process for dimethyl ether synthesis
JPH04264046A (en) * 1990-10-24 1992-09-18 Air Prod And Chem Inc Production of dimethyl ether from synthesis gas
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Also Published As

Publication number Publication date
DE69731496D1 (en) 2004-12-09
DE69731496T2 (en) 2005-10-27
AU2004797A (en) 1997-11-20
DE69721944T8 (en) 2004-09-23
EP1174408B1 (en) 2004-11-03
AU701666B2 (en) 1999-02-04
US6147125A (en) 2000-11-14
EP0845294B1 (en) 2003-05-14
DE69721944D1 (en) 2003-06-18
EP1174408A1 (en) 2002-01-23
EP0845294B8 (en) 2003-08-06
DE69721944T2 (en) 2004-04-01
ID17203A (en) 1997-12-11
US6562306B1 (en) 2003-05-13
EP0845294A2 (en) 1998-06-03

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