CA2184531A1 - Method for producing hydrogen-carbon monoxide mixed gas, and apparatus thereof - Google Patents

Method for producing hydrogen-carbon monoxide mixed gas, and apparatus thereof

Info

Publication number
CA2184531A1
CA2184531A1 CA 2184531 CA2184531A CA2184531A1 CA 2184531 A1 CA2184531 A1 CA 2184531A1 CA 2184531 CA2184531 CA 2184531 CA 2184531 A CA2184531 A CA 2184531A CA 2184531 A1 CA2184531 A1 CA 2184531A1
Authority
CA
Canada
Prior art keywords
natural gas
methyl alcohol
coal
mixture
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2184531
Other languages
French (fr)
Other versions
CA2184531C (en
Inventor
Fumihiko Kiso
Norio Arashi
Atsushi Morihara
Shuntaro Koyama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Publication of CA2184531A1 publication Critical patent/CA2184531A1/en
Application granted granted Critical
Publication of CA2184531C publication Critical patent/CA2184531C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/064—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle in combination with an industrial process, e.g. chemical, metallurgical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/485—Entrained flow gasifiers
    • C10J3/487—Swirling or cyclonic gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643—Conversion of synthesis gas to energy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)

Abstract

A method and apparatus for producing methyl alcohol with high efficiency and low cost involve producing an H2-CO mixture that is used for synthesizing methyl alcohol, using coal, natural gas, steam, and an oxidizing agent, such as oxygen, as raw materials. At least one of the ratios of natural gas/coal, oxygen/coal, and steam/natural gas are controlled to generate the H2-CO mixture in which the ratio of H2/CO is equal to 2, which is suitable for synthesizing the methyl alcohol.
In producing the H2-CO mixture, coal and oxygen are reacted to generate CO, CO2, H2O, H2, and heat, and the heat is utilized to react the natural gas and steam for generating the H2-CO
mixture. In comparison with conventional methods for producing methyl alcohol from natural gas, and by coal gasification, the conversion ratio from the raw material to methyl alcohol can be improved by about 10 - 15 %.
CA 2184531 1995-08-31 1996-08-30 Method for producing hydrogen-carbon monoxide mixed gas, and apparatus thereof Expired - Fee Related CA2184531C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP22299095A JPH0967582A (en) 1995-08-31 1995-08-31 Process and apparatus for preparing hydrogen/carbon monoxide mixed gas
JP7-222990 1995-08-31

Publications (2)

Publication Number Publication Date
CA2184531A1 true CA2184531A1 (en) 1997-03-01
CA2184531C CA2184531C (en) 1999-10-12

Family

ID=16791081

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2184531 Expired - Fee Related CA2184531C (en) 1995-08-31 1996-08-30 Method for producing hydrogen-carbon monoxide mixed gas, and apparatus thereof

Country Status (5)

Country Link
JP (1) JPH0967582A (en)
CN (1) CN1066186C (en)
AU (1) AU694052B2 (en)
CA (1) CA2184531C (en)
DE (1) DE19634857C2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109908616A (en) * 2019-04-24 2019-06-21 中国轻工业西安设计工程有限责任公司 The energy-saving distillation system and its distillating method of carbon monoxide ethyl alcohol
CN115505429A (en) * 2021-06-07 2022-12-23 本田技研工业株式会社 Fuel preparation system

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100358851C (en) * 2004-05-21 2008-01-02 庞玉学 Method for producing methanol synthetic gas with hydrocarbon gas and coal as raw materials
US20080202028A1 (en) * 2005-06-03 2008-08-28 Plasco Energy Group Inc. System For the Conversion of Carbonaceous Fbedstocks to a Gas of a Specified Composition
JP5139714B2 (en) * 2007-04-24 2013-02-06 バブコック日立株式会社 Gasifier and gasifier
JP5144755B2 (en) * 2007-07-13 2013-02-13 ユニバーシティ オブ サザン カリフォルニア Electrolysis of carbon dioxide to carbon monoxide and hydrogen in aqueous media for methanol production
CN102165047B (en) * 2008-09-29 2015-04-22 Gtl汽油有限公司 Combined synthesis gas generator
WO2012118511A1 (en) * 2011-03-03 2012-09-07 Sri International Gasification of a carbonaceous material
US9102882B2 (en) * 2012-09-04 2015-08-11 General Electric Company Gasification system and method
CN104560204B (en) * 2013-10-22 2017-05-17 任相坤 Water coal slurry and natural gas combined gasification furnace with multiple nozzles
CN104560205B (en) * 2013-10-22 2017-05-03 任相坤 Water-coal slurry and natural gas combined gasifier
CN104560213B (en) * 2013-10-22 2017-11-24 任相坤 A kind of water-coal-slurry and natural gas combined vaporizing nozzle
CN103937552B (en) * 2014-03-24 2015-11-18 北京交通大学 A kind of three-section type entrained flow bed coal hydrogenation gasification stove and combined operation system
CN105400548B (en) * 2015-11-20 2018-07-10 新奥科技发展有限公司 A kind of coal hydrogenation gasification method and system
CN111019711B (en) * 2019-12-16 2021-09-14 武汉科技大学 Thermal cracking gasification process for household garbage
CN113072980B (en) * 2021-04-28 2021-12-07 宁夏神耀科技有限责任公司 Downward full waste boiler entrained flow bed gasification equipment of superheated steam and coal chemical system

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4278446A (en) * 1979-05-31 1981-07-14 Avco Everett Research Laboratory, Inc. Very-high-velocity entrained-bed gasification of coal
JPS59176391A (en) * 1983-03-28 1984-10-05 Hitachi Ltd Coal gasifying oven
GB2164951A (en) * 1984-09-26 1986-04-03 Shell Int Research Method and apparatus for producing synthesis gas
IN167311B (en) * 1985-04-16 1990-10-06 Dow Chemical Co
US4903521A (en) * 1988-09-02 1990-02-27 Redicon Corporation Method and apparatus for forming, reforming and curling shells in a single press
JP3404755B2 (en) * 1991-10-31 2003-05-12 芝浦メカトロニクス株式会社 Wire bonding equipment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109908616A (en) * 2019-04-24 2019-06-21 中国轻工业西安设计工程有限责任公司 The energy-saving distillation system and its distillating method of carbon monoxide ethyl alcohol
CN115505429A (en) * 2021-06-07 2022-12-23 本田技研工业株式会社 Fuel preparation system

Also Published As

Publication number Publication date
AU694052B2 (en) 1998-07-09
DE19634857C2 (en) 2002-01-31
CA2184531C (en) 1999-10-12
AU6206496A (en) 1997-03-06
DE19634857A1 (en) 1997-03-06
CN1152021A (en) 1997-06-18
CN1066186C (en) 2001-05-23
JPH0967582A (en) 1997-03-11

Similar Documents

Publication Publication Date Title
CA2184531A1 (en) Method for producing hydrogen-carbon monoxide mixed gas, and apparatus thereof
CA2204776A1 (en) Methanol production process using a high nitrogen content synthesis gas with a hydrogen recycle
AU695795B2 (en) Process for the generation of electrical power
CA2064303A1 (en) Process for converting natural gas to synthesis gas
ATE265390T1 (en) METHOD FOR PRODUCING A HYDROGEN-RICH GAS AND A CARBON DIOXIDE-RICH GAS AT HIGH PRESSURES
US4060397A (en) Two stage partial combustion process for solid carbonaceous fuels
TW335431B (en) Integration of steam reforming unit and cogeneration power plant
Otsuka et al. The production of synthesis gas by the redox of cerium oxide
ATE248766T1 (en) METHOD FOR PRODUCING HYDROGEN AND ELECTRICAL ENERGY BY REFORMING BIOETHANOL
CA2179080A1 (en) Method for Producing Oxygen and Generating Power Using a Solid Electrolyte Membrane Integrated with a Gas Turbine
CA2236192A1 (en) Methods for producing oxidized product and generating power using a solid electrolyte membrane integrated with a gas turbine
CA2163615A1 (en) Gasification process combined with steam methane reforming to produce syngas suitable for methanol production
MXPA02005707A (en) Hydrogen production from carbonaceous material.
GB1519083A (en) Apparatus for reforming combustible into gaseous fuel by rreaction with decomposition product of hydrogen peroxide
CA2043743A1 (en) Process for producing dimethyl carbonate
WO2004078645A8 (en) Method for preparing synthesis gas, method for preparing dimethyl ether using synthesis gas, and furnace for preparing synthesis gas
DE69501882D1 (en) METHOD FOR PRODUCING HYDROGEN AND CARBON OXIDS FROM DIMETHYL ETHER
CA2060108A1 (en) Process for the combined production of organic compounds and power
NZ213732A (en) Production of syngas with increased h 2 /co ratio from normally gaseous hydrocarbons
SE8501006D0 (en) GASING AND / OR REFORMING COLLECTORS
MY115870A (en) Production of metal such as aluminium, magnesium, silicon and the like from metal oxide compounds
ES8602099A1 (en) Carbon gasification
AU778771B2 (en) Cogeneration of methanol and electrical power
WO2001009038A3 (en) Natural gas conversion to hydrocarbons and ammonia
ES530239A0 (en) A PROCEDURE OF CONVERTING SYNTHESIS GAS INTO A GAS QUALITY FINAL PRODUCT FOR METHANE-RICH GAS PIPELINE

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed