EP0839899B1 - Gewebeweichmacherzusammensetzungen - Google Patents

Gewebeweichmacherzusammensetzungen Download PDF

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Publication number
EP0839899B1
EP0839899B1 EP96870134A EP96870134A EP0839899B1 EP 0839899 B1 EP0839899 B1 EP 0839899B1 EP 96870134 A EP96870134 A EP 96870134A EP 96870134 A EP96870134 A EP 96870134A EP 0839899 B1 EP0839899 B1 EP 0839899B1
Authority
EP
European Patent Office
Prior art keywords
weight
composition
oxide
alkyl
moieties
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP96870134A
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English (en)
French (fr)
Other versions
EP0839899A1 (de
Inventor
Raphael Angeline Alfons Ceulemans
Bruno Albert Jean Hubesch
Franciscus Joseph Madeleine De Block
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP96870134A priority Critical patent/EP0839899B1/de
Priority to DE69626985T priority patent/DE69626985T2/de
Priority to AT96870134T priority patent/ATE235544T1/de
Priority to ARP970105034A priority patent/AR010731A1/es
Priority to CA002270383A priority patent/CA2270383C/en
Priority to BR9712716-7A priority patent/BR9712716A/pt
Priority to PCT/US1997/019794 priority patent/WO1998018890A1/en
Publication of EP0839899A1 publication Critical patent/EP0839899A1/de
Application granted granted Critical
Publication of EP0839899B1 publication Critical patent/EP0839899B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds

Claims (11)

  1. Verdünnte Textilweichmacherzusammensetzung, umfassend:
    a) einen kationischen Textilweichmacher in einer Menge von weniger als 10 Gew.%;
    b) eine Fettsäure, und
    c) eine nichtionische Verbindung, gewählt aus der Gruppe, bestehend aus:
    i) Blockcopolymeren von Terephthalat und Ethylenoxid oder Propylenoxid;
    ii) Blockcopolymeren von Propylenoxid und Ethylenoxid, bei denen der Mittelblock Polypropylenoxid ist; und
    iii) Mischungen hiervon.
  2. Zusammensetzung nach Anspruch 1, wobei der kationische Textilweichmacher und die Fettsäure in einem Gewichtsverhältnis von Textilweichmacher zu Fettsäure von 25:1 bis 6,5:1, vorzugsweise 20:1 bis 10:1, vorliegen.
  3. Zusammensetzung nach Anspruch 1 und/oder 2, wobei der kationische Textilweichmacher ein bioabbaubarer Textilweichmacher ist, gewählt aus:
    Figure 00240001
    worin Q gewählt ist aus -O-C(O)-, -C( -O-C(O)-O-, -NR4-C(O)-, -C(O)-NR4-;
    R1 (CH2)n-Q-T2 oder T3 ist;
    R2 (CH2)m-Q-T4 oder T5 oder R3 ist;
    R3 C1-C4-Alkyl oder C1-C4-Hydroxyalkyl oder H ist;
    R4 H oder C1-C4-Alkyl oder C1-C4-Hydroxyalkyl ist:
    T1, T2, T3, T4, T5 unabhängig C11-C22-Alkyl oder -Alkenyl sind;
    n und m ganze Zahlen von 1 bis 4 sind; und
    X- ein Weichmacher verträgliches Anion ist.
  4. Zusammensetzung nach mindestens einem der Ansprüche 1-3, wobei der Textilweichmacher in einer Menge von weniger als 10 Gew.-%, vorzugsweise 1 bis 9 Gew.-%, und weiter vorzugsweise 2 bis 7 Gew.-% der Zusammensetzung vorliegt.
  5. Zusammensetzung nach mindestens einem der Ansprüche 1-4, wobei das Blockcopolymer von Terephthalat und Ethylenoxid oder Propylenoxid die Formel besitzt:
    Figure 00250001
    worin jedes T eine O- oder NH-Bindung, vorzugsweise O-Bindung ist;
    worin jedes X aus der Gruppe gewählt ist, bestehend aus H, Alkyl- oder Acyl-Gruppen mit 1 bis 4 Kohlenstoffatomen;
    worin p mindestens 6 ist und vorzugsweise mindestens 8, n im Bereich von 6 bis 113 liegt, u weniger als 10 ist;
    worin die R14-Einheiten im wesentlichen 1,4-Phenyleneinheiten sind; und
    worin die R15-Einheiten Ethylen- oder substituierte Ethyleneinheiten sind.
  6. Zusammensetzung nach mindestens einem der Ansprüche 1-5, wobei das Blockcopolymer von Terephthalat und Ethylenoxid oder Propylenoxid in einer Menge von 0,005 bis 1 Gew.-%, vorzugsweise 0,01 bis 0,5 Gew.-% der Zusammensetzung vorliegt.
  7. Zusammensetzung nach mindestens einem der Ansprüche 1-6, wobei das Blockcopolymer von Propylenoxid und Ethylenoxid, worin der Mittelblock Polypropylenoxid ist, ein Molekulargewicht von mindestens 4000 besitzt, und wobei das Copolymer 50 bis 30 Gew.-% Poly(ethylenoxid) enthält.
  8. Zusammensetzung nach mindestens einem der Ansprüche 1-7, wobei das Blockcopolymer von Propylenoxid und Ethylenoxid, worin der Mittelblock Polypropylenoxid ist, in einer Menge von 0,005 bis 1 Gew.-%, weiter vorzugsweise 0,01 bis 0,5 Gew.-% der Zusammensetzung vorliegt.
  9. Zusammensetzung nach mindestens einem der Ansprüche 1-8, wobei die Zusammensetzung weiterhin ein Polyethylenglycol umfaßt.
  10. Verfahren zum Behandeln von Textilien, umfassend den Schritt des Kontaktierens der Textilien im Spülzyklus mit einem wässrigen Medium, das eine wie in mindestens einem der Ansprüche 1-9 definierte Zusammensetzung enthält.
  11. Verfahren nach Anspruch 10, wobei das wässrige Medium sich bei einer Temperatur zwischen 2 und 40°C, vorzugsweise zwischen 5 und 25°C befindet.
EP96870134A 1996-10-30 1996-10-30 Gewebeweichmacherzusammensetzungen Expired - Lifetime EP0839899B1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP96870134A EP0839899B1 (de) 1996-10-30 1996-10-30 Gewebeweichmacherzusammensetzungen
DE69626985T DE69626985T2 (de) 1996-10-30 1996-10-30 Gewebeweichmacherzusammensetzungen
AT96870134T ATE235544T1 (de) 1996-10-30 1996-10-30 Gewebeweichmacherzusammensetzungen
ARP970105034A AR010731A1 (es) 1996-10-30 1997-10-29 Composicion suavizante de telas diluida y un metodo para tratar telas con dicha composicion
CA002270383A CA2270383C (en) 1996-10-30 1997-10-30 Fabric softening compositions
BR9712716-7A BR9712716A (pt) 1996-10-30 1997-10-30 Composições amaciantes de tecido
PCT/US1997/019794 WO1998018890A1 (en) 1996-10-30 1997-10-30 Fabric softening compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96870134A EP0839899B1 (de) 1996-10-30 1996-10-30 Gewebeweichmacherzusammensetzungen

Publications (2)

Publication Number Publication Date
EP0839899A1 EP0839899A1 (de) 1998-05-06
EP0839899B1 true EP0839899B1 (de) 2003-03-26

Family

ID=8226172

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96870134A Expired - Lifetime EP0839899B1 (de) 1996-10-30 1996-10-30 Gewebeweichmacherzusammensetzungen

Country Status (7)

Country Link
EP (1) EP0839899B1 (de)
AR (1) AR010731A1 (de)
AT (1) ATE235544T1 (de)
BR (1) BR9712716A (de)
CA (1) CA2270383C (de)
DE (1) DE69626985T2 (de)
WO (1) WO1998018890A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1127940A1 (de) * 2000-02-26 2001-08-29 Ciba Spezialitätenchemie Pfersee GmbH Weichgriffmittel für Textilien auf Cyclodextrinbasis
WO2016209617A1 (en) * 2015-06-23 2016-12-29 Rohm And Haas Company Fabric softener compositions and methods of use
EP3390600B1 (de) * 2015-12-15 2019-05-08 Unilever Plc. Gewebepflegezusammensetzung
US10808206B2 (en) 2017-11-14 2020-10-20 Henkel IP & Holding GmbH Detergent boosters, detergent systems that include a detergent booster, and methods of laundering fabric

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK131432A (de) 1968-12-09
JPS5028515B2 (de) 1971-09-30 1975-09-16
US3954632A (en) 1973-02-16 1976-05-04 The Procter & Gamble Company Softening additive and detergent composition
US3861870A (en) 1973-05-04 1975-01-21 Procter & Gamble Fabric softening compositions containing water-insoluble particulate material and method
US3974076A (en) 1974-01-11 1976-08-10 The Procter & Gamble Company Fabric softener
US4145184A (en) 1975-11-28 1979-03-20 The Procter & Gamble Company Detergent composition containing encapsulated perfume
US4209417A (en) 1976-08-13 1980-06-24 The Procter & Gamble Company Perfumed particles and detergent composition containing same
GB1587122A (en) 1976-10-29 1981-04-01 Procter & Gamble Ltd Fabric conditioning compositions
US4237016A (en) 1977-11-21 1980-12-02 The Procter & Gamble Company Textile conditioning compositions with low content of cationic materials
US4327133A (en) 1977-11-21 1982-04-27 Lever Brothers Company Additives for clothes dryers
DE2966013D1 (en) 1979-01-11 1983-09-01 Procter & Gamble Concentrated fabric softening composition
US4233164A (en) 1979-06-05 1980-11-11 The Proctor & Gamble Company Liquid fabric softener
DK187280A (da) 1980-04-30 1981-10-31 Novo Industri As Ruhedsreducerende middel til et fuldvaskemiddel fuldvaskemiddel og fuldvaskemetode
US4308151A (en) 1980-05-12 1981-12-29 The Procter & Gamble Company Detergent-compatible fabric softening and antistatic compositions
FR2482636A1 (fr) 1980-05-14 1981-11-20 Lesieur Cotelle Et Associes Sa Composition adoucissante concentree pour fibres textiles
US4421792A (en) 1980-06-20 1983-12-20 Lever Brothers Company Additives for clothes dryers
GB2095275B (en) 1981-03-05 1985-08-07 Kao Corp Enzyme detergent composition
US4439335A (en) 1981-11-17 1984-03-27 The Procter & Gamble Company Concentrated fabric softening compositions
US4460485A (en) 1983-07-15 1984-07-17 Lever Brothers Company Polyester fabric conditioning and whitening composition
US4515705A (en) 1983-11-14 1985-05-07 The Procter & Gamble Company Compositions containing odor purified proteolytic enzymes and perfumes
GB8333816D0 (en) 1983-12-20 1984-02-01 Procter & Gamble Fabric softening compositions
US4661269A (en) 1985-03-28 1987-04-28 The Procter & Gamble Company Liquid fabric softener
US4749596A (en) 1985-08-22 1988-06-07 The Procter & Gamble Company Articles and methods for treating fabrics
US4661267A (en) 1985-10-18 1987-04-28 The Procter & Gamble Company Fabric softener composition
GB2188653A (en) 1986-04-02 1987-10-07 Procter & Gamble Biodegradable fabric softeners
US4711730A (en) 1986-04-15 1987-12-08 The Procter & Gamble Company Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents
US4976879A (en) 1987-10-05 1990-12-11 The Procter & Gamble Company Sulfoaroyl end-capped ester oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles
US4877896A (en) 1987-10-05 1989-10-31 The Procter & Gamble Company Sulfoaroyl end-capped ester of oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles
US4818569A (en) 1987-10-05 1989-04-04 The Procter & Gamble Company Articles and methods for treating fabrics in clothes dryer
US5102564A (en) 1989-04-12 1992-04-07 The Procter & Gamble Company Treatment of fabric with perfume/cyclodextrin complexes
GB8905552D0 (en) * 1989-03-10 1989-04-19 Unilever Plc Fabric conditioning
US5094761A (en) * 1989-04-12 1992-03-10 The Procter & Gamble Company Treatment of fabric with perfume/cyclodextrin complexes
US4956447A (en) 1989-05-19 1990-09-11 The Procter & Gamble Company Rinse-added fabric conditioning compositions containing fabric sofening agents and cationic polyester soil release polymers and preferred cationic soil release polymers therefor
CA2082279C (en) 1990-05-09 2007-09-04 Grethe Rasmussen Cellulase preparation comprising an endoglucanase enzyme
US5139687A (en) 1990-05-09 1992-08-18 The Proctor & Gamble Company Non-destructive carriers for cyclodextrin complexes
JPH0759792B2 (ja) 1990-08-22 1995-06-28 花王株式会社 柔軟仕上剤
EP0523956B2 (de) * 1991-07-17 1999-02-03 Unilever Plc Wasserlösliches oder in Wasser dispergierbares Copolymer mit UV-Strahlen absorbierendem Monomer enthaltendes Wäschepflegemittel
PT687291E (pt) * 1993-03-01 2000-09-29 Procter & Gamble Composicoes concentradas e biodegradaveis amaciadoras de texteis a base de amonio quaternario e compostos contendo cadeias de acido gordo insaturado possuindo um valor de iodo intermedio
JP3357453B2 (ja) * 1993-09-10 2002-12-16 花王株式会社 液体柔軟仕上剤組成物並びに新規第４級アンモニウム塩並びに該塩の製造法

Also Published As

Publication number Publication date
WO1998018890A1 (en) 1998-05-07
DE69626985D1 (de) 2003-04-30
BR9712716A (pt) 1999-10-26
CA2270383A1 (en) 1998-05-07
ATE235544T1 (de) 2003-04-15
EP0839899A1 (de) 1998-05-06
AR010731A1 (es) 2000-07-12
CA2270383C (en) 2002-08-20
DE69626985T2 (de) 2004-03-04

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