EP0832964A1 - Compositions de nettoyage liquides stables et épaisses - Google Patents
Compositions de nettoyage liquides stables et épaisses Download PDFInfo
- Publication number
- EP0832964A1 EP0832964A1 EP96870120A EP96870120A EP0832964A1 EP 0832964 A1 EP0832964 A1 EP 0832964A1 EP 96870120 A EP96870120 A EP 96870120A EP 96870120 A EP96870120 A EP 96870120A EP 0832964 A1 EP0832964 A1 EP 0832964A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- sulphonate
- composition
- quaternary ammonium
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 173
- 239000007788 liquid Substances 0.000 title claims abstract description 35
- 238000004140 cleaning Methods 0.000 title abstract description 13
- -1 alkyl sulphonate Chemical compound 0.000 claims abstract description 71
- 239000004094 surface-active agent Substances 0.000 claims abstract description 63
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 40
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 37
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 29
- 239000001301 oxygen Substances 0.000 claims description 29
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- 239000002304 perfume Substances 0.000 claims description 28
- 230000002378 acidificating effect Effects 0.000 claims description 20
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical class S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 150000003863 ammonium salts Chemical class 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 230000008719 thickening Effects 0.000 description 26
- 230000008901 benefit Effects 0.000 description 11
- 239000002738 chelating agent Substances 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 239000002516 radical scavenger Substances 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 4
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 4
- WTEVQBCEXWBHNA-YFHOEESVSA-N neral Chemical compound CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- IRAQOCYXUMOFCW-OSFYFWSMSA-N cedr-8-ene Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(C)=CC2 IRAQOCYXUMOFCW-OSFYFWSMSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- WTEVQBCEXWBHNA-JXMROGBWSA-N citral A Natural products CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 3
- IRAQOCYXUMOFCW-UHFFFAOYSA-N di-epi-alpha-cedrene Natural products C1C23C(C)CCC3C(C)(C)C1C(C)=CC2 IRAQOCYXUMOFCW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 150000002432 hydroperoxides Chemical class 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 150000004965 peroxy acids Chemical class 0.000 description 3
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- DYLPEFGBWGEFBB-OSFYFWSMSA-N (+)-β-cedrene Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(=C)CC2 DYLPEFGBWGEFBB-OSFYFWSMSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 2
- KNENSDLFTGIERH-UHFFFAOYSA-N 2,2,4,4-tetramethyl-3-phenylpentan-3-ol Chemical compound CC(C)(C)C(O)(C(C)(C)C)C1=CC=CC=C1 KNENSDLFTGIERH-UHFFFAOYSA-N 0.000 description 2
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 2
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical group CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 239000005792 Geraniol Substances 0.000 description 2
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 2
- 235000003704 aspartic acid Nutrition 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- 235000000484 citronellol Nutrition 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 2
- 229940113087 geraniol Drugs 0.000 description 2
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 229930007744 linalool Natural products 0.000 description 2
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- GJQIMXVRFNLMTB-UHFFFAOYSA-N nonyl acetate Chemical compound CCCCCCCCCOC(C)=O GJQIMXVRFNLMTB-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- GGHMUJBZYLPWFD-UHFFFAOYSA-N patchoulialcohol Chemical compound C1CC2(C)C3(O)CCC(C)C2CC1C3(C)C GGHMUJBZYLPWFD-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 229930004725 sesquiterpene Natural products 0.000 description 2
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- UWSCPROMPSAQOL-UHFFFAOYSA-N trimethylazanium;sulfate Chemical compound CN(C)C.CN(C)C.OS(O)(=O)=O UWSCPROMPSAQOL-UHFFFAOYSA-N 0.000 description 2
- WJUFSDZVCOTFON-UHFFFAOYSA-N veratraldehyde Chemical compound COC1=CC=C(C=O)C=C1OC WJUFSDZVCOTFON-UHFFFAOYSA-N 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- YOVSPTNQHMDJAG-QLFBSQMISA-N β-eudesmene Chemical compound C1CCC(=C)[C@@H]2C[C@H](C(=C)C)CC[C@]21C YOVSPTNQHMDJAG-QLFBSQMISA-N 0.000 description 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 description 2
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 description 1
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
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- 239000000796 flavoring agent Substances 0.000 description 1
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- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- ONKNPOPIGWHAQC-UHFFFAOYSA-N galaxolide Chemical compound C1OCC(C)C2=C1C=C1C(C)(C)C(C)C(C)(C)C1=C2 ONKNPOPIGWHAQC-UHFFFAOYSA-N 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- OEWKLERKHURFTB-UHFFFAOYSA-M hexadecyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCC[N+](C)(C)C OEWKLERKHURFTB-UHFFFAOYSA-M 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 244000056931 lavandin Species 0.000 description 1
- 235000009606 lavandin Nutrition 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- MBKDYNNUVRNNRF-UHFFFAOYSA-N medronic acid Chemical compound OP(O)(=O)CP(O)(O)=O MBKDYNNUVRNNRF-UHFFFAOYSA-N 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 229940102398 methyl anthranilate Drugs 0.000 description 1
- WYTNTFGZBBTWNR-UHFFFAOYSA-M methyl sulfate;trimethyl(octadecyl)azanium Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)C WYTNTFGZBBTWNR-UHFFFAOYSA-M 0.000 description 1
- VXBSKVAMQMBCCA-UHFFFAOYSA-M methyl sulfate;trimethyl(tetradecyl)azanium Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCC[N+](C)(C)C VXBSKVAMQMBCCA-UHFFFAOYSA-M 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 229940067137 musk ketone Drugs 0.000 description 1
- DUNCVNHORHNONW-UHFFFAOYSA-N myrcenol Chemical compound CC(C)(O)CCCC(=C)C=C DUNCVNHORHNONW-UHFFFAOYSA-N 0.000 description 1
- 229930008383 myrcenol Natural products 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
- HIGQPQRQIQDZMP-FLIBITNWSA-N neryl acetate Chemical compound CC(C)=CCC\C(C)=C/COC(C)=O HIGQPQRQIQDZMP-FLIBITNWSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical group [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical compound OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Definitions
- the present invention relates to liquid self-thickened compositions for cleaning hard surfaces. More particularly, the present invention relates to stable acidic thickened liquid compositions typically comprising a source of active oxygen. These compositions find particular application in the cleaning of inclined hard-surfaces, such as toilet bowls and the like.
- viscosity allows a more controlled handling, e.g., a more accurate dispensing of the product during use, as compared to a thinner product.
- viscosity allows a better action of the product on inclined surfaces, such as toilets, bath tubs and the like, because viscosity prevents the product from running down inclined surfaces, like thinner liquids would.
- viscosity is built up by a so-called self-thickening system as opposed to using a thickener compound for that specific purpose.
- thickeners such as gums or polymers have at least one drawback that they affect the formula cost, while providing only one benefit, which is thickening. They do not participate to the actual cleaning of the surface and therefore represent “inert” materials. Also, some thickeners are detrimental to the physical and/or chemical stability of the products they are formulated in.
- compositions known in the art that have the requisite viscosity characteristics.
- most of the self-thickening surfactant systems known in the art whilst allowing to effectively increase the viscosity of liquid compositions, do have some disadvantages in use. Indeed, thickening surfactants like nonionic surfactants (nonyl phenol ethoxylates) or quaternary ammonium compounds have the disadvantage that they require to be used at high levels to achieve satisfactory viscosity, thus making their use expensive.
- liquid self-thickened compositions especially liquid self-thickened acidic compositions, preferably comprising a source of active oxygen, having improved thickening properties at low total thickening surfactant level.
- thickening surfactants show significant instability when formulated in liquid thickened compositions in the acidic pH range and typically in presence of a source of active oxygen, e.g., hydrogen peroxide, or a source thereof, like monopersulfate. This may also result in a loss of the total amount of active oxygen which would otherwise be available to perform bleaching action on the surface to be cleaned.
- a source of active oxygen e.g., hydrogen peroxide, or a source thereof, like monopersulfate.
- liquid self-thickened compositions especially liquid self-thickened acidic compositions typically comprising a source of active oxygen, which are physically and chemically stable for long storage periods.
- a liquid composition preferably a liquid acidic composition typically comprising a source of active oxygen
- a liquid acidic composition typically comprising a source of active oxygen
- the present invention allows to use low level of total thickening surfactant to achieve a given viscosity.
- a lower level of total thickening surfactants quaternary ammonium surfactants and C12-C18 alkyl and/or C12-C18 alkyl aryl sulphonate
- quaternary ammonium surfactants and C12-C18 alkyl and/or C12-C18 alkyl aryl sulphonate is sufficient in the present invention, as compared to the level of quaternary ammonium surfactant which would otherwise be required to obtain the same thickening effect when used alone, in absence of any C12-C18 alkyl or C12-C18 alkyl aryl sulphonate, or as compared to the total level of quaternary ammonium surfactant and short chain alkyl or aryl sulphonate (e.g., xylene sulphonate) which would be required to obtain the same thickening.
- the liquid thickened compositions according to the present invention exhibit excellent chemical and physical stability.
- the decomposition of said source of active oxygen e.g. persulfate salt
- the decomposition of said source of active oxygen is reduced, as compared to the same compositions but with other surfactant blends, like for instance alkylethoxylated alcohols, instead of said quaternary ammonium surfactant and C12-C18 alkyl/alkyl aryl sulphonate.
- a further advantage of the present invention is that the liquid thickened compositions herein are transluscent, as opposed to clouded, and thus well accepted from a consumer view point. Also, the present invention allows to formulate compositions that are Newtonian. By “Newtonian” it is meant herein a composition which has the same viscosity whichever applied shear stress.
- An additional benefit derived from said compositions is that they are low foaming, both in the sense of the amount of foam initially generated during use, as well as in terms of foam stability. This benefit adds to the ease of rinsing benefit already obtained with the "mechanistic" benefit derived from the viscosity profile of the composition. Yet another benefit of the present invention is that this thickening system leads to excellent spreading and clinging on wet surfaces.
- compositions herein, and especially those acidic compositions typically comprising a source of active oxygen are efficient on various surfaces to clean various soils and stains.
- preferred liquid thickened acidic compositions of the present invention when used to treat hard surfaces, especially toilet bowls, exhibit outstanding soil discoloration, soil solubilization and emulsification properties together with a germicidal action, this when used both in neat or diluted form.
- compositions herein are less sensitive to the presence of perfumes, whereas high levels of perfume are known to have a general tendency to significantly decrease composition viscosity by changing micellar aggregation.
- EP-A-275 043 discloses an acidic cleaner for aluminum surfaces containing a peroxide, acids, a C12-C22 alkyl dimethylamine oxide. Said cleaner has a pH of at most 2.
- EP-A-275 043 discloses cationic surfactants as optional ingredients but no specific compounds of this class of surfactants are mentioned, let alone quaternary ammonium surfactants.
- GB 2071 688 discloses liquid acidic compositions comprising an inorganic acid and as a thickening agent a mixture of an amine or amine oxide with a cationic or nonionic surfactant. No anionic surfactants are disclosed.
- US 3997 453 discloses a fabric softening composition
- a fabric softening composition comprising from 60% to 20% of a cationic quaternary ammonium softener and an anionic sulphonate, the weight ratio of cationic softener to anionic sulphonate being of from 40 to 5.
- EP-A-720642 discloses compositions (having a viscosity of 40 cps to 4000 cps) comprising a viscosity decreasing short chain (C6-C10) surfactant and a viscosity restoring long chain surfactant mixture, i.e., a C12-C16 amine oxide and C12-C14 alkyl sulphate.
- a viscosity decreasing short chain (C6-C10) surfactant i.e., a C12-C16 amine oxide and C12-C14 alkyl sulphate.
- C6-C10 viscosity decreasing short chain
- a viscosity restoring long chain surfactant mixture i.e., a C12-C16 amine oxide and C12-C14 alkyl sulphate.
- no liquid thickened compositions comprising quaternary ammonium surfactants (a) and long chain alkyl/alkyl aryl sulphonates (C12-
- European patent application number 96870001.3 discloses perfumed acidic compositions having a pH below 2, a source of active oxygen, surfactants and a terpene/sesquiterpene perfume.
- Preferred compositions are thickened compositions comprising a quaternary ammonium surfactant and an amine oxide surfactant.
- Other surfactants like anionic alkyl or aryl sulphonates are disclosed therein.
- no thickened liquid compositions comprising quaternary ammonium surfactants (a) and long chain alkyl/alkyl aryl sulphonates (C12-C18) (b) at a weight ratio of (a) to (b) of 10:1 to 25:1 are disclosed.
- EP-A-265 979 discloses acidic thickened aqueous cleaning compositions comprising a disinfecting and/or oxidizing agent, an organic anionic sulphonate selected from the group consisting of xylene sulphonate, cumene sulphonate and toluene sulphonate, and a surfactant selected from the group of (1) quaternary ammonium compounds wherein at least one of the hydrocarbon groups linked to the nitrogen is a linear or branched alkyl group containing at least 12 carbon atoms and of (2) tertiary amine oxides wherein at least one of the hydrocarbon groups linked to the nitrogen is a linear or branched alkyl group containing at least 16 carbon atoms.
- the present invention uses quaternary ammonium surfactants together with long chain alkyl/alkyl aryl sulphonates (C12-C18) as the thickening system.
- RD 30115 discloses thickened cleaning compositions displaying shear thinning behaviour.
- the thickeners comprise a fatty alkyl quaternary ammonium (e.g., hexadecyl trimethyl ammonium chloride) and a low-alkyl substituted arene sulphonate (e.g., sodium xylene sulphonate).
- the following composition is exemplified 1% of C16 trimethyl ammonium chloride, 0.9% of sodium xylene sulphonate, 3% of citric acid and 5% of hydrogen peroxide. No long chain alkyl/alkyl aryl sulphonates (C12-C18) are disclosed.
- EP-A-188 025 discloses aqueous stable thickened low-pH bleaching compositions comprising an inorganic peroxy compound, a strong acid and a thickening surfactant.
- the compositions are said to have a viscosity of 10 to 250 mPa.s.
- the thickening surfactant is selected from (1) amine oxides wherein at least one of the hydrocarbon groups linked to the nitrogen is a linear or branched alkyl group of C6 to C18 carbon atoms, preferably C12 to C18, (2) amines and (3) quaternary ammonium salts wherein at least one of the hydrocarbon groups linked to the nitrogen is a linear or branched alkyl group of C8 to C18 carbon atoms.
- EP-A-188 025 teaches to use as a thickening surfactant one of these thickening surfactants.
- No C12-C18 alkylsulphonates or C12-C18 alkyl aryl sulphonates are disclosed, let alone liquid compositions comprising, as the thickening system, a quaternary ammonium surfactant together with a C12-C18 alkyl and/or C12-C18 alkyl aryl sulphonate at a weight ratio of quaternary ammonium surfactant to C12-C18 alkyl and/or C12-C18 alkyl aryl sulphonate of 10:1 to 25:1.
- the present invention encompasses a liquid thickened composition having a viscosity of more than 250 cps, when measured with a Carri-med rheometer at 50 dyne/cm 2 at 20°C, comprising a C12-C18 alkyl sulphonate or C12-C18 alkyl aryl sulphonate or mixtures thereof, and from 0.01% to 15% by weight of the total composition of a quaternary ammonium surfactant, at a weight ratio of said quaternary ammonium surfactant to said sulphonate of 10:1 to 25:1.
- liquid thickened compositions herein are acidic compositions, and in an even more preferred embodiment of the present invention said acidic compositions further comprise a source of active oxygen.
- the present invention also encompasses a process of treating a hard-surface, especially a toilet bowl, wherein a liquid thickened composition according to the present invention, is applied in its neat or diluted form onto said surface, optionally left to act thereto for an effective period of time and then removed.
- compositions of the present invention comprise as an essential element a thickening system.
- Said thickening system comprises a quaternary ammonium surfactant, or mixtures thereof, together with a C12-C18 alkyl or C12-C18 alkyl aryl sulphonate, or mixtures thereof, at a weight ratio of quaternary ammonium surfactant to sulphonate of 10:1 to 25:1, preferably 11:1 to 20:1, more preferably 12:1 to 17:1 and most preferably 13:1 to 17:1.
- a quaternary ammonium surfactant with a C12-C18 alkyl sulphonate and/or a C12-C18 alkyl aryl sulphonate at a weight ratio of said quaternary ammonium surfactant to said sulphonate of 10:1 to 25:1, in an aqueous medium, a viscosity of more than 250 cps, when measured with a Carri-med rheometer at 50 dyne/cm2 at 20°C, is obtained while exhibiting excellent physical and chemical stability.
- the present invention allows to use low level of total thickening surfactant to achieve a given viscosity.
- the total level of thickening system i.e., of quaternary ammonium surfactant and C12-C18 alkyl sulphonate and/or C12-C18 alkyl aryl sulphonate, to be used in a given liquid composition depends on the thickness desired for said composition, said level being lower than 20%, preferably between 1% and 10%, more preferably between 1% and 6%, and most preferably between 1% and 3.5%.
- compositions of the present invention have a viscosity of more than 250 cps at 20°C, preferably from 260 cps to 1500 cps, more preferably from 280 cps to 900 cps, and most preferably from 300 cps to 500 cps, when measured with a Carri-med rheometer CLS 100® by TA Instruments at 50 dyne/cm2 with a 4 cm diameter cone spindle.
- Suitable quaternary ammonium surfactants to be used according to the present invention are quaternary ammonium surfactants according to the formula R 1 R 2 R 3 R 4 N + X - , wherein R 1 is a saturated or unsaturated, linear or branched alkyl, or aryl group of 1 to 30 carbon atoms, preferably of 10 to 25 carbon atoms, more preferably 12 to 20 carbon atoms and most preferably 14 to 18 carbon atoms, wherein R 2 , R 3 and R 4 are independently substituted or unsubstituted, linear or branched alkyl groups of from 1 to 4 carbon atoms, preferably of from 1 to 3 carbon atoms, and more preferably are methyl groups, and wherein X is selected from the group consisting of chloride, fluoride, methyl sulphate, methyl sulphonate, or hydroxide and the like.
- a source of active oxygen like persulfate is present in the compositions herein
- trimethyl quaternary ammonium surfactants like myristyl trimethylammonium methyl sulphate, cetyl trimethylammonium methyl sulphate and/or tallow trimethylammonium methyl sulphate.
- trimethyl quaternary ammonium surfactants are commercially available from Hoechst, or from Albright & Wilson under the trade name EMPIGEN CM®.
- compositions according to the present invention comprise from 0.01% to 15% by weight of a quaternary ammonium surfactant, or mixtures thereof, preferably of from 0.1% to 10%, more preferably of from 0.5% to 5%.
- Suitable C12-C18 alkyl sulphonates to be used herein include water-soluble salts or acids of the formula RSO 3 M wherein R is a C 12 -C 18 linear or branched, saturated or unsaturated, alkyl group, preferably a C12-C16 alkyl group and more preferably a C14-C16 alkyl group, and M is H or a cation, e.g., an alkali metal cation (e.g., sodium, potassium, lithium), or ammonium or substituted ammonium (e.g., methyl-, dimethyl-, and trimethyl ammonium cations and quaternary ammonium cations, such as tetramethyl-ammonium and dimethyl piperdinium cations and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine, and mixtures thereof, and the like).
- R is a C 12
- Suitable C12-C18 alkyl aryl sulphonates to be used herein include water-soluble salts or acids of the formula RSO 3 M wherein R is an aryl, preferably a benzyl, substituted by a C12-C18 linear or branched saturated or unsaturated alkyl group, preferably a C12-C16 alkyl group and more preferably a C14-C16 alkyl group, and M is H or a cation, e.g., an alkali metal cation (e.g., sodium, potassium, lithium), or ammonium or substituted ammonium (e.g., methyl-, dimethyl-, and trimethyl ammonium cations and quaternary ammonium cations, such as tetramethyl-ammonium and dimethyl piperdinium cations and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine,
- secondary C12-C18 alkyl or C12-C18 alkyl aryl sulphonates are particularly suitable to be used herein.
- secondary C12-C18 alkyl or C12-C18 alkyl aryl sulphonates it is meant herein that in the formula as defined above, the SO3M or aryl-SO3M group is linked to a carbon atom of the alkyl chain being placed between two other carbons of the said alkyl chain (secondary carbon atom).
- C14-C16 alkyl sulphonate is Hostapur ® SAS available from Hoechst.
- An example of commercially available alkyl aryl sulphonate is Lauryl aryl sulphonate from Su.Ma.
- compositions according to the present invention may further comprise a variety of other ingredients including other surfactants of all types to boost the performance over a wider range of soils/encrustations, acids, a source of active oxygen, bleach activators, organic or inorganic alkalis, dyes (like for example ⁇ or ⁇ metal phthalocyanines), optical brighteners, builders, chelants, pigments, enzymes, dye transfer inhibitors, solvents, buffering agents, stabilizers and the like.
- the liquid compositions according to the present invention are preferably aqueous compositions. Therefore, they comprise from 50% to 98% by weight of the total composition of water, preferably from 60% to 95% and more preferably from 70% to 90%.
- One of the achievements of the present invention is that the viscosity build up described hereinafter can be achieved with such a high amount of water, i.e., a small amount of actives.
- liquid thickened compositions of the present invention are liquid thickened acidic compositions.
- compositions of the present invention are typically formulated at a pH between 0 to 7, preferably at a pH between 0 and 6, more preferably at a pH between 0 and 4, and most preferably at a pH between 0 and 2.
- Acidity contributes to formulate compositions according to the present invention which exhibit good limescale removing performance while having also good disinfecting properties.
- the compositions herein further comprise a source of active oxygen
- the acidic pH contributes to the chemical stability of said compositions.
- the compositions of the present invention further comprise organic and/or inorganic acids.
- Particularly suitable organic acids to be used herein are aryl and/or alkyl sulfonate, such as methane sulfonic acid or naphtalene disulfonic acid, citric acid, succinic acid, sulphamic acid, glutaric acid, adipic acid and the like.
- Particularly suitable inorganic acids are sulfuric acid, phosphoric acid, nitric acid and the like.
- compositions herein further comprise a source of active oxygen or mixture thereof.
- the source of active oxygen acts as an oxidizing agent, it increases the ability of the compositions to remove colored stains and organic stains in general, to destroy malodorous molecules and to kill germs.
- Suitable sources of active oxygen are hydrogen peroxide or sources thereof.
- a hydrogen peroxide source refers to any compound which produces perhydroxyl ions when said compound is in contact with water.
- Suitable water-soluble inorganic sources of hydrogen peroxide for use herein include persulfates, percarbonates, perborates, persilicates, dialkylperoxides, diacylperoxides, performed percarboxylic acids, organic and inorganic peroxides and/or hydroperoxides and mixtures thereof.
- Suitable organic peroxides/hydroperoxides include diacyl and dialkyl peroxides/hydroperoxides such as dibenzoyl peroxide, t-butyl hydroperoxide, dilauroyl peroxide, dicumyl peroxide, and mixtures thereof.
- Suitable preformed peroxyacids for use in the compositions according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalic acid, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof.
- Persulfate salts or mixtures thereof are the preferred sources of active oxygen to be used in the compositions according to the present invention.
- Preferred persulfate salt to be used herein is the monopersulfate triple salt.
- monopersulfate salt commercially available is potassium monopersulfate commercialised by Peroxide Chemie GMBH under the trade name Curox®.
- Other persulfate salts such as dipersulfate salts commercially available from Peroxide Chemie GMBH can be used in the compositions according to the present invention.
- Persulfate salts are preferred to be used herein, as they allow when used together with the surfactant system of the present invention comprising a quaternary ammonium surfactant and a C12-C18 alkyl sulphonate and/or a C12-C18 alkyl aryl sulphonate to further increase the viscosity of a composition comprising them. Indeed, it is believed that the (HSO 5 - ) anions coming from the persulfate salt, like monopersulfate salt, strongly interact with the cationic head group of the quaternary ammonium surfactant displacing its own counterion (e.g., methylsulfate).
- compositions according to the present invention may comprise from 0.1% to 30% by weight of the total composition of a source of active oxygen, or mixtures thereof, preferably from 0.1% to 20%, and more preferably from 0.1% to 15%.
- compositions according to the present invention are chemically stable.
- chemically stable it is for example meant herein that a composition comprising a source of active oxygen or mixtures thereof, such as persulfate salt, preferably does not undergo more than 40 % persulfate loss, in six months at room temperature (20°C-25°C).
- Persulfate concentration can be measured by back titration with potassium permanganate of a solution containing ammonium ferrous sulphate. Said stability test method is well-known in the art and is reported, for example, on the technical information sheet of Curox® commercially available from Interox.
- persulfate concentration can also be measured using a chromatography method described in the literature for peracids (F. Di Furia et al., Gas-liquid Chromatography Method for Determination of Peracids, Analyst, Vol 113, May 1988, p 793-795).
- compositions according to the present invention are physically stable.
- physically stable it is meant herein that the compositions of the present invention do not split in two or more phases when exposed in stressed conditions, e.g., at a temperature of 50 °C during 2 weeks.
- compositions as described hereinbefore further comprise a perfume or mixtures thereof. It is well-known that perfumes have a general tendency to significantly decrease the viscosity of compositions in which they are introduced.
- An advantage of the thickened compositions of the present invention, especially the acidic liquid thickened compositions that further comprise a source of active oxygen is, that they are less sensitive to the presence of perfume, even the presence of high levels of perfumes.
- perfume ingredients and compositions suitable to be used herein are the conventional ones known in the art. Suitable perfume compounds and compositions can be found in the art including U.S. Pat. Nos. : 4,145,184, Brain and Cummins, issued March 20, 1979; 4,209,417, Whyte, issued June 24, 1980; 4,515,705, Moeddel, issued May 7, 1985; and 4,152,272, Young, issued May 1, 1979, all of said patents being incorporated herein by reference. In general, the degree of substantivity of a perfume is roughly proportional to the percentages of substantive perfume material used. Relatively substantive perfumes contain at least about 1%, preferably at least about 10%, substantive perfume materials.
- Substantive perfume materials are those odorous compounds that deposit on surfaces via the cleaning process and are detectable by people with normal olfactory acuity. Such materials typically have vapor pressures lower than that of the average perfume material. Also, they typically have molecular weights of about 200 and above, and are detectable at levels below those of the average perfume material.
- Perfume ingredients useful herein, along with their odor character, and their physical and chemical properties, such as boiling point and molecular weight, are given in "Perfume and Flavor Chemicals (Aroma Chemicals),” Steffen Arctander, published by the author, 1969, incorporated herein by reference.
- Examples of the highly volatile, low boiling, perfume ingredients are : anethole, benzaldehyde, benzyl acetate, benzyl alcohol, benzyl formate, iso-bornyl acetate, camphene, ciscitral (neral), citronellal, citronellol, citronellyl acetate, para-cymene, decanal, dihydrolinalool, dihydromyrcenol, dimethyl phenyl carbinol, eucaliptol, cedrol, geranial, geraniol, geranyl acetate, geranyl nitrile, cis-3-hexenyl acetate, hydroxycitronellal, d-limonene, linalool, linalool oxide, linalyl acetate, linalyl propionate, methyl anthranilate, alpha-methyl ionone, methyl nonyl acetal
- lavandin contains as major components : linalool; linalyl acetate; geraniol; and citronellol. Lemon oil and orange terpenes both contain about 95% of d-limonene.
- moderately volatile perfume ingredients are : amyl cinnamic aldehyde, iso-amyl salicylate, beta-caryophyllene, cedrene, cinnamic alcohol, coumarin, dimethyl benzyl carbinyl acetate, ethyl vanillin, eugenol, iso-eugenol, flor acetate, heliotropine, 3-cis-hexenyl salicylate, hexyl salicylate, lilial (para-tertiarybutyl-alpha-methyl hydrocinnamic aldehyde), gamma-methyl ionone, nerolidol, patchouli alcohol, phenyl hexanol, beta-selinene, trichloromethyl phenyl carbinyl acetate, triethyl citrate, vanillin, and veratraldehyde.
- Cedarwood terpenes
- Examples of the less volatile, high boiling, perfume ingredients are : benzophenone, benzyl salicylate, ethylene brassylate, galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-gama-2-benzopyran), hexyl cinnamic aldehyde, lyral (4-(4-hydroxy-4-methyl pentyl)-3-cyclohexene-10-carboxaldehyde), methyl cedrylone, methyl dihydro jasmonate, methyl-beta-naphthyl ketone, musk indanone, musk ketone, musk tibetene, and phenylethyl phenyl acetate.
- compositions according to the present invention comprise up to 3% by weight of the total composition of a perfume or mixtures thereof, preferably of from 0.1% to 2% and more preferably of from 0.2% to 1%.
- compositions of the present invention may further comprise a chelating agent or mixtures thereof.
- a chelating agent Any cheating agents known to those skilled in the art are suitable to be used herein.
- chelating agents include the ones selected from the group consisting of phosphonate chelating agents, amino carboxylate chelating agents, polyfunctionally-substituted aromatic chelating agents, and further cheating agents like glycine, salicylic acid, aspartic acid, glutamic acid, malonic acid, and mixtures thereof.
- Chelating agents when used, are typically present herein in amounts ranging from 0.001% to 5% by weight of the total composition and preferably from 0.05% to 2% by weight.
- Suitable phosphonate chelating agents to be used herein may include ethydronic acid, metaphosphoric acid (HPO3) n , pyrophosphoric acid (H4P2O7), methylidene di phosphonic acid (CH2(H2PO3) 2 ), as well as amino phosphonate compounds, including aminotri(methylene phosphonic acid), amino alkylene poly (alkylene phosphonate), alkali metal ethane 1-hydroxy diphosphonates, nitrilo trimethylene phosphonates, ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene phosphonates.
- amino phosphonate compounds including aminotri(methylene phosphonic acid), amino alkylene poly (alkylene phosphonate), alkali metal ethane 1-hydroxy diphosphonates, nitrilo trimethylene phosphonates, ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene
- the phosphonate compounds may be present either in their acid form or as salts of different cations on some or all of their acid functionalities.
- Preferred phosphonate cheating agents to be used herein are diethylene triamine penta methylene phosphonates. Such phosphonate chelating agents are commercially available from Monsanto under the trade name DEQUEST® .
- Polyfunctionally-substituted aromatic chelating agents may also be useful in the compositions herein. See U.S. patent 3,812,044, issued May 21, 1974, to Connor et al.
- Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1,2-dihydroxy -3,5-disulfobenzene.
- a preferred biodegradable chelating agent for use herein is ethylene diamine N,N'- disuccinic acid, or alkali metal, or alkaline earth, ammonium or substitutes ammonium salts thereof or mixtures thereof.
- Ethylenediamine N,N'- disuccinic acids, especially the (S,S) isomer have been extensively described in US patent 4, 704, 233, November 3, 1987, to Hartman and Perkins.
- Ethylenediamine N,N'-disuccinic acid is, for instance, commercially available under the tradename ssEDDS® from Palmer Research Laboratories.
- Suitable amino carboxylates to be used herein include ethylene diamine tetra acetates, diethylene triamine pentaacetates, diethylene triamine pentaacetate (DTPA),N- hydroxyethylethylenediamine triacetates, nitrilotri-acetates, ethylenediamine tetrapropionates, triethylenetetraaminehexa-acetates, ethanoldiglycines, propylene diamine tetracetic acid (PDTA) and methyl glycine diacetic acid (MGDA), both in their acid form, or in their alkali metal, ammonium, and substituted ammonium salt forms.
- PDTA propylene diamine tetracetic acid
- MGDA methyl glycine diacetic acid
- Particularly suitable amino carboxylates to be used herein are diethylene triamine penta acetic acid, propylene diamine tetracetic acid (PDTA) which is, for instance, commercially available from BASF under the trade name Trilon FS® and methyl glycine di-acetic acid (MGDA).
- PDTA propylene diamine tetracetic acid
- MGDA methyl glycine di-acetic acid
- Particularly preferred chelating agents to be used herein are diethylene triamine methylene phosphonate, ethylene N,N'-disuccinic acid, diethylene triamine pantaacetate, aminotri(methylene phosphonic acid), glycine, salicylic acid, aspartic acid, glutamic acid, malonic acid or mixtures thereof.
- compositions of the present invention may further comprise a radical scavenger or mixtures thereof.
- a radical scavenger Any radical scavengers known to those skilled in the art are suitable to be used herein.
- Suitable radical scavengers for use herein include the well-known substituted mono and dihydroxy benzenes and their analogs, alkyl and aryl carboxylates and mixtures thereof.
- radical scavengers for use herein include di-tert-butyl hydroxy toluene (BHT), hydroquinone, di-tert-butyl hydroquinone, mono-tert-butyl hydroquinone, tert-butyl-hydroxy anysole, benzoic acid, toluic acid, catechol, t-butyl catechol, benzylamine, 1,1,3-tris(2-methyl-4-hydroxy-5-t-butylphenyl) butane, n-propylgallate or mixtures thereof and highly preferred is di-tert-butyl hydroxy toluene.
- Radical scavengers when used, are typically present herein in amounts ranging from 0.001% to 2% by weight of the total composition and preferably from 0.001% to 0.5% by weight.
- the present invention further encompasses a process of treating a hard-surface, especially inclined surfaces, wherein a composition according to the present invention is applied in its neat or diluted form onto said surface, optionally left to act thereto for an effective period of time and then removed for example by rinsing or flushing.
- compositions herein may be diluted with water up to 99% of water. Dilution may occur either before, after or while the composition is applied to a hard-surface.
- compositions herein find a preferred application in the cleaning of toilet bowls and bath tubs.
- the compositions of the present invention are applied neat onto the inclined surface, especially a toilet bowl, then left to act thereto typically for 1 minute to 1 hour, preferably 1 minute to 30 minutes and then removed by rinsing or flushing.
- the compositions according to the present invention may be diluted while or after they are applied to the surface to be cleaned.
- said compositions may be dispensed from a container neat onto said hard-surface, then diluted in water and left to act onto said surfaces for an effective period of time and then removed by rinsing or flushing.
- the expression "treating" includes washing as the compositions used in the process according to the present invention comprise surfactants, optionally descaling limescale as said compositions may also be acidic, and optionally bleaching as said compositions may also comprise a source of active oxygen, preferably hydrogen peroxide and/or persulfate salts. Preferably the three treatments are performed.
- compositions according to the present invention may be manufactured by adding the different ingredients in any order. However, the desired initial viscosity of an aqueous composition of the present invention is obtained immediately, when following a preferred mixing order for the incorporation of the different ingredients in said composition. Accordingly, the present invention further encompasses a process for the manufacture of the liquid thickened compositions of the present invention, wherein said process comprises the steps of:
- compositions are made which comprise the listed ingredients in the listed proportions (weight %).
- COMPOSITIONS (weight %) I II III IV V VI Curox® 4 4 - - - - Hydrogen peroxide - - 3 3 3 3 Sulfuric acid - - 6 6 6 6 6 Naphtalen di sulphonic acid 8 8 - - - - C16 trimethyl ammonium sulphate 2.3 2.5 3.1 2.9 2.7 2.7 Lauryl aryl suphonate 0.15 0.15 0.25 0.2 0.18 0.16 Hostapur SAS® - - - - - - - Perfume 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4
- the initial viscosity of the above compositions were measured by a Carri-Med Rheomoter CLS 100 by TA instruments at fixed shear stress of 50 dyne/cm 2 at 20°C with a 4 cm diameter cone spindle.
- 50 dyne/cm 2 as shear stress value is representative of a fluid flow occurring on an inclined surface when the product thickness on the surface is about 1 mm and the only external force is due to the gravity field, as in a toilet cleaning application.
- compositions according to the present invention are translucent, Newtonian compositions that provide significant benefits in toilet soils cleaning both when used neat or diluted. Said compositions are stable over long periods of time. Indeed, these compositions have not more than 10% available oxygen loss after 1 month at room temperature.
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Priority Applications (1)
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EP96870120A EP0832964A1 (fr) | 1996-09-19 | 1996-09-19 | Compositions de nettoyage liquides stables et épaisses |
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EP96870120A EP0832964A1 (fr) | 1996-09-19 | 1996-09-19 | Compositions de nettoyage liquides stables et épaisses |
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Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2000020548A1 (fr) * | 1998-10-01 | 2000-04-13 | Albemarle Corporation | Compositions biocides tensio-actives et utilisation de ces dernieres |
EP1001012A1 (fr) * | 1998-11-10 | 2000-05-17 | The Procter & Gamble Company | Compositions désinfectantes de nettoyage |
EP1001008A1 (fr) * | 1998-11-10 | 2000-05-17 | The Procter & Gamble Company | Compositions de blanchiment liquides et aqueuses contenant un tensioactif anionique sulfoné |
WO2000057730A1 (fr) * | 1999-03-26 | 2000-10-05 | Ecolab Inc. | Compositions antimicrobiennes et antivirales et traitement de surface d'aliments |
WO2001019944A1 (fr) * | 1999-09-14 | 2001-03-22 | S.C. Johnson & Son, Inc. | Procede de nettoyage de cuvette de toilettes et d'urinoirs |
US6436445B1 (en) | 1999-03-26 | 2002-08-20 | Ecolab Inc. | Antimicrobial and antiviral compositions containing an oxidizing species |
WO2004027012A1 (fr) * | 2002-09-20 | 2004-04-01 | Unilever N.V. | Procédé de fabrication de compositions de gel détergent |
US6794348B2 (en) | 2002-09-20 | 2004-09-21 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Gel laundry detergent and/or pre-treater composition |
US6815409B2 (en) | 2002-09-20 | 2004-11-09 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Gel laundry detergent and/or pretreater which piles up after dispensing |
US6849587B2 (en) | 2002-09-20 | 2005-02-01 | Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. | Liquid or gel laundry detergent which snaps back at the end of dispensing |
US6855328B2 (en) | 2002-03-28 | 2005-02-15 | Ecolab Inc. | Antimicrobial and antiviral compositions containing an oxidizing species |
US6972278B2 (en) | 2004-02-05 | 2005-12-06 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Laundry detergent gel with suspended particles |
US6992053B2 (en) | 2001-03-26 | 2006-01-31 | The Procter & Gamble Company | Hard surface cleaning composition comprising a bleach, acid, and silicone glycol polymer |
EP1894990A1 (fr) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Dose d'unité de la composition pâteuse pour des articles sanitaires |
EP1894989A1 (fr) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Composition pâteuse pour articles sanitaires |
WO2008049616A1 (fr) * | 2006-10-25 | 2008-05-02 | Lonza Inc. | Compositions de phosphonium et d'ammonium quaternaires aqueuses à mousse contrôlée |
EP3085760A1 (fr) | 2015-04-20 | 2016-10-26 | Tomil s.r.o. | Produit de nettoyage en base aqueuse pour le domaine sanitaire |
US10160850B2 (en) | 2006-11-09 | 2018-12-25 | The Lubrizol Corporation | Quaternary ammonium salt of a polyalkene-substituted amine compound |
CN110721108A (zh) * | 2019-09-26 | 2020-01-24 | 广州妮趣化妆品有限公司 | 一种椰油酰基丙氨酸盐的增稠组合物及其应用 |
EP3623455A1 (fr) * | 2018-09-12 | 2020-03-18 | Bolton Manitoba S.p.A. | Formulation détartrante pour toilettes |
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Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2000020548A1 (fr) * | 1998-10-01 | 2000-04-13 | Albemarle Corporation | Compositions biocides tensio-actives et utilisation de ces dernieres |
EP1001012A1 (fr) * | 1998-11-10 | 2000-05-17 | The Procter & Gamble Company | Compositions désinfectantes de nettoyage |
EP1001008A1 (fr) * | 1998-11-10 | 2000-05-17 | The Procter & Gamble Company | Compositions de blanchiment liquides et aqueuses contenant un tensioactif anionique sulfoné |
WO2000027971A1 (fr) * | 1998-11-10 | 2000-05-18 | The Procter & Gamble Company | Compositions de blanchiment aqueuses liquides comprenant un tensioactif anionique sulfone |
WO2000027981A1 (fr) * | 1998-11-10 | 2000-05-18 | The Procter & Gamble Company | Compositions desinfectantes et lavantes |
WO2000057730A1 (fr) * | 1999-03-26 | 2000-10-05 | Ecolab Inc. | Compositions antimicrobiennes et antivirales et traitement de surface d'aliments |
US6436445B1 (en) | 1999-03-26 | 2002-08-20 | Ecolab Inc. | Antimicrobial and antiviral compositions containing an oxidizing species |
US6534075B1 (en) | 1999-03-26 | 2003-03-18 | Ecolab Inc. | Antimicrobial and antiviral compositions and treatments for food surfaces |
WO2001019944A1 (fr) * | 1999-09-14 | 2001-03-22 | S.C. Johnson & Son, Inc. | Procede de nettoyage de cuvette de toilettes et d'urinoirs |
US6425406B1 (en) | 1999-09-14 | 2002-07-30 | S. C. Johnson & Son, Inc. | Toilet bowl cleaning method |
US6992053B2 (en) | 2001-03-26 | 2006-01-31 | The Procter & Gamble Company | Hard surface cleaning composition comprising a bleach, acid, and silicone glycol polymer |
US6855328B2 (en) | 2002-03-28 | 2005-02-15 | Ecolab Inc. | Antimicrobial and antiviral compositions containing an oxidizing species |
US6849587B2 (en) | 2002-09-20 | 2005-02-01 | Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. | Liquid or gel laundry detergent which snaps back at the end of dispensing |
US6815409B2 (en) | 2002-09-20 | 2004-11-09 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Gel laundry detergent and/or pretreater which piles up after dispensing |
US6794347B2 (en) | 2002-09-20 | 2004-09-21 | Unilever Home & Personal Care Usa A Division Of Conopco, Inc. | Process of making gel detergent compositions |
US6794348B2 (en) | 2002-09-20 | 2004-09-21 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Gel laundry detergent and/or pre-treater composition |
WO2004027012A1 (fr) * | 2002-09-20 | 2004-04-01 | Unilever N.V. | Procédé de fabrication de compositions de gel détergent |
US6972278B2 (en) | 2004-02-05 | 2005-12-06 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Laundry detergent gel with suspended particles |
WO2008026192A1 (fr) * | 2006-09-01 | 2008-03-06 | The Procter & Gamble Company | Composition pâteuse destinée à des équipements sanitaires |
EP1894989A1 (fr) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Composition pâteuse pour articles sanitaires |
WO2008026185A1 (fr) * | 2006-09-01 | 2008-03-06 | The Procter & Gamble Company | Dose unitaire de composition en pâte destinée aux appareils sanitaires |
EP1894990A1 (fr) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Dose d'unité de la composition pâteuse pour des articles sanitaires |
WO2008049616A1 (fr) * | 2006-10-25 | 2008-05-02 | Lonza Inc. | Compositions de phosphonium et d'ammonium quaternaires aqueuses à mousse contrôlée |
AU2007308351B2 (en) * | 2006-10-25 | 2013-05-16 | Innovative Water Care, Llc | Controlled Foam Alkyl Quat Formulations |
CN101563140B (zh) * | 2006-10-25 | 2013-06-19 | 隆萨公司 | 可抑制泡沫的水性季铵和/或季磷组合物 |
US10160850B2 (en) | 2006-11-09 | 2018-12-25 | The Lubrizol Corporation | Quaternary ammonium salt of a polyalkene-substituted amine compound |
EP3085760A1 (fr) | 2015-04-20 | 2016-10-26 | Tomil s.r.o. | Produit de nettoyage en base aqueuse pour le domaine sanitaire |
EP3623455A1 (fr) * | 2018-09-12 | 2020-03-18 | Bolton Manitoba S.p.A. | Formulation détartrante pour toilettes |
CN110721108A (zh) * | 2019-09-26 | 2020-01-24 | 广州妮趣化妆品有限公司 | 一种椰油酰基丙氨酸盐的增稠组合物及其应用 |
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