EP0827936B1 - Verfahren und Vorrichtung zum Verdrängen der Luft aus mit karbonisierten Getränken gefüllten Flaschen - Google Patents

Verfahren und Vorrichtung zum Verdrängen der Luft aus mit karbonisierten Getränken gefüllten Flaschen Download PDF

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Publication number
EP0827936B1
EP0827936B1 EP19960113832 EP96113832A EP0827936B1 EP 0827936 B1 EP0827936 B1 EP 0827936B1 EP 19960113832 EP19960113832 EP 19960113832 EP 96113832 A EP96113832 A EP 96113832A EP 0827936 B1 EP0827936 B1 EP 0827936B1
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EP
European Patent Office
Prior art keywords
headspace
bottles
liquid nitrogen
nitrogen
conveyor
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19960113832
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English (en)
French (fr)
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EP0827936A1 (de
Inventor
Olaf Dipl.-Ing. Babel
Detlef Bennewitz
Hans Dipl.-Ing. Erler
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Air Products and Chemicals Inc
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Air Products and Chemicals Inc
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Publication date
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Priority to DE1996601710 priority Critical patent/DE69601710T2/de
Priority to EP19960113832 priority patent/EP0827936B1/de
Priority to ES96113832T priority patent/ES2130727T3/es
Publication of EP0827936A1 publication Critical patent/EP0827936A1/de
Application granted granted Critical
Publication of EP0827936B1 publication Critical patent/EP0827936B1/de
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/02Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
    • B67C3/22Details
    • B67C3/222Head-space air removing devices, e.g. by inducing foam

Definitions

  • the invention relates to a process for headspace inertization of bottles filled with carbonated beverages or beer and a device for carrying out this process.
  • beer is filled into bottles in such a fashion that a residual gas volume remains in the headspace of the containers.
  • This residual volume is at first filled with carbon dioxide in the case of beers containing CO 2 . Since the bottles are exposed to ambient air during transfer from the bottling station to the sealing station, there is a risk of oxygen entering the headspace during this transfer, which promotes germ formation in such beverages and thus greatly reduces their storage stability.
  • beer is conventionally foamed during transfer from the bottling station to the sealing station by means of introducing a gaseous or liquid medium into the headspace onto the surface of the beer so that the resultant foam expels the gas volume, and thus also the oxygen that has entered, from the headspace.
  • the oxygen content in the headspace can be reduced at the moment the bottle is sealed.
  • a jet of liquid here in particular water
  • the impulse of the water jet can be regulated.
  • the beverage foam becomes relatively large-pored after the high-pressure water injection so that, despite larger overfoam volumes (2 to 5 ml/bottle), the average oxygen values that can be achieved in the headspace are no better than 0.018 to 0.1 mg per liter.
  • the disadvantageous large overfoaming results in a high waste water pollutant load and thus substantial liquid waste disposal costs; also, the large overfoam volumes are equivalent to net beverage losses which, of course, are expensive per se.
  • a process for treating containers and a device according to the preamble of claim 8. is disclosed in EP-0,723,928 A1. According to this document liquid nitrogen is positioned on the surface of a beverage in a bottle and the air volume in the headspace is expelled by the expansion of the gasifying nitrogen. A foaming up does not take place.
  • a filling height correction for bottling liquids is described in DE-OS 4018660 A1.
  • an inert gas is used to build up an exactly defined pressure in the headspace of a bottle, by means of which an excess liquid volume is expelled from the bottle.
  • the disadvantage is that the desired foaming does not take place here; the oxygen already contained in the headspace of the bottle remains there, and reduces the storage stability of the beverage.
  • the object of the present invention is to create a method and a device for headspace inertization of bottles filled with carbonated beverages or beer, which overcome the aforementioned disadvantages of the prior art.
  • the invention is intended to achieve a good storage stability of the bottled beverages and as few foaming losses as possible.
  • the advantage of foaming the beer according to the invention is firstly that the foam arising from liquid nitrogen foaming has much finer pores than, for instance, that arising from water injection, and thus becomes substantially more gas-tight.
  • the amount of oxygen remaining in the headspace after foaming is very low, and in a range that conventional high-pressure injection systems with comparable overfoaming losses cannot even come close to.
  • Another advantage is that the microporous foam arising from liquid nitrogen injection can be regulated very well with regard to the resultant foam quantity, so foaming losses can be minimized.
  • the overfoam volumes which are expensive per se and waste water polluting, can be greatly reduced. There is no longer a gas exchange with the ambient air in the headspace of the filled bottle, but only with the inert nitrogen.
  • a further advantage of the foaming according to the invention consists in the fact that special plant technologies for preparing germ-free water are no longer required since, as a matter of course, no water is used any more as a foaming agent.
  • the bottles pass along a bottling conveyor, a transfer conveyor and a sealing conveyor, with the injection point for the liquid nitrogen being located after the transfer point of the containers from the bottling conveyor to the transfer conveyor.
  • the foaming of the beer is already carried out shortly after bottling, i.e. there is little time for the oxygen-containing ambient air to enter the headspace. This, too, reduces the oxygen percentage in the headspace yet again.
  • the liquid nitrogen to be introduced into the headspace of the bottle is metered in pulsed fashion or as a permanent flow at one or several points of a metering means contained in the foaming means.
  • the metering quantity and the charging mode can be adjusted in each case as a function of the size and the speed of the containers that pass through.
  • the liquid nitrogen to be introduced into the headspace is high-purified in a purification means contained in the foaming means prior to its being introduced into the headspace.
  • a purification means contained in the foaming means prior to its being introduced into the headspace.
  • the use of high-pure, sterile nitrogen results in only very small amounts of impurities entering the beer and/or the headspace so that this measure also improves storage stability.
  • the amount of the liquid nitrogen entering the headspace is adjusted by means of a controller in the foaming means to a value at which no excessive overpressure is built up in the containers, so that damage to the containers can be avoided.
  • the liquid subcooled nitrogen is advantageously injected into the headspace onto the surface of the beer at a regulatable overpressure ranging from about 2 to 20 bar.
  • the foaming of the beer is brought about by the kinetic energy of the hard jet of the liquid nitrogen. Since different beers also foam differently, the overpressure with which the liquid nitrogen is introduced into the headspace can in each case be adjusted so accurately that foaming losses are minimized while, at the same time, the greatest possible amount of oxygen is expelled.
  • a means is provided in a preferred embodiment of the present invention which surrounds the nitrogen jet with a haze of gaseous nitrogen.
  • the foaming means comprises a pressure control means which brings the nitrogen to be injected into the headspace onto the surface of the beer to a liquid subcooled condition at a controllable overpressure ranging from about 2 to 20 bar.
  • the foaming means of the device according to the invention comprises preferably a feeder for gaseous nitrogen, a feeder for liquid nitrogen, a pressure control and metering means for the liquid nitrogen to be delivered, a charging pipeline for feeding the liquid nitrogen to the injection point, a capillary tube and an exhaust pipe.
  • the capillary tube for the subcooled, pressurized liquid nitrogen has a diameter of 0.3 to 0.7 mm, preferably of about 0.5 mm.
  • the outer diameter of the capillary tube ranges from 1.3 to 1.9 mm in an embodiment of the device according to the invention and is preferably 1.6 mm. In the thus defined range for the line and/or nozzle cross-section, suitable heat exchange takes place through the tube cross-section, so that the nozzle does not clog due to icing.
  • the charging pipeline can extend horizontally, while the nozzle at its end extends vertically after a portion that is bent downwards.
  • the entire foaming means is preferably arranged in such a fashion that the charging pipeline and the nozzle extend vertically in one line so that disadvantageous effects caused by deflection of the liquid nitrogen jet can be avoided.
  • the capillary tube consists of stainless steel or advantageously of a material with a low heat conductivity, in particular of polytetrafluoroethylene. This choice of material, as well, enables advantageous heat flow, thus avoiding nozzle icing.
  • the inner diameter of the capillary tube and the pressure of the delivered nitrogen must be adapted to each other in order to be able to set the optimum amount of liquid nitrogen for foaming in each case.
  • the advantages described above can be achieved as a result of the interaction of all setting measures to be taken, i.e. pressure control of the liquid nitrogen, suitable metering and suitable design of the capillary tube. Foaming losses can in particular be reduced by 50% or more as compared with the prior art.
  • Fig. 1 shows an elevation of an embodiment of a device according to the invention for headspace inertization.
  • the foaming means of this device is designated in general with the reference numeral 10. It comprises a pressure and/or temperature control and metering means 15 which is firmly anchored to the floor next to a transfer conveyor 33 indicated in dash-dotted lines.
  • the transfer conveyor 33 conveys bottles 18 already filled with beer from a bottling conveyor 31 to a sealing conveyor 32 (cf. Fig. 3).
  • a feeder 11 for gaseous nitrogen is represented as a connection at the upper part of the pressure and/or temperature control and metering means 15.
  • a manometer 12 is attached to this connection with which the pressure of the inflowing gaseous nitrogen can be monitored.
  • the connection 13 for the feeding of liquid nitrogen (also called LIN in the following) is affixed at the upper part of the pressure and/or temperature control and metering means 15.
  • the third component, a flue pipe, which is located at the upper part of the means 15, is designated with the reference numeral 14.
  • the pressure control and metering means 15 prepares a flow of liquid nitrogen flowing in pulsed or permanent fashion from the infed nitrogen flows, which is introduced into the charging pipeline 16. This flow of liquid nitrogen is subcooled and is at a pressure level of 2 to 20 bar overpressure when it leaves the bent capillary tube 17 which adjoins the charging pipeline 16, and is injected as a jet into the headspace of a bottle 18 onto the surface of the beer contained therein.
  • the pressure, the temperature and the amount of the subcooled liquid nitrogen jet to be delivered are adjusted in the pressure control and metering device 15 in such a fashion that a nitrogen jet is always injected for a specific type of beer with a predetermined carbonization and/or a predetermined CO 2 content which effects a foaming in the beer, but does not result in high foaming losses.
  • the aforementioned parameters of the liquid nitrogen jet are always adjusted in such a fashion that the jet still remains in liquid condition upon its exit from the capillary tube 17 (cf. Fig. 2), i.e. also in the case of an expansion to ambient pressure.
  • a "hard" liquid nitrogen jet impinges onto the surface of the beer filled into the bottle and induces foaming due to its kinetic energy. In the optimum case, the nitrogen jet impinges onto a black surface.
  • the foaming of the bottled beer results, if a nitrogen jet is used, in a highly microporous foam which displaces the gas volume contained in the bottle up to then due to its rising in the headspace of the bottles 18. Because of its microporosity, the resultant foam is highly gas-tight and effects a type of piston flow in the bottleneck. Due to this, only a very small amount of the original gas volume remains in the headspace; the gas tightness of the microporous foam alone prevents air from the environment from entering the headspace. As a result of this process, the oxygen content in the headspace is brought to a very low value when the bottles 18 are sealed, a result that conventional high-pressure water injections in which large-pore foam is formed do not even get close to achieving.
  • Fig. 2 the end of the capillary tube 17 is represented in its cross-section.
  • Stainless steel tubes with a small wall thickness can be used; plastic materials such as polytetrafluoroethylene are also used with preference.
  • Suitable wall thicknesses for the capillary wall 21 are an inner diameter ranging from 0.3 to 0.7 mm, preferably of 0.5 mm.
  • the outer diameter range for the tube wall 21 can be defined as 1.3 to 1.9 mm, preferably 1.6 mm.
  • FIG. 3 A top view of the headspace inertization means according to the invention is again shown in Fig. 3.
  • the arrangement of the foaming means 10 with the pressure control and metering means 15, the charging pipeline 16 and the capillary tube 17 in relation to the conveying facilities for the bottles 18 is made clear in this view.
  • Filled bottles 18 are delivered by a bottling conveyor 31 that rotates clockwise, and is partially shown at the lefthand side, to a transfer conveyor which rotates counter-clockwise.
  • the subcooled, pressurized liquid nitrogen is injected into a bottle 18 positioned on the transfer conveyor 33. This injection takes place that shortly after the filling of the bottles 18 so that as little ambient air as possible can enter the headspaces of the bottles 18 during transfer.
  • the injection takes place according to the functional principle described above.
  • the beverage liquid contained in the bottles 18 foams, so that no ambient air can enter the headspace of the bottles 18 until the bottles are sealed in the sealing conveyor 33 which adjoins the transfer conveyor 33.
  • One possibility consists in arranging the foaming means 10 in such a fashion that it is located directly above the injection point so that the charging pipeline and the adjoining capillary tube extend in a straight line. This avoids disadvantageous effects due to deflection of the jet of liquid nitrogen.
  • a further development possibility consists in providing a means at the injection point which surrounds it with a haze of gaseous nitrogen. This prevents atmospheric oxygen from the environment from being entrained by the jet of liquid nitrogen into the headspace of the bottles 18.
  • a pressure control and metering means 15 for the liquid nitrogen to be delivered is schematically represented in Fig. 4. At the upper lefthand, two feeding means for liquid nitrogen 13 and gaseous nitrogen 11 are represented. These lead into the means 15 with the interposition of pressure and/or temperature control means 41, 42, 43, 44, 46, 47.
  • control elements 40, 45, 48, 49 which are located in the intermediate pipelines.
  • a jet of liquid subcooled nitrogen (LIN) which is at an overpressure of 2 to 20 bar, depending upon the requirements to be met by foaming, exits from the pressure control and metering means 15. This is the nitrogen flow which is introduced into the charging pipeline 16 (cf. Figs. 1 and 3).
  • gaseous nitrogen N 2 exits which is delivered to the exhaust pipe 15 shown in Fig. 1 and is blown off.
  • the metering and the pressure of the nitrogen jet to be delivered are adjusted, also in relation to the dimensions of the capillary tube 17 and the charging pipeline, by means of the control system shown in Fig. 4 in such a fashion that an optimum jet of liquid nitrogen can be injected in each case for different foaming applications.

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  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Vacuum Packaging (AREA)

Claims (15)

  1. Verfahren zur Inertisierung des Kopfraumes von Flaschen (18), die mit karbonisierten bzw. kohlensäurehaltigen Getränken gefüllt sind, vorzugsweise mit Bier, mit den folgenden Schritten:
    a) nach dem Einfüllen der Getränke, vorzugsweise Bier, in die Flaschen (18), werden die Flaschen zu einer Aufschäumeinrichtung (10) überfährt,
    b) ein Strahl aus unter Druck stehendem und unterkühltem flüssigem Inertgas, insbesondere Stickstoff, wird in dosierter und druckgeregelter Weise in den Kopfraum der Flasche (18) eingebracht und dazu gebracht, auf die Oberfläche des Getränks aufzutreffen, wobei er das Aufschäumen aufgrund seiner kinetischen Energie bewirkt,
    c) aufgrund des resultierenden Aufschäumens wird das Gasvolumen, das vorher im Kopfraum enthalten war, aus diesem entfernt, und
    d) die Flaschen (18) werden verschlossen.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Flaschen (18) durch einen Abfüllförderer (31), einen Überführungsförderer (33) und einem Verschlußförderer (32) hindurchgehen, wobei der Einbringpunkt für den flüssigen Stickstoff nach dem Übergangspunkt der Flaschen (18) vom Abfüllförderer (31) zum Überführungsförderer (33) angeordnet ist.
  3. Verfahren nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, daß zur Einbringung des flüssigen Stickstoffs in den Kopfraum der Flasche (18), der flüssige Stickstoff an einem oder an mehreren Punkten einer Dosiereinrichtung (15) impulsartig oder als Permanentstrom dosiert wird.
  4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß der flüssige Stickstoff, der in den Kopfraum eingebracht wird, vor der Einbringung hochgereinigt wird.
  5. Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die Menge des flüssigen Stickstoffs, der in den Kopfraum eingebracht wird, auf einen Wert eingestellt wird, bei welchem kein zu hoher Überdruck in den verschlossenen Flaschen (18) gebildet wird.
  6. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß der flüssige unterkühlte Stickstoff in den Kopfraum auf die Oberfläche des Getränks bei einem regelbaren Überdruck eingespritzt wird, der im Bereich von 2 bis 20 bar liegt.
  7. Verfahren nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß der Strahl des flüssigen Stickstoffs von einem Schleier aus gasförmigem Stickstoff umgeben ist, um zu verhindern, daß Umgebungsluft in den Kopfraum hinein mitgerissen wird.
  8. Vorrichtung zur Inertisierung des Kopfraumes von Flaschen, die mit karbonisierten bzw. kohlenstoffhaltigen Getränken gefüllt sind, vorzugsweise mit Bier, mit:
    a) einer Einrichtung (31) zum Füllen des Getränks in die Flaschen (18),
    b) einer Einrichtung (10), zu welcher die Flaschen (18) überführt werden, nachdem sie gefüllt worden sind, und mittels welcher das vorher im Kopfraum der Flaschen (18) vorhandene Gasvolumen aus diesem entfernt wird,
    c) einer Verschließvorrichtung (32) für die Flaschen (18) und
    d) einer Einrichtung (16, 17) für die druckgeregelte Einbringung eines Strahls aus unter Druck stehendem, unterkühltem, flüssigem Inertgas, insbesondere Stickstoff, in den Kopfraum der Flaschen (18),
    dadurch gekennzeichnet, daß die Einrichtung ferner umfaßt:
    e) eine Dosiereinrichtung (15) zum Einbringen des flüssigen Stickstoffs in den Kopfraum der Flaschen (18), mit welcher der flüssige Stickstoff impulsartig oder als Permanentstrom an einem oder mehreren Punkten dosiert wird, und
    f) einer Druckregelungseinrichtung (15), mittels welcher der Stickstoff, der in dem Kopfraum auf die Oberfläche des Getränks eingespritzt werden soll, in einem flüssigen unterkühlten Zustand bei einem regelbaren Überdruck gebracht wird, der im Bereich von 2 bis 20 bar liegt.
  9. Vorrichtung nach Anspruch 8, gekennzeichnet durch einen Abfüllförderer (31), einen Überführungsförderer (33) und einen Verschlußförderer (32), wobei der Einbringpunkt für den flüssigen Stickstoff hinter dem Übergangspunkt der Flaschen (18) vom Abfüllförderer (31) zum Überführungsförderer (33) angeordnet ist.
  10. Vorrichtung nach einem der Ansprüche 8 oder 9, gekennzeichnet durch eine Reinigungseinrichtung, mittels welcher der flüssige Stickstoff, der in dem Kopfraum eingebracht werden soll, vor seiner Einbringung hochgereinigt wird.
  11. Vorrichtung nach einem der Ansprüche 8 bis 10, gekennzeichnet durch einen Regler, welcher die Menge des in den Kopfraum einzubringenden flüssigen Stickstoffes auf einen Wert einstellt, bei welchem kein zu hoher Überdruck in den verschlossenen Flaschen (18) gebildet wird.
  12. Vorrichtung nach einem der Ansprüche 8 bis 11, gekennzeichnet durch eine Aufschäumvorrichtung (10) mit
    einer Zuführeinrichtung (13) für gasförmigen Stickstoff,
    einer Zuführeinrichtung (11) für flüssigen Stickstoff,
    einer Druck- und/oder Temperaturregelungs- und Dosiereinrichtung (15) für zuzuführenden flüssigen Stickstoff,
    einer Beschickungsleitung (15) zum Zuführen des flüssigen Stickstoffs zum Einspritzpunkt,
    einem Kapillarrohr (17) am Ende der Beschickungsleitung (16) zum Zuführen des flüssigen Stickstoffs, und
    einer Ablaßleitung (14).
  13. Vorrichtung nach Anspruch 12, dadurch gekennzeichnet, daß die Beschickungsleitung (16) und/oder das Kapillarrohr (20) einen Innendurchmesser von 0,3 bis 0,7 mm, vorzugsweise ungefähr 0,5 mm und einen Außendurchmesser von 1,3 bis 1,9 mm, vorzugsweise 1,6 mm haben.
  14. Vorrichtung nach einem der Ansprüche 12 oder 13, dadurch gekennzeichnet, daß die Beschickungsleitung (16) und/oder das Kapillarrohr (12) aus Edelstahl und vorzugsweise aus einem Material mit geringer Wärmeleitung bestehen, insbesondere aus Polytetrafluorethylen.
  15. Vorrichtung nach einem der Ansprüche 8 bis 14, gekennzeichnet durch eine Schleiereinrichtung, mittels welcher der Strahl des flüssigen Stickstoffs durch einen Schleier aus gasförmigem Stickstoff umgeben wird, um das Mitreißen von Umgebungsluft in den Kopfraum zu verhindern.
EP19960113832 1996-08-29 1996-08-29 Verfahren und Vorrichtung zum Verdrängen der Luft aus mit karbonisierten Getränken gefüllten Flaschen Expired - Lifetime EP0827936B1 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE1996601710 DE69601710T2 (de) 1996-08-29 1996-08-29 Verfahren und Vorrichtung zum Verdrängen der Luft aus mit karbonisierten Getränken gefüllten Flaschen
EP19960113832 EP0827936B1 (de) 1996-08-29 1996-08-29 Verfahren und Vorrichtung zum Verdrängen der Luft aus mit karbonisierten Getränken gefüllten Flaschen
ES96113832T ES2130727T3 (es) 1996-08-29 1996-08-29 Un procedimiento y un dispositivo para la eliminacion del aire del cuello de las botellas llenas con una bebida carbonatada.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19960113832 EP0827936B1 (de) 1996-08-29 1996-08-29 Verfahren und Vorrichtung zum Verdrängen der Luft aus mit karbonisierten Getränken gefüllten Flaschen

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EP0827936A1 EP0827936A1 (de) 1998-03-11
EP0827936B1 true EP0827936B1 (de) 1999-03-10

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DE (1) DE69601710T2 (de)
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101687621B (zh) * 2007-07-10 2011-10-12 克朗斯股份公司 容器处理机

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2773552B1 (fr) * 1998-01-15 2000-02-25 Aubreby Jean Pierre D Procede et dispositif pour ajouter un complement de mousse dans un recipient a boisson contenant un volume de biere
DE102007020625A1 (de) * 2007-04-30 2008-11-06 Khs Ag Verfahren zum Verarbeiten, insbesondere zum Verpacken von Produkten unter Verwendung eines sauerstofffreien Prozessgases

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2134640C3 (de) * 1971-07-12 1975-05-07 Seitz-Werke Gmbh, 6550 Bad Kreuznach Verfahren und Vorrichtung zum Verdrängen der Luft aus Flaschen od. dgl. Behälter durch Schaumentwicklung des abgefüllten Getränks
DE4030081A1 (de) * 1990-09-22 1992-03-26 Seitz Enzinger Noll Masch Aufschaeumvorrichtung zum verdraengen des restluftvolumens aus mit einem aufschaeumbaren fluessigen fuellgut gefuellten behaeltern, insbesondere flaschen
DE4135438A1 (de) * 1991-10-26 1993-04-29 Orthmann & Herbst Vorrichtung zum aufschaeumen von karbonisierten getraenken in flaschen
DE19502452A1 (de) * 1995-01-26 1996-08-01 Kronseder Maschf Krones Verfahren und Vorrichtung zum Behandeln von Gefäßen

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101687621B (zh) * 2007-07-10 2011-10-12 克朗斯股份公司 容器处理机

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DE69601710T2 (de) 1999-07-22
ES2130727T3 (es) 1999-07-01
EP0827936A1 (de) 1998-03-11
DE69601710D1 (de) 1999-04-15

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