EP0813374B1 - Article with bristles, such as brush, paint brush or the like - Google Patents
Article with bristles, such as brush, paint brush or the like Download PDFInfo
- Publication number
- EP0813374B1 EP0813374B1 EP96905823A EP96905823A EP0813374B1 EP 0813374 B1 EP0813374 B1 EP 0813374B1 EP 96905823 A EP96905823 A EP 96905823A EP 96905823 A EP96905823 A EP 96905823A EP 0813374 B1 EP0813374 B1 EP 0813374B1
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- EP
- European Patent Office
- Prior art keywords
- bristles
- bristle
- brush
- brushware
- different
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000870659 Crassula perfoliata var. minor Species 0.000 title 1
- 239000004033 plastic Substances 0.000 claims abstract description 13
- 229920003023 plastic Polymers 0.000 claims abstract description 13
- 230000008719 thickening Effects 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 2
- 241000218631 Coniferophyta Species 0.000 claims 1
- 230000000694 effects Effects 0.000 description 17
- 238000004140 cleaning Methods 0.000 description 11
- 241000894006 Bacteria Species 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000009966 trimming Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 210000004195 gingiva Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004413 injection moulding compound Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/06—Arrangement of mixed bristles or tufts of bristles, e.g. wire, fibre, rubber
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/02—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/02—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
- A46B9/04—Arranged like in or for toothbrushes
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1066—Toothbrush for cleaning the teeth or dentures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S15/00—Brushing, scrubbing, and general cleaning
- Y10S15/05—Varied length bristle
Definitions
- the invention relates to bristle goods, e.g. Brush, Brushes or the like which are damp during use is exposed and a bristle holder and a bristle trim has, which at least partially from individually standing plastic bristles.
- bristle goods e.g. Brush, Brushes or the like which are damp during use is exposed and a bristle holder and a bristle trim has, which at least partially from individually standing plastic bristles.
- Bristle goods that are exposed to moisture it for cleaning purposes in a humid atmosphere be used, e.g. Toothbrushes, or for application serve moist media, e.g. Brush, dry after Inadequate use because the bristles form bundles are summarized and the moisture in the long capillaries between the bristles.
- This damp atmosphere creates ideal conditions for that Nest and for the growth of bacteria and microbes.
- This disadvantageous effect is supported due to dirt particles or residues of application agents that get stuck in the narrow capillaries and also at intensive cleaning efforts insufficiently removed can be because the bristles in the root area too narrow stand.
- These negative effects are still supported in that the bristle holder in many brush designs is provided with recesses into which the Bristle bundles are used. In these cavities Bacteria have a particularly small cross-section slightly firm, as well as dirt particles and residues of Order materials cannot be removed there.
- the bristle trimmings are not made up of bundles, but consists of individual bristles on the carrier and with each other by thermal processes, in particular connected with each other by laser technology.
- the bristles also lie at their end on the carrier side free by making the bristle holder a large recess according to the outline of the bristle trim and the bristles are inserted into this recess in such a way that they are exposed at the back of the carrier.
- the Bristles themselves should only be in the area of these Recess and only in the area of their tangent Lateral surfaces to be connected. This is to ensure be that continuous capillaries between the bristles remain.
- the pull-out strength of the bristles on the finished product is due to the thickening of the embedded Bristle end favorably influenced, but is the embedding not sufficient on the remaining length of the bristles guaranteed.
- the thickening When the thickening is immersed, it gives way Plastic mass due to the surface tension. Even if they have a sufficiently low viscosity flows back behind the thickening, remains due to the surface tension around the bristle crater-shaped depression, in the area of which the bristle is not embedded. To the necessary pull-out strength To achieve this, the embedding length must be appropriate be great. Regardless, the problem remains that there are impurities in the crater-shaped depression collect and nest bacteria.
- the invention has for its object bristle goods, their bristle trimmings from individually standing bristles, to further develop that ensures a quick drying of the brush and thus nesting and growth of bacteria and the storage of contaminants is successfully met, on the other hand a free one Design options for the bristle geometry given is the achievement of different usage properties allowed.
- Today's plastic technology enables seamless Fasten even small bristles Diameter on a flat surface, namely that of Bristle carrier. This is done by injection molding by overmolding the bristle ends with the plastic mass. Due to the injection pressure when molding the bristles ensures that there is no recess around the bristle rather, the bristle forms over the entire embedding length is firmly enclosed in the bristle holder. Come in addition, that the injection molding compound due to the injection pressure in the existing surface roughness of the bristle penetrates, which contributes to better anchoring of the bristle. The necessary pull-out strength can thus be with a minimum embedding length that is in an area that is less than four times the Bristle diameter.
- the Individual bristles at such a distance in the area of Arranged 0.5 to 4 times the bristle diameter from each other can be that between the bristles neither Bacteria nest, can still multiply there and grow also dirt (plaque, care agent or application agent residues) cannot fix. The gaps can be easily rinsed out.
- a brush constructed in this way dries quickly Time from which the dangers mentioned are also effective met.
- the bristle itself absorbs little or no liquid at all and releases these when drying, so that after the Use their original in a short time Strength properties regained.
- Paints, varnishes, mascara, or of cleaning and polishing agents such as toothpastes, gels, Serve polishing pastes or the like.
- the respective usage properties are exclusive by the geometry of the bristles themselves (diameter and length) and their material (polyamide, polyester etc.) as well as the geometry of the arrangement (more or less tight, but in any case always at a distance).
- This training ensures in particular that that, for example, with toothbrushes some longer Bristles are effective in, for example, interdental spaces penetrate while the shorter bristles on the tooth surfaces be effective.
- the bristles of different lengths also lead to different in the cleaning movement Spring out and spring back of the bristles Glide over the tooth surfaces while the shorter bristles rather take effect with their ends. This leaves a more or less scratching or stroking Achieve effect. Again, this can be done through different Distances of the bristles within the bristle stock are supported, with which a different Rebound and rebound of the bristles is connected.
- the Rigidity of the entire bristle trim cannot be achieved solely by dimensioning the bristle (diameter, Length) and the material, but especially by the distance between the bristles varies in fine increments.
- the bristles can also be combined into groups and the distance of the bristles of a group is the same, however be different from that of the other group. So can for example, the head or edge area of a toothbrush have a greater bristle density than that middle range.
- the bristles can also be different Stiffness, e.g. different diameters, have bristle groups different, but the same within the group Stiffness can be provided.
- the distance between the bristles from each other is usually 1.5 to 2 times the Bristle diameter.
- the Distance but also smaller than the bristle diameter be.
- the embodiment according to FIG. 3 has on the bristle carrier 1 in turn bristles 2 of different lengths, which in are evenly graded in this case.
- FIG. 5 shows an embodiment with bristles 8 smaller cross-section and bristles 9 larger cross-section, where the thinner and the thicker Bristles arranged at the same distance from each other are.
- Figure 6 shows an enlarged partial view of a single bristle with a cylindrical cross section and a spherical one rounded tip 10, which forms the end on the user side.
- this is Use-side end 11 conically shaped
- Figure 8 a bristle 2 with a spherical thickening on shows end of use. Because the bristles are arranged individually, in contrast to bundle arrangement - the end on the usage side its entire contoured surface and also that Shell surface take effect.
- FIG. 9 shows a bristle 2 with a contoured surface 13 with possibly abrasive effect, which in turn due to the solitary arrangement of the individual bristles Effectiveness can develop over a long length.
- the bristle 2 from a shaft 14 e.g. made of plastic, and one for example abrasive coating 15.
- the Shank 14 of the bristle 2 is flocked with fine fibers 16.
Landscapes
- Brushes (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Paints Or Removers (AREA)
- Cosmetics (AREA)
- Harvester Elements (AREA)
- Developing Agents For Electrophotography (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Saccharide Compounds (AREA)
- Apparatus For Radiation Diagnosis (AREA)
Abstract
Description
Die Erfindung betrifft eine Borstenware, z.B. Bürste, Pinsel od. dgl., die während des Gebrauchs Feuchtigkeit ausgesetzt ist und einen Borstenträger und einen Borstenbesatz aufweist, der zumindest teilweise aus einzeln stehenden Kunststoffborsten besteht.The invention relates to bristle goods, e.g. Brush, Brushes or the like which are damp during use is exposed and a bristle holder and a bristle trim has, which at least partially from individually standing plastic bristles.
Borstenwaren, die der Feuchtigkeit ausgesetzt sind, sei es daß sie zu Reinigungszwecken in feuchter Atmosphäre eingesetzt werden, z.B. Zahnbürsten, oder aber zum Auftragen feuchter Medien dienen, z.B. Pinsel, trocknen nach Gebrauch nur unzureichend ab, weil die Borsten zu Bündeln zusammengefaßt sind und sich die Feuchtigkeit in den engen Kapillaren zwischen den Borsten lange hält. Diese feuchte Atmosphäre bildet ideale Voraussetzungen für das Einnisten und für das Wachstum von Bakterien und Mikroben. Dieser nachteilige Effekt wird noch unterstützt durch Schmutzpartikel oder Reste von Auftragsmitteln, die sich in den engen Kapillaren festsetzen und auch bei intensiven Reinigungsbemühungen nur unzureichend entfernt werden können, da die Borsten im Wurzelbereich zu eng stehen. Diese negativen Effekte werden noch unterstützt dadurch, daß bei vielen Bürstenkonstruktionen der Borstenträger mit Ausnehmungen versehen ist, in die die Borstenbündel eingesetzt sind. In diesen Kavitäten kleinsten Querschnitts setzen sich Bakterien besonders leicht fest, wie auch Schmutzpartikel und Reste von Auftragsmitteln dort nicht zu entfernen sind.Bristle goods that are exposed to moisture it for cleaning purposes in a humid atmosphere be used, e.g. Toothbrushes, or for application serve moist media, e.g. Brush, dry after Inadequate use because the bristles form bundles are summarized and the moisture in the long capillaries between the bristles. This damp atmosphere creates ideal conditions for that Nest and for the growth of bacteria and microbes. This disadvantageous effect is supported due to dirt particles or residues of application agents that get stuck in the narrow capillaries and also at intensive cleaning efforts insufficiently removed can be because the bristles in the root area too narrow stand. These negative effects are still supported in that the bristle holder in many brush designs is provided with recesses into which the Bristle bundles are used. In these cavities Bacteria have a particularly small cross-section slightly firm, as well as dirt particles and residues of Order materials cannot be removed there.
Diese nachteiligen Effekte werden bei Zahnbürsten in besonderem Ausmaß festgestellt, da bei diesen Bürsten das Bestreben dahin geht, Borsten mit kleinstmöglichem Durchmesser in enger Pressung innerhalb des Bündels einzusetzen mit der Folge, daß die Kapillaren und Kavitäten besonders eng sind. Hinzu kommt, daß trotz Verwendung hochwertiger Kunststoffe für die Borsten, z.B. Polyamide, Feuchtigkeit auch in das Borstenmaterial eindringt und beim Abtrocknen nicht oder nur unzureichend abgegeben wird. Dies äußerst sich in einer Veränderung der Festigkeitseigenschaften der Borste. Die Borste verliert an Steifigkeit und damit an Wiederaufrichtungsvermögen, so daß die Reinigungswirkung nicht mehr der des Ursprungszustandes entspricht.These adverse effects are found in toothbrushes of particular magnitude, because with these brushes the Efforts go there, bristles with the smallest possible diameter to be used in tight pressure within the bundle with the result that the capillaries and cavities are particularly tight. In addition, despite use high quality plastics for the bristles, e.g. Polyamides, Moisture also penetrates into the bristle material and not or only insufficiently released when drying becomes. This manifests itself in a change in the strength properties the bristle. The bristle loses Stiffness and thus in the ability to rebuild, so that the cleaning effect is no longer that of the original state corresponds.
Die vorgenannten Nachteile treten bei Zahnbürsten dann besonders nachteilig in Erscheinung, wenn die aus zahnmedizinischen Gründen empfohlenen Putzintervalle (dreimal am Tag) eingehalten werden, da die dazwischen liegende Zeit nicht ausreicht, um ein vollständiges Abtrocknen der Borsten, vor allem im trägernahen Bereich, zu ermöglichen.The aforementioned disadvantages then occur with toothbrushes particularly detrimental in appearance if that from dental Recommended cleaning intervals (three times during the day), as the one in between There is not enough time to completely dry the Bristles, especially in the area close to the carrier.
In Erkenntnis dieser hygienischen Probleme ist man früh daran gegangen, bei der Befestigung der Borsten am Borstenträger Fügeverfahren aus der Kunststofftechnologie einzusetzen, um insbesondere Hohlräume am Borstenträger im Bereich des Borstenansatzes zu vermeiden. Hierzu zählt insbesondere das Verschweißen von Borsten und Borstenträger (EP 0 165 546) und das Einspritzen der Borsten in den Träger (DE 1 532 809). In Verbindung mit dem Verschweißen (EP 0 165 546) ist auch schon vorgeschlagen worden, den Borstenbesatz nicht nur aus Bündeln zu bilden, sondern daneben auch einzeln stehende Borsten in dichter Anordnung vorzusehen. Dabei wird insbesondere der Zweck verfolgt, den Borstenbesatz so zu gestalten, daß der bereichsweise unterschiedlich starken Abnutzung Rechnung getragen wird. Auch ist damit eine Anpassung der verschiedenen Bereiche des Borstenbesatzes an unterschiedliche Gebrauchsfunktionen (Reinigung, Massage od. dgl.) möglich.You are early to recognize these hygienic problems gone about fixing the bristles to the bristle holder Joining process from plastic technology to use, in particular, cavities on the bristle carrier to avoid in the area of the bristle attachment. That counts especially the welding of bristles and bristle carriers (EP 0 165 546) and the injection of the bristles into the Carrier (DE 1 532 809). In connection with welding (EP 0 165 546) has also already been proposed Bristle trimmings not only to form from bundles, but besides also standing bristles in a dense arrangement to provide. The main purpose is to design the bristle trim so that the area different degrees of wear and tear will be carried. It is also an adaptation of the various Areas of the bristle trim to different Utility functions (cleaning, massage or the like) possible.
Diesen unterschiedlichen Gebrauchsfunktionen trägt eine
andere bekannte Ausführung Rechnung (GB 2 035 076), bei
der im Längsmittelbereich des Borstenträgers Borstenbündel
angeordnet sind, während beiderseits des Längsmittelbereichs
Reihen von Kunststoffstiften unterschiedlicher
Gestaltung vorgesehen sind, wobei der Bürstenkopf außerdem
in Richtung beider Achsen gekrümmt ist. Auf diese
Weise sollen die Borsten nur an den Zahnpartien wirksam
werden, während die demgegenüber relativ weichen Kunststoffstifte
vornehmlich eine Massagewirkung auf die
Gingiva ausüben sollen. Abgesehen von der komplizierten
Fertigung einer solchen Zahnbürste, wird weder im Bereich
des Borstenbesatzes das hygienische Problem gelöst, noch
genügt sie modernen zahnmedizinischen Erkenntnissen für
eine effektive Reinigung der Zähne und eine ausreichende
Massage des Zahnfleischs, indem die Bürste nicht vom
Zahnfleisch zu den Zähnen (rot nach weiß) geführt werden
kann. One carries these different usage functions
other known execution invoice (
Die geschilderten hygienischen Probleme sollen bei einer weiteren bekannten Ausführung (EP 0 060 592) dadurch behoben werden, daß der Borstenbesatz nicht aus Bündeln, sondern aus Einzelborsten besteht, die am Träger und untereinander durch thermische Verfahren, insbesondere durch Lasertechnik miteinander verbunden werden. Dabei liegen die Borsten auch an ihrem trägerseitigen Ende frei, indem der Borstenträger eine große Aussparung entsprechend dem Umriß des Borstenbesatzes aufweist und die Borsten in diese Aussparung eingesetzt sind derart, daß sie an der Rückseite des Trägers freiliegen. Die Borsten selbst sollen untereinander nur im Bereich dieser Aussparung und nur im Bereich ihrer einander tangierenden Mantelflächen verbunden sein. Damit soll gewährleistet sein, daß zwischen den Borsten durchgehende Kapillaren verbleiben. Diese Kapillaren sollen es angeblich ermöglichen, Bakterien und Plaque-Reste abzusaugen. Wie dies im einzelnen geschehen soll und welche physikalischen Kräfte hierfür anzuwenden sind, läßt die Druckschrift offen. Entscheidend ist aber, daß die Borsten an den Mantelflächen einander anliegen müssen, um sie an den Mantelflächen miteinander verbinden zu können. Dies bedeutet aber, daß letztendlich die gleiche enge Borstenpackung vorhanden ist, wie in einem Bündel, denn auch dort liegen die Borsten an den Mantelflächen nur linienförmig einander an. Es bilden sich also die gleichen Kapillaren aus, wie bei einem Borstenbündel. Hinzukommt, daß das Einnisten und Wachstum von Bakterien nicht nur an einer Seite, sondern an beiden Seiten des Borstenträgers möglich ist.The described hygienic problems should be with one further known embodiment (EP 0 060 592) that the bristle trimmings are not made up of bundles, but consists of individual bristles on the carrier and with each other by thermal processes, in particular connected with each other by laser technology. Here the bristles also lie at their end on the carrier side free by making the bristle holder a large recess according to the outline of the bristle trim and the bristles are inserted into this recess in such a way that they are exposed at the back of the carrier. The Bristles themselves should only be in the area of these Recess and only in the area of their tangent Lateral surfaces to be connected. This is to ensure be that continuous capillaries between the bristles remain. These capillaries are said to enable Aspirate bacteria and plaque residues. Like this should happen in detail and what physical Forces are to be applied for this, the publication open. It is crucial, however, that the bristles on the Shell surfaces must be in contact with each other in order to To be able to connect lateral surfaces with one another. This but means that ultimately the same tight bristle pack is present, as in a bundle, because too there the bristles lie only linearly on the lateral surfaces each other. So the same are formed Capillaries, like a bundle of bristles. Come in addition, that the nesting and growth of bacteria doesn't just start one side, but on both sides of the bristle holder is possible.
Bei einer anderen bekannten Ausführung für beliebige Bürsten (WO 82/00406) werden einzelne Borsten mit Abstand voneinander auf einem Trägerband aufgeklebt, wobei die Borsten in der Ebene des Trägerbandes liegen und dieses an einer Kante überragen. An dem überragenden Ende jeder Borste wird durch Erhitzen eine Verdickung angeformt. Das Trägerband wird dann zu einem Formkörper gewickelt und der Wickel mit den freien Borstenenden voraus in eine Form getaucht, die zuvor mit einer flüssigen Kunststoffmasse ausgegossen wurde, um auf diese Weise den Bürstenkörper zu bilden. Das außerhalb der Form liegende Trägerband wird nach Zugabe eines Lösungsmittels für den Klebstoff abgezogen, wodurch die zunächst am Trägerband festgeklebten Borsten freigelegt werden. Anschließend wird der ausgehärtete Bürstenkörper aus der Form entnommen. Dieses Verfahren ist außerordentlich arbeits- und zeitaufwendig und ist mit den heutigen Anforderungen an eine automatische Serienfertigung in keiner Weise vereinbar.In another known version for any Brushes (WO 82/00406) become individual bristles at a distance glued from each other on a carrier tape, the Bristles lie in the plane of the carrier tape and this protrude at an edge. At the towering end of everyone Bristles are thickened by heating. The Carrier tape is then wound into a shaped body and the wrap with the free bristle ends ahead in one Mold dipped previously with a liquid plastic mass was poured out in this way the brush body to build. The carrier tape outside the form after adding a solvent to the adhesive subtracted, which initially on the carrier tape stuck bristles are exposed. Subsequently the hardened brush body is removed from the mold. This process is extremely labor and time consuming and is in line with today's requirements automatic series production is in no way compatible.
Die Auszugsfestigkeit der Borsten an dem fertigen Erzeugnis wird zwar durch die Verdickung an dem eingebetteten Borstenende günstig beeinflußt, doch ist die Einbettung auf der übrigen Länge der Borsten nicht hinreichend gewährleistet. Beim Eintauchen der Verdickung weicht die Kunststoffmasse aufgrund der Oberflächenspannung aus. Selbst wenn sie bei ausreichend niedriger Viskosität hinter der Verdickung wieder zurückfließt, verbleibt aufgrund der Oberflächenspannung um die Borste eine kraterförmige Vertiefung, in deren Bereich die Borste nicht eingebettet ist. Um die notwendige Auszugsfestigkeit zu erreichen, muß die Einbettungslänge entsprechend groß sein. Unabhängig davon bleibt das Problem bestehen, daß sich in der kraterförmigen Vertiefung Verunreinigungen sammeln und Bakterien einnisten.The pull-out strength of the bristles on the finished product is due to the thickening of the embedded Bristle end favorably influenced, but is the embedding not sufficient on the remaining length of the bristles guaranteed. When the thickening is immersed, it gives way Plastic mass due to the surface tension. Even if they have a sufficiently low viscosity flows back behind the thickening, remains due to the surface tension around the bristle crater-shaped depression, in the area of which the bristle is not embedded. To the necessary pull-out strength To achieve this, the embedding length must be appropriate be great. Regardless, the problem remains that there are impurities in the crater-shaped depression collect and nest bacteria.
Der Erfindung liegt die Aufgabe zugrunde, Borstenwaren, deren Borstenbesatz aus einzeln stehenden Borsten besteht, dahingehend weiterzuentwickeln, daß ein schnelles Abtrocknen der Bürste gewährleistet ist und auf diese Weise dem Einnisten und Wachstum von Bakterien und der Einlagerung von Verunreinigungen erfolgreich begegnet wird, andererseits eine freie Gestaltungsmöglichkeit für die Borstengeometrie gegeben ist, die die Erzielung unterschiedlicher Gebrauchseigenschaften gestattet.The invention has for its object bristle goods, their bristle trimmings from individually standing bristles, to further develop that ensures a quick drying of the brush and thus nesting and growth of bacteria and the storage of contaminants is successfully met, on the other hand a free one Design options for the bristle geometry given is the achievement of different usage properties allowed.
Diese Aufgabe wird erfindungsgemäß dadurch gelöst, daß der Borstenbesatz aus einzeln und eng stehenden, einander nicht berührenden Borsten besteht, deren Abstand voneinander im Bereich des 0,5-fachen bis 4,0-fachen des Borstendurchmessers liegt und die durch Umspritzen im Borstenträger befestigt und im Borstenträger auf einer Länge eingebettet sind, die kleiner als der 4-fache Borstendurchmesser ist.This object is achieved in that the bristle trimmings of individually and closely related, each other there are non-contacting bristles, the distance from each other in the range of 0.5 times to 4.0 times the Bristle diameter is and by overmolding in Bristle holder attached and in the bristle holder on one Length embedded are less than 4 times Bristle diameter is.
Die heutige Kunststofftechnologie ermöglicht ein übergangsloses Befestigen auch einzelner Borsten kleinen Durchmessers auf einer ebenen Fläche, nämlich der des Borstenträgers. Dies geschieht im Wege des Spritzgießens durch Umspritzen der Borstenenden mit der Kunststoffmasse. Durch den Spritzdruck beim Umspritzen der Borsten ist gewährleistet, daß es um die Borste herum keine Vertiefung bildet, die Borste vielmehr auf der gesamten Einbettungslänge im Borstenträger fest umschlossen ist. Hinzukommt, daß die Spritzgießmasse aufgrund des Spritzdrucks in stets vorhandene Oberflächenrauhigkeiten der Borste eindringt, was zur besseren Verankerung der Borste beiträgt. Die notwendige Auszugsfestigkeit läßt sich also mit einer minimalen Einbettungslänge erreichen, die in einem Bereich liegt, der kleiner als das Vierfache des Borstendurchmessers ist. Gerade bei Einzelborsten kann -im Gegensatz zu Bündeln- das Entstehen von Ausnehmungen, Vertiefungen od. dgl. vermieden werden, wohingegen bei Bündeln wegen der größeren aufzuschmelzenden Masse und/oder der unkontrollierbaren Abkühlung aufgrund eben dieser größeren Massen eine glatte Trägeroberfläche kaum zu erzielen ist. Hinzu kommt, daß bei Bündeln eine ausreichende Auszugsfestigkeit nur dann gewährleistet ist, wenn alle Borsten eines Bündels am befestigungsseitigen Ende aufgeschmolzen und miteinander verbunden werden, wodurch sich eine Verdickung bildet, die wegen ihrer entsprechenden Masse zu den vorgenannten negativen Effekten führt. Diese Nachteile treten bei Einzelborsten im Bereich ihrer Befestigung nicht auf. Hinzu kommt, daß die Einzelborsten in einem solchen Abstand im Bereich des 0,5- bis 4-fachen des Borstendurchmessers voneinander angeordnet werden können, daß zwischen den Borsten sich weder Bakterien einnisten, noch dort vermehren können und sich ferner Schmutz (Plaque-, Pflegemittel- oder Auftragsmittelreste) nicht festsetzen können. Die Zwischenräume lassen sich problemlos ausspülen.Today's plastic technology enables seamless Fasten even small bristles Diameter on a flat surface, namely that of Bristle carrier. This is done by injection molding by overmolding the bristle ends with the plastic mass. Due to the injection pressure when molding the bristles ensures that there is no recess around the bristle rather, the bristle forms over the entire embedding length is firmly enclosed in the bristle holder. Come in addition, that the injection molding compound due to the injection pressure in the existing surface roughness of the bristle penetrates, which contributes to better anchoring of the bristle. The necessary pull-out strength can thus be with a minimum embedding length that is in an area that is less than four times the Bristle diameter. Especially with single bristles - in contrast to bundles - the formation of recesses, Wells or the like can be avoided, whereas at Bundling because of the larger mass to be melted and / or the uncontrollable cooling due to these larger masses hardly a smooth support surface can be achieved. Add to that that with bundles sufficient Pull-out strength is only guaranteed if all bristles of a bundle on the fastening side Melted end and connected together, which forms a thickening due to its corresponding mass to the aforementioned negative effects leads. These disadvantages occur with single bristles Area of their attachment not on. In addition, the Individual bristles at such a distance in the area of Arranged 0.5 to 4 times the bristle diameter from each other can be that between the bristles neither Bacteria nest, can still multiply there and grow also dirt (plaque, care agent or application agent residues) cannot fix. The gaps can be easily rinsed out.
Eine solchermaßen aufgebaute Bürste trocknet in kurzer Zeit ab, womit den genannten Gefahren gleichfalls wirksam begegnet ist. Hinzu kommt, daß auch die Borste selbst keine oder allenfalls wenig Flüssigkeit aufnimmt und diese beim Abtrocknen wieder abgibt, so daß sie nach dem Gebrauch in kurzer Zeit wieder ihre ursprünglichen Festigkeitseigenschaften zurückgewinnt. Durch den wenn auch kleinen Abstand der Borsten entstehen Kanäle, die zur Aufnahme und Halterung von flüssigen bis pastösen Auftragsmitteln, z.B. Farben, Lacken, Wimperntusche, oder von Reinigungs- und Poliermitteln, wie Zahnpasten, Gelen, Polierpasten od. dgl. dienen.A brush constructed in this way dries quickly Time from which the dangers mentioned are also effective met. In addition, the bristle itself absorbs little or no liquid at all and releases these when drying, so that after the Use their original in a short time Strength properties regained. By the if even small distances between the bristles create channels that for holding and holding liquid to pasty Order resources, e.g. Paints, varnishes, mascara, or of cleaning and polishing agents, such as toothpastes, gels, Serve polishing pastes or the like.
Die jeweiligen Gebrauchseigenschaften werden ausschließlich durch die Geometrie der Borsten selbst (Durchmesser und Länge) und deren Werkstoff (Polyamid, Polyester etc.) sowie durch die Geometrie der Anordnung (mehr oder weniger dicht, jedenfalls aber stets mit Abstand) bestimmt.The respective usage properties are exclusive by the geometry of the bristles themselves (diameter and length) and their material (polyamide, polyester etc.) as well as the geometry of the arrangement (more or less tight, but in any case always at a distance).
Die Gebrauchseigenschaften und die Erzielung bestimmter Reinigungs- und/oder Massagewirkungen ist ferner dadurch möglich, daß die einzelnen Borsten oder Gruppen von Einzelborsten unterschiedliche Länge aufweisen und ihre freien Enden auf einer gekrümmten oder gestuften Hüllfläche liegen.The performance characteristics and the achievement of certain This also has cleaning and / or massage effects possible that the individual bristles or groups of Individual bristles have different lengths and their free ends on a curved or stepped envelope surface lie.
Mit dieser Ausbildung wird insbesondere gewährleistet, daß beispielsweise bei Zahnbürsten einzelne längere Borsten wirksam in die beispielsweise Interdentalräume eindringen, während die kürzeren Borsten an den Zahnflächen wirksam werden. Die unterschiedlich langen Borsten führen bei der Reinigungsbewegung auch zum unterschiedlichen Ausfedern und Rückspringen der Borsten beim Gleiten über die Zahnflächen, während die kürzeren Borsten eher mit ihren Enden wirksam werden. Dadurch läßt sich ein mehr oder weniger kratzender bzw. streichender Effekt erreichen. Auch dies kann wiederum durch unterschiedliche Abstände der Borsten innerhalb des Borstenbesatzes unterstützt werden, womit ein unterschiedliches Ausfedern und Rückfedern der Borsten verbunden ist. Die Steifigkeit des gesamten Borstenbesatzes läßt sich nicht allein durch die Dimensionierung der Borste (Durchmesser, Länge) und den Werkstoff, sondern vor allem auch durch den Abstand der Borsten in feinen Abstufungen variieren.This training ensures in particular that that, for example, with toothbrushes some longer Bristles are effective in, for example, interdental spaces penetrate while the shorter bristles on the tooth surfaces be effective. The bristles of different lengths also lead to different in the cleaning movement Spring out and spring back of the bristles Glide over the tooth surfaces while the shorter bristles rather take effect with their ends. This leaves a more or less scratching or stroking Achieve effect. Again, this can be done through different Distances of the bristles within the bristle stock are supported, with which a different Rebound and rebound of the bristles is connected. The Rigidity of the entire bristle trim cannot be achieved solely by dimensioning the bristle (diameter, Length) and the material, but especially by the distance between the bristles varies in fine increments.
Es können die Borsten auch zu Gruppen zusammengefaßt sein und der Abstand der Borsten einer Gruppe gleich, jedoch von dem der anderen Gruppe verschieden sein. So kann beispielsweise bei einer Zahnbürste der Kopf- oder Randbereich eine größere Borstendichte aufweisen als der mittlere Bereich.The bristles can also be combined into groups and the distance of the bristles of a group is the same, however be different from that of the other group. So can for example, the head or edge area of a toothbrush have a greater bristle density than that middle range.
Wie schon angedeutet, können die Borsten auch unterschiedliche Steifigkeit, z.B. unterschiedliche Durchmesser, aufweisen, wobei auch hier wieder Borstengruppen unterschiedlicher, innerhalb der Gruppe aber gleicher Steifigkeit vorgesehen sein können.As already indicated, the bristles can also be different Stiffness, e.g. different diameters, have bristle groups different, but the same within the group Stiffness can be provided.
Es ist an sich bekannt, Monofile für Borsten mit strukturierten Oberflächen, abrasiv wirkenden Einlagerungen, außenseitiger Beflockung etc. auszustatten oder aber die Monofile zu profilieren, z.B. zu wellen od. dgl., um andere oder zusätzliche Reinigungseffekte zu erreichen, die mit dem einfachen linearen oder glattwandigen Monifil nicht möglich sind. Diese Maßnahmen kommen bei einem Bündel aufgrund der Anlage der Borsten aneinander nur unzureichend zur Wirkung. Anders bei der erfindungsgemäß ausgebildeten Bürste mit einzeln stehenden Borsten, da hier größere Teile der Mantelfläche im Bereich der freien Enden während der Reinigungsbewegung wirksam werden.It is known per se, monofilaments for bristles with structured Surfaces, abrasive deposits, outside flocking etc. or the Profiling monofilaments, e.g. to wave or the like to to achieve other or additional cleaning effects, the one with the simple linear or smooth-walled Monifil are not possible. These measures come with one Bundles due to the abutment of the bristles only insufficient to effect. Different with the invention trained brush with individually standing bristles, because here larger parts of the lateral surface in the area of the free Ends take effect during the cleaning movement.
Schließlich ist es bekannt (EP 0 471 312) die Borsten eines Bündels an ihrem freien Ende zu formen, insbesondere mit einer sphärischen Verdickung zu versehen. Auch die hiermit angestrebten besonderen Effekte werden durch den dichten Borstenstand im Bündel nur unzureichend verwirklicht, wohingehen bei der erfindungsgemäßen Bürste das freie Ende der Einzelborste ungehindert zur Wirkung kommt, so daß die Formgebung des freien Endes, z.B. durch Verrunden, Konifizieren oder Anbringen einer sphärischen Verdickung, ihre Wirkung voll entfalten kann.Finally, it is known (EP 0 471 312) the bristles to form a bundle at its free end, especially to be provided with a spherical thickening. Also the hereby desired special effects are achieved by the insufficient bristle stand in the bundle, where in the brush according to the invention free end of the individual bristles unimpeded for effect comes so that the shape of the free end, e.g. by Rounding, conifying or attaching a spherical Thickening, their effect can develop fully.
In vorteilhafter Ausführung sind die Borsten an dem Borstenträger auf einer Länge eingebettet, die etwa dem 1,5-fachen des Borstendurchmessers entspricht. Durch die geringe Einbettungslänge ergibt sich der große Vorteil, daß die Bauhöhe des Borstenträgers sehr gering sein kann, was beispielsweise bei Zahnbürsten, insbesondere Kinderzahnbürsten von großer Wichtigkeit ist.In an advantageous embodiment, the bristles on the Bristle holder embedded on a length that is about that Corresponds to 1.5 times the bristle diameter. Through the small embedding length gives the big advantage that the overall height of the bristle carrier can be very low, what for example with toothbrushes, especially children's toothbrushes is of great importance.
Der Abstand der Borsten voneinander wird üblicherweise das 1,5- bis 2-fache des Borstendurchmessers betragen. Vorzugsweise kann der Abstand aber auch kleiner als der Borstendurchmesser sein.The distance between the bristles from each other is usually 1.5 to 2 times the Bristle diameter. Preferably, the Distance but also smaller than the bristle diameter be.
Nachstehend ist die Erfindung anhand von in der Zeichnung wiedergebenen Ausführungsbeispielen beschrieben. In der Zeichnung zeigen:
- Figur 1:
- eine schematische Darstellung eines Ausschnittes einer Bürste;
Figuren 2 bis 5:der Figur 1 ähnliche Ansichten einiger weiterer Ausführungsbeispiele;Figuren 6 bis 8:- je eine vergrößerte Ansicht einer Einzelborste im Bereich des nutzungsseitigen Endes;
- Figuren 9 bis 11:
- je einen Teilschnitt einer Einzelborste;
- Figure 1:
- a schematic representation of a section of a brush;
- Figures 2 to 5:
- 1 similar views of some other embodiments;
- Figures 6 to 8:
- each an enlarged view of a single bristle in the area of the end on the use side;
- Figures 9 to 11:
- each a partial section of a single bristle;
Bei dem Ausführungsbeispiel gemäß Figur 2 besteht der
Borstenbesatz aus Einzelborsten unterschiedlicher Länge,
nämlich kürzeren Borsten 4 und längeren Borsten 5, die
gegebenenfalls gruppenweise angeordnet sind.In the exemplary embodiment according to FIG
Bristles with individual bristles of different lengths,
namely
Die Ausführungsform nach Figur 3 weist am Borstenträger 1
wiederum unterschiedlich lange Borsten 2 auf, die in
diesem Fall gleichmäßig abgestuft sind.The embodiment according to FIG. 3 has on the
Während bei den vorgenannten Ausführungsbeispielen die
Borsten 2 abstandsgleich angeordnet sind, zeigt Figur 4
eine Ausführungsform, bei dem die einzeln stehenden
Borsten wieder gruppenweise angeordnet sind, wobei sie
innerhalb der Gruppe gleichen Abstand aufweisen. So sind
die Borsten 6 auf einem größeren, die Borsten 7 hingegen
auf einem kleineren Abstand angeordnet.While in the
Figur 5 zeigt ein Ausführungsbeispiel mit Borsten 8
kleineren Querschnittes und Borsten 9 größeren Querschnittes,
wobei jeweils die dünneren und die dickeren
Borsten untereinander in gleichem Abstand angeordnet
sind.FIG. 5 shows an embodiment with
Figur 6 zeigt eine vergrößerte Teilansicht einer Einzelborste
mit zylindrischem Querschnitt und einer sphärisch
verrundeten Kuppe 10, die das nutzungsseitige Ende bildet.
Bei dem Ausführungsbeispiel gemäß Figur 7 ist das
nutzungsseitige Ende 11 konisch geformt, während Figur 8
eine Borste 2 mit einer kugelförmigen Verdickung am
nutzungsseitigen Ende zeigt. Dadurch, daß die Borsten
einzeln stehend angeordnet sind, kann -im Gegensatz zur
bündelweisen Anordnung- das nutzungsseitige Ende mit
seiner gesamten konturierten Oberfläche und auch der
Mantelfläche wirksam werden.Figure 6 shows an enlarged partial view of a single bristle
with a cylindrical cross section and a spherical one
rounded
Figur 9 zeigt eine Borste 2 mit konturierter Oberfläche
13 mit gegebenenfalls abrasiver Wirkung, die wiederum
durch die solitäre Anordnung der einzelnen Borsten ihre
Wirksamkeit auf einer großen Länge entfalten kann. Bei
dem Ausführungsbeispiel gemäß Figur 10 besteht die Borste
2 aus einem Schaft 14 z.B. aus Kunststoff, und einer
beispielsweise abrasiven Beschichtung 15. Im Gegensatz
dazu zeigt Figur 11 eine Ausführungsform, bei der der
Schaft 14 der Borste 2 mit feinen Fasern 16 beflockt ist.FIG. 9 shows a bristle 2 with a
Claims (10)
- Brushware, e.g. brush, paintbrush, etc., which is exposed to moisture during use and which has a bristle carrier and a bristle facing comprising single, closely juxtaposed, non-contacting plastic bristles, whose mutual spacing is 0.5 to 4.0 times the bristle diameter and which are fixed in the bristle carrier by moulding and are embedded in the bristle carrier (1) to a length smaller than 4 times the bristle diameter.
- Brushware according to claim 1, characterized in that the single bristles (2) or groups (4, 5; 6, 7) of single bristles have different lengths and their free ends are located on a curved or stepped envelope surface.
- Brushware according to claim 1 or 2, characterized in that, within the overall bristle facing, the bristles (6, 7) have different mutual spacings.
- Brushware according to claim 3, characterized in that at least two groups of bristles (6, 7) are provided and the spacing of the bristles (6) within a group is the same, but differs from that of the other group (7).
- Brushware according to one of the claims 1 to 4, characterized in that the bristles (8, 9) have a different stiffness, e.g. different diameter.
- Brushware according to claim 5, characterized in that at least two groups of bristles (8, 9) are provided and the stiffness of the bristles of one group is the same, but different from that of the other group.
- Brushware according to one of the claims 1 to 6, characterized in that at least part of the bristles (2) are structured (13), flocked (16) or coated (15) on their circumferential surface.
- Brushware according to one of the claims 1 to 7, characterized in that the bristles (2) are shaped on their free ends, e.g. rounded (10), given a conifer shape (11) or provided with a spherical thickening (12).
- Brushware according to claim 1, characterized in that the bristles (2) are embedded on the bristle carrier (1) over a length representing approximately 1.5 times the bristle diameter.
- Brushware according to one of the claims 1 to 9, characterized in that the bristles (2) are given a mutual spacing smaller than the bristle diameter.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19507364 | 1995-03-03 | ||
DE19507364A DE19507364A1 (en) | 1995-03-03 | 1995-03-03 | Brush, in particular hygiene brush |
PCT/EP1996/000822 WO1996027308A1 (en) | 1995-03-03 | 1996-02-29 | Article with bristles, such as brush, paint brush or the like |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0813374A1 EP0813374A1 (en) | 1997-12-29 |
EP0813374B1 true EP0813374B1 (en) | 1999-07-14 |
Family
ID=7755486
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96905823A Expired - Lifetime EP0813374B1 (en) | 1995-03-03 | 1996-02-29 | Article with bristles, such as brush, paint brush or the like |
Country Status (23)
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US (1) | US5974619A (en) |
EP (1) | EP0813374B1 (en) |
JP (1) | JPH11500946A (en) |
KR (1) | KR100409097B1 (en) |
CN (1) | CN1105530C (en) |
AT (1) | ATE182057T1 (en) |
AU (1) | AU704531B2 (en) |
BR (1) | BR9607533A (en) |
CA (1) | CA2214405C (en) |
CZ (1) | CZ286851B6 (en) |
DE (2) | DE19507364A1 (en) |
DK (1) | DK0813374T3 (en) |
EA (1) | EA001737B1 (en) |
ES (1) | ES2134595T3 (en) |
FI (1) | FI109082B (en) |
GR (1) | GR3031536T3 (en) |
HU (1) | HUP9800050A3 (en) |
IN (1) | IN188069B (en) |
NO (1) | NO318183B1 (en) |
PL (1) | PL182350B1 (en) |
UA (1) | UA44768C2 (en) |
WO (1) | WO1996027308A1 (en) |
ZA (1) | ZA961693B (en) |
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DE7906716U1 (en) * | 1979-03-10 | 1979-06-07 | Schulze & Stelzner Gmbh, 2400 Luebeck | BRUSH FOR CLEANING CASTING MOLDS |
US4373541A (en) * | 1979-08-07 | 1983-02-15 | Nishioka Gary J | Bristle structure for brushes and brush assembly |
US4366592A (en) * | 1980-08-06 | 1983-01-04 | Bromboz Jonathan J | Brushes and method of making same |
LU83225A1 (en) * | 1981-03-18 | 1983-02-22 | Argembeau Etienne D | IMPROVEMENTS ON BRUSHES |
DE3116189A1 (en) * | 1981-04-23 | 1982-12-23 | Bodo 2000 Hamburg Jesse | Profiled bristles for toothbrushes and brushes of any kind |
US4610045A (en) * | 1982-04-21 | 1986-09-09 | Samuel Rauch | Toothbrush |
DE3247125A1 (en) * | 1982-12-20 | 1984-06-20 | Braun Ag, 6000 Frankfurt | Brush, especially attachable brush for an electric toothbrush |
US4804004A (en) * | 1983-03-18 | 1989-02-14 | Taylor Charles H | Molded mascara applicator |
CH661851A5 (en) * | 1983-03-22 | 1987-08-31 | Trisa Buerstenfabrik Ag | HAIR CARE DEVICE WITH BRUSH OR COMB TEETH IN PLASTIC. |
DE3422623A1 (en) * | 1984-06-19 | 1985-12-19 | Coronet - Werke Heinrich Schlerf Gmbh, 6948 Wald-Michelbach | TOOTHBRUSH |
DE3524586A1 (en) * | 1985-07-10 | 1987-01-15 | Blendax Werke Schneider Co | Tooth brush |
US4766633A (en) * | 1987-05-18 | 1988-08-30 | Clark Quentin S | Tooth and sulcus brush |
DE3717475A1 (en) * | 1987-05-23 | 1988-12-08 | Schlerf Coronet Werke | BRISTLE PRODUCT AND METHOD FOR THEIR PRODUCTION |
DE3835379A1 (en) * | 1988-10-18 | 1990-04-26 | Gerhard Schmehling | Toothbrush |
AU647782B2 (en) * | 1990-03-29 | 1994-03-31 | Colgate-Palmolive Company, The | Toothbrush |
MY109803A (en) * | 1990-08-13 | 1997-07-31 | Kao Corp | Toothbrush using such apparatus |
US5249327A (en) * | 1992-08-26 | 1993-10-05 | Marilyn O. Hing | String and ribbon floss holder for brushes |
DE4231515B4 (en) * | 1992-09-21 | 2008-04-24 | Anton Zahoransky Gmbh & Co. | Apparatus for making brushes |
US5398367A (en) * | 1993-12-27 | 1995-03-21 | Lu; Guixian | Toothbrush with both soft and hard bristles |
US5604951A (en) * | 1994-12-30 | 1997-02-25 | Shipp; Anthony D. | Prophy toothbrush |
-
1995
- 1995-03-03 DE DE19507364A patent/DE19507364A1/en not_active Withdrawn
-
1996
- 1996-02-29 DK DK96905823T patent/DK0813374T3/en active
- 1996-02-29 KR KR1019970706146A patent/KR100409097B1/en not_active IP Right Cessation
- 1996-02-29 CZ CZ19972476A patent/CZ286851B6/en not_active IP Right Cessation
- 1996-02-29 JP JP8526579A patent/JPH11500946A/en active Pending
- 1996-02-29 AT AT96905823T patent/ATE182057T1/en not_active IP Right Cessation
- 1996-02-29 UA UA97104892A patent/UA44768C2/en unknown
- 1996-02-29 CA CA002214405A patent/CA2214405C/en not_active Expired - Fee Related
- 1996-02-29 DE DE59602439T patent/DE59602439D1/en not_active Expired - Fee Related
- 1996-02-29 ES ES96905823T patent/ES2134595T3/en not_active Expired - Lifetime
- 1996-02-29 EA EA199700207A patent/EA001737B1/en not_active IP Right Cessation
- 1996-02-29 CN CN96192187A patent/CN1105530C/en not_active Expired - Fee Related
- 1996-02-29 US US08/894,380 patent/US5974619A/en not_active Expired - Fee Related
- 1996-02-29 HU HU9800050A patent/HUP9800050A3/en unknown
- 1996-02-29 BR BR9607533A patent/BR9607533A/en not_active IP Right Cessation
- 1996-02-29 EP EP96905823A patent/EP0813374B1/en not_active Expired - Lifetime
- 1996-02-29 AU AU49433/96A patent/AU704531B2/en not_active Ceased
- 1996-02-29 WO PCT/EP1996/000822 patent/WO1996027308A1/en active IP Right Grant
- 1996-02-29 PL PL96322049A patent/PL182350B1/en not_active IP Right Cessation
- 1996-03-01 IN IN381CA1996 patent/IN188069B/en unknown
- 1996-03-01 ZA ZA961693A patent/ZA961693B/en unknown
-
1997
- 1997-08-28 FI FI973548A patent/FI109082B/en active
- 1997-09-02 NO NO19974033A patent/NO318183B1/en unknown
-
1999
- 1999-10-14 GR GR990402623T patent/GR3031536T3/en unknown
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