EP0790395B1 - A method and a device for supplying fuel to an internal combustion engine - Google Patents

A method and a device for supplying fuel to an internal combustion engine Download PDF

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Publication number
EP0790395B1
EP0790395B1 EP97102329A EP97102329A EP0790395B1 EP 0790395 B1 EP0790395 B1 EP 0790395B1 EP 97102329 A EP97102329 A EP 97102329A EP 97102329 A EP97102329 A EP 97102329A EP 0790395 B1 EP0790395 B1 EP 0790395B1
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European Patent Office
Prior art keywords
fuel
pressure
reformed
components
supercritical
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EP97102329A
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German (de)
French (fr)
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EP0790395A3 (en
EP0790395A2 (en
Inventor
Mamoru Ishikiriyama
Sumio Kamiya
Makoto Hiei
Nobuaki Takazawa
Yasushi Takahashi
Syozi Miyazaki
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Toyota Motor Corp
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Toyota Motor Corp
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B51/00Other methods of operating engines involving pretreating of, or adding substances to, combustion air, fuel, or fuel-air mixture of the engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition

Definitions

  • the present invention relates to a method for supplying fuel to an internal combustion engine.
  • a fuel supply system for an internal combustion engine is required to supply liquid fuel to combustion chambers of the engine in the form of a very fine mist.
  • a direct cylinder injection system for injecting fuel into the combustion chamber directly such as the injection system of a diesel engine
  • the size of particles of the injected fuel largely affects the performance of the engine.
  • the combustion of the fuel in the combustion chamber, and thus the performance of the engine can be largely improved by reducing the size of the particles of the injected fuel.
  • a high pressure fuel injection in which fuel is injected from the fuel injection valve at a very high pressure, is effective in order to reduce the size of the particles of the injected fuel. Therefore, in recent fuel injection systems, the fuel injection pressure is set at a very high value in order to satisfy the requirement for low exhaust gas emission and low fuel consumption. For example, some of the fuel injection systems for diesel engines use a fuel injection pressure as high as more than 50 MPa (500 atm) to generate very fine particles of injected fuel in the combustion chamber.
  • US-A-5408 957 proposes a method in which gaseous fuel, which is stored in liquid form, is supplemented as a secondary fuel to a primary liquid fuel for assisting the vaporization of the primary fuel.
  • JP-A-55-007966 discloses a method of injecting a liquid fuel into an internal combustion engine by heating and pressurizing the fuel to a supercritical state just before being injected into a combustion chamber of the internal combustion engine.
  • the fuel although having gaseous characteristics, can be injected from an ordinary liquid fuel injection nozzle.
  • the object of the invention is to provide an alternative method for supplying fuel to an internal combustion engine which is capable of improving combustion of an internal combustion engine without using a very high fuel injection pressure.
  • liquid fuel is reformed on the vehicle by bringing the fuel into the supercritical state.
  • Liquid fuel such as diesel fuel
  • contains a relatively large amount of heavy components such as normal paraffin components and aromatic hydrocarbons having large molecular weights. These components, when burned in the combustion chamber, form particulate matter (carbon particles) in the exhaust gas. It is found that these heavy normal paraffin components are cracked at a relatively low temperature and produce light components such as normal paraffin having low molecular weight when the fuel is kept in the supercritical state. Therefore, in this aspect of the invention, liquid fuel containing a large amount of heavy components is reformed on the vehicle, and the reformed fuel which contains a large amount of light components is supplied to the combustion chamber of the engine. Therefore, the combustion of the engine is improved.
  • the reformed fuel may be supplied to the engine in the supercritical state.
  • the combustion of the engine is further improved due to the improvement in the atomization of the fuel and the increase in the amount of the light components in the supplied fuel.
  • an oxygen-containing substance when diesel fuel is used, an oxygen-containing substance may be added to the fuel before it reaches the supercritical state.
  • oxygen-containing substance means a substance such as water or methanol which contains oxygen or a hydroxyl group.
  • diesel fuel gas oil
  • the pressure is higher than 1.5 MPa. It is found that in these conditions, the heavy normal paraffin components in diesel fuel are cracked and produce lighter normal paraffin components. Further, the specific gravity and kinematic viscosity of the diesel fuel are largely lowered without changing the cetane number of the fuel by reforming the diesel fuel in these conditions. Therefore, by adding more than 1 percent weight of the reformed fuel to normal diesel fuel, the atomization of the fuel when injected into the combustion chamber is improved.
  • diesel fuel gas oil
  • the pressure is higher than 1.5 MPa. It was found that in these conditions, heavy normal paraffin components in the diesel fuel are cracked and produce lighter normal paraffin components without producing heavy alkylbenzene components. Also in this case, more than 1 percent by weight of the reformed fuel may be added to a normal diesel fuel.
  • the supercritical state is a state achieved by heating a substance above the critical temperature under a pressure higher than the critical pressure.
  • a liquid substance is pressurized and heated to the supercritical state, the phase of the substance changes from liquid to gas.
  • gas in the supercritical state has a very high density and, therefore, it shows physical characteristics very similar to liquid. Namely, when liquid is in the supercritical state, it becomes a supercritical fluid having physical characteristics between those of liquid and gas. Since the supercritical fluid has a very high density, it has a large energy and shows a unique behavior.
  • the supercritical fuel fluid when the supercritical fuel fluid is injected from a fuel injection valve into the combustion chamber which has a pressure and temperature lower than that of the supercritical state, a mist of fuel having particle sizes much smaller than those formed by the high pressure fuel injection is uniformly formed in the combustion chamber.
  • the temperature and/or pressure of the fluid becomes lower than the critical values. This causes the state of the fuel fluid to change from a supercritical to a subcritical in which the temperature or the pressure of the fuel fluid is lower than the critical value. Therefore, a part of the fuel fluid injected from the fuel injection valve changes to a normal gas state and diffuses throughout the entire combustion chamber.
  • the remaining part of the fuel fluid returns to a liquid state and forms a mist of fuel having very small particle size in the combustion chamber. Since the particles of fuel in the mist are formed by a change of phase (i.e., condensing), the size of the particles are very small compared to the size of the particles mechanically formed by high pressure fuel injection. In addition to that, since the injected supercritical fuel fluid, which has the characteristics of a gas, diffuses throughout the entire combustion chamber instantaneously, the formation of fine fuel particles by the above phase change (condensing) occurs simultaneously in the entire combustion chamber. Therefore, a very fine mist of fuel is uniformly formed in the entire combustion chamber.
  • the critical pressure of diesel fuel is relatively low (for example, generally lower than 10 MPa). This means that, by injecting fuel in the supercritical state, a uniform fine mist of fuel having a much smaller particle size compared to those in the high pressure fuel injection is obtained with much lower fuel pressure.
  • each of the fuel particles formed by the injection of supercritical fuel fluid have a high energy level due to latent heat released by the condensation and, therefore, readily react with oxygen.
  • the fine mist of fuel is uniformly formed in the entire combustion chamber by the injection of supercritical fuel fluid, sufficient oxygen is supplied to each fuel particle which is, as explained above, highly reactive. Therefore, the fuel in the combustion chamber is readily ignited and is burned completely, i.e., the combustion of the engine is largely improved and, thereby, both the exhaust gas emission and fuel consumption of the engine are reduced by the improvement of the combustion.
  • Fig. 3 is a graph illustrating the pressure and temperature conditions required to make diesel fuel reach the supercritical state.
  • diesel fuel is a mixture of normal paraffin (n-paraffin) having 11 to 20 carbon atoms and aromatic hydrocarbons (alkylbenzene) having 10 to 22 carbon atoms. Since the critical pressure and the critical temperature depend on the substance, each component of diesel fuel has different critical pressure and temperature.
  • Fig. 3 illustrates the change in the critical pressure and temperature of n-paraffin and alkylbenzene in accordance with the difference in the number of carbon atoms.
  • the vertical axis and the horizontal axis in Fig. 3 represent the critical pressure and the critical temperature of the respective components.
  • the critical pressure becomes lower as the number of carbon atoms is larger, and the critical temperature becomes higher as the number of carbon atoms is larger.
  • both the critical pressure and the critical temperature of the n-paraffin are generally lower than the same of the alkylbenzene.
  • the hatched portions A and B in Fig. 3 indicate the range of the numbers of carbon atoms of the n-paraffin components and the alkylbenzene components usually composing diesel fuel.
  • the region SC1 represents a pressure more than 3 to 6 MPa and a temperature more than 400 to 500°C.
  • the improvement of the combustion of the engine can be achieved even when only some of the components in diesel fuel reach a supercritical state.
  • the critical pressure becomes lower as the number of carbon atoms in the components increase while the critical temperature becomes higher as the number of carbon atoms in the components increase.
  • the pressure can be lowered when the temperature is maintained at high level.
  • combustion of the engine is improved, with a much lower fuel injection pressure compared to that of the high pressure fuel injection system, by injecting diesel fuel into combustion chambers in the supercritical state. Therefore, by injecting diesel fuel in the supercritical state, the pressure rating of the fuel injection pump can be largely lowered and, thereby, the cost of fuel injection pump can be lowered and the reliability thereof improved.
  • Fig. 4 shows the result of reforming of diesel fuel by the supercritical treatment.
  • the vertical axis represents the change in the concentrations of the n-paraffin components in diesel fuel caused by the supercritical treatment
  • the horizontal axis represents the number of carbon atoms in the respective n-paraffin components.
  • Fig. 4 shows the case where diesel fuel is held at the temperature between 400 and 500°C and the pressure between 4 and 5 MPa for about 20 minutes.
  • the concentrations of heavy n-paraffin components (number of carbon atoms is 13 or more) decrease and, at the same time, the concentrations of light n-paraffin components (number of carbon atoms is 12 or less) increase due to the supercritical treatment.
  • Fig. 6 shows the results of experiments in which diesel fuel is treated at various temperature and time under the pressure 1.5 MPa.
  • the letter C represents the case where no change of the concentrations of the components of the diesel fuel occurred by the treatment
  • the letter B represents the case where the amount of heavy n-paraffin components is slightly decreased by the treatment
  • the letter A represents the case where the amount of heavy n-paraffin components is decreased by the treatment.
  • diesel fuel is reformed (i.e., the heavy components in the diesel fuel decreases) when the temperature is more than 400°C.
  • Fig. 5 shows the change in the concentrations of alkylbenzene components in the same diesel fuel as Fig. 4 due to the supercritical treatment where the diesel fuel is kept at 600°C and 5 MPa for about 20 minutes.
  • the temperature in the supercritical treatment is high, light alkylbenzene components (the number of carbon atoms is 12 or less) increase due to the conversion of heavy n-paraffin components to light alkylbenzene components.
  • particulate matter in the exhaust gas of the engine increases as the alkylbenzene components or heavy n-paraffin components in diesel fuel increase.
  • the alkylbenzene components having the number of carbon atoms more than 12 increases the particulate matter in the exhaust gas. Therefore, it is not preferable that the heavy alkylbenzene components in diesel fuel increase by the supercritical reforming treatment.
  • Fig. 7 shows the results of experiments in which diesel fuel is treated at various temperature and time under a pressure of 5 MPa.
  • the letter C represents the case where the concentrations of the heavy alkylbenzene components of the diesel fuel are increased by the treatment
  • the letter B represents the case where the heavy alkylbenzene components are slightly increased by the treatment
  • the letter A represents the case where the heavy alkylbenzene components are not increased by the treatment.
  • the heavy alkylbenzene components increases when the temperature is higher than 550°C even the treatment time is 1 minute.
  • the treatment time which does not increase the heavy alkylbenzene components becomes longer.
  • an oxygen-containing substance such as water and methanol
  • the supercritical reforming treatment By applying the supercritical reforming treatment to diesel fuel after adding water or methanol by several percent to about twenty percent by weight, the conversion of decomposed heavy n-paraffin components to alkylbenzene components is suppressed. Further, it is known that small amounts of alkylbenzene components are produced by the combustion of n-paraffin components in diesel fuel.
  • the oxygen-containing substance to diesel fuel, the production of alkylbenzene components during the combustion of diesel fuel can be suppressed and, thus, the amount of the particulate matter in the exhaust gas can be reduced.
  • Fig. 8 shows changes in the physical properties of diesel fuel caused by the supercritical treatment.
  • Fig. 8 shows the physical properties of a normal diesel fuel (a gas oil which complies with JIS JTD-5) and the properties of the fuel obtained by reforming the same diesel fuel in the condition where the pressure is 5 MPa and the temperature is between 400 and 550°C.
  • the kinematic viscosity and flash point are lowered by the supercritical treatment while maintaining the same cetane number. This means that, when the reformed fuel is injected into the combustion chamber, it forms a fine mist (due to the lower kinematic viscosity) which readily ignites (due to the lower flash point) in the combustion chamber.
  • the reformed fuel can be used as an additive for the normal diesel fuel to promote initial combustion in the combustion chamber.
  • the concentration of the reformed fuel in the mixture should be more than 1 percent by weight, preferably more than 5 percent by weight.
  • Fig. 1 schematically illustrates the general configuration of a device which reforms diesel fuel in the storage tank 11 by supercritical treatment.
  • the reformed fuel is made into the supercritical state again and injected by a fuel injection valve into the respective combustion chambers of a diesel engine 1.
  • a supercritical reformer 31 and a first critical pressure pump 33 for feeding the fuel in the tank 11 to the supercritical reformer 31 are provided.
  • the reformed fuel is stored in a reformed fuel tank 35.
  • the first critical pressure pump 33 feeds the diesel fuel to the supercritical reformer 31 at a pressure higher than 1.5 MPa.
  • the supercritical reformer 31 is provided with a heater 31a and a heating passage 31b.
  • the fuel is heated by the heater 31a to a temperature higher than the critical temperature when it flows through the heating passage 31b, and reaches the supercritical state.
  • the flow velocity of the fuel in the heating passage 31b i.e., the time the fuel resides in the passage 31b is controlled by a flow control valve 37.
  • the capacity of the heater 31a and the flow of the fuel in the supercritical reformer 31 is selected so that the fuel is held within the heating passage 31b for about 1 to 20 minutes at a temperature between 400°C and 550°C.
  • Numeral 17 in Fig. 1 is a second critical pressure pump which feeds the reformed fuel from the reformed fuel tank 35 to a supercritical fuel injection pump 19 at a pressure higher than the critical pressure.
  • Numeral 18 is a supercritical state generating device which includes a heating device such as an electric heater 18b for heating the diesel fuel supplied from supercritical fuel injection pump 19 to the fuel injection valve 2 so that the temperature of the diesel fuel becomes higher than the critical temperature.
  • the reformed fuel in the reformed fuel tank is pressurized by the second critical pressure pump to, for example, 3 to 6 MPa and flows into a heating chamber 18a in the supercritical state generating device 18 through a fuel passage 19h disposed in the body 19a of the supercritical fuel injection pump 19, as explained later. Then, the fuel in the heating chamber 18a is heated by the heater 18b to a temperature higher than the critical temperature (for example, 400 to 500°C) and reaches the supercritical state. When a fuel injection timing occurs, the fuel in the heating chamber 18a is further pressurized by a plunger 19b of the supercritical fuel injection pump 19. When the pressure in the heating chamber 18a becomes higher than an opening pressure of the fuel injection valve 2, fuel in the supercritical state is injected from the fuel injection valve 2 and forms an extremely fine uniform fuel mist in the combustion chamber of the engine 1.
  • Fig. 2 shows a general construction of the supercritical fuel injection pump 19 in Fig. 1.
  • 19d is a cylinder of the supercritical fuel injection pump
  • 19c is a solenoid actuator which is mounted on the cylinder 19d
  • 19a is a spool disposed in the cylinder 19d.
  • 19b is a plunger which is driven by a camshaft (not shown) of the engine 1 and reciprocates within the cylinder
  • 19e in Fig. 2 is a pressure chamber defined in the cylinder 19d by the spool 19a and the plunger 19b. The stroke of the plunger is adjusted by a governor (not shown) in accordance with the load of the engine 1.
  • the spool 19a is held at a downward position as shown in Fig. 2 by the solenoid 19c. This causes the fuel from the critical pressure pump 17 to flow directly into the heating chamber 18a of the supercritical state generating device 18 through the pipe 21, the port 21a of the cylinder 19d, the fuel passage 19h of the spool 19a, the port 24a and the pipe 24. Fuel is also fed from the critical pressure pump 17 to the pressure chamber 19e through the pipes 22 and 22a. After the plunger 19b reaches a position of the port 23a during its downward stroke, excess fuel is returned to the storage tank 11 through the port 23a and the return pipe 23.
  • the return pipe 23 is provided with a cooling water jacket 23b for cooling the fuel flowing through the pipe 23.
  • the ports 23a and 22a are closed by the plunger 19b and the pressure of the fuel in the pressure chamber 19e increases.
  • the spool 19a is moved to an upward position by the solenoid 19c.
  • the fuel passage 19h is closed, and another fuel passage 19j is connected to the port 24a. Therefore, the fuel in the pressure chamber 19e which is pressurized by the upward motion of the plunger 19b flows into the heating chamber 18a of the supercritical state generating device 18. This causes the pressure in the heating chamber 18a to increase further.
  • the passage 19j is provided with check valve 19k for preventing the backflow of the pressurized fuel from the heating chamber 18a to the pressure chamber 19e.
  • the time the fuel resides in the heating chamber 18a can be arbitrary set by selecting the volume of the heating chamber 18a. Therefore, the residence time can be set long enough to assure that the fuel is heated to the temperature higher than the critical temperature by the heater 18b.
  • a liquid fuel in the supercritical state can be injected into the combustion chamber of the engine by the fuel injection system in Figs. 1 and 2.
  • the opening pressure of the fuel injection valve 2 and the temperature in the heating chamber 18a is higher than the pressure and the temperature which can make all the components in the fuel reach the supercritical state (for example, a temperature higher than 500°C and a pressure higher than 6 MPa.
  • the temperature and pressure conditions are set so that only some of the components in the fuel reach the supercritical state, it is possible to form a very fine mist in the combustion chamber.
  • all the devices required for reforming the fuel are disposed on the fuel path between the fuel storage tank 11 and the fuel injection valve 2. Therefore, when the system in Fig. 2 is applied to an engine for a vehicle, normal liquid fuel supplied to the vehicle can be reformed on the vehicle. This feature is especially advantageous because a normal fuel can be supplied to the vehicle and a facility for supplying the special (reformed) fuel to the vehicle is not required.
  • the reformed fuel is injected from the fuel injection valve in the supercritical state in this embodiment.
  • the combustion of the engine is largely improved even if the reformed fuel is injected in a normal state (i.e., at a lower fuel injection pressure).
  • a certain amount of the fuel may be reformed at a time.
  • a shutoff valve which may be opened and closed by a timer is provided instead of flow control valve 37 to hold a certain amount of the fuel within the supercritical reformer 31 for a predetermined time.
  • the shutoff valve is opened to drain the reformed fuel in the reformer 31 to the reformed fuel tank 35.
  • the oxygen-containing substance such as water or ethanol may be added to the fuel in the storage tank 11 in order to suppress the production of alkylbenzene components during the reforming and combustion of the reformed fuel.
  • the combustion in the combustion chamber of the engine is improved and, thereby, the exhaust gas emission and the fuel consumption of the engine are reduced at the same time by injecting and/or reforming liquid fuel in the supercritical state without using a very high fuel injection pressure.

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  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
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  • General Engineering & Computer Science (AREA)
  • Fuel-Injection Apparatus (AREA)
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Description

    BACKGROUND OF THE INVENTION 1. Field of the Invention
  • The present invention relates to a method for supplying fuel to an internal combustion engine.
  • 2. Description of the Related Art
  • In general, a fuel supply system for an internal combustion engine is required to supply liquid fuel to combustion chambers of the engine in the form of a very fine mist. Especially, in a direct cylinder injection system for injecting fuel into the combustion chamber directly, such as the injection system of a diesel engine, the size of particles of the injected fuel largely affects the performance of the engine. In the direct cylinder injection system, the combustion of the fuel in the combustion chamber, and thus the performance of the engine can be largely improved by reducing the size of the particles of the injected fuel.
  • It is considered that a high pressure fuel injection, in which fuel is injected from the fuel injection valve at a very high pressure, is effective in order to reduce the size of the particles of the injected fuel. Therefore, in recent fuel injection systems, the fuel injection pressure is set at a very high value in order to satisfy the requirement for low exhaust gas emission and low fuel consumption. For example, some of the fuel injection systems for diesel engines use a fuel injection pressure as high as more than 50 MPa (500 atm) to generate very fine particles of injected fuel in the combustion chamber.
  • However, in the high pressure fuel injection system a fuel pump which is capable of pressurizing the fuel to a very high pressure is required. Since the high pressure fuel pump is very expensive, this increases the cost of whole fuel injection system. Further, in the high pressure fuel pump, the clearances between the sliding parts must be small in order to prevent the high pressure fuel from leaking. This tends to cause wear of the sliding parts and lowers the reliability of the pump.
  • In view of the above, there have been proposed various methods for supplying fuel to an internal combustion engine which are capable of improving the combustion of the internal combustion engine without using a very high fuel injection pressure.
  • For example, US-A-5408 957 proposes a method in which gaseous fuel, which is stored in liquid form, is supplemented as a secondary fuel to a primary liquid fuel for assisting the vaporization of the primary fuel.
  • Further, JP-A-55-007966 discloses a method of injecting a liquid fuel into an internal combustion engine by heating and pressurizing the fuel to a supercritical state just before being injected into a combustion chamber of the internal combustion engine. As the transformation of the liquid fuel into the supercritical state does not involve a volumetric change, the fuel, although having gaseous characteristics, can be injected from an ordinary liquid fuel injection nozzle.
  • SUMMARY OF THE INVENTION
  • The object of the invention is to provide an alternative method for supplying fuel to an internal combustion engine which is capable of improving combustion of an internal combustion engine without using a very high fuel injection pressure.
  • The above object is achieved by the method according to claim 1 with further developments set forth in the corresponding subclaims.
  • In this invention, liquid fuel is reformed on the vehicle by bringing the fuel into the supercritical state. Liquid fuel, such as diesel fuel, contains a relatively large amount of heavy components such as normal paraffin components and aromatic hydrocarbons having large molecular weights. These components, when burned in the combustion chamber, form particulate matter (carbon particles) in the exhaust gas. It is found that these heavy normal paraffin components are cracked at a relatively low temperature and produce light components such as normal paraffin having low molecular weight when the fuel is kept in the supercritical state. Therefore, in this aspect of the invention, liquid fuel containing a large amount of heavy components is reformed on the vehicle, and the reformed fuel which contains a large amount of light components is supplied to the combustion chamber of the engine. Therefore, the combustion of the engine is improved.
  • The reformed fuel may be supplied to the engine in the supercritical state. In this case, the combustion of the engine is further improved due to the improvement in the atomization of the fuel and the increase in the amount of the light components in the supplied fuel.
  • Further, in the above aspects of the invention, when diesel fuel is used, an oxygen-containing substance may be added to the fuel before it reaches the supercritical state. In this specification, the term "oxygen-containing substance" means a substance such as water or methanol which contains oxygen or a hydroxyl group. When the fuel containing the oxygen-containing substance is burned, production of aromatic hydrocarbons during the combustion is suppressed and, thereby, the combustion is improved. Further, when the fuel containing an oxygen-containing substance is reformed in the supercritical state, production of aromatic hydrocarbons is suppressed during the cracking of heavy normal paraffin. Therefore, the combustion of the engine is improved.
  • In an embodiment of the invention, diesel fuel (gas oil) is reformed by keeping it in the conditions where the temperature is higher than 400°C and the pressure is higher than 1.5 MPa. It is found that in these conditions, the heavy normal paraffin components in diesel fuel are cracked and produce lighter normal paraffin components. Further, the specific gravity and kinematic viscosity of the diesel fuel are largely lowered without changing the cetane number of the fuel by reforming the diesel fuel in these conditions. Therefore, by adding more than 1 percent weight of the reformed fuel to normal diesel fuel, the atomization of the fuel when injected into the combustion chamber is improved.
  • In another embodiment of the invention, diesel fuel (gas oil) is reformed by keeping it in the conditions where the temperature is between 400°C and 550°C and the pressure is higher than 1.5 MPa. It was found that in these conditions, heavy normal paraffin components in the diesel fuel are cracked and produce lighter normal paraffin components without producing heavy alkylbenzene components. Also in this case, more than 1 percent by weight of the reformed fuel may be added to a normal diesel fuel.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The present invention will be better understood from the description as set forth hereinafter, with reference to the accompanying drawings in which:
  • Fig. 1 schematically illustrates the general configuration of an embodiment of the present invention;
  • Fig. 2 schematically illustrates the general configuration of an embodiment of the supercritical fuel injection pump;
  • Fig. 3 is a graph showing the critical pressure and the critical temperature of the components contained in diesel fuel; and
  • Figs. 4 through 8 are graphs and tables illustrating the result of the reforming of diesel fuel in the supercritical state.
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • Hereinafter, embodiments of the present invention will be explained in detail with reference to the accompanying drawings. However, before explaining the embodiments, the supercritical state of liquid fuel will be explained.
  • The supercritical state is a state achieved by heating a substance above the critical temperature under a pressure higher than the critical pressure. When a liquid substance is pressurized and heated to the supercritical state, the phase of the substance changes from liquid to gas. However, gas in the supercritical state has a very high density and, therefore, it shows physical characteristics very similar to liquid. Namely, when liquid is in the supercritical state, it becomes a supercritical fluid having physical characteristics between those of liquid and gas. Since the supercritical fluid has a very high density, it has a large energy and shows a unique behavior.
  • For example, when the supercritical fuel fluid is injected from a fuel injection valve into the combustion chamber which has a pressure and temperature lower than that of the supercritical state, a mist of fuel having particle sizes much smaller than those formed by the high pressure fuel injection is uniformly formed in the combustion chamber. When the supercritical fuel fluid is injected from the fuel injection valve, the temperature and/or pressure of the fluid becomes lower than the critical values. This causes the state of the fuel fluid to change from a supercritical to a subcritical in which the temperature or the pressure of the fuel fluid is lower than the critical value. Therefore, a part of the fuel fluid injected from the fuel injection valve changes to a normal gas state and diffuses throughout the entire combustion chamber. Further, the remaining part of the fuel fluid returns to a liquid state and forms a mist of fuel having very small particle size in the combustion chamber. Since the particles of fuel in the mist are formed by a change of phase (i.e., condensing), the size of the particles are very small compared to the size of the particles mechanically formed by high pressure fuel injection. In addition to that, since the injected supercritical fuel fluid, which has the characteristics of a gas, diffuses throughout the entire combustion chamber instantaneously, the formation of fine fuel particles by the above phase change (condensing) occurs simultaneously in the entire combustion chamber. Therefore, a very fine mist of fuel is uniformly formed in the entire combustion chamber.
  • Further, the critical pressure of diesel fuel is relatively low (for example, generally lower than 10 MPa). This means that, by injecting fuel in the supercritical state, a uniform fine mist of fuel having a much smaller particle size compared to those in the high pressure fuel injection is obtained with much lower fuel pressure.
  • Further, each of the fuel particles formed by the injection of supercritical fuel fluid have a high energy level due to latent heat released by the condensation and, therefore, readily react with oxygen. In addition to that, since the fine mist of fuel is uniformly formed in the entire combustion chamber by the injection of supercritical fuel fluid, sufficient oxygen is supplied to each fuel particle which is, as explained above, highly reactive. Therefore, the fuel in the combustion chamber is readily ignited and is burned completely, i.e., the combustion of the engine is largely improved and, thereby, both the exhaust gas emission and fuel consumption of the engine are reduced by the improvement of the combustion.
  • Fig. 3, is a graph illustrating the pressure and temperature conditions required to make diesel fuel reach the supercritical state. Generally speaking, diesel fuel is a mixture of normal paraffin (n-paraffin) having 11 to 20 carbon atoms and aromatic hydrocarbons (alkylbenzene) having 10 to 22 carbon atoms. Since the critical pressure and the critical temperature depend on the substance, each component of diesel fuel has different critical pressure and temperature.
  • Fig. 3 illustrates the change in the critical pressure and temperature of n-paraffin and alkylbenzene in accordance with the difference in the number of carbon atoms. The vertical axis and the horizontal axis in Fig. 3 represent the critical pressure and the critical temperature of the respective components. As shown in Fig. 3, in general, the critical pressure becomes lower as the number of carbon atoms is larger, and the critical temperature becomes higher as the number of carbon atoms is larger. Further, when the n-paraffin and the alkylbenzene having same number of carbon atoms are compared, both the critical pressure and the critical temperature of the n-paraffin are generally lower than the same of the alkylbenzene.
  • The hatched portions A and B in Fig. 3 indicate the range of the numbers of carbon atoms of the n-paraffin components and the alkylbenzene components usually composing diesel fuel. As can be seen from Fig. 3, it is required that both the pressure and the temperature of the diesel fuel must be in the region SC1 in Fig. 3 in order to make all the components in diesel fuel reach the supercritical state. The region SC1 represents a pressure more than 3 to 6 MPa and a temperature more than 400 to 500°C. However, in the actual operation, it is found that the improvement of the combustion of the engine can be achieved even when only some of the components in diesel fuel reach a supercritical state. Therefore, even in a pressure/temperature condition in which only some of the n-paraffin components and the alkylbenzene components are in the supercritical state, for example, when the pressure is more than 1 MPa and the temperature is more than 300°C, an improvement in the combustion of the engine can be achieved. As explained before, the critical pressure becomes lower as the number of carbon atoms in the components increase while the critical temperature becomes higher as the number of carbon atoms in the components increase.
  • Therefore, if only some of the components of diesel fuel should reach the supercritical state, the pressure can be lowered when the temperature is maintained at high level.
  • As explained above, combustion of the engine is improved, with a much lower fuel injection pressure compared to that of the high pressure fuel injection system, by injecting diesel fuel into combustion chambers in the supercritical state. Therefore, by injecting diesel fuel in the supercritical state, the pressure rating of the fuel injection pump can be largely lowered and, thereby, the cost of fuel injection pump can be lowered and the reliability thereof improved.
  • Next, reforming of fuel by a supercritical treatment is explained.
  • It is also found that heavy components in liquid fuel are converted to lighter components, i.e., reforming of fuel is performed, by keeping liquid fuel in the supercritical state for a certain time (i.e., a supercritical treatment).
  • Fig. 4 shows the result of reforming of diesel fuel by the supercritical treatment. In Fig. 4, the vertical axis represents the change in the concentrations of the n-paraffin components in diesel fuel caused by the supercritical treatment, and the horizontal axis represents the number of carbon atoms in the respective n-paraffin components. Fig. 4 shows the case where diesel fuel is held at the temperature between 400 and 500°C and the pressure between 4 and 5 MPa for about 20 minutes. As can be seen from Fig. 4, the concentrations of heavy n-paraffin components (number of carbon atoms is 13 or more) decrease and, at the same time, the concentrations of light n-paraffin components (number of carbon atoms is 12 or less) increase due to the supercritical treatment. This means that a part of the heavy components in diesel fuel are converted to the lighter components, i.e., diesel fuel is reformed by the supercritical treatment. Further, it is found that the increase in the light n-paraffin components becomes larger as the pressure and temperature in the supercritical treatment are higher and the time of the supercritical treatment is longer.
  • According to experiment, it was found that a pressure more than 1.5 MPa is preferable to reform the heavy components in diesel fuel. Fig. 6 shows the results of experiments in which diesel fuel is treated at various temperature and time under the pressure 1.5 MPa. In Fig. 6, the letter C represents the case where no change of the concentrations of the components of the diesel fuel occurred by the treatment, the letter B represents the case where the amount of heavy n-paraffin components is slightly decreased by the treatment and the letter A represents the case where the amount of heavy n-paraffin components is decreased by the treatment. As can be seen from Fig. 6, when the pressure is kept at 1.5 MPa, diesel fuel is reformed (i.e., the heavy components in the diesel fuel decreases) when the temperature is more than 400°C. Further, as can be seen from Fig. 6, as the temperature becomes higher, the time required for reducing the heavy components becomes shorter. For example, in Fig. 6, when the temperature is 400°C, a 120 minutes treatment time is required to reduce the heavy components. However, it takes less than 1 minute when the temperature is higher than 475°C.
  • As explained above, in order to reduce the heavy components in the diesel fuel, it is preferable to raise the temperature and pressure as high as possible. However considering the reliability of the elements in the reforming device and the seal problems, it is preferable to use a temperature lower than 600°C and a pressure lower than 30 MPa.
  • Further, it was also found that light alkylbenzene components are produced by the decomposition of heavy n-paraffin components and the concentrations of alkylbenzene components increase when the temperature of the supercritical treatment is high. Fig. 5 shows the change in the concentrations of alkylbenzene components in the same diesel fuel as Fig. 4 due to the supercritical treatment where the diesel fuel is kept at 600°C and 5 MPa for about 20 minutes. As can be seen from Fig. 5, when the temperature in the supercritical treatment is high, light alkylbenzene components (the number of carbon atoms is 12 or less) increase due to the conversion of heavy n-paraffin components to light alkylbenzene components.
  • Generally, particulate matter in the exhaust gas of the engine increases as the alkylbenzene components or heavy n-paraffin components in diesel fuel increase. Especially, the alkylbenzene components having the number of carbon atoms more than 12 increases the particulate matter in the exhaust gas. Therefore, it is not preferable that the heavy alkylbenzene components in diesel fuel increase by the supercritical reforming treatment.
  • Fig. 7 shows the results of experiments in which diesel fuel is treated at various temperature and time under a pressure of 5 MPa. In Fig. 7, the letter C represents the case where the concentrations of the heavy alkylbenzene components of the diesel fuel are increased by the treatment, the letter B represents the case where the heavy alkylbenzene components are slightly increased by the treatment and the letter A represents the case where the heavy alkylbenzene components are not increased by the treatment. As can be seen from Fig. 7, the heavy alkylbenzene components increases when the temperature is higher than 550°C even the treatment time is 1 minute. However, as can be seen from Fig. 7, as the temperature becomes lower, the treatment time which does not increase the heavy alkylbenzene components becomes longer.
  • Therefore, when the pressure is higher than 1.5 MPa, and the temperature between 400°C and 550°C, the conditions where the heavy n-paraffin components reform and, at the same time, the heavy alkylbenzene components do not increase can be found.
  • Further, in order to suppress the production of alkylbenzene during the supercritical reforming treatment, it is effective to add an oxygen-containing substance such as water and methanol to the diesel fuel to be treated. By applying the supercritical reforming treatment to diesel fuel after adding water or methanol by several percent to about twenty percent by weight, the conversion of decomposed heavy n-paraffin components to alkylbenzene components is suppressed. Further, it is known that small amounts of alkylbenzene components are produced by the combustion of n-paraffin components in diesel fuel. However, by adding the oxygen-containing substance to diesel fuel, the production of alkylbenzene components during the combustion of diesel fuel can be suppressed and, thus, the amount of the particulate matter in the exhaust gas can be reduced.
  • Fig. 8 shows changes in the physical properties of diesel fuel caused by the supercritical treatment. Fig. 8 shows the physical properties of a normal diesel fuel (a gas oil which complies with JIS JTD-5) and the properties of the fuel obtained by reforming the same diesel fuel in the condition where the pressure is 5 MPa and the temperature is between 400 and 550°C. As can be seen from Fig. 8, the kinematic viscosity and flash point are lowered by the supercritical treatment while maintaining the same cetane number. This means that, when the reformed fuel is injected into the combustion chamber, it forms a fine mist (due to the lower kinematic viscosity) which readily ignites (due to the lower flash point) in the combustion chamber. Further, the fact that the reformed fuel has a lower initial boiling point and a lower flash point means that the reformed fuel has a higher volatility than normal diesel fuel while maintaining the same cetane number. Therefore, the reformed fuel can be used as an additive for the normal diesel fuel to promote initial combustion in the combustion chamber. When used as an additive for normal diesel fuel to promote the initial combustion, the concentration of the reformed fuel in the mixture should be more than 1 percent by weight, preferably more than 5 percent by weight.
  • Next, an embodiment of a device capable of performing the method of the invention is explained.
  • Fig. 1 schematically illustrates the general configuration of a device which reforms diesel fuel in the storage tank 11 by supercritical treatment. The reformed fuel is made into the supercritical state again and injected by a fuel injection valve into the respective combustion chambers of a diesel engine 1.
  • In the embodiment in Fig. 1, a supercritical reformer 31 and a first critical pressure pump 33 for feeding the fuel in the tank 11 to the supercritical reformer 31 are provided. The reformed fuel is stored in a reformed fuel tank 35.
  • In this embodiment, the first critical pressure pump 33 feeds the diesel fuel to the supercritical reformer 31 at a pressure higher than 1.5 MPa. The supercritical reformer 31 is provided with a heater 31a and a heating passage 31b. The fuel is heated by the heater 31a to a temperature higher than the critical temperature when it flows through the heating passage 31b, and reaches the supercritical state. The flow velocity of the fuel in the heating passage 31b, i.e., the time the fuel resides in the passage 31b is controlled by a flow control valve 37. In this embodiment, the capacity of the heater 31a and the flow of the fuel in the supercritical reformer 31 is selected so that the fuel is held within the heating passage 31b for about 1 to 20 minutes at a temperature between 400°C and 550°C. By this arrangement, the fuel is reformed in the supercritical state when it flows through the heating passage 31b, and the reformed fuel flows into the reformed fuel tank 35.
  • Numeral 17 in Fig. 1 is a second critical pressure pump which feeds the reformed fuel from the reformed fuel tank 35 to a supercritical fuel injection pump 19 at a pressure higher than the critical pressure. Numeral 18 is a supercritical state generating device which includes a heating device such as an electric heater 18b for heating the diesel fuel supplied from supercritical fuel injection pump 19 to the fuel injection valve 2 so that the temperature of the diesel fuel becomes higher than the critical temperature.
  • The reformed fuel in the reformed fuel tank is pressurized by the second critical pressure pump to, for example, 3 to 6 MPa and flows into a heating chamber 18a in the supercritical state generating device 18 through a fuel passage 19h disposed in the body 19a of the supercritical fuel injection pump 19, as explained later. Then, the fuel in the heating chamber 18a is heated by the heater 18b to a temperature higher than the critical temperature (for example, 400 to 500°C) and reaches the supercritical state. When a fuel injection timing occurs, the fuel in the heating chamber 18a is further pressurized by a plunger 19b of the supercritical fuel injection pump 19. When the pressure in the heating chamber 18a becomes higher than an opening pressure of the fuel injection valve 2, fuel in the supercritical state is injected from the fuel injection valve 2 and forms an extremely fine uniform fuel mist in the combustion chamber of the engine 1.
  • Fig. 2 shows a general construction of the supercritical fuel injection pump 19 in Fig. 1.
  • In Fig. 2, 19d is a cylinder of the supercritical fuel injection pump 19, 19c is a solenoid actuator which is mounted on the cylinder 19d. 19a is a spool disposed in the cylinder 19d. Driven by the solenoid actuator 19c, the spool 19a slides within the cylinder 19d. 19b is a plunger which is driven by a camshaft (not shown) of the engine 1 and reciprocates within the cylinder. 19e in Fig. 2 is a pressure chamber defined in the cylinder 19d by the spool 19a and the plunger 19b. The stroke of the plunger is adjusted by a governor (not shown) in accordance with the load of the engine 1. During the downward motion of the plunger 19b, the spool 19a is held at a downward position as shown in Fig. 2 by the solenoid 19c. This causes the fuel from the critical pressure pump 17 to flow directly into the heating chamber 18a of the supercritical state generating device 18 through the pipe 21, the port 21a of the cylinder 19d, the fuel passage 19h of the spool 19a, the port 24a and the pipe 24. Fuel is also fed from the critical pressure pump 17 to the pressure chamber 19e through the pipes 22 and 22a. After the plunger 19b reaches a position of the port 23a during its downward stroke, excess fuel is returned to the storage tank 11 through the port 23a and the return pipe 23. The return pipe 23 is provided with a cooling water jacket 23b for cooling the fuel flowing through the pipe 23.
  • When the upward stroke of the plunger 19b starts, the ports 23a and 22a are closed by the plunger 19b and the pressure of the fuel in the pressure chamber 19e increases. In this condition, when a fuel injection timing occurs, the spool 19a is moved to an upward position by the solenoid 19c. At the upward position of the spool 19a, the fuel passage 19h is closed, and another fuel passage 19j is connected to the port 24a. Therefore, the fuel in the pressure chamber 19e which is pressurized by the upward motion of the plunger 19b flows into the heating chamber 18a of the supercritical state generating device 18. This causes the pressure in the heating chamber 18a to increase further. The passage 19j is provided with check valve 19k for preventing the backflow of the pressurized fuel from the heating chamber 18a to the pressure chamber 19e.
  • When the pressure of the fuel in the heating chamber becomes higher than the valve opening pressure of the fuel injection valve 2 during the upward motion of the plunger 19b, the supercritical state fuel in the chamber 18a is injected from the fuel injection valve 2 into the combustion chamber of the engine 1. After the required amount of the fuel is injected, the plunger 19b starts the downward stroke. This lowers the pressure of the fuel in the heating chamber 18a, and when the pressure in the chamber 18a becomes lower than the opening pressure of the fuel injection valve 2, the fuel injection stops. In this condition, since the check valve 19k closes, the pressure in the heating chamber 18a is kept higher than the critical pressure and, thereby the fuel in the heating chamber is kept in the supercritical state. Then, the spool 19a is moved to the downward position as shown in Fig. 2, and next fuel injection cycle starts.
  • The time the fuel resides in the heating chamber 18a can be arbitrary set by selecting the volume of the heating chamber 18a. Therefore, the residence time can be set long enough to assure that the fuel is heated to the temperature higher than the critical temperature by the heater 18b. As explained above, a liquid fuel in the supercritical state can be injected into the combustion chamber of the engine by the fuel injection system in Figs. 1 and 2.
  • It is preferable to set the opening pressure of the fuel injection valve 2 and the temperature in the heating chamber 18a higher than the pressure and the temperature which can make all the components in the fuel reach the supercritical state (for example, a temperature higher than 500°C and a pressure higher than 6 MPa. However, as explained before, even if the temperature and pressure conditions are set so that only some of the components in the fuel reach the supercritical state, it is possible to form a very fine mist in the combustion chamber.
  • According to the present embodiment, all the devices required for reforming the fuel are disposed on the fuel path between the fuel storage tank 11 and the fuel injection valve 2. Therefore, when the system in Fig. 2 is applied to an engine for a vehicle, normal liquid fuel supplied to the vehicle can be reformed on the vehicle. This feature is especially advantageous because a normal fuel can be supplied to the vehicle and a facility for supplying the special (reformed) fuel to the vehicle is not required.
  • The reformed fuel is injected from the fuel injection valve in the supercritical state in this embodiment. However, the combustion of the engine is largely improved even if the reformed fuel is injected in a normal state (i.e., at a lower fuel injection pressure). Further, though the fuel flows through the supercritical reformer 31, and reformed contiguously in the above embodiment, a certain amount of the fuel may be reformed at a time. In this case, a shutoff valve which may be opened and closed by a timer is provided instead of flow control valve 37 to hold a certain amount of the fuel within the supercritical reformer 31 for a predetermined time. After the fuel in the supercritical reformer 31 is reformed, the shutoff valve is opened to drain the reformed fuel in the reformer 31 to the reformed fuel tank 35. Further, the oxygen-containing substance such as water or ethanol may be added to the fuel in the storage tank 11 in order to suppress the production of alkylbenzene components during the reforming and combustion of the reformed fuel.
  • As explained above, according to the present invention, the combustion in the combustion chamber of the engine is improved and, thereby, the exhaust gas emission and the fuel consumption of the engine are reduced at the same time by injecting and/or reforming liquid fuel in the supercritical state without using a very high fuel injection pressure.

Claims (8)

  1. A method for supplying liquid fuel containing hydrocarbon components from a tank of an internal combustion engine to a combustion chamber of the internal combustion engine, including the steps:
    reforming at least part of the fuel from the tank of the internal combustion engine by adjusting temperature and pressure of the fuel in such a manner that at least some hydrocarbon components of the fuel reach a supercritical state;
    bringing the fuel out of the supercritical state and bringing said reformed fuel to a reformed fuel tank or mixing it with non-reformed fuel.
  2. A method according to claim 1, wherein the reformed fuel is supplied to the combustion chamber of the internal combustion engine in a supercritical state.
  3. A method according to claim 1 or 2, wherein said internal combustion engine is a diesel engine, and said liquid fuel is diesel fuel.
  4. A method according to claim 3, further comprising a step for adding an oxygen-containing substance to the fuel before it reaches the supercritical state.
  5. A method according to claim 3 or 4, wherein the diesel fuel is reformed by keeping the fuel in the condition where the temperature is higher than 400°C and the pressure is higher than 1.5 MPa.
  6. A method according to claim 5, wherein the temperature is between 400°C and 550°C.
  7. A method according to claim 5 or 6, wherein the reformed diesel fuel is mixed with diesel fuel not reformed so that the concentration of the reformed diesel fuel in the mixture is at least 1 percent by weight.
  8. A method according to claim 7, wherein the mixture is between 1 percent and 30 percent by weight.
EP97102329A 1996-02-14 1997-02-13 A method and a device for supplying fuel to an internal combustion engine Expired - Lifetime EP0790395B1 (en)

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JP2690396 1996-02-14
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DK1155225T3 (en) 1999-02-24 2003-11-17 Kema Nv Combustion unit for combustion of a liquid fuel and a power generation system comprising such combustion unit
DE60005149T2 (en) * 1999-02-24 2004-04-15 N.V. Kema COMBUSTION DEVICE AND POWER PLANT WITH SUCH A COMBUSTION DEVICE
DK2189174T3 (en) * 2005-09-26 2013-03-04 Univ Leeds METHOD OF ADMINISTRATING MEDICINE
US10794340B2 (en) * 2018-04-24 2020-10-06 Wisconsin Alumni Research Foundation Engines using supercritical syngas
EP4222364A1 (en) 2021-01-07 2023-08-09 Wisconsin Alumni Research Foundation Wet biofuel compression ignition

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