EP0789807B1 - Catalyst carrier element with internal insulation - Google Patents

Catalyst carrier element with internal insulation Download PDF

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Publication number
EP0789807B1
EP0789807B1 EP95936484A EP95936484A EP0789807B1 EP 0789807 B1 EP0789807 B1 EP 0789807B1 EP 95936484 A EP95936484 A EP 95936484A EP 95936484 A EP95936484 A EP 95936484A EP 0789807 B1 EP0789807 B1 EP 0789807B1
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EP
European Patent Office
Prior art keywords
exhaust gas
carrier body
passages
plastic deformation
process according
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EP95936484A
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German (de)
French (fr)
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EP0789807A1 (en
Inventor
Wolfgang Maus
Rolf BRÜCK
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Vitesco Technologies Lohmar Verwaltungs GmbH
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Emitec Gesellschaft fuer Emissionstechnologie mbH
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2842Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/14Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2260/00Exhaust treating devices having provisions not otherwise provided for
    • F01N2260/08Exhaust treating devices having provisions not otherwise provided for for preventing heat loss or temperature drop, using other means than layers of heat-insulating material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/02Fitting monolithic blocks into the housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/20Methods or apparatus for fitting, inserting or repairing different elements by mechanical joints, e.g. by deforming housing, tube, baffle plate or parts thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Catalysts (AREA)

Abstract

For the catalytic reaction of exhaust gases in an exhaust system, in particular an exhaust system for use in internal combustion engines, a device is proposed with a catalyst carrier element (1) which is provided with a plurality of channels (2) through which the exhaust gas can flow. The free cross section (4) of flow of the channels (2) is partially closed in the direction of flow of the exhaust gas by plastic deformation of the channel walls (11), specifically, in an outer ring region (3) of the catalyst carrier element (1). The plastic deformation can be carried out using, for example, a tool (17) provided for this purpose with a disc (18) which can rotate about an axis (19). The disc (18) is forced against the catalyst carrier element (1) and the casing (10) to create a plastic deformation of the casing tube (10) and channel walls (11) in the form of a peripheral crimp (20) pointing towards the carrier element (1). Other techniques can be applied to create the plastic deformation. The outer channels thus closed off form a thermal insulation against the casing tube (10) which helps the catalyst carrier element (1) to heat up more rapidly in the cold start phase.

Description

Die Erfindung bezieht sich auf eine Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem, insbesondere in einem Abgassystem von Verbrennungskraftmaschinen, mit einem Katalysator-Trägerkörper, der eine Vielzahl von einem Abgas durchströmbarer Kanäle aufweist und auf ein Verfahren zur Herstellung einer solchen Vorrichtung.The invention relates to a device for catalytic conversion of exhaust gases in an exhaust system, in particular in an exhaust system of internal combustion engines, with a catalyst carrier body, of a plurality of channels through which an exhaust gas can flow has and on a method for producing such a device.

Um eine möglichst vollständige Umsetzung der in einer Verbrennungskraftmaschine enthaltenen Kohlenwasserstoffe und des Kohlenmonoxydes zu erreichen, muß der Katalysator eine Mindesttemperatur haben, bei der die katalytische Umsetzung der Komponenten des Abgases stattfinden kann. Im allgemeinen spricht man von einer sogenannten Anspringtemperatur. Der Katalysator wird in der Kaltstartphase durch das heiße Abgas aufgeheizt. Es ist auch bekannt, den Katalysator-Trägerkörper wenigstens teilweise elektrisch zu beheizen. Damit der Schadstoffausstoß während der Kaltstartphase möglichst gering ist und aus mechanischen Gründen, ist daher vorgeschlagen worden, den Katalysator-Trägerkörper mit einer Innenisolierung auszubilden, um den Wärmeverlust an das Gehäuse und die Umgebung zu verringern.To ensure the most complete implementation possible in an internal combustion engine contained hydrocarbons and carbon monoxide To achieve, the catalyst must have a minimum temperature at which the catalytic conversion of the components of the exhaust gas take place can. In general one speaks of a so-called light-off temperature. The catalytic converter is in the cold start phase by the hot exhaust gas heated up. It is also known to at least support the catalyst carrier partially heated electrically. So that the pollutant emissions during the Cold start phase is as low as possible and for mechanical reasons therefore, it has been proposed to use a catalyst carrier body Form internal insulation to reduce heat loss to the housing and reduce the environment.

Durch die DE 36 02 134 A1 ist eine Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem, insbesondere in einem Abgassystem von Verbrennungskraftmaschinen, bekannt, die einen in einem Gehäuse angeordneten metallischen Katalysator-Trägerkörper aufweist. Der Trägerkörper weist eine Vielzahl von einem Abgas durchströmbarer Kanäle auf. Die Innenisolierung des Katalysator-Trägerkörpers ist gemäß dem Vorschlag der DE 36 02 134 A1 dadurch zu verwirklichen, daß vor dem Katalysator-Trägerkörper ein radial nach innen weisender Bund angeordnet ist, dessen Bundhöhe 3-15% des Katalysator-Durchmessers, mindestens aber 1 mm beträgt. Durch diesen Bund wird im Abgasstrom eine Wirbelzone geschaffen, durch die eine direkte Beaufschlagung eines äußeren ringförmigen Bereichs mit dem heißen Abgas vermieden wird.DE 36 02 134 A1 describes a device for catalytic Implementation of exhaust gases in an exhaust system, especially in one Exhaust system of internal combustion engines, known to one in a metallic catalyst carrier body arranged in a housing having. The carrier body has a plurality of exhaust gases through which an exhaust gas can flow Channels on. The interior insulation of the catalyst carrier body According to the proposal of DE 36 02 134 A1, that in front of the catalyst carrier body a radially inward Collar is arranged, the collar height of 3-15% of the catalyst diameter, is at least 1 mm. Through this covenant a vortex zone is created in the exhaust gas flow, through which a direct admission an outer annular region with the hot exhaust gas is avoided.

Durch das DE G 87 12 267.7 U1 ist eine Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem bekannt. Die Vorrichtung umfaßt einen Katalysator-Trägerkörper, der eine Vielzahl von Strömungskanälen für ein Abgas aufweist und der in einem hülsenförmigen Gehäuse eingesetzt ist. Das Gehäuse ist gegenüber dem Katalysator-Trägerkörper thermisch isoliert. Die Isolierung wird dadurch erreicht, daß der Katalysator-Trägerkörper zwischen Stirnringen angeordnet ist, die mindestens die äußere Lage des metallische Matrixkörpers und damit die äußeren Strömungskanäle in dieser Matrix verschließen. Hierdurch entsteht im Außenbereich des Katalysator-Trägerkörpers ein abgeschlossener, nicht von Abgas durchströmter, Luftspalt, der zur Wärmeisolierung dient.DE G 87 12 267.7 U1 is a device for catalytic Implementation of exhaust gases in an exhaust system known. The device includes a catalyst carrier body having a plurality of flow channels for an exhaust gas and in a sleeve-shaped housing is inserted. The housing is opposite the catalyst carrier body thermally insulated. The insulation is achieved in that the Catalyst carrier body is arranged between end rings, which at least the outer layer of the metallic matrix body and thus the Seal the outer flow channels in this matrix. This creates in the outer area of the catalyst carrier body a closed, Air gap not flowed through by exhaust gas, which is used for thermal insulation.

Der vorliegenden Erfindung liegt die Aufgabe zugrunde, die bekannten Vorrichtungen zur katalytischen Umsetzung von Abgasen so weiterzubilden, daß die Herstellung eines Katalysator-Trägerkörpers mit einer Innenisolierung vereinfacht wird. Ferner soll ein Verfahren zur Herstellung einer solchen Vorrichtung zur katalytischen Umsetzung von Abgasen bereitgestellt werden. The present invention has for its object the known To further develop devices for the catalytic conversion of exhaust gases, that the production of a catalyst carrier body with a Internal insulation is simplified. Furthermore, a method of manufacture is said to such a device for the catalytic conversion of exhaust gases to be provided.

Diese Aufgabe wird durch eine Vorrichtung mit den Merkmalen nach Anspruch 1 gelöst. Vorteilhafte Weiterbildungen sind Gegenstand der Unteransprüche.This object is achieved by a device with the features Claim 1 solved. Advantageous further developments are the subject of Subclaims.

Im Gegensatz zu den bekannten Vorrichtungen zur katalytischen Umsetzung von Abgasen wird ein im Außenbereich des Katalysator-Trägerkörpers abgeschlossener Luftspalt nicht durch zusätzliche Ringe oder desgleichen bewirkt, sondern dadurch, daß der freie Strömungsquerschnitt der Kanäle teilweise, d. h. in mindestens einem axialen Teilbereich, in Strömungsrichtung des Abgases durch plastische Verformung der Kanalwände verschlossen wird. Hierdurch vereinfacht sich die Herstellung der Vorrichtung, da nunmehr kein Bund oder Stirnring in das Gehäuse eingebracht werden muß. Besteht der Katalysator-Trägerkörper aus mehreren gewickelten Blechlagen, so kann die plastische Verformung bereits beim Wickeln erfolgen. Dies vereinfacht das Herstellungsverfahren gewikkelter Katalysatoren, da der Wickelvorgang und die plastische Verformung gleichzeitig erfolgen können.In contrast to the known devices for catalytic conversion Exhaust gases become in the outer area of the catalyst carrier body closed air gap not by additional rings or the like causes, but in that the free flow cross-section of the channels partially, d. H. in at least one axial section, in Flow direction of the exhaust gas due to plastic deformation of the duct walls is closed. This simplifies the manufacture of the Device, since now no collar or end ring in the housing must be introduced. The catalyst carrier body consists of several coiled sheet layers, the plastic deformation can already done while winding. This simplifies the manufacturing process more complicated Catalysts because of the winding process and the plastic deformation can be done simultaneously.

Vorzugsweise werden die Kanäle im Bereich des Abgaseintritts verschlossen. Die plastische Verformung der Kanäle erfolgt vorteilhafterweise vor der Aufbringung einer katalytischen wirksamen Schicht auf den Katalysator-Trägerkörper. Die Beschichtund (Washcoat) wird meist mittels einer den Katalysator-Trägerkörper durchfließenden Suspension aufgebracht. Der Katalysator-Trägerkörper kann so angeordnet werden, daß die Suspension in die einseitig verschlossenen Kanäle reinfließt. Der Washcoat füllt dann die Kanäle aus. Er bildet eine thermische Isolierung. Ordnet man den Katalysator-Trägerkörper so an, daß die verschlossenen Kanäle im Eintrittsbereich der Suspension in den Katalysator-Trägerkörper liegen, so können die Kanäle nicht mit der Suspension gefüllt werden. Dies verbessert die Isolation, da die Wärmeleitfähigkeit der Katalysator-Trägerschicht, die den Kanal vollständig ausfüllen würde besser ist als die der in den Kanälen enthaltenen Atmosphäre. Vorteilhafterweise sind die Kanäle im Abgaseintritts- und Abgasaustrittsbereich verschlossen. Sollte die plastische Verformung einzelne Kanäle nicht vollständig verschließen, so wird dies durch die nachträgliche Beschichtung, die kleine Spalte verschließt, ausgeglichen.The channels are preferably closed in the region of the exhaust gas inlet. The plastic deformation of the channels advantageously takes place before the application of a catalytically active layer on the catalyst carrier body. The coating and (washcoat) is usually by means of a applied suspension flowing through the catalyst support body. Of the Catalyst support body can be arranged so that the suspension flows into the channels closed on one side. The washcoat then fills the channels out. It forms thermal insulation. If you arrange that Catalyst carrier body so that the closed channels in the inlet area the suspension are in the catalyst carrier body, so the channels cannot be filled with the suspension. This improves the insulation, since the thermal conductivity of the catalyst support layer, that would fill the channel completely is better than that in the Channels contained atmosphere. The channels are advantageously in the Exhaust gas inlet and exhaust area closed. Should the plastic Deformation does not completely close off individual channels, this will through the subsequent coating that closes the small gaps, balanced.

Bei einer Vorrichtung, bei der die Kanäle im Katalysator-Trägerkörper lagenweise übereinander ausgebildet sind, ist es von Vorteil, in bis fünf Lagen der Kanäle durch plastische Verformung zu schließen, vorzugsweise zwei. Hierdurch wird ein vorteilhafter Kompromiß zwischen der notwendigen katalytisch aktiven Oberfläche und der Wärmeisolierung erzielt, ohne daß der Katalysator-Trägerkörper in seinen äußeren Abmessungen wesentlich vergrößert werden muß.In a device in which the channels in the catalyst carrier body are formed in layers one above the other, it is advantageous in up to five Layers of the channels should be closed by plastic deformation, preferably two. This is an advantageous compromise between the necessary catalytically active surface and thermal insulation achieved without that the catalyst carrier body in its outer dimensions essential must be enlarged.

Ein erfindungsgemäßes Verfahren zur Herstellung einer Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem wird durch die Merkmale des Anspruchs 5 angegeben. Vorteilhafte Weiterbildungen des Verfahrens sind Gegenstand der Unteransprüche 6 bis 17.A method according to the invention for producing a device for catalytic conversion of exhaust gases in an exhaust system is carried out by the features of claim 5 specified. Advantageous further training the method are the subject of dependent claims 6 to 17.

Gemäß dem Verfahren wird vorgeschlagen durch plastische Verformung der Kanäle in einem äußeren Ring im Bereich des Katalysator-Trägerkörpers den freien Strömungsquerschnitt der Kanäle teilweise in Strömungsrichtung des Abgases zu verschließen. Die plastische Verformung kann dadurch erfolgen, daß der Katalysator-Trägerkörper in eine Matrize eingestoßen wird. Beim Einstoßen des Katalysator-Trägerkörpers wird der äußere Bereich des Trägerkörpers deformiert, wodurch die Kanäle verschlossen werden. Die Einstoßmatrize kann mit einer konischen oder einer ringförmigen Wandung versehen sein. According to the method, plastic deformation is proposed of the channels in an outer ring in the region of the catalyst carrier body the free flow cross section of the channels partly in the direction of flow to close the exhaust gas. The plastic deformation can in that the catalyst carrier body in a matrix is kicked in. When the catalyst carrier body is pushed in, the outer area of the support body deformed, thereby closing the channels will. The insertion die can be made with a conical or be provided with an annular wall.

Statt den Katalysator-Trägerkörper in eine Matrize einzustoßen, kann die plastische Verformung der Kanalwände auch dadurch erfolgen, daß mittels eines Stempels auf einen äußeren Ringbereich eine Kraft ausgeübt wird, die zu der plastischen Verformung der Kanalwände führt. Der Stempel kann dabei ringförmig oder mit einer schräg von innen nach außen verlaufenden Wand ausgebildet sein. Ist der Stempel mit einer schräg von innen nach außen verlaufenden Wand versehen, so werden die freien Strömungsquerschnitte der Kanäle durch Biegen der Kanalwände geschlossen. Bei einem ringförmigen Stempel werden die Kanalwände gequetscht.Instead of pushing the catalyst carrier body into a die, the plastic deformation of the channel walls also take place in that exerted a force on an outer ring area by means of a stamp which leads to the plastic deformation of the channel walls. Of the Stamp can be ring-shaped or with an oblique from the inside out outside wall be formed. Is the stamp with a wall that runs diagonally from the inside to the outside the free flow cross sections of the channels by bending the channel walls closed. In the case of an annular stamp, the channel walls bruised.

Gemäß einem weiteren vorteilhaften Gedanken wird vorgeschlagen, während der plastischen Verformung den Katalysator-Trägerkörper an seinem der Krafteinleitung entgegengesetzem Ende gegenzuhalten. Dies hat den Vorteil, daß die einzelnen Lagen des Katalysator-Trägerkörpers gegeneinander nicht verschoben werden.According to a further advantageous idea, it is proposed that during the plastic deformation on the catalyst carrier body to hold its end opposite to the introduction of force. This has the advantage that the individual layers of the catalyst carrier body not be moved against each other.

Es sind Katalysator-Trägerkörper bekannt, die aus einer Vielzahl von sich abwechselnden strukturierten und vorzugsweise glatten Blechlagen bestehen. Solche metallischen Katalysator-Trägerkörper werden von einem Mantelrohr umgeben. Es wird daher vorgeschlagen, die plastische Verformung des Mantelrohres und der Kanäle in einem äußeren Ringbereich des Katalysator-Trägerkörpers durchzuführen, derart daß der freie Strömungsquerschnitt der Kanäle teilweise in Strömungsrichtung des Abgases verschlossen wird. Die plastische Verformung des Mantelrohres und der Kanäle kann dadurch erfolgen, daß in dem Mantelrohr wenigstens eine nach innen gerichtete umlaufende Sicke ausgebildet wird. Die Sicke kann auch zur Verbindung des Katalysator-Trägerkörpers mit einem Gehäuse genutzt werden. Catalyst support bodies are known which are composed of a large number of themselves alternating structured and preferably smooth sheet metal layers exist. Such metallic catalyst carrier bodies are made by one Surround the casing tube. It is therefore proposed the plastic deformation of the casing tube and the channels in an outer ring area perform the catalyst carrier body so that the free flow cross section of the channels partly in the flow direction of the exhaust gas is closed. The plastic deformation of the casing tube and the Channels can be made in that at least one in the jacket tube inward circumferential bead is formed. The bead can also for connecting the catalyst carrier body to a housing be used.

Die plastische Verformung erfolgt vorteilhafterweise durch Freiformen. Vorzugsweise wird die plastische Verformung durch Walzen oder Kneten durchgeführt.The plastic deformation is advantageously carried out by free molding. The plastic deformation is preferably carried out by rolling or kneading carried out.

Weitere Merkmale und Vorteile des Gegenstandes der Erfindung werden anhand von Ausführungsbeispielen erläutert, ohne daß eine Beschränkung auf diese Ausführungsbeispiele vorgenommen wird. Hierbei zeigt:

Figur 1
schematisch einen Katalysator-Trägerkörper und eine Matrize,
Figur 2
zeigt eine zweite Form einer Matrize,
Figur 3
zeigt schematisch einen Trägerkörper, welcher in eine Matrize nach Figur 2 eingestoßen wurde,
Figur 4
zeigt einen Katalysator-Trägerkörper und einen Stempel im Schnitt,
Figur 5
ein zweites Ausführungsbeispiel eines Stempels,
Figur 6
zeigt einen plastisch deformierten Trägerkörper, entsprechend Figur 4,
Figur 7
einen plastisch deformierten Trägerkörper durch Deformation mit einem Stempel nach Figur 5 und
Figur 8
einen Trägerkörper im Teilschnitt.
Further features and advantages of the subject matter of the invention are explained on the basis of exemplary embodiments, without being restricted to these exemplary embodiments. Here shows:
Figure 1
schematically a catalyst support body and a matrix,
Figure 2
shows a second form of a die,
Figure 3
schematically shows a carrier body which was pushed into a die according to FIG. 2,
Figure 4
shows a catalyst carrier body and a stamp in section,
Figure 5
a second embodiment of a stamp,
Figure 6
shows a plastically deformed carrier body, corresponding to Figure 4,
Figure 7
a plastically deformed carrier body by deformation with a stamp according to Figure 5 and
Figure 8
a carrier body in partial section.

Der Katalysator-Trägerkörper 1 weist eine Vielzahl von einem Abgas durchströmbarer Kanäle 2 auf. Die Kanäle 2 werden durch abwechselnde Anordnung von strukturierten Blechlagen 12 und glatten Blechlagen 13 gebildet. Jeder Kanal weist einen freien Strömungsquerschnitt 4 auf, der durch die Kanalwände 11 begrenzt wird. Die Kanalwände werden durch die Blechlagen 12, 13 gebildet. Zur plastischen Verformung in einem äußeren ringförmigen Bereich 3 des Katalysator-Trägerkörpers 1 wird dieser, wie aus der Figur 1 ersichtlich, in eine Matrize 7 eingestoßen. Hierzu kann der Katalysator-Trägerkörper 1 z. B. mittels nicht dargestellter Spannbacken gehalten und entsprechend in die Matrize 7 eingestoßen werden. In der Darstellung nach Figur 1 wird der Wabenkörper 1 mittels eines Werkzeuges 14 in die Matrize eingestoßen. In der Matrize 7 ist eine ringförmige Wandung 8 ausgebildet. Die Breite des Rings entspricht der Breite der zu verschließenden Kanäle im Wabenkörper 1. An die Wandung 8 schließt sich ein Mantel 15 an, dessen innere Kontur mit der Außenkontur des Katalysator-Trägerkörpers 1 entspricht.The catalyst carrier body 1 has a plurality of exhaust gases flow-through channels 2. The channels 2 are alternating Arrangement of structured sheet metal layers 12 and smooth sheet metal layers 13 educated. Each channel has a free flow cross section 4, the is limited by the channel walls 11. The canal walls are covered by the sheet metal layers 12, 13 formed. For plastic deformation in one outer annular region 3 of the catalyst carrier body 1 this, as can be seen from FIG. 1, pushed into a die 7. For this purpose, the catalyst carrier body 1 z. B. by means of not shown Clamping jaws held and pushed into the die 7 accordingly will. In the illustration according to FIG. 1, the honeycomb body 1 is by means of a tool 14 pushed into the die. In the die 7 is an annular wall 8 is formed. The width of the ring corresponds the width of the channels to be closed in the honeycomb body 1. To the Wall 8 is followed by a jacket 15, the inner contour of which corresponds to the outer contour of the catalyst carrier body 1.

In der Figur 2 ist ein zweites Ausführungsbeispiel einer Matrize 7 dargestellt. Die Matrize 7 hat eine Wandung 8, die konisch ausgebildet ist.FIG. 2 shows a second exemplary embodiment of a die 7 shown. The die 7 has a wall 8 which is conical is.

In der Figur 3 ist ein Wabenkörper 1 dargestellt, die in eine entsprechende Matrize 7 nach Figur 2 eingestoßen wurde. In dem ringförmigen Bereich 3 sind die Kanäle 2 verschlossen. Der Randbereich des Trägerkörpers 1 ist entsprechend schräg ausgebildet.A honeycomb body 1 is shown in FIG Die 7 was pushed in according to Figure 2. In the ring-shaped Area 3, channels 2 are closed. The edge area of the carrier body 1 is designed obliquely.

Statt den Trägerkörper 1 in die Matrize 7 einzustoßen, wird vorgeschlagen, die plastische Verformung der Kanäle 2 mittels eines Stempels 9 bzw. 9' zu verschließen. Der Stempel 9 bzw. 9' ist hin und her bewegbar und weist einen ringförmigen Absatz 16 auf. Instead of pushing the carrier body 1 into the die 7, it is proposed that the plastic deformation of the channels 2 by means of a stamp 9 or 9 'to close. The stamp 9 or 9 'can be moved back and forth and has an annular shoulder 16.

Der Stempel 9' unterscheidet sich vom Stempel 9 dadurch, daß dieser eine schräg von innen nach außen verlaufende Wand 21 aufweist.The stamp 9 'differs from the stamp 9 in that this has a wall 21 which extends obliquely from the inside to the outside.

In den Figuren 6 und 7 sind Trägerkörper 1 dargestellt, wobei in der Figur 6 ein Trägerkörper im Schnitt dargestellt ist, bei dem im äußeren Ringbereich die Kanäle 2 mittels des Stempels 9 verschlossen worden sind. In der Figur 7 ist ein Trägerkörper dargestellt, bei dem ein Stempel 9' nach Figur 5 verwendet wurde.6 and 7 support bodies 1 are shown, in which Figure 6 shows a carrier body in section, in which in the outer In the ring area, the channels 2 have been closed by means of the stamp 9 are. FIG. 7 shows a carrier body in which a stamp 9 'according to FIG. 5 was used.

Die Herstellung der Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem, insbesondere in einem Abgassystem für Verbrennungskraftmaschinen, mit einem von einem Mantelrohr 10 umgebenden Katalysator-Trägerkörper 1, der eine Vielzahl von Kanälen 2 aufweist, kann dadurch hergestellt werden, daß die plastische Verformung des Mantelrohres 10 und der Kanäle 2 in einem äußeren Ringbereich 3 erfolgt, so daß der freie Strömungsquerschnitt 4 der Kanäle 2 teilweise in Strömungsrichtung des Abgases verschlossenn wird. Die plastische Verformung kann mittels eines Werkzeuges 17 erfolgen. Das Werkzeug 17 weist eine um eine Achse 19 verdrehbare Scheibe 18 auf, die an ihrem äußeren Randbereich im wesentlichen einen dreieckförmigen Querschnitt aufweist. Die Scheibe 18 wird mit einer Kraft gegen den Katalysator-Trägerkörper 1 und den Mantel 10 gedrückt, so daß eine plastische Verformung des Mantelrohres 10 und der Kanalwandungen erfolgt. Es wird eine umlaufende zum Trägerkörper 1 gerichtete Sicke 20 erzeugt. The manufacture of the device for the catalytic conversion of Exhaust gases in an exhaust system, especially in an exhaust system for Internal combustion engines, with one surrounded by a casing tube 10 Catalyst carrier body 1, which has a plurality of channels 2 has, can be produced in that the plastic deformation of the casing tube 10 and the channels 2 in an outer ring region 3 takes place so that the free flow cross section 4 of the channels 2 partially is closed in the flow direction of the exhaust gas. The plastic one Deformation can take place by means of a tool 17. The tool 17 has a disk 18 which can be rotated about an axis 19 and which its outer edge region is essentially triangular Has cross section. The disc 18 is with a force against the Catalyst carrier body 1 and the jacket 10 pressed so that a plastic deformation of the casing tube 10 and the channel walls he follows. There is a circumferential bead 20 directed towards the carrier body 1 generated.

Das Werkzeug 17 kann um den Katalysator-Trägerkörper 1 rotieren. Es ist auch möglich, daß Werkzeug 17 stationär anzuordnen und den Katalysator-Trägerkörper 1 um seine Achse rotieren zu lassen.The tool 17 can rotate around the catalyst carrier body 1. It it is also possible to arrange the tool 17 stationary and the catalyst carrier body 1 to rotate around its axis.

Die Ausbildung der Sicke 20 kann stufenweise erfolgen, wozu das Werkzeug 17 entsprechend zugestellt wird. The formation of the bead 20 can be done in stages, for which the tool 17 is delivered accordingly.

BEZUGSZEICHENLISTEREFERENCE SIGN LIST

11
Katalysator-TrägerkörperCatalyst carrier body
22nd
Kanälechannels
33rd
RingbereichRing area
44th
StrömungsquerschnittFlow cross-section
55
Eintrittentry
66
Austrittexit
77
Matrizedie
88th
WandungWall
9,9'9.9 '
Stempelstamp
1010th
MantelrohrCasing pipe
1111
KanalwandCanal wall
12,1312.13
BlechlageSheet layer
1414
WerkzeugTool
1515
Mantelcoat
1616
Ringring
1717th
WerkzeugTool
1818th
Scheibedisc
1919th
Achseaxis
2020th
SickeSurround
2121
Wandwall

Claims (17)

  1. Apparatus for the catalytic conversion of exhaust gases in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, comprising a catalytic converter carrier body (1) having a plurality of passages (2) through which an exhaust gas can flow, characterised in that in an outer annular region (3) of the catalytic converter carrier body (1) the free flow cross-section (4) of the passages (2) is closed at least in a portion in the direction of flow of the exhaust gas by plastic deformation of the passage walls (11).
  2. Apparatus according to claim 1 characterised in that the passages (2) are closed in the region of the exhaust gas inlet (5).
  3. Apparatus according to claim 2 characterised in that the passages (2) are additionally closed in the region of the exhaust gas outlet (6).
  4. Apparatus according to claim 1, claim 2 or claim 3 wherein the passages (2) are formed in layer-wise mutually superposed relationship characterised in that up to five layers, preferably two layers, of the passages (2) are plastically deformed.
  5. A process for producing an apparatus for the catalytic conversion of exhaust gases in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, comprising a catalytic converter carrier body (1) having a plurality of passages (2) through which an exhaust gas can flow, characterised by plastic deformation of the passages (2) in an outer annular region (3) of the catalytic converter carrier body (1) so that the free flow cross-section (4) of the passages (2) is closed at least in a portion in the exhaust gas flow direction.
  6. A process according to claim 5 wherein the catalytic converter carrier body (1) is pushed into a die (7) for deformation of the passages (2).
  7. A process according to claim 6 characterised in that the catalytic converter carrier body (1) is pushed into a die (7) with a wall (8) of a conical configuration.
  8. A process according to claim 6 characterised in that the catalytic converter carrier body (1) is pushed into a die (7) having an annular wall (8).
  9. A process according to claim 5 characterised in that deformation of the passages (2) is effected by a ram (9, 9').
  10. A process according to claim 9 characterised in that deformation is effected by an annular ram (9).
  11. A process according to claim 10 characterised in that the annular ram (9') has a wall (21) which extends inclinedly from the inside outwardly.
  12. A process according to one or more of claims 5 to 11 characterised in that the catalytic converter carrier body (1) is counter-held during the plastic deformation.
  13. A process for producing an apparatus for the catalytic conversion of exhaust gas in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, comprising a catalytic converter carrier body (1) which is enclosed by a tubular casing (10) and which has a plurality of passages through which an exhaust gas can flow, characterised by plastic deformation of the tubular casing (10) and the passages (2) in an outer annular region (3) of the catalytic converter carrier body (1) in such a way that the free flow cross-section (4) of the passages (2) is closed at least in a portion in the exhaust gas flow direction.
  14. A process according to claim 13 characterised in that at least one peripherally extending crease (20) which is directed towards the carrier body (1) is formed in the tubular casing (10).
  15. A process according to claim 13 or claim 14 characterised in that the plastic deformation is produced by free shaping.
  16. A process according to claim 15 characterised in that the plastic deformation is produced by rolling.
  17. A process according to claim 15 characterised in that the plastic deformation is produced by kneading.
EP95936484A 1994-10-21 1995-10-12 Catalyst carrier element with internal insulation Expired - Lifetime EP0789807B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4437718 1994-10-21
DE4437718A DE4437718A1 (en) 1994-10-21 1994-10-21 Catalyst carrier body with an inner insulation
PCT/EP1995/004027 WO1996012876A1 (en) 1994-10-21 1995-10-12 Catalyst carrier element with internal insulation

Publications (2)

Publication Number Publication Date
EP0789807A1 EP0789807A1 (en) 1997-08-20
EP0789807B1 true EP0789807B1 (en) 1998-05-06

Family

ID=6531407

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95936484A Expired - Lifetime EP0789807B1 (en) 1994-10-21 1995-10-12 Catalyst carrier element with internal insulation

Country Status (7)

Country Link
US (1) US6274099B1 (en)
EP (1) EP0789807B1 (en)
JP (1) JP3801633B2 (en)
CN (1) CN1069947C (en)
DE (2) DE4437718A1 (en)
RU (1) RU2136910C1 (en)
WO (1) WO1996012876A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19639633A1 (en) * 1996-09-26 1998-04-02 Emitec Emissionstechnologie Honeycomb body with reduced thermal conductivity in the entry and exit area
DE19646025C2 (en) * 1996-11-08 1999-07-01 Heinrich Schuermann Heating arrangement for a catalyst
GB2325424B (en) * 1997-05-20 2001-01-24 Emitec Emissionstechnologie Production of a honeycomb body of twisted sheet layers
DE19723939C2 (en) * 1997-06-06 2003-02-27 Leico Werkzeugmaschb Gmbh & Co Process for producing an exhaust gas catalytic converter
US6391077B1 (en) * 1998-04-06 2002-05-21 Lead Industry Company, Ltd. Apparatus for removing fine particles in exhaust gas and apparatus for cleaning exhaust gas
CA2347376A1 (en) * 1999-08-30 2001-03-08 Yukihito Ichikawa Corrugated wall honeycomb structure and production method thereof
US10465585B2 (en) 2015-03-23 2019-11-05 Corning Incorporated Exhaust gas treatment article and methods of manufacturing same
WO2016182806A1 (en) 2015-05-08 2016-11-17 Corning Incorporated Housing, fluid stream treatment article, exhaust system and methods of manufacturing same
JP2016217305A (en) 2015-05-25 2016-12-22 本田技研工業株式会社 Exhaust emission control device of internal combustion engine
DE102018214929B4 (en) 2018-09-03 2022-01-27 Vitesco Technologies GmbH Catalyst with metallic honeycomb
CN113232243B (en) * 2021-01-16 2022-12-06 温州南冠机械有限公司 SCR denitration catalyst production mold and production method thereof

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Publication number Priority date Publication date Assignee Title
US3801289A (en) * 1972-05-19 1974-04-02 Corning Glass Works Catalytic converter
JPS5210491B2 (en) * 1972-10-20 1977-03-24
DE2312794A1 (en) * 1973-03-15 1974-09-19 Volkswagenwerk Ag CATALYST FOR THE CATALYTIC CLEANING OF EXHAUST GASES
US3904551A (en) * 1973-12-19 1975-09-09 Grace W R & Co Process for preparing an auto exhaust catalytic converter
DE2856030A1 (en) * 1978-12-23 1980-06-26 Sueddeutsche Kuehler Behr CARTRIDGE FOR EXHAUST GAS PURIFICATION
JPS56162220A (en) * 1980-05-20 1981-12-14 Ngk Insulators Ltd Ceramic honeycomb structural body
US5051241A (en) * 1988-11-18 1991-09-24 Pfefferle William C Microlith catalytic reaction system
US5219667A (en) * 1991-12-12 1993-06-15 Corning Incorporated Honeycomb structure and method of forming
DE9317050U1 (en) * 1993-11-08 1995-03-09 Emitec Emissionstechnologie Mechanically stabilized heating catalyst arrangement
JPH0842333A (en) * 1994-06-06 1996-02-13 Ford Motor Co Preparation of catalyst exhaust treating device

Also Published As

Publication number Publication date
JPH10508529A (en) 1998-08-25
EP0789807A1 (en) 1997-08-20
DE4437718A1 (en) 1996-04-25
CN1069947C (en) 2001-08-22
JP3801633B2 (en) 2006-07-26
US6274099B1 (en) 2001-08-14
WO1996012876A1 (en) 1996-05-02
CN1161727A (en) 1997-10-08
RU2136910C1 (en) 1999-09-10
DE59502127D1 (en) 1998-06-10

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