EP0789807A1 - Catalyst carrier element with internal insulation - Google Patents
Catalyst carrier element with internal insulationInfo
- Publication number
- EP0789807A1 EP0789807A1 EP95936484A EP95936484A EP0789807A1 EP 0789807 A1 EP0789807 A1 EP 0789807A1 EP 95936484 A EP95936484 A EP 95936484A EP 95936484 A EP95936484 A EP 95936484A EP 0789807 A1 EP0789807 A1 EP 0789807A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- channels
- catalyst carrier
- carrier body
- exhaust gas
- plastic deformation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/14—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2260/00—Exhaust treating devices having provisions not otherwise provided for
- F01N2260/08—Exhaust treating devices having provisions not otherwise provided for for preventing heat loss or temperature drop, using other means than layers of heat-insulating material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/02—Fitting monolithic blocks into the housing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/20—Methods or apparatus for fitting, inserting or repairing different elements by mechanical joints, e.g. by deforming housing, tube, baffle plate or parts thereof
Definitions
- the invention relates to a device for the catalytic conversion of exhaust gases in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, with a catalyst carrier body which has a plurality of channels through which an exhaust gas can flow and to a method for producing it such a device.
- the catalytic converter In order to achieve the most complete possible conversion of the hydrocarbons contained in a combustion engine and the carbon monoxide, the catalytic converter must have a minimum temperature at which the catalytic conversion of the components of the exhaust gas can take place. In general, one speaks of a so-called light-off temperature.
- the catalyst is heated by the hot exhaust gas in the cold start phase. It is also known to at least partially heat the catalyst carrier body electrically. So that the emission of pollutants during the cold start phase is as low as possible and for mechanical reasons, it has therefore been proposed to design the catalyst carrier body with an internal insulation in order to reduce the heat loss to the housing and the environment.
- an apparatus for the catalytic conversion of exhaust gases in an exhaust system in particular in an exhaust system of internal combustion engines, is known, the one in has a housing arranged metallic catalyst carrier body.
- the carrier body has a plurality of channels through which an exhaust gas can flow.
- the internal insulation of the catalyst carrier body is to be achieved in that a radially inwardly facing collar is arranged in front of the catalyst carrier body, the collar height of which is 3-15% of the catalyst diameter. is at least 1 mm. This collar creates a swirl zone in the exhaust gas flow, through which direct exposure of an outer annular area to the hot exhaust gas is avoided.
- a device for the catalytic conversion of exhaust gases in an exhaust gas system is known from DE G 87 12 267.7 U1.
- the device comprises a catalyst carrier body which has a multiplicity of flow channels for an exhaust gas and which is inserted in a sleeve-shaped housing.
- the housing is thermally insulated from the catalyst carrier body.
- the insulation is achieved in that the catalyst carrier body is arranged between end rings which seal at least the outer layer of the metallic matrix body and thus the outer flow channels in this matrix. This results in a closed, non-exhaust gas-flowed air gap in the outer region of the catalyst carrier body, which serves for thermal insulation.
- the present invention is based on the object of further developing the known devices for the catalytic conversion of exhaust gases in such a way that the production of a catalyst carrier body with internal insulation is simplified. Furthermore, a method for producing such a device for the catalytic conversion of exhaust gases is to be provided. This object is achieved by a device with the features of claim 1. Advantageous further developments are the subject of the subclaims.
- an air gap closed in the outer region of the catalyst carrier body is not brought about by additional rings or the like, but rather by the fact that the free flow cross section of the channels is partially, ie. H. is closed in at least one axial section, in the flow direction of the exhaust gas, by plastic deformation of the channel walls.
- This simplifies the manufacture of the device since now no collar or end ring has to be introduced into the housing.
- the catalyst carrier body consists of several wound sheet metal layers, the plastic deformation can take place during winding. This simplifies the manufacturing process of wound catalysts, since the winding process and the plastic deformation can take place simultaneously.
- the channels in the region of the exhaust gas inlet are preferably closed.
- the plastic deformation of the channels advantageously takes place before the application of a catalytically active layer to the catalyst carrier body.
- the coating and (washcoat) is usually applied by means of a suspension flowing through the catalyst carrier body.
- the catalyst carrier body can be arranged so that the suspension flows into the channels closed on one side.
- the washcoat then fills the channels. It forms thermal insulation. If the catalyst carrier body is arranged in such a way that the closed channels lie in the entry region of the suspension into the catalyst carrier body, the channels cannot be filled with the suspension. This improves the insulation, since the thermal conductivity of the catalyst carrier layer, which would fill the channel completely is better than that of the atmosphere contained in the channels.
- the channels in the exhaust gas inlet and exhaust gas outlet area are advantageously closed. If the plastic deformation does not completely close individual channels, this is compensated for by the subsequent coating, which closes the small gaps.
- the channels in the catalyst carrier body are formed in layers one above the other, it is advantageous to close the channels by plastic deformation in up to five layers, preferably two. This achieves an advantageous compromise between the necessary catalytically active surface and the thermal insulation, without the external dimensions of the catalyst carrier body having to be significantly increased.
- a method according to the invention for producing a device for the catalytic conversion of exhaust gases in an exhaust gas system is specified by the features of claim 5.
- Advantageous developments of the method are the subject of dependent claims 6 to 17.
- the method it is proposed to partially close the free flow cross section of the channels in the flow direction of the exhaust gas by plastically deforming the channels in an outer ring in the region of the catalyst carrier body.
- the plastic deformation can take place in that the catalyst carrier body is pushed into a die.
- the outer region of the carrier body is deformed, as a result of which the channels are closed.
- the insertion die can be provided with a conical or an annular wall.
- the plastic deformation of the channel walls can also take place in that a force is exerted on an outer ring area by means of a stamp, which leads to the plastic deformation of the channel walls.
- the stamp can be ring-shaped or with a wall that runs obliquely from the inside to the outside. If the stamp is provided with a wall running obliquely from the inside to the outside, the free flow cross sections of the channels are closed by bending the channel walls. In the case of an annular stamp, the channel walls are squeezed.
- Catalyst carrier bodies which consist of a large number of alternating structured and preferably smooth sheet metal layers. Such metallic catalyst carrier bodies are surrounded by a jacket tube. It is therefore proposed to carry out the plastic deformation of the casing tube and the channels in an outer ring area of the catalyst carrier body, such that the free flow cross section of the channels is partially closed in the flow direction of the exhaust gas.
- the plastic deformation of the casing tube and the channels can take place in that at least one inwardly directed circumferential bead is formed in the casing tube.
- the bead can also be used to connect the catalyst carrier body to a housing.
- the plastic deformation is advantageously carried out by free molding.
- the plastic deformation is preferably carried out by rolling or kneading.
- FIG. 1 schematically shows a catalyst carrier body and a matrix
- FIG. 2 shows a second form of a die
- FIG. 3 schematically shows a carrier body which was pushed into a die according to FIG. 2,
- Figure 4 shows a catalyst carrier body and a stamp in
- FIG. 5 shows a second exemplary embodiment of a stamp
- FIG. 6 shows a plastically deformed carrier body, corresponding to FIG. 4,
- FIG. 7 shows a plastically deformed carrier body by deformation with a stamp according to FIG. 5 and
- FIG. 8 shows a Crowgro ⁇ er in partial section.
- the catalyst carrier body 1 has a plurality of channels 2 through which an exhaust gas can flow.
- the channels 2 are formed by an alternating arrangement of structured sheet metal layers 12 and smooth sheet metal layers 13.
- Each channel has a free flow cross section 4 which is delimited by the channel walls 11.
- the channel walls are formed by the sheet metal layers 12, 13.
- the catalyst carrier body 1 z. B. held by means of clamping jaws, not shown, and pushed into the die 7 accordingly.
- the honeycomb body 1 is pushed into the die by means of a tool 14.
- An annular wall 8 is formed in the die 7.
- the width of the ring corresponds to the width of the channels to be closed in the honeycomb body 1.
- a wall 15 adjoins the wall 8, the inner contour of which corresponds to the outer contour of the catalyst carrier body 1.
- FIG. 2 shows a second exemplary embodiment of a die 7.
- the die 7 has a wall 8 which is conical.
- FIG. 3 shows a honeycomb body 1 which has been pushed into a corresponding die 7 according to FIG. 2.
- the channels 2 are closed in the annular region 3.
- the edge area of the carrier body 1 is correspondingly slanted.
- stamp 9 or 9 ' can be moved back and forth and has an annular shoulder 16.
- FIGS. 6 and 7 show carrier bodies 1, a carrier body being shown in section in FIG. 6, in which the channels 2 in the outer ring area have been closed by means of the stamp 9.
- FIG. 7 shows a carrier body in which a stamp 9 'according to FIG. 5 was used.
- the production of the device for the catalytic conversion of exhaust gases in an exhaust system, in particular in an exhaust system for internal combustion engines, with a catalyst carrier body 1 surrounding a jacket tube 10 and having a multiplicity of channels 2 can be produced in that the plastic Deformation of the casing tube 10 and the channels 2 takes place in an outer ring area 3, so that the free flow cross section 4 of the channels 2 is partially closed in the flow direction of the exhaust gas.
- the plastic deformation can take place by means of a tool 17.
- the tool 17 has a disk 18 which can be rotated about an axis 19 and which has an essentially triangular cross section at its outer edge region.
- the disc 18 is pressed with a force against the catalyst carrier body 1 and the jacket 10, so that there is a plastic deformation of the jacket tube 10 and the channel walls.
- a circumferential bead 20 directed toward the carrier body 1 is produced.
- the tool 17 can rotate around the catalyst carrier body 1. It is also possible to arrange the tool 17 in a stationary manner and to let the catalyst carrier body 1 rotate about its axis.
- the formation of the bead 20 can take place in stages, for which purpose the tool 17 is appropriately fed.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4437718 | 1994-10-21 | ||
DE4437718A DE4437718A1 (en) | 1994-10-21 | 1994-10-21 | Catalyst carrier body with an inner insulation |
PCT/EP1995/004027 WO1996012876A1 (en) | 1994-10-21 | 1995-10-12 | Catalyst carrier element with internal insulation |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0789807A1 true EP0789807A1 (en) | 1997-08-20 |
EP0789807B1 EP0789807B1 (en) | 1998-05-06 |
Family
ID=6531407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95936484A Expired - Lifetime EP0789807B1 (en) | 1994-10-21 | 1995-10-12 | Catalyst carrier element with internal insulation |
Country Status (7)
Country | Link |
---|---|
US (1) | US6274099B1 (en) |
EP (1) | EP0789807B1 (en) |
JP (1) | JP3801633B2 (en) |
CN (1) | CN1069947C (en) |
DE (2) | DE4437718A1 (en) |
RU (1) | RU2136910C1 (en) |
WO (1) | WO1996012876A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19639633A1 (en) * | 1996-09-26 | 1998-04-02 | Emitec Emissionstechnologie | Honeycomb body with reduced thermal conductivity in the entry and exit area |
DE19646025C2 (en) * | 1996-11-08 | 1999-07-01 | Heinrich Schuermann | Heating arrangement for a catalyst |
GB2325424B (en) * | 1997-05-20 | 2001-01-24 | Emitec Emissionstechnologie | Production of a honeycomb body of twisted sheet layers |
DE19723939C2 (en) * | 1997-06-06 | 2003-02-27 | Leico Werkzeugmaschb Gmbh & Co | Process for producing an exhaust gas catalytic converter |
US6391077B1 (en) * | 1998-04-06 | 2002-05-21 | Lead Industry Company, Ltd. | Apparatus for removing fine particles in exhaust gas and apparatus for cleaning exhaust gas |
KR100500223B1 (en) * | 1999-08-30 | 2005-07-11 | 니뽄 가이시 가부시키가이샤 | Corrugated wall honeycomb structure and production method thereof |
US10465585B2 (en) | 2015-03-23 | 2019-11-05 | Corning Incorporated | Exhaust gas treatment article and methods of manufacturing same |
WO2016182806A1 (en) | 2015-05-08 | 2016-11-17 | Corning Incorporated | Housing, fluid stream treatment article, exhaust system and methods of manufacturing same |
JP2016217305A (en) | 2015-05-25 | 2016-12-22 | 本田技研工業株式会社 | Exhaust emission control device of internal combustion engine |
DE102018214929B4 (en) | 2018-09-03 | 2022-01-27 | Vitesco Technologies GmbH | Catalyst with metallic honeycomb |
CN113232243B (en) * | 2021-01-16 | 2022-12-06 | 温州南冠机械有限公司 | SCR denitration catalyst production mold and production method thereof |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3801289A (en) * | 1972-05-19 | 1974-04-02 | Corning Glass Works | Catalytic converter |
JPS5210491B2 (en) * | 1972-10-20 | 1977-03-24 | ||
DE2312794A1 (en) * | 1973-03-15 | 1974-09-19 | Volkswagenwerk Ag | CATALYST FOR THE CATALYTIC CLEANING OF EXHAUST GASES |
US3904551A (en) * | 1973-12-19 | 1975-09-09 | Grace W R & Co | Process for preparing an auto exhaust catalytic converter |
DE2856030C2 (en) * | 1978-12-23 | 1987-02-12 | Süddeutsche Kühlerfabrik Julius Fr. Behr GmbH & Co KG, 7000 Stuttgart | Method for producing a carrier matrix wound from metal foils for an exhaust gas cartridge |
JPS56162220A (en) * | 1980-05-20 | 1981-12-14 | Ngk Insulators Ltd | Ceramic honeycomb structural body |
US5051241A (en) * | 1988-11-18 | 1991-09-24 | Pfefferle William C | Microlith catalytic reaction system |
US5219667A (en) * | 1991-12-12 | 1993-06-15 | Corning Incorporated | Honeycomb structure and method of forming |
DE9317050U1 (en) * | 1993-11-08 | 1995-03-09 | Emitec Gesellschaft für Emissionstechnologie mbH, 53797 Lohmar | Mechanically stabilized heating catalyst arrangement |
JPH0842333A (en) * | 1994-06-06 | 1996-02-13 | Ford Motor Co | Preparation of catalyst exhaust treating device |
-
1994
- 1994-10-21 DE DE4437718A patent/DE4437718A1/en not_active Withdrawn
-
1995
- 1995-10-12 EP EP95936484A patent/EP0789807B1/en not_active Expired - Lifetime
- 1995-10-12 DE DE59502127T patent/DE59502127D1/en not_active Expired - Lifetime
- 1995-10-12 RU RU97108131A patent/RU2136910C1/en not_active IP Right Cessation
- 1995-10-12 JP JP51361896A patent/JP3801633B2/en not_active Expired - Fee Related
- 1995-10-12 WO PCT/EP1995/004027 patent/WO1996012876A1/en active IP Right Grant
- 1995-10-12 CN CN95195785A patent/CN1069947C/en not_active Expired - Fee Related
-
1997
- 1997-04-21 US US08/843,804 patent/US6274099B1/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9612876A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE59502127D1 (en) | 1998-06-10 |
RU2136910C1 (en) | 1999-09-10 |
US6274099B1 (en) | 2001-08-14 |
EP0789807B1 (en) | 1998-05-06 |
WO1996012876A1 (en) | 1996-05-02 |
CN1069947C (en) | 2001-08-22 |
CN1161727A (en) | 1997-10-08 |
DE4437718A1 (en) | 1996-04-25 |
JP3801633B2 (en) | 2006-07-26 |
JPH10508529A (en) | 1998-08-25 |
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