EP0781967B1 - Annular combustion chamber for gas turbine - Google Patents
Annular combustion chamber for gas turbine Download PDFInfo
- Publication number
- EP0781967B1 EP0781967B1 EP96810777A EP96810777A EP0781967B1 EP 0781967 B1 EP0781967 B1 EP 0781967B1 EP 96810777 A EP96810777 A EP 96810777A EP 96810777 A EP96810777 A EP 96810777A EP 0781967 B1 EP0781967 B1 EP 0781967B1
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- EP
- European Patent Office
- Prior art keywords
- combustion chamber
- gas
- air
- turbine
- chamber according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/10—Air inlet arrangements for primary air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/045—Air inlet arrangements using pipes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
- F23R3/286—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply having fuel-air premixing devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/42—Continuous combustion chambers using liquid or gaseous fuel characterised by the arrangement or form of the flame tubes or combustion chambers
- F23R3/50—Combustion chambers comprising an annular flame tube within an annular casing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R2900/00—Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
- F23R2900/03041—Effusion cooled combustion chamber walls or domes
Definitions
- the invention relates to the field of combustion technology. It relates to a gas turbine ring combustion chamber, which is operated with premix burners, and a method for Operation of this device.
- Gas turbines essentially consist of the components compressor, Combustion chamber and turbine. For environmental reasons is increased instead of diffusion combustion worked with a low-pollutant premix combustion.
- the air coming out of the compressor is very high Speed (approx. 200 m / s) and is to the contained in it Recover kinetic energy, as lossless as possible delayed in a deflection diffuser.
- the speed in the combustion chamber strong at least locally downstream of the burner lowered. Usually a local recirculation zone with negative Speeds generated. In the combustion chamber the speed then about 50 m / s to a sufficient Preservation time and the heat transfer between hot gas and to keep the combustion chamber wall small. At the exit of the The combustion chamber accelerates again, so that on Entry of the turbine speeds up to close to the gas the speed of sound can be reached.
- the invention tries to avoid all these disadvantages. you is based on the task of a gas turbine ring combustion chamber, which is equipped with special premix burners develop, which is characterized by a small size and simplified compared to the known prior art is, with improved premixing of fuel and Air occurs with a lower total pressure drop.
- this is done in a gas turbine ring combustion chamber, which is arranged downstream of a compressor and on it Front plate with at least one arranged in a ring Premix burner row is equipped, achieved by direct downstream of the compressor outlet from the guide vanes of the last compressor series for each burner one as Diffuser-trained burner air duct leads to the latter downstream end there is at least one longitudinal vortex generator is located, at least in or downstream of the longitudinal vortex generator a fuel injection is provided and downstream the fuel injection ends in the combustion chamber Mixing channel of constant channel height and with a length that is approximately corresponds to twice the hydraulic duct height, is arranged.
- the combustion air is released immediately after it leaves the compressor into individual air flows for the burners and for the Cooling of the combustion chamber and turbine split, after that the speed of the air for the burners to about that delayed half the value of the compressor outlet speed, then at least one longitudinal vortex per combustion air duct generated in the air, during or downstream of the Longitudinal vortex generation fuel is added to the mixture now flows along in a mixing channel and with a total swirl contaminated flows into the combustion chamber and there finally burns.
- the advantages of the invention include that the combustion chamber compared to the prior art has smaller dimensions and the area to be cooled in the Combustion chamber is reduced. The pressure loss between the compressor outlet and turbine entry is smaller. Furthermore there is a very good and robust uniform distribution of the air on the burners and the premixing of fuel and combustion air will be improved.
- the ratio of the number the blades of the last row of compressors to the number of premix burners is an integer, especially 1 or 2, because then a combustion air duct directly to one or two blade ducts the last row of compressors can be coupled.
- the mixing channel is approximately rounded Cross-section, because then a good mixing of air and fuel is achieved. But also mixed channels with a rectangular cross section are conceivable. Likewise can if there is only one burner row, the mixing channel be designed as a segmented annular gap.
- combustion air channels are spiral are arranged around the axis of the gas turbine. In this way axial length can be saved.
- the axes of the mixing channels are advantageous (i.e. the direction of flow of the entering the combustion chamber Mixture), arranged so that it coincides with the axis of the Gas turbine an angle, preferably an angle of 45 °, form. This will allow the mixture and flame stabilization further improved.
- FIG. 1 shows a partial longitudinal section of a gas turbine system with an annular combustion chamber according to the prior art.
- an annular combustion chamber 4 Between a compressor 1 and a turbine 2, of which only one guide vane 3 of the first row of guide vanes is shown is an annular combustion chamber 4, which with premix burners 5 of the double cone design is equipped, arranged.
- the supply of fuel 6 to each premix burner 5 is realized over fuel lances 7.
- the annular combustion chamber 4 is cooled convectively or by means of impingement cooling.
- the compressor 1 essentially consists of the blade carrier 8, in which the guide vanes 9 are hooked in and out of the rotor 10, which receives the blades 11. In Fig. 1 are each only the last compressor stages are shown.
- a deflection diffuser 12 At the exit of the Compressor 1, a deflection diffuser 12 is arranged. It ends in a arranged between the compressor 1 and the annular combustion chamber 4 Plenary 13.
- the air 14 emerging from the compressor 1 has a very high high speed. It is delayed in the deflection diffuser 12, to recover the kinetic energy it contains so that in the adjoining the deflection diffuser 12 Plenary 13 only very low air speeds to rule. This can result in a uniform distribution of the air 14 the burner 5 can be reached and there can be cooling air without any problems for the combustion chamber 4 and the turbine 2 are removed. There but on the other hand for the reliable design of the premixing process of air 14 and fuel 6 at the mixing point the fuel 6 the speed in order to avoid must be high from flashback, the air 14 in the premixing zone be accelerated again strongly before again downstream of the burner 5 in the combustion chamber 4 for reasons of flame stability the speed is reduced.
- Air 14 is no longer delayed to plenary conditions, but instead the delay in the air 14 is only limited to that Speed level of the premix section. This allows the multiple redirection of the total air mass flow is eliminated and the size of the combustion chamber is significantly reduced become.
- each burner 5 of the annular combustion chamber 4 each designed as a diffuser Burner air duct 15 leads.
- At least one fuel injection 17 is provided and downstream of the fuel injection 17 is in the combustion chamber 4 ending mixing channel 19 of constant height H and with a length L, which is about twice the value of the hydraulic channel diameter D corresponds to arranged.
- the deflection diffuser 12 and 12 is therefore omitted plenary session 13.
- the air from the compressor 1 is immediately after the outlet from the compressor 1 into a large number of individual channels divided, namely into the combustion air channels 15 and in annular Channels 20 arranged on the hub side or housing side for the cooling air 21 of the combustion chamber 4 and the turbine 2, the is provided here at a high pressure level. Furthermore can air 22 from the channels 20 for flushing out the Mixing channel 19 forming boundary layer can be removed. This is only an example for the innermost mixing channel 19 shown.
- the combustion air channels 15 are designed as diffusers and delay the air speed to about half the value the compressor outlet speed, with a maximum of 75% of the dynamic energy can be converted into pressure gain.
- the longitudinal vortex generator 16 After the combustion air 14 to an appropriate speed level was delayed at the longitudinal vortex generator 16 generates one or more longitudinal vortices per combustion air duct 15.
- the longitudinal vortex generator 16 is an integrated Fuel injection 17 fuel 6, which for example is supplied by fuel lances 7, mixed with the air 14.
- the fuel injection 17 also downstream of the longitudinal vortex generator 16 may be arranged.
- the longitudinal vortices generated guarantee a good mixture of fuel 6 and combustion air 14 in the subsequent mixing channels 19. These have a constant height H and are approximately double as long as two hydraulic channel diameters D.
- the mixing channels 19 have a circular shape Cross section, are therefore a mixing tube.
- the mixing tube axes 24 are arranged parallel to the axis 25 of the gas turbine.
- the mixing channels 19 not shown here in the drawing can the mixing channels 19 a right or have polygonal cross-section or they can also be a segmented annular gap.
- FIGS. 1 and 2 the reduction in the area of the combustion chamber wall to be cooled can be clearly seen according to the invention.
- a gas turbine from the 170 MWel class, eg GT13E2 should serve as an example. While according to the prior art (FIG. 1) the outer diameter in the area of the combustion chamber is approximately 4.5 m, this value is only 3.5 m when using the invention, so that the size is reduced by approx. 20% is reached. Due to the greatly reduced area to be cooled in the new combustion chamber and the extremely low NOx emissions that can be achieved with good premix burner technology at relatively high flame temperatures (theoretically approx. 5 ppm NOx at 15% O 2 and 1850 K flame temperature), the combustion chamber can be cooled via film or effusion cooling.
- FIG. 3 is a partial cross section of a two-row annular combustion chamber corresponding to a section in the plane III-III of the in Fig. 2 shown four-row combustion chamber.
- the annular combustion chamber 4 according to FIG. 3 is thus with two rows Premix burners 5 equipped.
- the arrows in Fig. 3 are intended an opposite angle of attack of the burner 5 in the side by side Clarify rows. By this opposite Angle of attack is achieved in the combustion chamber 4 no total swirl is generated.
- the cross section of the mixing channels 19 is not round in this embodiment, but elliptical.
- the mixing tube axes 24 are opposite the shaft in the circumferential direction, i.e. the mixing tube axis 24 forms an angle of ⁇ with the machine axis 25 approx. 45 °. This will allow the mixture and flame stabilization improved in the combustion chamber 4.
- combustion air channels 15 spiral about the axis 25 of the Gas turbine arranged to the axial length of the machine to keep it as small as possible.
- the invention is particularly suitable for the use of MBtu as fuel, i.e. fuel with a medium calorific value, for example in the gasification of heavy oil, coal and Tar arises.
- the fuel admixture can be used in this case very easily into a higher speed range (> 100 m / s) to be relocated to these fuels, too are characterized by a high flame speed, to avoid backfire to the fuel injector.
- the high-frequency generated by the last row of compressor runs (> 1000 Hz) pressure pulsations (wake of the blades) particularly support the fuel-air mixing process, because between the end of the compressor 1 and the fuel injection 17 only a short delay section, i.e. a short burner air duct 15 designed as a diffuser, is required
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Description
Die Erfindung bezieht sich auf das Gebiet der Verbrennungstechnik. Sie betrifft eine Gasturbinenringbrennkammer, welche mit Vormischbrennern betrieben wird, sowie ein Verfahren zum Betrieb dieser Vorrichtung.The invention relates to the field of combustion technology. It relates to a gas turbine ring combustion chamber, which is operated with premix burners, and a method for Operation of this device.
Gasturbinen bestehen im wesentlichen aus den Bauteilen Verdichter, Brennkammer und Turbine. Aus Gründen des Umweltschutzes wird anstelle einer Diffusionsverbrennung vermehrt mit einer schadstoffarmen Vormischverbrennung gearbeitet.Gas turbines essentially consist of the components compressor, Combustion chamber and turbine. For environmental reasons is increased instead of diffusion combustion worked with a low-pollutant premix combustion.
Es ist bekannter Stand der Technik (vgl. H. Neuhoff und K.
Thoren: "Die neuen Gasturbinen GT 24 und GT 26 - hohe Wirkungsgrade
dank sequentieller Verbrennung", ABB Technik
2(1994), S. 4-7 und D. Viereck: "Die Gasturbine GT13E2 - ein
richtungsweisendes Konzept für die Zukunft", ABB Technik
6(1993), S. 11-16), zwischen dem Verdichter und der mit mehreren
Vormischbrennern ausgerüsteten Ringbrennkammer einer
Gasturbine ein Plenum anzuordnen, in dem sehr geringe Luftgeschwindigkeiten
herrschen. Durch das Plenum soll eine Gleichverteilung
der Luft auf die Brenner erreicht werden. Zusätzlich
wird damit eine Möglichkeit geschaffen, Kühlluft für die
Brennkammer und die Turbine auf hohem Druckniveau zu entnehmen.It is known prior art (see H. Neuhoff and K.
Thoren: "The new
Die aus dem Verdichter austretende Luft hat eine sehr hohe Geschwindigkeit (ca. 200 m/s) und wird, um die in ihr enthaltene kinetische Energie zurückzugewinnen, möglichst verlustfrei in einem Umlenkdiffusor verzögert.The air coming out of the compressor is very high Speed (approx. 200 m / s) and is to the contained in it Recover kinetic energy, as lossless as possible delayed in a deflection diffuser.
Um eine schadstoffarme Verbrennung zu erreichen, werden Brennstoff und Verbrennungsluft im Brenner vorgemischt. Zwecks betriebssicherer Gestaltung des Vormischvorgangs muss an der Einmischungsstelle, in deren Nähe sich eine Zone mit stöchiometrischem Gemisch befindet, die Geschwindigkeit aber sehr hoch sein, damit ein Rückschlagen der Flamme sicher vermieden werden kann. Die Luft, die im Plenum nur noch sehr geringe Geschwindigkeiten (ca. 10 m/s) aufweist, muss daher wieder auf hohe Geschwindigkeiten (ca. 80 bis 100 m/s) in der Vormischzone beschleunigt werden.In order to achieve low-pollution combustion, Fuel and combustion air premixed in the burner. For the operationally reliable design of the premixing process at the point of interference, in the vicinity of which there is a zone with stoichiometric mixture, but the speed be very high so that the flame does not kick back can be. The air in the plenum is very low Speeds (approx. 10 m / s) must therefore back to high speeds (approx. 80 to 100 m / s) in the Premix zone can be accelerated.
Um die Flamme stromab des Vormischbrenners an einem festen Ort zu stabilisieren, wird die Geschwindigkeit in der Brennkammer zumindestens lokal stromab des Brenners wieder stark abgesenkt. Meist wird eine lokale Rezirkulationszone mit negativen Geschwindigkeiten erzeugt. In der Brennkammer beträgt die Geschwindigkeit dann etwa 50 m/s, um eine hinreichende Verweilzeit zu erhalten und den Wärmeübergang zwischen Heissgas und Brennkammerwand klein zu halten. Am Austritt der Brennkammer erfolgt wiederum eine Beschleunigung, so dass am Eintritt der Turbine Geschwindigkeiten des Gases bis nahe an die Schallgeschwindigkeit erreicht werden.Around the flame downstream of the premix burner on a fixed Stabilize place, the speed in the combustion chamber strong at least locally downstream of the burner lowered. Usually a local recirculation zone with negative Speeds generated. In the combustion chamber the speed then about 50 m / s to a sufficient Preservation time and the heat transfer between hot gas and to keep the combustion chamber wall small. At the exit of the The combustion chamber accelerates again, so that on Entry of the turbine speeds up to close to the gas the speed of sound can be reached.
Die mehrfachen Beschleunigungen und Verzögerungen der strömenden Medien (Luft, Brennstoff/Luft-Gemisch, Heissgase) zwischen Verdichteraustritt und Turbineneintritt haben den Nachteil, dass sie jeweils mit Verlusten behaftet sind. Sie erfordern ausserdem mehrfache Umlenkungen des gesamten Luftmassenstromes, da der Abstand zwischen Verdichteraustritt und Turbineneintritt aus rotordynamischen Gründen klein gehalten werden muss, so dass dadurch die Baugrösse der Brennkammer nach dem bekannten Stand der Technik recht gross und kompliziert ist.The multiple accelerations and decelerations of the flowing Media (air, fuel / air mixture, hot gases) between Compressor outlet and turbine inlet have the disadvantage that they are each subject to losses. You require in addition, multiple redirections of the entire air mass flow, because the distance between the compressor outlet and Turbine inlet kept small for rotor dynamic reasons must be, so that the size of the combustion chamber quite large and complicated according to the known prior art is.
Die Erfindung versucht, all diese Nachteile zu vermeiden. Ihr liegt die Aufgabe zugrunde, eine Gasturbinenringbrennkammer, welche mit speziellen Vormischbrennern ausgerüstet ist, zu entwickeln, die sich durch eine geringe Baugrösse auszeichnet und gegenüber dem bekannten Stand der Technik vereinfacht ist, wobei eine verbesserte Vormischung von Brennstoff und Luft bei einem geringeren Gesamtdruckverlust erfolgt.The invention tries to avoid all these disadvantages. you is based on the task of a gas turbine ring combustion chamber, which is equipped with special premix burners develop, which is characterized by a small size and simplified compared to the known prior art is, with improved premixing of fuel and Air occurs with a lower total pressure drop.
Erfindungsgemäss wird dies bei einer Gasturbinenringbrennkammer, welche stromab eines Verdichters angeordnet und auf ihrer Frontplatte mit mindestens einer ringförmig angeordneten Vormischbrennerreihe bestückt ist, dadurch erreicht, dass direkt stromab des Verdichteraustritts von den Leitschaufeln der letzten Verdichterreihe zu jedem Brenner jeweils ein als Diffusor ausgebildeter Brennerluftkanal führt, an dessem stromabwärtigen Ende sich mindestens ein Längswirbelerzeuger befindet, wobei im oder stromab des Längswirbelerzeugers mindestens eine Brennstoffeindüsung vorgesehen ist und stromab der Brennstoffeindüsung ein in die Brennkammer endender Mischkanal konstanter Kanalhöhe und mit einer Länge, die etwa dem zweifachen Wert der hydraulischen Kanalhöhe entspricht, angeordnet ist.According to the invention, this is done in a gas turbine ring combustion chamber, which is arranged downstream of a compressor and on it Front plate with at least one arranged in a ring Premix burner row is equipped, achieved by direct downstream of the compressor outlet from the guide vanes of the last compressor series for each burner one as Diffuser-trained burner air duct leads to the latter downstream end there is at least one longitudinal vortex generator is located, at least in or downstream of the longitudinal vortex generator a fuel injection is provided and downstream the fuel injection ends in the combustion chamber Mixing channel of constant channel height and with a length that is approximately corresponds to twice the hydraulic duct height, is arranged.
Die Verbrennungsluft wird direkt nach Austritt aus dem Verdichter in einzelne Luftströme für die Brenner und für die Kühlung der Brennkammer und Turbine aufgeteilt, danach wird die Geschwindigkeit der Luft für die Brenner auf etwa den halben Wert der Verdichteraustrittsgeschwindigkeit verzögert, anschliessend wird pro Brennluftkanal mindestens ein Längswirbel in der Luft erzeugt, wobei während oder stromab der Längswirbelerzeugung Brennstoff beigemischt wird, das Gemisch nunmehr in einem Mischkanal entlangströmt und mit einem Gesamtdrall behaftet in die Brennkammer strömt und dort schliesslich verbrennt.The combustion air is released immediately after it leaves the compressor into individual air flows for the burners and for the Cooling of the combustion chamber and turbine split, after that the speed of the air for the burners to about that delayed half the value of the compressor outlet speed, then at least one longitudinal vortex per combustion air duct generated in the air, during or downstream of the Longitudinal vortex generation fuel is added to the mixture now flows along in a mixing channel and with a total swirl contaminated flows into the combustion chamber and there finally burns.
Die Vorteile der Erfindung bestehen unter anderem darin, dass die Brennkammer im Vergleich zum bisherigen Stand der Technik geringere Abmasse aufweist und die zu kühlende Fläche in der Brennkammer verringert wird. Der Druckverlust zwischen Verdichteraustritt und Turbineneintritt ist kleiner. Ausserdem erfolgt eine sehr gute und robuste Gleichverteilung der Luft auf die Brenner und die Vormischung von Brennstoff und Verbrennungsluft wird verbessert.The advantages of the invention include that the combustion chamber compared to the prior art has smaller dimensions and the area to be cooled in the Combustion chamber is reduced. The pressure loss between the compressor outlet and turbine entry is smaller. Furthermore there is a very good and robust uniform distribution of the air on the burners and the premixing of fuel and combustion air will be improved.
Es ist besonders zweckmässig, wenn das Verhältnis der Anzahl der Schaufeln der letzten Verdichterreihe zur Anzahl der Vormischbrenner ganzzahlig, insbesondere 1 oder 2 ist, weil dann ein Brennluftkanal unmittelbar an ein oder zwei Schaufelkanäle der letzten Verdichterreihe angekoppelt werden kann.It is particularly useful if the ratio of the number the blades of the last row of compressors to the number of premix burners is an integer, especially 1 or 2, because then a combustion air duct directly to one or two blade ducts the last row of compressors can be coupled.
Von Vorteil ist es, wenn der Mischkanal einen annähernd runden Querschnitt aufweist, weil dann eine gute Durchmischung von Luft und Brennstoff erreicht wird. Aber auch Mischkanäle mit einem rechteckigen Querschnitt sind denkbar. Ebenso kann beim Vorhandensein von nur einer Brennerreihe der Mischkanal als ein segmentierter Ringspalt ausgebildet sein.It is advantageous if the mixing channel is approximately rounded Cross-section, because then a good mixing of air and fuel is achieved. But also mixed channels with a rectangular cross section are conceivable. Likewise can if there is only one burner row, the mixing channel be designed as a segmented annular gap.
Ferner ist es vorteilhaft, wenn die Brennluftkanäle spiralig um die Achse der Gasturbine angeordnet sind. Auf diese Weise kann axiale Länge gespart werden.It is also advantageous if the combustion air channels are spiral are arranged around the axis of the gas turbine. In this way axial length can be saved.
Schliesslich werden mit Vorteil die Achsen der Mischkanäle (d.h. die Strömungsrichtung des in die Brennkammer eintretenden Gemisches), so angeordnet, dass sie mit der Achse der Gasturbine einen Winkel, vorzugsweise einen Winkel von 45°, bilden. Dadurch wird die Mischung und Flammenstabilisierung weiter verbessert.Finally, the axes of the mixing channels are advantageous (i.e. the direction of flow of the entering the combustion chamber Mixture), arranged so that it coincides with the axis of the Gas turbine an angle, preferably an angle of 45 °, form. This will allow the mixture and flame stabilization further improved.
Weiterhin ist es zweckmässig, wenn beim Vorhandensein von mehr als einer ringförmigen Vormischbrennerreihe die Brenner von Reihe zu Reihe gegensinnig in Umfangsrichtung angestellt sind. Dadurch wird der Gesamtdrall in der Brennkammer zu Null.Furthermore, it is useful if in the presence of more than one ring-shaped premix burner row from row to row in opposite directions in the circumferential direction are. As a result, the total swirl in the combustion chamber becomes too Zero.
Es ist ausserdem von Vorteil wenn zusätzlich Luft in die Grenzschicht des Mischkanales eingedüst wird, weil dadurch ein Flammenrückschlag in die Mischzone weiter verhindert wird.It is also an advantage if there is additional air in the Boundary layer of the mixing channel is injected because of this a flashback in the mixing zone is further prevented becomes.
Vorteilhaft ist es, wenn bei Verwendung von Brennstoff mit mittlerem Heizwert (MBtu) dieser in einen Bereich hoher Luftgeschwindigkeit (>100 m/s) eingemischt wird. Dadurch wird auch bei diesen Brennstoffen, die eine sehr hohe Flammengeschwindigkeit aufweisen, ein Rückzünden zum Brennstoffinjektor sicher vermieden.It is advantageous if when using fuel with average calorific value (MBtu) of this in an area of high air speed (> 100 m / s) is mixed in. This will even with these fuels, which have a very high flame speed have backfire to the fuel injector safely avoided.
In der Zeichnung sind mehrere Ausführungsbeispiele der Erfindung dargestellt.In the drawing are several embodiments of the invention shown.
Es zeigen:
- Fig. 1
- einen Teillängsschnitt einer Gasturbinenanlage mit einer mit Vormischbrennern bestückten Ringbrennkammer nach dem Stand der Technik;
- Fig. 2
- einen Teillängsschnitt einer Gasturbinenanlage mit einer erfindungsgemässen vierreihigen Ringbrennkammer;
- Fig. 3
- einen Teilquerschnitt einer zweireihigen Brennkammer entsprechend einem Schnitt in der Ebene III-III der in Fig. 2 dargestellten vierreihigen Brennkammer;
- Fig. 4
- eine Abwicklung der Vormischstrecke (entlang IV-IV in Fig. 3) zwischen Verdichteraustritt und Brennkammerfrontplatte .
- Fig. 1
- a partial longitudinal section of a gas turbine system with an annular combustion chamber equipped with premix burners according to the prior art;
- Fig. 2
- a partial longitudinal section of a gas turbine plant with a four-row annular combustion chamber according to the invention;
- Fig. 3
- a partial cross section of a two-row combustion chamber corresponding to a section in the plane III-III of the four-row combustion chamber shown in Fig. 2;
- Fig. 4
- a settlement of the premixing section (along IV-IV in Fig. 3) between the compressor outlet and the combustion chamber front plate.
Es sind nur die für das Verständnis der Erfindung wesentlichen Elemente gezeigt. Nicht dargestellt sind von der Anlage beispielsweise das Abgasgehäuse der Gasturbine mit Abgasrohr und Kamin sowie die Eintrittspartien des Verdichterteils und die Niederdruckverdichterstufen. Die Strömungsrichtung der Arbeitsmittel ist mit Pfeilen bezeichnet.It is only essential for understanding the invention Elements shown. The system is not shown for example the exhaust gas casing of the gas turbine with an exhaust pipe and chimney and the inlet sections of the compressor section and the low pressure compressor stages. The flow direction of the Work equipment is indicated by arrows.
Nachfolgend wird die Erfindung anhand von Ausführungsbeispielen und der Fig. 1 bis 4 näher erläutert.The invention is described below using exemplary embodiments and FIGS. 1 to 4 explained in more detail.
Fig. 1 zeigt zunächst einen Teillängsschnitt einer Gasturbinenanlage
mit einer Ringbrennkammer nach dem Stand der Technik.
Zwischen einem Verdichter 1 und einer Turbine 2, von der
nur eine Leitschaufel 3 der ersten Leitschaufelreihe dargestellt
ist, ist eine Ringbrennkammer 4, welche mit Vormischbrennern
5 der Doppelkegelbauart bestückt ist, angeordnet.
Die Zufuhr des Brennstoffes 6 zu jedem Vormischbrenner 5 wird
über Brennstofflanzen 7 realisiert. Die Ringbrennkammer 4
wird konvektiv bzw. mittels Prallkühlung gekühlt. Der Verdichter
1 besteht im wesentlichen aus dem Schaufelträger 8,
in dem die Leitschaufeln 9 eingehängt sind und aus dem Rotor
10, der die Laufschaufeln 11 aufnimmt. In Fig. 1 sind jeweils
nur die letzten Verdichterstufen dargestellt. Am Austritt des
Verdichters 1 ist ein Umlenkdiffussor 12 angeordnet. Er mündet
in ein zwischen Verdichter 1 und Ringbrennkammer 4 angeordnetes
Plenum 13.1 shows a partial longitudinal section of a gas turbine system
with an annular combustion chamber according to the prior art.
Between a
Die aus dem Verdichter 1 austretende Luft 14 hat eine sehr
hohe Geschwindigkeit. Sie wird im Umlenkdiffusor 12 verzögert,
um die in ihr enthaltene kinetische Energie zurückzugewinnen,
so dass im sich an den Umlenkdiffusor 12 anschliessenden
Plenum 13 nur noch sehr geringe Luftgeschwindigkeiten
herrschen. Dadurch kann eine Gleichverteilung der Luft 14 auf
die Brenner 5 erreicht werden und es kann problemlos Kühlluft
für die Brennkammer 4 und die Turbine 2 entnommen werden. Da
aber andererseits zur betriebssicheren Gestaltung des Vormischvorgangs
von Luft 14 und Brennstoff 6 an der Einmischstelle
des Brennstoffes 6 die Geschwindigkeit zwecks Vermeidung
von Flammenrückschlag hoch sein muss, muss die Luft 14
in der Vormischzone wieder stark beschleunigt werden, bevor
wiederum stromab der Brenner 5 in der Brennkammer 4 aus Flammenstabilitätsgründen
eine Absenkung der Geschwindigkeit erfolgt.
Am stromabwärtigen Ende der Brennkammer 4 wird dann
das Gas wiederum beschleunigt, so dass am Eintritt in die
Turbine 2 Geschwindigkeiten nahe der Schallgeschwindigkeit
erreicht werden. Die mehrfache Beschleunigungen und Verzögerungen
zwischen Verdichteraustritt und Turbineneintritt sind
mit Verlusten behaftet und die erforderlichen mehrfachen Umlenkungen
des Luftmassenstromes führen zu einer recht grossen
Bauhöhe. So beträgt beispielsweise bei einer Gasturbine aus
der 170 MWel Klasse nach dem Stand der Technik (siehe Fig. 1)
der äussere Durchmesser im Bereich der Brennkammer ca. 4,5 m.The
In Fig. 2 ist ein Ausführungsbeispiel der Erfindung anhand
einer vierreihigen Gasturbinenringbrennkammer dargestellt. Im
Unterschied zum oben beschriebenen Stand der Technik wird die
Luft 14 nicht mehr auf Plenumsbedingungen verzögert, sondern
die Verzögerung der Luft 14 beschränkt sich nur noch auf das
Geschwindigkeitsniveau der Vormischstrecke. Dadurch kann die
mehrfache Umlenkung des Gesamtluftmassenstromes entfallen und
die Baugrösse im Bereich der Brennkammer wesentlich reduziert
werden.2 is an embodiment of the invention based on
a four-row gas turbine ring combustion chamber. in the
Difference from the prior art described above
Bei der in Fig. 2 dargestellten Ausführungsvariante der Erfindung
ist unmittelbar stromab des Verdichteraustritts an
den Leitschaufeln 9 der letzten Verdichterschaufelreihe ein
Brennerluftverteilersystem angeordnet, bei dem zu jedem Brenner
5 der Ringbrennkammer 4 jeweils ein als Diffusor ausgebildeter
Brennerluftkanal 15 führt. Am stromabwärtigen Ende
des Brennluftkanales 15 befindet sich mindestens ein Längswirbelerzeuger
16. Im oder stromab des Längswirbelerzeugers
16 ist mindestens eine Brennstoffeindüsung 17 vorgesehen und
stromab der Brennstoffeindüsung 17 ist ein in die Brennkammer
4 endender Mischkanal 19 konstanter Höhe H und mit einer Länge
L, die etwa dem zweifachen Wert des hydraulischen Kanaldurchmessers
D entspricht, angeordnet. Der hydraulische Kanaldurchmesser
ist definiert als Verhältnis der vierfaches
Querfläche des Kanals zum Kanalumfang. Bei einem kreisförmigen
Kanal gilt demnach: H=D.In the embodiment variant of the invention shown in FIG. 2
is immediately downstream of the compressor outlet
the
Gemäss der Erfindung entfällt somit der Umlenkdiffusor 12 und
das Plenum 13.According to the invention, the
Die Luft aus dem Verdichter 1 wird direkt nach dem Austritt
aus dem Verdichter 1 in eine Vielzahl von einzelnen Kanälen
aufgeteilt, und zwar in die Brennluftkanäle 15 und in ringförmige
nabenseitig bzw. gehäuseseitig angeordnete Kanäle 20
für die Kühlluft 21 der Brennkammer 4 und der Turbine 2, die
hier auf hohem Druckniveau bereitgestellt wird. Ausserdem
kann aus den Kanälen 20 Luft 22 zur Ausspülung der sich im
Mischkanal 19 ausbildenden Grenzschicht entnommen werden.
Dies ist nur für den innersten Mischkanal 19 beispielhaft
dargestellt. The air from the
Die Brennluftkanäle 15 sind als Diffusoren ausgestaltet und
verzögern die Luftgeschwindigkeit auf etwa den halben Wert
der Verdichteraustrittsgeschwindigkeit, wobei maximal 75% der
dynamischen Energie in Druckgewinn umgewandelt werden können.The
Nachdem die Verbrennungsluft 14 auf ein geeignetes Geschwindigkeitsniveau
verzögert wurde, werden am Längswirbelerzeuger
16 ein oder mehrere Längswirbel pro Brennluftkanal 15 erzeugt.
Im Längswirbelerzeuger 16 wird durch eine integrierte
Brennstoffeindüsung 17 Brennstoff 6, welcher beispielsweise
durch Brennstofflanzen 7 zugeführt wird, der Luft 14 beigemischt.
Selbstverständlich kann in einem anderen Ausführungsbeispiel
die Brennstoffeindüsung 17 auch stromab der Längswirbelerzeuger
16 angeordnet sein. Die erzeugten Längswirbel
garantieren eine gute Vermischung von Brennstoff 6 und Verbrennungsluft
14 in den sich anschliessenden Mischkanälen 19.
Diese weisen eine konstante Höhe H auf und sind etwa doppelt
so lang wie zwei hydraulische Kanaldurchmesser D. Im vorliegenden
Fall besitzen die Mischkanäle 19 einen kreisförmigen
Querschnitt, sind also ein Mischrohr. Die Mischrohrachsen 24
sind dabei parallel zur Achse 25 der Gasturbine angeordnet.
In anderen, hier nicht zeichnerisch dargestellten Ausführungsbeispielen
können die Mischkanäle 19 auch einen rechtoder
mehreckigen Querschnitt aufweisen oder sie können auch
ein segmentierten Ringspalt sein.After the
Es ist von Vorteil, wenn die vom Längswirbelerzeuger 16 hervorgerufenen
Längswirbel im Mischkanal 19 einen Gesamtdrall
erzeugen, der nach Austritt des Brennstoff/Luft-Gemisches 23
in die Brennkammer 4 zu einer hochturbulenten Flammenstabilisierungszone
führt, indem der Wirbel aufplatzt und auf der
Achse eine Zone mit sehr geringer oder negativer Axialgeschwindigkeit
erzeugt wird. Ein Flammenrückschlag in die
Mischzone kann durch ein ausgeglichenes Axialgeschwindigkeitsprofil
mit einer Überhöhung auf der Achse und durch eine
zusätzliche Eindüsung von Luft 22 in die Grenzschicht des
Mischkanales 19 sicher unterbunden werden.It is advantageous if those caused by the
Günstig ist es, wenn die Anzahl der Leitschaufeln 9 der letzten
Verdichterreihe und die Anzahl der Vormischbrenner 5 in
einem ganzzahligen Verhältnis zueinander stehen. Dadurch kann
ein Brennerluftkanal 15 unmittelbar an beispielsweise einen
oder zwei Schaufelkanäle der letzten Verdichterreihe angekoppelt
werden.It is expedient if the number of
Vergleicht man die Fig. 1 und 2, so ist deutlich die Reduktion der zu kühlenden Fläche der Brennkammerwand gemäss der Erfindung zu erkennen. Als Beispiel soll eine Gasturbine aus der 170 MWel Klasse, z.B. GT13E2, dienen. Während nach dem Stand der Technik (Fig. 1) der äussere Durchmesser im Bereich der Brennkammer etwa 4,5 m beträgt, ergibt sich für diesen Wert bei Einsatz der Erfindung nur noch 3,5 m, so dass eine Reduktion der Baugrösse um ca. 20% erreicht wird. Durch die stark verringerte zu kühlende Fläche in der neuen Brennkammer und durch die mit einer guten Vormischbrennertechnik erreichbaren extrem niedrigen NOx-Emmissionen bei relativ hohen Flammentemperaturen (theoretisch ca. 5 ppm NOx bei 15% O2 und 1850 K Flammentemperatur) kann die Kühlung der Brennkammer über Film- oder Effusionskühlung erfolgen.Comparing FIGS. 1 and 2, the reduction in the area of the combustion chamber wall to be cooled can be clearly seen according to the invention. A gas turbine from the 170 MWel class, eg GT13E2, should serve as an example. While according to the prior art (FIG. 1) the outer diameter in the area of the combustion chamber is approximately 4.5 m, this value is only 3.5 m when using the invention, so that the size is reduced by approx. 20% is reached. Due to the greatly reduced area to be cooled in the new combustion chamber and the extremely low NOx emissions that can be achieved with good premix burner technology at relatively high flame temperatures (theoretically approx. 5 ppm NOx at 15% O 2 and 1850 K flame temperature), the combustion chamber can be cooled via film or effusion cooling.
Fig. 3 und Fig. 4 zeigen ein weiteres Ausführungsbeispiel. In
Fig. 3 ist ein Teilquerschnitt einer zweireihigen Ringbrennkammer
entsprechend einem Schnitt in der Ebene III-III der in
Fig. 2 dargestellten vierreihigen Brennkammer dargestellt.
Die Ringbrennkammer 4 gemäss Fig. 3 ist somit mit zwei Reihen
Vormischbrennern 5 bestückt. Die Pfeile in Fig. 3 sollen
einen gegensinnigen Anstellwinkel der Brenner 5 in den nebeneinanderliegenden
Reihen verdeutlichen. Durch diesen gegensinnigen
Anstellwinkel wird erreicht, dass in der Brennkammer
4 kein Gesamtdrall erzeugt wird. Der Querschnitt der Mischkanäle
19 ist in diesem Ausführungsbeispiel nicht rund, sondern
elliptisch.3 and 4 show a further exemplary embodiment. In
Fig. 3 is a partial cross section of a two-row annular combustion chamber
corresponding to a section in the plane III-III of the in
Fig. 2 shown four-row combustion chamber.
The
In Fig. 4 ist eine Abwicklung der Vormischstrecke zwischen
dem Verdichteraustritt und der Brennkammerfrontplatte 18 entlang
IV-IV dargestellt. Die Mischrohrachsen 24 sind gegenüber
der Welle in Umfangsrichtung angestellt, d.h. die Mischrohrachse
24 bildet mit der Maschinenachse 25 einen Winkel von α
ca. 45°. Dadurch wird die Mischung und Flammenstabilisierung
in der Brennkammer 4 verbessert.4 is a settlement of the premix section between
along the compressor outlet and the
In einem weiteren, nicht dargestellten Ausführungsbeispiel
sind die Brennluftkanäle 15 spiralig um die Achse 25 der
Gasturbine angeordnet, um die axiale Länge der Maschine
möglichst klein zu halten.In a further embodiment, not shown
are the
Die Erfindung eignet sich besonders für die Verwendung von
MBtu als Brennstoff, also Brennstoff mit mittlerem Heizwert,
der beispielsweise bei der Vergasung von Schweröl, Kohle und
Teer entsteht. Die Brennstoffzumischung kann in diesem Falle
sehr einfach in einen Bereich höherer Geschwindigkeit (>100
m/s) verlegt werden, um auch bei diesen Brennstoffen, die
durch eine hohe Flammengeschwindigkeit charakterisiert sind,
ein Rückzünden zum Brennstoffinjektor sicher zu vermeiden.
Die durch die letzte Verdichterlaufreihe erzeugten hochfrequenten
(>1000 Hz) Druckpulsationen (Nachläufe der Schaufeln)
unterstützen hier den Brennstoff-Luft-Mischungsvorgang besonders,
weil zwischen dem Ende des Verdichters 1 und der Brennstoffeindüsung
17 nur eine kurze Verzögerungsstrecke, d.h.
ein kurzer als Diffusor ausgebildeter Brennerluftkanal 15,
erforderlich ist The invention is particularly suitable for the use of
MBtu as fuel, i.e. fuel with a medium calorific value,
for example in the gasification of heavy oil, coal and
Tar arises. The fuel admixture can be used in this case
very easily into a higher speed range (> 100
m / s) to be relocated to these fuels, too
are characterized by a high flame speed,
to avoid backfire to the fuel injector.
The high-frequency generated by the last row of compressor runs
(> 1000 Hz) pressure pulsations (wake of the blades)
particularly support the fuel-air mixing process,
because between the end of the
- 11
- Verdichtercompressor
- 22
- Turbineturbine
- 33
-
Leitschaufel von Pos. 2Guide vane from
item 2 - 44
- Ringbrennkammerannular combustion chamber
- 55
- Vormischbrennerpremix
- 5a5a
- äussere Brennerreiheouter row of burners
- 5b5b
- innere Brennerreiheinner row of burners
- 66
- Brennstofffuel
- 77
- Brennstofflanzefuel lance
- 88th
- Schaufelträgerblade carrier
- 99
-
Leitschaufel von Pos. 1Guide vane from
item 1 - 1010
- Rotorrotor
- 1111
- Laufschaufel von Pos. 1Blade from pos. 1
- 1212
- Umlenkdiffusordeflection diffusor
- 1313
- Plenumplenum
- 1414
- Luftair
- 1515
- als Diffusor ausgebildeter BrennluftkanalCombustion air duct designed as a diffuser
- 1616
- LängswirbelerzeugerLongitudinal vortex generators
- 1717
- Brennstoffeindüsungfuel injection
- 1818
- Frontplattefront panel
- 1919
- Mischkanalmixing channel
- 2020
-
Kanal für Pos. 21Channel for
item 21 - 2121
- Kühlluftcooling air
- 2222
- Luft zur Ausspülung der Grenzschicht in Pos. 19Air to flush out the boundary layer in pos. 19
- 2323
- Brennstoff/Luft-GemischFuel / air mixture
- 2424
-
Achse von Pos. 19Axis from
item 19 - 2525
- Maschinenachsemachine axis
- HH
-
Höhe von Pos. 19Height of
item 19 - LL
-
Länge von Pos. 19Length of
item 19 - DD
- hydraulischer Kanaldurchmesserhydraulic channel diameter
- αα
-
Winkel zwischen Pos. 24 und 25Angle between
24 and 25items
Claims (15)
- Gas-turbine annular combustion chamber (4) which is arranged downstream of a compressor (1) and is equipped on its front plate (18) with at least one row of premix burners (5) arranged in an annular form, characterized in that in each case a combustion-air duct (15) designed as a diffuser leads directly downstream of the compressor outlet from the guide vanes (9) of the last compressor row to each burner (5), at the downstream end of which combustion-air duct (15) at least one longitudinal-vortex generator (16) is located, at least one fuel injection means (17) being provided in or downstream of the longitudinal-vortex generator (16), and a mixing duct (19) which ends in the combustion chamber (4) and has a constant height (H) and a length (L) which corresponds approximately to twice the value of the hydraulic duct diameter (D) being arranged downstream of the fuel injection means (17).
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the ratio of the number of blades (9) of the last compressor row to the number of premix burners (5) is integral.
- Gas-turbine annular combustion chamber according to Claim 2, characterized in that the ratio of the number of blades (9) of the last compressor row to the number of premix burners (5) is one.
- Gas-turbine annular combustion chamber according to Claim 2, characterized in that the ratio of the number of blades (9) of the last compressor row to the number of premix burners (5) is two.
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the combustion-air ducts (15) are arranged spirally around the axis (25) of the gas turbine.
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the mixing duct (19) has a round cross section.
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the mixing duct (19) has a rectangular cross section.
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the mixing duct (19) is a segmented annular gap.
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the axes (24) of the mixing ducts (19) and the axis (25) of the gas turbine are parallel.
- Gas-turbine annular combustion chamber according to Claim 1, characterized in that the axes (24) of the mixing ducts (19) form an angle (α) with the axis (25) of the gas turbine.
- Gas-turbine annular combustion chamber according to Claim 10, characterized in that the angle (α) is about 45°.
- Gas-turbine annular combustion chamber according to one of claims 1 to 11, characterized in that, in the case of more than one annular premix-burner row, the burners (5) are set in an opposed manner from row (5a) to row (5b) in the peripheral direction.
- Method of operating a gas-turbine annular combustion chamber according to one of claims 1 to 12, characterized in that the combustion air (15), directly after discharge from the compressor (1), is split up into individual air flows for the burners and for the cooling of the combustion chamber and the turbine, in that the velocity of the air (14) for the burners (5) is then decelerated in the combustion-air ducts (15) to about half the value of the compressor outlet velocity, and in that at least one longitudinal vortex is then generated in the air (14) per combustion-air duct (15), fuel (6) being admixed during or downstream of the longitudinal-vortex generation, the mixture flowing along in a mixing duct (19) and flowing with an overall swirl imposed on it into the combustion chamber (4) and being burnt there.
- Method according to Claim 13, characterized in that air (22) is additionally injected into the boundary layer of the mixing duct (19).
- Method according to Claim 13, characterized in that, when fuel (6) having an average calorific value (MBtu) is used, this fuel (6) is intermixed in a region of high air velocity of greater than 100 m/s.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19549143 | 1995-12-29 | ||
DE19549143A DE19549143A1 (en) | 1995-12-29 | 1995-12-29 | Gas turbine ring combustor |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0781967A2 EP0781967A2 (en) | 1997-07-02 |
EP0781967A3 EP0781967A3 (en) | 1999-04-07 |
EP0781967B1 true EP0781967B1 (en) | 2003-04-02 |
Family
ID=7781645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96810777A Expired - Lifetime EP0781967B1 (en) | 1995-12-29 | 1996-11-12 | Annular combustion chamber for gas turbine |
Country Status (5)
Country | Link |
---|---|
US (1) | US5839283A (en) |
EP (1) | EP0781967B1 (en) |
JP (1) | JPH09196379A (en) |
CN (1) | CN1088151C (en) |
DE (2) | DE19549143A1 (en) |
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-
1995
- 1995-12-29 DE DE19549143A patent/DE19549143A1/en not_active Withdrawn
-
1996
- 1996-11-12 DE DE59610298T patent/DE59610298D1/en not_active Expired - Fee Related
- 1996-11-12 EP EP96810777A patent/EP0781967B1/en not_active Expired - Lifetime
- 1996-11-18 US US08/751,721 patent/US5839283A/en not_active Expired - Fee Related
- 1996-12-25 JP JP8345880A patent/JPH09196379A/en not_active Abandoned
- 1996-12-27 CN CN96123618A patent/CN1088151C/en not_active Expired - Fee Related
Also Published As
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JPH09196379A (en) | 1997-07-29 |
CN1088151C (en) | 2002-07-24 |
US5839283A (en) | 1998-11-24 |
DE59610298D1 (en) | 2003-05-08 |
EP0781967A2 (en) | 1997-07-02 |
EP0781967A3 (en) | 1999-04-07 |
CN1158383A (en) | 1997-09-03 |
DE19549143A1 (en) | 1997-07-03 |
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