EP0704519A1 - Mélange d'amines, polymères d'hydrocarbures et solvants huileux, convenant comme additif pour combustibles et lubrifiants - Google Patents

Mélange d'amines, polymères d'hydrocarbures et solvants huileux, convenant comme additif pour combustibles et lubrifiants Download PDF

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Publication number
EP0704519A1
EP0704519A1 EP95114693A EP95114693A EP0704519A1 EP 0704519 A1 EP0704519 A1 EP 0704519A1 EP 95114693 A EP95114693 A EP 95114693A EP 95114693 A EP95114693 A EP 95114693A EP 0704519 A1 EP0704519 A1 EP 0704519A1
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Prior art keywords
mixture
fuel
component
lubricant additive
weight
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EP95114693A
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German (de)
English (en)
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EP0704519B1 (fr
Inventor
Jürgen Dr. Thomas
Harald Dr. Schwahn
Peter Dr. Schreyer
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BASF SE
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BASF SE
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    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/28Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
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    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/48Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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Definitions

  • the invention further relates to the use of the mixture as fuel and lubricant additives and fuels for gasoline engines and lubricant compositions which contain the mixture in effective amounts.
  • Carburetor and intake systems of gasoline engines are increasingly contaminated by contaminants caused by dust particles from the air, unburned hydrocarbon residues from the combustion chamber and the ventilation gases from the crankshaft housing that are conducted into the carburetor .
  • the residues adsorb fuel and shift the air-fuel ratio at idle and in the lower part-load range, so that the mixture becomes richer, the combustion incomplete and in turn the proportions of unburned or partially burned hydrocarbons in the exhaust gas increase and the gasoline consumption increases.
  • the document (1) further teaches that in fuel additives up to about 50 wt .-% of the active substance, that is, the polyisobutylamine, can be replaced by polyisobutene without loss of effectiveness; such a replacement is primarily for cost reasons. There is no indication of an improvement in effectiveness with certain amounts of polyisobutene.
  • carrier oils Another important additive component for fuels are so-called carrier oils. These carrier oils are usually high-boiling, thermostable liquids.
  • EP-B 356 726 (2) discloses esters of aromatic polycarboxylic acids with long-chain alcohols as carrier oils.
  • EP-A 374 461 (3) describes combinations of polyethers based on propylene oxide and / or butylene oxide with a molecular weight of at least 500 with esters of mono- or polycarboxylic acids and alkanols of the polyols, these esters having a minimum viscosity of 2 mm2 / s at 100 ° C, described, which increase the efficiency of the detergent via synergistic mechanisms of action.
  • US Pat. No. 5,006,130 (4) discloses mixtures of aliphatic alkylene polyamines with at least one oil-soluble synthetic or mineral carrier oil.
  • WO-A 91/03529 (5) teaches the combination of detergents which carry certain amino groups with polyether alcohols as carrier oils. This combination contributes less than its individual components to the increase in octane requirement (ORI, Octane Requirement Increase), which results from deposits of fuel or additives on engine parts. A new engine only reaches its final octane requirement after a considerable operating time, which can then be considerably higher than at the beginning. In general, additives should at least not increase this effect.
  • the object of the present invention was therefore to provide fuel and lubricant additives with improved effectiveness as detergents.
  • the mixture defined at the outset was found, which is characterized by a weight ratio of component A to component B of 80:20 to 60:40, in particular 77:23 to 65:35.
  • Component A is primarily effective as a detergent in fuels.
  • Suitable component A are those amines which have a hydrocarbon radical with an average molecular weight of 500 to 10,000, preferably from 600 to 2500 and particularly preferably from 700 to 1500.
  • the hydrocarbon residue is usually branched.
  • such a residue is obtainable by polymerizing olefins.
  • olefins are preferably C2 to C6 olefins, such as ethylene, propylene, 1-butene, 1-pentene, but particularly preferably isobutene.
  • Both homopolymers and copolymers e.g. Polymers made from 70 to 100 wt% isobutene and 0 to 30 wt% 1-butene. Due to their manufacturing process, these polyolefins generally consist of a mixture of compounds of different molecular weights.
  • these polyolefins can be reacted with amines after chlorination.
  • hydroformylation of the polyolefin and amination of the aldehyde and alcohol mixture thus obtained is preferred under hydrogenating conditions, as described, for example, in (1), since this route leads to chlorine-free products.
  • the amine group of detergent A is derived from known amines such as ammonia, primary amines such as methylamine, ethylamine, butylamine, hexylamine, octylamine, secondary amines such as dimethylamine, diethylamine, dibutylamine, dioctylamine or heterocycles such as piperazine, pyrrolidine, morpholine, which may be further can carry inert substituents. Ammonia is particularly preferred.
  • component A is a polyisobutylamine with an average molecular weight of 700 to 1500, where up to 20% by weight of the isobutene units can be replaced by 1-butene units.
  • hydrocarbon polymer B Particularly suitable as hydrocarbon polymer B are the olefin polymers described as precursors to component A.
  • component B such olefin polymers have an average molecular weight of preferably 400 to 1750, in particular 500 to 1500.
  • the hydrocarbon polymer B can still contain olefinic double bonds due to the production process; however, such double bonds can also have been hydrogenated.
  • Component B can either be added separately or can be introduced into the mixture according to the invention by carrying out a suitable reaction in the preparation of component A from an excess of the olefin polymers described.
  • a very particularly preferred embodiment for component B is a polyisobutene with an average molecular weight of 500 to 1500, where up to 20% by weight of the isobutene units can be replaced by 1-butene units.
  • Both component A and component B can each be mixtures of different individual compounds.
  • carrier oils C can also be poly- ⁇ -olefins or polymers from internal olefins, i.e. Olefins with non-terminal double bonds can be used.
  • mixtures of the aforementioned carrier oils e.g. from (a) and (b), (a) and (c), (a) and (d), (b) and (c) or (c) and (d).
  • a component oil mixture of polyethers (b) and esters (d) is used as component C, with (b) and (d) preferably in a weight ratio of 20:80 to 80:20, in particular 35:65 until 65:35.
  • Component C is usually present in the mixture according to the invention in a ratio by weight to the sum of amine A and hydrocarbon polymer B of 5:95 to 85:15, in particular 20:80 to 70:30.
  • the mixture according to the invention can contain further components D, the amounts of D being 0 to 40% by weight, preferably 0 to 10% by weight, based on the total weight of components A to C. These components D only slightly influence the properties of the mixtures according to the invention with regard to their use in fuels.
  • Component D comprises additives known per se for mixtures which are added to fuels and lubricants. These include in particular corrosion inhibitors, demulsifiers, detergents or understand dispersants such as amides and imides of polyisobutyl succinic anhydride.
  • the present invention also relates to the use of the mixture of components A to C described as fuel and lubricant additives.
  • the present invention further relates to fuels for gasoline engines which contain effective amounts of the mixture according to the invention.
  • Leaded and unleaded regular and premium gasoline can be used as fuels.
  • the gasolines can also contain components other than hydrocarbons, e.g. Contain alcohols such as methanol, ethanol, tert-butanol and ethers such as methyl tert-butyl ether.
  • the fuels according to the invention generally contain the mixtures of components A to C in amounts of 10 to 5000 ppm, based on the total mass, preferably 50 to 1000 ppm.
  • the fuels according to the invention can also contain antioxidants, e.g. N, N'-di-sec-butyl-para-phenylenediamine, and stabilizers, e.g. N, N'-disalicylidene-1,2-diaminopropane.
  • Components A to C can be mixed to form clear, homogeneous solutions.
  • Additive fuels show significantly lower valve deposits than pure fuels. Furthermore, the additives do not contribute to an increase in the octane requirement (ORI).
  • ORI octane requirement
  • the present invention further relates to lubricant compositions which contain effective amounts of the mixture according to the invention.
  • Effective amounts are generally understood to mean 0.1 to 6% by weight, in particular 0.5 to 5% by weight, based on the weight of the lubricant composition.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Lubricants (AREA)
EP95114693A 1994-09-28 1995-09-19 Mélange d'amines, polymères d'hydrocarbures et solvants huileux, convenant comme additif pour combustibles et lubrifiants Expired - Lifetime EP0704519B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4434603 1994-09-28
DE4434603A DE4434603A1 (de) 1994-09-28 1994-09-28 Als Kraft- und Schmierstoffadditiv geeignete Mischung aus Aminen, Kohlenwasserstoffpolymeren und Trägerölen

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Publication Number Publication Date
EP0704519A1 true EP0704519A1 (fr) 1996-04-03
EP0704519B1 EP0704519B1 (fr) 1999-05-06

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Country Status (4)

Country Link
US (1) US6579329B1 (fr)
EP (1) EP0704519B1 (fr)
DE (2) DE4434603A1 (fr)
ES (1) ES2131243T3 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999040166A1 (fr) * 1998-02-06 1999-08-12 Basf Aktiengesellschaft Additifs solides pour carburants
EP0950704A1 (fr) * 1998-04-14 1999-10-20 The Lubrizol Corporation compositions contenant une amine substituée par un polyakene et un polyether alcool
WO2000002978A1 (fr) * 1998-07-09 2000-01-20 Basf Aktiengesellschaft Compositions de carburant contenant du propoxilate
WO2000014185A1 (fr) * 1998-09-08 2000-03-16 Infineum Usa Lp Compositions d'huile lubrifiante et carburants pour moteurs a deux temps
WO2000047698A1 (fr) * 1999-02-09 2000-08-17 Basf Aktiengesellschaft Composition de carburant
EP1104749A2 (fr) * 1999-11-09 2001-06-06 Basf Aktiengesellschaft Procédé d'oxyalkylation des alcanols avec des oxydes d'alkylène
WO2001085874A2 (fr) * 2000-05-05 2001-11-15 Basf Aktiengesellschaft Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission
WO2002022765A2 (fr) * 2000-09-13 2002-03-21 The Associated Octel Company Limited Composition
WO2003068895A1 (fr) * 2002-02-12 2003-08-21 Shell Internationale Research Maatschappij B.V. Compositions a base d'essence
US7601185B2 (en) 2002-03-06 2009-10-13 Basf Aktiengesellschaft Fuel additive mixtures for gasolines with synergistic IVD performance

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* Cited by examiner, † Cited by third party
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US7204863B2 (en) 2001-12-11 2007-04-17 Exxonmobil Research And Engineering Company Gasoline additives for reducing the amount of internal combustion engine intake valve deposits and combustion chamber deposits
US7226489B2 (en) 2001-12-12 2007-06-05 Exxonmobil Research And Engineering Company Gasoline additives for reducing the amount of internal combustion engine intake valve deposits and combustion chamber deposits
US20050160662A1 (en) * 2002-06-11 2005-07-28 Oryxe Energy International, Inc. Method and composition for using stabilized beta-carotene as cetane improver in hydrocarbonaceous diesel fuels
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WO1999040166A1 (fr) * 1998-02-06 1999-08-12 Basf Aktiengesellschaft Additifs solides pour carburants
EP0950704A1 (fr) * 1998-04-14 1999-10-20 The Lubrizol Corporation compositions contenant une amine substituée par un polyakene et un polyether alcool
AU744324B2 (en) * 1998-04-14 2002-02-21 Lubrizol Corporation, The Compositions containing polyalkene-subsituted amine and polyether alcohol
US6348075B1 (en) 1998-04-14 2002-02-19 The Lubrizol Corporation Compositions containing polyalkene-substituted amine and polyether alcohol
US7250065B1 (en) 1998-07-09 2007-07-31 Basf Aktiengesellschaft Fuel compositions containing propoxylate
AU751122C (en) * 1998-07-09 2003-07-03 Basf Aktiengesellschaft Fuel compositions containing propoxilate
WO2000002978A1 (fr) * 1998-07-09 2000-01-20 Basf Aktiengesellschaft Compositions de carburant contenant du propoxilate
AU751122B2 (en) * 1998-07-09 2002-08-08 Basf Aktiengesellschaft Fuel compositions containing propoxilate
US6498129B1 (en) 1998-09-08 2002-12-24 Exxon Chemical Patents Inc. Two-cycle lubricating oil containing polyisobutylene amine
WO2000014185A1 (fr) * 1998-09-08 2000-03-16 Infineum Usa Lp Compositions d'huile lubrifiante et carburants pour moteurs a deux temps
WO2000047698A1 (fr) * 1999-02-09 2000-08-17 Basf Aktiengesellschaft Composition de carburant
EP1277828A3 (fr) * 1999-02-09 2003-07-02 Basf Aktiengesellschaft Composition de combustible
EP1277828A2 (fr) * 1999-02-09 2003-01-22 Basf Aktiengesellschaft Composition de combustible
JP2002536531A (ja) * 1999-02-09 2002-10-29 ビーエーエスエフ アクチェンゲゼルシャフト 燃料組成物
EP1104749A2 (fr) * 1999-11-09 2001-06-06 Basf Aktiengesellschaft Procédé d'oxyalkylation des alcanols avec des oxydes d'alkylène
EP1104749A3 (fr) * 1999-11-09 2001-11-21 Basf Aktiengesellschaft Procédé d'oxyalkylation des alcanols avec des oxydes d'alkylène
WO2001085874A3 (fr) * 2000-05-05 2002-04-04 Basf Ag Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission
US6840970B2 (en) 2000-05-05 2005-01-11 Basf Aktiengesellschaft Fuel additive compositions for fuels for internal combustion engines with improved viscosity properties and good IVD performance
WO2001085874A2 (fr) * 2000-05-05 2001-11-15 Basf Aktiengesellschaft Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission
WO2002022765A2 (fr) * 2000-09-13 2002-03-21 The Associated Octel Company Limited Composition
WO2002022765A3 (fr) * 2000-09-13 2007-10-18 Ass Octel Composition
WO2003068895A1 (fr) * 2002-02-12 2003-08-21 Shell Internationale Research Maatschappij B.V. Compositions a base d'essence
US7601185B2 (en) 2002-03-06 2009-10-13 Basf Aktiengesellschaft Fuel additive mixtures for gasolines with synergistic IVD performance

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EP0704519B1 (fr) 1999-05-06
ES2131243T3 (es) 1999-07-16
DE59505828D1 (de) 1999-06-10
US6579329B1 (en) 2003-06-17

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