EP0680413A1 - Verfahren zur dekorativen beschichtung von substraten. - Google Patents
Verfahren zur dekorativen beschichtung von substraten.Info
- Publication number
- EP0680413A1 EP0680413A1 EP94904714A EP94904714A EP0680413A1 EP 0680413 A1 EP0680413 A1 EP 0680413A1 EP 94904714 A EP94904714 A EP 94904714A EP 94904714 A EP94904714 A EP 94904714A EP 0680413 A1 EP0680413 A1 EP 0680413A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- opaque surface
- coating
- particulate material
- intimate mixture
- opaque
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 33
- 239000011248 coating agent Substances 0.000 title claims abstract description 32
- 239000000758 substrate Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 34
- 239000011236 particulate material Substances 0.000 claims abstract description 18
- 229920005596 polymer binder Polymers 0.000 claims abstract description 10
- 239000002491 polymer binding agent Substances 0.000 claims abstract description 10
- 239000011872 intimate mixture Substances 0.000 claims description 23
- 238000001035 drying Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 239000011147 inorganic material Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 230000003014 reinforcing effect Effects 0.000 claims description 2
- 239000013011 aqueous formulation Substances 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 210000003462 vein Anatomy 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008365 aqueous carrier Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241001466460 Alveolata Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/005—Removing selectively parts of at least the upper layer of a multi-layer article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D3/00—Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
- B44F9/02—Designs imitating natural patterns wood grain effects
Definitions
- the present invention is concerned with a decorative method, and particularly a decorative method for providing a grained appearance on a substrate, such as a method of simulating the appearance of limed wood (especially oak) or the like.
- Grain imitation techniques are known in which a scumble glaze is applied to a painted wood substrate, the scumble glaze being applied in a streaky discontinuous manner to give the appearance of natural graining.
- Currently used techniques are very time consuming and require considerable expertise, such as that of a craftsman, to create a desired natural grain appearance. They do not therefore appeal to amateur (that is, "do-it-yourself") painters, who represent an increasingly important part of the market. I have now developed a method which helps alleviate the above problems and which has been found to have its own aesthetic attraction to home owners.
- a method of providing a decorative coating for an opaque surface comprises applying to said opaque surface a substantially continuous layer comprising an intimate mixture comprising a particulate (preferably non film-forming) material and an aqueous film-forming polymer binder, said particulate material and said layer both being lighter in colour than said opaque surface, and discontinuously removing part of said layer (preferably in streaks) so as to selectively expose part of said opaque surface.
- NCS International System of colour definition
- the NCS is described in the "ICI Colour Dimensions Colour Atlas” published by Imperial Chemical Industries Pic of London in 1986 ("Colour Dimensions” is a registered trade mark of Imperial Chemical Industries).
- the NCS defines colour in terms of a cypher, the first two digits of which extend from 00 to 99 with 00 representing white (that is, the ultimate lightness) and 99 representing black with the intermediate values from 01 to 98 representing increasingly darker shades. Lighter shades therefore have a lower pair of first digits. It is preferred that the particulate material and the continuous layer have an NCS value at least 10 units lower than that of the surface.
- the particulate material is typically an inorganic material, which may be hydrated, such as plaster (gypsum), clay or the like, or non-hydrated, such as chalk or titanium dioxide.
- inorganic material such as plaster (gypsum), clay or the like, or non-hydrated, such as chalk or titanium dioxide.
- the intimate mixture used in the method according to the invention may be fire retardant.
- an organic particulate material such as hollow or alveolate beads of polystyrene or the like, or finely chopped fibres may be used. Suitable organic beads are described for example in European patent specification 0113435B (the contents of which are herein incorporated by reference).
- the particulate material is intimately mixed with the aqueous polymer binder, preferably together with thixotropising material, such as a polyurea adduct or bentonite clay, so as to provide a thixotropic mixture.
- the intimate mixture further comprises reinforcing fibres which can serve to strengthen a resulting coating provided on the opaque surface.
- the intimate mixture further comprises a drying retardant (a material which retards drying of the coating).
- a drying retardant a material which retards drying of the coating.
- a preferred drying retardant comprises a gel material.
- gels suitable for use as a drying retardant are cellulose-based products such as carboxymethyl cellulose, hydroxymethyl cellulose and methyl cellulose, acrylamide and acrylate polymers and copolymers, gelatin, polysaccharides, polyoxamers (polyoxyethylene-polyoxypropylene block copolymers), pectins and agar.
- the aqueous polymer binder is translucent.
- the binder comprises an aqueous dispersion of particles of polymer which are capable of coalescing as the dispersion dries so as to form a film of polymeric material.
- Suitable polymers include polymers and copolymers of esters such as methyl, ethyl, propyl and hexyl esters of acrylic or methacrylic acids optionally with acrylic or methacrylic acid or polymers or copolymers of vinyl esters including vinyl acetate. Certain copolymers of these types are now available as aqueous solutions as opposed to dispersions.
- the aqueous polymer binder may, in some cases, contain a minor proportion by weight of an organic solvent, which should be miscible with water.
- an organic solvent which should be miscible with water.
- An example of such a solvent is an alcohol.
- the intimate mixture comprises substantially equal amounts of an aqueous carrier, typically water, and the particulate material, the aqueous carrier and particulate material being present in excess of the polymer binder.
- a preferred intimate mixture comprises 4 to 6 parts by weight of the particulate material, 4 to 6 parts by weight of water optionally 0 to 2 parts organic (preferably alcoholic) co-solvent to assist film formation and 0.5 to 3 parts by weight of the aqueous polymer binder.
- the intimate mixture further comprises a drying retardant substantially as hereinbefore described
- the preferred intimate mixture includes 0.5 to 3 parts by weight of the drying retardant.
- the opaque surface may be provided by wood, plastics, metal or the like, and it should have a darker colour than the intimate mixture.
- the substrate comprises wood.
- the invention is particularly advantageous in enabling the production of an article having a grained appearance, such as that simulating limed oak, a pine effect, or the like.
- the substrate may, for example, be timber, or a fibre board such as MDF (medium density fibre board).
- the substrate comprises a building structure such as a wall panel, door, window frame or the like.
- the substrate may comprise a furniture component such as a fitted kitchen or bedroom unit, cupboard door, table, seat or the like.
- the substrate comprises at least one generally planar surface which is required to have a grained appearance as described above.
- the method involves applying an opaque protective or decorative coating to the substrate so as to provide the latter with a sufficiently dark opaque surface substantially as hereinbefore described.
- the opaque coating is preferably applied so as to substantially cover an exposed surface of the substrate.
- the opaque coating is water based, although organic solvent-based coatings may be employed.
- the method involves applying a translucent or transparent coating (such as a varnish, which is preferably water-based), over the discontinuous decorative coating described above.
- a translucent or transparent coating such as a varnish, which is preferably water-based
- the translucent or transparent coating may itself contain a stain material, pigment, dye or the like; alternatively a stain may be applied to the translucent or transparent coating.
- the opaque surface typically comprises a paint selected to provide a surface of the substrate with a desired base colour.
- a particularly preferred colour of the opaque surface is brown or beige, which can contrast with the lighter colour of the intimate mixture, and give the appearance of a naturally grained effect.
- Further preferred colours of the opaque surface include grey, or other background colours, such as blue, green, red, yellow or the like.
- the particulate material preferably has a white, cream, beige or brown colour which contrasts with the darker colour of the opaque surface. Examples of such colours are Y 00 R (usually written as "Y") up to Y 90 R according to the NCS definition referred to above.
- the particulate material may advantageously be mixed with colorants or the like to provide the intimate mixture with a desired colour.
- the colour combination of the opaque surface and the intimate mixture is advantageously selected to simulate a grained appearance of a desired wood effect.
- the decorative coating may be applied by brushing, pad spreading, rolling or spraying onto the opaque surface.
- the decorative coating is allowed to substantially dry (typically for at least one hour) before subsequent application of the intimate mixture thereon.
- the intimate mixture is preferably similarly applied to the opaque surface by brushing, pad spreading, rolling or spraying thereon.
- the intimate mixture is preferably applied to provide a substantially continuous layer having a thickness (prior to drying) in the range of 0.3 to 2mm.
- the thickness of the layer is selected to provide an appearance of a desired grain, a preferred thickness being about 0.5mm.
- removal of the continuous layer involves at least two stages.
- the continuous layer is discontinuously removed in non ⁇ linear streaks to give the opaque surface a veined, streaked or grained appearance, preferably using a comb member including a plurality of distal teeth, the comb member being drawn along the opaque surface to provide a veined appearance resembling that of natural grain.
- the tips of the teeth each respectively comprise a contact edge extending for about 2 to 5mm in the general direction of the comb member, the tips advantageously being spaced apart by about 2 to 10mm.
- the veined, grained or streaked surface is treated with at least one tool member having a plurality of spaced apart proud formations (typically of plastics or elastomeric material or the like), to selectively expose parts of the opaque surface.
- a tool member may be a rockable tool, which preferably comprises a convex face, such that the tool can be rocked about the convex face, with a plurality of substantially concentric raised arc formations on the convex face.
- the rockable tool is typically drawn along the opaque surface, advantageously in the general direction of the previously formed veined, grained or streaked appearance, so as to provide a heart grain effect on the opaque surface. This heart grain has been found to be especially aesthetically attractive. It is further preferred that as the rockable tool is drawn along the opaque surface, the convex face thereof is rocked in the direction of travel of the tool.
- the present invention is particularly advantageous in providing a decorated article, and a method of producing the same, which are largely free of organic solvents (except for small amounts of co-solvent).
- This aspect is environmentally beneficial, which is particularly advantageous when the resulting articles are found or used within building interiors.
- a decorative coating provided on said surface and comprising an intimate mixture comprising a particulate material and an aqueous film-forming polymer binder, said coating being lighter in colour than said surface and being discontinuously provided thereon so as to expose part of said surface.
- Figure 1 is a schematic view, by way of example, of the second stage of removal of the continuous layer in the method according to the invention.
- Figures 2a, 2b and 2c respectively show end, side and plan elevations of the tool used in the method shown in Figure 1.
- FIG. 1 there is shown a hand 1 holding a rockable tool 2 which can be drawn in the direction of arrow A across a surface 3 having thereon a streaked or veined coating previously applied.
- Tool 2 has an elongate edge strip 4 and an elongate grip strip 5.
- the tool 2 is of generally pear-shaped cross-section (see Figure 2a), comprising an elongate grip strip 5 and, integral therewith, a bulbous edge strip 4 on which is a working face 6, which is concave and arcuate, such that the tool can be rocked as it is drawn over the surface 3.
- Working face 6 (as shown in Figures 2b and 2c) has a series of alternating arcuate raised ridges 7 and furrows 8, which are concentric and centred on an intermediate part 9 of the working face 6. (The working face and the ridges and furrows are not shown in detail in Figure 1.)
- a wood panel suitable for use as a building door was primed with white spirit based alkyd paint to receive a base coating of paint thereon.
- the paint for the base coating selected was light brown or beige (resembling the colour of light oak).
- the base paint was brushed onto a major face of the panel so as to provide a complete coating thereon and allowed to dry for two hours.
- An intimate mixture was prepared containing four parts plaster, four parts water, one part film-forming of an aqueous polyacrylate dispersion, one part of a cellulose based gel, and a small amount of an alcohol based co-solvent.
- the intimate mixture was applied onto the base paint coating so as to form a continuous layer thereon.
- a comb was drawn across the continuous layer, along the length of the panel, so as to penetrate to the paint coating and to discontinuously remove the layer and expose the underlying paint, and thereby provide an irregular veined appearance resembling that of natural grain, with the grains extending in a longitudinal direction of the panel.
- a rocking tool having a convex face with raised arc formations was then drawn across the veined layer in the general direction of the previously provided veins; the convex face was drawn in the direction of travel of the rocking tool while at the same time slowly rocked, so as to produce a heart grain effect on the panel.
- the decorative grained layer was then allowed to dry, and a finishing varnish applied thereover.
- the result was an aesthetically pleasing, resembling the appearance of limed oak.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Laminated Bodies (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB939301394A GB9301394D0 (en) | 1993-01-25 | 1993-01-25 | A decorated surface |
GB9301394 | 1993-01-25 | ||
PCT/GB1994/000136 WO1994016910A1 (en) | 1993-01-25 | 1994-01-24 | Method for decoratively coating a substrate |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0680413A1 true EP0680413A1 (de) | 1995-11-08 |
EP0680413B1 EP0680413B1 (de) | 1996-12-04 |
Family
ID=10729259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94904714A Expired - Lifetime EP0680413B1 (de) | 1993-01-25 | 1994-01-24 | Verfahren zur dekorativen beschichtung von substraten |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0680413B1 (de) |
AT (1) | ATE145865T1 (de) |
AU (1) | AU676708B2 (de) |
CA (1) | CA2154650A1 (de) |
DE (1) | DE69401052T2 (de) |
DK (1) | DK0680413T3 (de) |
ES (1) | ES2097634T3 (de) |
GB (1) | GB9301394D0 (de) |
WO (1) | WO1994016910A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6465072B1 (en) | 1993-01-25 | 2002-10-15 | Prosser Edward C. | Blank for a decorator's tool |
GB9417186D0 (en) * | 1994-08-25 | 1994-10-12 | Prosser Edward C | A decorative tool |
ES2123414B1 (es) * | 1996-03-05 | 1999-11-16 | Newlac Recubrimientos Superfic | Procedimiento para el tratamiento de superficies de aluminio, |
IE970351A1 (en) * | 1997-05-16 | 1998-11-18 | Alfrank Designs Intellectual P | A process for the treatment and manufacture of furniture and¹furnishings |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE375218C (de) * | 1920-10-16 | 1923-05-11 | Robert Oldenbruch | Verfahren zur Imitation von Kernpartien tiefporiger Hoelzer |
US2877588A (en) * | 1954-03-18 | 1959-03-17 | Carl J Ernst | Method of graining |
US3904791A (en) * | 1971-09-10 | 1975-09-09 | Elizabeth M Iverson | Ornamental coating method and articles |
US4921891A (en) * | 1986-12-10 | 1990-05-01 | Di Giorgio Corporation | Wood coating composition and process of use thereof |
-
1993
- 1993-01-25 GB GB939301394A patent/GB9301394D0/en active Pending
-
1994
- 1994-01-24 WO PCT/GB1994/000136 patent/WO1994016910A1/en active IP Right Grant
- 1994-01-24 AT AT94904714T patent/ATE145865T1/de not_active IP Right Cessation
- 1994-01-24 CA CA002154650A patent/CA2154650A1/en not_active Abandoned
- 1994-01-24 AU AU58645/94A patent/AU676708B2/en not_active Ceased
- 1994-01-24 DK DK94904714.6T patent/DK0680413T3/da active
- 1994-01-24 ES ES94904714T patent/ES2097634T3/es not_active Expired - Lifetime
- 1994-01-24 EP EP94904714A patent/EP0680413B1/de not_active Expired - Lifetime
- 1994-01-24 DE DE69401052T patent/DE69401052T2/de not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9416910A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2154650A1 (en) | 1994-08-04 |
GB9301394D0 (en) | 1993-03-17 |
AU5864594A (en) | 1994-08-15 |
DK0680413T3 (da) | 1997-06-02 |
ES2097634T3 (es) | 1997-04-01 |
ATE145865T1 (de) | 1996-12-15 |
EP0680413B1 (de) | 1996-12-04 |
WO1994016910A1 (en) | 1994-08-04 |
AU676708B2 (en) | 1997-03-20 |
DE69401052T2 (de) | 1997-05-28 |
DE69401052D1 (de) | 1997-01-16 |
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