EP0665198B1 - Schlagfeste oxidationsbeständige Beschichtung für Graphitteile - Google Patents

Schlagfeste oxidationsbeständige Beschichtung für Graphitteile Download PDF

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Publication number
EP0665198B1
EP0665198B1 EP95101076A EP95101076A EP0665198B1 EP 0665198 B1 EP0665198 B1 EP 0665198B1 EP 95101076 A EP95101076 A EP 95101076A EP 95101076 A EP95101076 A EP 95101076A EP 0665198 B1 EP0665198 B1 EP 0665198B1
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EP
European Patent Office
Prior art keywords
graphite part
substrate
grooves
refractory coating
coating layer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP95101076A
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English (en)
French (fr)
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EP0665198A1 (de
Inventor
John Franklin Pelton
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Foseco International Ltd
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Foseco International Ltd
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/06—Obtaining aluminium refining
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5027—Oxide ceramics in general; Specific oxide ceramics not covered by C04B41/5029 - C04B41/5051
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/87—Ceramics
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/06—Obtaining aluminium refining
    • C22B21/064—Obtaining aluminium refining using inert or reactive gases
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0087—Uses not provided for elsewhere in C04B2111/00 for metallurgical applications
    • C04B2111/00879—Non-ferrous metallurgy

Definitions

  • the invention relates to the refining of aluminum. More particularly, it relates to the protection of the graphite stator used in aluminum refining operations from oxidation.
  • a rotating nozzle In the refining of aluminum, a rotating nozzle is commonly employed to disperse a refining gas into a body of molten aluminum contained in a refining vessel.
  • a graphite rotor is used for this purpose, with said graphite rotor being carried on, and driven by, a graphite shaft.
  • the graphite shaft is fastened to, and driven by, a metal shaft.
  • the two shafts are fastened together by a threaded connection that holds the shafts in proper alignment with one another so that they can rotate as a unitary structure.
  • the graphite spinning nozzle assembly includes an outer graphite stator as well as an inner graphite rotating shaft having a graphite rotor at the bottom end thereof.
  • a spinning nozzle assembly is installed in a refining chamber, which is filled with molten aluminum up to an idle level.
  • the molten aluminum level will rise to a higher operating level.
  • An inert process gas will then be supplied to the spinning nozzle rotor for dispersion in the molten aluminum, forming gas bubbles that eventually rise to the surface of the molten aluminum.
  • the gas will then leave through any opening in the refining chamber.
  • the upper portion of the graphite stator in the refining chamber which extends further upward through the roof of the refining chamber, oxidizes very slowly, if at all, because the upper portion of the refining chamber is much cooler than the lower portions of the headspace near the idle level of the molten aluminum in the refining chamber.
  • the coating is then readily broken away from the surface of the graphite stator at the slightest touch in the course of cleaning operations, or the coating may be carried away from the graphite stator it is intended to protect by turbulence in the body of molten aluminum during aluminum refining operations in the refining chamber.
  • Thick coverings of oxidation protective coatings capable of excluding oxygen from the surface of the graphite stator, have been provided by two methods.
  • One such method is to pre-form a refractory sleeve that is placed onto the graphite stator in the vulnerable zone thereof.
  • the other method is to form a relatively thick coating on the vulnerable part of the graphite stator by applying a refractory mortar or cement.
  • This coating may be reinforced by incorporating into it one or more layers of fiberglass cloth. Both of these methods then provide a protective covering that will inhibit oxidation of the graphite stator to a useful degree, so long as the protective coating or sleeve remains intact. Under many operating conditions, however, the protective coatings or sleeve will be cracked or chopped away from the surface of the graphite stator during refining vessel cleaning operations.
  • JP-A-03 134 172 seeks to improve the adhesive properties between the BN films in corner parts and a graphite base body.
  • the corner parts were previously provided with grooves of a specific size on both sides in the corner parts at the time of forming the BN films by a CVD method on the basic body.
  • BN films being free from rupture and peeling in heat cycles of heating and cooling are formed.
  • EP-A-0 176 055 relates to oxidation resistant carbon bodies for application inter allia as electrodes in electrochemical processes, whereby a body of carbon into the surface of which an etched and filled layer extending to a predetermined depth in the body is provided.
  • Said layer comprises substantially silicon carbide and silicon boride.
  • the graphite stator or other graphite parts of an aluminum refining system are surrounded with a refractory sleeve formed in place on the graphite stator or other graphite parts. Longitudinal grooves, and either circular grooves or end shoulders, are used to lock the refractory sleeve to the graphite stator or other such part. The resistance of the sleeve to impact damage is thereby greatly increased.
  • the invention provides for an oxidation protective coating formed in place on the graphite part and locked to the graphite part by a series of grooves in the graphite part so as to reinforce the oxidation protective coating against breakage upon impact during cleaning.
  • the impact resistance provided by the invention enables the useful life of a graphite stator or other graphite parts to be greatly increased beyond those of graphite parts having such oxidation protective coatings not having such impact resistance feature.
  • a refining chamber is generally represented by the numeral 1, said refining chamber having cover or roof 2.
  • the spinning nozzle assembly includes graphite stator 3 and graphite rotor 4.
  • Refining chamber 1 has inlet 5 for the passage of molten aluminum to the chamber, and outlet 6 for the passage of molten aluminum therefrom.
  • molten aluminum is present in refining chamber 1 at idle level 7, with an oxidizing atmosphere generally being present in the headspace above the idle level of molten aluminum.
  • the molten aluminum is at the higher operating level 8 during aluminum refining operations.
  • the invention is directed to the providing of oxidation protection for the graphite stator and other graphite parts, such as baffles or partitions, as desired.
  • the practice of the invention enables the undesired, premature failure of the graphite stator, as discussed above, to be overcome so as to greatly increase the useful life of said stator to the benefit of the overall aluminum refining system.
  • sideways forces 15 and 16 are generated that push coating 9 apart, as with said sideways forces 15 and 16 generated by chisel or pointed tool 11 upon being driven into coating 9 in the Fig. 3 embodiment. If the coating adheres strongly to the substrate, it will have much greater resistance to being split apart as compared to a coating that is only lightly attached.
  • Graphite substrate 17 is shown with grooves 18 cut therein.
  • Refractory layer 19 is formed on said graphite substrate 17 with refractory coating material from said layer being forced into said grooves 18 in said substrate.
  • said grooves 18 serve to keep refractory layer 19 from splitting apart when a chisel or other pointed tool is driven into said refractory layer 19.
  • the sideways force of the coatings under such impact which would otherwise tend to split refractory layer 19 apart, are transmitted to graphite substrate 17 by the refractory coating material in said grooves 18, thus greatly increasing the resistance of the coating, i.e. refractory layer, to impact damage.
  • a square pattern of grooves such as shown in Fig. 6 of the drawings, is very effective.
  • a square pattern of grooves 21 is provided on flat surface 22 prior to the application of a refractory layer thereto, with refractory material applied to said flat surface passing into the grooves as an inherent part of the coating operation.
  • a coating of refractory material i.e., refractory layer 29, several cylindrical graphite substrate diameters long, is applied to cylindrical graphite substrate 30 shown in Fig. 9 of the drawings, said refractory layer 29 having axial direction grooves (not shown) formed therein.
  • a pointed tool 31 near the center of said length of coating, e.g., as at point A, it is found to be fairly resistant to cracking perpendicular to the axis of cylindrical graphite substrate 30. This is because the opening of a crack would require a long cylindrical piece of coating to slide axially on either or both sides of point A to form a crack.
  • refractory layer 29 When refractory layer 29 is struck by pointed tool 31 near one end thereof, as at point B, only a small section of one side of the cylindrical coating 24 has to move axially, i.e., slightly to the right in the embodiment illustrated in Fig. 9, and thus much less impact will cause a crack 32 to open in refractory layer 29. To counter such undesired crack formation, it is desirable to have some restraint against such refractory layer 29 movement in the axial directions at the ends of said refractory layer 29.
  • a convenient means for achieving such restraint is to provide shoulders on both ends of refractory layer 29, i.e., shoulders 33 and 34 in cylindrical graphite substrate 30 as shown in Fig. 10 of the drawings.
  • refractory material will pass into said circumferential grooves so as to form an anchoring portion thereof that serves to preclude axial movement of the refractory layer in a manner to that achieved by the providing of shoulders in the cylindrical graphite substrate.
  • Such circumferential grooves in the substrate are indicated by the numerals 35 and 36 at the opposite ends of refractory layer 29 in Fig. 9, it being understood that refractory layer material would fill such circumferential grooves during the coating operation and create the desired restraint to movement of the refractory layer, or a portion thereof, in the axial direction.
  • the coated length of the graphite cylindrical substrate is many times longer than the diameter of the cylindrical part, it may be beneficial to provide additional circumferential grooves at several locations, i.e., in the midsection, as well as at the ends of the coated area.
  • the refractory coating can be locked onto the graphite part in both directions by other groove patterns, e.g., the groove patterns as showing in Figs. 11 and 12 of the drawings.
  • the axial direction grooves may be interrupted as shown in Fig. 11, wherein a partial surface of cylindrical substrate is represented by the numeral 37, with end surface 38 representing the end of the portion of the substrate to be coated.
  • the axial direction of the substrate is indicated by the numeral 39.
  • Axial direction grooves 40 are provided in cylindrical substrate 37 prior to the applying of a refractory coating layer to the desired portion of the substrate.
  • the gaps 41 between axial direction grooves from one axial groove to the other are preferably staggered for enhanced locking of the refractory layer coating to the cylindrical graphite substrate.
  • a series of circumferential grooves is interrupted to provide the desired coating-substrate locking action.
  • partial surface 43 of a cylindrical substrate having an axial direction indicated by the numeral 44 and end 45 of the desired covered portion, has continuous, non-interrupted axial direction grooves 46 provided therein.
  • Interrupted circumferential grooves 47 are provided with lands 48 positioned so as to provide a preferable staggered effect of said interrupted circumferential grooves.
  • a variety of groove shapes can be cut in the graphite substrate for purposes of the invention.
  • the shape illustrated in Fig. 13A is readily cut with a standard high speed router bit and may be preferred for this reason. If a single point shaped tool is used to cut the grooves, then slightly slanting sides, as shown in Fig. 13B, will make the grooves somewhat easier to cut.
  • the other shapes illustrated in Figs. 13C, 13D and 13E are useful and may be employed, but have no particular advantage over the other groove shapes.
  • the V-shaped groove of Fig. 13F can also be used, but will probably not be as beneficial as grooves not having such steeply slanting sides.
  • coating thicknesses of about 1/8 inch to 1/4 inch are generally preferred.
  • the grooves should generally be from about 1/16 inch to 1/4 inch in width, with a depth of about 1/4 to 1/2 of the width of the groove.
  • the land or space between grooves should generally be on the order of about 1/2 to 3 times the groove width.
  • the desired coating can be made of any refractory mortar or cement that can be formed around the graphite part to be protected and that has suitable properties for the intended applications. It has been found, however, that air setting refractory mortars which harden by drying, are more easily handled than other types of cement or mortar.
  • the Fraxbond® 3000 mortar supplied by the Carborundum Co. has been found particularly useful for purposes of the invention, although various other commercially available refractory cements or mortars can also be employed.
  • the refractory coating used in the practice of the invention may also be a refractory cement or mortar reinforced with fiberglass cord or cloth, or an alumina-silica fiber cord or cloth, such as Nextel® supplied by 3M Co., but such reinforcement is not essential to the invention.
  • fiberglass cord or cloth it is unlikely that it adds much strength to the coating as used in molten aluminum refining after it has been in service for a period of time.
  • the very small fibers that give such materials considerable strength at room temperature frequently sinter or fuse together at aluminum refining temperatures, transforming the multi-fiber cord into a solid glass rod.
  • Such reinforcement does, however, add to the room temperature resistance to impact damage, and thus may be useful for purposes of avoiding handling damage to a graphite stator or other graphite part before it is in position in the refining chamber of an aluminum refining system. Such reinforcement may also help to control shrinkage cracking during drying or curing of the refractory coating on the graphite part.
  • the invention will be seen as representing a significant advance in the aluminum refining art.
  • the invention serves to appreciably reduce the breakage of the refractory layer that commonly occurs during such handling, use and cleaning operations.
  • the invention thus overcomes the serious problem of premature graphite stator or other part failure commonly encountered in aluminum refining operations.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Ceramic Products (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Nonmetallic Welding Materials (AREA)

Claims (20)

  1. Graphitteil, das sich zum Gebrauch in der Raffinierkammer eines Aluminiumraffinationssystems eignet und mit einem Schutz gegen vorzeitiges oxidationsbedingtes Versagen versehen ist, mit:
    (a) einem Graphitsubstratteil, welches in der Raffinierkammer angeordnet werden kann, wobei das Graphitsubstratteil oder ein Teil davon während Ruheperioden im Betrieb des Aluminiumraffinationssystems gegenüber einer oxidierenden Atmosphäre freiliegt, wobei mindestens der freiliegende Teil mit Nuten versehen ist, die sich bei dem Beschichten mit einer feuerfesten Beschichtungslage mit einem feuerfesten Beschichtungswerkstoff füllen;
    (b) einer feuerfesten Beschichtungslage, die auf den freiliegenden Teil des Graphitsubstratteils aufgebracht ist, wobei der feuerfeste Beschichtungswerkstoff die Nuten des Graphitsubstratteils füllt, wobei die Nuten und die feuerfeste Beschichtung darin so angeordnet sind, daß die feuerfeste Beschichtungslage auf dem Graphitsubstratteil arretiert ist, wodurch eine unerwünschte Bewegung der feuerfesten Beschichtungslage auf der Oberfläche des Graphitsubstratteils verhindert wird,
    wodurch die feuerfeste Beschichtungslage eine verbesserte Beständigkeit gegenüber Erschütterungen aufweist, so daß Schäden während der Handhabung, der Installation und dem Gebrauch bei Aluminiumraffinationsvorgängen und Reinigungsvorgängen der Raffinationskammer minimiert werden, wodurch die Gebrauchsdauer des Graphitteils gesteigert und dessen vorzeitiges Versagen ausgeschlossen wird.
  2. Graphitteil nach Anspruch 1, wobei der freiliegende Teil des Graphitsubstratteils eine flache Oberfläche ist und wobei die Nuten im wesentlichen in einem quadratischen Muster angeordnet sind, wodurch seitwärts gerichtete Kräfte bei einer Erschütterung der feuerfesten Beschichtungslage auf die flache Oberfläche des Graphitsubstratteils übertragen werden, wodurch die Beständigkeit der feuerfesten Beschichtungslage gegenüber Erschütterungen erheblich gesteigert wird.
  3. Graphitteil nach Anspruch 1, wobei der freiliegende Teil des Graphitsubstratteils eine zylindrische Oberfläche ist und wobei die Nuten in einer axialen Richtung ausgerichtet sind, wodurch seitwärts gerichtete Kräfte einer Erschütterung der feuerfesten Beschichtungslage auf die zylindrische Oberfläche des Graphitsubstratteils übertragen werden, so daß eine erheblich größere Erschütterungskraft bzw. eine erheblich größere Anzahl an Erschütterungen erforderlich ist, um einem Sprung in der feuerfesten Beschichtungslage zu bewirken und die Beständigkeit der feuerfesten Beschichtungslage gegen ein Wegschieben von der zylindrischen Oberfläche des Graphitsubstratteils erheblich gesteigert wird.
  4. Graphitteil nach Anspruch 3, ferner versehen mit einem Schulterbereich in dem Graphitsubstratteil an jedem Ende des freiliegenden Teils davon, auf den die feuerfeste Beschichtungslage aufgebracht ist, wodurch die Beständigkeit der feuerfesten Beschichtungslage gegenüber Bewegungen in einer axialen Richtung bei Erschütterungen nahe einem der axialen Enden der feuerfesten Beschichtungslage gesteigert wird.
  5. Graphitteil nach Anspruch 3, ferner versehen mit in Umfangsrichtung verlaufenden Nuten in dem Graphitsubstratteil an jedem Ende des freiliegenden Teils davon, auf den die feuerfeste Beschichtungslage aufgebracht ist, wodurch die Beständigkeit der feuerfesten Beschichtungslage gegenüber Bewegungen in einer axialen Richtung bei Erschütterungen nahe einem der axialen Enden der feuerfesten Beschichtungslage gesteigert wird.
  6. Graphitteil nach Anspruch 5, ferner versehen mit einer oder mehreren zusätzlichen in Umfangsrichtung verlaufenden Nuten in dem Graphitsubstratteil an Zwischenstellen zwischen den Enden des freiliegenden Teils des Graphitsubstratteils.
  7. Graphitteil nach Anspruch 3, bei welchem die axialen Nuten unterbrochen sind, um für Spalte in den Nuten in axialer Richtung zu sorgen.
  8. Graphitteil nach Anspruch 7, bei welchem die Spalte zwischen den unterbrochenen Abschnitten der axialen Nuten von einer axialen Nut zur nächsten versetzt sind.
  9. Graphitteil nach Anspruch 5, bei welchem die in Umfangsrichtung verlaufenden Nuten unterbrochen sind, um für Spalte in den Nuten in einer Umfangsrichtung zu sorgen.
  10. Graphitteil nach Anspruch 9, bei welchem die axialen Nuten unterbrochen sind, um für Spalte in den Nuten in einer axialen Richtung zu sorgen.
  11. Graphitteil nach Anspruch 3, bei welchem das Graphitteil ein Graphitstator ist.
  12. Graphitsubstratteil, das sich zum Gebrauch in der Raffinierkammer eines Aluminiumraffinationssystems eignet und dafür ausgelegt ist, in der Raffinierkammer angeordnet zu werden, wobei das Graphitsubstratteil oder ein Teil davon während Ruheperioden im Betrieb des Aluminiumraffinationssystems gegenüber einer oxidierenden Atmosphäre freiliegt, wobei der freiliegende Teil des Graphitsubstratteils mit Nuten versehen ist, die sich bei dem Beschichten mit einer feuerfesten Beschichtungslage mit einem feuerfesten Beschichtungswerkstoff füllen, und wobei die Nuten so angeordnet sind, daß dann, wenn sie sich beim Aufbringen der feuerfesten Lage mit dem feuerfesten Beschichtungswerkstoff füllen, die feuerfeste Beschichtungslage auf dem Graphitsubstratteil arretiert wird, wodurch eine unerwünschte Bewegung der feuerfesten Beschichtungslage auf der Oberfläche des Graphitsubstratteils verhindert wird,
    wodurch die auf das Graphitsubstratteil aufgebrachte feuerfeste Beschichtungslage eine verbesserte Beständigkeit gegenüber Erschütterungen aufweist, so daß Schäden während der Handhabung, der Installation und dem Gebrauch bei Aluminiumraffinationsvorgängen und Reinigungsvorgängen der Raffinationskammer minimiert werden, wodurch die Gebrauchsdauer des Graphitteils gesteigert und dessen vorzeitiges Versagen ausgeschlossen wird.
  13. Graphitsubstratteil nach Anspruch 12, bei welchem der freiliegende Teil des Graphitsubstratteils eine flache Oberfläche ist und wobei die Nuten im wesentlichen in einem quadratischen Muster angeordnet sind, wodurch seitwärts gerichtete Kräfte bei einer Erschütterung der auf die Oberfläche des Graphitsubstratteils aufgebrachten feuerfesten Beschichtung auf das flache Graphitsubstratteil übertragen werden, wodurch die Beständigkeit der feuerfesten Beschichtungslage gegenüber Erschütterungen erheblich gesteigert wird.
  14. Graphitsubstratteil nach Anspruch 12, wobei der freiliegende Teil des Graphitsubstratteils eine zylindrische Oberfläche ist und wobei die Nuten in einer axialen Richtung ausgerichtet sind.
  15. Graphitsubstratteil nach Anspruch 14, ferner versehen mit einem Schulterbereich des Graphitsubstratteils an jedem Ende des freiliegenden Teils davon, auf den eine feuerfeste Beschichtungslage aufgebracht werden soll.
  16. Graphitsubstratteil nach Anspruch 14, ferner versehen mit in Umfangsrichtung verlaufenden Nuten in dem Graphitsubstratteil an jedem Ende des freiliegenden Teils davon, auf den eine feuerfeste Beschichtungslage aufgebracht werden soll.
  17. Graphitsubstratteil nach Anspruch 14, bei welchem die axialen Nuten unterbrochen sind, um für Spalte in den Nuten in einer axialen Richtung zu sorgen.
  18. Graphitsubstratteil nach Anspruch 17, bei welchem die Spalte zwischen den unterbrochenen Abschnitten der axialen Nuten von einer axial ausgerichteten Nut zur nächsten versetzt sind.
  19. Graphitsubstratteil nach Anspruch 16, bei welchem die in Umfangsrichtung verlaufenden Nuten unterbrochen sind, um für Spalte in den Nuten in einer Umfangsrichtung zu sorgen.
  20. Graphitsubstratteil nach Anspruch 14, bei welchem das Graphitsubstratteil ein Graphitstator ist.
EP95101076A 1994-01-27 1995-01-26 Schlagfeste oxidationsbeständige Beschichtung für Graphitteile Expired - Lifetime EP0665198B1 (de)

Applications Claiming Priority (2)

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US18695094A 1994-01-27 1994-01-27
US186950 1994-01-27

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EP0665198B1 true EP0665198B1 (de) 1998-07-01

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EP (1) EP0665198B1 (de)
JP (1) JPH07216472A (de)
KR (1) KR950032660A (de)
CN (1) CN1112609A (de)
AU (1) AU1139195A (de)
CA (1) CA2141137A1 (de)
DE (1) DE69503156D1 (de)
IS (1) IS4254A (de)
NO (1) NO950173L (de)

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CN107557591A (zh) * 2017-09-29 2018-01-09 派罗特克（广西南宁）高温材料有限公司 一种带钢丝包布的石墨杆
CN113277869B (zh) * 2021-05-26 2023-03-31 湖南世鑫新材料有限公司 一种具有耐磨及抗氧化涂层的碳陶制动盘及其制备方法

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DE2703814A1 (de) * 1977-01-29 1978-08-03 Greenspan Donald Mit einem biologisch aktiven glas beschichtete aluminiumoxid-keramika und verfahren zu ihrer herstellung
FR2512067B1 (fr) * 1981-08-28 1986-02-07 Pechiney Aluminium Dispositif rotatif de dispersion de gaz pour le traitement d'un bain de metal liquide
CA1258409A (en) * 1984-09-24 1989-08-15 Robert A. Holzl Oxidation resistant carbon body and method for making same
US5435889A (en) * 1988-11-29 1995-07-25 Chromalloy Gas Turbine Corporation Preparation and coating of composite surfaces
JPH03134172A (ja) * 1989-10-18 1991-06-07 Sumitomo Metal Mining Co Ltd 窒化ホウ素被覆体
DE4029396A1 (de) * 1990-09-17 1992-03-19 Vaw Ver Aluminium Werke Ag Vorrichtung zum reinigen von ne-metallschmelzen, insbesondere aluminiumschmelzen

Also Published As

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EP0665198A1 (de) 1995-08-02
CN1112609A (zh) 1995-11-29
DE69503156D1 (de) 1998-08-06
IS4254A (is) 1995-07-28
KR950032660A (ko) 1995-12-22
NO950173D0 (no) 1995-01-17
AU1139195A (en) 1995-08-03
CA2141137A1 (en) 1995-07-28
NO950173L (no) 1995-07-28
JPH07216472A (ja) 1995-08-15

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