EP0657694A2 - Method for disposal of contaminated adsorbents from flue gas purification - Google Patents

Method for disposal of contaminated adsorbents from flue gas purification Download PDF

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Publication number
EP0657694A2
EP0657694A2 EP94119577A EP94119577A EP0657694A2 EP 0657694 A2 EP0657694 A2 EP 0657694A2 EP 94119577 A EP94119577 A EP 94119577A EP 94119577 A EP94119577 A EP 94119577A EP 0657694 A2 EP0657694 A2 EP 0657694A2
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Prior art keywords
adsorbent
burned
grate
ground
loaded
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EP94119577A
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German (de)
French (fr)
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EP0657694B1 (en
EP0657694A3 (en
Inventor
M. Dipl.-Ing. Kappen
Klaus Peter Ing. Grell
Heinrich Dipl. Ing. Oldenkotte
M. Dr. rer. nat. Schäfer
H. Dipl.-Ing. Stöckmann
Johannes Dipl.-Ing. c/o Austrian Energy Sparrer
Siegfried c/o Austrian Energy & Melcher
Rudolf c/o Austrian Energy & Wagner
Michael c/o Austrian Energy & Kainz
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Ae Energietechnik rwe Energie Aktiengesellsch GmbH
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Austrian Energy and Environment AG and Co KG
Austrian Energy and Environment SGP Waagner Biro GmbH
RWE Energie AG
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/006—General arrangement of incineration plant, e.g. flow sheets
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/80—Shredding
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00—Combustion
    • F23G2202/10—Combustion in two or more stages
    • F23G2202/106—Combustion in two or more stages with recirculation of unburned solid or gaseous matter into combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/30—Sorption devices using carbon, e.g. coke

Definitions

  • the invention relates to a method for the combustion of pollutants loaded with exhaust gas cleaning adsorbents, in particular carbon-containing absorbents, such as. B. activated coke, an incinerator for household waste or household-like waste, with pre- and post-separation of the pollutants liberated during combustion, an adsorbent, in particular brown coal coke, being used in the post-separation to separate organic pollutants and / or inorganic residues.
  • adsorbents in particular carbon-containing absorbents, such as. B. activated coke, an incinerator for household waste or household-like waste, with pre- and post-separation of the pollutants liberated during combustion, an adsorbent, in particular brown coal coke, being used in the post-separation to separate organic pollutants and / or inorganic residues.
  • activated coke loaded with pollutants is normally legally declared as hazardous waste, it must be disposed of in a hazardous waste incineration plant, unless it can be proven that the additional incineration in the plant does not increase the pollutant load.
  • the combustion of coal dust-containing substances and also of activated coke is known from DE-OS 3036504, but in the known systems there is the disadvantage that unburned substances containing pollutants can get onto the grate or into the ash funnel, so that the pollutants additionally cause the amount of pollutants in the Increase ash and are therefore not to be treated in the sense of the statutory exemption. In other words, the ashes would have to be cleaned or special constructions should be chosen.
  • the object of the invention is therefore to overcome the disadvantages and to carry out the combustion or the preparation for the combustion in such a way that no additional organic pollutants, in particular dioxins and furans on the gas or solids side, are released.
  • the invention is characterized in that the adsorbent loaded in the adsorber is ground before it is burned, in particular to a particle size distribution of 90% less than 90 ⁇ m, and via a burner, which is aimed at a main furnace, in particular waste incineration grate, before it comes into contact with the grate ash is already completely burned.
  • the ground adsorbent is burned via a burner with auxiliary firing.
  • the adsorbent is preferably burned in a calorific value ratio of approximately 1: 100.
  • an exhaust gas laden with dust and gaseous pollutants is generated, which is first cleaned dry, for example in an electrostatic filter 2, and then wet in a gas scrubber.
  • the gas, which still contains residual pollutants, is freed of the residual pollutants in a solid filter 4, for example adsorber, which can be designed as an activated coke filter, and finally fed to the chimney 6 and thus to the free atmosphere via a fan 5.
  • a solid filter 4 for example adsorber, which can be designed as an activated coke filter, and finally fed to the chimney 6 and thus to the free atmosphere via a fan 5.
  • the solid matter filter 4 the solid matter (activated coke) is loaded with the pollutants and drawn off, the amount withdrawn being replaced by fresh adsorbent via the feed 7.
  • the loaded solid is stored in the intermediate storage 8 and fed to a grinding device 9, in which the coarse grain is ground to a grain size in which 90% are less than 90 ⁇ m.
  • the ground solid is again stored in an intermediate storage 10 and continuously fed from there to the combustion chamber 1, the combustion of the loaded adsorbent being carried out at normal waste incineration temperature, for example 800 ° C., with a minimum residence time of 2 seconds, the combustion being carried out in such a way that the adsorbent is burned before it comes into contact with the grate or the fuel mixed with ash on the grate or before it comes into contact with the ash, so that no pollutants from the adsorbent combustion get into the ashes.
  • Activated coke in particular lignite coke or a solid with a high active surface, the organic portion of which can be completely burned, can be used as the adsorbent. So that the firing can be carried out continuously and the streak formation of the resulting pollutant is minimized, it is on a main firing such.
  • the combustion rate of the adsorbent is chosen so that the calorific value ratio of the burned adsorbent to that of the main furnace is approximately 1: 100.
  • the adsorbent combustion Preheated air is fed via line 11 to accelerate the oxidation.
  • 1 to 10 kg of loaded dust-like adsorbent is burned per ton of waste burned on the grate.
  • the invention is not only limited to waste incineration plants, but can also in metal melting plants such.
  • B. shaft furnaces, blast furnaces are used, especially in the treatment of scrap metal when chlorine-containing scrap is used and the exhaust gases contain dioxins and / or furans.
  • the adsorbent loaded with pollutants is placed on the melt and oxidized there and thereby becomes a partial deoxidizing agent, especially when activated carbon is used.
  • non-oxidizable pollutants such as SOx and / or HCl not accumulate in the system, it is essential that 4 pollutant sinks such as z.
  • B. electrostatic precipitators (mainly for heavy metal dusts) and also wet scrubbers for separating the volatile heavy metals and acid-forming pollutants, such as SO2 and HCl, may be provided in several stages using different absorbents, to which the majority of the pollutants are absorbed and thus separated.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

In the case of a method for burning contaminated adsorbents from flue gas purification, the extracted and contaminated adsorbent, such as, for example, activated coke (charcoal), is ground after intermediate storage to a particle-size distribution of 90% less than 90 mu m and subsequently introduced into the combustion chamber and burnt. In order to achieve this purpose, the burner is aligned with a main furnace, in particular a refuse-incineration grate, or the ground coke is burnt by means of an auxiliary furnace, the adsorbent being burnt approximately in the calorific-value ratio 1:100, optionally with preheated air, before it comes into contact with the grate ash or the grate.

Description

Die Erfindung betrifft ein Verfahren zur Verbrennung von mit Schadstoffen aus der Abgasreinigung beladenen Adsorbentien, insbesondere kohlenstoffhältigen Absorbentien, wie z. B. Aktivkoks, einer Verbrennungsanlage für Hausmüll oder hausmüllähnlichem Abfall, mit Vor- und Nachabscheidung der bei der Verbrennung frei werdenden Schadstoffe, wobei in der Nachabscheidung ein Adsorbens, insbesondere Braunkohlenkoks, zur Abscheidung von organischen Schad- und/oder anorganischen Reststoffen verwendet wird.The invention relates to a method for the combustion of pollutants loaded with exhaust gas cleaning adsorbents, in particular carbon-containing absorbents, such as. B. activated coke, an incinerator for household waste or household-like waste, with pre- and post-separation of the pollutants liberated during combustion, an adsorbent, in particular brown coal coke, being used in the post-separation to separate organic pollutants and / or inorganic residues.

Da mit Schadstoff beladener Aktivkoks im Normalfall als Sondermüll gesetzlich deklariert ist muß derselbe in einer Sondermüllverbrennungsanlage entsorgt werden, es sei denn es wird nachgewiesen, daß durch die zusätzliche Verbrennung in der eigenen Anlage die Schadstoffbelastung nicht erhöht wird. Die Verbrennung kohlenstaubhaltiger Substanzen und auch von Aktivkoks ist aus der DE-OS 3036504 bekannt, doch entsteht bei den bekannten Anlagen der Nachteil, daß unverbrannte schadstoffhaltige Substanzen auf den Rost, bzw. in den Aschentrichter gelangen können, sodaß die Schadstoffe zusätzlich das Schadstoffaufkommen in der Asche erhöhen und damit nicht im Sinne der gesetzlichen Ausnahmeregelung zu behandeln sind. Mit anderen Worten, die Aschen müßten einer zusätzlichen Reinigung zugeführt werden bzw. spezielle Konstruktionen gewählt werden.Since activated coke loaded with pollutants is normally legally declared as hazardous waste, it must be disposed of in a hazardous waste incineration plant, unless it can be proven that the additional incineration in the plant does not increase the pollutant load. The combustion of coal dust-containing substances and also of activated coke is known from DE-OS 3036504, but in the known systems there is the disadvantage that unburned substances containing pollutants can get onto the grate or into the ash funnel, so that the pollutants additionally cause the amount of pollutants in the Increase ash and are therefore not to be treated in the sense of the statutory exemption. In other words, the ashes would have to be cleaned or special constructions should be chosen.

Die Erfindung hat es sich daher zur Aufgabe gestellt, den Nachteilen zu begegnen und die Verbrennung bzw. die Vorbereitung zur Verbrennung so zu führen, daß keine zusätzliche organische Schadstoffbelastung, insbesondere Dioxine und Furane an der Gas- bzw. Feststoffseite, freigesetzt wird.The object of the invention is therefore to overcome the disadvantages and to carry out the combustion or the preparation for the combustion in such a way that no additional organic pollutants, in particular dioxins and furans on the gas or solids side, are released.

Zur Entsorgung anfallender Schadstoffe in Form von Schlämmen und Aschen ist es gemäß DE-OS 40 02 741 bekannt, schadstoffbelastete Aufbereitungsschlämme in Schmelzkammerfeuerungen zur Beeinflussung der Ascheschmelzung zu verbrennen. Derartige Feuerungen sind infolge des inhomogenen Brennstoffes Müll bei Müllverbrennungsanlagen nur schwer vorstellbar. Gemäß DD-PS 249.854 werden Aschen in einem Feuerungsabgasreinigungsverfahren aus Kalkbasis zur Adsorption von SO₂ und SO₃ und NOx zur Verminderung des Kalkverbrauches verwendet. Beide Verfahren betreffen nicht die Entsorgung von Koks durch Verbrennung.For the disposal of accumulating pollutants in the form of sludges and ashes, it is known according to DE-OS 40 02 741 to burn contaminated processing sludges in furnace furnaces to influence the ash melting. Such furnaces are difficult to imagine due to the inhomogeneous fuel waste in waste incineration plants. According to DD-PS 249.854, ashes are used in a lime-based combustion exhaust gas cleaning process for the adsorption of SO₂ and SO₃ and NO x to reduce the lime consumption. Neither process affects the disposal of coke by incineration.

Die Erfindung ist dadurch gekennzeichnet, daß das im Adsorber beladene Adsorbens vor seiner Verbrennung, insbesondere auf eine Korngrößenverteilung von 90 % kleiner als 90µm, gemahlen und über einen Brenner, der auf eine Hauptfeuerung, insbesondere Müllverbrennungsrost, gerichtet ist, vor der Berührung mit der Rostasche bereits vollständig verbrannt wird. Insbesondere wird das gemahlene Adsorbens über einen Brenner mit Stützfeuerung verbrannt wird. Vorzugsweise wird das Adsorbens im Heizwertverhältnis von etwa 1:100 verbrannt. Weitere wesentliche Ausgestaltungen der Erfindung sind in den Unteransprüchen 4 - 7 angegeben.The invention is characterized in that the adsorbent loaded in the adsorber is ground before it is burned, in particular to a particle size distribution of 90% less than 90 µm, and via a burner, which is aimed at a main furnace, in particular waste incineration grate, before it comes into contact with the grate ash is already completely burned. In particular, the ground adsorbent is burned via a burner with auxiliary firing. The adsorbent is preferably burned in a calorific value ratio of approximately 1: 100. Further essential refinements of the invention are specified in subclaims 4-7.

In der angeschlossenen Figur ist das Schaltbild einer Rauchgasreinigungsanlage nach einer Verbrennungsanlage für Hausmüll beispielsweise dargestellt.In the attached figure, the circuit diagram of a flue gas cleaning system after an incinerator for household waste is shown, for example.

In der Verbrennungskammer 1 des Müllverbrennungskessels wird ein mit staub- und gasförmigen Schadstoffen beladenes Abgas erzeugt, welches zuerst trocken beispielsweise in einem Elektrofilter 2 und anschließend naß in einem Gaswäscher gereinigt wird. Das noch Restschadstoffe enthaltene Gas wird in einem Feststoffilter 4 beispielsweise Adsorber, der als Aktivkoksfilter ausgebildet sein kann, von den Restschadstoffen befreit und schließlich über ein Gebläse 5 dem Kamin 6 und damit der freien Atmosphäre zugeleitet. Im Feststoffilter 4 wird der Feststoff (Aktivkoks) mit den Schadstoffen beladen und abgezogen, wobei die abgezogene Menge durch frisches Adsorbens über die Zuführung 7 ersetzt wird. Der beladene Feststoff wird im Zwischenlager 8 gelagert und einer Mahleinrichtung 9 zugeführt, in welcher das Grobkorn auf eine Korngröße bei der 90 % kleiner als 90µm sind, gemahlen wird. Der gemahlene Feststoff wird nochmals in einer Zwischenlagerung 10 zwischengelagert und von dort kontinuierlich der Verbrennungskammer 1 zugeführt, wobei die Verbrennung des beladenen Adsorbens bei normaler Müllverbrennungstemperatur also beispielsweise 800° C mit einer Mindestverweildauer von 2 sek durchgeführt wird, wobei die Verbrennung so durchgeführt wird, daß das Adsorbens vor seiner eventuellen Berührung mit dem Rost bzw. dem am Rost liegenden mit Asche versetzten Brennstoff oder vor seiner Berührung mit der Asche verbrannt ist, sodaß keine Schadstoffe aus der Adsorbensverbrennung in die Asche gelangen. Als Adsorbens kann Aktivkoks insbesondere Braunkohlenkoks oder auch ein Feststoff mit hoher aktiver Oberfläche verwendet werden, dessen organischer Anteil vollständig verbrannt werden kann. Damit die Feuerung kontinuierlich durchgeführt werden kann und die Strähnenbildung des entstehenden Schadstoffes minimiert ist, ist sie auf eine Hauptfeuerung wie z. B. Müllverbrennungsrost gerichtet oder die Verbrennung erfolgt über eine Stützfeuerung. Die Verbrennungsrate des Adsorbens ist so gewählt, daß das Heizwertverhältnis des verbrannten Adsorbens zu jenen der Hauptfeuerung etwa 1:100 ist. Ferner kann der Adsorbensverbrennung zur Beschleunigung der Oxidation vorgewärmte Luft über die Leitung 11 zugeführt werden. In einer Müllverbrennungsanlage wird beispielsweise je Tonne am Rost verbrannten Müll 1 bis 10 kg beladenes staubförmiges Adsorbens verbrannt.In the combustion chamber 1 of the waste incineration boiler, an exhaust gas laden with dust and gaseous pollutants is generated, which is first cleaned dry, for example in an electrostatic filter 2, and then wet in a gas scrubber. The gas, which still contains residual pollutants, is freed of the residual pollutants in a solid filter 4, for example adsorber, which can be designed as an activated coke filter, and finally fed to the chimney 6 and thus to the free atmosphere via a fan 5. In the solid matter filter 4, the solid matter (activated coke) is loaded with the pollutants and drawn off, the amount withdrawn being replaced by fresh adsorbent via the feed 7. The loaded solid is stored in the intermediate storage 8 and fed to a grinding device 9, in which the coarse grain is ground to a grain size in which 90% are less than 90 μm. The ground solid is again stored in an intermediate storage 10 and continuously fed from there to the combustion chamber 1, the combustion of the loaded adsorbent being carried out at normal waste incineration temperature, for example 800 ° C., with a minimum residence time of 2 seconds, the combustion being carried out in such a way that the adsorbent is burned before it comes into contact with the grate or the fuel mixed with ash on the grate or before it comes into contact with the ash, so that no pollutants from the adsorbent combustion get into the ashes. Activated coke, in particular lignite coke or a solid with a high active surface, the organic portion of which can be completely burned, can be used as the adsorbent. So that the firing can be carried out continuously and the streak formation of the resulting pollutant is minimized, it is on a main firing such. B. directed garbage incineration grate or the combustion takes place via a support fire. The combustion rate of the adsorbent is chosen so that the calorific value ratio of the burned adsorbent to that of the main furnace is approximately 1: 100. Furthermore, the adsorbent combustion Preheated air is fed via line 11 to accelerate the oxidation. In a waste incineration plant, for example, 1 to 10 kg of loaded dust-like adsorbent is burned per ton of waste burned on the grate.

Die Erfindung ist nicht nur auf Müllverbrennungsanlagen beschränkt, sondern kann auch bei Metallerschmelzungsanlagen wie z. B. Schachtöfen, Hochöfen verwendet werden, insbesondere bei der Altmetallaufbereitung, wenn chlorhaltiger Schrott verwendet wird und in den Abgasen Dioxine und/oder Furane enthalten sind. In diesem Fall wird das mit Schadstoff beladene Adsorbens auf die Schmelze aufgegeben und oxidiert dort und wird dadurch zum Teil Deoxidationsmittel, insbesondere dann wenn Aktivkohle verwendet wird.The invention is not only limited to waste incineration plants, but can also in metal melting plants such. B. shaft furnaces, blast furnaces are used, especially in the treatment of scrap metal when chlorine-containing scrap is used and the exhaust gases contain dioxins and / or furans. In this case, the adsorbent loaded with pollutants is placed on the melt and oxidized there and thereby becomes a partial deoxidizing agent, especially when activated carbon is used.

Damit sich die nichtoxidierbaren Schadstoffe wie z. B. SOx und/oder HCl sich nicht in der Anlage anreichern, ist es wesentlich, daß vor dem Feststoffilter 4 Schadstoffsenken wie z. B. Elektrofilter (hauptsächlich für Schwermetallstäube) und auch Naßwäscher zur Abscheidung der flüchtigen Schwermetalle und Säure bildenden Schadstoffe, wie SO₂ und HCl, eventuell in mehreren Stufen unter Verwendung von verschiedenen Absorbentien vorgesehen sind, an welchen die Hauptmenge der Schadstoffe absorbiert und damit abgeschieden werden.So that the non-oxidizable pollutants such. B. SOx and / or HCl not accumulate in the system, it is essential that 4 pollutant sinks such as z. B. electrostatic precipitators (mainly for heavy metal dusts) and also wet scrubbers for separating the volatile heavy metals and acid-forming pollutants, such as SO₂ and HCl, may be provided in several stages using different absorbents, to which the majority of the pollutants are absorbed and thus separated.

Claims (7)

Verfahren zur Verbrennung von mit Schadstoffen aus der Abgasreinigung beladenen Adsorbentien, insbesondere kohlenstoffhältigen Absorbentien, wie z. B. Aktivkoks, einer Verbrennungsanlage für Hausmüll oder hausmüllähnlichem Abfall, mit Vor- und Nachabscheidung der bei der Verbrennung frei werdenden Schadstoffe, wobei in der Nachabscheidung ein Adsorbens, insbesondere Braunkohlenkoks, zur Abscheidung von organischen Schad- und/oder anorganischen Reststoffen verwendet wird, dadurch gekennzeichnet, daß das im Adsorber beladene Adsorbens vor seiner Verbrennung, insbesondere auf eine Korngrößenverteilung von 90 % kleiner als 90µm, gemahlen und über einen Brenner, der auf eine Hauptfeuerung, insbesondere Müllverbrennungsrost, gerichtet ist, vor der Berührung mit der Rostasche bereits vollständig verbrannt wird.Process for the combustion of adsorbents loaded with pollutants from exhaust gas purification, in particular carbon-containing absorbents, such as, for. B. activated coke, an incinerator for household waste or household-like waste, with pre- and post-separation of the pollutants liberated during combustion, an adsorbent, in particular lignite coke, being used in the post-separation to separate organic pollutants and / or inorganic residues characterized in that the adsorbent loaded in the adsorber is ground before it is burned, in particular to a particle size distribution of 90% less than 90 µm, and is completely burned before it comes into contact with the grate ash via a burner which is aimed at a main combustion, in particular waste incineration grate . Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das gemahlene Adsorbens über einen Brenner mit Stützfeuerung verbrannt wird.A method according to claim 1, characterized in that the ground adsorbent is burned via a burner with auxiliary firing. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das gemahlene Adsorbens im Heizwertverhältnis von etwa 1:100 verbrannt wird.A method according to claim 1, characterized in that the ground adsorbent is burned in a calorific value ratio of about 1: 100. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das gemahlene Adsorbens mit vorerhitzter Luft ohne Zuführung von Zusatzenergie verbrannt wird.A method according to claim 1, characterized in that the ground adsorbent is burned with preheated air without the addition of additional energy. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das beladene Adsorbens vor und nach seiner Mahlung in an sich bekannter Weise zwischengelagert wird.Process according to Claim 1, characterized in that the loaded adsorbent is temporarily stored in a manner known per se before and after it is ground. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das beladene Adsorbens nach einer Aufmahlung im Feuerraum der eigenen Anlage kontinuierlich verbrannt wird.A method according to claim 1, characterized in that the loaded adsorbent is continuously burned after grinding in the furnace of the own plant. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß in der Müllverbrennungsanlage je Tonne am Rost verbrannten Müll 1 - 10 kg staubförmig gemahlenes, beladenes Adsorbens in einem in Richtung zum Rost geneigten Brenner verbrannt wird.A method according to claim 1, characterized in that 1-10 kg of dust-laden, loaded adsorbent is burned in a burner inclined towards the grate in the garbage incineration plant per ton of garbage burned on the grate.
EP19940119577 1993-12-13 1994-12-10 Method for disposal of contaminated adsorbents from flue gas purification Expired - Lifetime EP0657694B1 (en)

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AT251093A AT402339B (en) 1993-12-13 1993-12-13 METHOD FOR THE COMBUSTION OF ADSORBENTS LOADED WITH POLLUTANTS FROM THE EXHAUST GAS PURIFICATION
AT2510/93 1993-12-13
AT251093 1993-12-13

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EP0657694A2 true EP0657694A2 (en) 1995-06-14
EP0657694A3 EP0657694A3 (en) 1996-05-01
EP0657694B1 EP0657694B1 (en) 1999-07-07

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EP0770821A3 (en) * 1995-10-26 1998-09-02 Linde Aktiengesellschaft Method and apparatus for simultaneous disposal of finely divided bulk goods and other waste in thermal treatment plants
EP2305365A3 (en) * 2009-09-30 2011-10-12 Hitachi Ltd. Carbon dioxide capture power generation system
CN108105783A (en) * 2018-01-29 2018-06-01 深圳市地质局（深圳市地质灾害应急抢险技术中心） Oxygen blast burning zero discharge treatment garbage apparatus

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EP0657694A3 (en) 1996-05-01

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