EP0655966A1 - Ausrüstung zum kontinuierlichen herstellen von faserplatten - Google Patents
Ausrüstung zum kontinuierlichen herstellen von faserplattenInfo
- Publication number
- EP0655966A1 EP0655966A1 EP93919867A EP93919867A EP0655966A1 EP 0655966 A1 EP0655966 A1 EP 0655966A1 EP 93919867 A EP93919867 A EP 93919867A EP 93919867 A EP93919867 A EP 93919867A EP 0655966 A1 EP0655966 A1 EP 0655966A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gypsum
- manufacturing plant
- fiberboard
- water
- wallboard manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011094 fiberboard Substances 0.000 title claims abstract description 76
- 238000012545 processing Methods 0.000 title description 11
- 239000010440 gypsum Substances 0.000 claims abstract description 71
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 claims abstract description 35
- 239000000123 paper Substances 0.000 claims abstract description 33
- 239000002002 slurry Substances 0.000 claims abstract description 28
- 238000005520 cutting process Methods 0.000 claims abstract description 13
- 238000003825 pressing Methods 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000000835 fiber Substances 0.000 claims description 31
- 150000004683 dihydrates Chemical class 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims 5
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 30
- 239000000203 mixture Substances 0.000 description 26
- 230000008569 process Effects 0.000 description 24
- 239000011230 binding agent Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 12
- -1 and accelerators Substances 0.000 description 11
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 11
- 229940095672 calcium sulfate Drugs 0.000 description 10
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 10
- 239000007787 solid Substances 0.000 description 8
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 6
- 239000004927 clay Substances 0.000 description 6
- 239000011491 glass wool Substances 0.000 description 6
- 239000010455 vermiculite Substances 0.000 description 6
- 229910052902 vermiculite Inorganic materials 0.000 description 6
- 235000019354 vermiculite Nutrition 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000036571 hydration Effects 0.000 description 5
- 238000006703 hydration reaction Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 4
- 239000004566 building material Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000012784 inorganic fiber Substances 0.000 description 4
- 238000004537 pulping Methods 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 239000011490 mineral wool Substances 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000013029 homogenous suspension Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 125000005625 siliconate group Chemical group 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229940095564 anhydrous calcium sulfate Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000007676 flexural strength test Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- CKRORYDHXIRZCH-UHFFFAOYSA-N phosphoric acid;dihydrate Chemical compound O.O.OP(O)(O)=O CKRORYDHXIRZCH-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000020004 porter Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B5/00—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping
- B28B5/02—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type
- B28B5/026—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type the shaped articles being of indefinite length
- B28B5/027—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type the shaped articles being of indefinite length the moulding surfaces being of the indefinite length type, e.g. belts, and being continuously fed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
- B28B1/525—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement containing organic fibres, e.g. wood fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
- B28B1/526—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement by delivering the materials on a conveyor of the endless-belt type
Definitions
- This invention relates to equipment for the continuous processing of gypsum-containing fiberboard, and more particularly, to wet processing equipment for producing fiberboards of high strength at minimum cost.
- Gypsum fiberboard is a construction material made from admixing water, stucco and cellulosic fibers to form a wet mixture, and permitting the stucco, also known as gypsum hemihydrate, to cure to form a set gypsum dihydrate-containing board.
- stucco also known as gypsum hemihydrate
- gypsum dihydrate-containing board Unlike paper-faced wallboard, which is really a laminar construction including a weak gypsum core disposed between two relatively heavy paper sheets, fiberboard is typically unfaced.
- wallboard relies upon these paper facings to provide as much as 90% of the requisite bending strength
- fiberboard relies upon an intimate mixture of gypsum dihydrate crystals and cellulosic fibers which adhere together to distribute applied forces uniformly throughout the composite structure. This unique feature of fiberboard has made it attractive in applications requiring a high degree of mechanical strength, such as in fire door cores and edge banding.
- Fiberboards produced by this process were strong, having modulus of rupture values approaching as high as 1,750 lbs. per square inch, but low efficiency and the costs associated with removing all that water made the boards too expensive.
- Porter suggested a continuous operation for producing endless webs of fiberboard, which could have helped to alleviate these costs, but his disclosure failed to provide sufficient details for practicing such an operation.
- sheet making equipment has been employed to promote more continuous manufacturing of fiberboard.
- readily available and inexpensive forms of gypsum dihydrate, such as flue gas desulfurization and phosphoric acid dihydrate industrial by-products have been employed as a filler in these boards to further reduce costs.
- the mixture is conveyed to a bunker of a matformer, where it is then formed into an endless mat of a dry plaster- gypsum-fiber mix on a spreading belt.
- the endlessly formed mat is then transferred onto a screen belt and wetted with a minimum amount of water. Vacuum boxes located beneath the wetting unit facilitate the penetration of water through the cross section of the mat.
- the wetted mat then enters a movable, open cycle press, where it is pressed between a plastic coated texture belt running synchronously on top of the mat.
- the water squeezed out from the mat is drained into a press pit. After the expiration of the pressing time, the press opens and returns into its initial starting position.
- the pressed mat is then ready for cutting and subsequent setting and curing operations.
- Vogt U.S. Patent No. 4,840,688
- Vogt teaches the wet shaping of gypsum dihydrate and wet-digested fibers, followed by the removal of water, the dry recrystallization of the dihydrate to hemihydrate by heating at atmospheric pressure, and then the subsequent conversion back to the dihydrate by the addition of water.
- the complexity and costs associated with Vogt's process detracts from its commercial value.
- Processing equipment for the continuous preparation of gypsum fiberboard is disclosed by this invention.
- admixing means are provided for mixing a hydratable gypsum, paper, and a quantity of water in excess of that necessary to completely hydrate the gypsum to form a substantially homogeneous slurry.
- the line also includes dewatering means for removing a portion of the excess water from the slurry to produce a substantially continuous wet web, pressing means for configuring the wet web to form a substantially continuous green board, cutting means for cutting said substantially continuous green board into individual uncured lengths, and heating means for curing the individual uncured lengths to form gypsum-dihydrate-containing fiberboards.
- a cost efficient manufacturing line for making unfaced fiberboard is provided by this invention.
- This equipment can be adapted for retrofitting to existing wallboard machinery to permit multiple products, such as glass-faced and paper-faced wallboard and fiberboard, to be produced on the same manufacturing line.
- This apparatus permits in-line dewatering and is capable of manufacturing fiberboards from about 1/8 to about 1.5 inches in thickness by varying the number and size of wedge presses and press rolls, and varying the belt speed.
- the process equipment of this invention can include textured rolls for creating light or heavy patterns, such as wood grains, into gypsum and cement fiberboards.
- Contoured press rolls can be incorporated during pressing for making stepped sheets suitable for siding or roofing applications.
- Boards having densities of about 30 lbs./ft. 3 -85 lbs./ft. 3 and varying in width from about 6 inches to in excess of about 12 feet are possible.
- Full wall sections of about 8 feet by 60 feet long can also be fabricated for interior and exterior surface sheathing applications.
- Property-improving additives can also be incorporated into the fiberboards of this invention in wet or dry form either through stucco metering or through pulping systems.
- the pulping system of this manufacturing line can also be used to include water-resistant additives, such as polyhydrogensiloxane, asphaltic wax emulsions, and siliconates, or water-soluble polymers which can be added to increase product strength.
- water-resistant additives such as polyhydrogensiloxane, asphaltic wax emulsions, and siliconates
- flue gas desulfurization gypsum, recycled paper, and waste gypsum wallboard can be employed to further reduce the cost of the finished board.
- a continuous manufacturing line which includes pulping means for mixing paper, water, and hydratable gypsum to form a homogenous suspension, dewatering means including a continuous travelling mesh belt for removing a portion of the water from the homogenous suspension to produce a substantially continuous wet web, pressing means including a wedge press and/or a plurality of press rolls having an increased diameter for forming a substantially continuous green board, cutting means including hydraulic cutters for cutting said substantially green board in at least two directions, and heating means including a multi-layered kiln for curing said individual uncured lengths to form gypsum- dihydrate-containing fiberboards.
- FIG. 1A is a diagrammatic view of the raw material feeding and dewatering sections of the preferred continuous processing manufacturing line of this invention
- FIG. IB is a diagrammatic view of the press section, cutting station, and setting belt portion of the manufacturing line of this invention.
- This invention is directed to a continuous wet processing equipment for the manufacture of fiberboard.
- This equipment can be operated in unison with a conventional wallboard machine so as to permit the manufacture of multiple products from the same production line.
- hydratable gypsum refers to both the hemihydrate and the anhydrous forms of calcium sulfate.
- the preferred fiberboard has a density of about 30-85 lbs./ft. 3 , preferably greater than about 50 lbs./ft. 3 , flexural strength of at least 30 lbs. (1/2 inch thick material) , and screw- holding capacity, measured as defined hereinafter, of at least about 400 lbs.
- These fiberboards preferably do not include a paper facing, which is desirably absent to promote fire and water resistance properties.
- composition of the preferred fiberboards is a uniform distribution of solids, which includes by weight, about 65% to about 90% set gypsum dihydrate, about 7% to about 30% cellulosic fiber, and preferably about 1.5% to about 35% of a performance booster selected from inorganic fiber, clay, starch, vermiculite, and binder polymer.
- One of the essential constituents of the gypsum- containing fiberboards of the present invention is hydratable gypsum.
- This constituent is derived from the hydration of any form of calcium sulfate which is capable of reacting with water to form set gypsum, such as, anhydrous calcium sulfate or calcium sulfate dihydrate. It is believed that the hemihydrate form of calcium sulfate will be used most widely. Of the “alpha” and "beta” forms of the hemihydrate, use of the latter is preferred.
- the hemihydrate can be produced from the naturally-occurring gypsum mineral by heating, or calcining, the dihydrate.
- calcium sulfate hemihydrate can exist in two different crystalline forms, namely a non-fibrous form and a fibrous form, for example, elongated needles, such as the fibrous alpha-calcium sulfate hemihydrate disclosed in
- waste-type materials can be used in fabricating the fiberboards.
- Another example of a waste- or scrap-type material that can be used in the practice of the present invention is scrap gypsum wallboard, which can be used as a source of both calcium sulfate and the paper constituent of the building product.
- scrap paper-faced gypsum wallboard can be ground into suitably small particles which are calcined in water under pressure and in the presence of a crystal modifier to form calcium sulfate hemihydrate.
- Scrap gypsum wallboard can also be transformed into a suitable material for use in the practice of the present invention by grinding and calcining it at atmospheric pressure.
- Sufficient water can be used to form the desired pulp-type material from which the product is conveniently made.
- This invention can employ any of the above-disclosed individual sources of calcium sulfate, but a mixture of the different sources of calcium sulfate can also be used.
- the non-fibrous calcium sulfate generally will comprise between about 53% and about 78% by weight of the total solids, preferably between about 55% and about 70% by weight, depending upon the specific application.
- the gypsum dihydrate content of the preferred fiberboards of this invention will be approximately 17-18.5 wt.% greater than the non-fibrous calcium sulfate content of the compositions from which they are made, the difference representing the added water of hydration in the set gypsum dihydrate. That is, by weight, the set gypsum will broadly be within the range of about 65% to about 90%, and preferably between about 70% and about 85% of the overall set composition.
- the composition of the preferred fiberboards of this invention also employs a substantial amount of cellulosic fiber.
- Cellulosic fiber includes the fibrous component of plants, such as cotton, linen, and flax, for example.
- paper stock is conveniently employed. That is, the solid component involved in each of the aforesaid aspects of the invention preferably includes by weight about 7% to about 30% paper fiber, more preferably between about 10% and about 17%.
- Building materials intended for use in various specific products may contain somewhat different amounts of paper fiber. The presence of the paper fiber makes it possible to produce building materials having good physical characteristics such as flexural strength, screw and nail holding ability, and surface hardness without having any separate surfacing membrane such as the paper facing used on conventional gypsum wallboard.
- the paper fiber can be derived from either virgin paper stock, or previously used, waste paper stock.
- the source of the paper can be wood, cotton or linen rags, straw, etc. , the origin or history of the paper not being important factors.
- the paper may be a product of the sulfite process, the sulfate (Kraft paper) process, or other processes.
- the types of paper stock that have been successfully employed are virgin and brown Kraft papers, and especially, newsprint. Waste newspaper provides very satisfactory results, is inexpensive, and its use helps to overcome an environmental pollution problem.
- the source of the paper stock can include the paper of ground paper-faced gypsum wallboard.
- Fiberboards within the scope of this invention desirably and preferably include one or more performance boosting additives, their specific nature depending to some extent on the intended utility of the final product.
- the performance booster generally will comprise about 1.5% to about 35% by weight of the solids and will preferably be selected from starch, inorganic fiber, clay, vermiculite, and binder polymer.
- Inorganic fiber includes glass textile fiber and mineral wool. These latter terms are defined in U.S. Patent No. 4,557,973, and those definitions are incorporated herein by reference.
- mineral wool means glass or other mineral fibers prepared by attenuating a melt of glass, basalt, blast furnace slag or other vitreous mineral composition from the face of a heated centrifugal rotor or the like. This process is in contrast to that used to produce textile fibers, where the melt is drawn through an orifice.
- An especially useful and readily available type of mineral wool is glass wool as found in glass wool insulation material.
- siliceous fiber Glass textile fiber and glass wool, jointly or severally, are referred to herein as "siliceous fiber.”
- the glass textile fiber also referred to herein as “fiberglass” generally will be chopped, e.g., the fibers may be about 1/2 inch long.
- the fiberboards of this invention also preferably include siliceous fiber. Siliceous fiber improves the fire resistance of the building materials and other products of this invention, apparently by decreasing the tendency of the gypsum construction to crack under thermal stress.
- the siliceous fiber preferably comprises up to about 7% by weight and may include glass textile fiber and, in addition, glass wool, depending upon the specific product.
- the performance booster may also include either clay or vermiculite, or both, especially if the intended board or panel requires excellent fire resistance. Both of these materials may be present in amounts up to about 6%, preferably about 3% to about 4% by weight of the solids.
- the clay to be employed will generally be kaolin clay, which is effective to control the shrinkage of fiberboards under extreme heat.
- the vermiculite is preferably raw, or unexpanded vermiculite, which swells when heated, helping to control shrinkage of the construction and possible cracking. The requirement for the presence of these materials depends somewhat on the intended use for the final product.
- the composition of the preferred fiberboards of this invention may also include a binder.
- the binder affects the physical properties of the fiberboards, especially their flexural strength, and also permits good fastener retention at lower density. Furthermore, the binder improves the surface characteristics of the board such as smoothing the surface and making it easier to finish. Both natural binders, such as raw, uncooked starch, and binder polymers, further described below, are available for providing these characteristics.
- the binder polymer when present, may comprise up to about 15% by weight of the solids, but preferably about 1% to about 3% by weight.
- binder polymer A number of different polymeric materials may be employed as the binder polymer, including homopolymers, such as poly(vinyl acetate) and polyacrylate, as well as copolymers, such as poly(ethylene)-co-(vinyl chloride), poly(styrene)-co-(butadiene) , and poly(vinyl acetate)-co- (methyl acrylate) .
- homopolymers such as poly(vinyl acetate) and polyacrylate
- copolymers such as poly(ethylene)-co-(vinyl chloride), poly(styrene)-co-(butadiene) , and poly(vinyl acetate)-co- (methyl acrylate) .
- esters of poly(vinyl alcohol) are especially effective, and poly(vinyl acetate) homopolymer is preferred. It is also convenient in most cases to introduce the binder polymer as an aqueous emulsion, many of which are commercially
- thermoplastic resins which when applied to the surface of the fiberboards tend to form a tough, forgiving film, rather than a brittle film or one which is soft and has a very low tensile strength.
- Thermoplastic resins are also preferred since the heat required to set a thermosetting resin tends to calcine the gypsum in the preferred fiberboard compositions of this invention.
- One particularly useful resin emulsion, which is suitable for use as the resin polymer of the preferred fiberboard composition is UCAR-130 poly-(vinyl acetate) polymer by Union Carbide.
- composition for preparing the fiberboards of this invention can also include water in an amount in excess of that required to react with and hydrate the calcined non- fibrous gypsum. That is, preferably at least about 15-fold, and more preferably, about 20- to 25-fold excess water can be present in wet processes.
- Fiberboard Continuous Process and Equipment Although the fiberboard compositions of this invention may be formulated in many different ways, and any number of different techniques may be employed, including both “dry” and “wet” processes, to produce the panels and boards of this invention, a manufacturing line which is preferred for making these structures is illustrated diagrammatically in FIGS. 1A and IB.
- dry processes employ a minimum amount of water necessary for hydration of the gypsum dihydrate, or only a minor amount of excess water, for example, from about 17-100% water (based upon the weight of the gypsum dihydrate) , where as “wet” process employ over about 150% water, and preferably in excess of about 250% (about 15-fold the amount necessary for complete hydration) .
- Hydratable gypsum or in certain instances, cement, is delivered from gypsum bin 22 to a metering system, such as a feeder screw 25.
- gypsum preferably comprises stucco, i.e., gypsum hemihydrate.
- the stucco may be mixed with cut glass fibers from bin 23 and other ingredients from bin 24, such as clay, vermiculite, and starch.
- Waterproofing agents such as silicones (e.g. polyhydrogensiloxane) , siliconates, such as potassium of sodium ⁇ iliconate, asphalt wax emulsions, and combinations thereof, can be added directly to the slurry in the mixer 26, the pulper, or into the gauging water.
- Preferred starting compositional ranges and starting weights for the primary ingredients are as follows:
- the preferred wet composition contains about 412 wt.% water (based upon the dry weight of stucco; or about 24.6-fold in excess of that required to completely hydrate the gypsum) and about 13 wt.% paper (from a 3.6% pulp solution) based on the dry weight of paper and stucco.
- water based upon the dry weight of stucco; or about 24.6-fold in excess of that required to completely hydrate the gypsum
- 13 wt.% paper from a 3.6% pulp solution
- the paper fiber which composes a major ingredient in the fiberboard, is preferably recycled newspaper which is pulped, in at least about 20 times its weight in water into individual fibers in a pulper 20, preferably to about a 3-5 wt.% pulp-in-water solution; although some modern pulpers are known to accommodate about a 6-9 wt.% pulp-in-water solution.
- a vacuum filter may be employed to reduce the water content of the pulp, following wet fiberization, to about a 20-25 wt.% pulp-in-water solution.
- siliceous fiber such as glass wool
- siliceous fiber such as glass wool
- the pulped ingredients are then pumped to a slurry mixer 26 where the paper pulp, and other pulped ingredients if desirable, are intimately mixed with the gypsum and other dry additives.
- the slurry mixer 26 can be a conventional wallboard gypsum mixer, a high-torque centrifugal pump, or the like.
- the slurry mixer 26 preferably receives the dry gypsum and other ingredients, thoroughly mixes the ingredients, and pumps them through to a slurry roll or head box 27.
- the head box 27 holds the mixture of gypsum, pulp, and other ingredients in suspension and spreads them evenly as a slurry 17 onto a travelling mesh belt 28.
- the thickness of the slurry 17 which is deposited onto the belt 28 is determined by the consistency of the inlet material and the speed of the belt 28.
- the starting slurry thickness for producing a .5 inch board is preferably about 1.6-2.0 inches, more preferably about 1.7 inches.
- the travelling mesh belt 28, as with all the belts in this process, moves approximately 25-100 ft./min, preferably about 50 ft./min.
- the dewatering of the slurry 17 through the mesh is assisted by a series of drain pipes 29 which can be vacuum-assisted for facilitating the removal of water.
- the slurry 17 is reduced to a soft web 37 which is introduced to an adjustable prepress roll 30.
- the soft web 37 at this point in the process has a thickness of preferably about 1.1-1.3 inches, more preferably about 1.2 inches, and a water content of about 70.2 wt.%.
- the prepress roll 30 can be set for various nip thicknesses and can be equipped to introduce porous top and bottom belts 33 and 31.
- the web 37 is then delivered by the porous belts 31 and 33 to wedge press 32, which may contain vacuum boxes, suction slices, and/or perforated metal plates for helping to remove water which enters through the belts.
- wedge press 32 may contain vacuum boxes, suction slices, and/or perforated metal plates for helping to remove water which enters through the belts.
- the thickness of the web 37 at this point in the process is approximately .85- .925 inches, preferably about .89 inches, and the water content is about 62.2 wt.%.
- the wet web 37 then enters a first press roll section shown in FIG. 2, which includes three 18 inch press rolls 36 and suction slices 38.
- the porous belts continue through this first press section.
- the thickness of the web at this point in the processing is approximately .640-.690 inches, preferably about .67 inches, and the water content is about 52.8 wt.%.
- the web 37 then enters a second press roll section which includes three 24 inch press rolls 40 and the same top and bottom belts 33 and 31 with vacuum-assisted suction slices 42.
- the thickness of the web 37 at this stage is approximately .53-.550 inches, preferably about .54 inches, and the water content is about 44.6 wt.%.
- the web 37 is introduced into the last press roll section which includes three 36 inch press rolls 44 and vacuum-assisted suction slices 46.
- a new bottom belt 53 is preferably introduced, although the board now has sufficient green strength to be processed on rolls 50, without belts.
- the thickness of the web is now about .5 inches and the water content is about 41.5 wt.%, which represents the 310 lbs. of water needed for hydration and the 1,200 lbs. of water to be evaporated in the dryer.
- the pressing operation of this invention may consist of anywhere from about 4 to about 28 press rolls, and may contain contouring, profiling, or embossing rolls for individual product needs. Additionally, the rolls in each press section may contain ridges or drilled holes for carrying away water from the wet web.
- the main purpose of the press section of FIG. 2 is to define caliper and density while simultaneously removing water. As the web leaves the press section, it is in a form of a "green" board 47, i.e., is not past its initial stiffening point. See U.S. Patent No. 4,643,771 for an explanation of the various curing stages of gypsum boards, which is hereby incorporated by reference.
- the green board is preferably cut to length and trimmed with water jets, as illustrated in FIG. 3.
- the water jets preferably use about 1,800-2,600 p ⁇ i, more preferably about 2,200 psi water pressure and include side trimmers 39 and a chain driven length cutter 41 angled at about 45° to the processing line for cutting the running board square. Because the green board 47 is very soft, the water jets cut effortlessly through the thickness to trim the boards to about their final length and width dimensions.
- the process also includes repulpers 43 following the trimmers 39 for receiving the edge trim refuse, as well as entire scrap boards, which can be reground, mixed with water from nozzle 45 to form a slurry, and transferred back to the starting tanks or slurry mixer for recycling.
- the cut-to-size, green boards 57 are then transferred to a setting belt 48 which permits the gypsum to slowly set as it is conveyed.
- the setting belts of a conventional wallboard line can alternatively be used as a setting belt, which would carry the fiberboards past the conventional pin mixer 51 and shaping roll 52.
- the substantially set boards are then oven dried prior to conventional trimming of the water-cut ends and edges, sanding, and silicone sealing operations.
- an adjustment table 49 is provided which preferably adds a setting belt 48 to the conventional wallboard machine prior to the first board line carrier belt.
- the adjustment table 49 further preferably includes a lift mechanism for (1) selectively introducing the belt when fiberboard is running, (2) lifting the wallboard paper handling equipment out of the way while replacing it with carrier rolls for the bottom belt, and (3) withdrawing the belt when wallboard is being manufactured downline.
- the continuous wet fiberboard process described above permits on-line dewatering and facilitates the manufacture of nominal .125 inch to about 1.5 inch thick fiberboard products.
- This equipment can be adapted for different types of boards by alternating the number of press rolls as well as the speed of the belt.
- Cement and/or gypsum can be used in the starting materials and the final boards can be embossed with light or heavy patterns, such as wood grains.
- the process of this invention can permit the manufacture of fiberboards having a density of about 30-85 lbs./ft. 3 and widths from about 6 inches to about 12 feet.
- Additives can be introduced in both the wet or dry state either through the stucco metering or the pulping systems, such as the gauge water.
- This novel process can also produce different formulations of layers deposited through separate head boxes onto the moving belt for achieving different densities and finishes on the face and back of selected boards.
- the processes of the present invention can be used to make unfaced fiberboard which has a substantially uniform and homogeneous composition throughout its thickness.
- the term "unfaced” is used herein to mean that the fiberboard layer is preferably not faced with a sheet material, for example, the paper or glass fiber mat that is often used as a facing material for gypsum wallboard, although structrually improved faced-products can be readily produced by employing the fiberboard compositions of this invention in the cores of such boards.
- the fiberboard layer of the present invention have a density within the broad range of about 30-85 lbs./ft. 3 , and preferably about 50-65 lbs./ft. 3 .
- the flexural strength and screw-holding capacity values referred to above (30 lbs. and 400 lbs. respectively) in fiberboards having densities much below 60 lbs./ft. 3
- binder polymer for example, about 15 wt.% to about 35 wt.% based upon the solids content.
- the use of a binder polymer can be absent or provided in smaller amounts.
- the density of the fiberboard can be controlled by the use of pressure in forming the product and/or by the use of a low-density material, for example, expanded perlite.
- the flexural strength of fiberboards within the scope of this invention generally should be at least about 30 lbs., preferably at least about 40 lbs. (1/2 inch thick sample tested in accordance with a modified ASTM C 473-86a procedure, as described in U.S. Serial No. 420,362).
- the screw-holding capacity of fiberboards within the scope of this invention is preferably at least about 400 lbs., and in a building board to be used as fire door edge banding, preferably at least about 600 lbs., and most preferably in excess of about 700 lbs., when tested in accordance with the procedures otherwise described in U.S. Serial No. 420,362 for one inch samples.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Producing Shaped Articles From Materials (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Panels For Use In Building Construction (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Preliminary Treatment Of Fibers (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US92633992A | 1992-08-06 | 1992-08-06 | |
US926339 | 1992-08-06 | ||
PCT/US1993/007273 WO1994003318A1 (en) | 1992-08-06 | 1993-08-03 | Continuous processing equipment for making fiberboard |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0655966A1 true EP0655966A1 (de) | 1995-06-07 |
EP0655966A4 EP0655966A4 (de) | 1995-07-19 |
EP0655966B1 EP0655966B1 (de) | 2001-03-21 |
Family
ID=25453077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93919867A Expired - Lifetime EP0655966B1 (de) | 1992-08-06 | 1993-08-03 | Ausrüstung zum kontinuierlichen herstellen von faserplatten |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0655966B1 (de) |
AT (1) | ATE199852T1 (de) |
CA (1) | CA2141804C (de) |
DE (1) | DE69330053D1 (de) |
MX (1) | MX9304807A (de) |
WO (1) | WO1994003318A1 (de) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5155959A (en) | 1989-10-12 | 1992-10-20 | Georgia-Pacific Corporation | Firedoor constructions including gypsum building product |
US5632848A (en) * | 1989-10-12 | 1997-05-27 | Georgia-Pacific Corporation | Continuous processing equipment for making fiberboard |
FR2825658B1 (fr) * | 2001-06-07 | 2007-08-31 | Bpb Plc | Procede de fabrication d'une plaque a base de liant tel que platre, ciment ou autre, extrudeur pour la mise en oeuvre d'un tel procede, et plaque ainsi obtenue et son utilisation |
EP1358984A1 (de) * | 2002-05-03 | 2003-11-05 | Lafarge Platres | Verfahren und Vorrichtung zur Herstellung von Gipsplatten |
SE532999C2 (sv) * | 2008-10-13 | 2010-06-08 | Peter Lindberg | Förfarande för framställning av byggskivor |
EP3067176A1 (de) * | 2015-03-09 | 2016-09-14 | Eternit AG | Verfahren und Vorrichtung zur Herstellung eines hydrophobierten Faserzementprodukts |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0347809A1 (de) * | 1988-06-23 | 1989-12-27 | The Celotex Corporation | Verfahren zur Nassformung von Mineralfaserplatten unter Bildung von Faserknoten |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2156311A (en) * | 1938-04-09 | 1939-05-02 | Bakelite Building Prod Co Inc | Cement fiber product |
JPS5325339B2 (de) * | 1973-05-29 | 1978-07-26 | ||
DE2337374A1 (de) * | 1973-07-23 | 1975-04-10 | Gypsum Research | Verfahren zur herstellung von faserhaltigen baukoerpern |
US3944698A (en) * | 1973-11-14 | 1976-03-16 | United States Gypsum Company | Gypsum wallboard and process for making same |
DE2365161A1 (de) * | 1973-12-29 | 1975-07-03 | Heidelberg Portland Zement | Verfahren zur herstellung von gipsfaserplatten sowie vorrichtung zur durchfuehrung des verfahrens |
GB1536663A (en) * | 1975-10-28 | 1978-12-20 | Cape Boards & Panels Ltd | Fibre-reinforced articles |
US4647496A (en) * | 1984-02-27 | 1987-03-03 | Georgia-Pacific Corporation | Use of fibrous mat-faced gypsum board in exterior finishing systems for buildings |
-
1993
- 1993-08-03 CA CA002141804A patent/CA2141804C/en not_active Expired - Fee Related
- 1993-08-03 WO PCT/US1993/007273 patent/WO1994003318A1/en active IP Right Grant
- 1993-08-03 EP EP93919867A patent/EP0655966B1/de not_active Expired - Lifetime
- 1993-08-03 AT AT93919867T patent/ATE199852T1/de not_active IP Right Cessation
- 1993-08-03 DE DE69330053T patent/DE69330053D1/de not_active Expired - Lifetime
- 1993-08-06 MX MX9304807A patent/MX9304807A/es unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0347809A1 (de) * | 1988-06-23 | 1989-12-27 | The Celotex Corporation | Verfahren zur Nassformung von Mineralfaserplatten unter Bildung von Faserknoten |
Non-Patent Citations (1)
Title |
---|
See also references of WO9403318A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2141804C (en) | 2004-11-30 |
CA2141804A1 (en) | 1994-02-17 |
ATE199852T1 (de) | 2001-04-15 |
DE69330053D1 (de) | 2001-04-26 |
MX9304807A (es) | 1994-05-31 |
WO1994003318A1 (en) | 1994-02-17 |
EP0655966A4 (de) | 1995-07-19 |
EP0655966B1 (de) | 2001-03-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5632848A (en) | Continuous processing equipment for making fiberboard | |
AU644758B2 (en) | Gypsum-containing fire-resistant structural fiberboard | |
CA1197863A (en) | Boards and sheets | |
US6299970B1 (en) | Fire-resistant gypsum fiberboard | |
CA1065350A (en) | Perlite insulation board and method of making the same | |
US4303722A (en) | Building components | |
US6221521B1 (en) | Non-combustible gypsum/fiber board | |
US5637362A (en) | Thin, sealant-coated, fiber-reinforced gypsum panel | |
CN101883904B (zh) | 用于制造石膏纤维板的低纤维煅烧方法 | |
EP0020345A1 (de) | Verfahren zur herstellung glasfaserverstärkter gipsfolien und daraus geformte gipsplatte | |
AU2007297821B2 (en) | Method and apparatus for scrim embedment into wet processed panels | |
CA2645481A1 (en) | Light weight metal fire door core | |
CN108138492A (zh) | 适于用作屋顶盖板的轻质石膏纤维面板 | |
EP0655966B1 (de) | Ausrüstung zum kontinuierlichen herstellen von faserplatten | |
RU2617819C2 (ru) | Гипсоволокнистая плита и способ ее изготовления | |
GB1603625A (en) | Fibre reinforced articles | |
JPH08208307A (ja) | 木質繊維セメント板の湿式抄造法による製造法 | |
EP1102904A1 (de) | Baustoffplatte und ihre herstellung | |
JP2002018824A (ja) | 窯業系外装材の製造方法 | |
JP2002011714A (ja) | 窯業系外装材の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19950303 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 19950601 |
|
AK | Designated contracting states |
Kind code of ref document: A4 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE |
|
17Q | First examination report despatched |
Effective date: 19970630 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010321 Ref country code: LI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010321 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRE;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.SCRIBED TIME-LIMIT Effective date: 20010321 Ref country code: GR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20010321 Ref country code: FR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010321 Ref country code: CH Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010321 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010321 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010321 |
|
REF | Corresponds to: |
Ref document number: 199852 Country of ref document: AT Date of ref document: 20010415 Kind code of ref document: T |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REF | Corresponds to: |
Ref document number: 69330053 Country of ref document: DE Date of ref document: 20010426 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010621 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010621 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010621 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010622 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20010803 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20010803 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20010803 |
|
EN | Fr: translation not filed | ||
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20010927 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20020301 |
|
26N | No opposition filed | ||
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20010803 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |