EP0646065A1 - Method for making translucent colored-backed films - Google Patents

Method for making translucent colored-backed films

Info

Publication number
EP0646065A1
EP0646065A1 EP93916663A EP93916663A EP0646065A1 EP 0646065 A1 EP0646065 A1 EP 0646065A1 EP 93916663 A EP93916663 A EP 93916663A EP 93916663 A EP93916663 A EP 93916663A EP 0646065 A1 EP0646065 A1 EP 0646065A1
Authority
EP
European Patent Office
Prior art keywords
face
film
pvf film
pvf
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93916663A
Other languages
German (de)
French (fr)
Other versions
EP0646065A4 (en
Inventor
Ronald W. Lowther
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FLEX/TAG
Original Assignee
FLEX/TAG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FLEX/TAG filed Critical FLEX/TAG
Publication of EP0646065A1 publication Critical patent/EP0646065A1/en
Publication of EP0646065A4 publication Critical patent/EP0646065A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/08Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
    • B05C1/10Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the liquid or other fluent material being supplied from inside the roller
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/043Improving the adhesiveness of the coatings per se, e.g. forming primers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/24Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245Vinyl resins, e.g. polyvinyl chloride [PVC]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/14Homopolymers or copolymers of vinyl fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12Homopolymers or copolymers of methyl methacrylate

Definitions

  • the present invention relates generally to methods for manufacturing translucent colored vinyl films for use, for example, in back-lit outdoor signs.
  • Back-lit outdoor signs and awnings are known in the art.
  • Such signs and awnings include pressure-sensitive vinyl graphics on a suitable translucent carrier such as rigid acrylic or some other flexible sign-face material.
  • suitable translucent carrier such as rigid acrylic or some other flexible sign-face material.
  • TEDLAR is a thin, generally clear film that is dirt-resistant and exhibits excellent UV resistance.
  • Such color-pigmented film is difficult and expensive to produce, and it is only commercially available in a relatively few standard colors which do not satisfy the sign industry's requirements to provide custom colors.
  • a method for making colored backed film material using a polyvinyl fluoride (PVF) film having a first face and a second face opposite the first face, the first face pre-coated with an ink-receptive coating.
  • a carrier is first statically laminated to the second face of the PVF film.
  • Static lamination means that the carrier is only temporarily laminated and can be later removed from the remainder of the film.
  • a translucent acrylic ink is continuously applied onto the pre-coated first face of the PVF film to produce a colored PVF film.
  • This film is then passed through an oven to dry the ink.
  • the colored PVF film is then separated from the carrier. Such separation may be effected while the PVF film is collected on a continuous roll.
  • an adhesive coating may be continuously applied to the first face of the PVF film after the PVF film is separated from the carrier.
  • a backing paper is then continuously applied over the adhesive coating to produce a roll stock of colored film.
  • the roll stock is cut to the appropriate size, the backing paper is removed and the color-backed film is then applied to a" back-lit sign, awning or other suitable support.
  • FIGURE 1 is flowchart of the preferred processing steps of the present invention
  • FIGURE 2 is a schematic diagram of a rotary silkscreen apparatus for use in the method of the present invention
  • FIGURE 3 is a detailed perspective view of the rotary screen printing apparatus for use in the inventive method
  • FIGURE 4 is a detailed perspective view of the rotary screen and squeegee mechanism of the printing apparatus of FIGURE 3;
  • FIGURE 5 is a schematic diagram of the rotary screen and squeegee mechanism showing the position of these components relative to the counter pressure roller of the apparatus;
  • FIGURE 6 is an side view of the preferred structure of the color-backed film manufactured according to the method of the present invention. Similar reference characters refer to similar steps throughout the drawings.
  • PVF film such as DuPont® TEDLAR® film
  • TEDLAR is a thin, generally clear film that is dirt-resistant and exhibits excellent UV resistance. While in the preferred embodiment PVF film is used as the base web material, it should be appreciated that the method of the present invention is also useful for producing color-backed films made of other materials including, without limitation, polypropylene, polyvinyl chloride, polyester. The inventive process may thus be effected with other clear film polymer materials having surface tension characteristics suitable for supporting acrylic inks (either directly or through enhancement of such characteristics) .
  • the acrylic inks are translucent.
  • Such inks typically include three components: pigment, clear varnish (i.e., acrylic resins) and a solvent.
  • These inks are commercially available in several basic colors.
  • Custom colors are created by mixing appropriate commercial inks together (e.g., turquoise by mixing green, blue and white) .
  • custom colors such as turquoise
  • the method for making colored backed film material preferably uses a polyvinyl fluoride (PVF) film web or "base" having a first face and a second face opposite the first face.
  • PVF polyvinyl fluoride
  • the first face of the PVF film is preferably coated with an ink-receptive coating.
  • Such coatings are known in the art and function to increase the surface tension of the PVF film to thus facilitate the adhesion of the acrylic ink.
  • the ink receptive coating may be TC-160 print receptive coating provided by Flexcon Manufacturing.
  • the ink receptive coating is preferably applied during a pre-processing stage as opposed to during the application of the acrylic ink.
  • the PVF film may be said to be "pre-coated" with an ink receptive coating to facilitate the remaining processing steps.
  • the method is not intended to be limited in this regard and the ink receptive coating may be applied to the PVF film as part of the preferred method of carrying out the invention.
  • the surface tension of the PVF film is increased by flame or corona etching, or by a combination of such etching and application of the ink receptive coating as described above.
  • Such processing steps are known in the art.
  • the step of enhancing the surface tension of the clear film may be omitted if the surface tension of the film is adequate to retain the acrylic ink for the specific application and/or the desired shelf life of the product.
  • a carrier material is temporarily or "statically" laminated to the second face of the pre-coated PVF film (e.g., the PVF film having an ink receptive coating on its first face) .
  • "static" lamination means that the carrier is not adhered to the PVF film in a positive sense (i.e., through an adhesive or the like) and thus can be later removed in an simple manner by just separating the carrier and film.
  • the carrier sheet is preferably paper or clear polyester having a thickness of about 5.0 mil. The carrier is generally useful because the thickness of the PVF film is approximately 1.0 mil.
  • PVF films having greater thicknesses tend to be milky or creamy in color and thus tend to produce poor color-backed material.
  • the carrier sheet thus provides physical integrity to the clear film base so that the continuous ink processing may be effected as will hereafter be described.
  • the carrier may be omitted if thicker, yet clear films are used as the base web material.
  • step 14 a translucent acrylic ink is continuously applied onto the pre-coated first face of the PVF film.
  • step 16 the translucent acrylic ink coating is continuously dried.
  • step 18 the colored PVF film is separated from the carrier, which can then be reused.
  • step 20 the continuous application of a pressure sensitive adhesive coating over the previously-coated first face of the PVF film.
  • step 22 a backing paper is continuously applied over the pressure sensitive adhesive coating.
  • a rotary web silkscreen apparatus is used to provide continuous application of acrylic ink to a PVF film whose surface tension has been enhanced.
  • One such apparatus is the Stork Rotary Screen Coating/ Printing Line for coating and printing sold commercially as Type PD-IV-4300/ML by Stork X-cel BV of Holland.
  • the apparatus 20 is shown schematically in elevation in FIGURE 2 and comprises a number of functional components: an unwind mechanism 22, a rewind mechanism 24, a corona discharge mechanism
  • the unwind mechanism 22 comprises a movable stand 38 and a pneumatic brake 40.
  • the PVF film, with the ink receptive coating on the first face and the carrier sheet laminated to the second face, is supported in rolled form on the movable stand 38.
  • the pre-coated PVF film (with the carrier sheet laminate) is then threaded under the corona discharge mechanism 25, through the guide mechanism
  • the outfeed mechanism 28 guides the web to the rewind mechanism 24 and also functions to separate or delaminate the carrier sheet from the remainder of the material.
  • the corona discharge mechanism 25 operates to produce an electrical field disturbance across the first face of the film, thereby increasing the surface tension of the ink receptive coating and the PVF film.
  • the corona discharge enhances the adhesion of the acrylic ink to the film and thus lengthens the effective life of the product.
  • the corona discharge is optional, and when the mechanism is used it may not be necessary to apply an ink receptive coating. In the preferred embodiment. both the ink receptive coating and the corona discharge 25 are used to increase the surface tension of the film.
  • the corona treating unit comprises a generator, a high voltage transformer 5 and an electrode which function to provide a corona discharge at the electrode adjacent the passing web.
  • One such unit is a Model PBS Corona Discharge Unit manufactured by Sherman Treaters (North America) Inc. of Ontario, Canada.
  • the drive mechanism 30 is activated.
  • the PVF film is then unwound from the unwind mechanism and continuously processed through
  • This rotary web screen printing apparatus is
  • FIGURE 3 shows a portion of the apparatus including the guide mechanism 26, the drive mechanism 30, the rotary screen coating/printing unit 32, the drying mechanism 34, the cooling mechanism 36 and a portion
  • Guide mechanism 26 includes the guide rollers 40 and 42, and the web passes under roller 40 and over roller 42 as shown.
  • the drive mechanism includes rollers 44 and 46 upstream of the rotary screen coating/printing unit
  • the primary component of the apparatus is the rotary screen coating/printing mechanism 32.
  • J mechanism comprises a printing/coating head 52, a rotary screen 54, a squeegee 56 and a counter pressure roller 58.
  • a tray 60 underlies the rotary screen for collecting excess ink.
  • the printing/ coating head 52 receives the acrylic ink from a reservoir (not shown) and delivers the ink into the 5 interior 61 of a circular body portion 63 of the squeegee.
  • the circular body portion 63 of the squeegee includes a longitudinal slot 62 along a portion of its length.
  • a paste spreading blade 64 is attached ° to the body portion 63 and underlies the slot 62.
  • the paste spreading blade has a first or tray portion 62a, a lip portion 62b and a flexible third portion 62c.
  • a squeegee blade 66 overlies the portions 62b and 62c of the paste spreading blade 5 and is retained in a clamp 71.
  • the 66 includes a first portion 66a and a second portion 66b.
  • the first portion is preferably formed of chromium steel and the second section is formed of silicone rubber of polyurethane.
  • the web 68 passes between a distal edge of the sgueegee blade and the counter-pressure roller 58 substantially as shown.
  • the rotary screen 54 rotates counterclockwise while the counter-pressure roller rotates clockwise.
  • the head 52 receives the acrylic ink, which is delivered along the interior 61 of the body portion 63.
  • the ink passes out of the slot 62 and is collected between the paste spreading blade and the squeegee blade.
  • the squeegee blade forces the acrylic ink through the screen and onto the web to form a coating 65.
  • the ink and film are passed through an drying mechanism 34, which preferably comprises a plurality of hot air blowers 70.
  • the dryer removes the ink solvent to enable the web to be re-rolled. It is desirable to control the amount of drying because if too much of the solvent is removed, the ink becomes brittle. If too little solvent is removed, the ink remains sticky and the web cannot be effectively re-rolled.
  • the web After drying, the web is passed around a pair of cooling rollers 72 and 74 comprising the cooling mechanism 36. This mechanism lowers the temperature of the web. The web is then drawn through rollers 48 and 50 of the drive mechanism 30, and then passed through the outfeed mechanism having rollers 76 and 78. The carrier is then delaminated by the outfeed mechanism (and can be reused) and the color-backed film web is re-rolled on the rewind mechanism.
  • a translucent colored, pressure-sensitive PVF film can be formed with two additional processing steps.
  • an adhesive coating is continuously applied to the inked first face of the PVF film after the PVF film is separated from the carrier.
  • the adhesive is a non-toulene based composition that does not interfere with the ink.
  • V-156 pressure sensitive adhesive coating supplied by Flexcon Manufacturing. Such coatings are applied to the colored PVF film using, for example, a knife-over-roll apparatus, although the specific method of applying the adhesive coating is not meant to be limited in any way. Thereafter, a backing paper is continuously applied over the adhesive coating to form a translucent colored, pressure-sensitive TEDLAR® film.
  • the method of the present invention thus solves the problems of the prior art while allowing for the production of a color-backed film in continuous rolls by means of web machine silkscreen application of color. The rolls can be made in large widths (e.g., up to about eight feet).
  • the color-backing can be matched to any custom color and can be manufactured in minimal to maximum quantity, low cost production runs.
  • the resulting product satisfactorily addresses the problems of environmental dirt and solar degradation and facilitates the production of back-lit outdoor signs having pressure-sensitive vinyl graphics on a suitable translucent carrier or other sign face material.
  • the translucent colored, pressure-sensitive TEDLAR® film produced by the method of the present invention is shown in FIGURE 6.
  • the material comprises a TEDLAR® clear PVF film 90 (approximately l.o mil thick), a clear ink receptive coating 92 (approximately 0.03 mil thick), a coating of translucent custom-formulated colored ink 94, a clear pressure-sensitive adhesive coating 96, and a removable temporary backing paper 98 (approximately 5.0 mil thick).
  • the temporary backing paper 98 is removed and the material is applied to a translucent carrier or other sign face or awning material.
  • the rotary web screen apparatus has an 80 mesh (i.e., 80 holes per square inch) screen having a predetermined thickness of approximately 150 microns.
  • the openings in the screen are hexagonal and taper from the outside to the inside (i.e., to form conical openings).
  • the squeegee blade is positioned with its blade tip at the heart of the counter pressure roller, i.e., where contact is made with the rotary screen.
  • the squeegee pressure is relatively high and the length of the squeegee blade is relatively long.
  • a preferred squeegee blade is an ULDOME Stainless Steel from Stork.
  • the translucent acrylic ink has a predetermined viscosity of approximately 5000 centipoise.
  • the unwind and rewind mechanisms are run at the same predetermined speed between 10-12 meters per minute (and preferably 10 meters per minute) as the translucent acrylic ink is continuously applied to the pre-coated PVF film.
  • the pre-coating is preferably TC-160 coating (with thickness of approximately 0.03 mil) provided by Flexcon Manufacturing.
  • the oven preferably operates over a predetermined temperature range between 170-185 degrees Fahrenheit. Within these operating constraints and variables, the ink is much easier to spread and the pigments do not separate during the continuous application process. The inks are dried easily and the color-backed roll is able to be wound on the rewind mechanism without damaging the material.
  • the acrylic ink may be continuously applied to the PVF film by moving a print head along the length of a stationary length of film (instead of using a rotary web machine) . It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

A method is described for making colored backed film material using a polyvinyl fluoride (PVF) film (90) having a first face and a second face opposite the first face. The method comprises the steps of coating the first face of the PVF film (90) with an ink-receptive coating (65). A carrier is then statically laminated to the second face of the PVF film. Using a rotary web (68) printing apparatus (32), an acrylic ink is then continuously applied onto the first face of the PVF film (90). After drying the ink, the PVF film is separated from the carrier and the colored PVF film (90) is coated with a pressure-sensitive adhesive and provided with a release paper.

Description

METHOD FOR MAKING TRANSLUCENT COLORED-BACKED FILlti-S
The present invention relates generally to methods for manufacturing translucent colored vinyl films for use, for example, in back-lit outdoor signs. Back-lit outdoor signs and awnings are known in the art. Typically, such signs and awnings include pressure-sensitive vinyl graphics on a suitable translucent carrier such as rigid acrylic or some other flexible sign-face material. These prior art constructions, however, suffer from several deficiencies including, without limitation, solar degradation of the color graphics and environmental dirt contamination on the face of the graphics.
It is also known in the prior art to address such deficiencies of the prior art used color- pigmented polyvinyl fluoride ("PVF") film, such as DuPont® TEDLAR® film. TEDLAR is a thin, generally clear film that is dirt-resistant and exhibits excellent UV resistance. Such color-pigmented film, however, is difficult and expensive to produce, and it is only commercially available in a relatively few standard colors which do not satisfy the sign industry's requirements to provide custom colors.
Another approach to solving the problems of the prior art has been to laminate a pressure-sensitive colored film (sold commercially as SCOTCHCAL®) to a white fabric base formed by vinyl-coating a nylon mesh (PANAFLEX®) . This process produces a flexible sign material but this material w?ars poorly, is subject to streaking and is expensive to produce. Still another proposed solution to the deficiencies of the prior art has been to silkscreen colors onto TEDLAR film using a flatbed screen printing machine. This approach facilitates the formation of custom-colored PVF films but is not commercially practicable because the film can only be printed in a discrete (i.e., not continuous) manner. The size of each portion printed is limited to the area of the flatbed screen, and it is difficult to provide consistent coloration across multiple print cycles. The resulting product is unacceptable and extremely expensive to produce. This process cannot be used effectively on a commercial scale. There is therefore a need to provide an improved method of manufacturing translucent colored pressure-sensitive clear vinyl films for use in the sign and awning industry which overcome these and other problems of the prior art. it is a general object of the present invention to provide a method of making translucent colored PVF films for use in the sign and awning industry.
It is yet another object of the present invention to provide a method of making such films in a continuous fashion to facilitate the production of color-backed film in continuous rolls.
It is a further object of the invention to manufacture such film using rotary silkscreen web printing techniques that enable the production of custom-colored TEDLAR or other clear vinyl films in small to high quantity, yet low cost, production runs.
It is still another object of the invention to describe a method for manufacturing translucent colored PVF film wherein certain processing variables of the rotary web machine are within predetermined operating constraints to consistently create a high quality rolled product at low cost.
It is another feature of the invention to describe a method of continuously manufacturing colored TEDLAR films wherein the translucent acrylic ink has a predetermined viscosity and may be preprocessed to prevent streaking of the pigments therein during film production.
It is yet another object of the invention to describe a method of continuously manufacturing colored TEDLAR films wherein the film is preprocessed to increase the surface tension of the film prior to application of the ink.
In the preferred embodiment, a method is described for making colored backed film material using a polyvinyl fluoride (PVF) film having a first face and a second face opposite the first face, the first face pre-coated with an ink-receptive coating. According to the method, a carrier is first statically laminated to the second face of the PVF film. "Static" lamination means that the carrier is only temporarily laminated and can be later removed from the remainder of the film. Thereafter, a translucent acrylic ink is continuously applied onto the pre-coated first face of the PVF film to produce a colored PVF film. This film is then passed through an oven to dry the ink. After cooling, the colored PVF film is then separated from the carrier. Such separation may be effected while the PVF film is collected on a continuous roll.
If desired, an adhesive coating may be continuously applied to the first face of the PVF film after the PVF film is separated from the carrier. A backing paper is then continuously applied over the adhesive coating to produce a roll stock of colored film.
In use, the roll stock is cut to the appropriate size, the backing paper is removed and the color-backed film is then applied to a" back-lit sign, awning or other suitable support. The foregoing has outlined some of the more pertinent objects of the present invention. These objects should be construed to be merely illustrative of some of the more prominent features and applications of the invention. Many other beneficial results can be attained by applying the disclosed invention in a different manner or modifying the invention as will be described. Accordingly, other objects and a fuller understanding of the invention may be had by referring to the following Detailed Description of the preferred embodiment.
For a more complete understanding of the present invention and the advantages thereof, reference should be made to the following Detailed Description taken in connection with the accompanying drawings in which:
FIGURE 1 is flowchart of the preferred processing steps of the present invention; FIGURE 2 is a schematic diagram of a rotary silkscreen apparatus for use in the method of the present invention;
FIGURE 3 is a detailed perspective view of the rotary screen printing apparatus for use in the inventive method;
FIGURE 4 is a detailed perspective view of the rotary screen and squeegee mechanism of the printing apparatus of FIGURE 3;
FIGURE 5 is a schematic diagram of the rotary screen and squeegee mechanism showing the position of these components relative to the counter pressure roller of the apparatus; and
FIGURE 6 is an side view of the preferred structure of the color-backed film manufactured according to the method of the present invention. Similar reference characters refer to similar steps throughout the drawings.
Polyvinyl fluoride ("PVF") film, such as DuPont® TEDLAR® film, is well-known. TEDLAR is a thin, generally clear film that is dirt-resistant and exhibits excellent UV resistance. While in the preferred embodiment PVF film is used as the base web material, it should be appreciated that the method of the present invention is also useful for producing color-backed films made of other materials including, without limitation, polypropylene, polyvinyl chloride, polyester. The inventive process may thus be effected with other clear film polymer materials having surface tension characteristics suitable for supporting acrylic inks (either directly or through enhancement of such characteristics) .
In the preferred embodiment, the acrylic inks are translucent. Such inks typically include three components: pigment, clear varnish (i.e., acrylic resins) and a solvent. These inks are commercially available in several basic colors. Custom colors are created by mixing appropriate commercial inks together (e.g., turquoise by mixing green, blue and white) . According to the present invention, it is desirable to form custom colors (such as turquoise) by dispersing all necessary pigments (e.g., green, blue and white) into the clear varnish prior to putting the inks into solution. Thus, instead of forming separate inks and then combining them, it has been found desirable to disperse the pigments in the varnish first and then add the solvent. This reduces the tendency of the pigments to separate during application to the PVF film. Referring now to FIGURE 1, a flowchart is shown of the preferred processing steps of the present invention. As noted above, the method for making colored backed film material preferably uses a polyvinyl fluoride (PVF) film web or "base" having a first face and a second face opposite the first face. At step 10, the first face of the PVF film is preferably coated with an ink-receptive coating. Such coatings are known in the art and function to increase the surface tension of the PVF film to thus facilitate the adhesion of the acrylic ink. Although not meant to be limiting, the ink receptive coating may be TC-160 print receptive coating provided by Flexcon Manufacturing. The ink receptive coating is preferably applied during a pre-processing stage as opposed to during the application of the acrylic ink. Thus, in the preferred embodiment the PVF film may be said to be "pre-coated" with an ink receptive coating to facilitate the remaining processing steps. Of course, the method is not intended to be limited in this regard and the ink receptive coating may be applied to the PVF film as part of the preferred method of carrying out the invention.
Alternatively, the surface tension of the PVF film is increased by flame or corona etching, or by a combination of such etching and application of the ink receptive coating as described above. Such processing steps are known in the art. Of course, the step of enhancing the surface tension of the clear film may be omitted if the surface tension of the film is adequate to retain the acrylic ink for the specific application and/or the desired shelf life of the product.
Referring now back to FIGURE 1, the method continues at step 12 wherein a carrier material is temporarily or "statically" laminated to the second face of the pre-coated PVF film (e.g., the PVF film having an ink receptive coating on its first face) . As used herein, "static" lamination means that the carrier is not adhered to the PVF film in a positive sense (i.e., through an adhesive or the like) and thus can be later removed in an simple manner by just separating the carrier and film. The carrier sheet is preferably paper or clear polyester having a thickness of about 5.0 mil. The carrier is generally useful because the thickness of the PVF film is approximately 1.0 mil. PVF films having greater thicknesses tend to be milky or creamy in color and thus tend to produce poor color-backed material. The carrier sheet thus provides physical integrity to the clear film base so that the continuous ink processing may be effected as will hereafter be described. The carrier may be omitted if thicker, yet clear films are used as the base web material.
The method continues at step 14 wherein a translucent acrylic ink is continuously applied onto the pre-coated first face of the PVF film. At step 16, the translucent acrylic ink coating is continuously dried. Thereafter, at step 18, the colored PVF film is separated from the carrier, which can then be reused. The method then continues at step 20 through the continuous application of a pressure sensitive adhesive coating over the previously-coated first face of the PVF film. At step 22 a backing paper is continuously applied over the pressure sensitive adhesive coating.
In the preferred embodiment of the method, a rotary web silkscreen apparatus is used to provide continuous application of acrylic ink to a PVF film whose surface tension has been enhanced. One such apparatus, not to be considered by way of limitation, is the Stork Rotary Screen Coating/ Printing Line for coating and printing sold commercially as Type PD-IV-4300/ML by Stork X-cel BV of Holland. The apparatus 20 is shown schematically in elevation in FIGURE 2 and comprises a number of functional components: an unwind mechanism 22, a rewind mechanism 24, a corona discharge mechanism
25, a guide mechanism 26, an outfeed mechanism 28, a drive mechanism 30, a rotary screen coating/printing unit 32, a drying mechanism 34, and a cooling mechanism 36. The unwind mechanism 22 comprises a movable stand 38 and a pneumatic brake 40. The PVF film, with the ink receptive coating on the first face and the carrier sheet laminated to the second face, is supported in rolled form on the movable stand 38.
The pre-coated PVF film (with the carrier sheet laminate) is then threaded under the corona discharge mechanism 25, through the guide mechanism
26, through the drive mechanism 30, through the rotary screen coating/printing unit 32, through the drying mechanism 34, through the cooling mechanism 36, and then through the outfeed mechanism 28. The outfeed mechanism 28 guides the web to the rewind mechanism 24 and also functions to separate or delaminate the carrier sheet from the remainder of the material.
The corona discharge mechanism 25 operates to produce an electrical field disturbance across the first face of the film, thereby increasing the surface tension of the ink receptive coating and the PVF film. The corona discharge enhances the adhesion of the acrylic ink to the film and thus lengthens the effective life of the product. The corona discharge is optional, and when the mechanism is used it may not be necessary to apply an ink receptive coating. In the preferred embodiment. both the ink receptive coating and the corona discharge 25 are used to increase the surface tension of the film. The corona treating unit comprises a generator, a high voltage transformer 5 and an electrode which function to provide a corona discharge at the electrode adjacent the passing web. One such unit is a Model PBS Corona Discharge Unit manufactured by Sherman Treaters (North America) Inc. of Ontario, Canada.
10 After the pre-coated (or otherwise pre-treated) PVF film is threaded through the apparatus in the above-described manner, the drive mechanism 30 is activated. The PVF film is then unwound from the unwind mechanism and continuously processed through
15 the apparatus. As the film passes through the rotary screen coating/printing unit 32, an acrylic ink is continuously applied onto the first face of the film.
This rotary web screen printing apparatus is
20 shown in more detail in FIGURES 3-5. FIGURE 3 shows a portion of the apparatus including the guide mechanism 26, the drive mechanism 30, the rotary screen coating/printing unit 32, the drying mechanism 34, the cooling mechanism 36 and a portion
25 of the outfeed mechanism 28. Guide mechanism 26 includes the guide rollers 40 and 42, and the web passes under roller 40 and over roller 42 as shown. The drive mechanism includes rollers 44 and 46 upstream of the rotary screen coating/printing unit
30 32, and rollers 48 and 50 downstream of the cooling mechanism 36.
The primary component of the apparatus is the rotary screen coating/printing mechanism 32.
Referring simultaneously to FIGURES 3-4, the
~\ ~_ . . .
J mechanism comprises a printing/coating head 52, a rotary screen 54, a squeegee 56 and a counter pressure roller 58. A tray 60 underlies the rotary screen for collecting excess ink. The printing/ coating head 52 receives the acrylic ink from a reservoir (not shown) and delivers the ink into the 5 interior 61 of a circular body portion 63 of the squeegee. Referring now simultaneously to FIGURE 4-5, the circular body portion 63 of the squeegee includes a longitudinal slot 62 along a portion of its length. A paste spreading blade 64 is attached ° to the body portion 63 and underlies the slot 62. The paste spreading blade has a first or tray portion 62a, a lip portion 62b and a flexible third portion 62c. A squeegee blade 66 overlies the portions 62b and 62c of the paste spreading blade 5 and is retained in a clamp 71. The squeegee blade
66 includes a first portion 66a and a second portion 66b. The first portion is preferably formed of chromium steel and the second section is formed of silicone rubber of polyurethane. 0 The web 68 passes between a distal edge of the sgueegee blade and the counter-pressure roller 58 substantially as shown. As seen in FIGURE 4, the rotary screen 54 rotates counterclockwise while the counter-pressure roller rotates clockwise. In operation, the head 52 receives the acrylic ink, which is delivered along the interior 61 of the body portion 63. The ink passes out of the slot 62 and is collected between the paste spreading blade and the squeegee blade. As the rotary screen rotates, the squeegee blade forces the acrylic ink through the screen and onto the web to form a coating 65.
Referring back to FIGURE 3, after the acrylic ink is applied to the PVF film, the ink and film are passed through an drying mechanism 34, which preferably comprises a plurality of hot air blowers 70. The dryer removes the ink solvent to enable the web to be re-rolled. It is desirable to control the amount of drying because if too much of the solvent is removed, the ink becomes brittle. If too little solvent is removed, the ink remains sticky and the web cannot be effectively re-rolled.
After drying, the web is passed around a pair of cooling rollers 72 and 74 comprising the cooling mechanism 36. This mechanism lowers the temperature of the web. The web is then drawn through rollers 48 and 50 of the drive mechanism 30, and then passed through the outfeed mechanism having rollers 76 and 78. The carrier is then delaminated by the outfeed mechanism (and can be reused) and the color-backed film web is re-rolled on the rewind mechanism. A translucent colored, pressure-sensitive PVF film can be formed with two additional processing steps. At step 16, an adhesive coating is continuously applied to the inked first face of the PVF film after the PVF film is separated from the carrier. Although not meant to be limiting, preferably the adhesive is a non-toulene based composition that does not interfere with the ink. One such coating is V-156 pressure sensitive adhesive coating supplied by Flexcon Manufacturing. Such coatings are applied to the colored PVF film using, for example, a knife-over-roll apparatus, although the specific method of applying the adhesive coating is not meant to be limited in any way. Thereafter, a backing paper is continuously applied over the adhesive coating to form a translucent colored, pressure-sensitive TEDLAR® film. The method of the present invention thus solves the problems of the prior art while allowing for the production of a color-backed film in continuous rolls by means of web machine silkscreen application of color. The rolls can be made in large widths (e.g., up to about eight feet). The color-backing can be matched to any custom color and can be manufactured in minimal to maximum quantity, low cost production runs. The resulting product satisfactorily addresses the problems of environmental dirt and solar degradation and facilitates the production of back-lit outdoor signs having pressure-sensitive vinyl graphics on a suitable translucent carrier or other sign face material.
The translucent colored, pressure-sensitive TEDLAR® film produced by the method of the present invention is shown in FIGURE 6. The material comprises a TEDLAR® clear PVF film 90 (approximately l.o mil thick), a clear ink receptive coating 92 (approximately 0.03 mil thick), a coating of translucent custom-formulated colored ink 94, a clear pressure-sensitive adhesive coating 96, and a removable temporary backing paper 98 (approximately 5.0 mil thick). In use, the temporary backing paper 98 is removed and the material is applied to a translucent carrier or other sign face or awning material. 100
It has been found that controlling certain process variables and constraints significantly enhances the quality of the finished product. Preferably, the rotary web screen apparatus has an 80 mesh (i.e., 80 holes per square inch) screen having a predetermined thickness of approximately 150 microns. The openings in the screen are hexagonal and taper from the outside to the inside (i.e., to form conical openings). The squeegee blade is positioned with its blade tip at the heart of the counter pressure roller, i.e., where contact is made with the rotary screen. The squeegee pressure is relatively high and the length of the squeegee blade is relatively long. A preferred squeegee blade is an ULDOME Stainless Steel from Stork.
The translucent acrylic ink has a predetermined viscosity of approximately 5000 centipoise. The unwind and rewind mechanisms are run at the same predetermined speed between 10-12 meters per minute (and preferably 10 meters per minute) as the translucent acrylic ink is continuously applied to the pre-coated PVF film. The pre-coating is preferably TC-160 coating (with thickness of approximately 0.03 mil) provided by Flexcon Manufacturing. The oven preferably operates over a predetermined temperature range between 170-185 degrees Fahrenheit. Within these operating constraints and variables, the ink is much easier to spread and the pigments do not separate during the continuous application process. The inks are dried easily and the color-backed roll is able to be wound on the rewind mechanism without damaging the material.
It should be appreciated by those skilled in the art that the specific embodiments disclosed above may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present invention. For example, the acrylic ink may be continuously applied to the PVF film by moving a print head along the length of a stationary length of film (instead of using a rotary web machine) . It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims.

Claims

CLAIMSWhat is claimed is:
1. A method for making colored backed film material using a polyvinyl fluoride (PVF) film having a first face and a second face opposite the first face, comprising the steps of: processing the PVF film to increase the surface tension of the PVF film first face; statically laminating a carrier to the second face of the PVF film; continuously applying a translucent acrylic ink onto the first face of the PVF film; continuously drying the translucent acrylic ink applied to the PVF film; and separating the PVF film from the carrier.
2. The method as described in Claim 1 further including the steps of: continuously applying an adhesive coating to the first face of the PVF film after the PVF film is separated from the carrier; and continuously applying a backing paper over the adhesive coating.
3. The method as described in Claim 1 wherein the step of increasing the surface tension of the PVF film first face includes the step of: continuously passing the PVF film through a corona discharge.
4. The method as described in Claim 1 wherein the step of increasing the surface tension of the PVF film first face includes the step of: continuously coating the first face with an ink receptive coating.
5. The method as described in Claim 1 wherein the step of increasing the surface tension of the PVF film first face includes the steps of: continuously passing the PVF film through a corona discharge; and continuously coating the first face with an ink receptive coating.
6. The method as described in Claim 1 wherein the translucent acrylic ink is continuously applied to the PVF film using a rotary web silkscreen apparatus.
7. The method as described in Claim 6 wherein the rotary silksceen apparatus has a silkscreen having a predetermined thickness.
8. The method as described in Claim 7 wherein the predetermined thickness is approximately 150 microns.
9. The method as described in Claim 1 wherein the translucent acrylic- ink has a predetermined viscosity.
10. The method as described in Claim 9 wherein the predetermined viscosity is approximately 5000 centipoise.
11. The method as described in Claim 6 wherein the rotary web silkscreen apparatus operates at a predetermined speed to continuously apply the translucent acrylic ink to the PVF film.
12. The method as described in Claim 11 wherein the predetermined speed is between 10-12 meters per minute.
13. The method as described in Claim 6 wherein the rotary web silkscreen apparatus includes an oven for drying the PVF film after the translucent acrylic ink is applied.
14. The method as described in Claim 13 wherein the oven operates over a predetermined temperature range.
15. The method as described in Claim 14 wherein the predetermined temperature range is between 170-185 degrees Fahrenheit.
16. A method for making colored backed film material using a polyvinyl fluoride (PVF) film having a first face and a second face opposite the first face, the first face pre-coated with an ink-receptive coating, comprising the steps of: statically laminating a carrier to the second face of the PVF film; applying a translucent acrylic ink having a viscosity of approximately 5000 centipoise onto the pre-coated first face of the PVF film using a rotary web silkscreen apparatus, the rotary web silkscreen apparatus running at a speed between 10-12 meters per minute and having a silkscreen approximately 150 microns thick; continuously drying the PVF film in an oven operating at a temperature of approximately 170-185 degrees Fahrenheit; and separating the PVF film from the carrier.
17. The method as described in Claim 16 further including the step of: continuously passing the PVF film through a corona discharge apparatus prior to applying the translucent acrylic ink to increase the surface tension of the PVF film.
18. A method for making colored backed film material using a polyvinyl fluoride (PVF) film having a first face and a second face opposite the first face, comprising the steps of: coating the first face of the PVF film with an ink-receptive coating; statically laminating a carrier to the second face of the PVF film; continuously applying a translucent acrylic ink onto the first face of the PVF film; separating the PVF film from the carrier; continuously applying an adhesive coating to the first face of the PVF film after the PVF film is separated from the carrier; and continuously applying a backing paper over the adhesive coating.
EP93916663A 1992-06-19 1993-06-21 Method for making translucent colored-backed films. Withdrawn EP0646065A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US90143592A 1992-06-19 1992-06-19
US901435 1992-06-19
PCT/US1993/005930 WO1994000294A1 (en) 1992-06-19 1993-06-21 Method for making translucent colored-backed films

Publications (2)

Publication Number Publication Date
EP0646065A1 true EP0646065A1 (en) 1995-04-05
EP0646065A4 EP0646065A4 (en) 1996-11-27

Family

ID=25414185

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93916663A Withdrawn EP0646065A4 (en) 1992-06-19 1993-06-21 Method for making translucent colored-backed films.

Country Status (4)

Country Link
EP (1) EP0646065A4 (en)
AU (1) AU4644093A (en)
CA (1) CA2138524A1 (en)
WO (1) WO1994000294A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5827608A (en) * 1996-10-28 1998-10-27 Minnesota Mining And Manufacturing Company Method of forming a thermoplastic layer on a flexible two-dimensional substrate and powder for preparing same
KR20010041763A (en) 1998-03-11 2001-05-25 스프레이그 로버트 월터 Method of forming a thermoplastic layer on a layer of adhesive
CN105268600A (en) * 2015-11-19 2016-01-27 湖南省客来宝生物能源科技有限公司 Surface layer dyeing device for biodegradation film
CN114196341A (en) * 2020-09-02 2022-03-18 乔成辉 Colored polyvinyl fluoride bridge cable protection adhesive tape and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3616192A (en) * 1970-02-04 1971-10-26 Riegel Paper Corp Decorative polyvinyl fluoride laminations
US3889595A (en) * 1972-07-03 1975-06-17 Precision Screen Machines Continuous rotary screen printing method and apparatus
US4167595A (en) * 1975-01-08 1979-09-11 Alkor Gesellschaft Mit Beschrankter Haftung Kunststoffverkauf Method of printing on plastic foil
US4285274A (en) * 1979-07-05 1981-08-25 Toshin Kogyo Co., Ltd. Seamless cylindrical printing screen and process for preparation thereof
WO1992017870A1 (en) * 1991-03-28 1992-10-15 Brady Coated Products Co. Subsurface printable sheet material for outdoor signage

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3380871A (en) * 1963-11-14 1968-04-30 Reynolds Metals Co Method for making printable and/or glueable polyolefinic material
US4193829A (en) * 1977-03-16 1980-03-18 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Process for the manufacture of low density bis-maleimide-carbon microballoon composites
JPS5537378A (en) * 1978-09-11 1980-03-15 Dainippon Printing Co Ltd Method of printing on thermoplastic film
US4661182A (en) * 1985-07-31 1987-04-28 Color Communications, Inc. Method and composition for repairing minor surface damage to coated surfaces
US4724508A (en) * 1985-12-18 1988-02-09 Becton, Dickinson And Company Method and apparatus for the continuous corona discharge treatment of the surface of formed articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3616192A (en) * 1970-02-04 1971-10-26 Riegel Paper Corp Decorative polyvinyl fluoride laminations
US3889595A (en) * 1972-07-03 1975-06-17 Precision Screen Machines Continuous rotary screen printing method and apparatus
US4167595A (en) * 1975-01-08 1979-09-11 Alkor Gesellschaft Mit Beschrankter Haftung Kunststoffverkauf Method of printing on plastic foil
US4285274A (en) * 1979-07-05 1981-08-25 Toshin Kogyo Co., Ltd. Seamless cylindrical printing screen and process for preparation thereof
WO1992017870A1 (en) * 1991-03-28 1992-10-15 Brady Coated Products Co. Subsurface printable sheet material for outdoor signage

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO9400294A1 *

Also Published As

Publication number Publication date
AU4644093A (en) 1994-01-24
EP0646065A4 (en) 1996-11-27
WO1994000294A1 (en) 1994-01-06
CA2138524A1 (en) 1994-01-06

Similar Documents

Publication Publication Date Title
US5651852A (en) Method for making linerless labels with a specific tie coat
US5518762A (en) Method and apparatus for manufacturing linerless labels
DE69327611T2 (en) Self-adhesive, decorative surface covering material
US4960482A (en) Apparatus and method for manufacture of adhesive label
US5989380A (en) Process of dry printing a paper-like non-woven wall covering material
DE69018794T2 (en) Film coating for rigid and smooth surfaces.
US5000810A (en) Decorative or printed laminates and methods for making same
US5667618A (en) Method for making translucent colored-backed films and continuous length made thereby
USRE44113E1 (en) Method of making color fan deck
US4124431A (en) Dimensionally stable, calendered vinyl film
WO1994000294A1 (en) Method for making translucent colored-backed films
US20090130448A1 (en) Flexible magnets having a printable surface and methods of production
CN111040657A (en) Multicolor printing cloth-based adhesive tape and preparation method thereof
US5797316A (en) Transfer rolling device for producing banners
KR200428669Y1 (en) Structure of sticker
JP4682266B2 (en) Backed advertising poster sheet
JP2849432B2 (en) Pictured blind and method of manufacturing the same
KR20090027285A (en) Air ventability gummed paper and it's between laying method
JPH05171119A (en) Production tacky sheet
JP2607109Y2 (en) Printing sheet
KR970058959A (en) Print material for jet printer and manufacturing method thereof
JP2002149070A (en) Printing sheet with release sheet
JPH0692005A (en) Gravure printing method of cloth
JPS59115848A (en) Preparation of double-surface printed matter
JPS62247370A (en) Formation of protective film onto print photograph

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19950119

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI NL PT SE

A4 Supplementary search report drawn up and despatched

Effective date: 19961010

AK Designated contracting states

Kind code of ref document: A4

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI NL PT SE

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19980105