EP0619363A1 - Composition de nettoyage domestique liquide repoussant les insectes - Google Patents

Composition de nettoyage domestique liquide repoussant les insectes Download PDF

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Publication number
EP0619363A1
EP0619363A1 EP94200951A EP94200951A EP0619363A1 EP 0619363 A1 EP0619363 A1 EP 0619363A1 EP 94200951 A EP94200951 A EP 94200951A EP 94200951 A EP94200951 A EP 94200951A EP 0619363 A1 EP0619363 A1 EP 0619363A1
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EP
European Patent Office
Prior art keywords
detergent composition
mgk
insect repellent
liquid detergent
repellent material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94200951A
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German (de)
English (en)
Inventor
Robert J. Steltenkamp
John H. Puckhaber, Jr.
Daniel Colodney
Thomas C. Hendrickson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
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Colgate Palmolive Co
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Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of EP0619363A1 publication Critical patent/EP0619363A1/fr
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to liquid detergent compositions suitable for cleaning hard surfaces and which impart insect repelling properties. More particularly, this invention relates to liquid all purpose detergent compositions containing an insect repellent material, and to a process for cleaning and repelling insects from surfaces and articles to which such detergent compositions are applied.
  • insects common in households, such as German (Blattela germanica) or house cockroaches, are classified as pests, and much effort has been made to eradicate or at least to control them.
  • Mosquito repellents have long been marketed and various chemicals that are effective in repelling roaches have been discovered. Typically, these chemicals and repellents are used in the household by applying or spraying them to surfaces of walls, floors, cabinets, drawers, packages, containers, rugs, upholstery and carpeting, and in potential nesting places for insects, such as inside walls and between floors.
  • insect repellents have not been generally used in conjunction with hard surface cleaners so as to effectively clean a hard household surface, such as a kitchen wall, oven top, bathroom floor or the like, while at the same time applying a film of insect repellent material which is sufficiently substantive to the surface to which the composition is applied to repel insects therefrom.
  • U.S. Patent 3,018,217 to Bruce discloses floor wax coating compositions containing dibutyl succinate as an insect repellent.
  • U.S. Patent 3,034,950 to Goodhue et al discloses a class of insect repellent compounds which may be applied to surfaces dispersed in a wax.
  • U.S. 4,455,308 to Smolanoff there are described insect repellent formulations containing a liquid carrier such as liquid aliphatic or aromatic hydrocarbons.
  • An emulsifying agent such as a nonionic surfactant may be added to the liquid hydrocarbon to permit the composition to be dispersed in water for end use application.
  • U.S. Patent 4,822,614 to Rodero discloses an insect-repellent ingredient in a hydrocarbon-based solvent such as isoparaffinic hydrocarbons.
  • the present invention provides an aqueous liquid detergent composition capable of cleaning a hard surface and repelling insects therefrom comprising (i) a detersive proportion of a surface active detergent compound selected from the group consisting of anionic, nonionic, cationic and amphoteric detergent compounds; (ii) at least about 50%, by weight, water; and (iii) an effective amount of an insect repellent material which is sufficient to repel insects from such hard surface after application of the detergent composition thereto.
  • the liquid detergent composition is free of an insecticide.
  • the present invention is predicated on the discovery that the insect repellent properties of a repellent material is enhanced with regard to a specific area or location when such area or location is cleaned with a detergent composition as herein described. This effect may be attributed to the natural tendency of insects to preferentially congregate in soiled areas rather than upon a cleaned surface as well as the increased substantivity of the insect repellent material to such washed or cleaned surfaces.
  • insects is used herein in its broad sense and, is intended to encompass cockroaches, such as the German (Blattela germanica) and American (Periplaneta americana) roach, as well as mosquitoes, moths, flies, fleas, ants, lice and arachnids, such as spiders, ticks and mites.
  • cockroaches such as the German (Blattela germanica) and American (Periplaneta americana) roach
  • mosquitoes, moths, flies, fleas, ants, lice and arachnids such as spiders, ticks and mites.
  • insect repellent material is intended to encompass a wide variety of materials having insect repellent properties which are compatible with the type of detergent composition described herein and which manifest a sufficient substantivity to the hard surface to which the detergent composition is applied to be efficacious as a repellent.
  • insect repellent materials useful for the present invention are the following compounds which may be used individually or in combination with other repellent materials, the designation in parenthesis following certain compound names referring to its commercial or common designation:
  • N-alkyl neoalkanamides wherein the alkyl is of 1 to 4 carbon atoms, and the neoalkanoyl moiety is of 7 to 14 carbon atoms, preferably N-methyl neodecanamide: N,N-diethyl-meta-toluamide (DEET); 2-Hydroxyethyl-n-octyl sulfide (MGK 874);1 N-Octyl bicycloheptene dicarboximide (MGK 264); A preferred mixture of the above two materials comprising 66% MGK 264 and 33% MGK 874; Hexahydrodibenzofuran carboxaldehyde (MGK 11); Di-n-propyl isocinchomerate (MGK 326); 2-Ethyl-1,3-hexanediol (Rutgers 612); 2-(n-butyl)-2-ethyl-1,3-propane
  • insect repellent materials are longer lasting and are preferred for purposes of the present invention
  • other useful repellent materials include essential oils such as Mentha arvensis (Cornmint); Mentha piperita (Peppermint); Mentha spicata (American Spearmint); Mentha cardica (Scotch Spearmint); Lemongrass East Indian Oil; Lemon Oil; Citronella; Cedarwood (Juniperus virginiana L.); and Pine Oil.
  • Terpenoids are another class of materialshaving insect repellent properties, the most useful being (-)-Limonene; (+)-Limonene; (-)-Carvone; Cineole (Eucalyptol); Linalool; Gum Camphor; Citronellal; Alpha and Beta -Terpineol; Fencholic acid; Borneol iso Borneol, Bornyl acetate and iso Bornyl acetate.
  • non-commercial repellent materials useful for the invention are the following: N,N-Diethyl cyclohexylacetamide (DECA) 1,2,3,6-Tetrahydro-1-(2-methyl-1-oxopentyl) piperidine N,N-Diethyl-3-cyclohexyl propionamide (DCP) 2-Ethyl-1-(2-methyl-1-oxo-2-butenyl) piperidine N,N-diethyl nonanamide, and N,N-Diethyl Phenylacetamide.
  • DECA N,N-Diethyl cyclohexylacetamide
  • DCP 2-Ethyl-1-(2-methyl-1-oxo-2-butenyl) piperidine N,N-diethyl nonanamide
  • N,N-Diethyl Phenylacetamide N,N-Diethyl Phenylacetamide
  • the alkyl group is preferably methyl or ethyl, and most preferably is methyl.
  • the neoalkanoyl moiety is preferably neodecanoyl or neotridecanoyl.
  • the detergent compositions of the invention contain a detersive proportion of one or more surface active detergent compounds from among anionic, nonionic, cationic and amphoteric detergents, which generally will be in the range of from about 1 to about 30%, by weight, of the composition, preferably from about 2 to about 20%, by weight.
  • the detergent is preferably a synthetic organic detergent of the anionic or nonionic type and often a combination of anionic and nonionic detergents will be most preferred. Descriptions of many such detergents are found in the text Surface Active Agents and Detergents, Vol, II, pages 25-138, by Schwartz, Perry and Berch, published in 1958 by Interscience Publishers, Inc. Such compounds are also described in a 1973 publication by John W. McCutcheon, entitled Detergents and Emulsifiers. Both such publications are incorporated herein by reference.
  • the anionic detergents employed will normally be salts of alkali metals, such as sodium or potassium or ammonium or lower alkanolammonium salts, e.g., triethanolamine salts.
  • the anionic detergent may be a sulfate, sulfonate, phosphate or phosphonate or salt of other suitable acid but usually will be a sulfate or sulfonate.
  • the anionic detergents include a lipophilic group, which will normally have from 10 to 18 carbon atoms, preferably in linear higher alkyl arrangement, but other lipophilic groups may be present instead, preferably including 12 to 16 carbon atoms, such as branched chain alkyl benzene.
  • anionic detergents include higher fatty alcohol sulfonates, such as sodium tridecylbenzene sulfonate; sodium linear alkyl benzene sulfonates, e.g., sodium linear dodecylbenzene sulfonate; olefin sulfonates; and paraffin sulfonates.
  • the anionic detergents are preferably sodium salts but potassium, ammonium and triethanolammonium salts are often more desirable for some liquid compositions.
  • the suitable nonionic detergents will normally be condensation products of lipophilic compounds or moieties and lower alkylene oxides or polyalkoxy moieties.
  • Highly preferable lipophiles are higher fatty alcohols of 10 to 18 carbon atoms but alkyl phenols, such as octyl and nonyl phenols, may also be used.
  • the alkylene oxide of preference is ethylene oxide and normally from 3 to 30 moles of ethylene oxide will be present per mole of lipophile.
  • ethoxylate content will be 3 to 10 moles per mole of higher fatty alcohol and more preferably it will be 6 to 7 moles, e.g., 6.5 or 7 moles per mole of higher fatty alcohol (and per mole of nonionic detergent).
  • Both broad ranges ethoxylates and narrow range ethoxylate may be employed, with the difference between them being in the "spread" of number of ethoxylate groups present, which average within the ranges given.
  • NRE's which average 5 to 10 EtO groups per mole in the nonionic detergent will have at least 70% of the EtO content in polyethoxy groups of 4 to 12 moles of EtO and will preferably have over 85% of the EtO content in such range.
  • BRE nonionic detergents have a broader range of ethoxy contents than NRE's, often with a spread from 1 to 15 moles of EtO when the EtO chain is in the 5 to 10 EtO range (average).
  • BRE nonionic detergents examples include those sold by Shell Chemical Company under the trademark Neodol R , including Neodol 25-7, Neodol 23-6.5 and Neodol 25-3. Supplies of NRE nonionic detergents have been obtained from Shell Development Company, which identifies such materials as 23-7P and 23-7Z.
  • Cationic surface active compounds may also be employed. They comprise surface active detergent compounds which contain an organic hydrophobic group which forms part of a cation when the compound is dissolved in water, and an anionic group. Typical cationic detergents are amine and quaternary ammonium compounds.
  • the quaternary ammonium compounds useful herein are known materials and are of the high-softening type. Included are the N1N-di-(higher) C14-C24, N1N-di(lower C1-C4 alkyl quaternary ammonium salts with water solubilizing anions such as halide, e.g. chloride, bromide and iodide; sulfate, methosulfate and the like and the heterocyclic amides such as imidazolinium.
  • the aliphatic quaternary ammonium salts may be structurally defined as follows: wherein R and R1 represent alkyl of 14 to 24 and preferably 14 to 22 carbon atoms; R2 and R3 represent lower alkyl of 1 to 4 and preferably 1 to 3 carbon atoms, X represents an anion capable of imparting water solubility or dispersibility including the aforementioned chloride, bromide, iodide, sulfate and methosulfate.
  • Particularly preferred species of aliphatic quats include: distearyl dimethylammonium chloride di-hydrogenated tallow dimethyl ammonium chloride di tallow dimethyl ammonium chloride distearyl dimethyl ammonium methyl sulfate di-hydrogenated tallow dimethyl ammonium methyl sulfate.
  • Amphoteric detergents are also suitable for the invention. This class of detergents is well known in the art and many operable detergents are disclosed by Schwartz, Perry and Berch in "Surface Active Agents and Detergents", Vol. II, Interscience Publishers, Inc., New York (1958) in Chapter 4 thereof. Examples of suitable amphoteric detergents include: alkyl betaiminodipropionates, RN(C2H4COOM)2; and alkyl beta-amino propionates, RN(H)C2H4COOM.
  • Builders may be present in the liquid detergent composition in an amount of from about 1 to 20% to improve the detergency of the synthetic organic detergents.
  • Such builders may be inorganic or organic, water soluble or water insoluble. Included among such builders are polyphosphates, e.g., sodium tripolyphosphate; carbonates, e.g., sodium carbonate; bicarbonates, e.g., sodium bicarbonate; borates, e.g., borax; and silicates, e.g., sodium silicate; water insoluble inorganic builders, including zeolites, e.g., hydrated Zeolite 4A; and water soluble organic builders, including citrates, gluconates, NTA, and polyacetal carboxylates.
  • polyphosphates e.g., sodium tripolyphosphate
  • carbonates e.g., sodium carbonate
  • bicarbonates e.g., sodium bicarbonate
  • borates e.g., borax
  • silicates
  • Various adjuvants may be present in the detergent compositions such as fluorescent brighteners, antistatic agents, antibacterial agents, fungicides, foaming agents, anti-foams, flow promoters, suspending agents, antioxidants, anti-gelling agents, soil release promoting agents, and enzymes.
  • the liquid detergent compositions of the invention will generally comprise from about 2 to 20% of surface active detergent compounds which are preferably anionic and/or nonionic, from about 1 to 20%, by weight, of builder salts for such detergents and from about 0.2 to 20%, preferably 0.5 to 10%, by weight, of the insect repellent material, the balance being predominantly water, adjuvants and optionally an emulsifying agent, or hydrotrope such as sodium toluene sulfonate or a solvent suitable for the insect repellent material such as isopropyl alcohol or acetone.
  • surface active detergent compounds which are preferably anionic and/or nonionic
  • builder salts for such detergents and from about 0.2 to 20%, preferably 0.5 to 10%, by weight, of the insect repellent material, the balance being predominantly water, adjuvants and optionally an emulsifying agent, or hydrotrope such as sodium toluene sulfonate or a solvent suitable for the insect repellent material such as isopropyl alcohol or ace
  • a single composition in accordance with the invention formulated as shown below was used as the starting material to prepare by dilution six liquid compositions of varying degrees of dilution containing six correspondingly different levels of N-methyl neodecanamide (MNDA) insect repellent material.
  • MNDA N-methyl neodecanamide
  • Nonionic detergent (1) 2 MNDA 2.0 Coconut fatty acid 0.5 Soda ash 2 Sodium bicarbonate 1
  • Isopropyl alcohol 4 Water Balance Fragrance 1 (1) Condensation product of one mole of a mixture of fatty alcohols of 9-11 carbon atoms with 6 moles of ethylene oxide.
  • the percentage of MNDA in each of the six tested detergent compositions varied, respectively, as follows: 0.12, 0.20, 0.22, 0.29, 0.4 and 2.0%
  • insect repellency of each of these six hard surface cleaning detergent compositions was tested by the procedure described below and compared with the repellency imparted by three repellent-containing comparative compositions, i.e. three solutions of acetone containing 0.25, 0.5 and 1.0%, by weight, respectively, of MNDA.
  • the repellency of the various compositions to be tested were evaluated over time.
  • the procedure consisted of arranging five 3 x 3 inch asphalt tiles into a cubic shelter ("cup") and treating the tiles with the various test compositions. The treated sides faced inward. The method relies on the light avoidance response of the cockroaches.
  • Two milliliters of a test composition was applied to the entire inside surface of the cup.
  • Control cups were treated with acetone or water only. The cups were allowed to dry for 1 hr and then a control and a treated cup were inverted into each of the test cages. Food and water were provided in the center of each cage, outside of the cups.
  • Repellency was defined as the percentage of insects that avoided the treated surfaces and was calculated as where N t is the number of insects on the treated surface and N c is the number on the acetone treated control surfaces.
  • the repellency of compounds was evaluated on the basis of the number of days of 90% repellency which is based on (i) the number of days of complete (100%) repellency and (ii) a maximum likelihood probit analysis of time/repellency (SAS User's Guide, SAS Institute 1985) from which a measure was calculated of the number of days of 90% repellency (RT90 --10% of the insects on the treated surface, 90% on the control surface).
  • Figure 1 is a graph showing the number of days with 90% repellency as a function of the percent of MNDA in the test composition.
  • the comparative compositions not in accordance with the invention were unable to achieve 90% repellency at a level of MNDA repellent of 0.25%.
  • the compositions of the invention were able to provide almost 3 days of 90% repellency at a 0.2% level of MNDA.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)
EP94200951A 1993-04-08 1994-04-07 Composition de nettoyage domestique liquide repoussant les insectes Withdrawn EP0619363A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US4413793A 1993-04-08 1993-04-08
US4413893A 1993-04-08 1993-04-08
US44138 1993-04-08
US44137 1993-04-08

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EP0619363A1 true EP0619363A1 (fr) 1994-10-12

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EP (1) EP0619363A1 (fr)
JP (1) JPH06313199A (fr)
CN (1) CN1094087A (fr)
AU (1) AU679484B2 (fr)
BG (1) BG98700A (fr)
BR (1) BR9401414A (fr)
CA (1) CA2119832A1 (fr)
CZ (1) CZ82994A3 (fr)
DZ (1) DZ1770A1 (fr)
HN (1) HN1994002558A (fr)
HU (1) HUT67855A (fr)
MA (1) MA23153A1 (fr)
MY (1) MY118351A (fr)
NZ (1) NZ260145A (fr)
OA (1) OA09933A (fr)
PE (1) PE6395A1 (fr)
PL (1) PL177733B1 (fr)
PT (1) PT101478B (fr)
RO (1) RO114630B1 (fr)
SK (1) SK40894A3 (fr)
TN (1) TNSN94029A1 (fr)
UY (1) UY23753A1 (fr)
YU (1) YU48782B (fr)
ZA (1) ZA942051B (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0677578A1 (fr) * 1994-04-15 1995-10-18 Colgate-Palmolive Company (a Delaware corporation) Compositions de nettoyage liquides d'usage général en micro-émulsion contenant un agent repoussant les insectes
EP0677579A1 (fr) * 1994-04-15 1995-10-18 Colgate-Palmolive Company Compositions de nettoyage liquides en micro-émulsion contenant un agent repoussant les insectes
WO1996033800A1 (fr) * 1995-04-27 1996-10-31 Witco Corporation Compositions contenant du diol et/ou du diol alcoxylate
WO1996035769A1 (fr) * 1995-05-11 1996-11-14 Unilever Plc Compositions parfumees comprenant un polymere et un tensioactif non ionique
US5610130A (en) * 1993-08-04 1997-03-11 Colgate-Palmolive Company Microemulsion all-purpose liquid cleaning compositions with insect repellent
US5674832A (en) * 1995-04-27 1997-10-07 Witco Corporation Cationic compositions containing diol and/or diol alkoxylate
WO1997043369A1 (fr) * 1996-05-09 1997-11-20 Unilever Plc Compositions repulsives pour les insectes comprenant des agents antimicrobiens et des tensio-actifs non ioniques
WO1997047195A1 (fr) * 1996-06-10 1997-12-18 Colgate-Palmolive Company Compositions insectifuges a base de n-alkyl neoalcanamide et de n,n-diethyl-meta-toluamide
FR2755141A1 (fr) * 1996-10-30 1998-04-30 Johan A Benckiser Gmbh Composition detergente insectifuge pour surface solide
WO1998017772A1 (fr) * 1996-10-17 1998-04-30 Merck Patent Gmbh Produit de nettoyage
WO1999031216A1 (fr) * 1997-12-12 1999-06-24 Colgate-Palmolive Company Microemulsion antimicrobienne multifonction renfermant un tensio-actif cationique
FR2777014A1 (fr) * 1998-04-06 1999-10-08 Benckiser Nv Composition detergente liquide insectifuge pour surfaces solides
WO2001002525A1 (fr) * 1999-07-06 2001-01-11 Helen Dolisznyj Detergent insecticide
WO2003013243A1 (fr) * 2001-08-11 2003-02-20 Quest International B.V. Insectifuges
US6548469B2 (en) 1996-10-17 2003-04-15 Merck Patent Gmbh Cleaning compositions
WO2006092570A1 (fr) * 2005-03-02 2006-09-08 Reckitt Benckiser (Australia) Pty Limited Additif insectifuge pour nettoyant à plancher comprenant une pyréthrine de synthèse

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US6326336B1 (en) * 1998-10-16 2001-12-04 Ethyl Corporation Turbine oils with excellent high temperature oxidative stability
JP2003226894A (ja) * 2002-02-04 2003-08-15 Johnson Co Ltd 洗浄剤組成物、及び洗浄シート
CN102920617B (zh) * 2012-11-15 2014-05-28 四川大学 一种水剂型避蚊胺组合物及其制备方法
JP6061222B2 (ja) * 2012-12-27 2017-01-18 株式会社大阪製薬 衛生害虫駆除剤
CN108991035A (zh) * 2018-08-27 2018-12-14 佛山科学技术学院 一种用于家纺的驱虫洗液
CN115895797A (zh) * 2022-12-14 2023-04-04 中山榄菊日化实业有限公司 一种具有驱虫功效的地板清洁剂

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Publication number Priority date Publication date Assignee Title
EP0367257A1 (fr) * 1988-11-04 1990-05-09 Colgate-Palmolive Company N-alkyl néoalcanamides insectifuges
EP0499992A1 (fr) * 1991-02-19 1992-08-26 Colgate-Palmolive Company N-aryl et N-cycloalkyl néoalcanamides insectifuges
EP0525893A1 (fr) * 1991-07-24 1993-02-03 Colgate-Palmolive Company Composition liquide de nettoyage à utilisation domestique contenant un agent repoussant les insectes

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US5258408A (en) * 1986-08-08 1993-11-02 Colgate-Palmolive Company Process of repelling insects from an area by application of N-alkyl neoalkanamide insect repellent thereto
US4804683A (en) * 1986-08-08 1989-02-14 Colgate-Palmolive Company N-alkyl neotridecanamide insect repellents

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0367257A1 (fr) * 1988-11-04 1990-05-09 Colgate-Palmolive Company N-alkyl néoalcanamides insectifuges
EP0499992A1 (fr) * 1991-02-19 1992-08-26 Colgate-Palmolive Company N-aryl et N-cycloalkyl néoalcanamides insectifuges
EP0525893A1 (fr) * 1991-07-24 1993-02-03 Colgate-Palmolive Company Composition liquide de nettoyage à utilisation domestique contenant un agent repoussant les insectes

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5610130A (en) * 1993-08-04 1997-03-11 Colgate-Palmolive Company Microemulsion all-purpose liquid cleaning compositions with insect repellent
EP0677578A1 (fr) * 1994-04-15 1995-10-18 Colgate-Palmolive Company (a Delaware corporation) Compositions de nettoyage liquides d'usage général en micro-émulsion contenant un agent repoussant les insectes
EP0677579A1 (fr) * 1994-04-15 1995-10-18 Colgate-Palmolive Company Compositions de nettoyage liquides en micro-émulsion contenant un agent repoussant les insectes
US5578250A (en) * 1994-04-15 1996-11-26 Colgate-Palmolive Company Microemulsion liquid cleaning compositions with insect repellent
WO1996033800A1 (fr) * 1995-04-27 1996-10-31 Witco Corporation Compositions contenant du diol et/ou du diol alcoxylate
US5674832A (en) * 1995-04-27 1997-10-07 Witco Corporation Cationic compositions containing diol and/or diol alkoxylate
WO1996035769A1 (fr) * 1995-05-11 1996-11-14 Unilever Plc Compositions parfumees comprenant un polymere et un tensioactif non ionique
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UY23753A1 (es) 1994-09-23
JPH06313199A (ja) 1994-11-08
HUT67855A (en) 1995-05-29
CA2119832A1 (fr) 1994-10-09
PT101478B (pt) 1999-11-30
PL177733B1 (pl) 2000-01-31
TNSN94029A1 (fr) 1995-04-25
HU9400997D0 (en) 1994-06-28
CN1094087A (zh) 1994-10-26
PE6395A1 (es) 1995-03-08
CZ82994A3 (en) 1995-01-18
HN1994002558A (es) 1997-08-13
AU679484B2 (en) 1997-07-03
DZ1770A1 (fr) 2002-02-17
BG98700A (en) 1995-03-31
OA09933A (fr) 1994-11-15
RO114630B1 (ro) 1999-06-30
MY118351A (en) 2004-10-30
PT101478A (pt) 1995-01-31
SK40894A3 (en) 1994-10-05
YU48782B (sh) 1999-12-27
YU18194A (sh) 1996-10-09
AU5926294A (en) 1994-10-13
ZA942051B (en) 1995-05-26
MA23153A1 (fr) 1994-12-31
BR9401414A (pt) 1994-11-22
NZ260145A (en) 1995-12-21

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