EP0592928A1 - Tapered fiber and napped fabric utilizing the same - Google Patents
Tapered fiber and napped fabric utilizing the same Download PDFInfo
- Publication number
- EP0592928A1 EP0592928A1 EP93116098A EP93116098A EP0592928A1 EP 0592928 A1 EP0592928 A1 EP 0592928A1 EP 93116098 A EP93116098 A EP 93116098A EP 93116098 A EP93116098 A EP 93116098A EP 0592928 A1 EP0592928 A1 EP 0592928A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- tapered
- sheath
- fiber
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 170
- 239000004744 fabric Substances 0.000 title claims abstract description 94
- 229920000728 polyester Polymers 0.000 claims abstract description 51
- 239000002131 composite material Substances 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000003513 alkali Substances 0.000 claims description 16
- 230000003301 hydrolyzing effect Effects 0.000 claims description 16
- 239000010419 fine particle Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 239000002562 thickening agent Substances 0.000 claims description 10
- 238000005530 etching Methods 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000005562 fading Methods 0.000 abstract description 15
- 239000002932 luster Substances 0.000 abstract description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 238000002310 reflectometry Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 8
- -1 polyethylene terephthalate Polymers 0.000 description 8
- 206010016173 Fall Diseases 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 208000003251 Pruritus Diseases 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 102100038509 E3 ubiquitin-protein ligase ARIH1 Human genes 0.000 description 2
- 101000808922 Homo sapiens E3 ubiquitin-protein ligase ARIH1 Proteins 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- OTPBAANTTKRERC-UHFFFAOYSA-N benzyl(dodecyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCNCC1=CC=CC=C1 OTPBAANTTKRERC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000007759 kiss coating Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000417 polynaphthalene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000009732 tufting Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/02—Pile fabrics or articles having similar surface features
- D04B21/04—Pile fabrics or articles having similar surface features characterised by thread material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23957—Particular shape or structure of pile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23957—Particular shape or structure of pile
- Y10T428/23964—U-, V-, or W-shaped or continuous strand, filamentary material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2978—Surface characteristic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Definitions
- the present invention relates to a tapered fiber that can constitute napped fabrics having good hand with HARI (anti-drape stiffness) and KOSHI (stiffness) and excellent color developing property and depth of color and causing, after being sewn, no white appearance along seams. More specifically, the present invention relates to polyester fiber-based napped fabrics usable in a wide variety of uses such as interior fabrics, e.g. car seats and carpets, artificial suedes and clothing and to tapered fibers constituting the nap of such fabrics.
- polyester fiber-based napped fabrics give, when dyed, different color shades depending on the angle seen, thereby creating variation in luster and depth of color. As a result they often show partly blackish and partly whitened as if covered with dust.
- Such napped fabrics further have a drawback that, when sewn, their raised fibers fall down along the seam and look whitish, i.e. what is known as "whitened seam", which impairs the high-quality feeling to a large extent. This is attributable to the fabrics having large surface reflection caused by large refractivity and smooth surface of the polyester fibers used and also to reduced color developing property due to large difference between the reflectivities of the side surface and cross-section of the polyester fibers.
- alkali etching of the resulting fiber sometimes causes selective decomposition, so that the treated fiber becomes too thin, whereby the finished napped fabric has weak KOSHI, the fiber being neatly tapered though.
- recesses having a diameter in the above range are formed on the surface (sheath surface) other than the tapered, exposed core part of the fiber, it is not necessary that they be formed on the whole surface other than the exposed core part.
- the object of the present invention can be achieved by such recesses being present at least on the surface of the tapered part other than the exposed core. It is, however, desirable for obtaining still deeper color and milder luster that the recesses be present on the entire surface other than the exposed core part of the fiber.
- tapered fibers having a group of recesses on the exposed core part of the tapered ends and another group of recesses having a different size range from that of the above first group recesses, for the nap of a napped fabric can render the fabric free from whitened seams, as well as from dark fading, white appearance and the like.
- the term "napped fabric” herein means fabrics with a soft fuzzy fibrous surface comprising a multiplicity of raised fibers and includes woven and knit fabrics of cut-pile and fabrics of moquette, double raschel, velour and velvet, thus being not limited to those obtained by brushing against a rough surface.
- the fineness of the root part is therefore preferably in a range of 2 to 6 deniers.
- a fiber fineness exceeding 3 deniers generally causes itchy, unpleasant feeling.
- the problem of itchy feeling is also solved, whereby thicker fibers can be used for nap, which in turn prevents falling-down phenomenon.
- all of the fibers constituting the nap be the above-described tapered fibers, and it is sufficient that part, for example at least 30%, preferably at least 50% of the constituting fibers be the tapered fibers.
- Sheath-core composite polyester fibers with the core containing 0.3 to 15% by weight of alkali-insoluble inorganic fine particles and the sheath containing 0.5 to 5% by weight of alkali-soluble inorganic fine particles is treated with alkali. Then, at least one end of each of the raised fibers is tapered and two groups of recesses having specific, different sizes are formed each in a specific number per unit area on the exposed core part of the tapered part and on the fiber surface other than the exposed core part.
- alkali-insoluble inorganic fine particles to be contained in the core examples include titanium oxide, zirconium oxide, zinc oxide, lithopone and barium sulfate, among which titanium oxide is preferred because of good, uniform dispersibility in polyester and higher reflectivity than polyester.
- titanium oxide is preferred because of good, uniform dispersibility in polyester and higher reflectivity than polyester.
- thickener to be added to the hydrolyzing agent used examples include natural polymeric thickeners such as starch, natural gum and sodium alginate and synthetic polymeric thickeners such as polyvinyl alcohol, sodium polyacrylate and styrene-maleic acid copolymer.
- Other thickeners are also usable without limitation insofar as they do not hydrolyze the composite fiber and can be homogeneously dispersed in the hydrolyzing agent solution used.
- Alkali treatment of napped fabrics with raised fibers comprising the tapered fibers of the present invention is also conducted in the same manner as for the fiber itself.
- padding which comprises for example passing a napped fabric, while keeping its napped face down, on a hydrolyzing solution in such a manner that only the napped part of the fabric is immersed in the solution and then squeezing the fabric through a mangle to remove excess hydrolyzing agent solution.
- the mangle squeezing ratio is preferably 30 to 70% by weight of remaining hydrolyzing agent solution based on the weight of the napped fabric, more preferably 40 to 60% by weight on the same bases.
- the hydrolyzing agent solution preferably has a viscosity of 150 to 1,000 cps and an alkali concentration of 1 to 30% by weight where sodium hydroxide is used.
- wet heat 80 to 180°C for 5 to 120 minutes.
- a viscous solution containing a hydrolyzing agent to the ends of the raised fibers of a napped fabric and comprising sheath-core composite polyester fibers, followed by heat treatment, permits the ends of the fibers to be tapered and, at the same time, forms two types of recesses having specific shapes in specific densities on the exposed core part of the tapered ends and on the fiber surface other than the exposed core part, respectively.
- the resulting fabric has a soft hand and further, when dyed, has the following excellent features.
- Each of the yarns was knitted into a double raschel knit (pile density: 18,000 pieces/cm2) with a ground yarn of conventional polyester yarn (75 denier/24 filaments).
- the knitted fabric was sheared into a cut pile fabric having a pile length of 3 mm and then dry pre-heatset at 180°C through a pin tenter.
- aqueous sodium hydroxide solution containing 3% by weight of sodium alginate as a thickener (concentration: 28% by weight; viscosity measured with a type-B viscometer at 20°C, 65% RH: 12,000 cps) was applied through a rotary screen to the nap part of each of the fabrics and then the fabrics were wet heat treated with super-heated steam in an H.T. steamer at 150°C for 5 to 15 minutes.
- the thus treated knits were dyed with two types, blue and beige, of disperse dyed in a Obermeyer dyeing machine.
- the ends of the dyed raised fibers were observed under an optical microscope to show that 25 to 30% of the raised length was tapered to the tip.
- the exposed core part at the tapered ends and the surface other than the exposed core part were observed in a scanning electron microscope, to show recesses with diameters and densities as shown in Table 1.
- Example 1 was repeated several times except that the inorganic fine particles contained in the core and those in the sheath were changed as shown in Tables 2 and 3, to prepare a series of double raschel knitted fabrics.
- the nap part of each of the knitted fabrics were treated with an aqueous sodium hydroxide solution containing a thickener, under different treating conditions.
- the treated fabric were dyed in blue and beige, and evaluated. The results are shown in Tables 2 and 3.
- the pile fabric of Comparative Example 1 had a small amount of very fine recesses on the exposed core part of the raised fibers so that it was difficult to soil.
- the fabric however showed dark fading, white appearance and whitened seams, particularly when dyed in beige.
- the pile fabrics of Comparative Examples 3 and 4 had almost no recesses on the surface of the sheath part of raised fibers so that it had poor appearance and showed marked white appearance and whitened seams.
- the pile fabrics of Comparative Examples 6 and 7 had recesses on the exposed core part.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Multicomponent Fibers (AREA)
- Woven Fabrics (AREA)
Abstract
Description
- The present invention relates to a tapered fiber that can constitute napped fabrics having good hand with HARI (anti-drape stiffness) and KOSHI (stiffness) and excellent color developing property and depth of color and causing, after being sewn, no white appearance along seams. More specifically, the present invention relates to polyester fiber-based napped fabrics usable in a wide variety of uses such as interior fabrics, e.g. car seats and carpets, artificial suedes and clothing and to tapered fibers constituting the nap of such fabrics.
- Napped fabrics such as standard cut-pile, moquette, double-raschel, velour and velvet have various appearances and hands and have been widely used as interior fabrics including car interior fabrics such as car seat covers, household interior fabrics such as carpets and flocked fabrics, artificial suedes and wearing apparel.
- Fibers comprising polyester, in particular polyethylene terephthalate, are widely used for clothing, industrial purposes and interior fabrics.
- In recent years in particular, polyethylene terephthalate fibers are penetrating rapidly into the field of car interior napped fabrics, utilizing its excellent light-fastness. However, napped fabrics comprising polyethylene terephthalate fiber have stiffer tactility and are significantly poorer in appearance such as luster and brightness, than those made of fibers of acrylic, nylon, rayon, silk, wool and the like. Besides, when these polyester fiber-based napped fabrics are dyed, they hardly give mild luster like that of napped fabrics comprising natural fibers such as wool and silk because of the surface of the fibers being smooth, and their hand lacks natural feeling, and it is difficult to give them deep color.
- To make deep the color of dyed napped fabrics, it is generally recommended to use a super bright type of polyester fiber, containing no inorganic fine particles. However, although napped fabrics using this type of fiber for their nap have improved color development, they give a shining appearance depending on the angle seen and lack high-quality feeling. To eliminate this shining appearance, polyester fibers of semi-dull type containing a small amount of titanium oxide are being used for naps, which, however, deteriorates color developing property of the napped fabrics and make them look whitened when dyed in light colors. Such napped fabrics cannot produce high-quality feeling.
- Furthermore, polyester fiber-based napped fabrics give, when dyed, different color shades depending on the angle seen, thereby creating variation in luster and depth of color. As a result they often show partly blackish and partly whitened as if covered with dust. Such napped fabrics further have a drawback that, when sewn, their raised fibers fall down along the seam and look whitish, i.e. what is known as "whitened seam", which impairs the high-quality feeling to a large extent. This is attributable to the fabrics having large surface reflection caused by large refractivity and smooth surface of the polyester fibers used and also to reduced color developing property due to large difference between the reflectivities of the side surface and cross-section of the polyester fibers.
- Various proposals have been made to solve the above problems, i.e. to improve the color developing property of polyester fiber to be used for raised fibers of napped fabrics.
- For examples, Japanese Patent Application Laid-open No. 268855/1987 discloses a sheath-core composite fiber comprising a core of polyester and a sheath of a cationically dyeable polyester. In this fiber, the sheath is dyed in a deeper color compared with the core, so that the side surface of the fibers become not so distinguishable even when exposed on the surface of the napped fabric containing them. However, the sheath, having been dyed with a cation dye to produce deep color, has poor lightfastness and hence napped fabrics utilizing such fibers are often unusable depending on the use.
- Japanese Patent Application Laid-open No. 124858/1991 disclose a pile fabric comprising sheath-core composite polyester fibers with their core containing a larger amount of titanium oxide compared with their sheath so that the mirror reflection of the fiber side surface is reduced and does not differ so much from that of the fiber cross-section. Japanese Patent Application Laid-open No. 306646/1989 discloses a pile fabric comprising sheath-core composite fibers and having good color development and, at the same time, no shining appearance by adding an inorganic fine powder having high refractivity to the sheath only. However, incorporation of an inorganic fine powder having high refractivity such as titanium oxide to the core and/or sheath of a sheath-core composite fiber permits the surface reflectivity the fiber cross-section to become close to that of the fiber side surface, thereby being unable to solving the problems of white appearance, whitened seams and the like due to severe falling down of raised fibers, of the napped fabrics comprising such fibers as their naps.
- It is known that roughening of the side surface of polyester fibers reduces the surface reflectivity because light incident on the roughened surface repeats zigzag reflections in the recesses and is eventually absorbed into the fibers. Japanese Patent Application Laid-open No. 214412/1992 discloses a napped fabric, utilizing the above technique, comprising raised fibers of sheath-core composite polyester fibers having roughened side surface to decrease the reflectivity of the fiber surface and being tapered to the ends to cause irregular reflection of light there, thereby increasing the surface reflectivity. With such polyester fibers, the difference between the surface reflectivities of the fiber cross-section and the fiber side surface becomes small and hence napped fabrics having a nap of such fibers no longer suffer from dark fading or white appearance. However, the problem of uneven color occurring with extreme falling down of raised fibers, such as whitened seams, cannot be solved completely with the napped fabrics with a nap comprising such fibers.
- Aiming at high-quality napped fabrics with nap of wool, the present inventors have made an intensive study on napped fabrics with raised fibers comprising polyester fibers and found a napped fabric having excellent color developing property and mild luster with no uneven color or luster, such as dark fading and white appearance and whitened seams due to fiber falling down, and having good hand with KOSHI.
- The present invention provides a tapered fiber comprising a sheath-core composite polyester fiber with at least one end thereof tapered along its tip to expose its core outwardly, said exposed core having on the surface thereof 0.1 to 20 pieces/100 µm² of recesses having a diameter of 0.5 to 5 µm, the surface other than said exposed core part of said fiber having 20 to 1,000 pieces/100 µm² of recesses having a diameter of 0.2 to 0.7 µm.
- The present invention further provides a napped fabric with raised fibers comprising sheath-core composite polyester fibers, the core of each of said fibers being exposed at the end and said fibers being tapered to the tips thereof in a length of at least 20% of their whole raised length.
- The present invention still further provides a process for producing the above napped fabric, which comprises subjecting to alkali etching treatment a napped fabric with raised fibers comprising sheath-core composite polyester fibers, said sheath containing 0.5 to 5% by weight of alkali-soluble inorganic fine particles such as colloidal silica and said core containing 0.3 to 15% by weight of alkali-insoluble inorganic fine particles such as titanium oxide.
- A more complete appreciation of the invention and many of the attendant advantages thereof will be readily obtained as the same become better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein:
- FIGURE 1 is a photograph showing the surface of the exposed-core part at the end of the tapered fiber of the present invention, and
- FIGURE 2 is a photograph showing the side surface of the sheath part of the tapered fiber of the present invention.
-
- The sheath-core composite polyester fiber (hereinafter referred to as "composite fiber") of the present invention is a composite fiber having single- or multi-core sheath-core cross-section. It is desirable that the fiber comprise for its core and sheath two different polyester components being melt composite spinnable and compatible with each other. It is also desirable that the fiber be a single-core composite fiber, which may either be concentric or eccentric. The cross-sectional shapes of the composite fiber and its core, which may be the same or different, may either be circular or irregular. The ratio by weight between the core and the sheath of the composite fiber is preferably in a range of 20/80 to 70/30, more preferably in a range of 30/70 to 60/40.
- Examples of the polyester constituting the core or sheath of the composite fiber are polyethylene terephthalate (PET), polybutylene terephthalate (PBT) and polynaphthalene terephthalate (PEN). The polyester may be copolymerized with a small amount of a copolymerizable component within a limit not to impair the crystallinity of the polyester, such as diethylene glycol, neopentyl glycol, cyclohexane dimethanol, cyclohexanedicarboxylic acid, isophthalic acid, sulfoisophthalic acid or its sodium salt or polyalkylene glycol. The polyester may incorporate additives such as a luster improving agent, a flame retardant, a dyeability improving agent and an ultraviolet absorber.
- There is no particular limitation to the degree of polymerization of the polyester used and it is preferably in the range used for ordinary polyester fiber, e.g. an intrinsic viscosity of about 0.6 to 0.8 dl/g.
- In order to make the end of the composite fiber be tapered by alkali etching treatment, it is desirable that the polyester used for the sheath has a smaller alkali dissolution rate than that of the polyester used for the core. However, it sometimes happens that, depending on the types and amounts of the inorganic powders added, the optimum dissolution rate relationship reverses. In any case, the combination of polyesters should be properly selected such that the end of the resulting composite fiber is tapered by alkali etching. If, however, the difference between the alkali dissolution rates of the sheath polyester and the core polyester is too large, alkali etching of the resulting fiber sometimes causes selective decomposition, so that the treated fiber becomes too thin, whereby the finished napped fabric has weak KOSHI, the fiber being neatly tapered though.
- The alkali dissolution rate herein is determined as follows. A yarn sample having the same fineness and number of filaments as the composite fiber is prepared from the polyester constituting the sheath or the core (if the sheath or core contains additives, the polyester sample for determination of the weight reduction percentage should also contain them in the same amounts). The yarn sample is treated with a 40 g/l aqueous sodium hydroxide solution at 96°C for 40 minutes. The weight reduction percentage is obtained and employed as the alkali dissolution rate of the polyester constituting the sheath or the core.
- The key feature of the present invention lies in the presence of recesses having a size range on the surface (surface of the sheath) other than the exposed core part of the composite fiber in a specific number per unit area and another group of recesses having a size range different from the above on the surface of the exposed core part of the tapered end in a specific number per unit area.
- That is, there are formed on the surface (sheath surface) other than the exposed core part of the composite fiber recesses having a diameter of 0.2 to 0.7 µm in a number per unit area of 20 to 1,000 pieces/100 µm² and on the surface of the exposed core part of the tapered end those having a diameter of 0.5 to 5 µm in a number per unit area of 0.1 to 20 pieces/100 µm².
- At first, the recesses formed on the surface (sheath surface) other than the exposed core part of the composite fiber are explained.
- The diameter of a recess herein means the planar distance between the bottom point of a recess and that of another recess adjacent to the recess and present on the same circumference perpendicular to the fiber axis. This distance and the number of recesses per unit area can be measured with a scanning electron microscope.
- While recesses having a diameter in the above range are formed on the surface (sheath surface) other than the tapered, exposed core part of the fiber, it is not necessary that they be formed on the whole surface other than the exposed core part. The object of the present invention can be achieved by such recesses being present at least on the surface of the tapered part other than the exposed core. It is, however, desirable for obtaining still deeper color and milder luster that the recesses be present on the entire surface other than the exposed core part of the fiber.
- If there are present recesses having a diameter as defined above of less than 0.2 µm or the number of the recesses having a diameter of 0.2 to 0.7 µm is less than 20 pieces/100 µm², the mirror reflectivity of the fiber surface will decrease only to a small extent, thereby producing little effect of improving shining or clamminess of luster. If the diameter exceeds 0.7 µm, there will be created diffusion of light so that the mirror reflectivity of the fiber surface does increase. Further if the number of the recesses having a diameter of 0.2 to 0.7 µm exceeds 1,000 pieces/100 µm², the roughened structure of the fiber surface will become too minute and be readily destroyed caused by wear or the like so that the surface has mirror-like luster and shows white appearance.
- To decrease the mirror reflectivity for light of the fiber surface (sheath surface) and promote absorption of light into the fiber, it is desirable that there be present recesses having a diameter in a range of 0.4 to 0.6 µm in a number per unit area of in a range of 50 to 500 pieces/100 µm².
- Next, the recesses formed on the exposed core part of the tapered end of the composite fiber is explained. The definition of the diameter of the recesses formed on the exposed core part is the same as that for the above recesses on the fiber surface (sheath surface) and the diameter and number of the recesses are measurable with a scanning electron microscope.
- If there are present recesses having a diameter as defined above of less than 0.5 µm or the number of the recesses having a diameter of 0.5 to 5 µm is less than 0.1 pieces/100 µm², napped fabrics utilizing such fiber will tend to produce dark fading. If the diameter exceeds 5 µm, the resulting napped fabrics will have poor hand. Likewise, if the number of the recesses having a diameter of 0.5 to 5 µm exceeds 20 pieces/100 µm², the napped fabrics will also have poor hand.
- To decrease absorption of light of the exposed core part and through the fiber cross-section, it is desirable that there be present recesses having a diameter in a range of 0.7 to 2 µm in a number per unit area of in a range of 0.1 to 10 pieces/100 µm²
- According to the present invention, use of tapered fibers having a group of recesses on the exposed core part of the tapered ends and another group of recesses having a different size range from that of the above first group recesses, for the nap of a napped fabric can render the fabric free from whitened seams, as well as from dark fading, white appearance and the like. The term "napped fabric" herein means fabrics with a soft fuzzy fibrous surface comprising a multiplicity of raised fibers and includes woven and knit fabrics of cut-pile and fabrics of moquette, double raschel, velour and velvet, thus being not limited to those obtained by brushing against a rough surface. With the fabric of the present invention, light incident on the surface other than the exposed core part of the nap fibers is reflected by minute recesses formed thereon and interfered with the reflected light. Besides, successively repeated reflection and absorption occurring around the peripheries of the recesses decreases the amount of reflected light. As a result, the mirror reflectivity of the fiber surface (sheath surface) decreases. On the other hand, since the recesses formed on the exposed core part of the fiber ends have larger diameter and are in smaller number compared with the recesses formed on the fiber surface (sheath surface), light incident on the exposed core part is diffused by the recesses there, whereby the light absorptivity of the exposed core part becomes small. This fact, together with the exposed core part being tapered to the tips, renders the side surface of the raised fibers undistinguishable from their cross-section and, thus, the problems of black fading, white appearance, as well as whitened seams as occurring upon extreme falling down of raised fibers, inherent to conventional napped fabrics with raised fibers of polyester fibers have been solved.
- It is desirable that the tapered part of raised fibers have a length from the tip of at least 20% of the whole raised length from the tip and, to prevent their falling down, preferably at least 50% of the whole raised length. The term "tapered part" herein means part of a raised fiber the diameter of which is substantially smaller than, more concretely not more than 90% of, that of the root part of the fiber.
- It is desirable that the napped fabric of the present invention have raised fibers with a raised length of not more than 10 mm, in particular not more than 5 mm. As the length increases beyond 10 mm, the effect produced by the present invention gradually decreases. The number per unit area of the raised fiber is preferably 7 x 10³ to 8 x 10⁶ pieces/cm², more preferably 10⁴ to 2 x 10⁵ pieces/cm². Too high a number per unit area renders it difficult to achieve uniform tapering by alkali etching to be described later herein. On the other hand, too low a number per unit area hardly produces suitably tapered shape.
- If the root part, which is not tapered, of tapered fibers constituting the nap becomes too thin, the fibers will readily fall down and the resulting fabric will have weak KOSHI. The fineness of the root part is therefore preferably in a range of 2 to 6 deniers. With conventional polyester fiber napped fabrics, a fiber fineness exceeding 3 deniers generally causes itchy, unpleasant feeling. According to the present invention, the problem of itchy feeling is also solved, whereby thicker fibers can be used for nap, which in turn prevents falling-down phenomenon.
- It is not necessary, in the napped fabric of the present invention, that all of the fibers constituting the nap be the above-described tapered fibers, and it is sufficient that part, for example at least 30%, preferably at least 50% of the constituting fibers be the tapered fibers.
- An example of available processes for obtaining the tapered fiber, having on its end part recesses with specific shape, of the present invention is described below.
- Sheath-core composite polyester fibers with the core containing 0.3 to 15% by weight of alkali-insoluble inorganic fine particles and the sheath containing 0.5 to 5% by weight of alkali-soluble inorganic fine particles is treated with alkali. Then, at least one end of each of the raised fibers is tapered and two groups of recesses having specific, different sizes are formed each in a specific number per unit area on the exposed core part of the tapered part and on the fiber surface other than the exposed core part.
- Examples of the alkali-insoluble inorganic fine particles to be contained in the core are titanium oxide, zirconium oxide, zinc oxide, lithopone and barium sulfate, among which titanium oxide is preferred because of good, uniform dispersibility in polyester and higher reflectivity than polyester. With the content being less than 0.3% by weight, the number of recesses formed on the exposed core part of the tapered fiber will become small so that the desired roughened surface structure cannot be obtained. On the other hand, if the content exceeds 15% by weight, there will occur, during spinning, frequent clogging of spinneret holes and filament breakage. There are no specific limitation to the average diameter of the alkali-insoluble inorganic fine particles used, but it is preferably not more than 1.0 µm, more preferably not more than 0.5 µm in order to form on the exposed core part recesses having a diameter of 0.5 to 5 µm in a number per unit area of 0.1 to 20 pieces/100 µm².
- Examples of the alkali-soluble inorganic fine particles to be contained in the sheath are silica, calcium carbonate and kaolin, among which colloidal silica is preferred because of its reflectivity being smaller than polyester. If such fine particles are contained in an amount less than 0.5% by weight, the number of recesses formed on the surface other than the exposed core part of the resulting tapered fiber will become small so that the effect of the present invention becomes difficult to produce. On the other hand, if the content exceeds 5% by weight, there will tend to generate aggregates of particles, which impair stability of fiber formation operation, the number of recesses increasing though. There is no particular limitation to the average particle diameter of the alkali-soluble inorganic fine particles, but it is preferably not more than 0.2 µm, more preferably not more than 0.1 µm, in order to form on the surface other than the exposed core part of the tapered fiber recesses having a diameter of 0.2 to 0.7 µm in a number per unit area of 20 to 1,000 pieces/100 µm². The diameter of an inorganic particle is measured by the known optical method or laser scattering method.
- The alkali treatment used in the present invention is conducted under the usual alkali etching conditions, preferably with an aqueous hydrolyzing agent solution containing a thickener, which assures uniform tapering. Alkaline compounds such as sodium hydroxide and potassium hydroxide are usable hydrolyzing agents. As occasions demand, hydrolysis accelerating agents such as laurylbenzylammonium chloride and cetyltrimethylammonium chloride may be used in combination.
- Examples of the thickener to be added to the hydrolyzing agent used are natural polymeric thickeners such as starch, natural gum and sodium alginate and synthetic polymeric thickeners such as polyvinyl alcohol, sodium polyacrylate and styrene-maleic acid copolymer. Other thickeners are also usable without limitation insofar as they do not hydrolyze the composite fiber and can be homogeneously dispersed in the hydrolyzing agent solution used.
- It is desirable that the hydrolyzing agent solution containing a thickener have a viscosity in a range of 100 to 2,000 cps under room temperature condition. This range suppresses too rapid hydrolysis and unfavorable capillarity effect of the hydrolyzing solution and realizes the desired, good tapered shape.
- Alkali treatment of napped fabrics with raised fibers comprising the tapered fibers of the present invention is also conducted in the same manner as for the fiber itself.
- At first, napped fabrics with raised fibers comprising the sheath-core composite polyester fibers are formed from any of knit pile, woven pile, moquette, double raschel, velour and velvet, or by tufting, electrical flocking or like processes. Then, a hydrolyzing agent solution containing a thickener is applied to the end part of the raised fibers of the obtained napped fabric by padding, gravure coating, kiss-coating, knife-coating, printing, rotary screen process. It is preferred to employ, among the above processes, padding which comprises for example passing a napped fabric, while keeping its napped face down, on a hydrolyzing solution in such a manner that only the napped part of the fabric is immersed in the solution and then squeezing the fabric through a mangle to remove excess hydrolyzing agent solution. This process enables the raised fibers to form recesses with specific shape down to the root part of the fibers. In this case the mangle squeezing ratio is preferably 30 to 70% by weight of remaining hydrolyzing agent solution based on the weight of the napped fabric, more preferably 40 to 60% by weight on the same bases. Upon padding this way, the hydrolyzing agent solution preferably has a viscosity of 150 to 1,000 cps and an alkali concentration of 1 to 30% by weight where sodium hydroxide is used.
- The napped fabric with the raised fibers to which a hydrolyzing agent solution has been applied by any one of the above processes is then heated by dry heating such as with hot air or infrared heater or wet heating such as steaming. Where dry heating is employed, there may often occur too early drying up of the hydrolyzing agent solution, thereby rendering it difficult to produce sufficient etching effect. To avoid this, it is desirable to select an appropriate heating system, temperature, time and the like depending on the composition and type of the fiber constituting the nap, type of the hydrolyzing agent solution and other conditions.
- It is generally preferred to wet heat at 80 to 180°C for 5 to 120 minutes.
- According to the present invention, application of a viscous solution containing a hydrolyzing agent to the ends of the raised fibers of a napped fabric and comprising sheath-core composite polyester fibers, followed by heat treatment, permits the ends of the fibers to be tapered and, at the same time, forms two types of recesses having specific shapes in specific densities on the exposed core part of the tapered ends and on the fiber surface other than the exposed core part, respectively. The resulting fabric has a soft hand and further, when dyed, has the following excellent features. Light incident on the fiber surface (sheath surface) other than the exposed core part is reflected outwardly only to a small extent due to minute recesses formed thereon, whereby the mirror reflectivity of the surface (sheath surface) becomes smaller. On the other hand, light incident on the exposed core part is diffused due to the presence of recesses formed thereon, whereby the light absorptivity of the exposed core part becomes small. The above phenomena, together with the fact that the exposed core part is tapered, render the side surface of the fibers constituting the nap undistinguishable from their cross-section. As a result, there can be solved the problems of dark fading and white appearance resulting from luster difference and color difference, in particular whitened seams due to extreme falling down of raised fibers, which have been inherent to conventional napped fabric with raised fibers comprising conventional polyester fibers.
- Other features of the invention will become apparent in the course of the following description of exemplary embodiments which are given for illustration of the invention and are not intended to be limiting thereof. In the Examples and Comparative Examples that follow, the intrinsic viscosity of polyester is determined by viscosity measurement conducted at 30°C on a sample dissolved in a 1:1 by weight mixed solvent of phenol/tetrachloroethane. To measure the diameter and number of recesses, electron microphotographs with a magnification of at least 5,000 are taken on 3 fiber samples and 2 parts of each photograph are subjected to measurement. For the number per unit area, an average of the results of 3 x 2 =n measurements is taken.
- A series of sheath-core composite filament yarns with the core comprising a polyethylene terephthalate having an intrinsic viscosity of 0.65 dl/g or polybutylene terephthalate having an intrinsic viscosity of 0.80 dl/g (Sample No. 5) and containing titanium oxide particles having an average particle diameter of 0.2 µm or 0.05 µm in amounts as shown in Table 1 and the sheath comprising another polyethylene terephthalate having an intrinsic viscosity of 0.68 dl/g and containing colloidal silica having an average particle diameter of 0.03 µm in amounts as shown in Table 1, the ratio by weight between the core and the sheath being 1:2 were spun and taken up at a speed of 1,000 m/min. The yarns were then drawn at 75°C in a ratio of 3.2 and heat treated at 130°C under tension, to yield drawn concentric sheath-core composite filament yarns of 200 denier/72 filaments.
- Each of the yarns was knitted into a double raschel knit (pile density: 18,000 pieces/cm²) with a ground yarn of conventional polyester yarn (75 denier/24 filaments). The knitted fabric was sheared into a cut pile fabric having a pile length of 3 mm and then dry pre-heatset at 180°C through a pin tenter.
- An aqueous sodium hydroxide solution containing 3% by weight of sodium alginate as a thickener (concentration: 28% by weight; viscosity measured with a type-B viscometer at 20°C, 65% RH: 12,000 cps) was applied through a rotary screen to the nap part of each of the fabrics and then the fabrics were wet heat treated with super-heated steam in an H.T. steamer at 150°C for 5 to 15 minutes.
- The thus treated knits were dyed with two types, blue and beige, of disperse dyed in a Obermeyer dyeing machine. The ends of the dyed raised fibers were observed under an optical microscope to show that 25 to 30% of the raised length was tapered to the tip. The exposed core part at the tapered ends and the surface other than the exposed core part were observed in a scanning electron microscope, to show recesses with diameters and densities as shown in Table 1.
- In the above table, the results of evaluation are expressed according to the following ratings.
- Ⓞ : soft hand, smooth touch
○ : smooth touch
△ : a little itchy
X : itchy and coarse - Ⓞ : moderate luster and calm appearance
○ : mild luster
△ : straw-colored
X : shining - Ⓞ : no dark fading at all
○ : difficult to recognize dark fading
△ : looks dark when viewed under direct sunlight
X : dark fading appears - Ⓞ : no white appearance at all
○ : difficult to recognize white appearance even when folded
△ : white appearance shows when folded and viewed from a low angle
X : overall white appearance - Ⓞ : no whitened seam at all
○ : difficult to recognize whitened seam
△ : whitened seam does not show when dyed in blue but shows when dyed beige
X : whitened seam shows both with blue and beige. - The pile fabrics of sample Nos. 2 through 6, which had raised fibers tapered smoothly to their tips, had good soft touch and, nevertheless, had HARI and KOSHI and developed good deep color. These fabrics showed little dark fading, white appearance or whitened seams. The pile fabric of sample No. 1, having too small number of recesses formed on the exposed core part, showed whitened seams both for blue and beige.
- Example 1 was repeated several times except that the inorganic fine particles contained in the core and those in the sheath were changed as shown in Tables 2 and 3, to prepare a series of double raschel knitted fabrics. The nap part of each of the knitted fabrics were treated with an aqueous sodium hydroxide solution containing a thickener, under different treating conditions. The treated fabric were dyed in blue and beige, and evaluated. The results are shown in Tables 2 and 3.
-
- The evaluation ratings are same as before.
- The pile fabric of Comparative Example 1 had a small amount of very fine recesses on the exposed core part of the raised fibers so that it was difficult to soil. The fabric however showed dark fading, white appearance and whitened seams, particularly when dyed in beige.
- The pile fabric of Comparative Example 2 had a small amount of relatively large recesses on the surface of the sheath part of the raised fibers so that it developed, when dyed, no deep color and had poor appearance. The fabric also showed marked whitened seams both for blue and beige.
- The pile fabrics of Comparative Examples 3 and 4 had almost no recesses on the surface of the sheath part of raised fibers so that it had poor appearance and showed marked white appearance and whitened seams.
- The pile fabrics of Comparative Example 5 had relatively large recesses on the surface of the sheath part so that it had a large mirror reflectivity and very poor appearance.
- The pile fabrics of Comparative Examples 6 and 7 had recesses on the exposed core part. The diameter and number of recesses, however, were both out of the range specified in the present invention. Such recesses cannot eliminate dark fading, white appearance or whitened seams.
- The pile fabric of Comparative Example 8 had two types of recesses on the exposed core part and sheath part respectively, but their diameters and densities were just reverse of those of the fabrics obtained in Example 1. The fabric had poor hand and produced no effect of improving dark fading, white appearance or whitened seams.
- Obviously, numerous modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.
Claims (10)
- A tapered fiber comprising a sheath-core composite polyester fiber with at least one end thereof tapered along its tip to expose its core outwardly, said exposed core part having on the surface thereof 0.1 to 20 pieces/100 µm² of recesses having a diameter of 0.5 to 5 µm, the surface other than said exposed core part of said fiber having 20 to 1,000 pieces/100 µm² of recesses having a diameter of 0.2 to 0.7 µm.
- The tapered fiber according to Claim 1, wherein the ratio by weight between the core and the sheath of said fiber other than the tapered part is 20/80 to 70/30.
- The tapered fiber according to Claim 1, having a fineness of 2 to 6 deniers.
- A process for producing tapered fibers which comprises subjecting sheath-core composite polyester fibers with the core containing 0.3 to 15% by weight of alkali-insoluble inorganic fine particles and the sheath containing 0.5 to 5% by weight of alkali-soluble inorganic fine particles, to permit said fibers to be tapered to their tips.
- A napped fabric with raised fibers comprising the tapered fibers according to Claim 1, each of the cores of said tapered fibers being exposed outwardly at the end part of said tapered fibers.
- The napped fabric according to Claim 5, wherein said raised fibers are tapered to the tips thereof in a length of at least 20% of the whole raised length thereof.
- The napped fabric according to Claim 5, wherein said raised fibers are tapered to the tips thereof in a length of 20 to 50% of the whole raised length thereof.
- The napped fabric according to Claim 5, wherein the raised length of said raised fibers is not more than 10 mm.
- A process for producing napped fabrics, which comprises subjecting to alkali etching treatment a napped fabric with raised fibers comprising sheath-core composite polyester fibers, said core containing 0.3 to 15% by weight of alkali-insoluble inorganic fine particles and said sheath containing 0.5 to 5% by weight of alkali-soluble inorganic fine particles, to permit the end part of said raised fibers to be tapered.
- The process for producing napped fabrics according to Claim 9, wherein said alkali etching treatment is conducted by applying an aqueous solution of a hydrolyzing agent containing a thickener to said raised fibers and heat treating said fabric at a temperature of 80 to 180°C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27434492 | 1992-10-13 | ||
JP274344/92 | 1992-10-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0592928A1 true EP0592928A1 (en) | 1994-04-20 |
EP0592928B1 EP0592928B1 (en) | 1998-01-28 |
Family
ID=17540352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93116098A Expired - Lifetime EP0592928B1 (en) | 1992-10-13 | 1993-10-05 | Tapered fiber and napped fabric utilizing the same |
Country Status (6)
Country | Link |
---|---|
US (1) | US5407735A (en) |
EP (1) | EP0592928B1 (en) |
KR (1) | KR960011612B1 (en) |
DE (1) | DE69316700T2 (en) |
ES (1) | ES2111685T3 (en) |
TW (1) | TW263536B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0758027A1 (en) * | 1995-02-28 | 1997-02-12 | Teijin Limited | Polyester filament yarn, process for the production thereof, woven and knitted fabrics thereof, and process for the production thereof |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2870706B2 (en) * | 1990-03-02 | 1999-03-17 | 株式会社クラレ | Napped fabric and method for producing the same |
US5849410A (en) * | 1996-12-12 | 1998-12-15 | E. I. Du Pont De Nemours And Company | Coextruded monofilaments |
US6605332B2 (en) * | 1997-07-29 | 2003-08-12 | 3M Innovative Properties Company | Unitary polymer substrate having napped surface of frayed end microfibers |
US6946182B1 (en) * | 1999-07-16 | 2005-09-20 | Allgeuer Thomas T | Fringed surface structures obtainable in a compression molding process |
US6872438B1 (en) * | 2000-07-17 | 2005-03-29 | Advanced Design Concept Gmbh | Profile or molding having a fringed surface structure |
AU2002311283A1 (en) * | 2002-06-27 | 2004-01-19 | Toyo Boseki Kabushiki Kaisha | High-function brush |
US20130255324A1 (en) * | 2012-03-30 | 2013-10-03 | Deckers Outdoor Corporation | Density enhancement method for wool pile fabric |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0134141A2 (en) * | 1983-08-12 | 1985-03-13 | Kanebo, Ltd. | Pile articles and their production |
JPH02200814A (en) * | 1989-01-30 | 1990-08-09 | Toray Ind Inc | Improved polyester fiber |
JPH02264068A (en) * | 1989-02-02 | 1990-10-26 | Kuraray Co Ltd | Raised woven or knit fabric and preparation thereof |
EP0450300A1 (en) * | 1990-03-02 | 1991-10-09 | Kuraray Co., Ltd. | Napped fabric and process for its production |
JPH0473242A (en) * | 1990-07-06 | 1992-03-09 | Kuraray Co Ltd | Raised woven or knit fabric and production thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3228254C2 (en) * | 1981-01-15 | 1989-06-08 | Kanebo Ltd | Process for the production of an artificial fur with a three-dimensionally varied pile |
JPS62268855A (en) * | 1986-05-12 | 1987-11-21 | カネボウ株式会社 | Car interior material |
JPH01306646A (en) * | 1988-06-02 | 1989-12-11 | Toray Ind Inc | Pile cloth |
JPH03124858A (en) * | 1989-10-09 | 1991-05-28 | Asahi Chem Ind Co Ltd | Pilelike fabric |
-
1993
- 1993-10-05 TW TW082108200A patent/TW263536B/zh active
- 1993-10-05 DE DE69316700T patent/DE69316700T2/en not_active Expired - Fee Related
- 1993-10-05 EP EP93116098A patent/EP0592928B1/en not_active Expired - Lifetime
- 1993-10-05 ES ES93116098T patent/ES2111685T3/en not_active Expired - Lifetime
- 1993-10-13 US US08/135,333 patent/US5407735A/en not_active Expired - Lifetime
- 1993-10-13 KR KR1019930021169A patent/KR960011612B1/en not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0134141A2 (en) * | 1983-08-12 | 1985-03-13 | Kanebo, Ltd. | Pile articles and their production |
JPH02200814A (en) * | 1989-01-30 | 1990-08-09 | Toray Ind Inc | Improved polyester fiber |
JPH02264068A (en) * | 1989-02-02 | 1990-10-26 | Kuraray Co Ltd | Raised woven or knit fabric and preparation thereof |
EP0450300A1 (en) * | 1990-03-02 | 1991-10-09 | Kuraray Co., Ltd. | Napped fabric and process for its production |
JPH04214412A (en) * | 1990-03-02 | 1992-08-05 | Kuraray Co Ltd | Napped cloth and production thereof |
JPH0473242A (en) * | 1990-07-06 | 1992-03-09 | Kuraray Co Ltd | Raised woven or knit fabric and production thereof |
Non-Patent Citations (3)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 14, no. 485 (C - 772) 23 October 1990 (1990-10-23) * |
PATENT ABSTRACTS OF JAPAN vol. 15, no. 17 (C - 796) 14 January 1991 (1991-01-14) * |
PATENT ABSTRACTS OF JAPAN vol. 16, no. 283 (C - 955) 24 June 1992 (1992-06-24) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0758027A1 (en) * | 1995-02-28 | 1997-02-12 | Teijin Limited | Polyester filament yarn, process for the production thereof, woven and knitted fabrics thereof, and process for the production thereof |
EP0758027A4 (en) * | 1995-02-28 | 1999-01-07 | Teijin Ltd | Polyester filament yarn, process for the production thereof, woven and knitted fabrics thereof, and process for the production thereof |
Also Published As
Publication number | Publication date |
---|---|
DE69316700T2 (en) | 1998-08-27 |
TW263536B (en) | 1995-11-21 |
KR960011612B1 (en) | 1996-08-24 |
DE69316700D1 (en) | 1998-03-05 |
EP0592928B1 (en) | 1998-01-28 |
US5407735A (en) | 1995-04-18 |
KR940010880A (en) | 1994-05-26 |
ES2111685T3 (en) | 1998-03-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20050202741A1 (en) | Woven or knit fabric and process for producing the same | |
EP0450300B1 (en) | Napped fabric and process for its production | |
JP2006307379A (en) | Woven or knitted fabric | |
WO2004029348A1 (en) | Multicolor fiber pile fabric and multicolor fiber pile fabric with concave-convex design | |
EP0592928B1 (en) | Tapered fiber and napped fabric utilizing the same | |
EP0134141B1 (en) | Pile articles and their production | |
US20070122585A1 (en) | Pile fabric and method for producing the same | |
JP3989883B2 (en) | Multicolored pile fabric with uneven pattern | |
JPH11222725A (en) | Polyester fiber | |
JPH08120575A (en) | Production of light and clear fabric | |
JP3966063B2 (en) | Wiping cloth | |
JP2824129B2 (en) | Knitted woolen fabric and method for producing the same | |
JP3401730B2 (en) | Tapered fiber, method for producing the same, and napped product comprising the same | |
JP2582149B2 (en) | Knitted woolen fabric and method for producing the same | |
JPH108345A (en) | Lightweight heat insulating fabric | |
JP3689994B2 (en) | Polyester composite fiber and method for producing the same | |
JP2001262434A (en) | Deeply dyeable polyester ultra-fine filament yarn and method of producing the same | |
JP3042947B2 (en) | Polyester loop fluff yarn | |
JP2702128B2 (en) | Pile yarn for napping fabric | |
JP2001164436A (en) | Polyester combined filament yarn and woven and knitted fabric using the same | |
JPH10212629A (en) | Mixed yarn having different denier and different shrinkage filaments | |
JPH0314941B2 (en) | ||
JPH10158953A (en) | Plush fabric | |
JPH05287613A (en) | Sheath-core conjugated fiber for multi-grooved fiber | |
JPH0559607A (en) | Fiber and its fabric excellent in cool feeling |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE ES FR GB IT |
|
17P | Request for examination filed |
Effective date: 19940804 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
17Q | First examination report despatched |
Effective date: 19970320 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE ES FR GB IT |
|
REF | Corresponds to: |
Ref document number: 69316700 Country of ref document: DE Date of ref document: 19980305 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2111685 Country of ref document: ES Kind code of ref document: T3 |
|
ITF | It: translation for a ep patent filed |
Owner name: MODIANO & ASSOCIATI S.R.L. |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20060928 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20061004 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20061031 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20061124 Year of fee payment: 14 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20071005 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080501 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20080630 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20061010 Year of fee payment: 14 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071005 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20071006 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071031 Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071006 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071005 |