EP0588182B1 - Elément composite pour isoler la température ou le son, son procédé de fabrication et l'utilisation - Google Patents
Elément composite pour isoler la température ou le son, son procédé de fabrication et l'utilisation Download PDFInfo
- Publication number
- EP0588182B1 EP0588182B1 EP93114133A EP93114133A EP0588182B1 EP 0588182 B1 EP0588182 B1 EP 0588182B1 EP 93114133 A EP93114133 A EP 93114133A EP 93114133 A EP93114133 A EP 93114133A EP 0588182 B1 EP0588182 B1 EP 0588182B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- powder
- foamed
- workpiece
- aluminium
- sound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000002131 composite material Substances 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000010276 construction Methods 0.000 claims abstract description 7
- 239000011148 porous material Substances 0.000 claims abstract description 5
- 239000004411 aluminium Substances 0.000 claims abstract 7
- 239000000843 powder Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 15
- 238000005187 foaming Methods 0.000 claims description 7
- -1 aluminium oxide compound Chemical class 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 3
- 238000005192 partition Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 27
- 210000004027 cell Anatomy 0.000 abstract description 15
- 239000004604 Blowing Agent Substances 0.000 abstract description 11
- 210000002421 cell wall Anatomy 0.000 abstract description 8
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 238000013016 damping Methods 0.000 abstract description 5
- 238000004064 recycling Methods 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 7
- 238000009413 insulation Methods 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910000048 titanium hydride Inorganic materials 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/162—Selection of materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1121—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers
- B22F3/1125—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers involving a foaming process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/002—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature
- B22F7/004—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature comprising at least one non-porous part
- B22F7/006—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature comprising at least one non-porous part the porous part being obtained by foaming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/105—Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
- B22F2003/1052—Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding assisted by energy absorption enhanced by the coating or powder
Definitions
- the invention relates to a thermally and acoustically insulating composite body in lightweight construction using a foam body and to a method for its production and its use.
- Such composite bodies are already known from DE-A-2 735 153, but are only acoustically effective. They have the task of forming the greatest possible resistance to the passage of sound waves from one side to the other of the component, which is referred to as "sound-absorbing".
- such composite bodies occasionally also have the task of damping the formation of sound waves on one side of the component, that is to say of performing a "sound-absorbing" function, for which purpose the composite body directly with the sound-emitting element, for example a body panel, by pressing or gluing and connecting clips.
- metal for example an aluminum alloy
- stabilizing particles for example aluminum oxide
- the foam components used primarily for sound insulation purposes mostly have plastics such as polyurethane (DE-OS 27 35 153).
- the cell walls represent more or less pliable cuticles.
- For special tasks it is also known to connect open-cell foam structures with those foam structures which are closed-cell or which are filled or impregnated with fillers. The manufacturing costs of such double structures are relatively high. This also applies to open-pore foam fleece (DE-PS 36 24 427).
- there are also problems with the disposal of constructions that are no longer usable such acoustically effective components are equipped.
- Thermally insulating laminate elements are also known (DE-A-38 21 468 and DE-U-92 03 734). These laminate elements are partly also acoustically effective. These components are each made up of several different layers of one or more materials, that is to say in a complicated manner. Because they are not self-supporting, you need additional stiffening, usually in the form of an aluminum support plate. With the variants, which are made of different materials, there is also the problem of recycling.
- the invention has for its object to improve the composite body of the type mentioned in such a way that with good acoustic effectiveness it also has good thermal insulation properties, is easy to manufacture, has lightweight construction features and offers advantages over other materials in disposal.
- the foam body is designed in a special way.
- the foam body is formed from a workpiece which has a compacted mixture of powdered aluminum or a powdered aluminum alloy on the one hand and powdered blowing agent or blowing agent on the other hand and, if required, powdered aluminum oxide compounds.
- the workpiece can For example, be prepared by the method described in DE-PS 40 18 360 and it has been shown that the use of that method, ie the circumvention of the method described in US Pat. No. 4,713,277, is acoustically more effective in producing the material Leads components.
- This compacted workpiece is placed, for example, in a mold, the cavity walls of which determine the outer contours of the finished foam body.
- the shape can be made from such that the top is open.
- the aluminum powder is melted by heating and the blowing gas or blowing gas is released when the blowing agent or blowing agent decomposes, which transforms the aluminum melt into a foam structure with preferably essentially closed cells.
- the open design With the open design, the possibility of free foaming is given.
- foamed workpieces By subsequent upsetting free, without thickness limitation, foamed workpieces, the normally relatively round to polygonal foam pores are flattened with increasing degree of compression and molded in an ellipsoidal manner or the cell webs fold in perpendicular to the direction of upsetting. This leads to an anisotropic heat conduction behavior, which leads to a reduction in the heat conduction in the workpiece thickness direction and a slightly increased heat conduction in the workpiece plane direction, ie, a higher thermal insulation of the workpiece.
- such a mat-shaped pressed workpiece made of the aluminum blowing agent powder mixture into cavities between components and to heat the workpiece so that it inflates between the opposite walls of the components and essentially completely fills the intermediate space.
- such a component also acts as a vibration-damping unit that dampens the adjacent components and also stiffens the overall construction.
- the invention therefore offers a simple possibility of forming composite bodies with both mechanical and acoustically damping or insulating functions.
- the composite body according to the invention favors disposal, since it can be easily separated from other materials of the overall assembly and can be reused without the formation of harmful and polluting gases and vapors in the usual metal separation and processing process. It is therefore also possible to use recyclable aluminum materials for the production of the compacted workpiece and therefore of the sound wave damping or insulating and heat insulating component.
- a blackening of the workpiece produced on one side leads to a significant increase in the emission coefficient and thus to an increase in thermal insulation.
- powdered aluminum in large excess over the proportions of the blowing agent powder, in a ratio between 10: 1 and 1000: 1. It is advisable to add compounds containing aluminum oxide in proportions of 0-30% (based on the total amount of powder). In all cases, it should Blowing agents, as well as other constituents, are largely homogeneously distributed in the aluminum powder, unless certain areas of the workpiece from the powder mixture are to foam less when heat is applied.
- the powder mixture is compacted to the workpiece under a pressure of advantageously between 10 and 500 MPa. Temperatures in the range between 400 and 900 ° C should be used for heating and foaming.
- the component according to the invention can also be cold-formed even after foaming in order to adapt it even better to certain space requirements.
- the component according to the invention is particularly preferably used in motor vehicles and machine systems, specifically as a sound-absorbing partition and / or sound-absorbing cover for vibrating wall parts and / or sound-absorbing thermal insulation of the entire exhaust line.
- components with cell walls made of aluminum or aluminum alloys of the foamed cells forming the foam form a multifunctional structural component which not only corresponds to the wishes of an acoustically good effectiveness, but also solves the above-mentioned object and also has other advantages brings:
- the aluminum structure is dimensionally stable and therefore self-supporting, but also much better thermally insulating compared to compact aluminum .
- the total weight is relatively low in the extent of the void formation. Disposal can be done together with the other metal components aluminum in particular without separating. The very costly segregation of plastic parts is avoided, particularly when used in automobile construction. The result is a simple recycling process.
- FIG. 1 schematically shows in cross section part of a type of “front shell” which, with its curved outer side 2, faces the passenger compartment within a motor vehicle.
- the component consists of an abundance of hollow cells 3, the cell walls 3a of which, as shown in FIG. 3, consist of aluminum. While the surface 2 facing the passenger compartment has an essentially closed, non-porous, thin aluminum skin which extends to the edge part 5, the sound-generating engine compartment can face the open-cell inner side 1, so that the sound enters the cells 3 or in spaces 3c can penetrate between adjacent cells 3.
- the inherently rigid foam body 8 from the hollow cells absorbs part of the sound waves that pass through the openings 3b in the cell walls 3a and / or into the spaces 3c penetrate neighboring cells 3, which do not, as at the connection point 3c of adjacent cells 3, frit and / or fuse together in the heat used in the foam formation.
- the aluminum skin 4 and the edge part 5 of the component are formed, for example, by fusing or frying the cell walls 3a.
- the component according to the exemplary embodiment of FIG. 1 is provided on the inside 1 with recesses 6;
- the component has a zone B of less thickness at this point than in the other zones A.
- the minimum thickness of the component should be 2 mm; the layer thickness of the edge part 5 of the component of FIGS. 1 and 2 is approximately 3 mm, while the layer thickness in the zones A is of the order of cm.
- the distribution of layer thicknesses, cell and cavity sizes and cell wall thicknesses depends on the functions of sound absorption. In many cases, it is advisable to alternate zones of very good sound absorption with zones per se of less good sound absorption, as a result of which very specific overlay functions can be formed.
- the mixture in a compacting stage under a pressure of, for example, 50 MPa becomes that in FIG. 4 schematically in cross section shown workpiece 7 pressed together.
- this can have relatively large dimensions and can be designed like a mat or profile.
- the workpiece 7 can be made like any other workpiece made of normal aluminum or aluminum alloy without additions using known machining methods, such as Bending, milling, cutting, drilling, punching, extrusion, can be brought into any two or three-dimensional shape 7a.
- the workpiece 7 is foamed in a heating and deformation stage, for example within a hollow mold, to give the foam body 8 shown schematically in cross section in FIG. 4, which has an essentially open-cell foam structure of the cells 3, but can be covered on the outside with a thin skin 4, without significantly affecting the acoustic effectiveness.
- a temperature of 750 ° C. is sufficient for heating in order to form a foam body 8 with an average porosity of approximately 80% and an average cell size of approximately 0.8 mm.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Multimedia (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Soundproofing, Sound Blocking, And Sound Damping (AREA)
- Powder Metallurgy (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Building Environments (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Golf Clubs (AREA)
- Electric Suction Cleaners (AREA)
- Stringed Musical Instruments (AREA)
Claims (16)
- Corps composite, isolant thermiquement et acoustiquement, en construction légère, par utilisation d'un corps en mousse (8), formé à partir d'une pièce d'oeuvre (7), déformée par chauffage, qui présente un mélange compacté d'aluminium pulvérulent ou d'alliage d'aluminium (9) et d'agent gonflant et d'agent moussant (10) pulvérulent et au besoin de composé d'oxyde d'aluminium (11) pulvérulent, et avec une porosité moyenne comprise entre 60 et 90 %.
- Corps composite selon la revendication 1, caractérisé en ce qu'un grand nombre des cellules (3) du corps en mousse (8) est ouvert.
- Corps composite selon la revendication 1 ou 2, caractérisé en ce qu'une partie de la surface (2) du corps en mousse (8) est recouverte d'une mince pellicule d'aluminium (4) non poreuse, sensiblement fermée.
- Corps composite selon l'une des revendications précédentes, caractérisé en ce que le corps en mousse (8) présente des zones (A) de plus grande épaisseur et d'autres zones (B) de moindre épaisseur.
- Corps composite selon l'une des revendications précédentes, caractérisé en ce que le corps en mousse (8) présente une grosseur de pore ou une grosseur de cellule moyenne entre 0,1 et 1,5 mm et/ou une densité comprise entre 0,3 et 2,0 g/cm3.
- Corps composite selon l'une des revendications précédentes, caractérisé en ce que le corps en mousse (8) est noirci sur une face.
- Procédé de fabrication d'un corps en mousse (8), dans lequel la poudre (9) présente de l'aluminium ou un alliage d'aluminium, avec une poudre (10) d'un agent moussant dans un rapport compris entre 10 : 1 et 1 000 : 1 (poudre d'aluminium par rapport à la poudre d'agent moussant) mélangée en un mélange réparti de façon sensiblement homogène et compactée pour donner la pièce d'oeuvre (7), par pressage, sous une pression comprise entre 10 et 500 MPa et expansée ensuite en un corps en mousse (8) avec cellules ouvertes, au moins sur une face, par chauffage entre 400 et 900 °C, caractérisé en ce que la poudre (9) présentant l'aluminium ou un alliage d'aluminium et la poudre d'agent moussant (10) avec une poudre (11) présentant de l'oxyde d'aluminium, celle-ci dans une proportion pouvant aller jusqu'à 30 % du mélange de poudre totale, sont mélangées et le chauffage est conduit de manière qu'il en résulte une porosité moyenne comprise entre 60 et 90 % du corps en mousse (8) isolant thermiquement et acoustiquement.
- Corps composite selon la revendication 7, caractérisé en ce que la pièce d'oeuvre (7 ou 7a) est chauffée, dans une forme sensiblement fermée, de manière qu'elle remplisse totalement celle-ci lors de l'expansion et se déforme dans la forme d'un corps en mousse (8), tout en n'étant pas absolument nécessaire que la pièce d'oeuvre (7a) doive être adaptée dans sa forme à la forme du corps en mousse (8) définitif, avant l'expansion.
- Corps composite selon la revendication 7, caractérisé en ce que la pièce d'oeuvre (7 ou 7a) est librement expansée puis est plus ou moins fortement comprimée et amenée ainsi à l'épaisseur définitive.
- Corps composite selon l'une des revendications 7 à 9, caractérisé en ce que le corps en mousse (8) est en supplément déformé à froid.
- Procédé selon l'une des revendications 7 à 10, caractérisé en ce que la pièce d'oeuvre est noircie sur une face par graphitage.
- Utilisation d'un élément de construction selon l'une des revendications 1 à 6 en tant qu'élément de construction d'isolation phonique, par exemple cloison, dans des véhicules automobiles, des avions, des bateaux ou des installations motrices.
- Utilisation d'un élément de construction selon l'une des revendications 1 à 6 en tant que couverture d'isolation phonique de parties de paroi vibrantes dans des véhicules automobiles, des avions, des bateaux ou des installations motrices.
- Utilisation d'un élément de construction selon l'une des revendications 1 à 6 en tant qu'élément de construction d'isolation thermique dans des véhicules automobiles, des avions, des bateaux ou des installations motrices.
- Utilisation d'un élément de construction selon l'une des revendications 1 à 6 en tant qu'élément de construction d'isolation ou d'amortissement du bruit et d'isolation thermique dans des véhicules automobiles, des avions, des bateaux ou des installations motrices.
- Utilisation d'un élément de construction selon l'une des revendications 1 à 6 en tant qu'élément de construction structurel autoporteur dans des véhicules automobiles, des avions, des bateaux ou des installations motrices.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE9212607U | 1992-09-18 | ||
DE9212607U DE9212607U1 (de) | 1992-09-18 | 1992-09-18 | Schallwellen dämpfendes und/oder dämmendes Bauelement aus Schaumstoff |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0588182A2 EP0588182A2 (fr) | 1994-03-23 |
EP0588182A3 EP0588182A3 (fr) | 1995-05-31 |
EP0588182B1 true EP0588182B1 (fr) | 1997-05-07 |
Family
ID=6883912
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93114133A Revoked EP0588182B1 (fr) | 1992-09-18 | 1993-09-03 | Elément composite pour isoler la température ou le son, son procédé de fabrication et l'utilisation |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0588182B1 (fr) |
AT (1) | ATE152851T1 (fr) |
CZ (1) | CZ282028B6 (fr) |
DE (2) | DE9212607U1 (fr) |
ES (1) | ES2102566T3 (fr) |
HU (1) | HU215772B (fr) |
PL (1) | PL172699B1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7682577B2 (en) | 2005-11-07 | 2010-03-23 | Geo2 Technologies, Inc. | Catalytic exhaust device for simplified installation or replacement |
US7682578B2 (en) | 2005-11-07 | 2010-03-23 | Geo2 Technologies, Inc. | Device for catalytically reducing exhaust |
US7722828B2 (en) | 2005-12-30 | 2010-05-25 | Geo2 Technologies, Inc. | Catalytic fibrous exhaust system and method for catalyzing an exhaust gas |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH687167A5 (de) * | 1992-12-18 | 1996-09-30 | Matec Holding Ag | Laermmindernde Kapselung. |
AT406649B (de) * | 1996-05-02 | 2000-07-25 | Mepura Metallpulver | Verfahren zur herstellung von porösen matrixmaterialien, insbesondere formkörpern, auf basis von metallen, und von halbzeug dafür |
DE19852277C2 (de) * | 1998-11-13 | 2000-12-14 | Schunk Sintermetalltechnik Gmb | Verfahren zur Herstellung eines metallischen Verbundwerkstoffes sowie Halbzeug für einen solchen |
DE19927837C1 (de) * | 1999-06-18 | 2001-01-25 | Schwaebische Werkzeugmaschinen | Verfahren zum Herstellen eines Metallbauteils aus Metallschaum für eine Werkzeugmaschine |
DE10034301C2 (de) * | 2000-07-14 | 2002-06-13 | Bruss Dichtungstechnik | Schallgedämpftes Gehäuse für Geräusch erzeugende Maschinen |
US6820923B1 (en) * | 2000-08-03 | 2004-11-23 | L&L Products | Sound absorption system for automotive vehicles |
GB0019913D0 (en) | 2000-08-15 | 2000-09-27 | Ventures & Consultancy Bradfor | Sound absorbing material |
US6793274B2 (en) | 2001-11-14 | 2004-09-21 | L&L Products, Inc. | Automotive rail/frame energy management system |
US7043815B2 (en) | 2002-01-25 | 2006-05-16 | L & L Products, Inc. | Method for applying flowable materials |
GB0203472D0 (en) * | 2002-02-14 | 2002-04-03 | Acoutechs Ltd | Sound absorbing material |
DE10246596C5 (de) * | 2002-10-05 | 2010-01-28 | J. Eberspächer GmbH & Co. KG | Schalldämpfer, insbesondere für Heizgerät |
US7180027B2 (en) | 2004-03-31 | 2007-02-20 | L & L Products, Inc. | Method of applying activatable material to a member |
DE202005006240U1 (de) * | 2005-04-18 | 2005-10-20 | Seeliger, Hans-Wolfgang | Metallschaum-Sandwichs |
US7211232B1 (en) | 2005-11-07 | 2007-05-01 | Geo2 Technologies, Inc. | Refractory exhaust filtering method and apparatus |
DE102006025933A1 (de) * | 2006-05-10 | 2007-11-22 | WKW Erbslöh Automotive GmbH | Dachreling sowie Verfahren zur Herstellung einer solchen Dachreling |
GB201207481D0 (en) | 2012-04-26 | 2012-06-13 | Zephyros Inc | Applying flowable materials to synthetic substrates |
PL241832B1 (pl) * | 2018-04-19 | 2022-12-12 | Akademia Gorniczo Hutnicza Im Stanislawa Staszica W Krakowie | Sposób recyklingu wiórów z aluminium lub jego stopów |
CN111824061A (zh) * | 2019-04-16 | 2020-10-27 | 宁波均胜汽车安全系统有限公司 | 一种安全带降噪装置 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2735153A1 (de) * | 1977-08-04 | 1979-02-15 | Helmut Pelzer | Spezifisch leichtes feder-masse- system in bekannter weise als doppelmatte ausgebildet |
US4197477A (en) * | 1978-07-12 | 1980-04-08 | General Electric Company | Armature lamina for a dynamoelectric machine |
US4458779A (en) * | 1981-07-02 | 1984-07-10 | Antiphon Ab | Silencer |
EP0210803B1 (fr) * | 1985-07-19 | 1989-09-20 | Agency Of Industrial Science And Technology | Mousse métallique et procédé pour sa fabrication |
DE3624427A1 (de) * | 1986-07-18 | 1988-01-21 | Stankiewicz Alois Dr Gmbh | Adhaesives zerstoerungsfrei entfernbares isolationssystem |
JPH01215933A (ja) * | 1988-02-24 | 1989-08-29 | Aisin Takaoka Ltd | 金属多孔質体およびその製造方法 |
US5112697A (en) * | 1989-09-06 | 1992-05-12 | Alcan International Limited | Stabilized metal foam body |
DE4018360C1 (en) * | 1990-06-08 | 1991-05-29 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | Porous metal body prodn. - involves compaction at low temp. followed by heating to near melting point of metal |
-
1992
- 1992-09-18 DE DE9212607U patent/DE9212607U1/de not_active Expired - Lifetime
-
1993
- 1993-09-03 AT AT93114133T patent/ATE152851T1/de not_active IP Right Cessation
- 1993-09-03 DE DE59306374T patent/DE59306374D1/de not_active Expired - Fee Related
- 1993-09-03 ES ES93114133T patent/ES2102566T3/es not_active Expired - Lifetime
- 1993-09-03 EP EP93114133A patent/EP0588182B1/fr not_active Revoked
- 1993-09-13 HU HU9302579A patent/HU215772B/hu not_active IP Right Cessation
- 1993-09-13 PL PL93300380A patent/PL172699B1/pl unknown
- 1993-09-17 CZ CZ931936A patent/CZ282028B6/cs not_active IP Right Cessation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7682577B2 (en) | 2005-11-07 | 2010-03-23 | Geo2 Technologies, Inc. | Catalytic exhaust device for simplified installation or replacement |
US7682578B2 (en) | 2005-11-07 | 2010-03-23 | Geo2 Technologies, Inc. | Device for catalytically reducing exhaust |
US7722828B2 (en) | 2005-12-30 | 2010-05-25 | Geo2 Technologies, Inc. | Catalytic fibrous exhaust system and method for catalyzing an exhaust gas |
Also Published As
Publication number | Publication date |
---|---|
PL300380A1 (en) | 1994-03-21 |
ES2102566T3 (es) | 1997-08-01 |
HUT68467A (en) | 1995-06-28 |
EP0588182A3 (fr) | 1995-05-31 |
PL172699B1 (pl) | 1997-11-28 |
CZ193693A3 (en) | 1994-04-13 |
HU215772B (hu) | 1999-02-01 |
DE9212607U1 (de) | 1994-02-24 |
DE59306374D1 (de) | 1997-06-12 |
EP0588182A2 (fr) | 1994-03-23 |
CZ282028B6 (cs) | 1997-04-16 |
HU9302579D0 (en) | 1994-03-28 |
ATE152851T1 (de) | 1997-05-15 |
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