EP0536420A4 - Process for producing hydrochloromethanes - Google Patents

Process for producing hydrochloromethanes

Info

Publication number
EP0536420A4
EP0536420A4 EP19920909542 EP92909542A EP0536420A4 EP 0536420 A4 EP0536420 A4 EP 0536420A4 EP 19920909542 EP19920909542 EP 19920909542 EP 92909542 A EP92909542 A EP 92909542A EP 0536420 A4 EP0536420 A4 EP 0536420A4
Authority
EP
European Patent Office
Prior art keywords
catalyst
reduction
elements
chloroform
carbon tetrachloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19920909542
Other languages
French (fr)
Other versions
EP0536420B1 (en
EP0536420A1 (en
Inventor
Shinsuke Morikawa
Masaru Asahi Glass Co. Ltd. Yoshitake
Shin Asahi Glass Company Ltd. Tatematsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
AG Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP3119457A external-priority patent/JPH04327546A/en
Priority claimed from JP3352257A external-priority patent/JP3004115B2/en
Application filed by AG Technology Co Ltd filed Critical AG Technology Co Ltd
Publication of EP0536420A1 publication Critical patent/EP0536420A1/en
Publication of EP0536420A4 publication Critical patent/EP0536420A4/en
Application granted granted Critical
Publication of EP0536420B1 publication Critical patent/EP0536420B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
    • C07C19/03—Chloromethanes
    • C07C19/04—Chloroform

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for producing hydrochloromethanes such as chloroform at high selectivity in high yields by reducing polychloromethanes such as carbon tetrachloride in the presence of a reduction catalyst. It is essential to conduct reduction in liquid phase so as to inhibit effectively the concomitant formation of impurities such as a polymer which deactivates the catalyst, whereby the catalyst can fully develop its high selectivity and activity. As the catalyst, at least one element is suitably selected among the group 8, 9 and 10 elements of the Periodic Table, such as ruthenium, rhodium, palladium or platinum. Also suitably usable is a catalyst which is based on any of the above elements and further contains at least one of the group 11 elements such as copper, silver or gold. When the liquid-phase reduction is to be conducted continuously, the use of a fixed bed is desirable, a dropping bed being particularly desirable. This process is also highly valuable as a process for converting carbon tetrachloride, the use of which is legally regulated from the viewpoint of the preservation of the global environment, into, for example, chloroform, which is useful as the starting material of various fluorine compounds.
EP92909542A 1991-04-23 1992-04-23 Process for producing hydrochloromethanes Expired - Lifetime EP0536420B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP119457/91 1991-04-23
JP3119457A JPH04327546A (en) 1991-04-23 1991-04-23 Production of hydrogen-containing chloromethanes
JP3352257A JP3004115B2 (en) 1991-12-13 1991-12-13 Production method of hydrogen-containing chloroalkanes
JP352257/91 1991-12-13
PCT/JP1992/000522 WO1992018447A1 (en) 1991-04-23 1992-04-23 Process for producing hydrochloromethanes

Publications (3)

Publication Number Publication Date
EP0536420A1 EP0536420A1 (en) 1993-04-14
EP0536420A4 true EP0536420A4 (en) 1993-09-29
EP0536420B1 EP0536420B1 (en) 1997-01-22

Family

ID=26457193

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92909542A Expired - Lifetime EP0536420B1 (en) 1991-04-23 1992-04-23 Process for producing hydrochloromethanes

Country Status (6)

Country Link
US (1) US5334782A (en)
EP (1) EP0536420B1 (en)
KR (1) KR100222459B1 (en)
CA (1) CA2086110C (en)
DE (1) DE69216977T2 (en)
WO (1) WO1992018447A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5621151A (en) * 1990-10-09 1997-04-15 E. I. Du Pont De Nemours And Company Halocarbon hydrogenolysis
GB9306334D0 (en) * 1993-03-26 1993-05-19 Univ Dundee Catalyst
US5817896A (en) * 1993-03-26 1998-10-06 The University Court Of The University Of Dundee Catalytic method of replacing halogen in halocarbons
JPH07285890A (en) * 1994-04-14 1995-10-31 Dow Chem Co:The Hydrodechlorination of chlorinated alkane
GB0020910D0 (en) * 2000-08-25 2000-10-11 Univ Birmingham Reduction method
IT1319258B1 (en) * 2000-10-31 2003-09-26 Sued Chemie Mt Srl CATALYST FOR THE HYDRODECLORURATION OF CARBON TETRACHLORIDE ACLOROFORM.
KR100484508B1 (en) * 2002-09-27 2005-04-20 학교법인 포항공과대학교 Method for disposing of carbontetrachloride
CN102690203A (en) * 2011-03-22 2012-09-26 中国科学院大连化学物理研究所 Method for preparing 1,3-cyclohexanebis(methylamine)
TWI537347B (en) 2015-04-02 2016-06-11 綠點高新科技股份有限公司 A sheath-core type catalyst for catalytic ink

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3579596A (en) * 1968-03-29 1971-05-18 Dow Chemical Co Hydrogenolysis of carbon tetrachloride and chloroform
JPH021414A (en) * 1988-03-28 1990-01-05 Kanto Denka Kogyo Co Ltd Substitution of halogen in carbon halide or halogenated hydrocarbon by hydrogen

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2737308B2 (en) * 1989-10-20 1998-04-08 旭硝子株式会社 Method for producing partially chlorinated methane
ES2018748A6 (en) * 1989-12-22 1991-05-01 Ercros Sa Method for producing chloroform.
FR2661671B1 (en) * 1990-05-03 1992-07-17 Atochem PROCESS FOR DECHLORINATION OF SUPERIOR CHLOROMETHANES.
JPH0426636A (en) * 1990-05-22 1992-01-29 Asahi Glass Co Ltd Reduction of halogenated carbon
US5105032A (en) * 1990-10-04 1992-04-14 The Dow Chemical Company Vapor phase hydrogenation of carbon tetrachloride
BE1004608A3 (en) * 1990-11-16 1992-12-22 Solvay Method for manufacturing of chloroform from carbon tetrachloride, catalyst composition and method for obtaining.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3579596A (en) * 1968-03-29 1971-05-18 Dow Chemical Co Hydrogenolysis of carbon tetrachloride and chloroform
JPH021414A (en) * 1988-03-28 1990-01-05 Kanto Denka Kogyo Co Ltd Substitution of halogen in carbon halide or halogenated hydrocarbon by hydrogen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO9218447A1 *

Also Published As

Publication number Publication date
CA2086110A1 (en) 1992-10-24
US5334782A (en) 1994-08-02
CA2086110C (en) 1999-05-11
EP0536420B1 (en) 1997-01-22
DE69216977D1 (en) 1997-03-06
DE69216977T2 (en) 1997-05-15
KR100222459B1 (en) 1999-10-01
KR930701369A (en) 1993-06-11
WO1992018447A1 (en) 1992-10-29
EP0536420A1 (en) 1993-04-14

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