EP0509134B1 - Verfahren und Anlage zum thermischen Aufbereiten von mit organischen Komponenten verunreinigten Abfällen, insbesondere von Metallschrott - Google Patents

Verfahren und Anlage zum thermischen Aufbereiten von mit organischen Komponenten verunreinigten Abfällen, insbesondere von Metallschrott Download PDF

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Publication number
EP0509134B1
EP0509134B1 EP91115548A EP91115548A EP0509134B1 EP 0509134 B1 EP0509134 B1 EP 0509134B1 EP 91115548 A EP91115548 A EP 91115548A EP 91115548 A EP91115548 A EP 91115548A EP 0509134 B1 EP0509134 B1 EP 0509134B1
Authority
EP
European Patent Office
Prior art keywords
stage
gas
installation
pyrolysis
temperature gasification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91115548A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0509134A2 (de
EP0509134A3 (en
Inventor
Heiner Sass
Paul Dipl.-Ing. Dr. Freimann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pka Umwelttechnik & Co Kg GmbH
Original Assignee
Pka Umwelttech & Co KG GmbH
Pka Umwelttechnik & Co Kg GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pka Umwelttech & Co KG GmbH, Pka Umwelttechnik & Co Kg GmbH filed Critical Pka Umwelttech & Co KG GmbH
Publication of EP0509134A2 publication Critical patent/EP0509134A2/de
Publication of EP0509134A3 publication Critical patent/EP0509134A3/de
Application granted granted Critical
Publication of EP0509134B1 publication Critical patent/EP0509134B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/62—Processes with separate withdrawal of the distillation products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/1223—Heating the gasifier by burners
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643—Conversion of synthesis gas to energy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C10J2300/1823—Recycle loops, e.g. gas, solids, heating medium, water for synthesis gas

Definitions

  • the invention relates to a method for the thermal treatment of waste contaminated with organic components. First and foremost, it is about the processing of metal scrap, namely the scrap that accumulates in a car shredder, in particular also aluminum scrap that is contaminated by the organic plastics used in automobile construction.
  • a high temperature gasification stage is also known as a single system (e.g. EP-A-0257018). However, a high proportion of free primary energy is required.
  • the invention is based on the object of specifying a method or a system for the thermal treatment of waste contaminated with organic components, in which, in addition to the reusable substances, waste materials to be disposed of with as little energy expenditure as possible are generated with as little effort as possible.
  • the pyrolysis gas produced in the smoldering stage is cleaned in the subsequent high-temperature gasification stage and converted into the marketable products heating gas and glazed slag.
  • the supply of primary energy to the high-temperature gasification stage is minimized by the supply of the pyrolysis gas produced in the carbonization stage and, depending on the proportion of organic substances, can even go to zero.
  • the heating gas produced in the high-temperature gasification stage is advantageously freed of undesired components before it is used for energy purposes.
  • a denitrification system, as well as a dioxin filter can then be dispensed with under certain circumstances. If a gas cleaning system is arranged, the gas is of course returned to the carbonization stage after the gas has been cleaned.
  • the invention also relates to a plant for carrying out the method described in claims 2 to 5.
  • the above statements relating to a method apply mutatis mutandis.
  • the scrap 1 contaminated with organic components is fed to a pre-comminution system 2 and comminuted there to piece sizes of a maximum of 5 cm. Larger pieces can be returned to the entrance of the pre-shredding unit 2.
  • the shredded scrap is then fed to a carbonization stage 3, which is operated at a temperature of approximately 550 ° to 600 ° C.
  • the level 3 is possibly Energy 21 and air or oxygen 22 supplied.
  • the solids 5 are separated from the pyrolysis gas 4 by pyrolysis.
  • the solids 5 are then separated into reusable metal 7 and pyrolysis coke 8 in a mechanical processing stage 6.
  • the cleaned metal 7 can be fed to a smelter as pure scrap.
  • the pyrolysis coke 8 comes into a high-temperature gasification stage 14.
  • the pyrolysis gas 4 also comes from the carbonization stage 3.
  • the high-temperature gasification stage 14 also has supply lines for energy 23 and an oxidizing agent 9, e.g. Air or oxygen, and possibly also for coke 10.
  • the pyrolysis gas 4 is supplied via a burner.
  • the treatment in the high-temperature gasification stage 14 takes place at a temperature of approx. 1600 ° C.
  • a glazed building material 19 and energy 20 are obtained, which can be given to consumers.
  • the heating gas 11 obtained in the high-temperature gasification stage 14 is fed to a gas cleaning system 13, where it is freed of undesirable additions, for example of HCl, HF, dust and dust constituents.
  • the gas purified in this way is then subjected to an energetic use 12, e.g. in the form of a boiler.
  • a portion 17 of the cleaned gas is returned to carbonization stage 3 and minimizes the supply of primary energy.
  • the energy obtained in the energetic use 12 is given to the consumer together with the energy 20 obtained in the high-temperature gasification stage.
  • a flue gas desulfurization system 16 is connected downstream of the energetic use 12, but this only happens as required.
  • the flue gas desulfurization system 16 can also be supplied with the flue gas 18 obtained in the carbonization stage 3. After desulfurization, the flue gas 24 goes into the atmosphere, optionally with the interposition of further filters.
  • the invention has been explained above on the basis of the processing of metal scrap. However, the invention can also be used in the treatment of other waste, household waste and special waste.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Treatment Of Sludge (AREA)
EP91115548A 1991-04-17 1991-09-13 Verfahren und Anlage zum thermischen Aufbereiten von mit organischen Komponenten verunreinigten Abfällen, insbesondere von Metallschrott Expired - Lifetime EP0509134B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4112593A DE4112593C2 (de) 1991-04-17 1991-04-17 Verfahren und Anlage zum thermischen Aufbereiten von mit organischen Komponenten verunreinigten Metallschrott
DE4112593 1991-04-17

Publications (3)

Publication Number Publication Date
EP0509134A2 EP0509134A2 (de) 1992-10-21
EP0509134A3 EP0509134A3 (en) 1993-01-13
EP0509134B1 true EP0509134B1 (de) 1994-06-08

Family

ID=6429818

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91115548A Expired - Lifetime EP0509134B1 (de) 1991-04-17 1991-09-13 Verfahren und Anlage zum thermischen Aufbereiten von mit organischen Komponenten verunreinigten Abfällen, insbesondere von Metallschrott

Country Status (7)

Country Link
US (1) US5170725A (da)
EP (1) EP0509134B1 (da)
JP (1) JPH0824904B2 (da)
AT (1) ATE106935T1 (da)
DE (2) DE4112593C2 (da)
DK (1) DK0509134T3 (da)
ES (1) ES2056544T3 (da)

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JP3153091B2 (ja) * 1994-03-10 2001-04-03 株式会社荏原製作所 廃棄物の処理方法及びガス化及び熔融燃焼装置
DE4139512A1 (de) * 1991-11-29 1993-06-03 Noell Dbi Energie Entsorgung Verfahren zur thermischen verwertung von abfallstoffen
DE4308551A1 (de) * 1993-03-17 1994-01-05 Siemens Ag Verfahren und Einrichtung zum Entsorgen von Abfall
DE4418562A1 (de) * 1993-06-29 1995-01-12 Leybold Durferrit Gmbh Verfahren und Vorrichtung zur Behandlung von im wesentlichen aus Kunststoff oder Gummi bestehendem Gut
DE4325081A1 (de) * 1993-07-22 1995-01-26 Video Computer Recycling Verfahren und Vorrichtung zum Entsorgen von Flüssigkristallsubstanzen aus Flüssigkristallanzeigen
US5402739A (en) * 1993-10-27 1995-04-04 Abboud; Harry I. Closed loop incineration process
DK0672743T3 (da) * 1994-03-18 1999-06-23 Ald Vacuum Techn Gmbh Fremgangsmåde og apparat til termisk behandling af materialer med andele af forkampelige stoffer
DE4409401C1 (de) * 1994-03-18 1995-06-01 Dieter Uschkoreit Verfahren zur Verbrennung von im wesentlichen anorganische und/oder organische Bestandteile enthaltendem Müll
CH690790A5 (de) * 1995-01-10 2001-01-15 Von Roll Umwelttechnik Ag Verfahren zur thermischen Behandlung von Abfallmaterial.
AU7318696A (en) * 1995-10-26 1997-05-15 Compact Power Limited Production of heat energy from solid carbonaceous fuels
JP4076233B2 (ja) 1996-06-25 2008-04-16 株式会社荏原製作所 固形廃棄物のガス化溶融処理方法及び装置
US6029588A (en) * 1998-04-06 2000-02-29 Minergy Corp. Closed cycle waste combustion
US6401633B2 (en) 1998-04-06 2002-06-11 Minergy Corporation Closed cycle waste combustion
JP4154029B2 (ja) 1998-04-07 2008-09-24 株式会社東芝 廃棄物の処理方法および廃棄物処理装置
JP3310245B2 (ja) * 1999-07-22 2002-08-05 株式会社豊栄商会 処理装置および処理方法
KR100309437B1 (ko) 1999-08-23 2001-09-26 윤명조 산소부화가스를 이용한 폐기물의 굴뚝없는 완전 자원화 처리공정
EP1233048A3 (fr) * 2000-12-22 2003-07-09 Soboref S.A. Procédé et installation pour le traitement combiné de résidus de broyage et de boues
EP1217059A1 (fr) * 2000-12-22 2002-06-26 Soboref S.A. Procédé et installation pour le traitement combine de résidus de broyage et de boues
IT1398597B1 (it) * 2009-04-29 2013-03-08 Protodesign Srl Processo ibrido di pirolisi e gassificazione per la conversione di un generico rifiuto in un combustibile gassoso (un particolare combustibile da rifiuto - c.d.r.) a basso impatto ambientale.
UY33038A (es) 2009-11-20 2011-06-30 Rv Lizenz Ag Uso termico y quimico de sustancias cabonaceas en particular para la generacion de energia sin emisiones
US20110247534A1 (en) * 2010-04-08 2011-10-13 E-Sunscience Co., Ltd. Waste recycling apparatus
US8696790B2 (en) 2011-07-27 2014-04-15 Conecsus Llc Conversion of organic wastes into a reducing agent—coke substitute
CN102614746B (zh) * 2012-03-27 2014-11-05 巨化集团技术中心 一种β-氟磺内酯生产过程中的废气处理方法
CN107470716A (zh) * 2017-10-10 2017-12-15 温州翔宇教育科技有限公司 一种可处理切削产物的金属板加工用切削装置
GB2575648B (en) * 2018-07-17 2020-07-29 North American Construction Service Ltd System for cleaning metallic scraps from organic compounds

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Also Published As

Publication number Publication date
ATE106935T1 (de) 1994-06-15
US5170725A (en) 1992-12-15
EP0509134A2 (de) 1992-10-21
DE4112593C2 (de) 1995-03-23
JPH04326974A (ja) 1992-11-16
DE4112593A1 (de) 1992-10-22
ES2056544T3 (es) 1994-10-01
DK0509134T3 (da) 1994-09-26
EP0509134A3 (en) 1993-01-13
DE59101878D1 (de) 1994-07-14
JPH0824904B2 (ja) 1996-03-13

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