EP0505466A1 - Impermeabilisation amelioree de garnissage fibreux en polyester - Google Patents

Impermeabilisation amelioree de garnissage fibreux en polyester

Info

Publication number
EP0505466A1
EP0505466A1 EP91901528A EP91901528A EP0505466A1 EP 0505466 A1 EP0505466 A1 EP 0505466A1 EP 91901528 A EP91901528 A EP 91901528A EP 91901528 A EP91901528 A EP 91901528A EP 0505466 A1 EP0505466 A1 EP 0505466A1
Authority
EP
European Patent Office
Prior art keywords
copolyetherester
ester units
chain ester
elastomer
fiberfill
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91901528A
Other languages
German (de)
English (en)
Inventor
Michael Stephen Frankosky
George Joseph Ostapchenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of EP0505466A1 publication Critical patent/EP0505466A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters

Definitions

  • This invention concerns improvements in and relating to providing polyester fiberfill with a waterproof coating layer, especially for use in apparel.
  • Polyester fiberfill (sometimes referred to as polyester fiberfilling material) has become well accepted as a reasonably inexpensive filling and/or insulating material, and is manufactured and used in large quantities for pillows, cushions and other furnishing materials, including
  • Polyester fiberfill batting is used commercially in many apparel articles because it is an efficient and economic alternative to down and feather insulation, and it is relatively insensitive to moisture. It is, however, desirable to prevent intrusion by
  • Such apparel has required, in practice, special seam-sealing wherever fabrics have been joined or attached, such as for arms and pockets.
  • This special seam-sealing has been expensive and has limited design possibilities, and, for sheer fabrics, has been aesthetically objectionable.
  • waterproof/breathable film has been attached to a scrim to be used as a drop-in liner; this approach gave more design freedom and reduced the amount of seam-sealing needed, but the films required special treatment to prepare them for lamination to the scrim and were attached to the scrim in a separate step.
  • slicken the fiberfill with a coating of durable (e.g., wash-resistant) coating, that has usually been a silicone, i.e., a cured polysiloxane, as disclosed, e.g., by Hofmann, U.S. Patent No. 3,271,189, Mead et al., U.S. Patent No. 3,454,422, Ryan, U.S. Patent No. 3,488,217, Salamon et al. , U.S. Patent No. 4,146,674, Pamm, U.S. Patent No. 4,281,042, Frankosky, U.S. Patent No. 4,304,817, and Takemoto Oil & Fat Co. Ltd., Japanese Published Patent Application No. 58-214,585 (1983) .
  • the slickener has long presented serious problems in obtaining good adhesion, as discussed in several of these references, such as Pamm and Frankosky.
  • a film of a particular copolyetherester elastomer that is hydrophilic can be - 3 -
  • a batt of polyester fiberfill, or a garment or other article filled with polyester fiberfill wherein the polyester fiberfill is secured to a continuous flexible layer of a waterproof hydrophilic elastomer having a water vapor transmission rate of at least 3500
  • hydrophilic elastomer being a copolyetherester elastomer or a mixture of two or more copolyetherester elastomers having a multiplicity of long-chain ester units and short-chain ester units joined head-to-tail through
  • G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having an average molecular weight of about 400-3500, and further, the amount of ethylene oxide groups incoporated
  • D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250; and said hydrophilic copolyetherester or mixture of two or more
  • copolyetheresters has from about 25-80 weight percent short- chain ester units.
  • the fiberfill is secured to the continuous layer of the hydrophilic elastomer by an intervening layer of a hydrophobic elastomer having a water vapor transmission rate of 400-2500 gm.mil/m 2 /24hrs, preferably about 800-1200 gm.mil/m 2 /24hrs, said hydrophobic elastomer is a copolyetherester having a multiplicity of recurring long-chain ester units and short-chain ester units, said long-chain ester units being represented by the formula
  • G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having an average molecular weight of about 400-3500, the amount of ethylene oxide groups incorporated in the copolyetherester by the poly(alkylene oxide)glycol is not greater than about 20 weight percent;
  • R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight less than 300;
  • D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250; and wherein said hydrophobic elastomer preferably has about 25-80 weight percent short-chain ester units.
  • the fiberfill may advantageously be bonded intermittently to the layer of hydrophobic elastomers by spot-bonding or in other discontinuous manner, preferably by use of binder fibers that are of lower melting point.
  • film may comprise more than one elastomer layer.
  • One layer is a hydrophilic elastomer layer, as above.
  • a second layer may be coextruded with the first and may be a hydrophobic elastomer, such as a copolyetherester containing 20.3 weight 5 percent 1.4-butylene terephthalate, 7.9 weight percent 1,4-butylene isophthalate, 51.7 weight percent poly(tetramethylene ether) isophthalate and 20.1 weight percent poly(tetramethylene ether) terephthalate wherein the poly(tetramethylene ether) glycol used had a molecular
  • Such second layer is more hydrophobic and has a lower melting point, which helps adhesion.
  • the polyester fiberfill is preferably slickened.
  • the batts etc are preferably of density within the range of 0.5 to 1 pound per cubic foot (about 0.008 to 0.016gm/cu
  • the waterproof fiberfill composites have shown an advantage in their ability to avoid delamination upon stretching and flexing in use over an extended period, such as would be
  • Preferred hydrophilic copolyetherester elastomers are those hydrophilic elastomers more particularly described by Ostapchenko in U.S. Patent No. 4,725,481, the disclosure of which is also hereby specifically incorporated by
  • polyester fiberfill battings can be better bonded overall to such copolyetherester films, in the sense that the integrity of the interfacial bond stands up better in practice to repeated stretching and flexing.
  • a suitable batt of polyester fiberfill preferably has a low density up to about 0.5 to 1 lb/cu ft, but the density may be up to about 1.5, or even up to about 2 lb/cu ft (corresponding to about 0.008 to 0.016, up to about 0.025, or even about 0.03 gm/cu cm).
  • a batt of fiberfill is not so dense as most fabrics, much less dense even than a nonwoven lightweight scrim (a nonwoven lightweight scrim fabric of spun bonded polyethylene terephthalate such as was used in Example 1 of Ostapchenko Patent No. 4,725,481 being about 7 to 7.5 lb/cu ft, i.e. about 0.12 gm/cu cm, for example), and presents fewer contact points to a film.
  • a nonwoven lightweight scrim a nonwoven lightweight scrim fabric of spun bonded polyethylene terephthalate such as was used in Example 1 of Ostapchenko Patent No. 4,725,481 being about 7 to 7.5
  • the composite according to the invention provides an apparel material that combines both thermal insulation and a barrier to penetration by liquid (water) , while allowing water vapor to escape.
  • Preferred materials combine strength with good aesthetics.
  • the materials may be made easily by extrusion of the hot tacky film onto the batting or by a laminating process, such as has been used previously, whichever is desired.
  • a pre-formed film is laminated to the batting, it is possible to use a solvent- based adhesive, but a low melting adhesive is generally preferred, in the form of binder fibers, spot-adhesion or other technique of avoiding a continuous layer of adhesive bonding to the film.
  • the materials may be processed conventionally into garments or articles other than apparel, as desired. An important advantage over prior suggestions is the ability of the new composites to have their seams sealed ultrasonically.
  • the linear speed of extrusion was about 2 yards per minute, while the take-up rolls were about 15 times faster (30 yards per minute) , thereby reducing the film thickness to about 0.7 mil, by the time the film was coated on to the batting.
  • the first contact with the batting occurred at the- nip between the two take-up rolls; the lower roll preheated the batting as it carried it to meet the film; the upper (pressure) roll provided a means to drive the film and batting together while cooling the film to cause it to solidify.
  • the upper (pressure) roll provided a means to drive the film and batting together while cooling the film to cause it to solidify.
  • adequate adhesion was obtained with negligible loss in batting bulk when the roll carrying the batting was maintained at 80°C and the pressure/quench roll was maintained at 60°C.
  • Example 2 In Example 2, all conditions were the same as for Example 1 except that 4.5 ounce batting was used which required different temperatures for the first contact rolls. The temperature of the lower roll carrying the batting was 93°C, while the upper pressure roll was maintained at 60°C.
  • Example 3 film making was separated from lamination.
  • the coextruded film was prepared using a 2.5 inch (6.4 cm) diameter extruder to feed copolyetherester A and a 1.5 (3.8 cm)inch diameter extruder to feed copolyetherester B to a combining block to join the respective polymer melts in a laminar fashion prior to extrusion through a slit die.
  • the 1.5 inch diameter extruder was maintained at 215°C, and the 2.5 inch diameter screw was maintained at 205°C.
  • the die lip opening was set at 10 mils( 0.25 mm) and the die temperature was maintained at 215°C.
  • Coextruded film was produced at a rate of 18 yards (16.6 meters)/min to yield a final film thickness of 0.7 mil (0.018 mm).
  • the ratio of extruder speeds was maintained such that the thickness of copolymer (A) was 0.6 mils and that of copolymer (B) was 0.1 mils.
  • a 10 yard commercial sample of batting like in Example 2
  • the spacing between the belts was adjusted to avoid compression of the batting.
  • the film contacted the bottom belt and was arranged so that copolymer (B) faced the batting.
  • the adhesive nonwoven was a 0.63 oz/sq yd polyester fabric having a 135°C mp, available under the trade name "Spunfab Type PE204", and was placed between the film and the batting.
  • the sandwich was processed at about 7 yards (6.4 meters) per minute using a belt temperature of 150°C.
  • Example 4 all conditions for film making were the same as for Example 3.
  • a 10 yard commercial sample of batting was co-fed into the flat ⁇ bed laminating unit without the binder fiber webbing, and with the bilayer film.
  • "Bostik" 5178 Polyester powder was applied at a rate of about 0.5 oz/sq yd onto the film surface.
  • the sandwich was processed at about 7 yards (6.4 meters) per minute using a belt temperature of 150°C.
  • Griltex EMS 6D2-2 may be used as an adhesive powder, instead of the "Bostik" 5178 Polyester powder. It is not necessary to apply as much adhesive, and good adhesion has been obtained by applying as little as 0.25 oz/sq yd, it being understood that the precise amount may depend on various factors, such as are known in the art, e.g. type and pattern of application, intended use, aesthetics and materials selected.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Multicomponent Fibers (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

On peut fixer étonnamment bien un film en copolyétherester hydrophile imperméable ayant une vitesse élevée de transmission de vapeur d'eau, à un rouleau de nappe de garnissage fibreux en polyester, ce qui présente des avantages au niveau du traitement, et confère un meilleur confort à l'utilisateur lorsque le composite est utilisé dans des vêtements.
EP91901528A 1989-12-12 1990-12-07 Impermeabilisation amelioree de garnissage fibreux en polyester Withdrawn EP0505466A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US44961589A 1989-12-12 1989-12-12
US449615 1999-11-30

Publications (1)

Publication Number Publication Date
EP0505466A1 true EP0505466A1 (fr) 1992-09-30

Family

ID=23784827

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91901528A Withdrawn EP0505466A1 (fr) 1989-12-12 1990-12-07 Impermeabilisation amelioree de garnissage fibreux en polyester

Country Status (10)

Country Link
EP (1) EP0505466A1 (fr)
JP (1) JPH05502194A (fr)
KR (1) KR927003901A (fr)
CN (1) CN1054108A (fr)
AR (1) AR244362A1 (fr)
AU (1) AU6979791A (fr)
BR (1) BR9007909A (fr)
CA (1) CA2071202A1 (fr)
MA (1) MA22012A1 (fr)
WO (1) WO1991009166A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE9408097U1 (de) * 1994-05-17 1995-09-14 M. Faist GmbH & Co KG, 86381 Krumbach Schalldämmender Bauteil
DE69811573T2 (de) * 1997-07-31 2003-12-11 Teijin Ltd., Osaka Mehrschichtmaterial und damit hergestelltes Zelt
US6203872B1 (en) 1998-07-23 2001-03-20 Akzo Nobel Nv Waterproof and water vapour permeable lining
US7070841B2 (en) * 2001-04-11 2006-07-04 E. I. Du Pont De Nemours And Company Insulating label stock
CN105621340A (zh) * 2015-12-30 2016-06-01 3M创新有限公司 保温填充材料及其制备方法、保温制品
CN108754868B (zh) * 2018-06-14 2022-01-14 3M创新有限公司 保温絮片材料、其制备方法及保温制品
US20210164140A1 (en) * 2018-06-14 2021-06-03 3M Innovative Properties Company Thermal insulation flocculus material, preparation method thereof, and thermal insulation article
DE102018123447A1 (de) * 2018-09-24 2020-03-26 Carl Freudenberg Kg Verwendung eines Vliesstoffs zur Herstellung eines Walkfutters

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4304817A (en) * 1979-02-28 1981-12-08 E. I. Dupont De Nemours & Company Polyester fiberfill blends
US4725481A (en) * 1986-10-31 1988-02-16 E. I. Du Pont De Nemours And Company Vapor-permeable, waterproof bicomponent structure

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9109166A1 *

Also Published As

Publication number Publication date
BR9007909A (pt) 1992-09-15
AU6979791A (en) 1991-07-18
CN1054108A (zh) 1991-08-28
JPH05502194A (ja) 1993-04-22
MA22012A1 (fr) 1991-07-01
CA2071202A1 (fr) 1991-06-13
WO1991009166A1 (fr) 1991-06-27
KR927003901A (ko) 1992-12-18
AR244362A1 (es) 1993-10-29

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