EP0496843A1 - Persulphate-containing preparation in granulate form, 2-part agent and process for bleaching and lightening hair - Google Patents
Persulphate-containing preparation in granulate form, 2-part agent and process for bleaching and lightening hairInfo
- Publication number
- EP0496843A1 EP0496843A1 EP91910553A EP91910553A EP0496843A1 EP 0496843 A1 EP0496843 A1 EP 0496843A1 EP 91910553 A EP91910553 A EP 91910553A EP 91910553 A EP91910553 A EP 91910553A EP 0496843 A1 EP0496843 A1 EP 0496843A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- preparation according
- persulfate
- preparation
- percent
- granules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0275—Containing agglomerated particulates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
Definitions
- Oxidizing preparations are used to decolorize and bleach hair. These usually consist, on the one hand, of a bleaching powder (powder mixture of inorganic persalts, such as, for example, sodium or ammonium persulfate, with alkali salts) and, on the other hand, of an aqueous hydrogen peroxide solution.
- a bleaching powder powder mixture of inorganic persalts, such as, for example, sodium or ammonium persulfate, with alkali salts
- an aqueous hydrogen peroxide solution aqueous hydrogen peroxide solution.
- the bleaching powder is stirred with the aqueous hydrogen peroxide solution, an applicable, non-draining cream or paste being obtained due to the thickening additives contained.
- the formulations In order to develop a sufficient bleaching effect, the formulations must have a pH which is between 8 and 11.5, preferably between 9 and 10
- the bleaching powder contains a larger proportion of alkaline alkali salts, such as. B. sodium carbonate or sodium silicate.
- alkali salts When bleaching powder and peroxide solution are mixed, the alkali salts firstly adjust the pH to the desired range, and secondly ammonia is released from the ammonium salts contained in the formulation, which causes swelling of the hair and thus an intensification of the bleaching effect.
- Demixing can be largely avoided by using powder mixtures with a very small grain size.
- these fine powders have the disadvantage that they tend to develop dust very easily.
- the development of dust occurs especially when the containers are opened, but to an even greater extent when the required amount is removed, which is usually done using a measuring spoon, and also when the ready-to-use formulation is mixed.
- the release of a fine dust can, especially through the used Persulfates, irritate the respiratory system.
- the powder mixtures due to the small size of the particles, the powder mixtures have a large surface area, which can lead to a higher absorption of moisture when opening and closing the containers and to a deactivation of the bleaching effect.
- DE-OS 20 23 922 recommends converting the constituents of the powder mixture into granules using a water-soluble polymer. As described there, this process results in a loss of ammonia when using aqueous solvents for the polymer. In order to compensate for this loss, it is recommended to increase the content of ammonium salts in the powder mixture.
- the ammonia loss in the industrial production of the granules described there is very difficult to keep constant, so that granules produced by this process fluctuate in chemical composition.
- the preparation in solid form can either consist exclusively of the persulfate granules or, in addition to the persulfate granules, other substances in solid form, e.g. B. as a powder or granules.
- the preparation according to the invention preferably consists of a mixture of the persulfate granules with granules of the other solid substances present, in particular the alkaline alkali or alkaline earth salts, the diameter of the granule particles of the granule mixture preferably being approximately the same size.
- the persulfate is present in the preparation in an amount of 30 to 65 percent by weight, preferably 40 to 60 percent by weight.
- the persulphate granules can be prepared by adding aqueous solutions of the persulphates, which also include additions of wetting agents, emulsifiers or water-soluble Thickeners can be converted into a solid form by spray drying or also in that the persulfates in solid form by spraying with an aqueous solution of wetting agents, emulsifiers or thickeners, for. B. can be granulated by the "rolling drum method". The water content is then adjusted to below 2% by weight, preferably below 1% by weight, by subsequent drying.
- the diameter of the granulate particles contained in the present preparation should be 0.1 to 0.6 cm, preferably 0.2 to 0.4 cm.
- the preparation preferably further contains alkaline alkali or alkaline earth metal salts, e.g. B. sodium silicate, sodium carbonate, sodium hydrogen carbonate or magnesium carbonate, in particular in a total concentration of 15 to 45 percent by weight, preferably 25 to 40 percent by weight, based on the total amount of the preparation. You can also chelating reagents for heavy metal ions such. B. salts of ethylenediamine-tetraacetic acid, in a concentration of 0.1 to 3 percent by weight, preferably 0.5 to 1.5 percent by weight, and dyes from the classes of ultramarine dyes or acid dyes in concentrations of up to 1 percent by weight.
- B. salts of ethylenediamine-tetraacetic acid in a concentration of 0.1 to 3 percent by weight, preferably 0.5 to 1.5 percent by weight, and dyes from the classes of ultramarine dyes or acid dyes in concentrations of up to 1 percent by weight.
- the substances mentioned above can be contained in the preparation either in commercial form as a powder or as granules, wherein the granules can be present as a mixture of granules of the individual substances or as granules of the finished mixture. These granules are produced in accordance with the manufacture of the persulfate granules, although further auxiliaries such as wetting agents, emulsifiers or water-soluble thickeners may also be present here.
- Suitable wetting agents or emulsifiers are substances from the classes of anionic, cationic or nonionic surface-active substances, such as.
- Suitable water-soluble thickeners are in particular cellulose ethers, e.g. As methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose or carboxymethyl cellulose, starches such as. B. corn starch, starch ether such. As carboxymethyl starch, hydroxy staryl starch or methyl starch, furthermore, thickeners such as guar gum, xanthan gum or algi- -4-
- the total concentration of the water-soluble thickeners is 0.1 to 15 percent by weight, preferably 1 to 10 percent by weight
- the persulfate granulate has sufficient abrasion resistance so that dust development during storage, removal and use is avoided.
- the separate use of granules of the persulfates and the other ingredients has the further advantage that, depending on the mixing ratio, products with different persulfate content can be produced, which also enable a differentiated degree of brightening.
- the segregation can be avoided by an appropriate choice of the grain size of the granules in question or by setting a specific bulk density.
- the invention further relates to an agent for bleaching and bleaching hair, comprising two components, the first component (A) being in solid form and containing an inorganic persulfate and the second component (B) an aqueous solution containing 4 is up to 18 percent by volume hydrogen peroxide, characterized in that component (A) is a preparation described above in which the persulfate is in the form of granules
- the agent according to the invention is used by immediately prior to use of an amount sufficient for hair bleaching, preferably 20 g to 40 g, in particular 30 g, of component (A) with component (B), the hydrogen peroxide content of which is 4 to 18 Volume percent, preferably 6 to 12 volume percent, in a weight ratio of 2: 1 to 1: 3, preferably 1: 1.5 to 1: 2, stirred in a dish.
- an amount sufficient for hair bleaching preferably 20 g to 40 g, in particular 30 g, of component (A) with component (B), the hydrogen peroxide content of which is 4 to 18 Volume percent, preferably 6 to 12 volume percent, in a weight ratio of 2: 1 to 1: 3, preferably 1: 1.5 to 1: 2, stirred in a dish.
- thickeners in component (A) thickened Blondie mass obtained, which can be easily applied to the hair without running off during the exposure time.
- the invention therefore furthermore relates to a process for decolorizing and blonding hair, in particular human hair, in which 20 to 40 g, preferably 30 g, of a preparation in solid form containing an inorganic persulfate are used immediately before use an aqueous solution containing 4 to 18 percent by volume of hydrogen peroxide, mixed in a weight ratio of 2: 1 to 1: 3, preferably 1: 1.5 to 1: 2, the mixture is applied to the hair, left to act for 15 to 60 minutes and then rinsed with water, characterized in that the preparation in solid form used is a preparation described above in which the persulfate is in the form of granules
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Une composition sert à préparer un agent de décoloration et d'éclaircissement des cheveux se présentant sous forme solide. On utilise à cet effet des mélanges de granulés contenant les ingrédients individuels ou au moins des persulfates granulés. La granulation peut se faire par un procédé technique usuel, par exemple séchage par pulvérisation, des agents de réticulation, des émulsifiants ou des épaississants pouvant être ajoutés aux substances de départ avant la granulation. La composition décrite se caractérise par une longue durée de conservation et n'a pas les inconvénients des compositions usuelles d'agents d'oxygénation, tels que la dissociation des composants ou des variations de la composition chimique entraînées par une perte d'ammoniac. L'invention concerne en outre un agent à deux composants et un procédé de décoloration et d'éclaircissement des cheveux au moyen de la composition susmentionnée.A composition is for preparing a hair bleaching and lightening agent in solid form. Granulated mixtures containing the individual ingredients or at least granulated persulphates are used for this purpose. The granulation can be carried out by a customary technical process, for example spray drying, crosslinking agents, emulsifiers or thickeners which can be added to the starting substances before the granulation. The described composition is characterized by a long shelf life and does not have the disadvantages of conventional oxygenating agent compositions, such as dissociation of components or variations in chemical composition caused by loss of ammonia. The invention further relates to a two-component agent and method for bleaching and lightening hair using the aforementioned composition.
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4026235A DE4026235A1 (en) | 1990-08-18 | 1990-08-18 | PREPARATION CONTAINING PERSULPHATE IN THE FORM OF A GRANULATE, 2-COMPONENT AGENT, AND METHOD FOR DETOLIATING AND BLONDING HAIR |
DE4026235 | 1990-08-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0496843A1 true EP0496843A1 (en) | 1992-08-05 |
Family
ID=6412521
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91910553A Withdrawn EP0496843A1 (en) | 1990-08-18 | 1991-06-06 | Persulphate-containing preparation in granulate form, 2-part agent and process for bleaching and lightening hair |
Country Status (6)
Country | Link |
---|---|
US (1) | US5279313A (en) |
EP (1) | EP0496843A1 (en) |
BR (1) | BR9105878A (en) |
DE (1) | DE4026235A1 (en) |
ES (1) | ES2042467T1 (en) |
WO (1) | WO1992003120A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5482704A (en) * | 1994-06-28 | 1996-01-09 | National Starch And Chemical Investment Holding Corporation | Cosmetic compositions containing amino-multicarboxylate modified starch |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4207475A1 (en) * | 1992-03-10 | 1993-09-16 | Goldwell Ag | MEDIUM FOR BLONDING HUMAN HAIR AND METHOD FOR THE PRODUCTION THEREOF |
DE4217920C2 (en) * | 1992-05-30 | 1996-05-09 | Goldwell Gmbh | Process for the preparation of powdered preparations for bleaching human hair |
CA2103683C (en) * | 1992-08-17 | 1998-06-16 | George Weeks | Methods of controlling dust and compositions produced thereby |
DE4233874C2 (en) * | 1992-10-08 | 1996-05-30 | Schwarzkopf Gmbh Hans | Hair dye based on powdered direct dyes in the form of a granulate and process for its production |
FR2703588B1 (en) * | 1993-04-05 | 1995-06-23 | Oreal | GRANULATED COMPOSITION BASED ON PEROXIDE DERIVATIVES USEFUL FOR THE DISCOLORATION OF HAIR AND PROCESS FOR PREPARING THE SAME. |
FR2703589B1 (en) * | 1993-04-05 | 1995-05-19 | Oreal | Bleaching composition in granulated form usable for bleaching hair and process for the preparation of said composition. |
DE4320508A1 (en) * | 1993-06-21 | 1994-12-22 | Hoechst Ag | Thickener combinations of macro surfactants and organic additives for aqueous application systems |
ATE125692T1 (en) | 1993-06-25 | 1995-08-15 | Goldwell Gmbh | AGENTS FOR DYING AND BLONDERING HUMAN HAIR AND METHOD FOR THE PRODUCTION THEREOF. |
DE4337178A1 (en) * | 1993-10-30 | 1995-05-04 | Wella Ag | Process for the production of a persulfate-containing granulate for decolourising or bleaching hair |
FR2715065B1 (en) * | 1994-01-14 | 1996-04-26 | Oreal | Cosmetic compositions for bleaching hair, method of synthesis and use. |
DE4430391A1 (en) * | 1994-08-26 | 1996-02-29 | Eilenburger Elektrolyse & Umwelttechnik Gmbh | Preferential oxidn. of harmful matter esp. organic halide in soln. |
DE19545853A1 (en) * | 1995-12-08 | 1997-06-12 | Wella Ag | Hair bleaching preparations |
DE19548132A1 (en) † | 1995-12-21 | 1997-06-26 | Henkel Kgaa | Bleaching agents |
DE19627498A1 (en) | 1996-07-08 | 1998-01-15 | Nat Starch Chem Invest | Starchy cleaning and care products |
WO1999060993A1 (en) * | 1998-05-29 | 1999-12-02 | Carson Products Company | Compositions and methods for removing the color from permanently dyed keratin fibers |
FR2788976B1 (en) * | 1999-01-29 | 2003-05-30 | Oreal | KERATIN FIBER DECOLORING ANHYDROUS COMPOSITION COMPRISING THE ASSOCIATION OF A WATER-SOLUBLE THICKENING POLYMER AND A NON-IONIC AMPHIPHILIC POLYMER COMPRISING AT LEAST ONE FAT CHAIN |
DE19909661A1 (en) * | 1999-03-05 | 2000-09-07 | Wella Ag | Means for decolourising or bleaching hair |
WO2000076469A1 (en) * | 1999-06-15 | 2000-12-21 | Revlon Consumer Products Corporation | One step method and compositions for simultaneously coloring and highlighting hair |
DE19927075C1 (en) | 1999-06-15 | 2001-07-19 | Cognis Deutschland Gmbh | Process for the permanent deformation of keratin fibers and the use of alkoxylated carboxylic acid esters and partial glycerides for the production of corrugating and fixing agents |
US20010007277A1 (en) * | 1999-09-28 | 2001-07-12 | Peter Gordon Jobling | Process and compositions for repulping paper |
HUP0204268A2 (en) | 2000-01-19 | 2003-04-28 | Artec Systems Group, Inc. | One-step bleach and coloring composition for hair and method of using same |
KR100366757B1 (en) * | 2000-12-12 | 2003-01-09 | 주식회사 비봉파인 | Permanent hair colorant without irritating to sensitive skin |
GB2386068A (en) * | 2001-03-20 | 2003-09-10 | Procter & Gamble | Oxidative treatment of hair with reduced hair damage |
DE10153686A1 (en) | 2001-10-31 | 2003-05-15 | Wella Ag | Means for decolourising or bleaching hair |
US20040098814A1 (en) * | 2002-11-27 | 2004-05-27 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method and composition for the gradual permanent coloring of hair which employ carbonates |
EP1713434A4 (en) * | 2004-01-29 | 2009-01-07 | Avlon Ind Inc | Conditioning hair lightener system, compositions, method and kit therefor |
US7098175B2 (en) * | 2004-06-08 | 2006-08-29 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Aqueous detergent composition containing ethoxylated fatty acid di-ester |
US7205268B2 (en) * | 2005-02-04 | 2007-04-17 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Low-foaming liquid laundry detergent |
US7291582B2 (en) * | 2005-09-20 | 2007-11-06 | Conopco, Inc., D/B/A Unilever | Liquid laundry detergent with an alkoxylated ester surfactant |
US8573232B2 (en) * | 2006-10-09 | 2013-11-05 | The Procter & Gamble Company | Hair treatment application system comprising an absorbent substrate |
DE602007013991D1 (en) * | 2006-10-09 | 2011-06-01 | Procter & Gamble | Hair trimming applicator and procedure |
US20080083420A1 (en) * | 2006-10-09 | 2008-04-10 | The Procter & Gamble Company | Hair treatment application system |
US20080152609A1 (en) * | 2006-12-08 | 2008-06-26 | John Jacob Wille | Suppression of sulfer fumes by higher boiling point oils |
EP1969961B1 (en) | 2007-03-13 | 2014-07-23 | The Procter and Gamble Company | A tool for separating a hair bundle |
WO2008152571A1 (en) * | 2007-06-15 | 2008-12-18 | The Procter & Gamble Company | Applicator for a hair treatment composition |
AU2008263455A1 (en) * | 2007-06-15 | 2008-12-18 | The Procter & Gamble Company | A system for highlighting hair |
CA2691365C (en) | 2007-06-15 | 2012-10-16 | The Procter & Gamble Company | Device for the application of a hair treatment composition to a hair bundle |
JP5276095B2 (en) * | 2007-06-15 | 2013-08-28 | ザ プロクター アンド ギャンブル カンパニー | Hair treatment applicator for providing benefits to hair strands |
MX2009013694A (en) | 2007-06-15 | 2010-07-30 | Procter & Gamble | Applicator for applying a hair treatment composition to a bundle of hair strands. |
EP2070833B1 (en) * | 2007-12-14 | 2011-02-23 | The Procter & Gamble Company | Container with a device to prevent clogging of a dispensing device of the container |
CN101842499B (en) * | 2007-12-19 | 2014-12-03 | 克拉里安特国际有限公司 | Retanning and fatliquoring agent for leather |
EP2198739B1 (en) * | 2008-12-10 | 2016-06-01 | The Procter and Gamble Company | Applicator for improved application of a hair treatment composition to a bundle of hair strands |
EP2196104B1 (en) * | 2008-12-10 | 2018-10-17 | Noxell Corporation | Applicator of a hair treatment composition for improved hair strand effects |
EP2198738B1 (en) * | 2008-12-10 | 2018-09-05 | Noxell Corporation | Hair treatment applicator for improved hair strand effects |
FR2975291B1 (en) * | 2011-05-20 | 2013-11-08 | Oreal | KERATIN FIBER DECOLORATION COMPOSITION IN THE FORM OF TABLET WITH PERSULFATE AND AMMONIUM SALT |
FR2975290B1 (en) * | 2011-05-20 | 2013-08-09 | Oreal | DECAYING COMPOSITION OF KERATIN FIBERS IN THE FORM OF TABLET WITH PERSULFATE AND A PARTICULAR POLYMER |
FR2975289B1 (en) * | 2011-05-20 | 2013-08-09 | Oreal | TABLET KERATIN FIBER DECOLORATION COMPOSITION WITH PERSULFATE AND WATER SOLUBLE SILICATE |
WO2012159929A2 (en) * | 2011-05-20 | 2012-11-29 | L'oreal | Process for bleaching keratin fibres comprising the application of a composition in compressed form |
FR2975288B1 (en) * | 2011-05-20 | 2013-11-08 | Oreal | KERATIN FIBER DECOLORATION PROCESS COMPRISING THE APPLICATION OF A TABLET COMPOSITION |
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US5077040A (en) * | 1990-04-30 | 1991-12-31 | Helene Curtis, Inc. | Hair-treating microemulsion composition and method of preparing and using the same |
-
1990
- 1990-08-18 DE DE4026235A patent/DE4026235A1/en not_active Withdrawn
-
1991
- 1991-06-06 EP EP91910553A patent/EP0496843A1/en not_active Withdrawn
- 1991-06-06 US US07/777,544 patent/US5279313A/en not_active Expired - Fee Related
- 1991-06-06 ES ES91910553T patent/ES2042467T1/en active Pending
- 1991-06-06 BR BR919105878A patent/BR9105878A/en not_active Application Discontinuation
- 1991-06-06 WO PCT/EP1991/001042 patent/WO1992003120A1/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO9203120A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5482704A (en) * | 1994-06-28 | 1996-01-09 | National Starch And Chemical Investment Holding Corporation | Cosmetic compositions containing amino-multicarboxylate modified starch |
Also Published As
Publication number | Publication date |
---|---|
WO1992003120A1 (en) | 1992-03-05 |
DE4026235A1 (en) | 1992-02-20 |
ES2042467T1 (en) | 1993-12-16 |
BR9105878A (en) | 1992-11-17 |
US5279313A (en) | 1994-01-18 |
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