EP0448773A2 - Stranggussform und Stranggussverfahren - Google Patents

Stranggussform und Stranggussverfahren Download PDF

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Publication number
EP0448773A2
EP0448773A2 EP90116077A EP90116077A EP0448773A2 EP 0448773 A2 EP0448773 A2 EP 0448773A2 EP 90116077 A EP90116077 A EP 90116077A EP 90116077 A EP90116077 A EP 90116077A EP 0448773 A2 EP0448773 A2 EP 0448773A2
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EP
European Patent Office
Prior art keywords
mold
molten metal
continuous
ceramics
lining
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Granted
Application number
EP90116077A
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English (en)
French (fr)
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EP0448773A3 (en
EP0448773B1 (de
Inventor
Chiyokatsu C/O Nippon Steel Corp. Hamaguchi
Tomoharu C/O Nippon Steel Corp. Shimokasa
Kazumi C/O Nippon Steel Corp. Daitoku
Fujiya C/O Nippon Steel Corp. Nogami
Kazuya C/O Nippon Steel Corp. Kudo
Kazumi C/O Nippon Steel Corp. Seki
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Nippon Steel Corp
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Nippon Steel Corp
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Priority claimed from JP8353090A external-priority patent/JPH03285741A/ja
Priority claimed from JP17028990A external-priority patent/JPH0459153A/ja
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Publication of EP0448773A2 publication Critical patent/EP0448773A2/de
Publication of EP0448773A3 publication Critical patent/EP0448773A3/en
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Publication of EP0448773B1 publication Critical patent/EP0448773B1/de
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/0401—Moulds provided with a feed head
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/059—Mould materials or platings

Definitions

  • This invention relates to molds of curved, vertical and horizontal continuous casters for casting slabs, blooms and billets and continuous casting processes using said molds, and more particularly to molds and continuous casting processes that prevent the occurrence of breakout and produce very clean castings free of oscillation marks, surface and other defects.
  • Fig. 1 shows how a solidifying shell is formed and grows.
  • Molten metal 5 is poured into a mold 1 where cooling water passed through cooling water piping 4 contained in the mold cools the molten metal by removing heat therefrom.
  • a solidifying shell 7 is formed and grows where the metal contacts the inner wall of the mold 1.
  • a powder 18 sprinkled over the molten metal 5 protects its surface from an oxidizing atmosphere. Infiltrating between the inner wall of the mold 1 and the solidifying shell 7 as a part of slag 19, the powder 18 serves as a lubricant to prevent the sticking of the solidifying shell 7.
  • the shell 7 solidifies and contracts as it descends through the mold 1 while forming localized air gaps between itself and the inner wall of the mold as a result of the bulging of the shell 7 caused by the recuperative action thereof until the leaving of a cast product therefrom.
  • the mold 1 When the powder 18 is used in continuous casting, the mold 1 is oscillated so that the powder 18 is fed along the inner wall of the mold 1. But this oscillation leaves oscillation marks on the solidifying shell 7 and causes other surface defects by entrapping the powder 18 therein.
  • molds 1 proposed in Japanese Provisional Patent Publications Nos. 173061 of 1983 and 195742 of 1986 have such materials affixed from the upper end to the lower end or middle thereof, including the point where solidification of molten metal starts, with a view to slowly cooling the molten metal 5 or the solidifying shell 7.
  • Japanese Provisional Patent Publication No. 13445 of 1983 proposes a mold 1 which has such wear-resistant materials as ceramics and stainless steel affixed to the inner wall thereof, including the vicinity of the lower and thereof, in order to prolong the mold life.
  • Japanese Provisional Patent Publication No. 93474 of 1989 discloses a method in which a layer of fine particles or fine powder of substances, which are strongly reactive and adhesive to ceramics and the substance to which the ceramics are affixed and whose particle size is smaller than the roughness of the surfaces to be joined together, and whose thickness is larger than the surface roughness, is inserted between them, with adhesion accomplished by subsequent application of pressure and heat.
  • Japanese Provisional Patent Publication No. 120579 of 1983 discloses a method of joining such inorganic substances as ceramics and glass to such metals as platinum and copper. In this method, a paste containing 20 to 80 percent by weight of a powder of the inorganic material and 80 to 20 percent by weight of a powder of the metal to be joined together is applied to both materials which are then joined together by the application of heat.
  • An object of this invention is to permit the production of high-quality castings by lining the inner wall of the mold with pieces of ceramics that function like a solid lubricant, with the thickness thereof varied in the direction in which the castings are withdrawn or in that direction and breadthwise, thereby eliminating the need of using lubricating powders.
  • Another object of this invention is to provide long-life ceramics-lined continuous-caster molds that are free from the lowering of adhesive strength, thermal stress absorption ability and heat conductivity that might occur when the ceramics-bonding adhesives used with conventional molds are heated.
  • continuous-caster molds comprise inner walls of copper or copper alloys or inner walls of copper sprayed, plated or otherwise covered with other materials that are lined with ceramics whose thickness is varied either stepwise or progressively.
  • the thickness of lining is varied to prevent the formation of air gaps between the surface of the lining and the solidifying shell and cool the steel being case according to the desired pattern, and/or to start solidification of the molten metal below the molten metal surface level.
  • Friction in continuous-casting processes can be reduced by designing the uppermost ceramics lining, which comes in contact with the molten metal surface, so that solification of the molten metal starts below the molten metal surace, with the inner wall of the mold tapered by considering the static pressure of the molten metal between the molten metal surface and the point of solidification.
  • the molten metal and solidifying shell are slowly cooled, with the sticking of the solidifying shell to the mold wall reduced.
  • the friction-free continuous-caster mold according to this invention permits making castings of excellent surface quality without employing mold powders and mold oscillation. Because solidification starts below the molten metal surface, the solidifying shell is free of defects that have conventionally resulted from the surface level changes at the point where solidification begins. As such, casting can be performed with the mold directly connected to a tundish.
  • This invention also provides a mold lined with ceramics whose thickness is varied in the direction of casting and also made variable breadthwise (the direction perpendicular to the casting direction) and a continuous casting process that assures solidification of the molten metal to start at the same level throughout the entire periphery of the mold and also uniform cooling even in the corners of the mold by use of the mold just described.
  • This invention furthermore provides a mold having a continued internally curved heat-insulating zone and cooling zone in the upper part thereof and a continuous casting process that withdraws the shell formed by initial solidification of the molten metal with reduced friction by use of the mold just described.
  • the ceramics are bonded to the inner wall of the continuous-caster mold of this invention with organic adhesives mixed with metal powder or metal fibers. Also, the ceramics are affixed to the inner wall of the continuous-caster mold of this invention with organic adhesives, with metal wire netting interposed therebetween.
  • the organic adhesives used with the molds of this invention are of epoxy, silicone, phenol and other similar resins that withstand the heat of from 70 to 260 °C.
  • surface irregularities are provided on the surface of the molds of copper or copper alloys that are bonded to the ceramics with organic adhesives or those mixed with metals, with the projecting portions of the irregularities held in contact with or in the vicinity of the ceramics.
  • the ceramics lining securely affixed to the inner wall of the continuous-caster molds of this invention gives longer service life, their excellent heat extraction characteristic permits high-speed casting just like the conventional molds.
  • the ceramics lined over the mold wall provide self-lubrication.
  • Fig. 1 shows the condition of metal being cast through a conventional continuous-caster mold.
  • Fig. 2 is a vertical cross-sectional view showing a continuous-caster mold according to this invention.
  • Fig. 3 graphically shows how the heat extraction through the mold shown in Fig. 2 changes along the direction of casting, compared with that of a conventional mold.
  • Fig. 4 is a partial vertical cross-sectional view of a mold according to this invention showing a curved portion of the inner wall thereof.
  • Fig. 5 graphically shows the relationship between the ferrostatic pressure of molten steel and the mold taper.
  • Figs. 6 (a) and (b) are perspective views showing the conditions of ceramics affixed to the inner wall of copper molds.
  • Fig. 7 shows the tolerable smoothness of the bonded area.
  • Fig. 8 is a vertical cross-sectional view showing a continuous-caster mold lined with pieces of ceramics.
  • Figs. 9 (a) and (b) are vertical cross-sectional views showing continuous-caster molds directly connected to a tundish viewed from the broad mold face side and the narrow mold face side, respectively.
  • Fig. 10 graphically compares the thickness of the solidifying shell formed in a mold of this invention to the one in a conventional mold.
  • Fig. 11 is a partial cross-sectional view of a continuous-caster mold according to this invention.
  • Fig. 12 is a partial cross-sectional view of a continuous-caster mold according to this invention, in which copper plates having surface irregularities are used in place of the wire netting used in the embodiment shown in Fig. 11.
  • Figs. 13 and 14 schematically illustrate the cross-sectional configuration and the planar appearance of the bonding layers shown in Table 4.
  • Fig. 15 is a schematic cross-sectional view of a bonding layer formed with an organic adhesive mixed with metal powder.
  • Figs. 16 (a), (b) and (c) graphically show the relationships between the ratio of the cross-sectional area occupied by metal. the shear stress (P) and the index of heat conductivity ( ⁇ ).
  • Fig. 2 shows a continuous-caster mold 1 according to this invention which has an inner wall 2 fabricated from copper having good heat conductivity and a cooling box 3 provided therebehind.
  • the cooling box 3 incorporates cooling water passages 4 to pass cooling water that cools and solidifies the molten metal 5 poured into the mold 1.
  • To the inner wall 2 are affixed ceramics tiles 6b to 6d whose thickness is varied in the direction in which the metal being cast is withdrawn, which is indicated by arrow P, thus making up an inner lining 6. Ceramics blocks 6a having a greater thickness than the tiles are provided on top of the tiles and the inner wall 2 to serve as a heat-insulating layer.
  • the inner wall 2 may also be either made of either a copper alloy or covered with a layer of an alloy of chromium, nickel or other metals.
  • the ceramics are made from such materials as boron nitride (BN) and silicon nitride (Si3N4) that have resistance to abrasive wear, heat and thermal shock, heat conductivity and lubricating property. Lining the inner wall 2 with the ceramics tiles 6b and 6d prevents the sticking of the solidifying shell 7, which forms when the molten metal 5 freezes, to the surface of the inner wall 2 or the risk of more serious breakouts in which the inner molten metal flows out through the ruptured shell 7. Elimination of the need of using lubricating powders between the inner wall and the solidifying shell 7 prevents the entrapment of powders due to molten -metal level variations and the occurrence of other surface defects. Although lubricating powders are unnecessary in operation, a molten -metal surface heat insulator 17 is used to provide the heat insulation and the maintenance of temperature required by the molten metal 5 poured from a pouring nozzle 16.
  • the ceramics tiles 6b to 6d affixed to the inner wall 2 are so smooth-surfaced that the castings are withdrawn smoothly. Consequently, the cast products have smooth, defect-free surfaces.
  • the ceramic tiles 6b to 6d affixed to the inner side of the inner wall 2 keep the molten metal 5 out of direct contact with the inner wall 2, while serving as a heat-insulating layer that permits the molten metal 5 or the solidifying shell 7 to cool slowly. Therefore, the shrinkage the solidifying shell 7 has undergone in the mold 1 is made up for by creep. Protected from rapid cooling and solidification, the solidifying shell 7 does not shrink to such an extent as to form air gaps. This results in a solidified shell of uniform thickness which, in turn, permits high-speed withdrawing.
  • the amount of heat transfer through the inner wall of the continuous-caster mold 1 lined with the ceramics tiles 6b to 6d changes in the casting direction P. Heat extraction at the top of the mold 1 where the thick ceramics blocks 6a are provided is practically negligible. Heat extraction can be varied by changing the thickness of the ceramics 6a to 6d according to the requirement of individual operations.
  • Curve (a) in Fig. 3 shows a heat extraction curve for a plain carbon steel that is attained by changing the thickness of the ceramics liners 6a to 6d is changed so that the amount of heat extraction decreases progressively from the peak in the initial solidifying stage.
  • This heat extraction pattern is equivalent to the most common one in the conventional continuous casting with mold powders.
  • Curve (b) shows a heat extraction pattern for steels that are cast at slow speed with slow cooling, such as chromium-bearing stainless steels and some other alloy steels.
  • the thickness of the ceramics liners 6a to 6d is reduced in that order to provide increasingly greater heat extraction downward.
  • Curve (c) shows a uniform heat extraction pattern that has proved effective for high-speed casting with slow cooling. The pattern according to curve (c) is obtained by varying the thickness of the ceramics tiles 6b to 6d downward from the top end of the mold so that uniform heat extraction is achieved throughout.
  • solidification of the molten metal 5 poured into the continuous-caster mold 1 begins at a solidification starting point 9 below the molten metal surface 8.
  • the solidification starting point 9 should be at least 30 mm below the molten metal surface 8. If the distance is less than 30 mm, the molten metal may entrap the heat-insulating mold powder sprinkled over the surface of the molten metal. Also, the influence of the variation in the molten metal surface may make it difficult to achieve the solidification below the meniscus level, which leads to the formation of a defective solidifying shell containing layers mixed with the heat-insulating mold powder and containing high percentages of floating non-metallic inclusions.
  • the formed shell 7 has a stable surface quality without being influenced by surface level variations.
  • casting operation should be carried out with a suitable heat extraction pattern and a corresponding lining taper that will provide the desired solidification and contraction for each individual type of steel.
  • the thickness of the solidifying shell 7 increases progressively as the rate of heat extraction changes through the continuous-caster mold 1 in the casting direction P, whereby the solidifying shell 7 is always in contact with the inner surface of the mold.
  • powder feed is not always uniform but sometimes becomes interrupted, with the resulting localized heavy cooling causing the shrinkage of the solidifying shell and forming air gaps. This tendency becomes more pronounced toward the lower end of the continuous-caster mold 1.
  • the mold of this invention by contrast, always provides such an ideal condition similar to the one obtained in a uniformly powdered conventional mold that the solidifying shell 7 is kept out of direct contact with the inner wall 2 and, therefore, always fits the inner profile of the mold.
  • the thickness of the ceramics is increased in the upper part of the continuous-caster mold 1 that is exposed to high temperatures and decreased in the lower part where the surface temperature remains relatively lower.
  • This arrangement permits keeping the temperature on the mold wall side of the ceramic tiles 6b to 6d at a relatively low level. As a consequence, the adhesive that bonds together the inner wall 2 and the ceramic tiles 6b to 6d is not exposed to high temperatures that might cause its deterioration.
  • Heat extraction in the conventional mold changes as indicated by S-shaped curve A in Fig. 3 because of the formation of air gaps.
  • the molten metal 5 is cooled immediately below the molten metal surface 8, forming a solidifying shell 7.
  • the solidifying shell 7 that forms and grows too rapidly tends to form an air gap between itself and the inner wall of the continuous-caster mold 1 as illustrated in Fig. 1. This results in a sharp reduction in heat extraction.
  • the air gap can be made smaller by increasing the withdrawal speed of the casting, but the withdrawal speed should not be increased beyond a certain limit because of the risk of breaking the powder film and increasing the frictional resistance.
  • the molten metal 5 and the solidifying shell 7 are slowly cooled, which results in castings having good surface quality. Because the ceramics tiles 6b to 6d allow the solidifying shell 7 to move forward smoothly, the casting is smoothly withdrawn from the continuous-caster mold 1 without using any powder or other lubricants.
  • the obtained castings are free of surface defects that might result from the entrapment of powders and oscillation marks. Very clean castings having stable surface properties can be obtained because the formation of the solidifying shell 7 begins at a point below the molten metal surface 8 that is unaffected by any changes at the surface level.
  • the ceramics block 6a mounted on top Of the continuous-caster mold 1 and the ceramics tiles 6b to 6d lined over the inner wall 2 are fastened as shown in Fig. 2.
  • the uppermost ceramics block 6a is pressed against the top surface of the inner wall 2 by means of a clamp 10.
  • the ceramics tiles 6b to 6d are bonded to the front surface of the inner wall 2 with a ceramics-type adhesive 11.
  • this risk can be avoided by providing steps on the inner wall 2 to support the lower ends of the ceramics tiles 6b to 6d as illustrated.
  • the molten metal superheated to a temperature 20 to 50 °C above the liquidus temperature is usually poured into the mold at a temperature 5 to 30 °C above the liquidus temperature.
  • the ceramics block 6a on top of the continuous-caster mold 1 functions as a heat-insulating layer that prevents the escape of heat from the molten metal so that the solidification thereof begins below the molten metal surface.
  • the heat-insulating layer of the ceramics block 6a should preferably have a thickness of 30 to 300 mm, though this value varies with the heat conductivity of the ceramics.
  • the casting having a square cross section like a bloom is cooled more strongly in the proximity of the corners of the mold than elsewhere.
  • the air gap resulting from over-cooling can be prevented by using thicker ceramics at the corners of the mold than in the middle portion thereof.
  • the casting having a rectangular cross section like a slab is cooled more strongly in the proximity of the ends of the broad face (close to the narrow face) of the mold than in the middle thereof.
  • solidification starts at different depths below the molten metal surface along the broad face of the mold.
  • this irregularity in the starting point of solidification can be smoothed out around the periphery of the mold by using thicker ceramics in the proximity of the ends of the broad face than in the middle portion thereof as in the case of the bloom. By so doing, bleeding marks, cavities and other surface defects resulting from over-cooling can be prevented.
  • the difference in the thickness of ceramics should preferably be between 0.3 and 3.0 mm, though this range varies with the cooling capacity of the mold, the condition of the metal flow in the mold and other factors. If the thickness difference exceeds 3.0 mm, the cooling rate will become so slow that the solidifying shell fails to grow fast enough to attain adequate strength to prevent skin ruptures. If the thickness difference is under 0.3 mm, on the other hand, it will become impossible to prevent the occurrence of bleeding marks, cavities and other surface defects.
  • the solidifying shell is pressed against the ceramics lining by the static pressure of the molten metal. Therefore, a frictional force arises between the cast strand and the ceramics lining when the strand is withdrawn from the mold. On the other hand, the thickness of the solidifying shell is still thin in the initial solidification region immediately below the point where solidification begins. To prevent the breaking of the cast strand by the withdrawing force, it is necessary to reduce the frictional force by ensuring that solidification proceeds in such a manner that the surface of the shell and the ceramics lining are softly in contact with each other.
  • Such a condition can be attained by forming a curved portion 6R on the ceramics lining 6 throughout the entire periphery of the mold, with the curved portion 6R containing the solidification starting point 9, having the arc extending in the withdrawing direction and the angle defined by the top and bottom ends of the arc limited to 90 degrees or under.
  • the strand withdrawing force exerts a force acting in the direction of the radius of curvature of the curved portion 6R or a force to pull the solidifying shell away from the surface of the mold lining against the static pressure of the molten metal. This reduces the frictional force that works on the shell during the initial stage of solidification. This permits carrying out a smooth casting within the limit in which the initially formed solidifying shell remains unruptured.
  • the radius of curvature r of the curved portion 6R should preferably be between 30 and 300 mm. If the radius of curvature is under 30 mm, the amount of the heat extracted decreases as the withdrawal proceeds, which can result in re-melting and double solidification. Also, the region in which the frictional force does not work decreases to lessen the effect of the reduced frictional force. If the radius of curvature r exceeds 300 mm, in contrast, the static pressure of the molten metal keeps the solidifying shell pressed against the surface of the mold lining, thereby nullifying the effect of the reduced frictional force. This can lead to skin ruptures and breakouts.
  • Fig. 5 shows an appropriate pattern chosen by considering the influence of the static pressure of the molten metal on the solidification below the molten metal surface.
  • H1 is the distance between the solidification starting point 9 and the molten metal surface 8 (or the thickness of the molten metal layer) and T1 is the index of taper on the inner surface of the mold between the upper and lower ends of the mold (derived by dividing the difference between the clearance at the top and the clearance at the bottom by 2, compared with the base figure of 0 that is obtained when the mold wall is vertical)
  • the optimum relationship between H1 and T1 from the viewpoint of friction is obtained in the hatched region.
  • the index of taper T1 should be increased on the negative side to expand the inner surface of the mold downward.
  • the index of taper T1 should be increased on the positive side to expand the inner surface of the mold upward to promote the growth of the solidifying shell 7.
  • the index of taper T1 should be increased on the positive side to expand the inner surface of the mold upward to promote the growth of the solidifying shell 7.
  • Provision of a taper corresponding to the amount of creep deformation (bulging) which the solidifying shell 7 undergoes under the influence of the static pressure of the molten metal in the casting direction P without impairing the cooling condition releases the friction offered by the static pressure of the molten metal.
  • provision of a taper holds down an increase in the friction offered by the static pressure of the molten metal, too. This taper adjustment reduces the frictional resistance of the continuous-caster mold 1, thereby permitting high-speed casting in spite of solid lubrication.
  • taper index T1 should preferably be kept between -2.0 and +1.8, more preferably between -1.5 and +1.0. If taper index T1 is smaller than -2.0, the inner surface of the mold is kept out of contact with the solidifying shell that deforms (through creeping and bulging) under the influence of the static pressure of the molten metal, whereby the mold loses the functions to support the solidifying shell and extract heat therefrom. When taper index T1 exceeds +1.8, the frictional force between the inner surface of the mold and the solidifying shell increases, with a resulting increase in mold wear and decrease in mold life. The solidifying shell that then becomes more susceptible to constraint by the inner surface of the mold and breakouts defies high-speed casting.
  • a taper having an appropriate angle with respect to the horizontal line n is provided to the inner surface of the mold used for horizontal continuous casting.
  • the ceramics tiles 6b to 6d are attached to the inner wall of the continuous-caster mold 1.
  • One-piece ceramic lining like the break ring of horizontal continuous casters, may be provided on the continuous-caster mold 1. But such larger ceramic lining involves various limitations on making, installation and use. With the mold of vertical continuous casters, therefore, it is preferable to use a lining consisting of smaller tiles as shown in Figs. 6 (a) and (b).
  • Fig. 6 (a) shows a width-adjustable mold and Fig. 6 (b) shows a fixed-width mold.
  • small-sized ceramic tiles a provided in a zigzag pattern on the inner side of the mold wall 2 make up an inner lining on the broad face 1a and the narrow face 1b. While conventional mold powders cannot provide uniform lubrication throughout, with the overall powder-mold contact ratio standing at about 50 percent at best, the tile lining assures very good heat extraction.
  • the surface irregularities of the joints between the individual tiles may seem to offer an obstacle to the formation of the solidifying shell. It has been experimentally proved, however, that sound shells can be formed smoothly if only the horizontal distance e and the joint f between adjoining ceramics tiles a are kept at 0.5 mm or under.
  • the joint f not larger than 0.5 mm prevents the penetration of the molten metal into between the ceramics tiles. It is also preferable to keep the joint f at 0.1 mm or under where the ceramics tiles are in contact with the molten metal.
  • the preferable size of the ceramics tiles is between 20 and 300 mm in both width and length. Tiles smaller than 20 mm in width and length result in more joints per unit area, which, in turn, increases the frictional resistance between the inner surface of the tile-lined mold and the steel being cast, decreases the heat to be extracted, and adds complexity to the lining work. If the width or length exceeds 300 mm, it becomes difficult to affix ceramics tiles to the inner wall of the mold with a uniform adhesive force. When thermal stresses are built up by repeated heating and cooling, some of the ceramics tiles will come off from the inner wall of the mold, thereby shortening the service life of the mold. Limiting the size of the ceramics tiles within the above range facilitates keeping the joints f at not wider than 0.5 mm or more preferable 0.1 mm.
  • the arrangement of the ceramics tiles is not limited to the one described above.
  • a smaller piece of ceramics 6f may be affixed to the inner wall of the continuous-caster mold 1 as shown in Fig. 8.
  • the portion of this ceramics piece 6f in the proximity of the molten metal surface 8 is thicker than the lower rest whose thickness is progressively decreased downward.
  • the thicker portion that comes in contact with the molten metal 5 near the surface 8 thereof permits solidification of the molten metal to start at a point 9 below the surface 8.
  • the mold that thus permits the molten metal to solidify below the surface thereof can be directly connected to the tundish.
  • Figs. 9 (a) and (b) show equipment arrangements including the continuous-caster mold of the type described above.
  • the molten metal 5 fed into a tundish 12 through a longs nozzle 13 is then poured into a continuous-caster mold 1 through a sliding nozzle 14 provided in the bottom wall of the tundish 12.
  • FIG. 9 (a) has a width-adjustable mold 1 suited for use, for example, in slab casting. Because the tundish 12 and the mold 1 are directly connected, the top of the mold 1 is not left open as in the conventional practices but closed with a cover 15. It is possible to slide the mold 1 in the directions of the arrows in which the narrow mold faces 1a are positioned perpendicular to the cover 15. Highly lubricating ceramics 6 provided in the upper portion of the mold 1 assure a smooth slide of the mold 1 with respect to the cover 15.
  • FIG. 9 (b) An arrangement shown in Fig. 9 (b) has a fixed-width continuous-caster mold 1 suited for use, for example, in bloom casting.
  • the mold 1 and tundish 12 are connected with a large or equal-sized opening to pour the molten metal to assure smooth casting without nozzle clogging and other hitches.
  • the static pressure of the molten metal 5 in the continuous-caster mold 1 is controlled to eliminate the risk of breakouts and other defects. It is also possible to control the static pressure by applying an upward driving force to the stream of molten metal flowing through the sliding nozzle 14 by means of a magnetic coil provided around the sliding nozzle 14.
  • the molten metal is poured through the nozzle in the bottom of the tundish 12 into the copper-lined mold 1 where it is cooled and solidified. Accordingly, solidification of the molten metal begins at the molten metal surface and powders are used to lubricate the interface between the copper lining and the solidifying shell. And these factors lead to various serious quality and operational problems, such as the entrapment of powders and aluminum-oxide-type inclusions, pinholes and blowholes due to the entrapment of sealing argon gas from the detachable immersion nozzle and air, and nozzle clogging.
  • Direct connection of the tundish and mold simplifies the casting operation and permits fully automatic casting and great labor saving because it reduces many difficult controls such as those of the pouring rate, molten metal surface and powder addition.
  • the use of a large-diameter pouring tube in place of an immersion nozzle prevents conventional defects due to the formation of inclusions by the powder and slag in the mold.
  • the large opening between the tundish and mold prevents nozzle clogging, permits casting at low temperatures, and greatly cut down refractories consumption and production costs through the improvement of segregation and the use of lower-temperature molten metal.
  • Direction connection of the tundish and mold permits providing a vertical section to a curved continuous caster, as a consequence of which the caster functions like a curved caster with a vertical section. As described above, this invention provides many beneficial affects.
  • Continuous casting was performed using a continuous-caster mold 1 of the type shown in Fig. 2 that has ceramics tiles 6b to 6d affixed to the front side of the inner wall 2 thereof.
  • the thickness of the ceramics tiles 6b to 6d was adjusted so that intense cooling in the upper part (indicated by curve (a) in Fig. 3), subdued cooling in the upper part (indicated by curve (b) in Fig. 3) and uniform cooling (indicated by curve (c) in Fig. 3) could be achieved.
  • continuous casting was also performed using a conventional mold without ceramics lining.
  • the cooling pattern in the compared example was S-shaped curve (indicated by curve (A) in Fig. 3).
  • an opening of 1 to 2 mm was left between the front side of the mold inner wall 2 and the upper ceramics tile 6b in order to suppress the transfer of heat from the molten metal to the inner wall.
  • the asterisks in Table 1 indicate the provision of the opening. Provision of this opening permits attaining a great heat-insulating effect and achieving solidification of the molten metal below the surface level even when the thickness of the ceramics tile 6b is reduced.
  • the ceramics block 6a was not mounted on top of the inner wall 2.
  • Castings having good surface quality was also obtained when molten metal was poured into the continuous-caster mold 1 from the tundish 12 directly connected thereto as shown in Fig. 9 (b). Kept out of contact with the atmosphere, the molten metal flowing down from the tundish 12 is as clean as when it was poured into the tundish 12, with its internal structure free from entrapped oxides.
  • Continuous casting was performed using a continuous-caster mold 1 of the type shown in Fig. 2 that has a BN ceramics block 6a pressed and fastened to the top of the mold 1 by a clamp 10.
  • the tiles 6b to 6d affixed to the front side of the inner wall 2 were of BN ceramics.
  • Sections were continuously cast by pouring molten metal having a composition of plain carbon steel into the mold 1 as in Example 1. The obtained results are shown in Table 2. Using the temperature of the copper lining determined by thermocouples, simulation was made by the finite element method. Then, the point of molten metal solidification 9 was found to be 40 to 70 mm below the molten metal surface 8.
  • the mold used in this example had a 120 mm thick beat-insulating BN block 6a on top thereof.
  • a combination of a heat-insulating zone surrounded by the ceramics blocks and a cooling zone lined with ceramics tiles 6b to 6d kept the molten metal in the upper part of the mold molten, with solidification of the molten metal allowed to start below the molten metal surface 8 in the cooling zone.
  • metal powder was added to organic adhesives.
  • This addition improved heat conductivity, made the temperature gradient gentler, and brought the temperature of the bonding layer into the tolerable temperature range, thereby maintaining the original adhesive strength and enhancing the heat extraction characteristic.
  • Powders of such high heat-conductivity metals as gold, silver, copper, aluminum and iron are suited for addition.
  • the amount of addition affects heat conductivity, adhesive strength and the efficiency of kneading. When the amount of addition exceeds 60 percent, heat conductivity increases but adhesive strength drops. When the amount is smaller than 10 percent, heat extraction becomes insufficient to raise the temperature to such a level as to lower the strength of organic adhesives. Therefore, the amount of metal powder addition to the adhesives used on the continuous-caster mold should be kept between 10 and 60 percent by volume.
  • the added powder must consist of spherical particles having a mean diameter of 10 ⁇ m, with a maximum diameter of 30 ⁇ . Still, the shape of the metal powder particles is not limited to spherical, but may also be flaky and fibrous.
  • This type of organic adhesives added with metal powders can be used in bonding ceramics tiles to the metal wall of larger molds too because the conventional need of applying pressure or heat is saved.
  • molten metal is poured, a temperature difference arises between both sides because the ceramics tiles are in contact with the molten metal and the metal plate with cooling water.
  • the organic adhesives with high buffer capacities absorb the strain and stress due to the difference in the coefficient of linear expansion between the metal plate and ceramics tiles. Therefore, the ceramics tiles do not crack or come off even when the mold is used repeatedly.
  • the organic adhesives absorbs the expansion of the metal powders mixed therein, internal cracking can be prevented as well.
  • the improved heat conductivity resulting from the addition of the metal powders permit extracting greater amount of heat and, therefore, forming a sufficiently thick, stable solidifying shell.
  • Table 3 shows the results obtained in continuously casting blooms and slabs through the molds lined with ceramics tiles bonded with adhesives added with metals.
  • This method bonds ceramics tiles to the front side of the inner wall of the mold with an organic adhesive, with a metal wire netting interposed therebetween.
  • the metal wire netting to be interposed between the copper lining and ceramics tiles are of gold, silver, copper, aluminum or iron, or alloys containing two or more of them, having wire diameters of 10 ⁇ m to 70 ⁇ m.
  • the wire netting may be made up of vertical lines alone, horizontal lines alone, or both of them.
  • the adhesive may contain powder of the same metal of which the wire netting is made.
  • wire netting In place of interposing the wire netting, surface irregularities may be provided on the ceramics tile side of the copper mold lining. Then, the ceramics tiles and copper plate are bonded together with an organic adhesive, with the projecting portion of the irregularly shaped copper plate held in contact with or in the vicinity of the ceramics tiles. Or otherwise, wire netting or metal powder of the type mentioned before may be provided in the openings left by the surface irregularities of the copper lining.
  • Figs. 11 and 12 are schematic cross sections of the continuous caster molds of the type just described.
  • Fig. 11 ceramics tiles 30 having a width and a length of 20 to 300 mm are placed over a metal wire netting 23 attached to the inner wall 2 that has a cooling water passage 4 therein, with the openings left therebetween filled with an organic adhesive 25.
  • surface irregularities 26 are provided, in place of the metal wire netting, on the surface of the mold inner wall that come in contact with the ceramics tiles 30. With the projecting portion of the irregularly shaped mold wall kept in point contact, as indicated by reference numeral 27 at the left, or in plane contact, as indicated by reference numeral 288 at the right, with the ceramics tiles 30, with the openings left between the inner wall 2 and ceramics tiles 30 filled with an organic adhesive 25.
  • Metal powders 10 to 60 percent in quantity, may be added to the organic adhesives used with the preferred embodiments shown in Figs. 11 and 12.
  • Table 4 shows the performance of various types of bonding layers formed with organic adhesives evaluated under the molten metal loads applied in simulation tests (see also Figs. 13 and 14).
  • a compared example designated as type e in Table 4 consists of an organic adhesive alone.
  • the bonding layer formed on the continuous-caster mold is exposed to high temperatures (of molten steel) on one side and kept at ordinary temperature (by cooling water) on the other. Under such condition, the temperature gradient in the bonding layer becomes very steep, as a result of which the interface temperature on the higher temperature side will exceed the tolerable limit of 260 °C. Therefore, the adhesive of type a should not be used where the temperature exceeds the tolerable limit.
  • Type f is an organic adhesive added with a metal powder, which keeps the temperature of the bonding layer within the tolerable limit by making gentler the temperature gradient therein through the enhancement of heat conductivity. This results in remarkably increased adhesive strength and heat extraction efficiency. But gas bubbles are likely to form during mixing. The gas bubbles inhibit heat extraction and uniform mixing of the metal powder. Therefore, the adhesive and metal powder must be mixed thoroughly.
  • Type A in Table 4 has a heat transfer surface at higher temperature (on the ceramics tiles side) and a heat transfer surface at lower temperature (on the water-cooled copper lining side) that are kept in direct contact with metal wire that have good heat conductivity. Therefore, type A exhibits high heat conductivity and good heat extraction characteristic. Because the temperature of the peripheral bonding layer is lowered, stable adhesive strength is obtained. The following paragraphs describe the characteristics of type A compared with those of type f.
  • heat conductivity can be enhanced by increasing the mixing ratio of the metal powder. But addition of the metal powder should not be continued when kneading becomes difficult and too many gas bubbles are formed. Containing many heat transfer interfaces and gas bubbles that lower heat conductivity, the bonding layer of type f transfers less heat than those of types A to D as shown in Fig. 15.
  • type A permits good heat transfer because the higher and lower temperature sides are directly connected by the metal wire that has high thermal conductivity.
  • Type B also produces good results analogous to those of type A. Effective heat extraction is achieved by means of the surface irregularities formed on the inner wall of the mold, in place of interposing the metal wire, with the projecting portion thereof held in contact with or in the vicinity of the heat transfer surface on the higher temperature side.
  • Types C and D which are combinations of the preferred embodiments described above, also provide as satisfactory results as type A.
  • the bonding layer of type A is formed by first making holes of 80 ⁇ m diameter in a metal frame at intervals of 100 ⁇ m, with 70 ⁇ m diameter wires stretched in one direction. To the wired metal frame mounted on the inner wall of the mold are bonded ceramics tiles with an organic adhesive by applying a given pressure. Finishing is applied when the adhesive has thoroughly solidified. By this method, a bonding layer having a uniform high heat conductivity can be easily obtained.
  • a two-way wired variation can be made also, though not as easily as the one-way wired embodiment, by forming a net-like pattern with wires stretched at right angles with each other.
  • the net-like grooves in type B can be easily made by machining.
  • the ratio of the cross-sectional area occupied by the added metal (to be more specific, the ratio of the area the added metal occupies in the vertical cross section of the bonding layer) can be varied as shown in the planar configurations of the bonding layer in Table 4. Then, satisfactory adhesive strength can be obtained by thus attaining a higher metal density in the upper portion and a lower metal density in the lower portion and by increasing the bonding area of the adhesive within the temperature limit tolerable to the adhesive.
  • Figs. 16 (a), (b) and (c) show the relationships among the index of shear stress (P), index of heat conductivity ( ⁇ ) and the cross-sectional area occupied by the added metal of types f and A to D shown in Table 4. Obviously, the preferred embodiments of this invention exhibit much higher shear stress and heat conductivity.
  • the percentage cross-sectional area occupied by the added metal should be kept between 25 and 85 percent. The higher the percentage cross-sectional area occupied by the added metal, the higher the heat conductivity. Then, the temperature of the bonding layer drops to enhance the soundness of the bonding layer. On the other hand, however, adhesive strength decreases as a result of a decrease in the bonded area.
  • the upper limits of the percentage cross-sectional area occupied by the added metal are indicated by hatching. The upper limits are those tolerable to satisfactory bonding.
  • the percentage should preferably be kept between 85 and 39.3 percent with the metal wire type (types A and C) and between 68.5 and 25.0 percent with the grooved type (types B and D). Good heat extraction and adhesive strength are obtained when the percentage is between 78.5 and 39.3 percent with type A, between 55 and 25 percent with type B, between 85 and 39.3 percent with type C, and between 68.5 and 25.0 percent with type D.
  • the higher temperature heat transfer surface of the ceramics tiles on the molten metal side and the lower temperature heat transfer surface on the copper mold lining side are brought into direct contact by means of the metal having good thermal conductivity, thereby forming a bonding layer that assures the transfer of heat at high temperatures. Because, in addition, the metal portion and adhesive are handled individually, the viscosity of the adhesive remains undamaged. As the metal occupies a greater portion of the bonding layer, heat conductivity can be increased without lowering the adhesive strength of the bonded joint.
  • the thickness of the ceramics lining is varied both in the withdrawing direction of the casting and along the width of the mold.
  • Table 5 shows the results of bloom and slab casting achieved by varying the thickness of the ceramics lining as described above.
  • the castings made by use of the molds according to this invention were free from surface defects, oscillation marks and impressions at corners. This was due to the fact that a substantially uniform cooling capacity was secured across the width of the mold by controlling the thickness of the lining in that direction. By contrast, the aforementioned surface defects occurred on the castings made for the purpose of comparison, using conventional molds. This was due to the nonuniform cooling capacity across the width of the mold, which resulted from the higher cooling capacity in the proximity of the ends of the mold width than in the middle.
  • the ceramics lining of this preferred embodiment is curved in the upper portion thereof.
  • Table 6 shows the results of bloom and slab casting achieved by varying the radius of curvature of the curved portion of the ceramics lining.
  • the inner surface of the mold described hereunder is tapered in the direction in which the casting is withdrawn.
  • Table 7 shows the results of bloom and slab casting achieved by using a mold whose inner surface narrows downward and one whose inner surface flares downward.
  • the molds according to this invention proved to exhibit a longer service life without causing breakouts. This was due to the fact that air gap formation between the inner surface of the mold and the solidifying shell is prevented by controlling the thickness of the lining and adjusting the taper of the inner surface of the mold according to the deformation (creeping and bulging) of the solidifying shell under the static pressure of the molten metal.
  • breakouts occurred on the castings made for the purpose of comparison, using conventional powdered molds. The occurrence of breakouts was due to the air gaps formed between the inner surface of the mold and the solidifying shell where uniform distribution of the mold powder and, therefore, adequate heat extraction were not attained.
EP19900116077 1990-03-30 1990-08-22 Stranggussform und Stranggussverfahren Expired - Lifetime EP0448773B1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP8353090A JPH03285741A (ja) 1990-03-30 1990-03-30 連続鋳造用セラミックス鋳型
JP83530/90 1990-03-30
JP170289/90 1990-06-29
JP17028990A JPH0459153A (ja) 1990-06-29 1990-06-29 連続鋳造用鋳型

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EP0448773A2 true EP0448773A2 (de) 1991-10-02
EP0448773A3 EP0448773A3 (en) 1993-03-17
EP0448773B1 EP0448773B1 (de) 1996-12-18

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AU (1) AU635311B2 (de)
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2318314A (en) * 1996-10-15 1998-04-22 Davy Distington Ltd Continuous casting mould with a coating of varying thickness
WO2006109739A1 (ja) 2005-04-11 2006-10-19 Hitachi Metals, Ltd. 合金溶湯の鋳造方法
WO2010042469A2 (en) * 2008-10-06 2010-04-15 Alcoa Inc. Process and apparatus for direct chill casting
US20180169761A1 (en) * 2014-08-21 2018-06-21 Molyworks Materials Corp. Process for producing metals and metal alloys using mixing cold hearth
CN110981172A (zh) * 2019-12-21 2020-04-10 张忠恕 一种外延工艺石英焊件组件及其加工工艺
CN115110018A (zh) * 2022-06-22 2022-09-27 武汉钢铁有限公司 结晶器铜板用涂层的制备方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110732648B (zh) * 2019-10-31 2021-05-11 杭州富通电线电缆有限公司 一种铜杆的制造工艺

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JPS5813445A (ja) * 1981-07-17 1983-01-25 Hitachi Zosen Corp 連続鋳造設備のモ−ルド銅板
JPS59153550A (ja) * 1983-02-23 1984-09-01 Kawasaki Steel Corp 連続鋳造用モ−ルド
JPS62114745A (ja) * 1985-11-12 1987-05-26 Sumitomo Electric Ind Ltd 連続鋳造用鋳型

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JPS5813445A (ja) * 1981-07-17 1983-01-25 Hitachi Zosen Corp 連続鋳造設備のモ−ルド銅板
JPS59153550A (ja) * 1983-02-23 1984-09-01 Kawasaki Steel Corp 連続鋳造用モ−ルド
JPS62114745A (ja) * 1985-11-12 1987-05-26 Sumitomo Electric Ind Ltd 連続鋳造用鋳型

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2318314A (en) * 1996-10-15 1998-04-22 Davy Distington Ltd Continuous casting mould with a coating of varying thickness
WO1998016336A1 (en) * 1996-10-15 1998-04-23 Davy Distington Limited Continuous casting mould
US6176298B1 (en) 1996-10-15 2001-01-23 Davy Distington Limited Continuous casting mould
WO2006109739A1 (ja) 2005-04-11 2006-10-19 Hitachi Metals, Ltd. 合金溶湯の鋳造方法
EP1870182A1 (de) * 2005-04-11 2007-12-26 Hitachi Metals, Ltd. Verfahren zum giessen von legierungsschmelze
EP1870182A4 (de) * 2005-04-11 2009-01-14 Hitachi Metals Ltd Verfahren zum giessen von legierungsschmelze
WO2010042469A2 (en) * 2008-10-06 2010-04-15 Alcoa Inc. Process and apparatus for direct chill casting
WO2010042469A3 (en) * 2008-10-06 2010-06-03 Alcoa Inc. Process and apparatus for direct chill casting
US20180169761A1 (en) * 2014-08-21 2018-06-21 Molyworks Materials Corp. Process for producing metals and metal alloys using mixing cold hearth
US10654106B2 (en) * 2014-08-21 2020-05-19 Molyworks Materials Corp. Process for producing metals and metal alloys using mixing cold hearth
CN110981172A (zh) * 2019-12-21 2020-04-10 张忠恕 一种外延工艺石英焊件组件及其加工工艺
CN115110018A (zh) * 2022-06-22 2022-09-27 武汉钢铁有限公司 结晶器铜板用涂层的制备方法
CN115110018B (zh) * 2022-06-22 2023-11-10 武汉钢铁有限公司 结晶器铜板用涂层的制备方法

Also Published As

Publication number Publication date
EP0448773A3 (en) 1993-03-17
EP0448773B1 (de) 1996-12-18
DE69029467D1 (de) 1997-01-30
AU6128790A (en) 1991-10-03
AU635311B2 (en) 1993-03-18
DE69029467T2 (de) 1997-07-10
CA2023826A1 (en) 1991-10-01

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