Classifications

• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
  • C04B24/003—Phosphorus-containing compounds
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
  • C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
  • C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
  • C04B2103/0004—Compounds chosen for the nature of their cations
  • C04B2103/0005—Organic ammonium compounds
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
  • C04B2103/40—Surface-active agents, dispersants
  • C04B2103/408—Dispersants

Definitions

• the present invention relates to an aqueous cementing composition. More particularly, the present invention relates to salt containing cementing compositions which contain polyethyleneimine phosphonate derivatives as cement slurry dispersants.
• the polyethyleneimine phosphonate derivatives are of the general structure and mixtures thereof.
• polyethyleneimine phosphonate derivatives as dispersant additives in salt containing cement slurries used in the cementing of oil and gas wells, allows slurries to be pumped in turbulent flow, a condition which aids in the removal of residual drilling mud and therefore improves the cementing bond to the producing formation.
• the dispersant of the present invention may be present in an amount of 0.05 to 1.0% by weight of cement (BWOC).
• polyethyleneimine phosphonate derivatives of the present invention greatly improves flow behavior of cement in oil and gas well cementing operations and allows for slurries to be pumped in turbulent flow, thereby effecting a more efficient bonding between the oil or gas well liners and the rock formations.
• Oil well cementing and other underground cementing operations often require placement of a slurry of cement, water and other additives in a porous environment such as porous earthen or rock strata.
• cement compositions are routinely used in the oil and gas industry to cement the annular space in the well bore between the surrounding formation and the pipe or casing.
• the cement slurry is pumped down the inside of the casing and back up the outside of the casing through the annular space.
• the slurry is allowed to set up or harden in the annular space, thereby forming a rigid column which ideally forms a bond with the earth or rock formations as well as with the metal pipe or casing.
• it is essential to achieve a tight bond to prevent vertical communication of fluids or gas along or within the column, which could contaminate the producing zone, or permit a loss of reserves.
• the primary functions of the cementing process are to restrict fluid movement between geological formations and to bond and support the casing or metal pipe.
• the cement aids in protecting the casing from corrosion, preventing "blow-outs" by quickly sealing formations, protecting the casing from shock loads in drilling deeper wells and sealing off lost circulation or thief zones.
• Dispersants are used to improve the flow properties of cement slurries used in completion of oil and gas wells.
• the improved flow behavior allows slurries to be pumped in turbulent flow, a condition which aids in the removal of residual drilling mud and therefore cement bonding to the producing formation.
• the thinning action of the dispersant makes it possible to mix dense slurries of over 20 lbs./gallon, which otherwise would be too viscous to be mixed in existing field equipment.
• dispersant usually sodium salts of sulfonated naphthalene/formaldehyde condensates.
• Representative among these is LOMAR® D, manufactured by the Diamond Shamrock Company. It has been a long standing problem in the art to arrive at a suitable dispersant for cement systems which contains a high level of salt, such as NaCl. The salts aid in bonding the cement to salt containing geological structures Because of the high ionic strength of the salt cement slurries, dispersants such as LOMAR® D have been unsatisfactory in such cement slurries.
• the present invention relates to salt containing cementing compositions and more particularly to dispersant additives which may be incorporated into such cement compositions.
• the salt containing cement compositions are useful in cementing operations in oil and gas wells and are comprised of water, salt containing hydraulic cement, fluid loss additives if desired, and a dispersant based on polyethyleneimine phosphonates.
• Polyethyleneimine phosphonate derivatives useful in the present invention are those having the general structure and mixtures thereof.
• Polyethyleneimine phosphonate derivatives are disclosed for use in oil, gas and water cement compositions as dispersants, which are as effective as conventional sulfonated dispersants, such as LOMAR® D, and which are clearly more effective as dispersants in cement compositions having high salt concentrations. NaCl inhibits the action of conventional dispersants such as LOMAR® D.
• polyethyleneimine phosphonate derivatives useful in the present invention have the general formula and mixture thereof.
• polyethyleneimine phosphonate derivatives of the present invention are made by condensing polyethyleneimine with a phosphonate in the manner which is well known to those skilled in the art.
• the dispersants can be added to the cement composition in dry, solution or emulsion form in an amount of from 0.05 to 1.0% by weight of the cement (BWOC).
• the result of the inclusion of the dispersion additives of the present invention are improved pumpability of the cement which generally improves drilling fluid removal and reduced possibility of lost circulation, when cementing a conduit penetrating a permeable earthen formation.
• the cement component of the cement composition of this invention may be any of the API classes of cement or cement blends, as are defined in the American Petroleum Institute Bulletin entitled “API Specification for Material and Testing for Well Cements,” Third Edition, dated July 1, 1986 (“API Spec. 10"), and incorporated herein by reference. These include cements defined as Classes A through H in API Spec. 10.
• the cement compositions may also include at least one inorganic salt.
• Suitable salts include inorganic monovalent and polyvalent metal salts, such as magnesium chloride, ammonium chloride, sodium and potassium chloride and calcium chloride
• additives conventionally added to cement compositions useful in cementing casings in the bore hole of a well can also be added to the cement compositions of this invention in the amount which are normally used by those skilled in the art.
• additives may include, for example, (1) heavy weight additives, such as hematite, ilmenite, silica flour and sand; (2) cement retarders such as lignins and lignosulfonates; and (3) additives for controlling lost circulation; such as walnut hulls and cellophane flakes.
• Table I is an explanation of the symbols and abbreviations used in the tables containing the data of the examples.
• the symbols and abbreviations used therein are standard in the art and are well known to those of ordinary skill in the art.
• dispersants based on naphthalene sulfonate formaldehyde condensates as LOMAR® D cause complete gelation of cement slurries containing 18% NaCl BWOW.
• slurries containing low molecular weight Polymin Phosphonate dispersants have a low PV and YP allowing their easy placement in the formation.
• An increase in the Molecular Weight of the Polymin moiety reduces the effectiveness of the dispersant mainly by increasing the YP of the slurries.
• the new dispersants claimed in the invention are more effective than the polynaphthalene sulfonate condensates tested.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Ceramic Engineering (AREA)
• Materials Engineering (AREA)
• Organic Chemistry (AREA)
• General Life Sciences & Earth Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Inorganic Chemistry (AREA)
• Structural Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
• Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
• Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Applications Claiming Priority (2)

Publications (2)

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Cited By (9)

Citations (3)

• 1991
  • 1991-02-22 DE DE91102594T patent/DE69100517T2/de not_active Expired - Fee Related
  • 1991-02-22 EP EP91102594A patent/EP0444542B1/de not_active Expired - Lifetime
  • 1991-03-01 NO NO910829A patent/NO306338B1/no not_active IP Right Cessation

Patent Citations (3)

Non-Patent Citations (1)

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