EP0430328A2 - Procédé de préparation de détergents en poudre à haute densité contenant des argiles - Google Patents

Procédé de préparation de détergents en poudre à haute densité contenant des argiles Download PDF

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Publication number
EP0430328A2
EP0430328A2 EP19900203012 EP90203012A EP0430328A2 EP 0430328 A2 EP0430328 A2 EP 0430328A2 EP 19900203012 EP19900203012 EP 19900203012 EP 90203012 A EP90203012 A EP 90203012A EP 0430328 A2 EP0430328 A2 EP 0430328A2
Authority
EP
European Patent Office
Prior art keywords
weight
detergent
clay
process according
bulk density
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19900203012
Other languages
German (de)
English (en)
Other versions
EP0430328B1 (fr
EP0430328A3 (en
Inventor
Graem Douglas Armstrong
Donal Gerard Cronin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP0430328A2 publication Critical patent/EP0430328A2/fr
Publication of EP0430328A3 publication Critical patent/EP0430328A3/en
Application granted granted Critical
Publication of EP0430328B1 publication Critical patent/EP0430328B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065—High-density particulate detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions

Definitions

  • the Japanese patent application 61 069897 discloses a process in which a spray-dried detergent powder containing a high level of anionic surfactant and a low level of builder (zeolite) is subjected successively to a pulverizing and a granulating treatment in a high-speed mixer/granulator.
  • the granulation is carried out in the presence of an "agent for improving surface properties" and optionally a binder.
  • the starting material for the process according to the invention comprises (a) from 10 to 70% by weight of non-soap detergent active material, and (b) at least 15% by weight of water-soluble crystalline inorganic salts, including sodium tripolyphosphate and/or sodium carbonate, the weight ratio of
  • the detergent active material may be selected from non-soap anionic, ampholytic, zwitterionic or nonionic detergent active materials or mixtures thereof. Particularly preferred are all anionic or mixtures with nonionic detergent active materials such as a mixture of an alkali metal salt of an alkyl benzene sulphonate together with an alkoxylated alcohol.
  • the preferred detergent compounds which can be used are synthetic anionic and nonionic compounds.
  • the former are usually water-soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms, the term alkyl being used to include the alkyl portion of higher acyl radicals.
  • nonionic detergent compounds include long-chain tertiary amine oxides, long-chain tertiary phosphine oxides and dialkyl sulphoxides.
  • Amounts of amphoteric or zwitterionic detergent compounds can also be used in the compositions of the invention but this in not normally desired owing to their relatively high cost. If any amphoteric or zwitterionic detergent compounds are used, it is generally in small amounts in compositions based on the much more commonly used synthetic anionic and/or nonionic detergent compounds.
  • the granulation step is similarly carried out by running the stirrer and the cutter at a relatively high speed, but here the presence of a liquid binder is necessary.
  • the preferred binder is water.
  • the amount of binder added should preferably not exceed about 6 % by weight, because higher levels may adversely affect the flow properties of the final product.
  • the liquid binder may be added before or during granulation, preferably by spraying it in while the apparatus is running.
  • the starting material may also already contain sufficient moisture, such that addition of further liquid binder is not necessary. In this case, pulverization and granulation may be carried out as a single operation.
  • a clay-containing material as a fabric softener will depend amongst other things on the level of smectite clay. Impurities such as calcite, feldspar and silica will often be present. Relatively impure clays can be used, provided that such impurities are tolerable in the composition.
  • the level of the fabric-softening clay material in the composition should be sufficient to provide a softening benefit. Amounts from 1.5% to 35% by weight, preferably from 4% to 20% by weight, calculated on the basis of the clay mineral per se were found to be effective.
  • the compositions according to the invention optionally may contain other ingredients usually found in detergent compositions, in the amounts in which such additives are normally employed in fabric-washing detergent compositions.
  • additives include the lather boosters such as alkanolamides, particularly the monoethanolamides derived from palm kernel fatty acids and coconut fatty acids, lather depressants, oxygen releasing bleaching agents such as sodium perborate and sodium percarbonate, peracid bleach precursors, chlorine releasing bleaching agents such as trichloroisocyanuric acid, fillers such as sodium sulphate, and, usually present in very minor amounts, fluorescent agents, perfumes, enzymes such as proteases, lipases and amylases, germicides and colorants.
  • the process of the present invention enables the preparation of detergent compositions having a high bulk density of at least 550 g/l. It is a surprising advantage of the process of the invention that the bulk density of the obtained powders is higher than when the clay is admixed to the crutcher slurry prior to spray-drying of the starting material.
  • Example 2 contained a Ca-clay (Prassa ex Colin Stewart Minerals, U.K.) which was added to the crutcher slurry and spray-dried. Sodium carbonate was in this case omitted from the slurry to maintain it at a sufficiently low viscosity to aid in spray-drying.
  • Example 3 was a spray-dried powder without clay but including carbonate.
  • Example 2 When the clay was added separately to the wash using the composition of Example 1, a softness value of 97.5 was found. Comparison of this value with the softness value of 99.5 found for Example 3 indicates that essentially the full softening performance is delivered by the process of the invention. However, when the clay was added to the crutcher slurry prior to spray-drying as in Example 2, a much lower softness value of 75.3 was found.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP90203012A 1989-11-27 1990-11-14 Procédé de préparation de détergents en poudre à haute densité contenant des argiles Expired - Lifetime EP0430328B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8926718 1989-11-27
GB898926718A GB8926718D0 (en) 1989-11-27 1989-11-27 Process for the preparation of detergent compositions

Publications (3)

Publication Number Publication Date
EP0430328A2 true EP0430328A2 (fr) 1991-06-05
EP0430328A3 EP0430328A3 (en) 1991-07-31
EP0430328B1 EP0430328B1 (fr) 1995-02-15

Family

ID=10666950

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90203012A Expired - Lifetime EP0430328B1 (fr) 1989-11-27 1990-11-14 Procédé de préparation de détergents en poudre à haute densité contenant des argiles

Country Status (12)

Country Link
EP (1) EP0430328B1 (fr)
JP (1) JPH0762160B2 (fr)
KR (1) KR950001687B1 (fr)
AU (1) AU627958B2 (fr)
BR (1) BR9005981A (fr)
CA (1) CA2030451C (fr)
DE (1) DE69016945T2 (fr)
ES (1) ES2067658T3 (fr)
GB (1) GB8926718D0 (fr)
IN (1) IN172032B (fr)
MY (1) MY104539A (fr)
ZA (1) ZA909477B (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998054289A1 (fr) * 1997-05-30 1998-12-03 Unilever Plc Compositions detergentes particulaires a ecoulement fluide
US5990073A (en) * 1995-06-30 1999-11-23 Lever Brothers Company Process for the production of a detergent composition
US6069124A (en) * 1997-05-30 2000-05-30 Lever Brothers Company Division Of Conopco, Inc. Granular detergent compositions and their production
EP1048713A1 (fr) * 1999-04-30 2000-11-02 The Procter & Gamble Company Compositions détergentes
US6191095B1 (en) 1997-05-30 2001-02-20 Lever Brothers Company, A Division Of Conopco, Inc. Detergent compositions
US6303558B1 (en) 1997-05-30 2001-10-16 Lever Brothers Co., Division Of Conopco Detergent composition containing at least two granular components
WO2013184981A2 (fr) * 2012-06-08 2013-12-12 The Procter & Gamble Company Particules esthétiques visuellement contrastantes possédant une solubilité dans l'eau accrue, particulièrement utiles pour une combinaison avec des compositions pulvérulentes ou granulaires

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5563673A (en) * 1991-09-06 1996-10-08 Canon Kabushiki Kaisha Camera
KR20040029501A (ko) * 2002-10-01 2004-04-08 김철홍 콜로이드성 은 입자 수용액을 이용한 무공해 콩나물재배방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2063289A (en) * 1979-11-13 1981-06-03 Unilever Ltd Low phosphate spray-dried powders
EP0229671A2 (fr) * 1986-01-17 1987-07-22 Kao Corporation Composition détergente granulaire de densité élevée
EP0340013A2 (fr) * 1988-04-29 1989-11-02 Unilever Plc Compositions détergentes et procédé pour leur préparation
EP0339996A1 (fr) * 1988-04-29 1989-11-02 Unilever Plc Procédé de préparation des compositions détergentes
EP0351937B1 (fr) * 1988-07-21 1994-02-09 Unilever Plc Compositions détergentes et procédé pour leur préparation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54149707A (en) * 1978-05-17 1979-11-24 Lion Corp Detergent composition
JPH0680160B2 (ja) * 1984-09-14 1994-10-12 花王株式会社 流動性の改良された高密度の粒状洗剤の製法
JPS6169897A (ja) * 1984-09-14 1986-04-10 花王株式会社 流動性の改良された高密度の粒状洗剤の製法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2063289A (en) * 1979-11-13 1981-06-03 Unilever Ltd Low phosphate spray-dried powders
EP0229671A2 (fr) * 1986-01-17 1987-07-22 Kao Corporation Composition détergente granulaire de densité élevée
EP0340013A2 (fr) * 1988-04-29 1989-11-02 Unilever Plc Compositions détergentes et procédé pour leur préparation
EP0339996A1 (fr) * 1988-04-29 1989-11-02 Unilever Plc Procédé de préparation des compositions détergentes
EP0351937B1 (fr) * 1988-07-21 1994-02-09 Unilever Plc Compositions détergentes et procédé pour leur préparation

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5990073A (en) * 1995-06-30 1999-11-23 Lever Brothers Company Process for the production of a detergent composition
US6221831B1 (en) 1997-05-30 2001-04-24 Lever Brothers Company, Division Of Conopco, Inc. Free flowing detergent composition containing high levels of surfactant
US6069124A (en) * 1997-05-30 2000-05-30 Lever Brothers Company Division Of Conopco, Inc. Granular detergent compositions and their production
WO1998054289A1 (fr) * 1997-05-30 1998-12-03 Unilever Plc Compositions detergentes particulaires a ecoulement fluide
US6303558B1 (en) 1997-05-30 2001-10-16 Lever Brothers Co., Division Of Conopco Detergent composition containing at least two granular components
US6191095B1 (en) 1997-05-30 2001-02-20 Lever Brothers Company, A Division Of Conopco, Inc. Detergent compositions
EP1048713A1 (fr) * 1999-04-30 2000-11-02 The Procter & Gamble Company Compositions détergentes
WO2000066686A1 (fr) * 1999-04-30 2000-11-09 The Procter & Gamble Company Compositions de detergents
GB2363801A (en) * 1999-04-30 2002-01-09 Procter & Gamble Detergent compositions
GB2363801B (en) * 1999-04-30 2003-03-19 Procter & Gamble Detergent compositions
WO2013184981A2 (fr) * 2012-06-08 2013-12-12 The Procter & Gamble Company Particules esthétiques visuellement contrastantes possédant une solubilité dans l'eau accrue, particulièrement utiles pour une combinaison avec des compositions pulvérulentes ou granulaires
WO2013184981A3 (fr) * 2012-06-08 2014-02-27 The Procter & Gamble Company Particules esthétiques visuellement contrastantes possédant une solubilité dans l'eau accrue, particulièrement utiles pour une combinaison avec des compositions pulvérulentes ou granulaires
WO2013184987A3 (fr) * 2012-06-08 2014-03-06 Amcol International Corporation Particules esthétiques visuellement contrastantes possédant une solubilité dans l'eau accrue, particulièrement utiles pour une combinaison avec des compositions pulvérulentes ou granulaires
US8969280B2 (en) 2012-06-08 2015-03-03 The Procter & Gamble Company Visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with powered or granular compositions
US9683204B2 (en) 2012-06-08 2017-06-20 Amcol International Corporation Visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with powdered or granular compositions

Also Published As

Publication number Publication date
ES2067658T3 (es) 1995-04-01
JPH03210398A (ja) 1991-09-13
JPH0762160B2 (ja) 1995-07-05
ZA909477B (en) 1992-07-29
BR9005981A (pt) 1991-09-24
KR950001687B1 (ko) 1995-02-28
IN172032B (fr) 1993-03-20
EP0430328B1 (fr) 1995-02-15
KR910009910A (ko) 1991-06-28
CA2030451A1 (fr) 1991-05-28
GB8926718D0 (en) 1990-01-17
MY104539A (en) 1994-04-30
CA2030451C (fr) 1999-07-27
AU6690690A (en) 1991-05-30
EP0430328A3 (en) 1991-07-31
DE69016945D1 (de) 1995-03-23
DE69016945T2 (de) 1995-06-14
AU627958B2 (en) 1992-09-03

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