EP0428555B1 - Verfahren und vorrichtung zum präparieren eines ballons - Google Patents
Verfahren und vorrichtung zum präparieren eines ballons Download PDFInfo
- Publication number
- EP0428555B1 EP0428555B1 EP89908440A EP89908440A EP0428555B1 EP 0428555 B1 EP0428555 B1 EP 0428555B1 EP 89908440 A EP89908440 A EP 89908440A EP 89908440 A EP89908440 A EP 89908440A EP 0428555 B1 EP0428555 B1 EP 0428555B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- neck
- balloon
- mandrel
- everted
- balloons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title description 3
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 230000001070 adhesive effect Effects 0.000 claims abstract description 17
- 230000001681 protective effect Effects 0.000 claims abstract description 12
- 238000004806 packaging method and process Methods 0.000 claims abstract description 3
- 210000003739 neck Anatomy 0.000 claims description 93
- 239000004821 Contact adhesive Substances 0.000 claims description 9
- 238000003825 pressing Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 3
- 239000003292 glue Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 9
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H27/00—Toy aircraft; Other flying toys
- A63H27/10—Balloons
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H27/00—Toy aircraft; Other flying toys
- A63H27/10—Balloons
- A63H2027/1025—Fabrication methods or special materials therefor
Definitions
- This invention relates to a process and apparatus for preparing self-sealing balloons.
- Balloons in various shapes and sizes are sold for use at many social gatherings (eg. children's and Christmas parties) and are used in larger quantities at many promotional or sporting events.
- balloons are inflated either by blowing into them by mouth or by filling them with helium gas from a large cylinder. The neck of the balloon is then knotted to prevent gas escaping. The knotting operation requires dexterity and becomes all the more tiresome when large quantities of balloons need to be inflated and sealed at, for example, promotional events.
- a gas-tight seal can never be achieved simply by tying a knot in the neck of a balloon, since there will always remain a minute passage through which gas can escape.
- British Patent Application GB-A-2200299 (published 3rd August 1988) describes a balloon which can be easily sealed by the use of an adhesive, which can be prepared at low unit cost, which does away with the need for interior protective sheets and which can be adapted to all types of balloons.
- the balloon described in GB-A-2200299 has at least a portion of its neck turned inside out (i.e. everted) and at least an outer annular part of said portion coated with a contact adhesive such as an untreated latex.
- the balloon described in GB-A-2200299 can be sealed after inflation simply by unfolding the neck of the balloon with a pulling action and by pinching the neck.
- the seal produced is entirely gas tight.
- the balloon does not require any protective strips, since contact adhesive is, in general, non-adhesive except with itself and premature sealing is prevented by the folding of the neck of the balloon.
- the balloon has the additional advantage in that it can be reused, since it is possible to break the seal by pulling the opposed surfaces of the neck apart.
- US 3108396 also shows a balloon with a folded back portion of the neck which is coated with a pressure-sensitive adhesive. The balloon is sealed by unrolling the neck, and pressing the neck surfaces together.
- the present invention provides an apparatus and a process whereby a manual worker, or a machine, can quickly and easily evert at least part of the neck of a balloon, as a preliminary step in the preparation of self-sealing balloons as described in GB-A-2200299.
- a process for everting at least part of the neck of a balloon comprising the steps of inserting at least an end portion of a mandrel into the neck of a balloon; and pressing at least a portion of the neck against the mandrel whilst firstly moving the mandrel relative to the balloon in a direction into the balloon body and subsequently moving the mandrel relative to the balloon in a direction out from the balloon body.
- the process may be applied to a balloon with a plain neck, but is especially suitable for conventional balloons provided with an annular collar at the open end of the balloon neck.
- the action of moving the mandrel in a direction into the balloon body causes the neck of the balloon to roll inwardly from the open end.
- reversing the movement of the mandrel does not simply reverse the rolling of the neck, but everts the neck.
- an apparatus for everting at least part of the neck of a balloon comprising a mandrel insertable within the neck of the balloon, pressure applying means for pressing at least a portion of the neck against the mandrel, and means for moving the mandrel in a reciprocating fashion relative to the pressure applying means and in a direction at least along the axis of the mandrel.
- the pressure applying means comprises one or more biased plates.
- the pressure applying means comprises a pair of biased plates.
- the plate is curved, so as to enable the mandrel to be easily located within the pressure applying means.
- a suitable biasing means may include a spring.
- An alternative pressure applying means comprises one or more inflatable collars which can surround a portion of the neck of the balloon when mounted on the mandrel.
- the apparatus may be provided with means for applying, and optionally drying, a layer of a contact adhesive, such as, for example untreated latex, to at least an outer annular part of the everted neck of the balloon.
- a contact adhesive such as, for example untreated latex
- the mandrel is rotatable about its longitudinal axis.
- the rotation of the mandrel will facilitate the application, and optional drying, of the contact adhesive to the everted neck of the balloon.
- the apparatus can also be provided with means for inserting a tube within the neck portion of the balloon.
- the apparatus may be further provided with means for forming the tubes from sheets of suitable flexible material.
- the purpose of the tubes is that they prevent the collapse of the necks during inflation and they also ease the folding down of the necks of the balloons during preparation.
- the tubes may be of a plastics material and may optionally be removed once the balloons are inflated. Plastics tubing is cheap and thus this part may be disposable.
- the tube extends out of the neck of the balloon. This prevents spittle affecting the contact adhesive, if the balloon is to be mouth inflated.
- the tube may also be easily removed if it extends out of the balloon.
- Such a tube is preferably provided with means adapted to form a substantially gas-tight connection with a gas source. Preferably, these means are one part of a bayonet fitting. This arrangement allows for a simple gas tight connection to be made to a suitable gas source such as a helium cylinder.
- the tube is inserted before the neck portion is everted. This may advantageously be achieved by placing a tube over the end of the mandrel, before the mandrel is inserted into the neck of the respective balloon.
- the apparatus may have means for applying a removable protective strip to at least the outer annular portion of the everted neck which has an applied layer of adhesive.
- the removeable protective strip prevents a collection of the balloons, when packaged loose together, from sticking together.
- the strip may simply be removed from the exterior of the balloon's neck prior to inflation.
- an assembly comprising a plurality of balloons each having a tube extending out of its neck wherein the tubes are attached to, or integral with a common member at spaced apart intervals.
- the tubes may form an integral injection moulded comb provided with frangible portions for the ready removal of individual balloons.
- An alternative assembly comprises a plurality of balloons, each having a tube extending out of its neck, wherein the balloons form a bandolier-type arrangement, which enables the balloons to be stored in cassette form for the ready removal of individual balloons.
- the apparatus may be provided with two or more mandrels, each with respective pressure applying means, and means to move each mandrel in a reciprocating fashion relative to each pressure applying means and in a direction at least along the axis of each mandrel.
- a preferred apparatus comprises a plurality of mandrels supported from a common, movable mandrel head; a plurality of pressure applying means supported on a common, movable block; means to apply a layer of self contact adhesive to at least part of the everted neck of each balloon; means to dry the layer of adhesive; means to secure each everted balloon to a removable protective strip; and means to package the secured, everted balloons in either a comb or a cassette form.
- the apparatus essentially comprises an elongate mandrel 1 and a pressure applying means generally shown as 3.
- the mandrel 1 has a tapered end portion (not shown) on which can be mounted a balloon shown generally as 5 in the manner as shown in Figure 1.
- Balloon 5 has a neck 7 and a body 9. The end of the neck 7 is provided with an annular collar 10.
- the pressure applying means 3 comprises a pair of curved plates 11, each pivoted at one end to a frame 13 by means of a suitable hinge 15. Between each of the hinges 15 and the frame 13 is a spring (not shown), which acts against each of the plates 11 and the frame 13. Onto each of the facing surfaces of plates 11 is affixed a thin rubber pad 17. The plates 11 are biased against each other, and thus define a nip 19 between the hinges 15, as shown in Figure 2.
- the end portion of the mandrel 1 is inserted into the neck 7, in a direction towards the balloon body 9, until the balloon 5 is securely mounted on the mandrel 1 as shown in Figure 1.
- the collar 10 is at a first position along the length of the mandrel 1.
- the mandrel 1, with the mounted balloon 5, is then placed into the nip 19, defined by the curved plates 11 of the pressure applying means 3.
- the mandrel 1 is then moved in a direction towards the free ends of the plates 11.
- the free ends of the plates 11 move apart and the rubber pads 17 press against the collar 10 of the mounted balloon 5 in the manner shown in Figure 3. It is apparent that this step can be conducted manually, or by means of a suitable, automated conveyor arrangement (not shown).
- the mandrel 1 Whilst the pads 17 are firmly pressed against the balloon collar 10, the mandrel 1 is moved in a downwards direction, while frame 13 remains in a fixed position. During the initial downward movement, the collar 10 rolls into the neck 7. On a further downward movement, the outer surface of the neck 7 rolls over the collar 10, now within the neck 7. On yet a further downward movement, the outer surface of the neck 11 rolls over itself within the neck. As a result of the downward motion of the mandrel, the neck rolls over itself and so the mandrel advances into the balloon body 9. Thus collar 10 moves in a rolling motion up the mandrel, within the neck 7, to a second position along the length of the mandrel.
- the folded neck of the balloon shown generally as 5 begins to fold over itself, as collar 10 rolls over the unfolded portion of the neck 7.
- the collar 10 moves in a direction from the second position on the mandrel to the first, and in doing so causes the folded neck portion to evert, as shown in Figure 4.
- the mandrel with the mounted balloon is then moved out from and away from the pressing means.
- the everted portion of the neck 7 is now ready for the administration of a suitable contact adhesive (ie. an adhesive which bonds to itself), such as, for example, an untreated latex.
- a suitable contact adhesive ie. an adhesive which bonds to itself
- suitable means not shown
- the balloons are simply removed from the mandrel. The balloons are now prepared and ready for use.
- a tube 21 may be fitted within the neck of the balloon as shown in Figure 5.
- the tube 21 will not only prevent collapse of the balloon neck during inflation, but also prevent spittle affecting the contact adhesive if the balloon is to be inflated by mouth.
- One way of fitting a tube within an everted portion of a neck of a balloon is to mount a tube 21 onto the end portion of the mandrel 1, before the mandrel is inserted into the unfolded neck 7 of the balloon 5.
- a tube 21 onto the end portion of the mandrel 1, before the mandrel is inserted into the unfolded neck 7 of the balloon 5.
- at least part of the neck 7 folds and subsequently unfolds over itself along the length of the tube 21.
- the everted portion of the neck 7 is mounted on the tube 21, as generally shown in Figure 5.
- FIG. 6 A suitable arrangement for preparing a number of balloons simultaneously is shown in Figure 6.
- the machine essentially comprises a plurality of juxtaposed mandrels 23, each supported from a common mandrel head 25, and a plurality of juxtaposed pressure applying means 27, each supported on a common block 29.
- each respective mandrel 1 which may or may not have a mounted tube.
- the mandrel head 25 then swings towards the pressure applying means 27, in the fashion shown in Figure 6, until the collar 10 of each balloon is firmly located between the pair of plates 5 of each pressure applying means.
- Either the mandrel head 25 or the block 29 then moves in an appropriate reciprocating fashion, as described above. The reciprocating motion causes at least a part of the neck of each balloon to evert in the manner described above.
- the mandrel head 25 swings away from the pressure applying means. This causes each mounted balloon to disengage from its respective pressure applying means.
- the everted part of the neck of each balloon, while supported on the mandrel, is now ready for the application of a suitable adhesive, such as, for example, untreated latex.
- each balloon is rotated, and the adhesive is then dried by suitable means (not shown). It will be appreciated that this method of applying adhesive may be used with any balloon having an everted neck, however prepared. Once the adhesive has dried, each prepared balloon can be removed from its respective mandrel either manually or by machine. However, if large quantities of balloons are required, it is preferable to have a machine which automates this removal stage.
- FIG. 7 A suitable machine for automating the removal stage is shown in Figure 7.
- the machine essentially comprises a pair of clamping blocks 31, each having a plurality of recesses 33, and a first web 35 and a second web 37. Webs 35 and 37 run between the clamping blocks 31 in the manner shown in Figure 7.
- the mandrel head 25, supporting the prepared balloons is lowered until the everted parts of the necks of the balloons are located between the webs 35 and 37.
- Clamping blocks 31 are then moved together, and in doing so the recesses 31 force portions of each of the webs 35 and 37 to entrap the everted neck portions of each prepared balloon.
- the web portions located between the recesses are then sealed together, for example by suitable heating means (not shown).
- the prepared balloons are now removably secured to the sealed webs.
- the mandrel head 25 moves upwards, causing the prepared balloons to become free from the mandrels.
- the clamping blocks are then moved apart, and the sealed webs are then advanced, thereby allowing fresh web portions to be located between the blocks.
- the secured balloons are then packaged in a suitable fashion, such as, for example, in a cassette form or comb (not shown).
- a cassette or comb form allows a person or an automated machine to inflate a large number of balloons in a small amount of time.
Landscapes
- Toys (AREA)
Claims (17)
- Verfahren zum Ausbringen bzw. Umlegen wenigstens eines Teils des Halses eines Ballons, mit den Schritten:
Einführen wenigstens eines Endabschnitts eines Dorns (1) in den Hals (7) eines Ballons (5); und
Pressen wenigstens eines Abschnitts des Halses gegen den Dorn (1) während der Dorn (1) zuerst relativ zum Ballon (5) in einer Richtung in den Ballonkörper hinein bewegt wird, und nachfolgendes Bewegen des Dorns (1) relativ zum Ballon (5) in einer Richtung aus dem Ballonkörper heraus. - Verfahren nach Anspruch 1, mit dem weiteren Schritt des Aufbringens einer Schicht eines Kontaktklebers auf wenigstens einen äußeren ringförmigen Teil des umgelegten Halses (7) des Ballons.
- Verfahren nach Anspruch 2, mit dem weiteren Schritt des Aufbringens eines entfernbaren Schutzstreifens auf wenigstens den äußeren ringförmigen Teil des umgelegten Halses (7).
- Verfahren nach einem der Ansprüche 1 bis 3, wobei der Ballon (5) einen Kragen (10) an dem offenen Ende des Halses (7) hat.
- Vorrichtung zum Ausbringen bzw. Umlegen wenigstens eines Teils eines Halses eines Ballons, mit einem langgestreckten Dorn (1) mit einem Endabschnitt, der in den Hals (7) eines Ballons (5) einsetzbar ist; und einer Druck-Aufbringeinrichtung (3; 27) zum Pressen wenigstens eines Abschnitts des Halses (7) gegen den Dorn (1); und
einer Einrichtung zum Bewegen des Dorns (1) in einer hin- und hergehenden Weise relativ zu der Druck-Aufbringeinrichtung (3; 27) und in einer Richtung wenigstens längs der Achse des Dorns (1). - Vorrichtung nach Anspruch 5, wobei die Druck-Aufbringeinrichtung (3; 27) eine oder mehrere vorgespannte Platten (11) aufweist.
- Vorrichtung nach Anspruch 6, wobei die Druck-Aufbringeinrichtung (3; 27) ein paar von vorgespannten Platten (11) aufweist.
- Vorrichtung nach einem der Ansprüche 5 bis 7, wobei jede Platte (11) gekrümmt ist.
- Vorrichtung nach einem der Ansprüche 5 bis 8, wobei die oder jede Platte (11) vorgespannt ist durch ein Gelenk (15) und eine Federanordnung.
- Vorrichtung nach einem der Ansprüche 5 bis 9, mit einer Vielzahl von langgestreckten Dornen (1) und entsprechenden Druckeinrichtungen (27).
- Vorrichtung nach Anspruch 10, wobei jeder Dorn (1) getragen ist von einem gemeinsamen beweglichen Dornkopf (25), und jede Druck-Aufbringeinrichtung (27) gehaltert ist auf einem gemeinsamen beweglichen Block (29).
- Vorrichtung nach einem der Ansprüche 5 bis 11, ferner mit einer Einrichtung zum Aufbringen und gewünschtenfalls Trocknen eines Klebstoffs auf dem umgelegten Abschnitt des oder jedes Halses.
- Vorrichtung nach einem der Ansprüche 5 bis 12, wobei ein Rohr (21) über dem Ende des oder jedes Dorns (1) angeordnet ist, bevor der oder jeder Dorn in den Hals (7) des oder jedes jeweiligen Ballons (5) engesetzt ist.
- Vorrichtung nach einem der Ansprüche 5 bis 13, ferner mit einer Einrichtung zum Aufbringen eines entfernbaren Schutzstreifens auf wenigstens den Abschnitt des oder jedes ausgebrachten Halses (7).
- Vorrichtung nach einem der Ansprüche 5 bis 14, ferner mit einer Einrichtung zum Packen des oder jedes Ballons, der an dem Schutzstreifen angebracht ist.
- Verfahren nach Anspruch 2 oder Anspruch 3, wobei der Klebstoff durch ein Verfahren aufgebracht wird, das aufweist das Drehen des Dorns (1) mit dem Ballon (5) darauf, und das Aufbringen des Klebstoffs auf den ausgebrachten Hals (7) von einer stationären Quelle in der Nähe des Dorns (1).
- Verfahren nach einem der Ansprüche 1 bis 4 oder Anspruch 16, wobei die Hälse (7) einer Anzahl von Ballons (5) ausgebracht werden und die ausgebrachten Ballons durch ein Verfahren an einem Gewebe bzw. einer Bahn befestigt werden, welches aufweist das Anordnen der Hälse (7) der Ballons, die an den Dornen angebracht sind, zwischen zwei Bahnen (35, 37) und Abdichten bzw. Verbinden der beiden Bahnen (35, 37) miteinander in dem Bereich zwischen benachbarten Ballons.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89908440T ATE104164T1 (de) | 1988-07-11 | 1989-07-11 | Verfahren und vorrichtung zum praeparieren eines ballons. |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8816470 | 1988-07-11 | ||
GB888816470A GB8816470D0 (en) | 1988-07-11 | 1988-07-11 | Process & apparatus for preparation of balloons |
PCT/GB1989/000733 WO1990000430A1 (en) | 1988-07-11 | 1989-07-11 | Process and apparatus for the preparation of balloons |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0428555A1 EP0428555A1 (de) | 1991-05-29 |
EP0428555B1 true EP0428555B1 (de) | 1994-04-13 |
Family
ID=10640247
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89908440A Expired - Lifetime EP0428555B1 (de) | 1988-07-11 | 1989-07-11 | Verfahren und vorrichtung zum präparieren eines ballons |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0428555B1 (de) |
JP (1) | JP2643507B2 (de) |
AU (1) | AU620128B2 (de) |
DE (1) | DE68914674T2 (de) |
GB (1) | GB8816470D0 (de) |
WO (1) | WO1990000430A1 (de) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9301810D0 (en) * | 1993-01-29 | 1993-03-17 | Lang Philip E | A sealable balloon neck,and a method and apparatus for the preparation thereof |
US5551982A (en) * | 1994-03-31 | 1996-09-03 | Applied Materials, Inc. | Semiconductor wafer process chamber with susceptor back coating |
US10675549B1 (en) | 2012-07-29 | 2020-06-09 | Wesley Warner | Self-sealing balloon and method of manufacture |
US9174141B2 (en) | 2012-07-29 | 2015-11-03 | Wesley Warner | Self-sealing balloon and method of manufacture |
US9844737B1 (en) | 2012-07-29 | 2017-12-19 | Wesley Warner | Self-sealing balloon and method of manufacture |
US10328353B2 (en) | 2012-07-29 | 2019-06-25 | Wesley Warner | Self-sealing balloon and method of manufacture |
US20160368628A1 (en) | 2015-06-19 | 2016-12-22 | Telebrands Corp. | System, device, and method for filling at least one balloon |
US9776744B2 (en) | 2015-06-19 | 2017-10-03 | Telebrands Corp. | Container sealing device |
US20160368627A1 (en) * | 2015-06-19 | 2016-12-22 | Telebrands Corp. | System, device, and method for filling at least one balloon |
US10259600B2 (en) | 2015-06-19 | 2019-04-16 | Telebrands Corp. | Container sealing device |
USD793484S1 (en) | 2015-11-20 | 2017-08-01 | Telebrands Corp. | Device for filling multiple water balloons |
USD793483S1 (en) | 2015-11-20 | 2017-08-01 | Telebrands Corp. | Device for filling multiple water balloons |
USD793485S1 (en) | 2015-11-20 | 2017-08-01 | Telebrands Corp. | Device for filling multiple water balloons |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3088242A (en) * | 1958-08-13 | 1963-05-07 | John J Mcglew | Self-seal balloon |
US3108396A (en) * | 1958-12-24 | 1963-10-29 | Dorman Isidore | Toy balloon sealing means and method |
FR1498473A (fr) * | 1966-07-25 | 1967-10-20 | Ballons gonflables cylindriques et ensembles réalisés à l'aide de ces ballons |
-
1988
- 1988-07-11 GB GB888816470A patent/GB8816470D0/en active Pending
-
1989
- 1989-07-11 AU AU39688/89A patent/AU620128B2/en not_active Ceased
- 1989-07-11 DE DE68914674T patent/DE68914674T2/de not_active Expired - Fee Related
- 1989-07-11 JP JP50785089A patent/JP2643507B2/ja not_active Expired - Lifetime
- 1989-07-11 EP EP89908440A patent/EP0428555B1/de not_active Expired - Lifetime
- 1989-07-11 WO PCT/GB1989/000733 patent/WO1990000430A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
JPH03505831A (ja) | 1991-12-19 |
AU620128B2 (en) | 1992-02-13 |
AU3968889A (en) | 1990-02-05 |
DE68914674T2 (de) | 1994-07-28 |
JP2643507B2 (ja) | 1997-08-20 |
DE68914674D1 (de) | 1994-05-19 |
WO1990000430A1 (en) | 1990-01-25 |
GB8816470D0 (en) | 1988-08-17 |
EP0428555A1 (de) | 1991-05-29 |
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