EP0421889A2 - Méthode pour former une couche de supraconducteur d'oxyde continue avec des régions différentes pour dispositifs supraconducteurs - Google Patents
Méthode pour former une couche de supraconducteur d'oxyde continue avec des régions différentes pour dispositifs supraconducteurs Download PDFInfo
- Publication number
- EP0421889A2 EP0421889A2 EP90402787A EP90402787A EP0421889A2 EP 0421889 A2 EP0421889 A2 EP 0421889A2 EP 90402787 A EP90402787 A EP 90402787A EP 90402787 A EP90402787 A EP 90402787A EP 0421889 A2 EP0421889 A2 EP 0421889A2
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- EP
- European Patent Office
- Prior art keywords
- thin film
- oxide superconductor
- superconductor thin
- thickness
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002887 superconductor Substances 0.000 title claims abstract description 141
- 238000000034 method Methods 0.000 title claims abstract description 62
- 239000010409 thin film Substances 0.000 claims abstract description 108
- 239000002184 metal Substances 0.000 claims abstract description 36
- 229910052751 metal Inorganic materials 0.000 claims abstract description 36
- 230000008569 process Effects 0.000 claims abstract description 28
- 238000005530 etching Methods 0.000 claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 238000001312 dry etching Methods 0.000 claims abstract description 4
- 238000010884 ion-beam technique Methods 0.000 claims description 5
- 230000001133 acceleration Effects 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 238000000059 patterning Methods 0.000 claims description 3
- 238000009751 slip forming Methods 0.000 claims 1
- 238000000427 thin-film deposition Methods 0.000 claims 1
- 239000010931 gold Substances 0.000 description 14
- 229920002120 photoresistant polymer Polymers 0.000 description 14
- 239000010408 film Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000004544 sputter deposition Methods 0.000 description 6
- 230000002411 adverse Effects 0.000 description 4
- 238000007738 vacuum evaporation Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000000206 photolithography Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910015901 Bi-Sr-Ca-Cu-O Inorganic materials 0.000 description 2
- 229910002480 Cu-O Inorganic materials 0.000 description 2
- 229910002370 SrTiO3 Inorganic materials 0.000 description 2
- 229910009203 Y-Ba-Cu-O Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000000992 sputter etching Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N60/00—Superconducting devices
- H10N60/01—Manufacture or treatment
- H10N60/0268—Manufacture or treatment of devices comprising copper oxide
- H10N60/0661—Processes performed after copper oxide formation, e.g. patterning
- H10N60/0688—Etching
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N60/00—Superconducting devices
- H10N60/01—Manufacture or treatment
- H10N60/0912—Manufacture or treatment of Josephson-effect devices
- H10N60/0941—Manufacture or treatment of Josephson-effect devices comprising high-Tc ceramic materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S505/00—Superconductor technology: apparatus, material, process
- Y10S505/725—Process of making or treating high tc, above 30 k, superconducting shaped material, article, or device
- Y10S505/728—Etching
Definitions
- the present invention relates to a method for manufacturing a superconductor device, and more specifically to a method for forming an oxide superconductor thin film having different thickness portions, in a process for manufacturing a superconductor device.
- a superconductor used in the superconductor devices is composed of an oxide superconductor such as Y-Ba-Cu-O oxide superconductor typified by Y1Ba2Cu3O x , Bi-Sr-Ca-Cu-O oxide superconductor typified by Bi2Sr2Ca2Cu3O y , and Tl-Ba-Ca-Cu-O oxide superconductor typified by Tl2Ba2Ca2Cu3O z , formation and working of the thin film have been performed as follows:
- a thin film of an oxide superconductor is formed by using a physical vapor deposition process such as a sputtering and molecular beam epitaxy, or a chemical vapor deposition process such as metal organic chemical vapor deposition (MO-CVD).
- a heat treatment can be performed in order to improve characteristics of the oxide superconductor thin film.
- a thin film having a thickness equal to the thickness of the thinnest thickness portion of the different thickness portions is first formed, and thereafter, a mask is deposited on a portion to be left as the thinnest portion, and an oxide superconductor is further deposited on the thin film having a thickness equal to the thinnest thickness.
- an oxide superconductor thin film having a central portion of 400nm thickness and opposite side portions of 100nm thickness is formed on the substrate by sputtering or another process.
- a portion of the thus deposited oxide superconductor thin film other than a central portion is masked with a photoresist, and an oxide superconductor is further deposited by sputtering or another thickness, so that the central portion is constituted of an oxide superconductor thin film having a thickness of 400nm.
- the conventional process is featured in which an oxide superconductor thin film having a thickness of the thinnest thickness portion is formed on a whole surface of the substrate, and thereafter, an unnecessary portion of the formed oxide superconductor thin film is covered with a mask and an oxide superconductor is selectively further deposited on only a required portion of the formed oxide superconductor thin film.
- the oxide superconductor thin film having different thickness portions is formed.
- the above mentioned process has been disadvantageous in that reaction occurs at an boundary between a photoresist used as the mask and a firstly formed oxide superconductor thin film, so that the characteristics of the oxide superconductor is deteriorated.
- a surface of the first formed oxide superconductor thin film is in contact with an alkaline developing liquid, a resist removing liquid and a cleaning water.
- An upper oxide superconductor layer is deposited on the surface of the lower oxide superconductor thin film which had once been in contact with these kinds of liquid.
- a discontinuous boundary is formed between the upper oxide superconductor layer and the lower oxide superconductor thin film, and a uniform oxide superconductor thin film having a thick portion and a thin portion cannot be obtained.
- a method for forming an oxide superconductor thin film having different thickness portions in a process for manufacturing a superconductor device, the method including the step of etching a portion of the oxide superconductor thin film so that the oxide superconductor thin film has a thin thickness portion.
- an oxide superconductor thin film is formed on a substrate, and a portion of the oxide superconductor thin film formed on the substrate is etched so that a convex portion having a thickness larger than a peripheral thin portion and having a contour defined by the peripheral thin portion is formed. At least a portion of an oxide superconductor thin film device is formed in the convex portion.
- the above mentioned method in accordance with the present invention is characterized in that only a portion of a relatively thick oxide superconductor thin film formed on a whole is etched so as to have a reduced thickness, in order to form an oxide superconductor thin film having different thickness portions in the process for manufacturing a superconductor device. Accordingly, in the case of forming an oxide superconductor thin film having different thickness portions on a given surface in accordance with the present invention, growth of an oxide superconductor thin film on the given surface can be performed in one step. Namely, an oxide superconductor thin film having a thickness equal to that of the thickest portion of the oxide superconductor thin film having different thickness portions is formed with the one step. Thereafter, a thin portion and/or unnecessary portion is formed or removed by electively etching the oxide superconductor thin film having the thickness equal to that of the thickest portion.
- the fact that the growth of an oxide superconductor thin film on the given surface is performed in one step, means that a single continuous or integral layer or sheet of an oxide superconductor thin film is grown in one step. Therefore, for a structure in which a non-superconductor is integrally sandwiched between a pair of superconductor thin films, for example a tunnel junction type superconducting weak link structure, a required number of superconductor thin films are formed in a single continuous step.
- these layers are preferably formed in a manner that the substrate is never taken out of a chamber of a film formation or deposition device until an uppermost layer is deposited, so that the oxide superconductor will never be contacted with air in the course of the oxide superconductor thin film formation process.
- a uniform oxide superconductor thin film having a good crystalline condition can be obtained. Therefore, in case of forming a junction such as superconducting weak link junction between an oxide superconductor thin film and another thin film, not only a uniform oxide superconductor thin film having a good crystalline condition can be obtained, but also a good boundary can be formed at the junction portion.
- the superconduction property of the oxide suporconductor thin film is greatly influenced by a crystalline orientation and composition. Therefore, an oxide superconductor thin film formed by many times of separate deposition cannot have a continuous crystal, and a boundary adversely occurs, with the result that a uniform superconduction property cannot be obtained. Needless to say, this oxide superconductor thin film is not suitable to form a superconducting weak link junction.
- the characteristics of the superconducting weak link junction is also greatly influenced by a condition of boundary in the junction portion. Particularly, if a surface or portion to be brought into the boundary is contacted with air in the manufacturing process and the surface condition is caused to adversely change, a desired characteristics of the superconducting weak link junction cannot be obtained. However, if the method in accordance with the present invention is used, this problem can be overcome.
- the method in accordance with the present invention can be applied to any type of oxide superconductor.
- the present invention can be applied to Y-Ba-Cu-O oxide superconductor typified by Y1Ba2Cu3O x (6 ⁇ x ⁇ 7), Bi-Sr-Ca-Cu-O oxide superconductor typified by Bi2Sr2Ca2Cu3O y (7 ⁇ y ⁇ 10), and Tl-Ba-Ca-Cu-O oxide superconductor typified by Tl2Ba2Ca2Cu3O ⁇ (7 ⁇ z ⁇ 10).
- the present invention is in no way limited to these oxide superconductors.
- the etching is preferably performed by a dry etching process, for example, an ion beam etching using inert gas such as Ar (argon), an ECR (electron cycroton resonance) etching, an RF (radio frequency) plasma etching, etc.
- Ar argon
- ECR electron cycroton resonance
- RF radio frequency
- an acceleration voltage for Ar-ions is preferred to be in a range of 600 V to 800 V. If the acceleration voltage is less than 600 V, the time for etching becomes too long, and if the acceleration voltage is greater than 800 V, the oxide superconductor crystal of a region in proximity of a surface is destroyed.
- a surface of the oxide superconductor thin film is preferably protected by covering the thin film surface with a film of metal which does not give an adverse influence to the oxide superconductor.
- This is particularly advantageous in the case of performing the etching after patterning a mask by use of a photolithography. If the oxide superconductor thin film surface is covered with the metal film, the oxide superconductor thin film will never be contacted with an alkaline developing liquid, a resist removing liquid and a cleaning water which are used in the photolithography process of the mask patterning. Therefore, even after the shaping of the oxide superconductor thin film, the superconducting characteristics will be not deteriorated.
- the metal used as the protection metal film is preferably Ag (silver), since Ag is remarkably low in reactivity to the oxide superconductor, and since Ag has a low contact resistance with the oxide superconductor and an excellent adhesion or bonding property to the oxide superconductor.
- a metal material having a low reactivity to oxide superconductors for example, Al, In, Zn, Cu, Ni, Au, Pt, Ti, Pd, etc.
- the protection metal film can be formed by means of an evaporation process.
- Oxide superconductor thin films were worked in accordance with the method of the present invention, and superconducting characteristics of the worked oxide superconductor thin films was measured.
- Figures 1A to 1D illustrate the process for forming on a substrate an oxide superconductor thin filin having a central portion of 400nm thickness and opposite side portions of 100nm thickness, similarly to that formed in the conventional process explained hereinbefore.
- an oxide superconductor thin film 1 having a thickness of 400nm was formed on a substrate 2 by sputtering.
- a metal film 3 of 100nm thickness was formed on an upper surface of the oxide superconductor thin film 1 by a vacuum evaporation process.
- a photoresist mask 8 was formed on a central portion of the metal film 3.
- Ar-ion beam etching was performed using the photoresist layer 8 as a mask, until opposite side portions of the oxide superconductor thin film 1 have a thickness of 100nm, as shown in Figure 1D.
- a remaining photoresist mask 8 is ashed by using O2 plasma, so that the remaining photoresist mask 8 is completely removed. With removal of the remaining photoresist mask 8 by a dry process, the oxide superconductor thin film 1 will in no way be in contact with a photoresist removing liquid and a cleaning water.
- the oxide superconductor thin film having a thick portion 1A and a thin portion 1B is formed.
- a superconducting device is formed on or in the thick portion 1A, and the thin portion 1B constitutes a lower side electrode of the superconducting device, or a lead conductor from the thick portion 1A.
- an electrode or contact for connection is formed on the thin portion 1B.
- the oxide superconductor thin film 1 was formed of Y1Ba2Cu3O x oxide superconductor, Bi2Sr2Ca2Cu3O y oxide superconductor and Tl2Ba2Ca2Cu3O z oxide superconductor, respectively.
- a MgO single crystalline substrate (100) is used as the substrate 2.
- the metal film 3 was formed of Au (gold).
- oxide superconductor thin films having the same shape were formed in accordance with the conventional method explained hereinbefore, and the superconducting characteristics of these thin films were measured.
- the following table shows the superconducting characteristics of the oxide superconductor thin films worked in accordance with the present invention method and in accordance with the conventional method.
- the oxide superconductor thin films worked in accordance with the present invention method have the superconducting characteristics more excellent than the conventional ones.
- FIG. 2 there is shown a diagrammatic section view illustrating one example of a superconducting device formed by utilizing the method in accordance with the present invention.
- the superconducting device shown in Figure 2 is a so-called Josephson mixer.
- the shown device includes a first superconducting electrode 11 formed of Y1Ba2Cu3O x thin film formed on a MgO substrate 2, an Au thin layer 4 formed on a central portion of the first superconducting electrode 11, and a second superconducting electrode 12 formed of Y1Ba2Cu3O x thin film formed on the Au thin layer 4 without directly contacting with the first superconducting electrode 11.
- a pair of metal electrodes 5 and 6 are located on the second superconducting electrode 12.
- another pair of metal electrodes 7 and 8 having connecting terminals 17 and 18, respectively, are provided respectively on opposite end portions of the first superconducting electrode 11 on which the Au layer 4 is not formed.
- the metal electrodes 5 and 6 excluding an upper surface thereof are covered with an insulating layer 9, and metal layers 15 and 16 are formed on the insulating layer 9 so as to extend from the upper surfaces of the metal electrode 5 and 6 and to be connected to connecting terminals 27 and 28 in proximity of the metal electrodes 7 and 8, respectively.
- the maximum thickness of each of the first and second superconducting electroes 11 and 12 was 400nm, and the thickness of the Au layer 4 was 10nm.
- the metal electrodes 5 and 6 formed on the second superconducting electrode 12 were formed in a double-layered structure having an lower layer of Ag in contact with the second superconducting electrode 12 and an upper layer Au formed on the Ag lower layer. This double-layered metal electrode does not give an adverse influence to the compound oxide superconductor, and has an excellent adhesion or bonding property to the compound oxide superconductor.
- a first Y1Ba2Cu3O x superconductor thin film 111, an Au layer 4, a second Y1Ba2Cu3O x superconductor thin film 112 and a metal layer 114 were formed on the MgO substrate 2 in the named order in such a manner that each layer completely covers an upper surface of a just-lower layer.
- the first Y1Ba2Cu3O x superconductor thin film 111 and the second Y1Ba2Cu3O x superconductor thin film 112 were deposited to have a thickness of 400nm by sputtering, respectively.
- the Au layer 4 was deposited to have a thickness of 10nm by vacuum evaporation.
- the metal layer 114 was formed by depositing an Ag layer of 150nm thickness by vacuum evaporation and also depositing an Au layer of 150nm thickness on the Ag layer by vacuum evaporation. Thereafter, a photoresist layer 8 is deposited on the metal layer 114, as shown in Figure 3A.
- the photoresist layer 114 was patterned so that resist masks 81 and 82 are left on portions of the metal layer 114 which become the metal electrodes in future.
- Ar-ion etching was performed by using the remaining resists 81 and 82 as a mask, so that the metal layer 114 not covered with the remaining resists 81 and 82 are completely removed.
- the metal electrodes 5 and 6 are formed as shown in Figure 3C.
- a photoresist layer 83 is deposited on the second Y1Ba2Cu3O x superconductor thin film 112 so as to cover the metal electrodes 5 and 6.
- Ar-ion etching was performed by using the photoresist 83 as a mask, so that the second Y1Ba2Cu3O x superconductor thin film 112 and the Au layer 4 which are not covered with the photoresist 83, were completely removed, and the first Y1Ba2Cu3O x superconductor thin film 111 which is not covered with the photoresist 83, was partially removed, with the result that the first superconducting electrode 11 and the second superconducting electrode 12 are formed as shown in Figure 3E.
- an insulating layer 9 is formed to cover portions excluding opposite end portions 37 and 38 of the first superconducting electrode 11 and an upper surface of each of the metal electrodes 5 and 6.
- metal electrodes 7 and 8 are formed on exposed opposite end portions 37 and 38 of the first superconducting electrode 11, and metal layers 15 and 16 are formed to cover the upper surface of the metal electrodes 5 and 6 and to extend from the upper surface of the metal electrodes 5 and 6 on the surface of the insulating layer 9.
- the superconducting device shown in Figure 2 is completed.
- the above mentioned superconducting device responded to a microwave of 9GHz and stably operated with a clear Shapiro step.
- the Au layer 4 can be replaced with a SrTiO3 layer of 1nm thickness.
- This superconducting device can be formed by depositing the SrTiO3 layer of 1nm thickness on the first Y1Ba2Cu3O x superconductor thin film 111 by sputtering, in place of depositing the Au layer 4, when the stacked structure illustrated in Figure 3A is formed.
- the method in accordance with the present invention can work an oxide superconductor thin film without deteriorating characteristics of the oxide superconductor. Therefore, the method in accordance with the present invention makes it easy to form a superconducting device by a fine working of a superconductor thin film, and therefore, utilization of superconduction technique is further facilitated.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Superconductor Devices And Manufacturing Methods Thereof (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP261491/89 | 1989-10-06 | ||
JP1261491A JPH03124077A (ja) | 1989-10-06 | 1989-10-06 | 超電導素子の作製方法 |
JP296740/89 | 1989-11-15 | ||
JP1296740A JPH03156983A (ja) | 1989-11-15 | 1989-11-15 | 超電導素子 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0421889A2 true EP0421889A2 (fr) | 1991-04-10 |
EP0421889A3 EP0421889A3 (en) | 1991-12-11 |
EP0421889B1 EP0421889B1 (fr) | 1996-03-27 |
Family
ID=26545106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90402787A Expired - Lifetime EP0421889B1 (fr) | 1989-10-06 | 1990-10-08 | Méthode pour former une couche de supraconducteur d'oxyde continue avec des régions différentes pour dispositifs supraconducteurs |
Country Status (4)
Country | Link |
---|---|
US (1) | US5418213A (fr) |
EP (1) | EP0421889B1 (fr) |
CA (1) | CA2027067C (fr) |
DE (1) | DE69026179T2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0445350A2 (fr) * | 1990-03-09 | 1991-09-11 | The Regents Of The University Of California | Passage supraconducteur microélectronique et bobine |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1416417A3 (fr) * | 2002-10-08 | 2007-03-07 | Bayer HealthCare LLC | Procédé et systèmes pour le traitement de données de diagnostic et de traitement de patients |
US7521932B2 (en) | 2003-05-06 | 2009-04-21 | The Penn State Research Foundation | Method and system for adjusting the fundamental symmetric mode of coupled high temperature superconductor coils |
US7295085B2 (en) * | 2003-08-21 | 2007-11-13 | E.I. Du Pont De Nemours And Company | Process for making high temperature superconductor devices each having a line oriented in a spiral fashion |
US7332910B2 (en) * | 2003-11-24 | 2008-02-19 | E.I. Du Pont De Nemours And Company | Frequency detection system comprising circuitry for adjusting the resonance frequency of a high temperature superconductor self-resonant coil |
US20070245374A1 (en) * | 2003-11-24 | 2007-10-18 | Inventec Corporation | Video program subtitle tex recording method and system |
US7301344B2 (en) | 2003-11-24 | 2007-11-27 | E.I. Du Pont De Nemours & Co. | Q-damping circuit including a high temperature superconductor coil for damping a high temperature superconductor self-resonant coil in a nuclear quadrupole resonance detection system |
WO2005059582A1 (fr) * | 2003-12-15 | 2005-06-30 | E.I. Dupont De Nemours And Company | Utilisation de plusieurs detecteurs dans un systeme de detection a resonance quadripole nucleaire visant l'augmentation de la vitesse de mesure |
EP1711840A2 (fr) * | 2004-02-04 | 2006-10-18 | E.I.Du pont de nemours and company | L'utilisation de deux capteurs ou plus dans un système de détection de résonance nucléaire à quadrupôle afin d'améliorer un rapport signal sur bruit |
WO2005078469A1 (fr) * | 2004-02-04 | 2005-08-25 | E.I. Dupont De Nemours And Company | Utilisation d'au moins deux capteurs pour la detection de signaux de resonance quadrupolaire nucleaire d'un compose cible |
US7265549B2 (en) | 2004-04-30 | 2007-09-04 | E. I. Du Pont De Nemours And Company | Scanning a band of frequencies using an array of high temperature superconductor sensors tuned to the same frequency |
EP1740967A2 (fr) * | 2004-04-30 | 2007-01-10 | E.I.Du pont de nemours and company | Procedes et appareil pour balayer une bande de frequences en utilisant un reseau de capteurs supraconducteurs haute temperature |
US7279897B2 (en) * | 2004-04-30 | 2007-10-09 | E. I. Du Pont De Nemours And Company | Scanning a band of frequencies using an array of high temperature superconductor sensors tuned to different frequencies |
EP1825288A2 (fr) | 2004-12-03 | 2007-08-29 | E.I. Dupont De Nemours And Company | Procede pour la reduction du couplage entre des bobines d'excitation et de reception d'un systeme de detection par resonance quadripolaire nucleaire |
EP1831714A1 (fr) * | 2004-12-13 | 2007-09-12 | E.I. Dupont De Nemours And Company | Alarme aux masques metalliques d'un systeme de detection de la contrebande rqn/rayons x |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0366949A1 (fr) * | 1988-10-03 | 1990-05-09 | Matsushita Electric Industrial Co., Ltd. | Dispositif Josephson et procédé de sa fabrication |
EP0397186A2 (fr) * | 1989-05-12 | 1990-11-14 | Matsushita Electric Industrial Co., Ltd. | Dispositif supraconducteur et méthode pour sa fabrication |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5041188A (en) * | 1989-03-02 | 1991-08-20 | Santa Barbara Research Center | High temperature superconductor detector fabrication process |
-
1990
- 1990-10-05 CA CA002027067A patent/CA2027067C/fr not_active Expired - Fee Related
- 1990-10-08 DE DE69026179T patent/DE69026179T2/de not_active Expired - Fee Related
- 1990-10-08 EP EP90402787A patent/EP0421889B1/fr not_active Expired - Lifetime
-
1993
- 1993-05-18 US US08/064,331 patent/US5418213A/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0366949A1 (fr) * | 1988-10-03 | 1990-05-09 | Matsushita Electric Industrial Co., Ltd. | Dispositif Josephson et procédé de sa fabrication |
EP0397186A2 (fr) * | 1989-05-12 | 1990-11-14 | Matsushita Electric Industrial Co., Ltd. | Dispositif supraconducteur et méthode pour sa fabrication |
Non-Patent Citations (2)
Title |
---|
1989 PROCEEDINGS OF THE 39TH ELECTRONIC COMPONENTS CONFERENCE vol. 39, May 22, 1989, HOUSTON, US pages 7 - 12; H. TSUGE ET AL.: 'Microfabrication processes for high-tc superconducting films ' * |
JOURNAL OF PHYSICS D. APPLIED PHYSICS. vol. 20, no. 10, October 14, 1987, LETCHWORTH GB pages 1330 - 1335; M.G. BLAMIRE ET AL.: 'Fabrication and properties of superconducting device structures in YBa2Cu3O7-x thin films ' * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0445350A2 (fr) * | 1990-03-09 | 1991-09-11 | The Regents Of The University Of California | Passage supraconducteur microélectronique et bobine |
EP0445350A3 (en) * | 1990-03-09 | 1991-12-11 | The Regents Of The University Of California | Microelectronic superconducting crossover and coil |
Also Published As
Publication number | Publication date |
---|---|
CA2027067C (fr) | 1996-07-23 |
DE69026179D1 (de) | 1996-05-02 |
EP0421889A3 (en) | 1991-12-11 |
EP0421889B1 (fr) | 1996-03-27 |
US5418213A (en) | 1995-05-23 |
DE69026179T2 (de) | 1996-10-10 |
CA2027067A1 (fr) | 1991-04-07 |
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