EP0410845B1 - Rückgewinnung von dem aus einer Anlage abgeführten Kohlendioxyd unter Verwendung von Membranen - Google Patents
Rückgewinnung von dem aus einer Anlage abgeführten Kohlendioxyd unter Verwendung von Membranen Download PDFInfo
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- EP0410845B1 EP0410845B1 EP90402043A EP90402043A EP0410845B1 EP 0410845 B1 EP0410845 B1 EP 0410845B1 EP 90402043 A EP90402043 A EP 90402043A EP 90402043 A EP90402043 A EP 90402043A EP 0410845 B1 EP0410845 B1 EP 0410845B1
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 186
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 93
- 239000001569 carbon dioxide Substances 0.000 title claims description 86
- 239000012528 membrane Substances 0.000 title claims description 54
- 238000011084 recovery Methods 0.000 title description 25
- 238000000034 method Methods 0.000 claims description 26
- 238000000926 separation method Methods 0.000 claims description 26
- 239000012466 permeate Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 22
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 4
- 239000012510 hollow fiber Substances 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 239000008246 gaseous mixture Substances 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims 1
- 229920001721 polyimide Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000007789 gas Substances 0.000 description 49
- 239000000047 product Substances 0.000 description 12
- 239000002912 waste gas Substances 0.000 description 9
- 238000004821 distillation Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011070 membrane recovery Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/0605—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
- F25J3/0625—H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/067—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/40—Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/80—Processes or apparatus using other separation and/or other processing means using membrane, i.e. including a permeation step
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/82—Processes or apparatus using other separation and/or other processing means using a reactor with combustion or catalytic reaction
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/70—Flue or combustion exhaust gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/04—Recovery of liquid products
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/80—Separating impurities from carbon dioxide, e.g. H2O or water-soluble contaminants
- F25J2220/82—Separating low boiling, i.e. more volatile components, e.g. He, H2, CO, Air gases, CH4
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/928—Recovery of carbon dioxide
- Y10S62/929—From natural gas
Definitions
- the present invention pertains to a passive membrane system which may be used to recover carbon dioxide from a carbon dioxide plant vent gas stream.
- CO2 carbon dioxide
- a variety of techniques have been used to separate CO2 from the mixture. For example, when the amount of CO2 present in the gas mixture is low, and purification cannot be achieved directly by cooling and partial condensation, it is possible to scrub the gas mixture with a suitable solvent to dissolve the CO2, and then to strip the CO2 from the solution so obtained. The carbon dioxide obtained can then be compressed, dried, cooled and further purified by partial condensation or distillation.
- the gas mixture contains a high amount of CO2, however, the gas mixture may be compressed and then dried by absorption or other means. Finally, after removing undesirable impurities such as sulfur containing compounds, the mixture is cooled and after distillation CO2 is obtained as a bottoms product. Unfortunately, the overhead product of the distillation column will always contain a significant amount of CO2 which is inevitably wasted. This problem is particularly acute in conventional CO2 liquifaction plants.
- CO2 liquifaction plant In a typical CO2 liquifaction plant, a significant percentage of the CO2 feed is lost as stripper vent gas. For example, in a 200 ton/day CO2 liquifaction plant, about 10 to 15% of the CO2 feed is lost.
- the composition of this dry waste gas steam is usually 75% or more of CO2 with the remainder being N2, O2, H2, and CH4 with trace amounts of NH3, CO and sulfur containing compounds.
- carbon dioxide is recovered from gas mixtures by subjecting the gas mixture to membrane separation, recovering from the membrane separation a permeate having a carbon dioxide concentration between the equilibrium concentration and about 98% by volume and then distilling the permeate at subambient temperature above the freezing temperature of the permeate and recovering carbon dioxide as a liquid bottoms product of the distillation.
- FIGURE 1 illustrates the effect of temperature on gaseous separation factors for mixtures of CO2/N2, CO2/O2 and CO2/H2.
- FIGURE 2 illustrates a single-stage membrane CO2 recovery unit in accordance with the present invention.
- FIGURE 3 illustrates a dual-stage membrane CO2 recovery unit in accordance with the present invention.
- FIGURE 4 illustrates the performance of the present single-stage and dual-stage membrane CO2 recovery units of the present invention by displaying the recovery as a function of product purity.
- the process of the present invention utilizes a semi-permeable gas membrane to recover carbon dioxide from a waste gas stream of a CO2 liquifaction plant.
- the recovery systems of the present invention are completely passive in that they contain no moving parts and use only the pressure energy of the waste gas stream to effect separation of CO2 from the gas mixture.
- the recovery systems of the present invention are advantageously operated at about the CO2 plant temperature in order to enhance the CO2/impurity separation and to improve process economics.
- the degree of separation achieved by the present invention may be further increased by operating the membrane at the cold temperature of the off-gas stream. The enriched CO2 strain that is produced by the membrane is then recycled back to the feed side of the liquifaction plant at a purity compatible with the feed gas stream to the plant.
- FIGURE 1 illustrates the effect of temperature on various separation factors for gaseous mixtures of CO2/N2, CO2/O2 and CO2/H2. With decreasing temperature, an improved separation factor is obtained. Thus, no external cooling of the gas is required in the present invention to achieve these high separation factors inasmuch as the vent gas temperature is already at low temperature, i.e., about -18.9°C (-2°F). Hence, the present CO2 recovery units enjoy very favorable process economics.
- a single-stage membrane recovery unit of the present invention is illustrated in Figure 2. This recovery system and the operation thereof will now be described.
- the carbon dioxide-containing feed gas mixture is provided through a feed header pipeline to a compressor 1 and then the compressed mixture is fed via pipeline 2 to condenser 3 which contains refrigeration unit 6, an exit 4 at the bottom of the condenser for removal of liquid CO2, and pipeline 5 through which the overhead stream or vent gas stream passes at elevated pressure through pressure regulator 7 to separation membrane 8.
- the term "elevated pressure” means that the pressure of the vent gas is sufficient to facilitate permeation of CO2 through the separation membrane. Typically, however, pressures in the range of about 17.25 x 105 Pa - 24.15 x 105 Pa (250-350 psia) are used. This will be explained in more detail below.
- the non-permeating waste gas is exhausted through a vent or pressure regulator 9 to the atmosphere.
- the CO2-enriched permeating gas passes through a back pressure regulator 10 on the permeate side of the membrane and is then recycled via conduit 11 to the feed side of the liquifaction plant for reprocessing.
- the purity of the CO2 obtained may be further increased by the addition of a catalytic burn-out system 10 in the permeate return line. Quite advantageously, it has been found that the passive catalytic unit reacts the remaining combustibles with oxygen in the product gas to raise the purity to above 99%. For this purpose, any commercially available catalytic unit will suffice.
- the vent gas is typically fed from the condenser at an elevated pressure in the range of about 17.25 x 105 Pa - 24.15 x 105 Pa (250-350 psia) and at a low temperature in the range of about -23.3°C - -15°C (-10°F to about 5°F).
- a pressure of about 19.32 x 105 Pa - 22.08 x 105 Pa (280-320 psia) is used, and a temperature of about -20.6°C to -17.8°C (-5°F) to 0°F is used.
- a pressure of about 20.7 x 105 Pa - 21.39 x 105 Pa (300-310 psia) is used. Most often, however, is used a pressure of about 21.05 x 105 Pa (305 psia), and a temperature of about -18.9°C (-2°F).
- the gas mixture can be filtered to remove impurities.
- a pressure regulator is advantageously used to provide a constant feed pressure on the membrane unit.
- back pressure regulators in the permeate (CO2 product) line and membrane vent line maintain adequate pressure on the module feed side and permeate side.
- a pressure in the range of about 0.69 x 105 Pa - 2.76 x 105 Pa (10 to 40 psia) is maintained on the permeate side and in the feed line returning to the CO2 liquifaction plant. It is essential only that the pressure of the gas at this stage have sufficient pressure to be returned to the feed side of the CO2-liquifaction plant.
- Non-permeating gas exits the membrane unit and is exhausted to the atmosphere.
- FIG 3 a dual-stage membrane CO2 recovery unit is illustrated. From Figure 3, it is seen that membranes 8 and 9a are positioned in series such that the permeate from the first stage becomes the feed to the second stage.
- a pressure regulator and three back pressure regulators maintain gas pressures at the desired levels within the system. Pressures in this system are in accordance with the pressures used in the single-stage system. For example, the permeate pressures in the single-stage and dual-stage recovery systems are maintained in a range of about 0.69 x 105 Pa - 2.76 x 105 Pa (10 to 40 psia).
- the non-permeate streams from stage 1 and stage 2 are vented to the atmosphere.
- the permeating gas from the first membrane 8, which is enriched in CO2, is then passed through pipeline 9 to the second separation membrane 9a.
- the non-permeating gas from this membrane is vented to the atmosphere via pressure regulator 9b.
- the permeating gas from the second membrane which is further enriched in CO2, is then passed through pipeline 10 at a pressure sufficient to push the highly CO2 enriched gas back to the feed side of the CO2 liquifaction plant.
- pressures on the permeate side of the second membrane are in the range of about 0.69 x 105 Pa - 2.76 x 105 Pa (10 to 40 psia), preferably 1.04 x 105 Pa - 3.11 x 105 Pa (15 to 30 psia). Most often, however, a pressure of about 1.59 x 105 Pa (23 psia) is used.
- any semi-permeable gas membrane may be used as the separation membrane or membranes provided that it exhibits sufficient permeability to CO2 and has a sufficient separation factor with respect to impurity gases.
- any such membrane may be used, one such membrane is one which is in the form of a bundle of hollow fibers.
- a test membrane consisting of a bundle of hollow fibers, with a bore side diameter of approximately 0.35 mm, was inserted into a pressure shell.
- a gas mixture containing CO2 at high pressure was fed to the feed side of the membrane module which allowed fast permeating CO2 to diffuse through the membrane into the lower pressure permeate side where it was recovered.
- the remainder of the slow permeating gas exited the module at high pressure from the end opposite the feed side and was vented.
- the operating limits of the membrane were a 6.9 x 105 Pa (100 psi) maximum pressure differential with a -28.9°C to -48.9°C (-20 to 120°F) temperature range.
- the results obtained were generated via computer model for a feed gas rate of 675 m3/h (25,000 SCFH) and a concentration of 75% CO2.
- the permeation coefficients for the individual gases were experimentally determined using a sample of membrane material.
- Example 2 an even higher purity CO2 is attained when a dual-stage membrane is used. Product purity of about 98% CO2 is attained at a 33% recovery.
- the best performance attained is a CO2 product purity of 97% at a 60% recovery which corresponds to about 18 tons of CO2 per day.
- Example 2 it is observed that when using a passive catalytic burn-out system with either the single- or dual-stage recovery system of the present invention to react the remaining combustibles and oxygen in the product gas, the purity of the resulting final product gas is raised to about 99%.
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Claims (14)
- Verfahren zur Verbesserung des Betriebs einer Kohlendioxidverflüssigungsanlage, bei dem ein aus einem kohlendioxidreichen Gasgemisch bestehender, einer Kohlendioxidverflüssigungsanlage zugeführter Gasstrom komprimiert wird, bei dem flüssiges Kohlendioxid vom Boden der Anlage Zurückgewonnen wird, und bei dem aus der Anlage ein Kohlendioxidgas umfassendes Gasgemisch ausgeleitet wird, wobei das Abgas (5) zumindest einer ersten halbdurchlässigen Gastrennmembran (8) zugeführt wird, um ein CO₂-angereichertes Permeatgas (9) und ein CO₂-abgereichertes nichtpermeierendes Gas zu bilden, wobei das nichtpermeierende Gas an die Atmosphäre abgegeben wird, dadurch gekennzeichnet, daß das CO₂-angereicherte Permeatgas (9, 9c, 11) an einen Zufuhreingang der CO₂-Verflüssigungsanlage mit einer Reinheit und einem Druck zurückgeleitet wird, der mit dem Zufuhrgasstrom verträglich ist.
- Verfahren nach Anspruch 1, wobei das CO₂-Permeat (9) durch eine passive Katalyse-Ausglüheinheit (10) geleitet wird.
- Verfahren nach Anspruch 1, wobei das Abgas der ersten halbdurchlässigen Gasmembran (8) unter einem Druck von etwa 19,32 x 10⁵ Pa (280 psia) bis 22,08 x 10⁵ Pa (320 psia) und mit einer Temperatur von etwa -20,6°C (-5°F) bis -17,8°C (O°F) zugeführt wird.
- Verfahren nach Anspruch 3, wobei das Abgas der ersten halbdurchlässigen Gasmembran (8) unter einem Druck im Bereich von etwa 20,7 x 10⁵ Pa (300 psia) bis 21,4 x 10⁵ Pa (310 psia) und mit einer Temperatur im Bereich von etwa -20,5°C (-5°F) bis -17,8°C (0°F) zugeführt wird.
- Verfahren nach Anspruch 4, wobei das Abgas der ersten halbdurchlässigen Membran (8) unter einem Druck von etwa 21 x 10⁵ Pa (305 psia) und mit einer Temperatur von etwa -18,9°C (-2°F) zugeführt wird.
- Verfahren nach einem der Ansprüche 1 bis 5, wobei der Druck an der Zufuhrseite und der Membranseite der ersten Membran (8) durch Druckregler (7, 8a, 9b, 9d) aufrechterhalten wird.
- Verfahren nach einem der Ansprüche 1 bis 6, wobei der Druck auf der Permeatseite der ersten Membran (8) im Bereich von etwa 0,69 x 10⁵ Pa bis 2,76 x 10⁵ Pa (10 bis 40 psia) liegt.
- Verfahren nach Anspruch 7, wobei der Druck auf der Permeatseite der ersten Membran (8) im Bereich von etwa 1 x 10⁵ Pa bis 2 x 10⁵ Pa (15 bis 30 psia) liegt.
- Verfahren nach Anspruch 8, wobei der Druck auf der Permeatseite der ersten Membran (8) etwa 1,59 x 10⁵ Pa (23 psia) beträgt.
- Verfahren nach einem der Ansprüche 1 bis 3, wobei das CO₂-angereicherte Permeat von der ersten halbdurchlässigen Gastrennmembran (8) einer zweiten halbdurchlässigen Gastrennmembran (9a) zugeführt wird.
- Verfahren nach Anspruch 10, wobei das CO₂-angereicherte Permeat von der zweiten halbdurchlässigen Gastrennmembran (9a) einer passiven Katalyse-Ausglüheinheit (10) zugeführt wird.
- Verfahren nach einem der Ansprüche 1 bis 11, wobei die halbdurchlässigen Gasmembranen (8, 9a) ein Hohlfaserbündel umfassen.
- Verfahren nach Anspruch 12, wobei die halbdurchlässigen Gasmembranen (8, 9a) eine mit abnehmender Temperatur zunehmende Selektivität für Kohlendioxid haben.
- Verfahren nach einem der Ansprüche 1 bis 13, wobei die Gasmembranen (8, 9a) aus einem Polymer bestehen, das aus der Polyimid, Polyaramidpolyester und Polyamid umfassenden Gruppe ausgewählt ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/380,380 US4990168A (en) | 1989-07-17 | 1989-07-17 | Recovery of carbon dioxide from a carbon dioxide plant vent gas using membranes |
US380380 | 1989-07-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0410845A1 EP0410845A1 (de) | 1991-01-30 |
EP0410845B1 true EP0410845B1 (de) | 1994-12-07 |
Family
ID=23500946
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90402043A Expired - Lifetime EP0410845B1 (de) | 1989-07-17 | 1990-07-16 | Rückgewinnung von dem aus einer Anlage abgeführten Kohlendioxyd unter Verwendung von Membranen |
Country Status (6)
Country | Link |
---|---|
US (1) | US4990168A (de) |
EP (1) | EP0410845B1 (de) |
AU (1) | AU622091B2 (de) |
CA (1) | CA2021236C (de) |
DE (1) | DE69014753T2 (de) |
NZ (1) | NZ234497A (de) |
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US8617292B2 (en) * | 2009-12-15 | 2013-12-31 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture |
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US9140186B2 (en) * | 2010-09-13 | 2015-09-22 | Membrane Technology And Research, Inc | Sweep-based membrane gas separation integrated with gas-fired power production and CO2 recovery |
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US8535638B2 (en) | 2010-11-11 | 2013-09-17 | Air Liquide Large Industries U.S. | Process for recovering hydrogen and carbon dioxide |
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-
1990
- 1990-07-13 AU AU58993/90A patent/AU622091B2/en not_active Ceased
- 1990-07-13 NZ NZ234497A patent/NZ234497A/xx unknown
- 1990-07-16 EP EP90402043A patent/EP0410845B1/de not_active Expired - Lifetime
- 1990-07-16 CA CA002021236A patent/CA2021236C/en not_active Expired - Fee Related
- 1990-07-16 DE DE69014753T patent/DE69014753T2/de not_active Expired - Fee Related
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PATENT ABSTRACTS OF JAPAN vol. 8, no. 172 (C-237)(1609), 9 August 1984, & JP-A-5969415 (ISHIKWAJIMA HARIMA JUKOGYO K.K.) 19.04.1984 * |
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AU2008200176B2 (en) * | 2007-01-23 | 2009-07-23 | Air Products And Chemicals, Inc. | Purification of carbon dioxide |
Also Published As
Publication number | Publication date |
---|---|
DE69014753T2 (de) | 1995-04-20 |
CA2021236A1 (en) | 1991-01-18 |
EP0410845A1 (de) | 1991-01-30 |
US4990168A (en) | 1991-02-05 |
DE69014753D1 (de) | 1995-01-19 |
NZ234497A (en) | 1992-12-23 |
AU5899390A (en) | 1991-01-17 |
CA2021236C (en) | 2000-10-31 |
AU622091B2 (en) | 1992-03-26 |
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