EP0410501B1 - Fluidized bed for quenching steel wire - Google Patents
Fluidized bed for quenching steel wire Download PDFInfo
- Publication number
- EP0410501B1 EP0410501B1 EP90201864A EP90201864A EP0410501B1 EP 0410501 B1 EP0410501 B1 EP 0410501B1 EP 90201864 A EP90201864 A EP 90201864A EP 90201864 A EP90201864 A EP 90201864A EP 0410501 B1 EP0410501 B1 EP 0410501B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluidized bed
- cooling
- temperature
- wires
- convection cooler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229910000831 Steel Inorganic materials 0.000 title claims description 19
- 238000010791 quenching Methods 0.000 title claims description 19
- 239000010959 steel Substances 0.000 title claims description 19
- 230000000171 quenching effect Effects 0.000 title claims description 17
- 238000001816 cooling Methods 0.000 claims description 65
- 239000007789 gas Substances 0.000 claims description 52
- 238000009434 installation Methods 0.000 claims description 24
- 230000001105 regulatory effect Effects 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 230000009466 transformation Effects 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims 1
- 239000003570 air Substances 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 238000007664 blowing Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005243 fluidization Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000012080 ambient air Substances 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000012809 cooling fluid Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/567—Continuous furnaces for strip or wire with heating in fluidised beds
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/573—Continuous furnaces for strip or wire with cooling
- C21D9/5732—Continuous furnaces for strip or wire with cooling of wires; of rods
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/64—Patenting furnaces
Definitions
- the invention relates to an installation adapted for continuous quenching of steel wires to a temperature of 250°C at the lowest, having a fluidized bed cooling chamber.
- a fluidized bed cooling chamber comprises a container that is filled to a certain height with granules for forming the fluidized bed.
- the granules are inert to high temperatures of 1500°C and more.
- At the bottom of the granule bed there is an inlet adapted for blowing a carrying gas upwards into the bed, with an input flow that is as equally as possible distributed over the bottom surface of the bed.
- Typical grain materials are silica-, almumina-, or zirconiasand, silicon carbide or ferrosilicon, and typical grain dimensions lie in the range between 0.03 and 0.5 millimeter and typical fluidized bed heights for wire applications lie around 0.3 - 0.6 meter.
- the blowing speed into the bed for fluidization thereof depends on the chosen grain type, and typical speeds lie in the range between 0.06 and 0.15 m/sec.
- the cooling medium receives a heat transmission coefficient towards the wires of the order of 200 to 600 W/m°K, which already comes near to the coefficient for cooling liquids. With such cooling medium it is then possible to quench steel wires i.e. to cool with a speed of more than 200°C per second.
- the fluidized bed cooling chamber is further provided with the necessary wire guiding and access means to guide the wire in and out the fluidized bed.
- the fluidized bed cooling chamber will be arranged for simultaneous and continuous treatment of a number of wires (typical quantities are 10 to 50), which pass side by side through the fluidized bed, in the axial direction of the wires.
- Typical wire thicknesses vary from 1 to 6 millimeter, and typical carbon contents lie in the range from 0.05 to 1%.
- Such a fluidized bed has to maintain its quenching temperature. This means that the quantity of heat that enters the bed via the hot wires and that is given off to the cooling fluid, must also be carried off with the same speed from the fluid. In a fluidized bed, this occurs via the carrying gas that is blown in at a comparatively low temperature, that then takes over the heat from the grains, and that then leaves the bed at the top of it at a higher temperature.
- the temperature of the fluidized bed is kept as a constant value (notwithstanding any disturbancies in the traveling speed and entrance temperature of the wires, and other disturbancies) by a regulator of the temperature that influences the entrance temperature of the carrying gas, as described in EP 195.473 (publication number). From the same document it is also known to additionally cool the fluidized bed by means of a propely system of water cooling pipes that are immersed in the fluidized bed, or by means of blowers that blow cooling air above the fluidized bed.
- Such fluidized bed is however limited with respect to its production capacity (i.e. kg of wire treated per second) per square meter of bed surface, so that a large production also needs a comparatively large fluidized bed.
- the primary cooling by the carrying gas is limited indeed, because the speed of the carrying gas through the bed cannot be forced up above values above 0.15 - 0.20 m/sec because the grains would then be blown out of the bed. Consequently, the flow input (m3/sec) per square meter of surface (is equal to the speed) has a limit, and the maximum possible difference between entrance and exit temperature of the carrying gas has also a limit that is mainly determined by the imposed quenching temperature.
- the startery cooling must be limited, because the water pipes cause a disturbance in the fluidization, and if there are too many of them, the fluidized bed appears rapidly to block up and to collapse.
- air blow cooling is used above the bed, then the heat drain capacity of the air is too small, and when this air is mixed up with atomized water, then it appears that this causes the upper surface of the bed to cake together.
- three measures are combined with each other : markedly increasing the density of the pipe system (indirect convection cooling), using a pipe system with air instead of water, and transferring the temperature control from the primary to the secondary cooling circuit.
- the density of the pipe system is consequently at least such, that its external surface where the cooling by convection of the fluidized bed occurs, takes at least 0.40 m per square meter bed surface, and preferably at least 0.80 m. And it is intended, when in use, to send a nominal air flow through it which causes a cooling capacity (KW/m bed surface) of the convection cooler that amounts to at least twice, and preferably four times, the cooling capacity of the primary cooling by the carrying gas.
- the depoty cooling system mustnot necessarily have the form of a number of pipes, but can also take other forms, in so far as the system is based on indirect convection cooling, i.e. cooling through a separating wall with convection on either side thereof.
- the control of the temperature of the fluidized bed is transferred from the primary cooling circuit, with the carrying gas, to the startery cooling circuit, with the indirect convection cooling with air.
- This is now easily feasible by control of the air flow that can be obtained at cold temperature and without any limit from the ambient air.
- Flow control of a water cooling system is much more difficult because this is continuously disturbed by steam formation. Due to the fact that according to said first measure, the bulk of the cooling has been transferred from the primary to the propely circuit, the steering with the propely cooling, from zero to the nominal cooling capacity, provides a very strong regulating system for the temperature.
- the cooling capacity of the convection cooler fed with air that is sucked in by a ventilator, can further be increased by injecting, in the air stream through the convection cooler, either in the cooler itself or in the supply duct, an atomized liquid, preferably water. Then it is possible to regulate the temperature of the bed by varying the flow, either of the cooling air, or of the liquid injection, or both. In fact, by acting on the injection of an atomized liquid, the specific heat C p of the cooling air is controlled. This specific heat is at its lowest level when the air is completely dry, but by injection of an atomized liquid, the vaporizing heat for the very small drops per unit of volume is added.
- the convection cooler has an inlet that is connected with an air source, and the specific heat flow H of the air stream through the convection cooler is variable, and the convection cooler comprises a regulator for keeping the fluidized bed temperature at a constant value, by varying said specific heat flow.
- Such a regulator will consequently, according to the general principles in control engineering, comprise a feeling device of the temperature of the fluidized bed, that produces a signal that is representative for that temperature, and a comparator, where said temperature is compared with an adjusted desired temperature and where a correction signal is generated that is representative of the observed deviation, to which is possibly added the integral and/or the derivative over the time of such difference (in the well-known P, PI, PD or PID regulating systems), and a correcting device where said correction signal is transformed into a variation of a magnitude by means of which the temperature is regulated (in this case the flow of air and/or the liquid injection).
- the system according to the invention and in which the fluidized bed is kept in a non-oxydising athmosphere, and in which the carrying gas comes from a furnace with uncomplete combustion, is extremely adapted for the quenching operation when continuously patenting steel wires.
- the wire is firstly continuously passed through an austenitizing furnace, in which the wire is heated up to a temperature ranging between 900°C and 1050°C, and then, on exit from the austenitizing furnace, is immediately quenched to a temperature ranging from 530°C to 570°C.
- the exhaust gas of the austenitizing furnace is used.
- the maximal heat drain capacity of the carrying gas per m of bed surface is limited to about 25 KW.
- the bed Owing to the presence of the strong depoty convection cooling, it is not necessary to design the bed for maximal cooling, so that a larger freedom exists for the design, and the bed can be designed for a heat drain of 10 to 15 KW per m bed surface.
- the nominal flow of the propely air cooling is then designed to a value that amounts to more than four times the above value, for instance five times, and in any case more than 50 KW/m, for instance 75 KW/m.
- Figure 1 shows a fluidized bed installation that is used for the continuous patenting of a row of steel wires 1, that are traveling side by side in the axial direction of the wires, i.e. in the direction of arrow 2.
- the row of steel wires is located in a single plane, perpendicular to the plane of the drawing, only one wire is visible.
- Figure 2 which is a partial view from the top, the parallel wires 1 are all visible.
- the whole of the fluidized bed installation consists of four fluidized bed chambers, 3, 4, 5 and 6 respectively, which are separated from each other by partitions 7 and 8, and which immediately follow the one after the other in downstream direction of the wires.
- the first chamber serves for quenching the entering wires, from a temperature inside the austenitizing range (depending on the steel and the desired final characteristics for the wire, this range lies in general between 900°C and 1050°C) to the patenting temperature, i.e. the temperature at which the formation of a fine sorbitic structure can start (depending on the steel and the desired final characteristics for the wire, this range lies in general between 530°C and 570°C). It is in this first chamber that the quenching has to occur, and where the problems arise that form the basis for the present invention, and consequently, it is this first chamber that is executed as an installation according to the invention.
- the second, third and fourth chamber serve to keep the wire at the patenting temperature during the time, necessary to allow the transformation into sorbite.
- the temperature of each chamber can be regulated to a temperature that must not necessarily be the same for the four chambers.
- the temperature difference can in theory be zero, or the fluidized bed temperature slightly higher, in order to compensate the radiation losses.
- the temperature in the last three chambers must not necessarily be the patenting temperature to which the wire was quenched in the first chamber, but can diverge therefrom by 30°C below or above said temperature, depending on the metallographic structure, aimed at for the sorbite.
- the length of the chambers may differ, and the number of chambers may vary from 2 to 8 or more.
- the whole of the fluidized bed installation is surrounded by a casing 9, that separates the fluidized bed chambers 3 to 6 as much as possible from the external athmosphere, with the exception of the slit openings 10 for the entrance and the exit of the row of wires 1 in and out the inside part of the installation, and of the inlet and outlet openings 11, respectively 12, for the carrying gas of each fluidized bed chamber separately.
- the four fluidized bed chambers 3 to 6 each comprise a fluidized bed 13 to 16 respectively, that is filled with grains of aluminium oxide with a grain size ranging between 0.03 and 0.5 mm, and in fluidized state, this bed reaches a height that in general is chosen between 0.3 and 0.6 meter, depending on the desired time for keeping the carrying gas in contact with the fluidized bed grains.
- the temperature to which the fluidized bed of the first chamber has to be regulated depends on the required cooling speed of the steel, i.e. on the diameter of the wires and their traveling speed, so that the cooling can penetrate to the core of the wire during the short dwelling time of the wire in the first chamber. For the traveling speeds used in this example, a temperature is taken around the value (500°C - 40d) in which d is the diameter of the wire in mm.
- the fluidized bed of the first chamber has a length, in the direction of the wires, of 1.10 m and a width of 1 meter, and the maximal number of wires that can be guided through this fluidized bed depends on the maximum heat drain capacity of the fluidized bed and on the diameter of the wires.
- the maximum total heat drain capacity has been designed for 105 KW, which corresponds with a capacity of quenching of maximum 1500 kg of steel per hour in the patenting operation, and this has to be taken into account when choosing the number of wires with a given diameter. In such choice it is also necessary to take into account the necessary dwelling time of the wire in the first chamber, which is inversely proportional to the diameter of the wire.
- this sytem will have a traveling speed of about 0,475 m/sec, and will be capable to treat up to 30 parallel wires at a maximum heat drain capacity of 105 KW.
- the system for guiding the wire through the fluidized bed has been designed for guiding 30 wires of a diameter of 1 to 6 mm. In the case of larger diameters, less than 30 wires shall then be treated in parallel, in order not to exceed the maximum designed production capacity.
- the exhaust gas is taken of a furnace (not shown), that is located immediately upstream, with respect to the wire movement, before the fluidized bed installation of Figure 1, which furnace is traversed by the same wires in order to be brought at an austenitizing temperature (between 900 and 1050°C). In this furnace, combustion takes place with a shortage of oxygen, so that this carrying gas cannot provoke any oxydation of the wire.
- the exhaust gas is sucked by a ventilator 17 via a heat exchanger 18, and is further blown through to the first fluidized bed 3.
- the exhaust gas is cooled down to about 150°C, and this gas is then blown in, via inlet 11 of the fluidized bed 3, in the plenum chamber 19 subjacent to fluidized bed 13.
- the plenum chamber 19 is separated from the fluidized bed 13 by the bottom 20 of fluidized bed chamber 3, and this bottom is provided with a multiplicity of blowing orifices 21, through which the carrying gas is blown, from the plenum chamber into the fluidized bed chamber, in a way, uniformly distributed over the bottom surface, and at a temperature of about 120°C.
- blowing orifices those as explained in US 4.813.653 are used.
- an equally distributed carrying gas stream is created in the upward direction, whereby the bed is fluidized, and the carrying gas that emerges at the top is then evacuated from the fluidized bed chamber via outlet opening 12.
- the outlet temperature is regulated to about 420°C, and this corresponds to a heat drain of about 12 KW.
- This comparatively low portion, taken by the primary cooling by the carrying gas (less than 15 KW per m bed surface,), of the total cooling capacity is possible in this quenching step of the patenting operation, because the largest portion of the heat is removed via the depoty cooling.
- the procury cooling occurs by means of air, that is sucked from the surrounding athmosphere by a ventilator 22 via inlet 36, and that is further blown, via flow regulator 23, through a system of pipes 24 towards an outlet 25.
- the pipe system consists in this case of eight pipes 26 having an U-form, that are immersed in oblique position in the bed, and that are connected together in parallel.
- the plane of each U, and also both legs of the U are perpendicular to the plane of the drawing, so that the U-form can not be seen.
- the U-form can be seen, although it is not located in the (horizontal) plane of the drawing.
- Each one of the eight U's comprises a straight and horizontally running entrance leg 27 and exit leg 28, that are connected together into a U-form by means of an elbow 29. All entrance legs 27 lie in the same horizontal plane 30 (Figure 1), and all exit legs 28 in another subjacent plane 31.
- the diameter of the pipes is not so large, and the pipe system not so compact, as to prevent to look through the pipe system in vertical projection ( Figure 2). Between the different legs, an interspace 32 is always visible in vertical projection. In this way, the fluidization through this comparatively compact pipe system is not jeopardized.
- cooling elements be not concentrated in a single horizontal plane, but that they should rather be distributed over two or more horizontal planes. It has further to be seen that the interspaces between the cooling elements can be reached as well as possible by the vertical gas stream, and that the resistance against this stream be distributed as equally as possible over the bed surface.
- the entrance and exit legs 27 respectively 28, are connected in parallel to an entrance and exit tube, 33 respectively 34, via a number of vertically running connecting tubes 35 outside the casing.
- the entrance and exit legs mustnot necessarily be perpendicular to the traveling direction of the wires, but may cross that direction otherwise than perpendicularly, although the perpendicular crossing is preferred.
- the flow regulator 23 is steered by a control system 37 for the control of the temperature of the fluidized bed around the wires, in order to keep this temperature at a constant value, despite all disturbances, such as fluctuations of the heat drain by the carrying gas, or of the heat input via the wire (mainly speed changes).
- a regulating system comprises a feeling device (not shown) of the temperature, located in the fluidized bed in the proximity of the wires, and that sends its output signal to a comparator that measures the deviation of the measured value from the desired value. This deviation is then transformed, in an analog or digital way, into a correction signal (having, as usual, a proportional, differential and integral portion), and this correction signal acts on flow regulator 23 so as to increase or to reduce the cooling air flow to the extent as wanted.
- a correction signal having, as usual, a proportional, differential and integral portion
- the cooling pipes are made of steel and have an outer diameter of 4.8 cm. This gives a cooling surface of about 2 m per square meter of bed surface. In normal operation with wires of 2 mm diameter traveling through the bed at 0,475 m/sec, the exit temperature of the air is then about 200°C at a nominal flow of 2000 Nm3 per hour, and this corresponds to a nominal heat-drain of about 93 KW, taking into account the heating-up of the air in the sucking ventilator. This is a heat drain capacity of 7.75 times the heat drain capacity of the primary cooling system.
- the advantage of the invention can however sufficiently be exploited when the cooling surface of the depoty circuit is larger than 0.4 m per square meter of bed surface and when the heat drain by the furnishy circuit is larger than three times the heat drain of the primary circuit.
- the second, third and fourth fluidized bed chamber respectively 4 to 6, have each, in this example of embodiment, an own inlet for the carrying gas.
- the carrying gas shall be blown in at this temperature (between 530°C and 570°C). This temperature can be different from one chamber to the other.
- This carrying gas shall preferably come from the same austenitizing furnace, but has to be cooled down to a lesser extent.
- the invention is not limited to quenching in the patenting operation, but can be applied in any installation with one or more fluidized bed chambers, in which each chamber has its own function in an overall heat treatment programme that the steel wires have to undergo, and in which one of these chambers serve for quenching from a higher temperature to a lower one, which has however not to be below about 250°C, in order to avoid condensation of moistness in the carrying gas.
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Description
- The invention relates to an installation adapted for continuous quenching of steel wires to a temperature of 250°C at the lowest, having a fluidized bed cooling chamber. As known, a fluidized bed cooling chamber comprises a container that is filled to a certain height with granules for forming the fluidized bed. The granules are inert to high temperatures of 1500°C and more. At the bottom of the granule bed, there is an inlet adapted for blowing a carrying gas upwards into the bed, with an input flow that is as equally as possible distributed over the bottom surface of the bed. Between a minimum and maximum blowing speed, the granules come to whirl up and down and the bed swells up so as to behave like a cooling fluid that can be traversed by the wires without any hindrance. Typical grain materials are silica-, almumina-, or zirconiasand, silicon carbide or ferrosilicon, and typical grain dimensions lie in the range between 0.03 and 0.5 millimeter and typical fluidized bed heights for wire applications lie around 0.3 - 0.6 meter. The blowing speed into the bed for fluidization thereof depends on the chosen grain type, and typical speeds lie in the range between 0.06 and 0.15 m/sec. In this way the cooling medium receives a heat transmission coefficient towards the wires of the order of 200 to 600 W/m°K, which already comes near to the coefficient for cooling liquids. With such cooling medium it is then possible to quench steel wires i.e. to cool with a speed of more than 200°C per second.
- In order to be adapted for the treatment of steel wires, the fluidized bed cooling chamber is further provided with the necessary wire guiding and access means to guide the wire in and out the fluidized bed. In general, the fluidized bed cooling chamber will be arranged for simultaneous and continuous treatment of a number of wires (typical quantities are 10 to 50), which pass side by side through the fluidized bed, in the axial direction of the wires. Typical wire thicknesses vary from 1 to 6 millimeter, and typical carbon contents lie in the range from 0.05 to 1%.
- Such a fluidized bed has to maintain its quenching temperature. This means that the quantity of heat that enters the bed via the hot wires and that is given off to the cooling fluid, must also be carried off with the same speed from the fluid. In a fluidized bed, this occurs via the carrying gas that is blown in at a comparatively low temperature, that then takes over the heat from the grains, and that then leaves the bed at the top of it at a higher temperature. The temperature of the fluidized bed is kept as a constant value (notwithstanding any disturbancies in the traveling speed and entrance temperature of the wires, and other disturbancies) by a regulator of the temperature that influences the entrance temperature of the carrying gas, as described in EP 195.473 (publication number). From the same document it is also known to additionally cool the fluidized bed by means of a secundary system of water cooling pipes that are immersed in the fluidized bed, or by means of blowers that blow cooling air above the fluidized bed.
- Such fluidized bed is however limited with respect to its production capacity (i.e. kg of wire treated per second) per square meter of bed surface, so that a large production also needs a comparatively large fluidized bed. The primary cooling by the carrying gas is limited indeed, because the speed of the carrying gas through the bed cannot be forced up above values above 0.15 - 0.20 m/sec because the grains would then be blown out of the bed. Consequently, the flow input (m³/sec) per square meter of surface (is equal to the speed) has a limit, and the maximum possible difference between entrance and exit temperature of the carrying gas has also a limit that is mainly determined by the imposed quenching temperature. Also the secundary cooling must be limited, because the water pipes cause a disturbance in the fluidization, and if there are too many of them, the fluidized bed appears rapidly to block up and to collapse. When air blow cooling is used above the bed, then the heat drain capacity of the air is too small, and when this air is mixed up with atomized water, then it appears that this causes the upper surface of the bed to cake together.
- Moreover, when the production capacity per square meter of bed surface is increased, there is a second problem : the regulability of the fluidized bed temperature. Due to the fact that a larger quantity of steel has to be treated in a smaller bed, larger irregularities in heat input and heat drain must be taken up by a smaller volume, so that there are also large temperature variations that must be taken up by a more powerful and more rapidly reacting regulating system.
- It is an object of the invention to provide, with simple means, an installation having a fluidized bed cooling chamber with increased production capacity, per square meter of bed surface, and that has an efficient temperature regulating system.
- The object is solved by the installation as claimed in
claim 1 and the process as claimed inclaim 8. Preferred embodiments are disclosed in thedependent claims 2 to 7 and 9 to 13. - According to the invention, three measures are combined with each other : markedly increasing the density of the pipe system (indirect convection cooling), using a pipe system with air instead of water, and transferring the temperature control from the primary to the secondary cooling circuit.
- It has been found indeed that the origin of the obstruction and the collapse of the fluidized bed when there are too many water cooling pipes, lies in the residual moistness of the carrying gas that causes condensation against the cooling pipes. This causes a cake-formation around the pipes and this gives the pipes a larger apparent diameter which causes a disturbance in the fluidized bed. From this, it appears that it remains possible to strongly increase the density of the cooling pipes, when care is taken that such condensation is avoided. A possible measure is the use of a very dry carrying gas, but this requires a special preparation of the gas, or else, the choice of the carrying gas is limited. Such gas may, for instance, consist of exhaust gases of a furnace, with a large inherent moistness, and it is often undesirable to be limited in the choice of the carrying gas.
- It is now a first measure according to the invention, to sensibly increase the density of the pipes, but then not to send cooling water through the pipes, but ambient air that is sucked in via a ventilator, although air has a smaller cooling capacity than water. However, by the fact that it is air, and not water, that runs through the pipes, the external surface of the pipes do no longer come at the temperature of the cooling water (below 100°C and, consequently, condensation), but at an intermediate temperature between the temperature of the cooling air (about 40°C at the exit of the sucking ventilator) and that of the fluidized bed (200°C or more). There is consequently no longer any condensation of residual moistness and it is possible to pass to a pipe system with much larger density, and which can be fed by a very large flow of cheap ambient air, whereby the lower cooling capacity of the air is largely compensated.
- The density of the pipe system is consequently at least such, that its external surface where the cooling by convection of the fluidized bed occurs, takes at least 0.40 m per square meter bed surface, and preferably at least 0.80 m. And it is intended, when in use, to send a nominal air flow through it which causes a cooling capacity (KW/m bed surface) of the convection cooler that amounts to at least twice, and preferably four times, the cooling capacity of the primary cooling by the carrying gas. The secundary cooling system mustnot necessarily have the form of a number of pipes, but can also take other forms, in so far as the system is based on indirect convection cooling, i.e. cooling through a separating wall with convection on either side thereof.
- Further according to the invention, and as a second measure in combination with the measure above, the control of the temperature of the fluidized bed is transferred from the primary cooling circuit, with the carrying gas, to the secundary cooling circuit, with the indirect convection cooling with air. This is now easily feasible by control of the air flow that can be obtained at cold temperature and without any limit from the ambient air. Flow control of a water cooling system is much more difficult because this is continuously disturbed by steam formation. Due to the fact that according to said first measure, the bulk of the cooling has been transferred from the primary to the secundary circuit, the steering with the secundary cooling, from zero to the nominal cooling capacity, provides a very strong regulating system for the temperature.
- The cooling capacity of the convection cooler, fed with air that is sucked in by a ventilator, can further be increased by injecting, in the air stream through the convection cooler, either in the cooler itself or in the supply duct, an atomized liquid, preferably water. Then it is possible to regulate the temperature of the bed by varying the flow, either of the cooling air, or of the liquid injection, or both. In fact, by acting on the injection of an atomized liquid, the specific heat Cp of the cooling air is controlled. This specific heat is at its lowest level when the air is completely dry, but by injection of an atomized liquid, the vaporizing heat for the very small drops per unit of volume is added. In general terms, by varying the flow of the cooling air and/or of the liquid injection, a variation is produced of the product of the flow with the specific heat of the air stream. This product H is called hereinafter the "specific heat flow" and is consequently equal to the specific heat Cp (in Joule per m³ and per °C) multiplied by the flow (in m³ per sec.). H is consequently a magnitude in Watt per °C.
- Accordingly, in more general terms, the convection cooler has an inlet that is connected with an air source, and the specific heat flow H of the air stream through the convection cooler is variable, and the convection cooler comprises a regulator for keeping the fluidized bed temperature at a constant value, by varying said specific heat flow.
- Such a regulator will consequently, according to the general principles in control engineering, comprise a feeling device of the temperature of the fluidized bed, that produces a signal that is representative for that temperature, and a comparator, where said temperature is compared with an adjusted desired temperature and where a correction signal is generated that is representative of the observed deviation, to which is possibly added the integral and/or the derivative over the time of such difference (in the well-known P, PI, PD or PID regulating systems), and a correcting device where said correction signal is transformed into a variation of a magnitude by means of which the temperature is regulated (in this case the flow of air and/or the liquid injection).
- Although it is not always necessary to avoid oxydation during quenching, it is often desirable, and sometimes also absolutely necessary to keep the fluidized bed in a non-oxydising athmosphere. In this case, a conventional non-oxydising carrying gas is used, and the fluidized bed and the athmosphere above is as much as possible separated from the external athmosphere, for instance by means of a casing around the fluidized bed that is as closed as possible (but having the necessary passages for the carrying gas and the wires). In a cheap and simple way it is then possible to have the carrying gas supplied from a combustion furnace, in which combustion takes place with a small shortage of oxygen, and of which the exhaust gas, before being blown in as a carrying gas, is passed through a cooling device first, in which the gas is cooled down to a temperature not below 120°C in order to avoid condensation of the water in the exhaust gas. In this case, the system of the invention is extremely well suited, because the temperature variations of this exhaust gas, as a carrying gas, cannot cause much disturbance any more : on one hand, the inlet temperature of this gas has no longer to be controlled as a steering factor for the temperature, and on the other hand, there is the strong regulating system in the secundary cooling system that takes up such temperature variations.
- The system according to the invention, and in which the fluidized bed is kept in a non-oxydising athmosphere, and in which the carrying gas comes from a furnace with uncomplete combustion, is extremely adapted for the quenching operation when continuously patenting steel wires. In such process, the wire is firstly continuously passed through an austenitizing furnace, in which the wire is heated up to a temperature ranging between 900°C and 1050°C, and then, on exit from the austenitizing furnace, is immediately quenched to a temperature ranging from 530°C to 570°C. Preferably, the exhaust gas of the austenitizing furnace is used. In this case, the maximal heat drain capacity of the carrying gas per m of bed surface is limited to about 25 KW. Owing to the presence of the strong secundary convection cooling, it is not necessary to design the bed for maximal cooling, so that a larger freedom exists for the design, and the bed can be designed for a heat drain of 10 to 15 KW per m bed surface. The nominal flow of the secundary air cooling is then designed to a value that amounts to more than four times the above value, for instance five times, and in any case more than 50 KW/m, for instance 75 KW/m.
- The invention will here further be explained by reference to some drawings in which :
- Figure 1
- is a side view of a fluidized bed installation, that comprises a number of fluidized bed chambers, the one immediately subsequent to the other, and in which the first one is designed according to the invention ;
- Figure 2
- is a top view of the first fluidized bed chamber of Figure 1.
- Figure 1 shows a fluidized bed installation that is used for the continuous patenting of a row of
steel wires 1, that are traveling side by side in the axial direction of the wires, i.e. in the direction ofarrow 2. As the row of steel wires is located in a single plane, perpendicular to the plane of the drawing, only one wire is visible. On Figure 2 however, which is a partial view from the top, theparallel wires 1 are all visible. The whole of the fluidized bed installation consists of four fluidized bed chambers, 3, 4, 5 and 6 respectively, which are separated from each other bypartitions - The first chamber serves for quenching the entering wires, from a temperature inside the austenitizing range (depending on the steel and the desired final characteristics for the wire, this range lies in general between 900°C and 1050°C) to the patenting temperature, i.e. the temperature at which the formation of a fine sorbitic structure can start (depending on the steel and the desired final characteristics for the wire, this range lies in general between 530°C and 570°C). It is in this first chamber that the quenching has to occur, and where the problems arise that form the basis for the present invention, and consequently, it is this first chamber that is executed as an installation according to the invention. The second, third and fourth chamber serve to keep the wire at the patenting temperature during the time, necessary to allow the transformation into sorbite. Here there are no similar problems of heat drain, and consequently they must not be made according to the invention, although this may be so, when the installation has also to serve for other sorts of metallographic transformations, in which two or more chambers are used for quenching the wires. When the installation is used for patenting steel wires, where the second, third and fourth chambers are only used for keeping the wire at a fixed temperature, then the temperature of each chamber can be regulated to a temperature that must not necessarily be the same for the four chambers. For the rapid quench in the first chamber, a rather large temperature difference between the wire and the fluidized bed will be necessary, but for keeping the wire on temperature in the subsequent chambers, the temperature difference can in theory be zero, or the fluidized bed temperature slightly higher, in order to compensate the radiation losses. The temperature in the last three chambers must not necessarily be the patenting temperature to which the wire was quenched in the first chamber, but can diverge therefrom by 30°C below or above said temperature, depending on the metallographic structure, aimed at for the sorbite. Finally, the length of the chambers may differ, and the number of chambers may vary from 2 to 8 or more.
- The whole of the fluidized bed installation is surrounded by a
casing 9, that separates thefluidized bed chambers 3 to 6 as much as possible from the external athmosphere, with the exception of theslit openings 10 for the entrance and the exit of the row ofwires 1 in and out the inside part of the installation, and of the inlet andoutlet openings 11, respectively 12, for the carrying gas of each fluidized bed chamber separately. - The four
fluidized bed chambers 3 to 6 each comprise afluidized bed 13 to 16 respectively, that is filled with grains of aluminium oxide with a grain size ranging between 0.03 and 0.5 mm, and in fluidized state, this bed reaches a height that in general is chosen between 0.3 and 0.6 meter, depending on the desired time for keeping the carrying gas in contact with the fluidized bed grains. The temperature to which the fluidized bed of the first chamber has to be regulated, depends on the required cooling speed of the steel, i.e. on the diameter of the wires and their traveling speed, so that the cooling can penetrate to the core of the wire during the short dwelling time of the wire in the first chamber. For the traveling speeds used in this example, a temperature is taken around the value (500°C - 40d) in which d is the diameter of the wire in mm. - The fluidized bed of the first chamber according to this example has a length, in the direction of the wires, of 1.10 m and a width of 1 meter, and the maximal number of wires that can be guided through this fluidized bed depends on the maximum heat drain capacity of the fluidized bed and on the diameter of the wires. In this example, the maximum total heat drain capacity has been designed for 105 KW, which corresponds with a capacity of quenching of maximum 1500 kg of steel per hour in the patenting operation, and this has to be taken into account when choosing the number of wires with a given diameter. In such choice it is also necessary to take into account the necessary dwelling time of the wire in the first chamber, which is inversely proportional to the diameter of the wire. Accordingly, for wires of 2 mm diameter, this sytem will have a traveling speed of about 0,475 m/sec, and will be capable to treat up to 30 parallel wires at a maximum heat drain capacity of 105 KW. In this example, the system for guiding the wire through the fluidized bed, has been designed for guiding 30 wires of a diameter of 1 to 6 mm. In the case of larger diameters, less than 30 wires shall then be treated in parallel, in order not to exceed the maximum designed production capacity.
- As a carrying gas for the
fluidized bed 13 of the first chamber, the exhaust gas is taken of a furnace (not shown), that is located immediately upstream, with respect to the wire movement, before the fluidized bed installation of Figure 1, which furnace is traversed by the same wires in order to be brought at an austenitizing temperature (between 900 and 1050°C). In this furnace, combustion takes place with a shortage of oxygen, so that this carrying gas cannot provoke any oxydation of the wire. The exhaust gas is sucked by aventilator 17 via aheat exchanger 18, and is further blown through to the firstfluidized bed 3. In theheat exchanger 18, the exhaust gas is cooled down to about 150°C, and this gas is then blown in, viainlet 11 of thefluidized bed 3, in theplenum chamber 19 subjacent tofluidized bed 13. Theplenum chamber 19 is separated from thefluidized bed 13 by the bottom 20 offluidized bed chamber 3, and this bottom is provided with a multiplicity of blowingorifices 21, through which the carrying gas is blown, from the plenum chamber into the fluidized bed chamber, in a way, uniformly distributed over the bottom surface, and at a temperature of about 120°C. As a bottom with blowing orifices, those as explained in US 4.813.653 are used. - In the fluidized bed, an equally distributed carrying gas stream is created in the upward direction, whereby the bed is fluidized, and the carrying gas that emerges at the top is then evacuated from the fluidized bed chamber via
outlet opening 12. For wires of 2 mm, the outlet temperature is regulated to about 420°C, and this corresponds to a heat drain of about 12 KW. This comparatively low portion, taken by the primary cooling by the carrying gas (less than 15 KW per m bed surface,), of the total cooling capacity is possible in this quenching step of the patenting operation, because the largest portion of the heat is removed via the secundary cooling. - The secundary cooling occurs by means of air, that is sucked from the surrounding athmosphere by a
ventilator 22 viainlet 36, and that is further blown, viaflow regulator 23, through a system of pipes 24 towards anoutlet 25. The pipe system consists in this case of eightpipes 26 having an U-form, that are immersed in oblique position in the bed, and that are connected together in parallel. In Figure 1, the plane of each U, and also both legs of the U, are perpendicular to the plane of the drawing, so that the U-form can not be seen. In the top view of Figure 2 however, the U-form can be seen, although it is not located in the (horizontal) plane of the drawing. Each one of the eight U's comprises a straight and horizontally runningentrance leg 27 andexit leg 28, that are connected together into a U-form by means of anelbow 29. Allentrance legs 27 lie in the same horizontal plane 30 (Figure 1), and allexit legs 28 in anothersubjacent plane 31. The diameter of the pipes is not so large, and the pipe system not so compact, as to prevent to look through the pipe system in vertical projection (Figure 2). Between the different legs, aninterspace 32 is always visible in vertical projection. In this way, the fluidization through this comparatively compact pipe system is not jeopardized. - For convector systems in general, having another configuration, in order to obtain good fluidization, care shall be taken that the cooling elements be not concentrated in a single horizontal plane, but that they should rather be distributed over two or more horizontal planes. It has further to be seen that the interspaces between the cooling elements can be reached as well as possible by the vertical gas stream, and that the resistance against this stream be distributed as equally as possible over the bed surface. This is obtained when care is taken, on one hand, that the cooling elements of one plane, when observed in vertical projection, only cover those of any other plane to an extent as small as possible, or preferably not at all, and that, on the other hand, the vertical projection of all cooling elements of the convector, do not cover the whole surface of the fluidized bed, but only for 50 to 80 %, in other words, that the convector, in vertical projection, still shows interstices and is still transparent, in vertical view.
- In the drawings, the entrance and exit
legs 27 respectively 28, are connected in parallel to an entrance and exit tube, 33 respectively 34, via a number of vertically running connectingtubes 35 outside the casing. The entrance and exit legs mustnot necessarily be perpendicular to the traveling direction of the wires, but may cross that direction otherwise than perpendicularly, although the perpendicular crossing is preferred. - The
flow regulator 23 is steered by acontrol system 37 for the control of the temperature of the fluidized bed around the wires, in order to keep this temperature at a constant value, despite all disturbances, such as fluctuations of the heat drain by the carrying gas, or of the heat input via the wire (mainly speed changes). As usual, such a regulating system comprises a feeling device (not shown) of the temperature, located in the fluidized bed in the proximity of the wires, and that sends its output signal to a comparator that measures the deviation of the measured value from the desired value. This deviation is then transformed, in an analog or digital way, into a correction signal (having, as usual, a proportional, differential and integral portion), and this correction signal acts onflow regulator 23 so as to increase or to reduce the cooling air flow to the extent as wanted. - The cooling pipes are made of steel and have an outer diameter of 4.8 cm. This gives a cooling surface of about 2 m per square meter of bed surface. In normal operation with wires of 2 mm diameter traveling through the bed at 0,475 m/sec, the exit temperature of the air is then about 200°C at a nominal flow of 2000 Nm³ per hour, and this corresponds to a nominal heat-drain of about 93 KW, taking into account the heating-up of the air in the sucking ventilator. This is a heat drain capacity of 7.75 times the heat drain capacity of the primary cooling system. The advantage of the invention can however sufficiently be exploited when the cooling surface of the secundary circuit is larger than 0.4 m per square meter of bed surface and when the heat drain by the secundary circuit is larger than three times the heat drain of the primary circuit.
- The second, third and fourth fluidized bed chamber, respectively 4 to 6, have each, in this example of embodiment, an own inlet for the carrying gas. As these chambers serve for keeping the wires at the temperature of sorbitic transformation, the carrying gas shall be blown in at this temperature (between 530°C and 570°C). This temperature can be different from one chamber to the other. This carrying gas shall preferably come from the same austenitizing furnace, but has to be cooled down to a lesser extent.
- The invention is not limited to quenching in the patenting operation, but can be applied in any installation with one or more fluidized bed chambers, in which each chamber has its own function in an overall heat treatment programme that the steel wires have to undergo, and in which one of these chambers serve for quenching from a higher temperature to a lower one, which has however not to be below about 250°C, in order to avoid condensation of moistness in the carrying gas.
Claims (13)
- Installation adapted for the continuous quenching of steel wires to a temperature of 250° at the lowest, having a fluidized bed cooling chamber (3) provided with an indirect convection cooler (24), characterized in that said installation has an air source (23) connected to an inlet (33) of said convection cooler, that said convection cooler has a cooling surface of at least 0.4 m per square meter fluidized bed surface, that the specific heat flow H (H = air flow x specific heat) of the air stream through the convection cooler is variable, and that said convection cooler further has a regulating system (37) for keeping the fluidized bed temperature at a constant value by variation of said specific heat flow.
- Installation according to claim 1, characterized in that the output flow of said air source (23) is variable and is steered by the output signal of said regulator (37).
- Installation according to any one of claims 1 or 2, characterized in that said inlet (33) of the convection cooler comprises an atomizer of liquid arranged for injecting a spray of liquid into the passageway of the air stream from the air source towards the convection cooler, which atomizer has a variable output flow and is steered by the output signal of said regulator (37).
- Installation according to any one of claims 1 to 3, characterized in that said convection cooler (24) comprises a number of cooling elements (26), that are distributed over more than one horizontal plane (30, 31), the vertical projection of the cooling elements of one plane not covering the vertical projection of the elements of any other plane, and the vertical projection of all cooling elements only taking maximum 80 % of the total bed surface.
- Installation according to claim 4, characterized in that said convection cooler (24) comprises a number of cooling pipes (26) in an U-form, of which the legs (27, 28) run horizontally through the bed (13), in a direction crossing the axial direction of the wires (1), and with one leg (27) in an upper (30), and the other leg (28) in a lower (31) horizontal plane, the pipes showing, in vertical projection, interstices (32) between the legs, and said legs being connected in parallel between the inlet (33) and the outlet (25) of the convection cooler.
- Installation according to any one of the preceding claims, characterized in that it is provided with a surrounding casing (9) that separates the athmosphere in and above the fluidized bed from the external athmosphere, and of which the inlet (11) for the carrying gas is connected, via a cooling device (18), with the exhaust outlet of a furnace.
- Installation adapted for the continuous patenting of a row of steel wires running side by side in parallel and in the axial direction of the wires, and comprising a furnace for the austenitizing of said wires, followed by a fluidized bed installation for the quenching and sorbitic transformation of the wires, the fluidized bed installation comprising a number of contiguous fluidized bed chambers (3,4,5,6) the one immediately following the other, characterized in that the first chamber (3) is executed as an installation according to any one of claims 1 to 6.
- A process for continuous quenching of steel wires (1) to a temperature of 250°C at the lowest, and in which the wires are continuously guided through a fluidized bed (13) that comprises an immersed convection cooler (24), characterized by sending an air stream through said convection cooler and hereby draining away at least three times the heat that is carried away by the carrying gas of the fluidized bed, and by regulating the temperature of the fluidized bed at a constant value by steering the specific heat flow H of the cooling air.
- A process according to claim 8, characterized in regulating the temperature of the fluidized bed by varying the air flow sent through the convection cooler.
- A process according to any one of claims 8 or 9, characterized by injecting an atomized liquid into said air stream, and regulating the temperature of the fluidized bed by varying the quantity of atomized liquid that is injected.
- A process according to any one of claims 8 to 10, characterized by keeping said fluidized bed under a non-oxydising athmosphere, and supplying the carrying gas for the fluidized bed from a combustion device in which a combustion is conducted with the shortage of oxygen.
- A process for the continuous patenting of steel wires (1) that are firstly passed through an austenitizing furnace and then are quenched in a fluidized bed (13) whereby the wires undergo a sorbitic transformation, characterized in that, for the quenching, the process is applied according to any one of claims 8 to 11, and that the carrying gas is taken from the exhaust gases of the austenitizing furnace.
- A process according to claim 12, characterized in that the carrying gas drains away a heat of not more than 15 KW per m bed surface, and the convection cooler at least 50 KW per m.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE8900809A BE1004383A3 (en) | 1989-07-26 | 1989-07-26 | Fluidized bed for deterring WIRE. |
BE8900809 | 1989-07-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0410501A1 EP0410501A1 (en) | 1991-01-30 |
EP0410501B1 true EP0410501B1 (en) | 1996-01-17 |
Family
ID=3884263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90201864A Expired - Lifetime EP0410501B1 (en) | 1989-07-26 | 1990-07-10 | Fluidized bed for quenching steel wire |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0410501B1 (en) |
JP (1) | JP2931053B2 (en) |
KR (1) | KR0180725B1 (en) |
BE (1) | BE1004383A3 (en) |
BR (1) | BR9003605A (en) |
DE (1) | DE69024869T2 (en) |
ES (1) | ES2084648T3 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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FI20011954A (en) * | 2001-10-08 | 2003-04-09 | Lahden Laempoekaesittely Oy | The heat treatment method |
JP3968406B1 (en) * | 2006-08-16 | 2007-08-29 | 株式会社アルケミー | Patenting method for steel wire rod |
PT2271779T (en) | 2008-04-30 | 2018-05-23 | Bekaert Sa Nv | Steel filament patented in bismuth |
WO2019239184A1 (en) | 2018-06-13 | 2019-12-19 | Arcelormittal | Vacuum deposition facility and method for coating a substrate |
WO2019239186A1 (en) | 2018-06-13 | 2019-12-19 | Arcelormittal | Vacuum deposition facility and method for coating a substrate |
JP2020143344A (en) * | 2019-03-07 | 2020-09-10 | 山田 榮子 | Fluidized bed furnace for heating and cooling steel wires |
KR102204335B1 (en) | 2020-08-31 | 2021-01-18 | 소병현 | Compost dryer with mobile stirring function |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1490853A (en) * | 1966-08-25 | 1967-08-04 | Schloemann Ag | Device for continuous patenting of rolled wire |
DE1602081B1 (en) * | 1967-03-04 | 1970-05-27 | Huettenwerk Oberhausen Ag | Device for the heat treatment of metallic material, in particular wire rod |
US3718024A (en) * | 1971-02-12 | 1973-02-27 | Morgan Construction Co | Apparatus including a fluidized bed for cooling steel rod through transformation |
DE3226582A1 (en) * | 1982-07-16 | 1984-01-19 | Ewald Schwing Verfahrenstechnik GmbH, 4133 Neukirchen-Vluyn | Device for cooling bar material |
GB8426455D0 (en) * | 1984-10-19 | 1984-11-28 | Bekaert Sa Nv | Fluidised bed apparatus |
GB8505491D0 (en) * | 1985-03-04 | 1985-04-03 | Bekaert Sa Nv | Heat treatment of steel |
DE3734169A1 (en) * | 1987-10-09 | 1989-04-27 | Ewald Schwing | METHOD FOR WARM BATHING ITEMS FROM ALLOY STEELS |
-
1989
- 1989-07-26 BE BE8900809A patent/BE1004383A3/en not_active IP Right Cessation
-
1990
- 1990-07-10 ES ES90201864T patent/ES2084648T3/en not_active Expired - Fee Related
- 1990-07-10 DE DE69024869T patent/DE69024869T2/en not_active Expired - Fee Related
- 1990-07-10 EP EP90201864A patent/EP0410501B1/en not_active Expired - Lifetime
- 1990-07-25 BR BR909003605A patent/BR9003605A/en not_active Application Discontinuation
- 1990-07-26 KR KR1019900011387A patent/KR0180725B1/en not_active IP Right Cessation
- 1990-07-26 JP JP2198950A patent/JP2931053B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69024869D1 (en) | 1996-02-29 |
EP0410501A1 (en) | 1991-01-30 |
KR910003120A (en) | 1991-02-26 |
JP2931053B2 (en) | 1999-08-09 |
DE69024869T2 (en) | 1996-05-30 |
JPH03146623A (en) | 1991-06-21 |
KR0180725B1 (en) | 1999-02-18 |
BE1004383A3 (en) | 1992-11-10 |
ES2084648T3 (en) | 1996-05-16 |
BR9003605A (en) | 1991-08-27 |
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