EP0407429A1 - Monitor für die verseuchung eines fluidums - Google Patents
Monitor für die verseuchung eines fluidumsInfo
- Publication number
- EP0407429A1 EP0407429A1 EP89903975A EP89903975A EP0407429A1 EP 0407429 A1 EP0407429 A1 EP 0407429A1 EP 89903975 A EP89903975 A EP 89903975A EP 89903975 A EP89903975 A EP 89903975A EP 0407429 A1 EP0407429 A1 EP 0407429A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- light
- light beam
- chamber
- fluid
- sampling chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 35
- 238000005070 sampling Methods 0.000 claims abstract description 31
- 239000002245 particle Substances 0.000 claims abstract description 24
- 238000012544 monitoring process Methods 0.000 claims description 17
- 230000001427 coherent effect Effects 0.000 claims description 6
- 239000013307 optical fiber Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 abstract 1
- 230000035945 sensitivity Effects 0.000 description 16
- 239000000779 smoke Substances 0.000 description 10
- 238000001514 detection method Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000000149 argon plasma sintering Methods 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
- 238000013461 design Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- CPBQJMYROZQQJC-UHFFFAOYSA-N helium neon Chemical compound [He].[Ne] CPBQJMYROZQQJC-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000001360 synchronised effect Effects 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B17/00—Fire alarms; Alarms responsive to explosion
- G08B17/10—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means
- G08B17/103—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means using a light emitting and receiving device
- G08B17/107—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means using a light emitting and receiving device for detecting light-scattering due to smoke
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N21/49—Scattering, i.e. diffuse reflection within a body or fluid
- G01N21/53—Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B17/00—Fire alarms; Alarms responsive to explosion
- G08B17/10—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means
- G08B17/11—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means using an ionisation chamber for detecting smoke or gas
- G08B17/113—Constructional details
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/02—Details
- G01J1/04—Optical or mechanical part supplementary adjustable parts
- G01J1/0407—Optical elements not provided otherwise, e.g. manifolds, windows, holograms, gratings
- G01J1/0411—Optical elements not provided otherwise, e.g. manifolds, windows, holograms, gratings using focussing or collimating elements, i.e. lenses or mirrors; Aberration correction
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N2021/0378—Shapes
- G01N2021/0382—Frustoconical, tapered cell
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/05—Flow-through cuvettes
- G01N2021/052—Tubular type; cavity type; multireflective
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N2021/4704—Angular selective
- G01N2021/4707—Forward scatter; Low angle scatter
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N2021/4704—Angular selective
- G01N2021/4711—Multiangle measurement
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/314—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
Definitions
- the present invention relates to detection and monitoring equipment for fluid pollution, including smoke and air pollution by light scatter techniques.
- Devices for the detection of smoke by light scatter techniques. Such devices include a light source configured to irradiate through a volume of air provided in a sampling region in which smoke, dust or like particles may be suspended. Light scattered off said particles is collected on a light detector means. The amplitude of the signal from said light detector is an indication of the quantity of particulates in the fluid.
- Particularly sensitive versions of such detectors are capable of monitoring low levels of fluid pollution and thus may be a useful tool for monitoring general atmospheric pollution.
- Such high sensitivity enables detection of fires at the earliest possible (incipient) stage, whereby the fire may be controlled by local personnel using portable extinguishers or by removal of the source of heat (e.g. by disconnection of electric current) before smoke levels become dangerous to life.
- Such detectors require a sensitivity as high as twenty microgra s of wood smoke per cubic metre for example, which is equivalent to a visual range of 40 kilometres.
- This prior apparatus can and does summon human intervention before smoke levels become dangerous to life or delicate equipment, it can cause an orderly shutdown of power supplies so that equipment overheating will subside (thereby preventing a fire), or it can operate automatic fire suppression and personnel evacuation systems.
- the prior art utilizes a sampling chamber as described in Australian Specification No. 31843/84 through which a representative sample of air within the zone to be monitored, is continuously drawn by an aspirator.
- the air sample is normally irradiated by an intense, wideband light pulse from a Xenon lamp.
- a miniscule proportion of the incident photons are scattered off airborne particles towards a very sensitive detector, to produce an analog signal which, after signal processing, represents the level of pollution (smoke) present in the air.
- the instrument is so sensitive that photons scattered off air molecules alone are detected. Therefore, minor pollution is readily detected as an increased signal.
- the rate of false alarms is much lower than for conventional smoke detectors (which are comparatively insensitive, by two or three orders of magnitude) .
- Photons scattered off air molecules are invisible to the naked eye, like faint starlight, whereas the incident light is of similar brilliance to sunlight (thus in the one instrument, the range of light levels spans "cosmic proportions").
- the task is to detect the equivalent of faint starlight in the presence of sunlight.
- This requires a chamber of advanced optical design, to separate the desired scattered light from the incident light, and advanced electronics to detect the miniscule scattered light component without resort to cryogenics or photomultipliers.
- the prior art has utilized a Xenon lamp as a suitable source of intense wideband light with low energy input.
- a fluid pollution monitoring apparatus including a fluid sampling chamber, means for projecting a coherent collimated light beam into said sampling chamber, means introducing sample air from an area to be monitored into said chamber to be exposed to said light beam, a light detector cell positioned at a location separated or shaded from the axis of said light beam, and means in said sampling chamber for directing any scattered light produced by the presence of airborne particles in the chamber towards said detector.
- the advantage of a coherent collimated light source is that light is not visible beyond the axis of the light beam, except as a result of light scattering off airborne particles. Therefore if a laser light beam is projected through the sampling chamber, its beam is invisible to the off-axis light detector cell.
- the introduction of airborne particles which scatter the light beam produces light capable of detection by said off-axis light detector cell.
- the incident light beam can be projected or reflected out through and beyond said chamber, such that it may be conveniently absorbed outside the said chamber and thereby readily separated from scattered light within the said chamber.
- the detector cell positioned within the chamber is responsive only to the scattered light component. Output from said detector cell varies in proportion to the level of scattered light, providing a measure of the concentration of particles within said chamber.
- said chamber is conveniently in the form of a highly reflective elliptical tube.
- the tube includes a flat wall at each end to confine the air sample, perpendicular to the axis of said light beam.
- the sampling tube preferably in the end walls contains an induction or exhaust port to enable the continuous renewal of the air sample.
- the laser beam is projected along one focus of said elliptical tube. Any particles present in the path of the said laser beam would cause light scattering in all directions, but the elliptical chamber design would cause much of the scattered light to pass through the second focus of said elliptical tube, after one reflection, and again after subsequent multiple reflections. This is especially so for light scattered at 90° to said light beam, as is often the predominant scattering direction in the case of gas molecules.
- the said second focus forms a line, parallel to the said laser beam.
- the detector cell should form the shape of a thin rod to collect light arriving in all directions, at all points along its length.
- One form of such a detector could be an optical fibre or preferably a long thin laser rod with a detector cell mounted at one end. This can be a difficult or costly requirement which can be simplified by the novel modification of tapering the said elliptical tube. Because the walls of said elliptical tube are not now parallel, then by multiple reflections most of the scattered light would be focussed at a line or point on an end wall. It should be noted that with a tapered tube, one end wall is larger than the other and focussing will occur at the second focus of the larger end wall.
- a comparatively simple detector cell is therefore placed at the second focus of the larger end wall.
- Said detector cell requires a wide reception angle, between a few degrees and approaching 90 degrees from its perpendicular, depending upon the length and taper of said elliptical chamber.
- a suitable light-collecting lens e.g. "fisheye"
- cone or prism may be used with the said detector cell.
- light may be predominantly scattered at 90° for gas molecules, in the case of larger particles, such as smoke, the majority of scattering occurs within 0° to 30° of the axis of said light beam.
- One method for detecting the light scattered at small angles to the axis of said light beam could be to position a very large detector cell at one end of said chamber such as a disc with a relatively small central.hole to permit the passage of said light beam.
- a very large detector cell at one end of said chamber such as a disc with a relatively small central.hole to permit the passage of said light beam.
- Such cells are not usually available with sufficient sensitivity and low noise, so a comparatively small cell must be used.
- a concave mirror or lens could be used.
- a light sensing device for use in a fluid pollution monitoring apparatus, including a fluid sampling chamber, means for providing or projecting a coherent collimated light beam into said sampling chamber, means introducing sample fluid from an area to be monitored into said chamber to be exposed to said light beam, a light detector cell positioned at a location separated or shaded from said light beam, reflecting means in said chamber focussing as much as possible the available scattered light towards said reflecting means onto said detector cell.
- said reflecting means is an axially disposed concave reflector,
- a further reflecting means is placed at the centre, and in front of said reflecting means, to reflect said light beam in a desired direction, such as back towards said source or towards a light absorbing means within or beyond said chamber.
- Said detector cell is mounted at the rear of said further reflecting means, and positioned to receive scattered light which has been collected and focussed by said concave reflector.
- the detector cell is prevented from detecting direct light from said laser beam but will receive a large proportion of the scattered light which is received by said further reflecting means.
- a combination of a reflective elliptical wall chamber and concave reflector to achieve a resultant combination of all sources of reflected light is also possible according to the present invention.
- Two detector cells may be used to indicate differing proportions of light scattered either at small angles or angles of up to 90° to the light beam axis respectively in response to incidence of particles of differing size.
- first mentioned version of the present invention utilizes a highly light-reflective chamber with a collimated coherent laser beam instead of a highly light-absorbing chamber with a wide-angle incoherent Xenon lamp.
- This improvement provides an opportunity for substantial improvement in the ratio of scattered light to remnant incident light, improving the "optical signal-to-noise ratio".
- the incident light intensity (required to produce a given scattered light intensity appropriately matched to the sensitivity of said detector cell), may be reduced. Therefore the energy consumption of the light source may be reduced.
- Use of a Xenon lamp in the prior art accounted for the majority of the power consumption of the entire instrument. Thus it is possible in the present invention to provide for a substantial reduction in power consumption.
- the laser beam may be pulsed or modulated.
- the modulation frequency may be synchronised with a digital filter means provided by a phase-locked loop or microprocessor circuit (not shown), to optimise the signal-to-noise ratio. This modification further reduces the required intensity of the laser beam, reducing the energy consumption of the overall instrument.
- Figure 1 shows a sectional view of a sampling chamber for a light sensing pollution detection device.
- Figure 2 shows a further embodiment of a sampling chamber.
- the two laser beams may be rendered colinear by use of a prism 12 or mirror system.
- a prism 12 or mirror system One embodiment of such a m - system would utilize the differing angle of refraction applicable to each wavelength.
- each laser beam would be projected at a differing incident angle such that the two beams emerge as a pair of colinear beams into the collimator 13.
- the laser beams are directed back towards said source, they strike said prism at an angle greater than the critical angle and may be totally reflected toward a light absorbing means.
- a light absorbing means may be employed within or without the chamber and thus allow
- each said laser could be pulsed alternately at a rate _ synchronised with a switched-gain amplifier means to compensate for said differing sensitivity. It is known that the light-scattering coefficient for any gas or aerosol is dependent upon the wavelength of the incident light. Rayleigh has found that for gases, this coefficient varies inversely with the fourth power of the wavelength employed. Larger airborne particules have a coefficient which varies inversely with an exponent less than four (possibly as low as zero).
- said compensation means could also be used to compensate for the differing light-scattering coefficients at the two said laser wavelengths.
- the whole instrument could be used to determine the said exponent for a known air/gas/particulate sample.
- a novel circular light absorbing device 22 is shown for receiving the unscattered light beam travelling through the chamber.
- the device is circular as shown with reflective walls so that received light is continually reflected around the walls as shown and prevented from returning into the sampling chamber. Scattered light is received by reflector 17 ( Figure
- the cell preferably has a finite dimension to enable receipt of more light without the necessity to focus the light to a sharp point.
- a lens or lens system (not shown) may be used as an alternative to the reflector.
- Port means 23 are provided for introducing sample air into and out of the chamber.
Landscapes
- Analytical Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPI751288 | 1988-03-30 | ||
AU7512/88 | 1988-03-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0407429A1 true EP0407429A1 (de) | 1991-01-16 |
EP0407429A4 EP0407429A4 (en) | 1991-08-21 |
Family
ID=3772973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19890903975 Withdrawn EP0407429A4 (en) | 1988-03-30 | 1989-03-30 | Fluid pollution monitor |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0407429A4 (de) |
KR (1) | KR900700871A (de) |
WO (1) | WO1989009392A1 (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5392114A (en) * | 1988-03-30 | 1995-02-21 | Cole; Martin T. | Fluid pollution monitor |
US5256886A (en) * | 1991-04-30 | 1993-10-26 | E. I. Du Pont De Nemours And Company | Apparatus for optically detecting contamination in particles of low optical-loss material |
CH684556A5 (de) * | 1992-09-14 | 1994-10-14 | Cerberus Ag | Optischer Rauchmelder. |
GB2272760A (en) * | 1992-11-20 | 1994-05-25 | Thorn Security | Optical detection of combustion products |
GB9315779D0 (en) * | 1993-07-30 | 1993-09-15 | Stoneplan Limited | Apparatus and methods |
JPH08233736A (ja) * | 1995-02-27 | 1996-09-13 | Nohmi Bosai Ltd | 微粒子検出センサ |
AUPN965896A0 (en) * | 1996-05-03 | 1996-05-30 | Vision Products Pty Ltd | The detection of airborne pollutants |
CA2228335A1 (en) * | 1997-02-04 | 1998-08-04 | Edward Dauskurdas | Photodetector with coated reflector |
DE19741853A1 (de) * | 1997-09-23 | 1999-03-25 | Bosch Gmbh Robert | Rauchmelder |
GB9721861D0 (en) * | 1997-10-15 | 1997-12-17 | Kidde Fire Protection Ltd | High sensitivity particle detection |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2108707A1 (de) * | 1971-02-24 | 1972-09-07 | Portscht R | Rauchdetektor nach dem Streulichtprinzip bei zwei Wellenlängen |
GB1394583A (en) * | 1972-06-30 | 1975-05-21 | Svenska Utvecklings Ab | Method of detecting aerosols in air or gases and apparatus for this purpose |
GB2042166A (en) * | 1979-01-02 | 1980-09-17 | Coulter Electronics | Measuring the distribution of radiant energy from particles |
GB2045456A (en) * | 1979-03-07 | 1980-10-29 | Svenska Utvecklings Ab | Detecting particles suspended in a gas |
FR2577317A1 (fr) * | 1985-02-08 | 1986-08-14 | Inst Rech Hydrologique | Appareil de mesure de la turbidite d'un liquide en flux continu. |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3515482A (en) * | 1967-06-27 | 1970-06-02 | Us Navy | Aerosol photometer with improved electronic circuitry |
EP0026046B1 (de) * | 1979-09-05 | 1988-01-13 | Imperial Chemical Industries Plc | Verfahren und Apparat zur Ermittlung gasförmiger Verunreinigungen |
GB8502506D0 (en) * | 1985-01-31 | 1985-03-06 | Emi Ltd | Smoke detector |
-
1989
- 1989-03-30 KR KR1019890702208A patent/KR900700871A/ko not_active Application Discontinuation
- 1989-03-30 WO PCT/AU1989/000138 patent/WO1989009392A1/en not_active Application Discontinuation
- 1989-03-30 EP EP19890903975 patent/EP0407429A4/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2108707A1 (de) * | 1971-02-24 | 1972-09-07 | Portscht R | Rauchdetektor nach dem Streulichtprinzip bei zwei Wellenlängen |
GB1394583A (en) * | 1972-06-30 | 1975-05-21 | Svenska Utvecklings Ab | Method of detecting aerosols in air or gases and apparatus for this purpose |
GB2042166A (en) * | 1979-01-02 | 1980-09-17 | Coulter Electronics | Measuring the distribution of radiant energy from particles |
GB2045456A (en) * | 1979-03-07 | 1980-10-29 | Svenska Utvecklings Ab | Detecting particles suspended in a gas |
FR2577317A1 (fr) * | 1985-02-08 | 1986-08-14 | Inst Rech Hydrologique | Appareil de mesure de la turbidite d'un liquide en flux continu. |
Non-Patent Citations (1)
Title |
---|
See also references of WO8909392A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO1989009392A1 (en) | 1989-10-05 |
EP0407429A4 (en) | 1991-08-21 |
KR900700871A (ko) | 1990-08-17 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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17P | Request for examination filed |
Effective date: 19901001 |
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Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 19930818 |