EP0368935A1 - Chewing gum containing sweet protein and salt - Google Patents
Chewing gum containing sweet protein and saltInfo
- Publication number
- EP0368935A1 EP0368935A1 EP88908803A EP88908803A EP0368935A1 EP 0368935 A1 EP0368935 A1 EP 0368935A1 EP 88908803 A EP88908803 A EP 88908803A EP 88908803 A EP88908803 A EP 88908803A EP 0368935 A1 EP0368935 A1 EP 0368935A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chewing gum
- salt
- sweet protein
- sweet
- gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000015218 chewing gum Nutrition 0.000 title claims abstract description 100
- 229940112822 chewing gum Drugs 0.000 title claims abstract description 96
- 150000003839 salts Chemical class 0.000 title claims abstract description 70
- 239000003764 sweet protein Substances 0.000 title claims abstract description 58
- 239000000796 flavoring agent Substances 0.000 claims abstract description 47
- 235000019634 flavors Nutrition 0.000 claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 235000009508 confectionery Nutrition 0.000 claims abstract description 21
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000001103 potassium chloride Substances 0.000 claims abstract description 6
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 6
- 239000011780 sodium chloride Substances 0.000 claims abstract description 6
- 239000004615 ingredient Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 23
- 239000000892 thaumatin Substances 0.000 claims description 21
- 235000010436 thaumatin Nutrition 0.000 claims description 21
- 239000000839 emulsion Substances 0.000 claims description 19
- 108090000623 proteins and genes Proteins 0.000 claims description 18
- 102000004169 proteins and genes Human genes 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- 108050004114 Monellin Proteins 0.000 claims description 10
- 239000002585 base Substances 0.000 claims description 8
- 230000002209 hydrophobic effect Effects 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011800 void material Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 17
- 235000003599 food sweetener Nutrition 0.000 description 15
- 239000003765 sweetening agent Substances 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 11
- 235000011187 glycerol Nutrition 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 230000008447 perception Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
- 239000004067 bulking agent Substances 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 239000000600 sorbitol Substances 0.000 description 5
- 235000010356 sorbitol Nutrition 0.000 description 5
- 235000000346 sugar Nutrition 0.000 description 5
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 4
- 108010011485 Aspartame Proteins 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- 229930195725 Mannitol Natural products 0.000 description 4
- 239000000619 acesulfame-K Substances 0.000 description 4
- 239000000605 aspartame Substances 0.000 description 4
- 235000010357 aspartame Nutrition 0.000 description 4
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 4
- 229960003438 aspartame Drugs 0.000 description 4
- 230000001055 chewing effect Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000008123 high-intensity sweetener Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000594 mannitol Substances 0.000 description 4
- 235000010355 mannitol Nutrition 0.000 description 4
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 235000020357 syrup Nutrition 0.000 description 4
- 239000006188 syrup Substances 0.000 description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 3
- 239000004376 Sucralose Substances 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 235000010358 acesulfame potassium Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- -1 cycla- ates Chemical compound 0.000 description 3
- 235000010445 lecithin Nutrition 0.000 description 3
- 239000000787 lecithin Substances 0.000 description 3
- 229940067606 lecithin Drugs 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 235000019204 saccharin Nutrition 0.000 description 3
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 3
- 229940081974 saccharin Drugs 0.000 description 3
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 3
- 235000019408 sucralose Nutrition 0.000 description 3
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- 229920001908 Hydrogenated starch hydrolysate Polymers 0.000 description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000008122 artificial sweetener Substances 0.000 description 2
- 235000021311 artificial sweeteners Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- HCAJEUSONLESMK-UHFFFAOYSA-N cyclohexylsulfamic acid Chemical class OS(=O)(=O)NC1CCCCC1 HCAJEUSONLESMK-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229960002737 fructose Drugs 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 235000019600 saltiness Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000905957 Channa melasoma Species 0.000 description 1
- 229920001412 Chicle Polymers 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- 235000019499 Citrus oil Nutrition 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 235000019739 Dicalciumphosphate Nutrition 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 240000001794 Manilkara zapota Species 0.000 description 1
- 235000011339 Manilkara zapota Nutrition 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 235000007265 Myrrhis odorata Nutrition 0.000 description 1
- 240000004760 Pimpinella anisum Species 0.000 description 1
- 235000012550 Pimpinella anisum Nutrition 0.000 description 1
- 206010039424 Salivary hypersecretion Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000007326 Thaumatococcus daniellii Species 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007961 artificial flavoring substance Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 230000001013 cariogenic effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 239000010500 citrus oil Substances 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000019868 cocoa butter Nutrition 0.000 description 1
- 229940110456 cocoa butter Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
- 229940038472 dicalcium phosphate Drugs 0.000 description 1
- 229910000390 dicalcium phosphate Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000007983 food acid Nutrition 0.000 description 1
- 239000008369 fruit flavor Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229960004903 invert sugar Drugs 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 1
- 239000008368 mint flavor Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229940098458 powder spray Drugs 0.000 description 1
- 208000026451 salivation Diseases 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/14—Chewing gum characterised by the composition containing organic or inorganic compounds containing peptides or proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/02—Apparatus specially adapted for manufacture or treatment of chewing gum
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/064—Chewing gum characterised by the composition containing organic or inorganic compounds containing inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/10—Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
Definitions
- This invention relates generally to chewing gum and in particular to chewing gum containing sweet protein.
- Chewing gum generally comprises chewable gum base, flavor, and a sweetener. Recently, the sweetness and flavor characteristics of chewing gum have been improved by using high intensity artificial sweeteners which have desirable organoleptic qualities. Further, these artificial sweeteners are non-cariogenic and nontoxic.
- High intensity sweeteners of recent interest for use in gums include aspartame, acesulfame K, cycla- ates, saccharin, sucralose, thaumatin, and monellin. Though most high intensity sweeteners currently known release relatively quickly from chewing gum, some, such as thaumatin, monellin, and like sweet proteins, do not completely release from the chewing gum upon salivation or during chewing. As a result, the flavor and sweet ⁇ ness of these high intensity sweeteners is not fully experienced.
- Thaumatin is a proteinaceous substance ob ⁇ tained from the fruit of the tropical plant Thaumato- coccus daniellii which grows in tropical Africa. Thaumatin is about 2,000 to 3,000 times sweeter than - 2 -
- sucrose sucrose and is known to have a lingering sweet after ⁇ taste.
- the sweet protein monellin obtained from the fruit of the tropical plant Diosocoreo-plyllum cumminsii, has taste properties similar to thaumatin.
- Thaumatin and monellin apart from their intense' sweetness, are recognized as high-potency flavor and sweetness adjuvants capable of potentiating sweetness and flavor in chewing gum compositions. See, for example, U.S. Patent No. 4,412,984 (van der Loo et al.) and U.S. Patent No. 4,228,198 (Burge et al.).
- sweet proteins are known to be further suppressed when allowed to interact with ionic type ingredients such as salt. It is theorized that the sweet protein tends to become bound up in the gum base when mixed directly with the base or is denatured (i.e. experiences a reduced sweetening and/or flavor affect) when interacted with a salt, resulting in a reduction of their flavor and sweetness potentiating properties.
- Chewing gums containing high intensity sweet proteins and salt which have enhanced flavor would therefore constitute an advance in the art. These gums would be readily accepted by the consuming public and enjoy commercial success.
- a chewing gum composition having enhanced flavor.
- the composition comprises chewing gum ingredients such as a chewable gum base and flavor, sweet protein, and salt selected from sodium chloride, potassium chloride, or mixtures thereof.
- the sweet protein is physically separated from the salt in the gum.
- the sweet protein and salt do not substantially interact before the gum is chewed.
- the salt is preferably present in the chewing gum in amounts between about 10 to about 1000 parts per million (ppm) by weight of the chewing gum.
- a method of manu ⁇ facturing chewing gum having enhanced flavor comprising chewing gum ingredients such as chewable gum base and flavor, sweet protein, and a salt selected from sodium chloride, potassium chloride, or mixtures thereof.
- the method comprises adding the sweet protein and salt to the chewing gum ingredients in a form such that the sweet protein and salt are physically separated in the gum and accordingly do not substantially interact before the gum is chewed.
- the salt is com ⁇ bined in an amount to yield between about 10 to about 1000 ppm by weight of the chewing gum.
- the combination of salt and sweet protein as contemplated herein provide a chewing gum composition having enhanced flavor.
- the sweet protein and salt physically separate in the chewing gum during storage, the salt is prevented from interacting with the sweet protein.
- longer shelf life is also achieved.
- Sweet proteins contemplated by the present invention include thaumatin, monellin, and other high intensity sweet proteins having similar release charac ⁇ teristics. Accordingly the present invention con ⁇ templates high intensity sweet proteins having a low release when mixed with other ingredients. Though a precise method for determining the release charac ⁇ teristics of thaumatin and monellin is not presently known; it is believed that the high intensity sweet proteins contemplated have less than about 20% by weight release from a gum after about ten minutes of chewing when admixed directly in their normal form.
- the term ⁇ r normal form is intended to mean the form in which the sweet protein is normally added to chewing gum ingredients. The form may thus be liquid or powder, but most likely will be powder.
- thaumatin and monellin are con ⁇ templated. It is to be understood, however, that other sweet proteins not specifically mentioned herein may also be employed in the present invention. Further ⁇ more, any combination of these high intensity sweet proteins may also be employed.
- sweet proteins comprise between about 5 and about 1000 ppm by weight of the chewing gum.
- sweet proteins comprise between about 40 and about 600 ppm by weight of the chewing gum. It should be understood, however, that the release characteristics of sweet protein vary with the method of manufacture of the chewing gum em ⁇ ployed.
- the chewing gum when the sweet protein thaumatin is added to other chewing gum ingredients in the powdered form, the chewing gum preferably comprises between about 100 and about 1000 ppm and more prefer ⁇ ably between about 500 and about 600 ppm by weight of the chewing gum.
- the chewing gum When applied to a chewable core center or combined as an emulsion, the chewing gum preferably comprises between about 5 and about 200 ppm and more preferably between about 75 and about 125 ppm by weight of the chewing gum.
- the chewing gum when combined with a liquid center fill, the chewing gum preferably comprises between about 5 and about 100 ppm and more preferably between -about 40 and about 60 ppm by weight of the chewing gum.
- the salt contemplated by the present in ⁇ vention may comprise sodium chloride, potassium chloride, or mixtures thereof. It is contemplated that the salt be of a food grade quality.
- the salt may be obtained from any commercial manufacturer or may be processed by any of the methods known to those skilled in the art.
- the chewing gum comprises the salt in amounts between about 10 and about 1000 ppm by weight of the chewing gum.
- the chewing gum comprises salt in amounts between about 30 and about 100 ppm and most preferably between about 50 and about 80 ppm by weight of the chewing gum.
- the chewing gum however should not contain salt in amounts greater than about 1000 ppm because this is the point where it is believed that the perception saltines by the consumer occurs. It is to be understood that this perception level may vary depending upon the type and strength of flavor em ⁇ ployed, the level of sweetness, and the perception of other ingredients in the chewing gum.
- mild flavors such as mild fruits and various mild mint flavors may be combined with up to 1000 ppm salt in chewing gum before saltiness is perceived by the consumer.
- Strong flavors, especially strong fruit flavors, in combination with acids and cinnamon type flavors may be combined with slightly higher amounts of salt without a saltiness perception by the consumer.
- compositions containing acesulfame-K or fructose may possess a lower level of salt perception, possibly about 900 ppm.
- the chewing gum of the present invention preferably comprises salt in an amount below the salt perception level which is determined by the particular combination of the chewing gum ingredients. It is presently believed that this perception level is about 1000 ppm by weight of the chewing gum.
- a chewing gum composition com ⁇ prises a water soluble bulk portion and a water insoluble chewable gum base portion and, typically water insoluble flavors.
- the water soluble portion dissipates with a portion of the flavor over a period of time during chewing.
- the gum base portion is re ⁇ tained in the mouth throughout the chew.
- the insoluble gum base generally comprises elastomers, resins, fats and oils, waxes,, softeners and inorganic fillers.
- Elastomers may include polyiso- butylene, isobutylene-isoprene copolymer, styrene butadiene rubber as well as natural latexes such as chicle.
- Resins include polyvinylacetate and terpene resins.
- Fats and oils may also be included in the gum base, including tallow, hydrogenated and partially hydrogenated vegetable oils, and cocoa butter.
- Com ⁇ monly employed waxes include paraffin, microcrystalline and natural waxes such as beeswax and carnuba.
- the insoluble gum base constitutes between about 5 to 95 weight percent of the gum.
- the insoluble gum base comprises about 10 to about 50 weight percent of the gum and more preferably about 20 to about 30 weight percent.
- the gum base typically also includes a filler • component.
- the filler component such as calcium carbonate, magnesium carbonate, talc, dicalcium phosphate and the like.
- the filler may constitute be ⁇ tween about 5 to about 60 weight percent of the gum base.
- the filler comprises about 5 to 50 weight percent of the chewing gum base.
- Gum bases typically also contain softeners, including glycerol monostearate and glycerol tri ⁇ acetate. Further, gum bases may also contain optional ingredients such as antioxidants, colors, and emulsi- fiers. The present invention contemplates employing any commercially acceptable gum base.
- the water soluble portion of chewing gum may further comprise softeners, sweeteners, flavors and combinations thereof.
- Softeners are added to the chewing gum in order to optimize the chewability and mouth feel of the gum.
- Softeners also known in the art as plasticizers or plasticizing agents, generally constitute between about 0.5 to about 15.0 weight percent of the chewing gum.
- Softeners contemplated by the present invention include glycerin, lecithin, and combinations thereof.
- aqueous sweetener solu ⁇ tions such as those containing sorbitol, hydrogenated starch hydrolysates, corn syrup and combinations thereof may be used as softeners and binding agents in gum.
- sweeteners include both sugar and sugarless components.
- Sugar sweeteners generally include saccharide contain ⁇ ing components commonly known in the chewing gum art which comprise but are not limited to sucrose, dextrose, maltose, dextrin, dried invert sugar, fruc ⁇ tose, levulose, galactose, corn syrup solids, and the like, alone or in any combination.
- Sugarless sweeteners include components with sweetening charac ⁇ teristics but are devoid of the commonly known sugars and comprise but are not limited to sugar alcohols such as sorbitol, mannitol, xylitol, hydrogenated starch hydrolysates, maltitol, and the like, alone or in any combination. Also contemplated are relatively faster releasing sweeteners such as aspartame, sucralose, acesulfame-K, cyclamates and saccharin.
- any combination of sugar and/or sugarless sweeteners may be employed in the chewing gum.
- the sweetener may be present in the chewing gum in whole or in part as a water soluble bulking agent.
- the softener may be combined with the sweetener such as in an aqueous sweetener solution.
- Flavors contemplated by the present invention include any liquid flavoring which is of food accept ⁇ able quality.
- the flavor may comprise essential oils, synthetic flavors, or mixtures thereof including but not limited to oils derived from plants and fruits such as citrus oils, fruit essences, peppermint oil, spear ⁇ mint oil, clove oil, oil of wintergreen, anise, and the like.
- Artificial flavoring components are also contem ⁇ plated by the present invention. Those skilled in the art will recognize that natural and artificial flavors may be combined in any sensorally acceptable blend. All such flavors and blends are contemplated by the present invention.
- Flavors may be present in the chewing gum in an mount within the range of from about 0.1 to about 10.0 weight percent and preferably from about 0.5 to about 3.0 weight percent of the gum.
- the flavor may comprise the components already mentioned.
- Optional ingredients such as colors, emulsi- fiers and pharmaceutical agents may be added to the chewing gum.
- the chewing gum of the present invention is manufactured by combining chewing gum ingredients such as chewable gum base and flavor, with sweet protein and salt which are in a form such that they are substanti ⁇ ally physically separate in the gum. Accordingly, the present invention contemplates employing any of the commonly known chewing gum manufacturing methods which achieve a substantial physical separation of the sweet protein and salt.
- the chewing gum may be manufactured by adding the sweet protein and/or salt to various chewing gum ingredients in any commercially available mixer known in the art. After the ingredients have been thoroughly mixed, the gum mass is discharged from the mixer and shaped into the desired form such as by - 10 -
- the ingredients are mixed by first melting the gum base and adding it to the running mixer.
- the base may also be melted in the mixer it ⁇ self. Color may also be added at this time.
- a softener such as glycerin may then be added next along with syrup and a portion of bulking agent. Further portions of the bulking agent may then be subsequently added to the mixer. Flavor is typically added with the final portion of the bulking agent.
- the salt and sweet protein may be added at any time as long as either one or both of the compounds are in a form which will keep the two compounds physically separate from one another.
- the sweet proteins contemplated may be combined in the form of an emulsion while the salt is separately added in aqueous solution.
- the emulsion may be formed in any way.
- the emulsion is prepared by first dissolving the sweet protein in water to form an aqueous solution, and them emulsifying the aqueous solution with a com ⁇ pound possessing hydrophobic characteristics.
- the aqueous solution may be emulsified with the hydrophobic compound in any known manner, but it is preferred that an emulsifier be employed to accomplish this purpose.
- the hydrophobic compound com ⁇ prises a liquid flavor oil.
- flavor oils include synthetic and natural flavoring compounds.
- the hydro- phobic compound may also comprise non-flavor compounds.
- vegetable oils and other hydrophobic non-flavor compounds are also contemplated.
- the aqueous sweetener solution may comprise up to 25 weight percent of the sweet protein. Con ⁇ centrations above 25 weight percent, however, should be avoided to prevent foaming of the solution. Prefer ⁇ ably, the aqueous sweet protein solution comprises about 1 weight percent of the sweet protein. In any event, the present invention contemplates aqueous solutions of various concentrations.
- the aqueous solution may be heated in order to enhance dissolution and/or its emulsifying action.
- glycerin or a similar compound, may be added to the aqueous solution to prevent gellation.
- the emulsion may be prepared by mixing the aqueous solution with flavor.
- the emulsion may be formed by any manner known in the art, but preferably • the emulsion is formed with the aid of an emulsifier.
- Emulsifiers contemplated include any span, tween, or similar compound.
- the emulsifier employed is matched to the hydrophobic compound by its Hydrophile-Lipophile Balance (HLB) number.
- HLB Hydrophile-Lipophile Balance
- the HLB of an emulsifier is an expression of its hydrophilic- lipophile balance, i.e., the balance of the size and strength of the hycrophilic and the lipophilic groups of an emulsifier.
- the HLB system which has been known to those skilled in the art since the later 1940' s is useful in choosing an appropriate emulsifier is lecithin, a well known, inexpensive emulsifier.
- the salt may be added to the chewing gum ingredients independently of the emulsion, either before or after the emulsion and in either the solid phase or dissolved in a liquid.
- the salt may also be modified to a form which enhances its physical separa ⁇ tion from the sweet protein. Accordingly the salt may be encapsulated or coated in manners known in the art.
- the emulsion may also comprise other ingredients nonessential to the formation of the emulsion.
- ingredients include but are not limited to coloring agents such as dyes, lakes, and natural colorants, food acids, glycerin and like components, medicants, and relatively fast releasing high potency sweeteners such as aspartame, sucralose, acesulfame-K, cyclamates, and saccharin.
- the chewing gum composition may com ⁇ prise separate portions, one portion containing the salt and the other containing the sweet protein.
- the chewing gum may contain a core portion and a layer portion, with sweet protein and salt being present in separate portions.
- a high intensity sweetener may be contained in the core portion or applied to the surface of the core portion.
- the core portion of the chewing gum is manufactured in a conventional manner. Accordingly, the base is heated and placed in a mixer. If coloring is desired it may be added at this point followed by the sweetener, plasticizing agent and flavor. When the core portion of the chewing gum is removed from the mixer, it is rolled in conventional product forming equipment as is well known in the art.
- a layer containing sweet protein may be deposited on the surface of a salt containing core portion by applying a rolling compound comprising the sweet protein.
- the rolling compound contemplated comprises sweet protein in combination with mannitol, sorbitol, sucrose, starch, calcium carbonate, talc, other orally acceptable substances or mixtures thereof.
- the rolling compound may comprise from about 0.25% to about 10.0% but preferably about 1% to about 3% by weight of the chewing gum composition.
- the rolling compound is preferably applied to the surface of the core portion by employing the well known dusting procedure immediately prior to rolling the gum in the product forming equipment in order to prevent adhesion of the gum and the rollers, particular ⁇ ly when the gum is warm.
- the sweet protein may be deposited onto the surface of the core portion by using a powder spray process.
- the powder containing the sweet protein is suspended in a pressurized gas which is sprayed onto a surface.
- sweet protein may be applied to the surface of the core portion by way of a solution which is sprayed thereon.
- a solution which is sprayed thereon.
- an aqueous solution containing sweet protein is formed and then sprayed as an aerosol mist.
- the chewing gum composition may comprise a chewable gum base shell enclosing an internal void and a liquid center fill in the void.
- the liquid center fill comprises sweet protein and the chewable gum base comprises salt.
- the shell portion of the chewing gum composi ⁇ tion may be manufactured by any conventional manner. Accordingly, first the base is heated and placed in a running mixer. If coloring is desired it may be added at this point followed by a bulking agent, plasticizing agent, flavor and the salt. To enhance separation either the salt or the sweet protein may be further treated'by physical separation techniques such as formation in emulsion, encapsulation, etc. When the chewing gum is removed from the mixer it is shaped and then filled with the liquid center fill using con ⁇ ventional product forming equipment in a known manner.
- the liquid center fill may comprise in addi ⁇ tion to sweet protein, one or more carbohydrate syrups, glycerin, thickners, flavors, acidulants, colors, sugars and sugar alcohols in conventional amounts. These ingredients may be combined in any conventional manner. Of course, the makeup may be reversed whereby the salt is present in the liquid center and the sweet protein is present in the shell.
- the chewing gum may be flat and contain separate layers, one of which comprises the salt and the other comprises the sweet protein.
- Multilayered chewing gums may be produced by coex- trusion or by combining separately extruded layers.
- the salt and/or the sweet protein may be treated to enhance their physical separation by any technique known in the art. Such techniques include but are not limited to encapsulation, spray-drying, spray-chilling, fluid bed coating, and mixing the sweetner with aqueous gelatin followed by drying, grinding and optional granulation.
- an emulsion containing salt and thaumatin is prepared.
- This aqueous solution is mixed with a solution containing emulsifier such as lecithin and a hydrophobic ingredient such as flavor to form an emulsion.
- the emulsion containing salt and thaumatin is added to the other chewing ingredients to yield a chewing gum containing 100 ppm salt and 25 ppm thaumatin.
- the resulting gum may be a standard sugarless chewing gum containing commonly accepted amounts of gum base, glycerin, sorbitol, mannitol, and asparta e.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Confectionery (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10095987A | 1987-09-25 | 1987-09-25 | |
US100959 | 1987-09-25 | ||
US24609888A | 1988-09-19 | 1988-09-19 | |
US246098 | 1999-02-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0368935A4 EP0368935A4 (en) | 1989-10-04 |
EP0368935A1 true EP0368935A1 (en) | 1990-05-23 |
Family
ID=26797748
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88908803A Withdrawn EP0368935A1 (en) | 1987-09-25 | 1988-09-23 | Chewing gum containing sweet protein and salt |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0368935A1 (ja) |
JP (1) | JPH02501265A (ja) |
AU (1) | AU2526688A (ja) |
ES (1) | ES2010808A6 (ja) |
FI (1) | FI892502A (ja) |
GR (1) | GR880100638A (ja) |
WO (1) | WO1989002703A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5198251A (en) * | 1989-04-19 | 1993-03-30 | Wm. Wrigley Jr. Company | Gradual release structures for chewing gum |
US5139794A (en) * | 1989-04-19 | 1992-08-18 | Wm. Wrigley Jr. Company | Use of encapsulated salts in chewing gum |
US5154939A (en) * | 1989-04-19 | 1992-10-13 | Wm. Wrigley Jr. Company | Use of salt to improve extrusion encapsulation of chewing gum ingredients |
US5165944A (en) * | 1989-04-19 | 1992-11-24 | Wm. Wrigley Jr. Company | Gradual release structures for chewing gum |
US5229148A (en) * | 1989-04-19 | 1993-07-20 | Wm. Wrigley Jr. Company | Method of combining active ingredients with polyvinyl acetates |
AU639645B2 (en) * | 1989-10-10 | 1993-07-29 | Wm. Wrigley Jr. Company | Gradual release structures made from fiber spinning techniques |
US5128155A (en) * | 1990-12-20 | 1992-07-07 | Wm. Wrigley Jr. Company | Flavor releasing structures for chewing gum |
JP4579050B2 (ja) * | 2004-05-13 | 2010-11-10 | 三栄源エフ・エフ・アイ株式会社 | 甘味及び/又は香味の持続性に優れたチューインガム |
US20120052154A1 (en) * | 2009-06-10 | 2012-03-01 | Sandrine Cudre | Inverse emulsion and use thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2315864A1 (fr) * | 1975-07-04 | 1977-01-28 | Tate & Lyle Ltd | Compositions sucrantes contenant des agents sucrants proteiniques |
DE3010836A1 (de) * | 1980-03-21 | 1981-10-01 | Barnängen Deutschland GmbH, 5020 Frechen | Kaugummi und verfahren zu seiner herstellung |
WO1984002450A1 (en) * | 1982-12-27 | 1984-07-05 | Wrigley W M Jun Co | Chewing gum composition and method of sweetening |
EP0185442A2 (en) * | 1984-10-05 | 1986-06-25 | Warner-Lambert Company | A novel sweetener delivery system and a chewing gum composition comprising the sweetener delivery system |
US4642235A (en) * | 1984-10-26 | 1987-02-10 | Wm. Wrigley Jr. Company | Chewing gum with center fill comprising thaumatin or monellin and method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3681087A (en) * | 1970-04-15 | 1972-08-01 | Meditron Inc | Chewing gum composition |
-
1988
- 1988-09-23 JP JP50801088A patent/JPH02501265A/ja active Pending
- 1988-09-23 AU AU25266/88A patent/AU2526688A/en not_active Abandoned
- 1988-09-23 WO PCT/US1988/003283 patent/WO1989002703A1/en not_active Application Discontinuation
- 1988-09-23 EP EP88908803A patent/EP0368935A1/en not_active Withdrawn
- 1988-09-26 GR GR880100638A patent/GR880100638A/el unknown
- 1988-09-26 ES ES8802918A patent/ES2010808A6/es not_active Expired
-
1989
- 1989-05-23 FI FI892502A patent/FI892502A/fi not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2315864A1 (fr) * | 1975-07-04 | 1977-01-28 | Tate & Lyle Ltd | Compositions sucrantes contenant des agents sucrants proteiniques |
DE3010836A1 (de) * | 1980-03-21 | 1981-10-01 | Barnängen Deutschland GmbH, 5020 Frechen | Kaugummi und verfahren zu seiner herstellung |
WO1984002450A1 (en) * | 1982-12-27 | 1984-07-05 | Wrigley W M Jun Co | Chewing gum composition and method of sweetening |
EP0185442A2 (en) * | 1984-10-05 | 1986-06-25 | Warner-Lambert Company | A novel sweetener delivery system and a chewing gum composition comprising the sweetener delivery system |
US4642235A (en) * | 1984-10-26 | 1987-02-10 | Wm. Wrigley Jr. Company | Chewing gum with center fill comprising thaumatin or monellin and method |
Non-Patent Citations (1)
Title |
---|
See also references of WO8902703A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2010808A6 (es) | 1989-12-01 |
FI892502A0 (fi) | 1989-05-23 |
FI892502A (fi) | 1989-05-23 |
AU2526688A (en) | 1989-04-18 |
EP0368935A4 (en) | 1989-10-04 |
WO1989002703A1 (en) | 1989-04-06 |
GR880100638A (el) | 1989-06-22 |
JPH02501265A (ja) | 1990-05-10 |
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