EP0344574A1 - Suscepteurs ayant une couche métallisée déposée sur du papier pour le chauffage des aliments dans un four à micro-ondes - Google Patents

Suscepteurs ayant une couche métallisée déposée sur du papier pour le chauffage des aliments dans un four à micro-ondes Download PDF

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Publication number
EP0344574A1
EP0344574A1 EP89109225A EP89109225A EP0344574A1 EP 0344574 A1 EP0344574 A1 EP 0344574A1 EP 89109225 A EP89109225 A EP 89109225A EP 89109225 A EP89109225 A EP 89109225A EP 0344574 A1 EP0344574 A1 EP 0344574A1
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EP
European Patent Office
Prior art keywords
susceptor
paper
metal
heating
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP89109225A
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German (de)
English (en)
Inventor
Peter S. Peshek
Craig Shevlin
Jonathon D. Kemske
Michael R. Perry
Matthew W. Lorence
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Pillsbury Co
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Pillsbury Co
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Publication date
Priority claimed from US07/267,545 external-priority patent/US4970360A/en
Application filed by Pillsbury Co filed Critical Pillsbury Co
Publication of EP0344574A1 publication Critical patent/EP0344574A1/fr
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
    • B65D81/3446—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package specially adapted to be heated by microwaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3439—Means for affecting the heating or cooking properties
    • B65D2581/344—Geometry or shape factors influencing the microwave heating properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3463—Means for applying microwave reactive material to the package
    • B65D2581/3466—Microwave reactive material applied by vacuum, sputter or vapor deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3463—Means for applying microwave reactive material to the package
    • B65D2581/3467—Microwave reactive layer shaped by delamination, demetallizing or embossing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3463—Means for applying microwave reactive material to the package
    • B65D2581/3468—Microwave reactive material directly applied on paper substrate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3472—Aluminium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3471—Microwave reactive substances present in the packaging material
    • B65D2581/3477—Iron or compounds thereof
    • B65D2581/3478—Stainless steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3486—Dielectric characteristics of microwave reactive packaging
    • B65D2581/3487—Reflection, Absorption and Transmission [RAT] properties of the microwave reactive package

Definitions

  • Microwave heating of foods in a microwave oven differs significantly from conventional heating in a conventional oven.
  • Conventional heating involves surface heating of the food by energy transfer from a hot oven atmosphere.
  • microwave heating involves the absorption of microwaves which may penetrate significantly below the surface of the food.
  • the oven atmosphere will be at a relatively low temperature. Therefore, surface heating of foods in a microwave oven can be problematical.
  • a susceptor is a microwave responsive heating device that is used in a microwave oven for purposes such as crispening the surface of a food product or for browning. When the susceptor is exposed to microwave energy, the susceptor gets hot, and in turn heats the surface of the food product.
  • Conventional susceptors have a thin layer of poly­ester, used as a substrate, upon which is deposited a thin metallized film.
  • U.S. Patent No. 4,641,005 issued to Seiferth, discloses a conventional metallized polyester film-type susceptor which is bonded to a sheet of paper.
  • substrate is used to refer to the material on which the metal layer is directly deposited, e.g., during vacuum evaporation, sputtering, or the like.
  • a biaxially oriented polyester film is the substrate used in typical conventional susceptors.
  • polyester film cannot, however, be heated by itself or with many food items in a microwave oven without undergoing severe structural changes: the polyester film, initially a flat sheet, may soften shrivel, shrink, and eventually may melt during microwave heating. Typical polyester melts at approximately 220-­260° C.
  • polyester film has been thought to be necessary as a substrate in order to provide a suitable surface upon which a metal film may be effectively deposited.
  • a metallized layer of polyester is typi­cally bended to a sheet of paper or paperboard.
  • the thin film of metal is positioned at the adhesive interface between the layer of polyester and the sheet of paper.
  • metallized polyester will tend to break up during heating, even when the metallized polyester is adhesively bonded to a sheet of paper. Such breakup of the metallized polyester layer reduces the responsiveness of the susceptor to microwave heating. It has been observed that some areas of a conventional susceptor may initially heat substantially when exposed to microwave radiation, and then the heating effects of microwave radiation will appear to reduce. The responsiveness of those areas of the susceptor to micro­wave radiation decreases significantly as a result of breakup.
  • U.S. Patent No. 4,735,513, issued to Watkins et al. discloses an attempt to use backing sheets in addition to a coated susceptor substrate in order to maintain the structural integrity of the susceptor.
  • U.S. Patent No. 4,267,420, issued to Brastad discloses a flexible suscep­tor film which includes a thin metal film on a dielectric substrate such as thin polyester. This thin structure may then be supported by more rigid dielectric material such as paperboard.
  • U.S. Patent No. 4,705,929, issued to Atkinson discloses a rigid microwave tray and method for producing such a tray. A microwave interactive layer of material is provided on the upper face of the tray. None of these patents disclose a metallized layer deposited directly on a paper substrate.
  • a susceptor for heating a food substance in a microwave oven which has a thin film of metal deposited on a dimensionally stable paper substrate. Other rough substrates may be used.
  • the susceptor should have a complex impedance measured prior to heating, at the frequency of the microwave oven, which has a real part of the impedance, most preferably between 30 and 200 ohms per square for typical loads.
  • a substrate such as paper may be used which has a surface that it much less smooth than what has been heretofore thought to be required for a substrate.
  • a substrate having a surface smoothness which may be expressed as an arithmetic average roughness, measured to be greater than 0.5 microns, may be used with the present invention.
  • the preferred thickness of the thin film of metal is interrelated to the conductivity of the metal and the smoothness of the paper substrate.
  • the metal film is preferably aluminum having a thickness between 50 Angstroms and 600 Angstroms.
  • FIG. 1 illustrates a susceptor 10 for heating the surface of a food product in a microwave oven.
  • the susceptor 10 has a paper substrate 11.
  • the paper substrate 11 is preferably dimensionally stable. That is, the substrate 11 substantially maintains its shape, struc­tural integrity, and dimensions in both length and width during microwave heating. This is an advantage over poly­ester substrates which tend to shrink and shrivel during microwave heating, if not adhesively bonded to a stable material.
  • the paper substrate 11 may be a flexible paper sheet. Alternatively, the paper substrate 11 may be a rigid sheet of paper or paperboard.
  • the substrate 11 may be made from fibrous material such as paper. Under a microscope, the surface 13 of a sheet of paper 11 may appear rough, with microscopic hills and valleys. As will be explained more fully herein, the degree of roughness of the paper substrate 11 is an important determinant of the susceptor electrical properties.
  • a thin layer of metal film 12 is deposited on the surface 13 of the paper substrate 11.
  • the thin layer of metal film 12 is deposited directly on the surface 13 of the paper substrate 11.
  • the "thick­ness" of the thin metal film is defined as follows.
  • the thickness of the metal layer is determined during deposi­tion using a Inficon Model XTC crystal thickness monitor.
  • the monitor utilizes a 6 MHz plano-convex quartz crystal whose frequency of oscillation varies as a function of the amount of metal deposited upon it, the density of the metal, and the modulus of elasticity in shear of the deposited metal.
  • the monitor may be preprogrammed with the values of these constants for the material to be deposited.
  • a tooling factor which specifies the ratio of thickness at the substrate holder to the thickness at the quartz crystal is also preprogrammed and assures that the thickness reported by the thickness monitor is that of the deposit on the substrate holder.
  • Accurate calibration is accomplished by measuring the thickness of the deposit on the substrate by independent means. Typically, a profilometer or optical spectrometer is employed for verification of calibration of thickness reported by the crystal monitor.
  • the metal film thicknesses herein refer to the film thickness deposited on the smooth face of the crystal monitor.
  • the actual thickness deposited on the less-­regular paper substrate surface probably varies from point to point and would be extremely difficult to measure accurately.
  • the metal thicknesses reported by the crystal monitor are believed to be reproducible to within about ⁇ 10%.
  • the thickness of the metal film 12 is critical to the successful operation of the susceptor 10. If the metal film 12 is made too thin, the susceptor 10 will not heat adequately in response to microwave radiation. If the metal film 12 is made too thick, the susceptor 10 will suffer from the problem of arcing. Thus, the thickness of the metal film 12 has an upper limit due to arcing, and a lower limit which is insufficient to cause adequate heating of the food. A thickness which falls in the range between these two extremes will provide satisfactory results in practice. However, the upper and lower limits of the range are affected by the smoothness of the surface 13 of the paper substrate 11, and also by the composition of the metal which is deposited in forming the metal film 12.
  • the thickness should preferably be between 50 Angstroms and 600 Angstroms.
  • a thinner metal film 12 will be operable to provide adequate heating. If the surface 13 of the paper substrate 11 is less smooth, a slightly thicker metal film 12 will be necessary before adequate heating will be observed. A similar fact is observed for the thickness of the metal film 12 which produces arcing. A thinner metal film 12 will result in arcing for a smoother surface 13 as compared with a less smooth surface 13 of the paper substrate 11. Therefore, the range of thick­nesses for the metal film 12 which will provide satisfac­tory results in practice will be shifted downwardly for a smoother surface 13 as compared with a less smooth surface 13 of the paper substrate 11.
  • the heating performance of the susceptor is dependent upon the thickness of the metal film 12 and the smoothness of the surface 13.
  • the best way to predict the heating performance of a susceptor is by measuring the impedance of the susceptor using a network analyzer.
  • the impedance is a complex number having a reactive part or imaginary part, and having a resistive part or real part. Of particular interest is the resistive or real part of the surface impedance of the susceptor. A thinner metal film 12 will have a higher resistive component to its impedance.
  • the impedance of the susceptor must be measured at the frequency of the microwave oven.
  • the frequency is 2450 MHz.
  • surface resistance of a susceptor has been measured under direct current conditions. While such measurements may have been useful in characterizing thin film susceptors deposited directly on polyester, such measurement tech­niques are inadequate for the present invention. Some metal coatings may appear discontinuous when measured with direct current, while being operative for purposes of the present invention. Therefore, all impedances, and surface resistances, specified in the present application for the present invention refer to measurements made at the frequency of the microwave oven, which in all cases is 2450 MHz unless otherwise stated.
  • Resistive components of the complex impedance measured at the frequency of the microwave oven may differ significantly from surface resistivities measured under direct current conditions. It is generally believed that the prior art fails to recognize the need to characterize a susceptor comprising a thin film of metal deposited directly on a paper substrate by measuring the complex impedance at the frequency of the microwave oven.
  • a lower limit for the resistive component of the complex impedance of the susceptor is determined by the desire to avoid arcing. This relates to the maximum thickness for the metal film 12.
  • the lower limit for the resistive component of the impedance of the susceptor is dependent upon the metal comprising the conductive film and upon the smoothness of the surface 13 of the paper substrate 11.
  • a resistive component less than 30 ohms/­square should be avoided, because arcing has been observed in practice where the metal film 12 was made of aluminum and the resistive component was less than 30 ohms/square. Where the resistive component is between about 30 ohms/­square and about 125 ohms/square, for aluminum, arcing is dependent upon the substrate 11. Where the resistive component is greater than 125 ohms/square, no arcing was observed for metal films 12 made of aluminum. Measurement of the resistive component is made prior to microwave heating.
  • the upper limit for the resistive component of the impedance of the susceptor is dependent upon heating efficacy. Where the resistive component of the impedance is too high, the susceptor will not adequately heat.
  • a resistive component less than about 35,000 ohms/square is preferred.
  • a resistive component less than about 14,500 ohms/square is more preferred.
  • a resistive component less than about 7,000 ohms/square is even more preferred.
  • a resistive component of about 4,500 ohms/square is especi­ally preferred.
  • a resistive component of the impedance of the susceptor less than about 3,300 ohms/square is more especially preferred.
  • a resistive component of the impedance of the susceptor less than about 2000 ohms/square is most especially preferred.
  • absorption may be measured with a network analyzer to determine the minimum thinness of the metal film 12.
  • An absorption greater than about 1% is preferred.
  • An absorption greater than about 2.5% is more preferred.
  • An absorption greater than about 5% is even more preferred.
  • An absorption greater than about 7.5% is especially preferred.
  • An absorption, as measured with a network analyzer, greater than about 10% is most especially preferred.
  • the value of absorption may be tailored to the particular food product which is to be heated.
  • the metal film 12 is preferably made of aluminum.
  • the metal film is applied using a suitable deposition process, including vacuum deposition, sputtering, E-beam, chemical vapor deposition, or combinations of these methods. Any method capable of depositing a thin film layer of metal unto a paper substrate may be used.
  • the metal film 12 may also be advantageously made of stainless steel.
  • the metal film 12 preferably has a thickness between about 50 Angstroms and about 3500 Angstroms.
  • the thickness of the metal film 12 is more preferably between about 100 Angstroms and about 3000 Angstroms, for stainless steel.
  • the metal film 12 preferivelyably has a complex impedance measured at the frequency of the microwave oven which has a resistive part between about 60 ohms/square to about 7000 ohms/square.
  • the real part of the resistivity is more preferably between about 300 ohms/square to about 5000 ohms/square for stainless steel.
  • stainless steel includes any iron alloy having chromium included therein. This includes iron alloys sometimes referred to as rust-­free or rust-resistant.
  • the metal film 12 may also be made of nickel, gold, tantalum, tungsten, silver, nichrome, titanium, oxides of titanium, oxides of vanadium, as well as other metals, metal oxides, and alloys. Other conductive materials may be used to produce a thin film which heats responsive to microwave radiation.
  • the substrate 11 preferably comprises cellulose fiber formed into a sheet.
  • the substrate 11 should be a "micro­wave stable" material, that is, it should not signifi­cantly shrivel, shrink or melt during microwave heating for a predetermined period of time necessary to heat a food product. Rough substrates other than paper may be used. Paper sheets are considered herein to be paper substrates having a thickness less than about 0.0254 cm. Paperboard may include paper substrates which have a thickness greater than about 0.0254 cm. Various types of paper may be used, including SBS, SUS, sulfite, writing, parchment, news, as well as other types and grades of paper.
  • the paper substrate 11 may include a coating or surface treatment, or filler, to enhance smoothness.
  • Clay coatings have been used with satisfactory results. Clay coatings have been found to improve the stability of the electrical impedance of the susceptor during microwave heating, and are preferred where stability is an important design consideration. Coatings or surface treatments may also be used to enhance brightness or structural integrity.
  • the finish on the surface 13 of the paper substrate 11 may be modified by calendering, chemical treatment, or lacquers.
  • Table I shows the relationship between the thickness of the metal film 12 and the measured resistive component of the surface impedance, as measured with a network analyzer, for various paper substrates and two examples of polyester substrates.
  • the paper substrates 11 which were used included bond paper, copier paper, filter paper, parchment paper, and Westvaco clay coated paperboard.
  • the two polyester substrates which were used were biaxially oriented polyester (BOPET) bonded to a support member, and polyester extruded onto paperboard (EXPET).
  • BOPET biaxially oriented polyester
  • EXPET polyester extruded onto paperboard
  • samples having a surface resistance less than about 110 ohms/square experienced arcing.
  • Samples having a surface resistance between about 110 ohms/square and about 300 ohms/square may or may not have experienced arcing depending upon the composition of the substrate 11.
  • No samples having a thin metal film of stainless steel experienced arcing where the surface resistance was greater than about 300 ohms/square.
  • substrates may be used which have a surface smoothness that is significantly rougher than conventional polyester film typically used for substrates.
  • the roughness of a substrate may be expressed as an arithmetic average (AA) roughness, measured as hereinafter described.
  • AA arithmetic average
  • Substrates having an arithmetic average roughness greater than 0.2 microns have provided good results in accordance with the present invention.
  • Substrates having an arithmetic average roughness greater than 0.5 microns are satisfac­tory.
  • the present invention provides for the effective use of substrates having a much rougher surface than was previously thought to be possible.
  • FIG. 4 illustrates the measured roughness for conventional polyester sheet used as a substrate for a typical conventional metallized polyester susceptor.
  • the polyester sheet was a commercially available polyester sheet sold under the trade name "DuPont-D" by E. I. duPont de Nemours & Company.
  • Conventional metallized polyester susceptors have been made using polyester substrates which are typically as smooth as the example illustrated in FIG. 4.
  • FIG. 5 illustrates the roughness measured for the smooth (or shiny) side of 16 point clay coated SBS paperboard, with a clay wash on the dull side, sold by the Waldorf Corporation of St. Paul, Minnesota. This is a very smooth shiny-appearing paper­board material.
  • FIG. 6 illustrates the surface roughness measured for copier paper.
  • the copier paper used was Compat DP sub 20, 8-1/2 inch by 11 inch (216 mm by 280 mm), white paper made by Nationwide Papers.
  • FIG. 7 illus­trates the surface roughness measured for commercially available bond paper.
  • the bond paper used was Eagle A typing paper, catalog number F420C, Trojan Bond radiant white cockle, 8-1/2 inch by 11 inch (216 mm by 280 mm), 75 g/m2 basis weight paper, made by Fox River Paper Company of Appleton, Wisconsin.
  • an arithmetic average roughness was computed for the Dupont-D polyester film in this example.
  • An arithmetic average roughness of 0.021 microns was computed.
  • the example of clay coated paperboard shown in FIG. 5 provided an arithmetic average roughness of 1.069 microns.
  • the copier paper, see FIG. 6, provided an arithmetic average roughness of 2.074 microns.
  • the bond paper of FIG. 7 provided an arithmetic average roughness of 5.013 microns.
  • Table II illustrates the arithmetic average roughness computed for several different examples of substrates.
  • SUBSTRATE AA Movable AA
  • PAPER 6.497 BOND PAPER 5.013 19 PT.
  • MILK CARTON STOCK (DULL SIDE) 4.823 24 PT.
  • CLAY COATED SBS (DULL SIDE) 3.522 19 PT.
  • MILK CARTON STOCK (SHINY SIDE) 2.831 ARTIST PAPER 2.305 COPIER PAPER 2.074 16 PT.
  • CLAY COATED SBS (DULL SIDE) 1.857 POLYESTER SIDE OF OVENABLE PAPERBOARD 1.333 16 PT.
  • substrates having arithmetic average (AA) roughness measurements greater than 0.5 microns may be sucessfully used in accordance with the present invention.
  • The, susceptor 10 in accordance with the present invention provides a dimensionally stable substrate 11 which maintains its structural integrity during microwave heating.
  • the degree of breakup of the metal film 12 depends on the characteristics of the paper substrate.
  • FIG. 8 illustrates the effects of a phenomenon, which is sometimes referred to as "breakup", for a conventional metallized polyester type susceptor.
  • a typical conven­tional metallized polyester susceptor may be formed from a thin (48 gauge) sheet of biaxially oriented polyester which has a thin film of metal such as aluminum deposited thereon. This metallized polyester sheet is then adhesively bonded to a support sheet of paper or paper­ board.
  • the metallized polyester type susceptor is heated in a microwave oven, the polyester tends to become soft and break up.
  • the reflectance, absorption, and transmission of such a susceptor, as measured with a network analyzer changes dramatically after microwave heating. This is illustrated in the tricoordinate graph of FIG.
  • FIG. 8 which illustrates data for a conventional metallized polyester type susceptor.
  • Biaxially oriented polyester on paperboard which had been metallized with aluminum, was used for the experiment of FIG. 8.
  • the data point on the left represents measurements taken prior to microwave heating.
  • the data point on the right represents data points taken after microwave heating. Arrows are drawn between the "before heating” data points and the "after heating” data points, to show the change which occurred.
  • FIG. 9 illustrates impedance measurements taken for a conventional metallized polyester type susceptor. Measurements were taken in one second intervals. During each one second interval, the complex impedance of the susceptor was measured, and a point representing the imaginary or reactive component of the impedance was plotted as "Xs", and a point corresponding to the real or resistive component of the impedance was plotted as "Rs".
  • FIG. 9 shows that after a certain period of time, when the susceptor exceeded 180° C, the impedance of the susceptor began to change significantly. The reactive component "Xs" began to increase dramatically.
  • the resistive component "Rs" also increased, reached a maximum of about 190 ohms/square, and then began to decrease to a value less than 160 ohms/square. These changes in a conven­tional susceptor typically result in a reduced responsive­ness to the heating effects of microwave radiation.
  • the measurement technique used to produce the data plotted in FIG. 9 is hereafter described in more detail; however, it should be noted that the susceptor temperature effect plotted on the horizontal axis was achieved as a result of heating due to microwave radiation.
  • a susceptor which is more electrically stable during heating.
  • stability refers to the ability of the susceptor to maintain its electrical characteristics, i.e., complex impedance, reflection, absorption and trans­mission, during microwave heating.
  • the present invention may be utilized to produce a susceptor which does not deteriorate as extensively during microwave heating as a conventional susceptor.
  • FIG. 10 an example of aluminum deposited directly on paper was measured. The measurements of absorption, reflection and transmission, measured prior to microwave heating, are shown on the left. The data point measured after micro­wave heating is shown slightly to the right. Comparison of the "before heating" data point with the "after heating” data point shows that the measurements barely changed.
  • the susceptor was much more stable. This is an example of what can be done with a susceptor constructed in accordance with the present invention, if stability is desired. In applications where stability of susceptor performance is a desirable design consideration, this example, see FIG. 10, would perform significantly better than the prior art metallized polyester type susceptor, see FIG. 8.
  • FIG. 11 illustrates data measurements taken with the susceptor used for the data shown in FIG. 10.
  • the impedance and temperature were measured for one second intervals during microwave heating.
  • a data point was plotted corresponding to the resistive component "Rs" of the impedance
  • a data point was plotted corresponding to the reactive component "Xs" of the impedance.
  • the impedance of the susceptor constructed in accordance with the present invention was relatively stable, as shown in FIG. 11. Of particular note is the low value of the reactive component "Xs", which remained low during heating.
  • the susceptor did not continue heating beyond 230°C. Because the susceptor in this example had a relatively low impedance, the susceptor did not continue to increase in temperature because a steady state condition was achieved where the rate of power absorbed by the susceptor was equal to the rate of power dissipated to the environment. Because the susceptor is so stable, if more power had been applied, or if the susceptor had a higher resistive component "Rs" for the impedance, the temperature would have continued to increase until a new steady state condition was reached. It is possible, in accordance with the present invention, to make a susceptor which is stable, and which continues to absorb microwave radiation at a constant rate during exposure to microwave radiation. Higher temperatures can be reached than those previously reached by typical conventional susceptors.
  • FIG. 12 is a tricoordinate graph illustrating measurements of reflection, absorption and transmission of another stable susceptor constructed in accordance with the present invention.
  • the data point on the left repre­sents measurements taken prior to microwave heating.
  • the data point on the right represents measurements taken after microwave heating. Comparing the "before heating" data point and the "after heating” data point, the changes which occurred as a result of microwave heating are not significant.
  • the susceptor was constructed from a thin film of stainless steel deposited on 16 point clay coated, natural kraft paperboard, sold by Mead Paperboard Products, a division of Mead Corporation, under the catalog designation Carton Kote H-12; (the paperboard was obtained from a Livingston, Alabama facility). The thickness of the stainless steel coating was 1895 Angstroms.
  • FIG. 13 represents measurements of impedance and temperature taken at half second intervals during micro­wave heating of the susceptor used to plot the data points shown in FIG. 12. During each half second interval, the impedance was measured, and a data point representing the reactive component "Xs" was plotted, and a data point representing the resistive component "Rs" was plotted. It can be seen from FIG. 13 that the impedance of the suscep­tor remained relatively stable during microwave heating. Also apparent, is the fact that the susceptor is capable of continuing to heat beyond the maximum temperature which can be attained using a conventional metallized polyester type susceptor. The susceptor temperature exceeded 260° C before power was shut down. In some applications, this heating performance may be a desirable characteristic.
  • FIG. 14 is a graph illustrating measurements of absorption, reflection and transmission (versus tempera­ture) for an example of a susceptor constructed in accord­ance with the present invention which heated rapidly when exposed to microwave radiation.
  • This example also had stable electrical characteristics. Each data point repre­sents a measurement taken at one second intervals. This susceptor reached 260° C in only 4 seconds. The suscep­tor's electrical characteristics also remained stable.
  • the thin film stainless steel coating was measured as having a thickness of 2005 Angstroms. Measurement of the impedance of the susceptor resulted in a measurement of about 730 ohms/square resistive component, and about -120 ohms/square reactive component.
  • a susceptor constructed in accordance with this example may be useful in connection with an embodiment of the invention employing a susceptor having disruptions in the continuity of the metallized film.
  • the susceptor heats very quickly and remains electrically stable. This is discussed more fully below.
  • the power absorbed and thus the heating achieved may, in some cases, exceed that required by the product.
  • the susceptor surface may be modified as taught in application Serial No. 197,634 (incorporated herein by reference) and illustrated in FIG. 15, in order to achieve the desired heating result.
  • Cuts or other disruptions 18 to the continuity of the thin metal film 19 are introduced in the surface of the susceptor 20. This "detunes" the susceptor 20.
  • the impedance can be set to a desired level prior to heating by introducing disruptions 18 to the continuity of the metal film 19. Due to the stability introduced by the present invention, the susceptor 20 will tend to maintain its electrical characteristics and impedance during heating.
  • the overall impedance has been increased, and therefore heating decreased, by intro­ducing electrical discontinuity 18 in the thin film surface 19.
  • the perimeter 21 has been "detuned" more than the center 22 to control edge overheating.
  • FIG. 3 illustrated an alternative embodiment of a susceptor 14.
  • a first thin film of metal 15 and a second thin film of metal 16 are provided on two sides of a paper substrate 17.
  • opposite sides of the paper substrate 17 are both coated with a thin film of metal 15 and 16.
  • the thickness of the metal films 15 and 16 are greatly exaggerated for purposes of illustration in FIG. 3. Coating two sides of the paper substrate 17 provides increased power absorption and resultant heating without arcing. This enhances performance for heating foods.
  • Coating two sides of a paper substrate 17 provides the ability to achieve a lower net effective impedance for the susceptor 14 without arcing. Such a structure is more stable, both physically and electrically.
  • a sheet of clay coated solid bleached sulfate paperboard from Waldorf Corporation, 16 point paper was coated on both sides with a thin metal film of aluminum.
  • the thickness of the thin metal film on each side was 200 Angstroms.
  • an identical sheet of paper was coated on the same side with a thin film of aluminum that was 400 Angstroms thick.
  • the impedance of both susceptors was measured.
  • the first two-sided susceptor when measured with a network analyzer, yielded an impedance measured as 16.5 - j 1.8 ohms/square.
  • the susceptor example which was coated on one side only yielded an impedance measurement of 23.5 - j 1.4 ohms/square.
  • Both susceptors were placed into a microwave oven and exposed to microwave radiation for 4 seconds. No arcing was observed on the two-sided susceptor.
  • the susceptor which was coated on one side exhibited severe arcing during the sample period of time.
  • the impedances of the two susceptors were again measured.
  • the two-sided susceptor yielded an impedance measurement of 24.2 - j 7.4 ohms/square.
  • the susceptor coated on one side only yielded an impedance measurement of 39.1 - j 103.6 ohms/square.
  • the two-sided susceptor appeared to be electrically stable.
  • the impedance did not change significantly as a result of exposure to microwave radiation.
  • the susceptor coated on one side only exhibited a significant change in impedance after exposure to microwave radiation.
  • the reflection (“R”), transmission (“T”) and absorption (“A”) for each susceptor was measured using a network analyzer, both before exposure to microwave radiation and after exposure.
  • Two-sided susceptors provide the ability to operate at low impedances which were not possible previously.
  • two-sided susceptors provide very stable performance where exposed to microwave radiation.
  • the non-metallized side of the susceptor in contact with the food product.
  • 1005 Angstroms of stainless steel was deposited on artist paper. Initially, the surface impedance was 317 - j 7 ohms/square.
  • This susceptor was placed metal-side-down under a Totino's Microwave Pizza, replacing the conventional in-package susceptor. The pizza was microwaved for 2 minutes on high. In this case, the susceptor was effective to dramatically heat the pizza crust.
  • the present invention addresses this problem effectively.
  • the present invention provides the ability to adjust the performance characteristics of a susceptor within a wide range.
  • the thickness of the metal coating, the composition of the metal, the roughness of the paper substrates, coatings applied to the substrate, etc. provide a wide range of possible susceptor characteristics which may be used to adjust the susceptor to match the food product. More significantly, the stability achieved by the present invention renders such efforts worthwhile, because the susceptor performance characteristics can be made to remain relatively stable and thereby remain in matching relationship to the food product. It has been observed experimentally that clay coated paper substrates generally tend to be more stable when used to heat many food products, than paper substrates which are not clay coated. It has also been observed that stainless steel susceptors are often more stable than aluminum susceptors.
  • the graph of FIG. 20 reflects tests using different types of paper substrates. The graph does not reveal the actual path the performance change followed nor the length of time the susceptor remained at any given performance condition (i.e., place on the graph) during microwave heating. Thus, two different susceptors which had identical starting points and identical ending points could give different cooking results if one susceptor very quickly moved to its end point during microwave heating, while the other remained at its starting point, and did not move to its end point until late during the heating cycle. Coatings for the paper, such as clay coatings, may reduce the amount of moisture absorbed by the susceptor and thereby improved stability during microwave heating.
  • the metal is believed to deposit in discrete regions, areas or "globs" which grow and coalesce as more metal is deposited.
  • the film begins as discrete, electrically unconnected regions and becomes electrically more connected as the metal thickness increases.
  • Coating a rough surface to a predetermined desired surface resistance requires the deposition of more metal than would be required to achieve the same resistance on a smooth substrate.
  • rough substrates have more actual surface area per square centimeter of material
  • the coating uniformity at the micron and sub-micron level may be less uniform due to local shadowing (e.g., by a protruding paper fiber), and a surface roughness makes achieving any particular degree of film electrical connectedness more difficult.
  • the first metal to arrive at the substrate may be subject to chemical reaction with compounds absorbed on the surface.
  • These equations may be used to estimate the thickness "t" of aluminum required to achieve a desired predeter­mined surface resistance "Rs" for a substrate with a roughness of AA microns.
  • the roughness AA is measured.
  • the conductivity for the specific metal is corrected for mean free path effects to determine sf.
  • the roughness AA is plugged into the above equations to calculate C and to. Then t may be calculated using the equation described above.
  • This procedure can reduce the time required to empirically determine the optimum metal thickness for a given substrate material.
  • the crucibles were charged with alumi­num or stainless steel 316.
  • the samples to be coated were attached onto the rotating racks.
  • the chamber was pumped down to, typically, 10 ⁇ 5 to 10 ⁇ 6 torr.
  • the deposition then proceeded, using a crystal monitor to measure the coating thickness progress.
  • Susceptor surface impedance, surface resistance, absorption (or absorbance), reflection (or reflectance), and transmission (or transmittance) measurements were made at the microwave oven operating frequency of 2.45 GHz and at room temperature (20-25° C) unless otherwise specified.
  • References to absorption or absorbance mean power absorp­tion.
  • References to reflection or reflectance mean power reflection.
  • References to transmission or transmittance mean power transmission. A network analyzer is used to make such measurements.
  • a Hewlett Packard Model 8753A network analyzer in combination with a Hewlett Packard 85046A S-parameter test set is connected to either WR-340 or WR-284 waveguide and calibrated according to procedures published by Hewlett Packard. Measurements are made without the presence of a food item, unless otherwise specified.
  • Measurements are preferably made by placing a sample to be measured between two adjoining pieces of waveguide.
  • Conductive silver paint may be placed around the outer edges of the sample sheet which is cut slightly larger than the cross-sectional opening of the waveguide.
  • Colloidal silver paint made by Ted Pella, Inc. has given satisfactory results in practice.
  • the sample is preferivelyably cut so that it overlaps the waveguide perimeter by about 0.127 cm around the edge.
  • Scattering parameters S11 and S21 are measured directly by the network analyzer, and are used to calcu­late power absorption (or absorbance), reflection (or reflectance), transmission (or transmittance), and surface impedance. From port 1 of the network analyzer, the power S11 squared and the power transmission is the magnitude of S21 squared. The power absorption in the waveguide is then equal to one minus the sum of the power reflection in the guide and the power transmission in the guide. The susceptor absorption, transmission, and reflection values reported herein are corrected to free-space values using the impedance of free space, the impedance of the waveguide in which the measurements are made, and the equations presented by J. Altman, Microwave Circuits , pp. 370-371 (1964).
  • the complex surface impedance of the susceptor is calculated using equations presented in R.L. Ramey and T. S. Lewis, "Properties of Thin Metal Films at Microwave Frequencies", Journal of Applied Physics , Vol. 39, No. 1, pp. 3383-3384 (1968), substitut­ing Zs, the complex surface impedance for 1/ ⁇ d, where ⁇ is the conductivity of the metal film and d is its thick­ness.
  • ⁇ is the conductivity of the metal film and d is its thick­ness.
  • Substrate surface roughness is measured using the stylus method more fully described in the Handbook of Thin Film Technology, pages 6-33 to 6-39 (ed. L.I. Maissel & R. Glang 1970) [1983 Reissue], which is incorporated herein by reference.
  • the deflection of a Dektak Model II profilometer with a stylus tip diameter of 12.5 microns was recorded as the stylus was drawn across a substrate surface. Individual scan lengths of about 30 millimeters were used, several of which were concatenated together. Digital data was provided by the Dektak and output in a computer.
  • the film should be taped to an optically polished flat surface and gently stretched to flatten the film against the flat support. This is done to avoid erroneously high roughness readings generated by buckling of the film as the stylus is drawn across the film.
  • the flat support and the film should be rigorously free of dust before measurement with the profilometer. Where the film is transparent, proper stretching can be verified since stretching will result in the appearance of a few interference fringes generated by the air gap between the film and support.
  • the raw data produces a plot which includes rough­ness, waviness and flatness.
  • Surface profile plots for several substrates are shown in FIGS. 16 to 19. It is desirable to eliminate the waviness and flatness informa­tion.
  • the waviness and flatness information contained in the plots of FIGS. 16-19 was eliminated to produce the corresponding plots of FIGS. 4-7, respectively. This was conveniently done using computer software such as that used for processing electrical signals to simulate the effect of a filter.
  • a low pass filter having a cutoff frequency of 0.03 was simulated using Asyst 2.01 software, commercially available from Macmillian Software Company.
  • the output of the low pass filter was then subtracted from the raw data plotted in FIGS. 16-19, thereby leaving only the roughness informa­tion shown in FIGS. 4-7.
  • the effect of this was to exclude waviness components having a period on the hori­zontal axis greater than 1.5 millimeters. In other words, only the high frequency components (i.e., the roughness data) were left after this processing.
  • AA roughness can be calculated as described in the Handbook of Thin Film Technology.
  • the data, now having only the roughness information, is analyzed using Asyst 2.01 software, by placing an array containing the roughness information on the computer's stack. A statistical mean is calculated. The mean is subtracted from a duplicate of the original data to produce a set of data with a zero offset. In analogy to electrical signal processing, this step was equivalent to eliminating any remaining direct current components.
  • AA roughness value was calculated by taking the absolute value of the resulting array of data points, and subsequently computing the average. Using Asyst 2.01 software, this was done using the Asyst commands "ABS" and "MEAN".
  • Import data from a Lotus file starting in cell B4, and extending down N cells. Then apply a filter whose frequency is set by SET.CUTOFF.FREQ. Subtract the filtered data from the raw data to leave the (desired) high frequency data on the stack. Plot it and send it to Lotus. Calculate the AA, the roughness average, and send it to Lotus.
  • the test apparatus shown in FIG. 21 measures the surface impedance and operating temperature of a susceptor 30 under high power microwave radiation conditions similar to those in a microwave oven.
  • the source of microwave radiation 32 comprises a conventional half wave voltage doubler microwave oven power supply 31 with the addition of a variac in the anode high voltage supply circuit 31.
  • the attenuated output of the source 32 is applied to the susceptor 30 via the wave­guide system 33 shown in FIG. 21.
  • the apparatus can apply an incident power of up to 125 watts to the susceptor sample 30.
  • the rate of susceptor temperature rise is determined by the incident power which can be adjusted to allow accurate tracking of the surface temperature by a thermometric device 34.
  • the susceptor sample 30 is cut to be larger than the inside dimensions of the waveguide 33 and then mounted on the waveguide flange 35.
  • a conventional thermocouple 34 is attached to the center of the susceptor 30 by silicone grease as shown in FIG. 22.
  • the thermocouple wire 34 is routed so as to be perpendicular to the electric field in the waveguide 33 to avoid atypical local overheating near the tip 34.
  • a Luxtron thermometric device with remote sensing phosphor painted to the susceptor surface has also been used with similar results.
  • the susceptor sample 30 with attached thermocouple 34 is then clamped between the flange 35 and a corresponding flange on a one quarter wavelength long shorted waveguide 33.
  • the guide 33 is thus terminated in the impedance of the susceptor at the location of the susceptor 30.
  • a dual directional coupler 36 in conjunction with a network analyzer 37 measures the real 40 and imaginary 41 parts (denoted as R and I in the drawing) of the reflection coefficient seen at the refer­ence plane 38 defined by the waveguide flange 35 where the susceptor 30 is mounted.
  • the impedance at the reference plane 38 is easily computed from the complex reflection coefficient. This impedance is the surface impedance of the susceptor 30. From the surface impedance, the power absorbed in, reflected from, and transmitted through the susceptor 30 may be computed for a wide variety of other circumstances.
  • a blanking pulse 39 from the network analyzer 37 is used to suppress collection of invalid data occurring when the network analyzer 37 is not in phase lock with the pulsed microwave output of the magnetron 32.
  • the present invention provides a susceptor which has dimensional stability and structural integrity during microwave heating without requiring additional laminated layers.
  • the degree of breakup of the thin metal film can be adjusted.
  • the susceptor is more responsive to the heating effects of microwave radiation, and is responsive for a longer period of time during microwave heating, than is the case with a conventional susceptor formed from a metallized layer of polyester which may be adhesively bonded to the a supporting layer.
  • the present invention further provides the advantage of simplicity and economy of manufacture.
  • the paper substrate which is used for the susceptor may form an integral part of the package material.
  • the thin film of metal may be applied to paperboard which forms part of a carton or tray.
  • the inherent structural integrity and dimensional stability of the susceptor constructed in accordance with the present invention eliminates the need for additional manufacturing processes to provide additional dimensional support for the susceptor. Lamination to a structural reinforcing member is not required.
  • the present invention provides the ability to with­stand higher temperatures without adverse consequences such as melting.
  • Paper substrates can withstand substan­tially more heat than commonly used polyester films.
  • a paper substrate is not subject to shrinking during heating as is the case with conventional biaxially oriented polyester sheets.
  • the present invention further provides the advantage of coating both sides of a paper substrate to improve microwave heating performance. Higher heating rates may be obtained without incurring problems of arcing. In some cases, a higher reflection percentage can be maintained throughout the heating cycle. The achievement of higher reflection and absorption without arcing is a significant advantage.
  • the present invention utilizes a thin film of metal which is deposited directly on a paper substrate, the use of adhesives to laminate layers together to form a substrate may be avoided. It is not necessary to have adhesives in direct contact with the thin metal film.
EP89109225A 1988-05-23 1989-05-23 Suscepteurs ayant une couche métallisée déposée sur du papier pour le chauffage des aliments dans un four à micro-ondes Withdrawn EP0344574A1 (fr)

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US19763488A 1988-05-23 1988-05-23
US07/267,545 US4970360A (en) 1988-11-04 1988-11-04 Susceptor for heating foods in a microwave oven having metallized layer deposited on paper
US267545 1988-11-04
US197634 1998-11-23

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0371739A2 (fr) * 1988-11-28 1990-06-06 Beckett Industries Inc. Article de chauffage et son procédé de chauffage
US5220140A (en) * 1991-06-17 1993-06-15 Alcan International Limited Susceptors for browning or crisping food in microwave ovens
WO2014005915A1 (fr) 2012-07-02 2014-01-09 Nestec S.A. Matériau interactif à micro-ondes à haute température

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FR2166554A5 (en) * 1971-12-29 1973-08-17 Funai Electric Co High frequency cooking process - gives scorch-grilled outer layer, using carbon wrapping
US4230924A (en) * 1978-10-12 1980-10-28 General Mills, Inc. Method and material for prepackaging food to achieve microwave browning
EP0063108A2 (fr) * 1981-04-10 1982-10-20 AB Akerlund & Rausing Matériau d'emballage
EP0161739A2 (fr) * 1984-02-15 1985-11-21 Alcan International Limited Emballage pour le chauffage à micro-ondes
EP0205304A2 (fr) * 1985-06-06 1986-12-17 Donald Edward Beckett Emballage utilisable dans des Fours à microondes
EP0244179A2 (fr) * 1986-04-28 1987-11-04 Toyo Seikan Kaisha Limited Récipient en papier résistant à la chaleur et son procédé de fabrication
WO1988005249A1 (fr) * 1986-12-24 1988-07-14 Mardon Son & Hall Limited Chauffage aux micro-ondes

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2166554A5 (en) * 1971-12-29 1973-08-17 Funai Electric Co High frequency cooking process - gives scorch-grilled outer layer, using carbon wrapping
US4230924A (en) * 1978-10-12 1980-10-28 General Mills, Inc. Method and material for prepackaging food to achieve microwave browning
EP0063108A2 (fr) * 1981-04-10 1982-10-20 AB Akerlund & Rausing Matériau d'emballage
EP0161739A2 (fr) * 1984-02-15 1985-11-21 Alcan International Limited Emballage pour le chauffage à micro-ondes
EP0205304A2 (fr) * 1985-06-06 1986-12-17 Donald Edward Beckett Emballage utilisable dans des Fours à microondes
EP0244179A2 (fr) * 1986-04-28 1987-11-04 Toyo Seikan Kaisha Limited Récipient en papier résistant à la chaleur et son procédé de fabrication
WO1988005249A1 (fr) * 1986-12-24 1988-07-14 Mardon Son & Hall Limited Chauffage aux micro-ondes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0371739A2 (fr) * 1988-11-28 1990-06-06 Beckett Industries Inc. Article de chauffage et son procédé de chauffage
EP0371739A3 (fr) * 1988-11-28 1991-12-27 Beckett Industries Inc. Article de chauffage et son procédé de chauffage
US5220140A (en) * 1991-06-17 1993-06-15 Alcan International Limited Susceptors for browning or crisping food in microwave ovens
WO2014005915A1 (fr) 2012-07-02 2014-01-09 Nestec S.A. Matériau interactif à micro-ondes à haute température

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