EP0341116A2 - Übertragungsblatt zur Endbearbeitung von Leder - Google Patents
Übertragungsblatt zur Endbearbeitung von Leder Download PDFInfo
- Publication number
- EP0341116A2 EP0341116A2 EP89401109A EP89401109A EP0341116A2 EP 0341116 A2 EP0341116 A2 EP 0341116A2 EP 89401109 A EP89401109 A EP 89401109A EP 89401109 A EP89401109 A EP 89401109A EP 0341116 A2 EP0341116 A2 EP 0341116A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- transfer sheet
- finishing
- support
- leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000010985 leather Substances 0.000 title claims abstract description 23
- 238000007730 finishing process Methods 0.000 title description 2
- 239000010410 layer Substances 0.000 claims abstract description 46
- 239000004814 polyurethane Substances 0.000 claims abstract description 18
- 229920002635 polyurethane Polymers 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000006185 dispersion Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 5
- 239000012790 adhesive layer Substances 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims abstract description 4
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 3
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 3
- 125000003118 aryl group Chemical group 0.000 claims abstract description 3
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 3
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- GWESVXSMPKAFAS-UHFFFAOYSA-N Isopropylcyclohexane Natural products CC(C)C1CCCCC1 GWESVXSMPKAFAS-UHFFFAOYSA-N 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000011877 solvent mixture Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 206010039509 Scab Diseases 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000218158 Clematis Species 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
- B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/12—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to leather
Definitions
- the present invention relates to a transfer sheet for a leather finishing process.
- a transfer sheet according to the invention for finishing leather in the form of skin or in the form of a ready-to-use piece for making shoes, leather goods or the like, comprising a support provided with layers superimposed of priming and / or finishing products, as well as a separate adhesive layer or incorporated into one of the priming and / or finishing products suitable for being reactivated when hot and having dielectric losses is characterized in that the material of the layer in contact with the support and intended to form the surface finishing is chosen from products of the plasticized nitrocellulose or single-component polyurethane type dissolved in solvents suitable for its attachment to said support, in that said first layer is coated with a second layer ensuring the solidity of the finish and the color, the material of which is chosen from aqueous dispersions of aliphatic polyurethane and acrylic colopymers es or one-component polyurethanes of aromatic type in organic solution and in that in said second layer is incorporated a thermoplastic adhesive of the polyurethane / vinyl acetate copolymer
- the first layer, in contact with the silicone paper, and which is intended to provide the finishing of the skin or the piece of leather can be tinted or transparent.
- the dyes used are those used in the leather industry, for example little organic and mineral pigments, in a modified nitrocellulosic binder.
- Such an arrangement is particularly preferred when it is desired to give the skin or the piece of leather a coloration in two tones or two colors, for example for producing patterns giving the skin or the pieces of leather the appearance snake scales, or the like.
- the transfer sheet Given the nature of the constituents of the transfer sheet, it can be easily manufactured on an automatic machine by a continuous process according to which said constituents are arranged in successive layers on the base support.
- the manufacturing process as defined above provides a constant, uniform film thickness, allowing the leather to retain its natural suppleness and also providing a significant saving in finishing and / or finishing products.
- the transfer sheet thus produced is first pre-bonded to the leather by a thermal application process carried out either using a heating press or a rotary press. continuous tightening and this to easily separate the silicone paper from the finishing layer, this pre-bonding being carried out either on whole skins, or on pre-cut pieces according to the leather pieces that one wishes to use for the manufacture of shoes, leather goods, or the like.
- the skin or piece of leather is then subjected to a final operation in a high-frequency machine, as described in the aforementioned French patent for obtaining a particular grain on said skin or pieces or part of a piece.
- a transfer sheet according to the invention is prepared from a support constituted by a silicone paper of the type of that sold under the name PU 2000 by the company ARJOMARI.
- a second layer is added to it to ensure the solidity of the finish and, if necessary, the color of the leather.
- This second base layer is added by spraying with a thickness of 0.01 mm.
- Said second layer is then coated with a third layer of adhesive, suitable for being reactivated at around 100 ° C. and intended to ensure the adhesion of the entire film formed by the three layers on the crust or leather grain. which we want to finish.
- a silicone paper of the type of those sold by the company ARJOMARI under the name PU 2000 is first coated with a first layer as described in Example 1 which, after drying, is provided with a second layer in which a thermoplastic adhesive is incorporated in the form of a polyurethane / vinyl acetate co-polymer.
- a transfer sheet according to Example 1 For the finishing of a piece or skin of chrome tanned leather, using a transfer sheet according to Example 1, said transfer sheet is pre-glued in a thermal press and then, after introduction of the assembly into a silicone or resin mold suitable for high-frequency treatment, the graining is carried out in an HF machine, with an appropriate generator.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Decoration By Transfer Pictures (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8805901 | 1988-05-03 | ||
| FR8805901A FR2631041A1 (fr) | 1988-05-03 | 1988-05-03 | Feuille-transfert pour procede de finissage de cuir |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0341116A2 true EP0341116A2 (de) | 1989-11-08 |
| EP0341116A3 EP0341116A3 (de) | 1991-03-20 |
Family
ID=9365924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19890401109 Withdrawn EP0341116A3 (de) | 1988-05-03 | 1989-04-20 | Übertragungsblatt zur Endbearbeitung von Leder |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0341116A3 (de) |
| BR (1) | BR8902062A (de) |
| FR (1) | FR2631041A1 (de) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1463072A (en) * | 1973-03-14 | 1977-02-02 | Shoe & Allied Trades Res Ass | Transfer dyeing |
| FR2277130A1 (fr) * | 1974-07-05 | 1976-01-30 | Ugine Kuhlmann | Procede de revetement de substrats souples par projection d'elastomeres de polyurethane-polyuree et produit obtenus |
| DE2629704C3 (de) * | 1976-07-02 | 1979-07-12 | Bayer Ag, 5090 Leverkusen | Verfahren zur Beschichtung von Leder oder Spaltleder |
| DD206761A1 (de) * | 1981-12-03 | 1984-02-08 | Guenter Reich | Verfahren zur beschichtung flaechenhafter materialien |
-
1988
- 1988-05-03 FR FR8805901A patent/FR2631041A1/fr not_active Withdrawn
-
1989
- 1989-04-20 EP EP19890401109 patent/EP0341116A3/de not_active Withdrawn
- 1989-05-02 BR BR898902062A patent/BR8902062A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2631041A1 (fr) | 1989-11-10 |
| EP0341116A3 (de) | 1991-03-20 |
| BR8902062A (pt) | 1989-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): BE DE ES GB IT LU NL |
|
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
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| AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): BE DE ES GB IT LU NL |
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| 17P | Request for examination filed |
Effective date: 19910722 |
|
| 17Q | First examination report despatched |
Effective date: 19921208 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19930803 |