EP0340784B1 - A device for reducing atmospheric pollution by exhaust gases from internal combustion engines - Google Patents

A device for reducing atmospheric pollution by exhaust gases from internal combustion engines Download PDF

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Publication number
EP0340784B1
EP0340784B1 EP89108116A EP89108116A EP0340784B1 EP 0340784 B1 EP0340784 B1 EP 0340784B1 EP 89108116 A EP89108116 A EP 89108116A EP 89108116 A EP89108116 A EP 89108116A EP 0340784 B1 EP0340784 B1 EP 0340784B1
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EP
European Patent Office
Prior art keywords
inlet
outlet
cartridge
mineral fibres
exhaust gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89108116A
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German (de)
French (fr)
Other versions
EP0340784A1 (en
Inventor
Roberto Evangelisti
Pier Luigi Tenci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ATEC Srl
ENTE PER LE NUOVE TECNOLOGIE L'ENERGIA E L'AMBIEN
Original Assignee
ATEC Srl
Agenzia Nazionale per le Nuove Tecnologie lEnergia e lo Sviluppo Economico Sostenibile ENEA
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Priority to AT89108116T priority Critical patent/ATE79442T1/en
Publication of EP0340784A1 publication Critical patent/EP0340784A1/en
Application granted granted Critical
Publication of EP0340784B1 publication Critical patent/EP0340784B1/en
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/0217—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters the filtering elements having the form of hollow cylindrical bodies
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0226—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being fibrous
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2835—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support fibrous
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • F01N3/2892—Exhaust flow directors or the like, e.g. upstream of catalytic device
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00—Structure of catalyst support or particle filter
    • F01N2330/10—Fibrous material, e.g. mineral or metallic wool
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00—Structure of catalyst support or particle filter
    • F01N2330/12—Metallic wire mesh fabric or knitting
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2410/00—By-passing, at least partially, exhaust from inlet to outlet of apparatus, to atmosphere or to other device
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2410/00—By-passing, at least partially, exhaust from inlet to outlet of apparatus, to atmosphere or to other device
    • F01N2410/08—By-passing, at least partially, exhaust from inlet to outlet of apparatus, to atmosphere or to other device in case of clogging, e.g. of particle filter
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2470/00—Structure or shape of gas passages, pipes or tubes
    • F01N2470/08—Gas passages being formed between the walls of an outer shell and an inner chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2470/00—Structure or shape of gas passages, pipes or tubes
    • F01N2470/18—Structure or shape of gas passages, pipes or tubes the axis of inlet or outlet tubes being other than the longitudinal axis of apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction

Definitions

  • the present invention relates to a device for reducing atmospheric pollution by exhaust gases of internal combustion engines. More particularly, the present invention relates to a device for reducing atmospheric pollution by the exhaust gas as from diesel cycle engines both those installed on vehicles and those installed in static installations (for example generating plants).
  • a catalytic exhaust gas purifying device wherein a purifying body is formed of a plurality of layers of metallic fibres housed between a pair of stainless tubular screens secured to two end discs, in turn housed in a cylindrical casing.
  • the object of the present invention is that of providing a device reducing atmospheric pollution by exhaust gases from internal combustion engines of Diesel cycle, able to effect a purification such as drastically to reduce the toxicity of such exhaust gases whilst being of a restricted production cost in comparison with known devices of the above specified type.
  • a device for reducing atmospheric pollution by exhaust gases of internal combustion engines formed according to the principles of the present invention is generally indicated with the reference numeral 1.
  • the device 1 is of the type comprising a hollow casing 2 provided with an inlet 3 for the exhaust gases to be purified and an outlet 4 for the purified exhaust gases, and purifier means 5 interposed between the said inlet 3 and outlet 4.
  • the casing 2 has a cylindrical structure with tubular side walls 7, an upper wall 8 and a lower wall 9.
  • the upper wall 8 has an axial through-hole 11 and supports a conical diffuser 12 the purpose of which is to allow a progressive expansion of the exhaust gas to be purified coming from the inlet 3.
  • the lower wall 9 has an offset through-hole 13 in which is fixed a tubular connector 14.
  • the purifier means 5 are essentially constituted by mineral fibres 6 rendered active by means of a noble metal catalyst deposit thereon. Moreover, these are preferably constituted by quartz and/or silica fibres, whilst the noble metal catalyst is advantageously a platinum catalyst.
  • the device 1 includes support means 15 for the mineral fibres 6, essentially constituted by a stocking of woven filiform material contacting these fibres 6 in such a way as to define, between the inlet 3 and the outlet 4, alternate layers of filiform material 15 and mineral fibres 6.
  • the stocking 15 of woven filiform material is constituted by a plurality of free and elastically deformable meshes conveniently made by mechanical knitting of a stainless steel wire particularly adapted to resist high temperatures such as those of the exhaust gases of an internal combustion engine.
  • the mineral fibres 6 and the stocking 15 of woven filiform material are wound in a coil (as illustrated in Figure 4) in such a way as to define a tubular mattress 17 which is interposed between two tubular metal meshes, respectively an inner mesh 18 and an outer mesh 19.
  • these meshes 18, 19 are obtained as expanded metal meshes of stainless steel sheet of a type adapted to resist high temperature as specified above.
  • the mineral fibres 6, the stocking 15 and the rigid meshes 18, 19 together define a cartridge 20 which is installed in axial position within the casing 2 and is dimensioned in such a way that the diameter of the inner mesh 18 is substantially coincident with the diameter of the through-hole 11 in the upper wall 8 of the casing 2.
  • the upper portion of the cartridge 20 is positioned, in use, between inner and outer centring collars 21, 22 extending from the inner side of the upper wall 8 of the casing 2 through the through-hole 11 mentioned above.
  • the lower portion of the cartridge 20 is housed within an annular bowl 24 substantially constituted by a flat ring 25 and two collars 26, 27 extending perpendicularly from this latter and entirely identical to the collars 21, 22 described above.
  • the cartridge 20 is retained in the working position by means of a disc 30 resting on the lower surface of the annular bowl 24 and mechanically connected to a crosspiece 31 supported by the collar 21 by means of an axial tie rod 32 a threaded leg 33 of which retains the disc 30 by means of a nut 34.
  • the material constituting the tie rod 32 is of the same type as that constituting the rigid meshes 18, 19 of the cartridge 20, in such a way as to present a substantially identical thermal expansion to that of the meshes 18, 19 themselves.
  • the disc 30 is provided with a set of three radial tongues 35 angularly equidistant from one another and extending towards the inner surface of the lateral wall 7 of the casing 2 ( Figures 2 and 3).
  • the tongues 35 are bent with respect to the plane of the disc 30 in such a way as to form with this latter an angle of substantially 45° and present a circular outline such that these do not dig in to the wall 7 during longitudinal excursions of the cartridge 20 by the effect of the increase in the working temperature.
  • the device 1 For the purpose of distributing exhaust gases uniformly over the entire inner surfaces of the cartridge 20 the device 1 is provided with a pair of flow deflectors 37, 38 substantially constituted by tubular elements of conical profile of different diameters fixed coaxially to the crosspiece 31.
  • the disc 30 is provided with a through-hole 40 of suitable dimensions, which puts the inlet 3 in direct communication with the outlet 4 of the casing 2.
  • the device 1 operates in general in a manner similar to known devices of this type in the sense that the exhaust gases gain access to the interior of the casing 2 through the inlet 3 and subsequently flow to the outlet 4 after having traversed the cartridge 2 and having been purified by means of the purifier 5 contained in it.
  • the use of the stocking 15 of woven wire-like material certainly performs two important functions: a principle function consisting in supporting the mineral fibres 6 correctly for the purpose of maintaining them always distributed in a uniform manner within the interior of the cartridge 20 and therefore making the purifying effect homogeneous in time; a secondary, but equally important function, consisting in creating, between the inlet 3 and the outlet 4, an alternating set of layers of mineral fibres and wire material, this latter causing a certain separation between adjacent layers of mineral fibres and therefore a good distribution of the flow of gas between the mineral fibres themselves, and, ultimately, an optimum purifying effect.
  • the system for fixing the cartridge 20 to the casing 2 by means of the tie rod 32 (having a coefficient of thermal expansion similar to that of the rigid meshes 18, 19) allows, simultaneously, the fixing of the cartridge 20 to the casing 2 and the free expansion of the meshes 18, 19 without casuing rupture of these meshes by exceeding the yield points of the respective metal materials.
  • the presence of the hole 40 in the disc 30 has substantially no effect in normal operating conditions of the device 1, that is to say in the case in which the combustion residues are consumed by part of the purifier means 5 in such a way as to cause no accumulation of these between the fibres 6.
  • the momentary blockage of the cartridge 20 and the constant inflow of gases to the interior thereof cause an excess pressure which does not exceed a predetermined safety level since the discharge gas can momentarily flow out through the hole 40 allowing the purifier means 5 to digest the overload of combustion residues.
  • the combined action of the diffuser 12 and the flow deflectors 37, 38 permits possible damage due to the rapid expansion of the exhaust gas jet flowing into the interior of the cartridge 20 to be reduced to the minimum.
  • the high efficiency of the purifier means 5, conveniently supported by the stocking 15 of resiliently deformable woven metal wire permits a drastic reduction in the more noxious and repeated emissions, such as the particles, oxides of nitrogen oxides of carbon and unburnt hydrocarbons, containing the back pressure within more than acceptable limits.
  • the device 1 can be made at an overall cost which is significantly less than the cost of ceramic devices currently utilised and described above.
  • the device formed according to the present invention can be utilised advantageously to treat exhaust gases from internal combustion engine of the Diesel cycle installed on vehicles or in fixed installations (for example generators) as well as to treat the exhaust gases of heating boilers adapted for industrial and civil installations.
  • the support for the cartridge 20 could be achieved by means of several tie rods either positioned within or outside the cartridge itself, the concept of utilising a material with a coefficient of thermal expansion as close as possible to that of the rigid meshes 18, 19 remaining the same. It is also evident that other ways of support could be thought up, for example utilising resilient means able to maintain the cartridge in the correct working position whilst allowing termal expansion in longitudinal and transverse directions within the associated case.
  • the number of flow deflectors could be greater or less than two, and the associated structure could be different from the conical structure described above.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Inorganic Fibers (AREA)
  • Catalysts (AREA)
  • Processes For Solid Components From Exhaust (AREA)

Abstract

The device (1) comprises a hollow casing (2) provided with an inlet (3) for exhaust gases to be purified and an outlet (4) for the purified exhaust gases, and purifier means (5) interposed between the said inlet (3) and outlet (4) and substantially constituted by mineral fibres (6) activated by a noble metal catalyst deposited on them. The device (1) further includes support means (15) for the mineral fibres (6) essentially constituted by a woven filiform material engaged on the fibres (6) in such a way as to define, between the said inlet (3) and outlet (4), a substantial alternation of layers of filiform material (15) and mineral fibres (6).

Description

  • The present invention relates to a device for reducing atmospheric pollution by exhaust gases of internal combustion engines. More particularly, the present invention relates to a device for reducing atmospheric pollution by the exhaust gas as from diesel cycle engines both those installed on vehicles and those installed in static installations (for example generating plants).
  • As is known, internal combustion engine exhaust gases, particularly from diesel cycle engines utilising diesel oil as a fuel, contain numerous noxious substances such as, for example, unburnt hydrocarbons, particles, oxides of nitrogen and carbon etc.
  • There are many known systems and devices designed for reducing atmospheric pollution due to internal combustion engine exhaust gases. In general these are of the type comprising a hollow casing provided with an inlet for the exhaust gas to be purified and an outlet for the purified exhaust gas, and purifying means interposed between the said inlet and outlet.
  • By way of example it is known to use ceramic trap devices which retain the particles present in the exhaust gas and then burn them by means of suitable heating flames supplied by an appropriate burner. Such devices have not found wide application because of the excessively high cost.
  • It is also known from the US-A-4 175 107 a catalytic exhaust gas purifying device, wherein a purifying body is formed of a plurality of layers of metallic fibres housed between a pair of stainless tubular screens secured to two end discs, in turn housed in a cylindrical casing.
  • The object of the present invention is that of providing a device reducing atmospheric pollution by exhaust gases from internal combustion engines of Diesel cycle, able to effect a purification such as drastically to reduce the toxicity of such exhaust gases whilst being of a restricted production cost in comparison with known devices of the above specified type.
  • Said object is achieved by the pollution reducing device defined in the Claim 1.
  • For a better understanding of the present invention a preferred embodiment is described hereinafter purely by way of non-limitative example and with reference to the attached drawings, in which:
    • Figure 1 is a sectional side view of a device formed according to the present invention;
    • Figure 2 is a section, on an enlarged scale, taken on the line II-II of Figure 1;
    • Figure 3 is a view on an enlarged scale of a detail of Figure 1;
    • Figure 4 illustrates a detail of a production stage of a detail of the device in question; and
    • Figure 5 illustrates on an enlarged scale the structure of a detail of Figure 4.
  • With particular reference to Figure 1, a device for reducing atmospheric pollution by exhaust gases of internal combustion engines formed according to the principles of the present invention is generally indicated with the reference numeral 1.
  • The device 1 is of the type comprising a hollow casing 2 provided with an inlet 3 for the exhaust gases to be purified and an outlet 4 for the purified exhaust gases, and purifier means 5 interposed between the said inlet 3 and outlet 4.
  • In more detail, the casing 2 has a cylindrical structure with tubular side walls 7, an upper wall 8 and a lower wall 9. The upper wall 8 has an axial through-hole 11 and supports a conical diffuser 12 the purpose of which is to allow a progressive expansion of the exhaust gas to be purified coming from the inlet 3. The lower wall 9 has an offset through-hole 13 in which is fixed a tubular connector 14.
  • According to an aspect of the present invention the purifier means 5 are essentially constituted by mineral fibres 6 rendered active by means of a noble metal catalyst deposit thereon. Moreover, these are preferably constituted by quartz and/or silica fibres, whilst the noble metal catalyst is advantageously a platinum catalyst.
  • According to an essential aspect of the present invention the device 1 includes support means 15 for the mineral fibres 6, essentially constituted by a stocking of woven filiform material contacting these fibres 6 in such a way as to define, between the inlet 3 and the outlet 4, alternate layers of filiform material 15 and mineral fibres 6.
  • The stocking 15 of woven filiform material, a portion of which is illustrated in detail in Figure 5, is constituted by a plurality of free and elastically deformable meshes conveniently made by mechanical knitting of a stainless steel wire particularly adapted to resist high temperatures such as those of the exhaust gases of an internal combustion engine.
  • It is observed that the mineral fibres 6 and the stocking 15 of woven filiform material are wound in a coil (as illustrated in Figure 4) in such a way as to define a tubular mattress 17 which is interposed between two tubular metal meshes, respectively an inner mesh 18 and an outer mesh 19. Preferably, these meshes 18, 19 are obtained as expanded metal meshes of stainless steel sheet of a type adapted to resist high temperature as specified above.
  • The mineral fibres 6, the stocking 15 and the rigid meshes 18, 19 together define a cartridge 20 which is installed in axial position within the casing 2 and is dimensioned in such a way that the diameter of the inner mesh 18 is substantially coincident with the diameter of the through-hole 11 in the upper wall 8 of the casing 2.
  • The upper portion of the cartridge 20 is positioned, in use, between inner and outer centring collars 21, 22 extending from the inner side of the upper wall 8 of the casing 2 through the through-hole 11 mentioned above.
  • The lower portion of the cartridge 20 is housed within an annular bowl 24 substantially constituted by a flat ring 25 and two collars 26, 27 extending perpendicularly from this latter and entirely identical to the collars 21, 22 described above.
  • For the purpose of allowing, in use, an expansion of the cartridge within the casing 2 without creating mechanical stresses between these two components, the cartridge 20 is retained in the working position by means of a disc 30 resting on the lower surface of the annular bowl 24 and mechanically connected to a crosspiece 31 supported by the collar 21 by means of an axial tie rod 32 a threaded leg 33 of which retains the disc 30 by means of a nut 34. The material constituting the tie rod 32 is of the same type as that constituting the rigid meshes 18, 19 of the cartridge 20, in such a way as to present a substantially identical thermal expansion to that of the meshes 18, 19 themselves.
  • The disc 30 is provided with a set of three radial tongues 35 angularly equidistant from one another and extending towards the inner surface of the lateral wall 7 of the casing 2 (Figures 2 and 3). The tongues 35 are bent with respect to the plane of the disc 30 in such a way as to form with this latter an angle of substantially 45° and present a circular outline such that these do not dig in to the wall 7 during longitudinal excursions of the cartridge 20 by the effect of the increase in the working temperature.
  • For the purpose of distributing exhaust gases uniformly over the entire inner surfaces of the cartridge 20 the device 1 is provided with a pair of flow deflectors 37, 38 substantially constituted by tubular elements of conical profile of different diameters fixed coaxially to the crosspiece 31.
  • According to a further characteristic of the present invention the disc 30 is provided with a through-hole 40 of suitable dimensions, which puts the inlet 3 in direct communication with the outlet 4 of the casing 2.
  • The device 1 operates in general in a manner similar to known devices of this type in the sense that the exhaust gases gain access to the interior of the casing 2 through the inlet 3 and subsequently flow to the outlet 4 after having traversed the cartridge 2 and having been purified by means of the purifier 5 contained in it.
  • By examining in detail the structure of the device 1 numerous characteristics are noted which render this device signficantly effective.
  • In particular, the use of the stocking 15 of woven wire-like material certainly performs two important functions:
       a principle function consisting in supporting the mineral fibres 6 correctly for the purpose of maintaining them always distributed in a uniform manner within the interior of the cartridge 20 and therefore making the purifying effect homogeneous in time;
       a secondary, but equally important function, consisting in creating, between the inlet 3 and the outlet 4, an alternating set of layers of mineral fibres and wire material, this latter causing a certain separation between adjacent layers of mineral fibres and therefore a good distribution of the flow of gas between the mineral fibres themselves, and, ultimately, an optimum purifying effect.
  • The system for fixing the cartridge 20 to the casing 2 by means of the tie rod 32 (having a coefficient of thermal expansion similar to that of the rigid meshes 18, 19) allows, simultaneously, the fixing of the cartridge 20 to the casing 2 and the free expansion of the meshes 18, 19 without casuing rupture of these meshes by exceeding the yield points of the respective metal materials.
  • The presence of the hole 40 in the disc 30 has substantially no effect in normal operating conditions of the device 1, that is to say in the case in which the combustion residues are consumed by part of the purifier means 5 in such a way as to cause no accumulation of these between the fibres 6. In the case in which such eventuality occurs, the momentary blockage of the cartridge 20 and the constant inflow of gases to the interior thereof cause an excess pressure which does not exceed a predetermined safety level since the discharge gas can momentarily flow out through the hole 40 allowing the purifier means 5 to digest the overload of combustion residues.
  • Finally, the combined action of the diffuser 12 and the flow deflectors 37, 38 permits possible damage due to the rapid expansion of the exhaust gas jet flowing into the interior of the cartridge 20 to be reduced to the minimum.
  • From a study of the characteristics of the device formed according to the present invention the advantages which it allows to be obtained are therefore evident.
  • The high efficiency of the purifier means 5, conveniently supported by the stocking 15 of resiliently deformable woven metal wire permits a drastic reduction in the more noxious and repeated emissions, such as the particles, oxides of nitrogen oxides of carbon and unburnt hydrocarbons, containing the back pressure within more than acceptable limits.
  • Beyond the overall improvement in the purifying efficiency and functionality, it is observed that the device 1 can be made at an overall cost which is significantly less than the cost of ceramic devices currently utilised and described above.
  • As far as the possible utilisation of the device formed according to the present invention is concerned, it is noted that, as a rule, it can be utilised advantageously to treat exhaust gases from internal combustion engine of the Diesel cycle installed on vehicles or in fixed installations (for example generators) as well as to treat the exhaust gases of heating boilers adapted for industrial and civil installations.
  • Finally, it is clear that the device 1 described above can have modifications and variations introduced thereto without however departing from the present invention.
  • For example, it is evident that wide modifications can be introduced to the structure of the cartridge 2 whilst retaining the principle of interposing between the inlet 3 and the outlet 4 of the casing 2 alternate layers of mineral fibres and stockings of woven wire-like material. In the case in which these two elements are wound in a spiral (as illustrated in Figure 4) the stocking 15 could be disposed on a single face of the layer 6 of fibres in that during the course of the winding this alternation of layers described above would in any case be obtained.
  • The support for the cartridge 20 could be achieved by means of several tie rods either positioned within or outside the cartridge itself, the concept of utilising a material with a coefficient of thermal expansion as close as possible to that of the rigid meshes 18, 19 remaining the same. It is also evident that other ways of support could be thought up, for example utilising resilient means able to maintain the cartridge in the correct working position whilst allowing termal expansion in longitudinal and transverse directions within the associated case.
  • The number of flow deflectors could be greater or less than two, and the associated structure could be different from the conical structure described above.

Claims (13)

1. A device reducing atmospheric pollution by the exhaust gases of internal combustion engines of the type comprising a hollow casing (2) provided with an inlet (3) for exhaust gases to be purified, and an outlet (4) for the purified exhaust gases, and purifier means (5) interposed between said inlet (3) and said outlet (4) and essentially comprising mineral fibres (6), characterized by support means (15) for said mineral fibres (6) essentially constituted by woven filiform material in contact with said fibres (6) in such a way to define, between said inlet (3) and outlet (4), a substantial alternation of layers of filiform material (15) and mineral fibres (6).
2. A device according to Claim 1, characterized in that said support means (15) are essentially constituted by a stocking of filiform material having a plurality of resiliently deformable free loops conveniently obtained by mechanically knitting a stainless steel wire particularly adapted to resist high temperatures.
3. A device according to Claim 1 or 2, characterized in that said mineral fibres (6) are constituted by quartz and/or silica.
4. A device according to any of Claims 1 to 3, characterized in that said mineral fibres (6) are rendered active by a catalyst.
5. A device according to Claim 2, characterized in that said mineral fibres (6) and said stocking (15) of filiform material are wound into a spiral in such a way to define a tubular mattress (17) interposed between an inner (18) and an outer tubular metal mesh (19), said mineral fibres (6), said stocking (15) and said rigid meshes (18, 19) together defining a cartridge (20).
6. A device according to Claim 5, characterized in that said cartridge (20) is maintained in its working position inside said casing (2) by a disc (30) resting against an outlet portion of said cartridge (20) and mechanically connected to an inlet wall (8) of said casing (2) by at least an axial tie rod (32).
7. A device according to Claim 6, characterized in that said tie rod (32) is made of a material of the same type as the one of said meshes (18, 19) as to present substantially a thermal expansion similar to that of said meshes (18, 19).
8. A device according to Claim 6 or 7, characterized in that said disc (30) is provided with spacer and guide means (35) for excursions of the outlet portion of said cartridge (20) along a side wall (7) of said casing (2).
9. A device according to Claim 8, characterized in that said spacer and guide means comprise a plurality of equidistant tongues (35) radially extending from said disc (30) toward the inner surface of said side wall (7) without engaging said inner surface.
10. A device according to Claim 9, characterized in that said tongues (35) are bent with respect to the plane of said disc (30) toward said inlet wall (8) and present a circular outer profile such as not digging into said side wall (7) even when expanded due to the working temperature.
11. A device according to any Claim from 6 to 10, characterized in that said disc (30) is provided with a through-hole (40) for direct communication between said inlet (3) and said outlet (4), said outlet (4) having a through-hole (13) which is offset with respect to said inlet (3).
12. A device according to any Claim from 6 to 11, characterized in that said inlet (3) is connected to a through-hole (11) of said inlet wall (8) by means of a diffuser (12) located downstream of said inlet (3), at least a deflector (37, 38) having a conical profile being located between said inlet (3) and said cartridge (20) coaxially with centering means (21, 22) for an upper portion of said cartridge (20) with respect to said inlet wall (8) of said casing (2).
13. A device according to any preceding Claim, characterized in that said inlet (3) is connected to the exhaust of a diesel engine and said outlet (4) is connected to a heat recovery unit.
EP89108116A 1988-05-06 1989-05-05 A device for reducing atmospheric pollution by exhaust gases from internal combustion engines Expired - Lifetime EP0340784B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89108116T ATE79442T1 (en) 1988-05-06 1989-05-05 DEVICE FOR REDUCING AIR POLLUTION CAUSED BY ENGINE EXHAUST.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT6741788 1988-05-06
IT67417/88A IT1219270B (en) 1988-05-06 1988-05-06 DEVICE FOR THE REDUCTION OF ATMOSPHERIC POLLUTION FROM EXHAUST GAS OF INTERNAL COMBUSTION ENGINES

Publications (2)

Publication Number Publication Date
EP0340784A1 EP0340784A1 (en) 1989-11-08
EP0340784B1 true EP0340784B1 (en) 1992-08-12

Family

ID=11302207

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89108116A Expired - Lifetime EP0340784B1 (en) 1988-05-06 1989-05-05 A device for reducing atmospheric pollution by exhaust gases from internal combustion engines

Country Status (5)

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EP (1) EP0340784B1 (en)
AT (1) ATE79442T1 (en)
DE (1) DE68902417T2 (en)
ES (1) ES2034477T3 (en)
IT (1) IT1219270B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992020910A1 (en) * 1991-05-13 1992-11-26 Saverio Megna Exhaust gas purifying device for an internal combustion engine
FR2683854A1 (en) * 1991-11-19 1993-05-21 Ecia Equip Composants Ind Auto SUPPORT STRUCTURE OF AT LEAST ONE EXHAUST GAS CATALYST MATERIAL FOR AN ENGINE, PARTICULARLY A MOTOR VEHICLE.
EP0679799A2 (en) * 1994-04-28 1995-11-02 Isuzu Ceramics Research Institute Co., Ltd. Exhaust particulate filter for diesel engine
EP1123728A1 (en) 2000-02-08 2001-08-16 Luigi Pellegrino Device for reducing atmospheric pollution due to exhaust gases

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5298046A (en) * 1993-01-06 1994-03-29 Minnesota Mining And Manufacturing Company Diesel particulate filter element and filter
DE4303850C1 (en) * 1993-02-10 1994-10-13 Alfred Buck Device for the catalytic cleaning of flowing gases, in particular exhaust gases from internal combustion engines
DE19504450A1 (en) * 1995-02-10 1996-08-22 Florian Gamel Exhaust gas purification device for internal combustion engines
FR2751559B1 (en) * 1996-07-25 1998-09-04 Sprint Metal Sa FILTER FOR THE RETENTION OF SOLID PARTICLES CONTAINED IN THE EXHAUST GASES OF A DIESEL ENGINE AND FILTRATION BUFFER
FR2782744B1 (en) * 1998-03-26 2001-05-18 Charles Lauricella 3 JCL ANTI-POLLUTION EXHAUST PIPE
DE19919928C2 (en) * 1999-04-30 2001-04-26 Oberland Mangold Gmbh Filter structure for filtering solids from a gas stream as well as particle filters
EP1340890A1 (en) * 2002-02-28 2003-09-03 Luigi Pellegrino A device for reducing the atmospheric pollution due to exhaust gas
AU2003303085A1 (en) * 2003-09-26 2005-04-14 N.V. Bekaert S.A. Catalytic converter and method for making the same
US20070041880A1 (en) * 2003-12-20 2007-02-22 Bernd Reinsch Exhaust treatment device
EP1584369A1 (en) * 2004-04-05 2005-10-12 Luigi Pellegrino Device for reducing polluting substances present in exhaust gases of an internal-combustion engine
EP1624165A1 (en) * 2004-08-05 2006-02-08 Luigi Pellegrino Device for reducing polluting substances present in exhaust gases of an internal-combustion engine
KR101378791B1 (en) * 2011-09-26 2014-03-27 최승현 Scr reactor

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB832890A (en) * 1957-08-08 1960-04-21 Bendix Aviat Corp Coalescer element construction
FR87613E (en) * 1964-11-05 1966-04-15 Berliet Automobiles Device for cleaning the exhaust gases of heat engines containing solid components
US4195063A (en) * 1974-09-03 1980-03-25 Matsushita Electric Industrial Co., Ltd. Catalyst element for cleaning exhaust gases
GB1519343A (en) * 1974-09-03 1978-07-26 Matsushita Electric Ind Co Ltd Gas purifying devices
GB1567593A (en) * 1976-10-20 1980-05-21 Matsushita Electric Ind Co Ltd Exhaust gas control equipment
DE3228325A1 (en) * 1982-07-29 1984-02-02 Fa. J. Eberspächer, 7300 Esslingen FILTER AND AFTER COMBUSTION DEVICE
DE3545762A1 (en) * 1985-12-21 1987-07-02 Leistritz Maschfabrik Paul Soot filter

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992020910A1 (en) * 1991-05-13 1992-11-26 Saverio Megna Exhaust gas purifying device for an internal combustion engine
FR2683854A1 (en) * 1991-11-19 1993-05-21 Ecia Equip Composants Ind Auto SUPPORT STRUCTURE OF AT LEAST ONE EXHAUST GAS CATALYST MATERIAL FOR AN ENGINE, PARTICULARLY A MOTOR VEHICLE.
EP0543710A1 (en) * 1991-11-19 1993-05-26 Ecia - Equipements Et Composants Pour L'industrie Automobile Structure of the catalytic support of the exhaust of a vehicle engine
EP0679799A2 (en) * 1994-04-28 1995-11-02 Isuzu Ceramics Research Institute Co., Ltd. Exhaust particulate filter for diesel engine
EP1123728A1 (en) 2000-02-08 2001-08-16 Luigi Pellegrino Device for reducing atmospheric pollution due to exhaust gases

Also Published As

Publication number Publication date
IT1219270B (en) 1990-05-03
IT8867417A0 (en) 1988-05-06
ES2034477T3 (en) 1993-04-01
DE68902417D1 (en) 1992-09-17
ATE79442T1 (en) 1992-08-15
DE68902417T2 (en) 1993-01-07
EP0340784A1 (en) 1989-11-08

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