Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H19/00—Coated paper; Coating material
  • D21H19/80—Paper comprising more than one coating
  • D21H19/82—Paper comprising more than one coating superposed
  • D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
  • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
  • B41M5/506—Intermediate layers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
  • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
  • B41M5/508—Supports
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
  • B41M5/52—Macromolecular coatings
  • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays

Definitions

• This invention relates to coated paper suitable for printing by the rotogravure process or by offset lithography, and to methods of preparing the same.
• GB-2039789 discloses an electrostatic imaging sheet wherein one side of the sheet is electrically conductive and the other side of the sheet has a continuous dielectric layer comprising a mixture of a smectite clay and an electrically insulating polymer.
• a paper suitable for printing by offset lithography and/or by a rotogravure process comprising a cellulosic sheet material provided with first and second pigmented coats each of which is hydrophilic, water absorbent and porous, said first coat being a base coat and said second coat being a top coat; wherein the pigment of one of said coats is predominantly of non smectite-type nature, whilst the pigment of the other of the said coats is predominantly of a smectite-type nature comprising at least 60% by weight of a water-swellable smectite-type clay.
• a method of preparing paper suitable for printing by offset lithography and/or by a rotogravure process which method includes the steps of applying the following pigmented coats to a cellulosic sheet material;
• a method of printing an image on a paper using a rotogravure or an offset lithography printing process, the paper on which the image is printed comprising a cellulosic sheet material provided with first and second pigmented coats each of which is hydrophilic, water absorbent and porous, said first coat being a base coat and said second coat being a top coat; wherein the pigment of one of said coats is predominantly of non smectite-type nature, whilst the pigment of the other of the said coats is predominantly of a smectite-type nature comprising at least 60% by weight of a water-swellable smectite-type clay.
• both the base coat and the top coat of a paper according to the present invention need to be hydrophilic, water absorbent and porous so that water can be transported rapidly away from the surface of the paper.
• the smectite-type clay may, for example, be bentonite, montmorillonite, hectorite, saponite or fullers earth, but especially preferred is a natural bentonite which has, or has been treated to have, predominantly sodium ions in its exchangeable cation sites.
• the pigment which is predominantly of a smectite-type nature contain at least 75%, more preferably at least 90%, by weight of the smectite-type clay.
• the pigment employed in the other coating may, for example, be a white pigment, other than a smectite-type clay, such as a kaolin clay, a natural or a synthetic calcium carbonate, talc or a natural or synthetic calcium sulphate.
• a smectite-type clay such as a kaolin clay, a natural or a synthetic calcium carbonate, talc or a natural or synthetic calcium sulphate.
• other conventional pigments may be employed. It is possible that the pigment in the other coating may, in some instances, also contain a minor amount of a smectite-type clay.
• the paper may be provided with further coatings. It is preferred however, that the material comprises two coatings, the top coating including a pigment which is predominantly smectite-type clay, typically bentonite, whilst the other coating, or base coating, includes a pigment which is substantially non-smectite in nature. It is, however, within the scope of the invention to provide a paper in which the pigment of the base coating is predominantly smectite clay in nature and the top coating substantially non-smectite clay. Most preferably, the base coating contains kaolin and the top coating bentonite.
• each of the coatings is preferably bound together by an adhesive which may, for instance, be one of the conventional adhesives used in paper coating, such as a rubber latex, for example an acrylic copolymer latex (styrene butadiene rubber latex), or a starch.
• an adhesive which may, for instance, be one of the conventional adhesives used in paper coating, such as a rubber latex, for example an acrylic copolymer latex (styrene butadiene rubber latex), or a starch.
• the quantity of adhesive solids required is in the range of from 1 to 20 parts by weight to 100 parts by weight of the pigment.
• the quantity of adhesive solids may be up to 300 parts by weight to 100 parts by weight of the pigment; in some circumstances, if the smectite-­type coat is the base coat, the pigment may be employed in the absence of an adhesive as it has been found that adequate adhesion of the clay to the cellulosic fibres is achieved without the presence of an adhesive.
• an adhesive it is found that for a paper intended for rotogravure printing a latex adhesive is preferred and especially an acrylic copolymer latex.
• the quantity of adhesive used will be in the range from 1 to 300 parts by weight of dry polymer to 100 parts by weight of dry smectite clay.
• the pigment of the coat which is predominantly smectite-type in nature is provided by applying to the sheet material an aqueous suspension comprising up to 20% by weight of a pigment comprising at least 60% by weight of a water-swellable smectite clay.
• a rotogravure base paper of substance weight 38 gm ⁇ 2 (grams per square metre) was coated by means of a laboratory coating apparatus of the type described in British Patent Specification No. 1032536 running at a speed of 200 m min ⁇ 1.
• Three different coating procedures were used, namely:- 1.
• a single coat of a composition consisting of 100 parts by weight of a kaolin clay, 5 parts by weight of an acrylic copolymer latex adhesive (dry basis), and water to form a suspension containing 57.4% by weight of total solids.
• the kaolin clay had a particle size distribution such that 6% by weight consisted of particles having an equivalent spherical diameter larger than 10 microns and 43% by weight consisted of particles having an equivalent spherical diameter smaller than 2 microns.
• the latex contained 50% weight of acrylic copolymer solids.
• Samples of the base paper were coated with the composition at four different coat weights. 2. a). A base coat of an aqueous suspension containing 5% by weight of the European bentonite having sodium and calcium exchangeable cations. The coat weight of bentonite applied to the base paper was 0.5 gm ⁇ 2. b). A top coat of the same composition as was described under 1 above applied at four different coat weights. 3. a). A base coat of the same composition as was described under 1 above applied at four different coat weights. b). A top coat of the same aqueous suspension of bentonite as was described under 2a. above at a coat weight of 0.5 gm ⁇ 2.
• a further measurement of print density was performed on the reverse side of the paper in the region of the solid black area in order to determine the degree of "strike through" of the printing ink.
• the degree of "speckle" in the half tone area of each print was determined by estimating the percentage of gravure printing dots which were missing from the test print.
• the gloss of an un-printed area of each coated paper sample was also measured by the TAPPI Standard Method No. T480ts-65.
• An offset base paper of substance weight 65 gm ⁇ 2 was coated by means of the laboratory coating apparatus used in Example 1 running at a speed of 400 m min ⁇ 1 firstly with a composition consisting of: 100 parts by weight of a kaolin clay 11 parts by weight of styrene butadiene rubber latex (dry basis) 1 part by weight of sodium carboxymethyl cellulose; water to form a suspension containing 60.8% by weight of total solids
• the kaolin clay had a particle size distribution such that 0.2% by weight consisted of particles having an equivalent spherical diameter larger than 10 microns and 10% by weight consisted of particles having an equivalent spherical diameter smaller than 2 microns.
• the latex contained 50% by weight of styrene butadiene rubber solids. Samples of the base paper were coated with this composition at four different coat weights.
• Samples of the paper coated with the composition described above at four different coat weight were each treated with a second coating composition which consisted of a 5% by weight suspension in water of a European bentonite having sodium and calcium exchangeable cations at a coat weight of 0.5 gm ⁇ 2.
• Samples of the coated paper were tested for offset lithography printing properties by means of an IGT Model AC2 printability tester.
• the paper samples were clipped to the moving sector of the instrument which was set to move at a constant velocity of 1 ms ⁇ 1.
• An aluminium alloy damping roll of face width 25 mm and a rubber covered printing roll of face width 20 mm were rotatably and removably mounted on spindles provided on the fixed part of the instrument with the damping roll contacting the surface of the paper sample 70 mm in advance of the line of contact of the printing roll with the paper surface in the sense of the direction of relative motion between the sector bearing the paper sample and the rolls.
• each paper sample was printed with a strip of solid colour 20 mm in width, the first 70 mm being printed on dry paper and the remaining 140 mm on pre-wetted paper.
• the damping roll was biased against the paper sample with a force of 25 kg and the printing roll was biased against the sample with a force of 50 kg. Both the damping roll and the printing roll had an overall diameter of 68 mm.
• the damping roll was loaded with a substantially identical weight of water, namely approximately 0.6 g of water per square metre of roll surface area by condensation of water vapour on the surface of the roll.
• the damping roll was placed in a refrigerator having an internal temperature of -8 ⁇ 1°C and a coiled temperature probe connected to a digital thermometer was placed in the central spindle hole of the roll.
• a desiccator in which a humidity of 55% RH was maintained by means of a saturated solution of sodium dichromate.
• the block of solid colour printed on the dry and pre-wetted areas, respectively, of the paper samples was tested for print gloss by means of a Hunterlab Glossmeter Model D16 and at an angle of 75° with the normal to the paper surface in accordance with TAPPI Standard No. T480ts-65, the mean of five determinations for each area being recorded.
• the block of solid colour printed on the dry and pre-wetted areas, respectively, was also tested for print density by means of a Macbeth RD514 Reflection Densitometer, in this case the mean of ten determinations for each area being recorded.
• a matt offset printing base paper of substance weight 59 gm ⁇ 2 was coated in two stages, each stage being by means of the laboratory coating apparatus used in Examples 1 and 2 running at a speed of 4000 m min ⁇ 1.
• the coating composition used consisted of: 100 parts by weight of natural calcium carbonate 11 parts by weight of a styrene butadiene rubber latex (dry basis) 0.5 parts by weight of sodium carboxymethyl cellulose 0.1 part by weight of sodium hydroxide water to form a suspension containing 66.9% by weight of total solids.
• the natural calcium carbonate was a ground marble having a particle size distribution such that 1% by weight consisted of particles having an equivalent spherical diameter larger than 10 microns and 90% by weight consisting of particles having an equivalent spherical diameter small than 2 microns.
• the latex contained 50% by weight of styrene butadiene rubber solids.
• Example 2 The same offset lithography printing tests as are described in Example 2 were performed on the paper samples coated in two stages and, as a comparison, on a sample coated only with the calcium carbonate containing composition. In addition the gloss of an un-printed area of each coated paper sample was also measured by the TAPPI Standard Method No. T480ts-65.

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• Chemical & Material Sciences (AREA)
• Inorganic Chemistry (AREA)
• Paper (AREA)

Applications Claiming Priority (2)

Publications (1)

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Country Status (6)

Cited By (5)

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Citations (6)

• 1988
  • 1988-04-12 GB GB888808552A patent/GB8808552D0/en active Pending
• 1989
  • 1989-04-12 BR BR898906809A patent/BR8906809A/pt unknown
  • 1989-04-12 JP JP1504553A patent/JPH02503933A/ja active Pending
  • 1989-04-12 WO PCT/GB1989/000388 patent/WO1989009852A1/en not_active Ceased
  • 1989-04-12 FI FI895929A patent/FI895929A7/fi not_active IP Right Cessation
  • 1989-04-12 GB GB8908201A patent/GB2217233A/en not_active Withdrawn
  • 1989-04-12 EP EP89303636A patent/EP0337771A1/de not_active Withdrawn

Patent Citations (6)

Non-Patent Citations (2)

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