EP0335012A1 - Method for continuously producing a wear resistant metal-hard material composite by centrifugal casting - Google Patents

Method for continuously producing a wear resistant metal-hard material composite by centrifugal casting Download PDF

Info

Publication number
EP0335012A1
EP0335012A1 EP88121821A EP88121821A EP0335012A1 EP 0335012 A1 EP0335012 A1 EP 0335012A1 EP 88121821 A EP88121821 A EP 88121821A EP 88121821 A EP88121821 A EP 88121821A EP 0335012 A1 EP0335012 A1 EP 0335012A1
Authority
EP
European Patent Office
Prior art keywords
centrifugal casting
casting
hard materials
mold
molten metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88121821A
Other languages
German (de)
French (fr)
Other versions
EP0335012B1 (en
Inventor
Karl-Hermann Busse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Busse Karl-Hermann
Original Assignee
SPRAYTEC GESELLSCHAFT fur OBERFLACHENTECHNIK MBH
Busse Karl-Hermann
SPRAYTEC GES fur OBERFLACHENTE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SPRAYTEC GESELLSCHAFT fur OBERFLACHENTECHNIK MBH, Busse Karl-Hermann, SPRAYTEC GES fur OBERFLACHENTE filed Critical SPRAYTEC GESELLSCHAFT fur OBERFLACHENTECHNIK MBH
Priority to AT88121821T priority Critical patent/ATE89205T1/en
Publication of EP0335012A1 publication Critical patent/EP0335012A1/en
Application granted granted Critical
Publication of EP0335012B1 publication Critical patent/EP0335012B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D13/00Centrifugal casting; Casting by using centrifugal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/08Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal

Definitions

  • the invention relates to a method for the continuous production of a wear-resistant hard metal composite by centrifugal casting.
  • a disadvantage of these procedures is, in particular, that when hard materials are added to the ladle filled with molten metal, a large part of the hard materials dissolves due to the long action time of the molten metal on the solid particles and the exchange of substances supported by stirring, for example, and therefore does not act as a wear protection or an additional time-consuming work step is associated with the sprinkling of the hard materials onto a dough or liquid centrifugal casting layer.
  • hard materials of low density such as B4C, TiB2, TiC, although these have a much higher hardness than e.g. Tungsten carbide, do not use to reinforce the mold wall facing outer surface of the casting.
  • these hard materials accumulate preferentially on the inside or in the core area of the casting and are therefore ineffective with regard to the wear protection of the outer surface of cast solid bodies.
  • the present invention aims to overcome the disadvantages mentioned.
  • the invention has for its object to develop a method for the continuous production of a wear-resistant hard metal composite by centrifugal casting (vertical and horizontal centrifugal casting), which in particular in a cost-effective manner a simple parameter control for reproducible generation of such a composite for reinforcing large rotationally symmetrical components against Wear also possible with the use of metallic and non-metallic hard materials of high hardness and low density.
  • This object is achieved in that solid powdery and / or granular synthetic metallic and / or non-metallic hard materials during the pouring of the molten metal into a centrifugal casting mold rotating around its axis of symmetry with the aid of a conveyor device using an inert conveying gas temporarily into the metal stream flowing into the mold be injected.
  • the duration of stay of the hard materials in the molten metal before entering the mold is reduced and their discharge increased
  • the distribution and depth of storage of the hard materials can be adjusted in a simple, reproducible manner by choosing the time and the duration of the injection.
  • the casting process is continued continuously with pure metal melt to complete the casting.
  • Metal melts composed of alloyed or unalloyed steel or gray cast iron, pure non-ferrous metals such as cobalt and nickel or of a nickel or cobalt-based alloy are preferably suitable for the application of synthetic hard materials.
  • carbides of the elements Mo, Nb, Ta, V, W and Zr are advantageous, in particular because of their high density and low dissolution rate. Due to the high centrifugal acceleration occurring during centrifugal casting, these are transported radially through the melt towards the mold wall and accumulate in the cast body in front of the outer processing layer.
  • very hard and only slowly soluble borides, oxides and carbides of low density such as TiB2, Al2O3, TiO2, B4C, TiC
  • metals and / or high density carbides such as Co, Ni, Ta, W, TaC, W2C, WC, are connected.
  • the advantages achieved by the invention are, in particular, that the casting process for producing a hard material-metal composite takes place in a continuous and simple, inexpensive manner and that the distribution, composition, concentration and depth of the hard materials in the centrifugal casting body can be adjusted reproducibly.
  • FIG. 1 shows the diagrammatic representation of the method according to the invention for the continuous production of a wear-resistant hard material-metal composite by centrifugal casting (here: horizontal centrifugal casting).
  • the centrifugal casting mold 1 is first set in rotation by its drive rollers 2 about its axis of symmetry. After reaching a sufficiently high rotational speed for the uniform distribution of the molten metal in the centrifugal casting mold 1, after the usual application of a size to the mold wall (not shown in the figure), pure molten metal 3 from the ladle 4 through the casting device 5 into the cold centrifugal casting mold 1 poured. Due to the high heat dissipation caused by the cold centrifugal casting mold 1, an approx. 5 - 15 mm thick processing layer 6 solidifies immediately of the casting, the machining of this layer, the manufacturing tolerances attributable to the casting process and the mold contour can be compensated for.
  • solid powdery and / or granular hard materials 9 are now passed through an opening 10 in the casting device 5 with an inert protective gas as carrier or conveying gas 8, preferably argon the vicinity of the centrifugal casting mold 1 into which the metal stream flowing through the casting device 5 is injected.
  • an inert protective gas as carrier or conveying gas 8 preferably argon the vicinity of the centrifugal casting mold 1 into which the metal stream flowing through the casting device 5 is injected.
  • the hard materials are metered in a simple manner by adjusting the carrier gas pressure.
  • the casting process is continued by interrupting the powder supply with pure metal melt 12 until the casting is finished.
  • FIG. 2 shows an example of a cross section through a roller cast according to the developed method with a processing layer made of cast steel 13, a wear-resistant layer 14 made of cast steel with embedded synthetic hard materials 15 and a core made of cast steel 16.

Abstract

In order to produce a wear-resistant hard-metal material composite in a continuous fashion by centrifugal casting (vertical and horizontal centrifugal casting), solid, pulverulent and/or granular, synthetic, metallic and/or non-metallic hard materials are from time to time during the casting process injected into the metal stream flowing into the mould, by means of a conveying device and using an inert conveying gas. As a result of the associated simplicity of parameter control, the armouring of large, rotationally symmetrical components, such as rolls and rollers, against wear using solid synthetic hard materials by casting is for the first time possible in an economical and reproducible manner. By agglomeration of hard materials and metals of different densities with the aid of organic and inorganic binders, it is possible to use even very hard low-density borides, oxides and carbides which dissolve very slowly in molten metals for armouring the outer surface of the casting, namely the surface facing the mould wall. <IMAGE>

Description

Die Erfindung betrifft ein Verfahren zum kontinuierlichen Herstellen eines verschleißbeständigen Hartstoff-­Metallverbundes durch Schleudergießen.The invention relates to a method for the continuous production of a wear-resistant hard metal composite by centrifugal casting.

Es ist bekannt, rotationssymmetrische Gußkörper durch Schleudergießen herzustellen, die in unterschiedlichen Bereichen pulverförmige oder körnige Hartstoffe aufweisen können (deutsche Patentschriften Nr. 891324 und Nr. 2254705).It is known to produce rotationally symmetrical cast bodies by centrifugal casting, which can have powdery or granular hard materials in different areas (German patent specifications No. 891324 and No. 2254705).

Dabei ist es allerdingt nötig, entweder zunächst feste Hartstoffe in eine Metallschmelze zuzugeben und anschließend die Hartstoffe gemeinsam mit der Metallschmelze in eine Schleudergußkokille einzugießen (deutsche Patentschrift Nr. 891324) oder erst nach dem Eingießen der Metallschmelze in die Schleudergußkokille Hartstoffe auf die Innenoberfläche der Schleudergußlage aufzustreuen (deutsche Patentschrift Nr. 2254705).However, it is absolutely necessary to either first add solid hard materials into a molten metal and then pour the hard materials together with the molten metal into a centrifugal casting mold (German Patent No. 891324) or to sprinkle hard materials onto the inner surface of the centrifugal casting layer only after the molten metal has been poured into the centrifugal casting mold (German Patent No. 2254705).

Nachteilig bei diesen Verfahrensweisen ist insbesondere, daß beim Zugeben von Hartstoffen in die mit Metallschmelze gefüllte Gießpfanne aufgrund der langen Einwirkzeit der Metallschmelze auf die Feststoffpartikel und des durch z.B. Rühren unterstützten Stofftausches ein großer Teil der Hartstoffe in Lösung geht und daher nicht als Verschleißschutz zur Wirkung kommt oder mit dem Aufstreuen der Hartstoffe auf eine teigige oder flüssige Schleudergußlage ein zusätzlicher zeitintensiver Arbeitsschritt verbunden ist.A disadvantage of these procedures is, in particular, that when hard materials are added to the ladle filled with molten metal, a large part of the hard materials dissolves due to the long action time of the molten metal on the solid particles and the exchange of substances supported by stirring, for example, and therefore does not act as a wear protection or an additional time-consuming work step is associated with the sprinkling of the hard materials onto a dough or liquid centrifugal casting layer.

Zudem ist bei diesen beiden Verfahrensweisen eine aufwendige Parameteroptimierung erforderlich, um die Verteilung und Tiefe der Hartstoffe in dem Gußstück reproduzierbar einstellen zu können.In addition, these two procedures require complex parameter optimization in order to be able to reproducibly adjust the distribution and depth of the hard materials in the casting.

Hierdurch bedingt können insbesondere Fertigungstoleranzen bei der Herstellung von großen und teuren Bauteilen, wie z.B. Walzen und Rollen, nicht sicher eingehalten werden.This can result in particular manufacturing tolerances in the manufacture of large and expensive components, such as Rolls and rolls, are not adhered to safely.

Daher sind die bekannten Verfahrensweisen zum Erzeugen eines Hartstoff-Metallverbundes für große Präzisionsteile nicht geeignet.The known methods for producing a hard material-metal composite are therefore not suitable for large precision parts.

Ferner können zur verschleißfesten Panzerung der Kokillenwand zugekehrten Außenfläche von rotationssymmetrischen Gußkörpern nach dem Schleudergußverfahren nur Hartstoffe sehr hoher Dichte, wie z.B. Wolframkarbid, die infolge der beim Schleudergießen einwirkenden Zentrifugalkraft radial durch die Schmelze in Richtung Kokillenwand transportiert werden, zum Einsatz kommen.Furthermore, for wear-resistant armoring of the mold wall facing the outer surface of rotationally symmetrical cast bodies using the centrifugal casting method, only hard materials of very high density, such as Tungsten carbide, which is transported radially through the melt towards the mold wall due to the centrifugal force acting during centrifugal casting, is used.

Demgegenüber lassen sich Hartstoffe geringer Dichte, wie z.B. B₄C, TiB₂, TiC, obwohl diese eine wesentlich höhere Härte als z.B. Wolframkarbid aufweisen, nicht zur Bewehrung der Kokillenwand zugekehrten äußeren Oberfläche des Gußteils verwenden. Diese Hartstoffe reichern sich infolge der Strömungsbedingungen der Metallschmelze in der Schleudergußkokille bevorzugt auf der Innenseite bzw. im Kernbereich des Gußteils an und sind deshalb hinsichtlich des Verschleißschutzes der Außenfläche von gegossenen Vollkörpern ohne Wirkung.In contrast, hard materials of low density, such as B₄C, TiB₂, TiC, although these have a much higher hardness than e.g. Tungsten carbide, do not use to reinforce the mold wall facing outer surface of the casting. As a result of the flow conditions of the molten metal in the centrifugal casting mold, these hard materials accumulate preferentially on the inside or in the core area of the casting and are therefore ineffective with regard to the wear protection of the outer surface of cast solid bodies.

Die vorliegende Erfindung bezweckt, die genannten Nachteile zu beseitigen.The present invention aims to overcome the disadvantages mentioned.

Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zum kontinuierlichen Herstellen eines verschleißbeständigen Hartstoff-Metallverbundes durch Schleudergießen (Vertikal- und Horizontal-Schleuderguß) zu entwickeln, welches insbesondere in kostengünstiger Weise eine einfache Parametersteuerung zum reproduzierbaren Erzeugen eines derartigen Verbundes zur Bewehrung großer rotationssymmetrischer Bauteile gegen Verschleiß auch unter Verwendung von metallischen- und nichtmetallischen Hartstoffen hoher Härte und niedriger Dichte ermöglicht.The invention has for its object to develop a method for the continuous production of a wear-resistant hard metal composite by centrifugal casting (vertical and horizontal centrifugal casting), which in particular in a cost-effective manner a simple parameter control for reproducible generation of such a composite for reinforcing large rotationally symmetrical components against Wear also possible with the use of metallic and non-metallic hard materials of high hardness and low density.

Diese Aufgabe wird erfindungsgemäß dadurch gelöst, daß feste pulverförmige und/oder körnige synthetische metallische und/oder nichtmetallische Hartstoffe während des Eingießens der Metallschmelze in eine um ihre Symmetrieachse rotierende Schleudergußkokille mit Hilfe einer Fördereinrichtung unter Verwendung eines inerten Fördergases zeitweise in den in die Kokille einfließenden Metallstroms injiziert werden.This object is achieved in that solid powdery and / or granular synthetic metallic and / or non-metallic hard materials during the pouring of the molten metal into a centrifugal casting mold rotating around its axis of symmetry with the aid of a conveyor device using an inert conveying gas temporarily into the metal stream flowing into the mold be injected.

Hierdurch wird einerseits die Aufenthaltsdauer der Hartstoffe in der Metallschmelze vor dem Einlaufen in die Kokille verringert und ihr Ausbringen erhöht, andererseits kann die Verteilung und Einlagerungstiefe der Hartstoffe in einfacher Weise, reproduzierbar durch Wahl des Zeitpunkts sowie der Zeitdauer der Injektion eingestellt werden.In this way, on the one hand, the duration of stay of the hard materials in the molten metal before entering the mold is reduced and their discharge increased, on the other hand, the distribution and depth of storage of the hard materials can be adjusted in a simple, reproducible manner by choosing the time and the duration of the injection.

Da insbesondere bei großen durch Schleudergießen hergestellten Bauteilen, um die mit dem Gießvorgang und der Kokillenkontur verbundenen Fertigungstoleranzen auszugleichen, eine aufwendige Nachbearbeitung der Gußstücke erforderlich ist und diese bei hohen Hartstoffanteilen durch kostenintensives Schleifen erfolgen muß, wird zum Ausgleich der Fertigungstoleranzen vor der Zugabe von festen synthetischen Hartstoffen in den in die Kokille einfließenden Metallstrom zunächst eine spanbare Bearbeitungsschicht gegossen.Since, in particular in the case of large components produced by centrifugal casting, in order to compensate for the manufacturing tolerances associated with the casting process and the mold contour, an elaborate reworking of the castings is necessary and this has to be carried out with high hard material proportions by expensive grinding, to compensate for the manufacturing tolerances before the addition of solid synthetic Hard materials are first cast into a machinable processing layer in the metal stream flowing into the mold.

Nach dem unmittelbar erfolgenden Eingießen der mit synthetischen Hartstoffen beaufschlagten Metallschmelze in die Schleudergußkokille wird zur Fertigstellung des Gußkörpers der Gießvorgang kontinuierlich mit reiner Metallschmelze fortgesetzt.After the immediate pouring of the metal melt charged with synthetic hard materials into the centrifugal casting mold, the casting process is continued continuously with pure metal melt to complete the casting.

Zur Beaufschlagung mit synthetischen Hartstoffen eignen sich vorzugsweise Metallschmelzen, die aus legiertem oder unlegiertem Stahl- oder Grauguß, reinen Nichteisenmetallen, wie Cobalt und Nickel oder aus einer Nickel- oder Cobaltbasislegierung bestehen.Metal melts composed of alloyed or unalloyed steel or gray cast iron, pure non-ferrous metals such as cobalt and nickel or of a nickel or cobalt-based alloy are preferably suitable for the application of synthetic hard materials.

Ferner ist die Injektion von Karbiden der Elemente Mo, Nb, Ta, V, W und Zr in die Metallschmelze, insbesondere wegen ihrer hohen Dichte und niedrigen Lösungsgeschwindigkeit, vorteilhaft. Diese werden aufgrund der beim Schleudergießen auftretenden hohen Zentrifugalbeschleunigung radial durch die Schmelze in Richtung Kokillenwand transportiert und reichern sich im Gußkörper vor der äußeren Bearbeitungsschicht an. Zur Injektion der in die Kokille einströmenden Metallschmelze können auch sehr harte und in Metallschmelzen nur langsam lösliche Boride, Oxide und Karbide geringer Dichte, wie TiB₂, Al₂O₃, TiO₂, B₄C, TiC verwendet werden, die unter Zuhilfenahme eines anorganischen oder organischen Bindemittels durch Aggromeration mit Metallen und/oder Karbiden hoher Dichte, wie Co, Ni, Ta, W, TaC, W₂C, WC, verbunden sind.Furthermore, the injection of carbides of the elements Mo, Nb, Ta, V, W and Zr into the molten metal is advantageous, in particular because of their high density and low dissolution rate. Due to the high centrifugal acceleration occurring during centrifugal casting, these are transported radially through the melt towards the mold wall and accumulate in the cast body in front of the outer processing layer. For the injection of the molten metal flowing into the mold, very hard and only slowly soluble borides, oxides and carbides of low density, such as TiB₂, Al₂O₃, TiO₂, B₄C, TiC, can be used, which with the aid of an inorganic or organic binder by aggromeration with Metals and / or high density carbides, such as Co, Ni, Ta, W, TaC, W₂C, WC, are connected.

Aufgrund der Anbindung von Hartstoffen niedriger Dichte an metallische Elemente und/oder Karbide hoher Dichte werden diese "beschwert" und lassen sich zur Bewehrung der Kokillenwand gegenüberliegenden äußeren Oberfläche des Gußkörpers verwenden. Ferner können, durch den Einsatz derartig vorbehandelter Hartstoffe, deren Einbindung im erstarrten Gußteil verbessert und verschleißfeste Hartstoff-­Mischphasen während des Gießvorganges erzeugt werden.Due to the binding of hard materials of low density to metallic elements and / or carbides of high density, these are "weighed down" and can be used to reinforce the outer surface of the cast body opposite the mold wall. Furthermore, by using such pretreated hard materials, their integration in the solidified casting can be improved and wear-resistant hard material mixing phases can be generated during the casting process.

Die mit der Erfindung erzielten Vorteile bestehen insbesondere darin, daß der Gießprozeß zur Herstellung eines Hartstoff-Metallverbundes in kontinuierlicher und einfacher, kostengünstiger Weise erfolgt sowie die Verteilung, Zusammensetzung, Konzentration und Tiefe der Hartstoffe im Schleudergußkörper reproduzierbar eingestellt werden kann.The advantages achieved by the invention are, in particular, that the casting process for producing a hard material-metal composite takes place in a continuous and simple, inexpensive manner and that the distribution, composition, concentration and depth of the hard materials in the centrifugal casting body can be adjusted reproducibly.

Hierdurch lassen sich u.a. der Aufwand zur Fertigbearbeitung des Gußteiles erheblich reduzieren und die Eigenschaften des Hartstoff-Metallverbundes gezielt beeinflussen. Daher ist erstmals in wirtschaftlicher und reproduzierbarer Weise das Herstellen eines verschleißbeständigen Hartstoff-­Metallverbundes im Schleudergußverfahren (Vertikal- und Horizontal-Schleuderguß) zur verschleißfesten Panzerung von großen und teuren Bauteilen, wie z.B. Walzen, Rollen, möglich. Außerdem können auch sehr harte Boride, Oxide und Karbide zur Bewehrung der äußeren, der Kokillenwand zugekehrten Oberfläche des Gußkörpers zum Einsatz kommen.This allows, among other things, considerably reduce the effort required for finishing the cast part and specifically influence the properties of the hard metal-metal composite. It is therefore the first time in an economical and reproducible manner to manufacture a wear-resistant hard metal composite using the centrifugal casting method (vertical and horizontal centrifugal casting) for wear-resistant armouring of large and expensive components, e.g. Rolling, rolling, possible. In addition, very hard borides, oxides and carbides can be used to reinforce the outer surface of the cast body facing the mold wall.

Die Erfindung wird im folgenden unter Bezugnahme auf die Zeichnung näher beschrieben.
Es zeigt Fig. 1 die schaubildliche Darstellung des erfindungsgemäßen Verfahrens zum kontinuierlichen Herstellen eines verschleißbeständigen Hartstoff-Metallverbundes durch Schleudergießen (hier: Horizontal-Schleuderguß).
The invention is described in more detail below with reference to the drawing.
1 shows the diagrammatic representation of the method according to the invention for the continuous production of a wear-resistant hard material-metal composite by centrifugal casting (here: horizontal centrifugal casting).

Die Schleudergußkokille 1 wird zunächst durch die Antriebsrollen 2 in eine Drehbewegung um ihre Symmetrieachse versetzt. Nach dem Erreichen einer für die gleichmäßige Verteilung der Metallschmelze in der Schleudergußkokille 1 ausreichend hohen Drehgeschwindigkeit wird nach dem üblichen Aufbringen einer Schlichte auf die Kokillenwand (in der Figur nicht gezeigt) reine Metallschmelze 3 aus der Gießpfanne 4 durch die Gießvorrichtung 5 in die kalte Schleudergußkokille 1 gegossen. Durch die hohe Wärmeabfuhr, bedingt durch die kalte Schleudergußkokille 1, erstarrt unmittelbar eine ca. 5 - 15 mm starke Bearbeitungsschicht 6. Nach Fertigstellung des Gußstückes kann die spanhebende Bearbeitung dieser Schicht, die auf den Gießprozeß und die Kokillenkontur zurückzuführenden Fertigungstoleranzen ausgeglichen werden. Mit Hilfe einer Fördereinrichtung 7 (hier nach dem Prinzip einer Wirbelbett-Fördereinrichtung) werden nun mit einem inerten Schutzgas als Träger- bzw. Fördergas 8, vorzugsweise Argon, feste pulverförmige und/oder körnige Hartstoffe 9 durch eine Öffnung 10 in der Gießvorrichtung 5, in der Nähe der Schleudergußkokille 1, in den die Gießvorrichtung 5 durchfließenden Metallstrom injiziert. Die Dosierung der Hartstoffe erfolgt in einfacher Weise durch Einstellung des Trägergasdruckes. Nach Beaufschlagung der Metallschmelze mit synthetischen Hartstoffen 11 wird der Gießvorgang durch Unterbrechung der Pulverzufuhr mit reiner Metallschmelze 12 bis zur Fertigstellung des Gußteiles fortgesetzt.The centrifugal casting mold 1 is first set in rotation by its drive rollers 2 about its axis of symmetry. After reaching a sufficiently high rotational speed for the uniform distribution of the molten metal in the centrifugal casting mold 1, after the usual application of a size to the mold wall (not shown in the figure), pure molten metal 3 from the ladle 4 through the casting device 5 into the cold centrifugal casting mold 1 poured. Due to the high heat dissipation caused by the cold centrifugal casting mold 1, an approx. 5 - 15 mm thick processing layer 6 solidifies immediately of the casting, the machining of this layer, the manufacturing tolerances attributable to the casting process and the mold contour can be compensated for. With the aid of a conveying device 7 (here according to the principle of a fluidized bed conveying device), solid powdery and / or granular hard materials 9 are now passed through an opening 10 in the casting device 5 with an inert protective gas as carrier or conveying gas 8, preferably argon the vicinity of the centrifugal casting mold 1 into which the metal stream flowing through the casting device 5 is injected. The hard materials are metered in a simple manner by adjusting the carrier gas pressure. After the metal melt has been subjected to synthetic hard materials 11, the casting process is continued by interrupting the powder supply with pure metal melt 12 until the casting is finished.

Fig. 2 zeigt beispielhaft einen Querschnitt durch eine nach dem entwickelten Verfahren gegossene Walze mit einer Bearbeitungsschicht aus Stahlguß 13, einer verschleißbeständigen Schicht 14 aus Stahlguß mit eingebetteten synthetischen Hartstoffen 15 und einen Kern aus Stahlguß 16.2 shows an example of a cross section through a roller cast according to the developed method with a processing layer made of cast steel 13, a wear-resistant layer 14 made of cast steel with embedded synthetic hard materials 15 and a core made of cast steel 16.

Claims (6)

1. Verfahren zum kontinuierlichen Herstellen eines verschleißbeständigen Hartstoff-Metallverbundes durch Schleudergießen, dadurch gekennzeichnet, daß feste pulverförmige und/oder körnige synthetische metallische und/oder nichtmetallische Hartstoffe während des Eingießens der Metallschmelze in eine um ihre Symmetrieachse rotierende Schleudergußkokille mit Hilfe einer Fördereinrichtung unter Verwendung eines inerten Fördergases zeitweise in den in die Kokille einfließenden Metallstrom injiziert werden.1. A method for the continuous production of a wear-resistant hard metal composite by centrifugal casting, characterized in that solid powdery and / or granular synthetic metallic and / or non-metallic hard materials during the pouring of the molten metal into a centrifugal casting mold rotating around its axis of symmetry with the aid of a conveyor using a inert production gas are temporarily injected into the metal stream flowing into the mold. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß vor der Zugabe von festen synthetischen Hartstoffen in den in die Kokille einfließenden Metallstrom zunächst eine spanbare Bearbeitungsschicht gegossen wird.2. The method according to claim 1, characterized in that before the addition of solid synthetic hard materials into the metal stream flowing into the mold, a machinable processing layer is first cast. 3. Verfahren nach Anspruch 1 - 2, dadurch gekennzeichnet, daß nach dem Eingießen der mit synthetischen Hartstoff beaufschlagten Metallschmelze in die Schleudergußkokille der Gießvorgang mit reiner Metallschmelze kontinuierlich fortgesetzt wird.3. The method according to claim 1-2, characterized in that after the pouring of the synthetic molten metal melt in the centrifugal casting mold, the casting process is continued with pure metal melt. 4. Verfahren nach Anspruch 1 - 3, dadurch gekennzeichnet, daß die Metallschmelze aus legiertem oder unlegiertem Stahl- oder Grauguß, reinen Nichteisenmetallen, wie Cobalt und Nickel oder aus einer Nickel- oder Cobaltbasislegierung besteht.4. The method according to claim 1-3, characterized in that the molten metal consists of alloyed or unalloyed steel or gray cast iron, pure non-ferrous metals such as cobalt and nickel or of a nickel or cobalt-based alloy. 5. Verfahren nach Anspruch 1 - 4, dadurch gekennzeichnet, daß vorzugsweise zur Injektion in die Metallschmelze Karbide der Elemente Mo, Nb, Ta, V, W und Zr verwendet werden.5. The method according to claim 1-4, characterized in that carbides of the elements Mo, Nb, Ta, V, W and Zr are preferably used for injection into the molten metal. 6. Verfahren nach Anspruch 1 - 5, dadurch gekennzeichnet, daß zur Injektion der in die Kokille einströmenden Metallschmelze Boride, Oxide und Karbide geringer Dichte, wie TiB₂, Al₂O₃, TiO₂, B₄C, TiC, verwendet werden, die unter Zuhilfenahme eines anorganischen oder organischen Bindemittels durch Agglomeration mit Metallen und/oder Karbiden hoher Dichte, wie Co, Ni, Ta, W, TaC, W₂C, WC, verbunden sind.6. The method according to claim 1-5, characterized in that for the injection of the molten metal flowing into the mold borides, oxides and carbides of low density, such as TiB₂, Al₂O₃, TiO₂, B₄C, TiC, are used, with the aid of an inorganic or organic Binder by agglomeration with metals and / or high density carbides, such as Co, Ni, Ta, W, TaC, W₂C, WC, are connected.
EP88121821A 1988-03-08 1988-12-29 Method for continuously producing a wear resistant metal-hard material composite by centrifugal casting Expired - Lifetime EP0335012B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88121821T ATE89205T1 (en) 1988-03-08 1988-12-29 PROCESS FOR THE CONTINUOUS MANUFACTURE OF A WEAR-RESISTANT HARD MATERIAL-METAL COMPOSITE BY CENTRAL CASTING.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3807512 1988-03-08
DE3807512A DE3807512A1 (en) 1988-03-08 1988-03-08 METHOD FOR CONTINUOUSLY PRODUCING A WEAR-RESISTANT CARBIDE-METAL COMPOSITE BY SPIN CASTING

Publications (2)

Publication Number Publication Date
EP0335012A1 true EP0335012A1 (en) 1989-10-04
EP0335012B1 EP0335012B1 (en) 1993-05-12

Family

ID=6349121

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88121821A Expired - Lifetime EP0335012B1 (en) 1988-03-08 1988-12-29 Method for continuously producing a wear resistant metal-hard material composite by centrifugal casting

Country Status (4)

Country Link
EP (1) EP0335012B1 (en)
AT (1) ATE89205T1 (en)
DE (2) DE3807512A1 (en)
ES (1) ES2042706T3 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0379400A1 (en) * 1989-01-16 1990-07-25 Les Bronzes D'industrie Apparatus for manufacturing composite materials by centrifugation
WO2001045879A1 (en) * 1999-12-20 2001-06-28 Dochernee Predpriyatie Nexus Proizvodstvenno-Kommercheskaya Kompaniya Method for centrifugal casting of blanks for rollers used in machines for continuous casting of blanks
RU2443505C1 (en) * 2010-10-06 2012-02-27 Государственное образовательное учреждение высшего профессионального образования "Южно-Уральский государственный университет" (ГОУ ВПО "ЮУрГУ") Method of producing steel tube billets
WO2012048919A1 (en) * 2010-10-13 2012-04-19 Federal-Mogul Burscheid Gmbh Method for producing a piston ring having embedded particles
RU2643850C1 (en) * 2016-12-12 2018-02-06 Федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ (НИУ)") Method for producing thin-walled tube blank
RU2647975C1 (en) * 2016-12-12 2018-03-21 федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ" (НИУ)") Method of producing cast steel by centrifugal casting
RU2742093C1 (en) * 2020-07-30 2021-02-02 Федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" ФГАОУ ВО "ЮУрГУ (НИУ)" Method of producing steel tubing billet with high radiation resistance
CN112808966A (en) * 2019-11-15 2021-05-18 丰田自动车株式会社 Casting device

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT412074B (en) * 2002-09-16 2004-09-27 Bernhard Dr Feistritzer Producing ferrous castings with rotation symmetry, e.g. rolling mill and crusher roller mantles etc., has a mold to take the molten metal and which rotates around an axis with a defined centrifugal acceleration
CN101954466B (en) * 2010-11-02 2015-09-02 北京中煤矿山工程有限公司 Centrifugal casting process for shell of bimetal compound metallurgical wedge hob
DE102017208000A1 (en) * 2017-05-11 2018-11-15 Mahle International Gmbh Method for producing an engine block
CN114210943B (en) * 2021-12-28 2023-03-14 马鞍山市海天重工科技发展有限公司 Pouring production process for arc lining plate of discharge door

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE861005C (en) * 1944-09-07 1952-12-29 Gussstahlwerk Bochumer Ver Ag Process for the formation of pore-free and crack-free surfaces of a hollow body cast by centrifugal casting
US2681260A (en) * 1951-07-27 1954-06-15 Norton Co Cylinder and liner

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE861005C (en) * 1944-09-07 1952-12-29 Gussstahlwerk Bochumer Ver Ag Process for the formation of pore-free and crack-free surfaces of a hollow body cast by centrifugal casting
US2681260A (en) * 1951-07-27 1954-06-15 Norton Co Cylinder and liner

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN, Band 6, Nr. 150 (M-148)[1028], 10. August 1982; & JP-A-57 070 075 (KUBOTA TEKKO K.K.) 30-04-1982 *
PATENT ABSTRACTS OF JAPAN, Band 7, Nr. 79 (M-204)[1224], 31. März 1983; & JP-A-58 006 769 (KUBOTA TEKKO K.K.) 14-01-1983 *
PATENT ABSTRACTS OF JAPAN, Band 9, Nr. 286 (M-429)[2009], 13. November 1985; & JP-A-60 127 067 (KUBOTA TEKKO K.K.) 06-07-1985 *
SOVIET INVENTIONS ILLUSTRATED, Teil CH, Woche D11, 22. April 1981, Klasse M22, Nr. 18954 D/11, Derwent Publications Ltd, London, GB; & SU-A-595 579 (AS UKR CASTING PROB) 30.06.1980 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0379400A1 (en) * 1989-01-16 1990-07-25 Les Bronzes D'industrie Apparatus for manufacturing composite materials by centrifugation
WO2001045879A1 (en) * 1999-12-20 2001-06-28 Dochernee Predpriyatie Nexus Proizvodstvenno-Kommercheskaya Kompaniya Method for centrifugal casting of blanks for rollers used in machines for continuous casting of blanks
RU2443505C1 (en) * 2010-10-06 2012-02-27 Государственное образовательное учреждение высшего профессионального образования "Южно-Уральский государственный университет" (ГОУ ВПО "ЮУрГУ") Method of producing steel tube billets
WO2012048919A1 (en) * 2010-10-13 2012-04-19 Federal-Mogul Burscheid Gmbh Method for producing a piston ring having embedded particles
JP2013540969A (en) * 2010-10-13 2013-11-07 フェデラル−モーグル ブルシェイド ゲーエムベーハー Manufacturing method of particle-embedded piston ring
US9174276B2 (en) 2010-10-13 2015-11-03 Federal-Mogul Burscheid Gmbh Method of producing a piston ring having embedded particles
RU2643850C1 (en) * 2016-12-12 2018-02-06 Федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ (НИУ)") Method for producing thin-walled tube blank
RU2647975C1 (en) * 2016-12-12 2018-03-21 федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ" (НИУ)") Method of producing cast steel by centrifugal casting
CN112808966A (en) * 2019-11-15 2021-05-18 丰田自动车株式会社 Casting device
RU2742093C1 (en) * 2020-07-30 2021-02-02 Федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" ФГАОУ ВО "ЮУрГУ (НИУ)" Method of producing steel tubing billet with high radiation resistance

Also Published As

Publication number Publication date
ATE89205T1 (en) 1993-05-15
ES2042706T3 (en) 1993-12-16
EP0335012B1 (en) 1993-05-12
DE3807512A1 (en) 1989-09-21
DE3881029D1 (en) 1993-06-17

Similar Documents

Publication Publication Date Title
EP0335012B1 (en) Method for continuously producing a wear resistant metal-hard material composite by centrifugal casting
DE3937526C2 (en) Wear-resistant titanium alloy, process for its production and its use
EP0123961B1 (en) Abrasion-resistant composite article and process for its manufacture
DE2919477C2 (en) Wear-resistant composite material, method for its manufacture and use of the composite material
DE1783134A1 (en) Process for the production of hard alloys
DE2227043A1 (en) ONE-PIECE RING IN ONE-PIECE METAL OF DIFFERENT COMPOSITION AND METHOD OF MANUFACTURING IT
DE2440042A1 (en) ARRANGEMENT FOR FILLING METAL MELT
DE3214552A1 (en) CASTING PART WITH WEAR-RESISTANT PRESSELS AND METHOD FOR THE PRODUCTION THEREOF
DE2335588C3 (en) PROCESS FOR MANUFACTURING METALLIC COMPOSITE CASTINGS
DE2501370C3 (en) Process for the production of cast iron machine parts with surfaces subject to friction and high wear resistance
DE10210001A1 (en) Method and device for the precision investment casting of components made of non-ferrous metal alloys and non-ferrous metal alloys for carrying out the method
DD293754A5 (en) METHOD FOR PRODUCING PARTICULARLY WEAR-PROOFED CASTINGS
DE2812650A1 (en) WEAR-RESISTANT AND CORROSION-RESISTANT ALLOY
DE3807347A1 (en) Shaped body consisting of a plurality of metal layers and method for its production
DE3339118C2 (en) Process for the production of metal blocks with embedded hard material grains
DE4112000A1 (en) Wear resistant castings - formed by diffusive or penetrative coating by hard materials in casting process
EP1622734B1 (en) Method for centrifugal casting
DE3910603C2 (en)
DE2233148B2 (en) Process for the production of centrifugal castings from alloyed materials with wear-resistant surfaces
DE19901170B4 (en) Use of an iron base age alloy
DE3816348A1 (en) Method for the production of composite metal castings
EP0141966B1 (en) Process for centrifugal casting
DE3424022C2 (en)
JPS586769A (en) Cylindrical or columnar abrasion resistant casting and its production
DE2947393C2 (en) Method for producing a cemented carbide-cast steel composite body

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FR GB IT LI LU NL SE

17P Request for examination filed

Effective date: 19900222

17Q First examination report despatched

Effective date: 19900822

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: BUSSE, KARL-HERMANN

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE ES FR GB IT LI LU NL SE

REF Corresponds to:

Ref document number: 89205

Country of ref document: AT

Date of ref document: 19930515

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3881029

Country of ref document: DE

Date of ref document: 19930617

ITF It: translation for a ep patent filed

Owner name: STUDIO JAUMANN

ET Fr: translation filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19930708

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2042706

Country of ref document: ES

Kind code of ref document: T3

EPTA Lu: last paid annual fee
EAL Se: european patent in force in sweden

Ref document number: 88121821.8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19951010

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 19951025

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19951027

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19951031

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19951122

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19951228

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19951230

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19960104

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19961229

Ref country code: AT

Effective date: 19961229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19961230

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 19961230

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19961231

Ref country code: CH

Effective date: 19961231

Ref country code: BE

Effective date: 19961231

BERE Be: lapsed

Owner name: BUSSE KARL-HERMANN

Effective date: 19961231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19970701

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19961229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19970829

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19970701

EUG Se: european patent has lapsed

Ref document number: 88121821.8

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 19980119

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19980225

Year of fee payment: 10

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19981229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19991001

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20010301

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20051229

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT