EP0328516A1

EP0328516A1 - Method and equipment for the production of particularly finely divided dry powders

Info

Publication number: EP0328516A1
Application number: EP19870900144
Authority: EP
Inventors: Pertti Ovaskainen; Jouko Niemi
Original assignee: Finnpulva Oy AB; Larox Oyj
Current assignee: Finnpulva Oy AB; Outotec Filters Oy
Priority date: 1986-09-10
Filing date: 1986-11-26
Publication date: 1989-08-23
Also published as: AU6727587A; WO1988001906A1; DK253788A; ES2003950A6; DK253788D0

Abstract

Le procédé et l'équipement décrits servent à produire des poudres sèches particulièrement fines à partir d'un matériau d'entrée composé de particules plus grossières et au moyen d'un broyeur à jet (2) pourvu d'un alimentateur mécanique (1). Dans ce procédé, le jet, composé d'un gaz de travail et de particules solides, sortant du broyeur à jet (2) passe dans un trieur centrifuge (3), dans lequel on sépare le matériau fin et le matériau grossier l'un de l'autre, afin de remettre en circulation le matériau grossier dans l'alimentateur (1) du broyeur à jet et de faire passer le matériau fin dans le système de séparation (4) pour produits fins. La présente invention se caractérise par le fait que le matériau d'entrée passe du silo d'alimentation (5) dans un broyeur mécanique (6), ce qui permet de produire des microfissures dans les particules du matériau d'entrée et de broyer plus rapidement les particules broyées, puis par le fait que le matériau d'entrée ayant traversé le broyeur mécanique (6) repasse dans un trieur centrifuge (3), ce qui permet de séparer du matériau restant toute substance affinée présente dans le matériau d'entrée avant que ce dernier ne soit acheminé dans l'alimentateur (1) du broyeur à jet.The process and the equipment described serve to produce particularly fine dry powders from an input material composed of coarser particles and by means of a jet mill (2) provided with a mechanical feeder (1) . In this process, the jet, composed of a working gas and solid particles, leaving the jet mill (2) passes through a centrifugal sorter (3), in which the fine material and the coarse material are separated. on the other, in order to recirculate the coarse material in the feeder (1) of the jet mill and to pass the fine material through the separation system (4) for fine products. The present invention is characterized by the fact that the input material passes from the feed silo (5) into a mechanical mill (6), which makes it possible to produce microcracks in the particles of the input material and to crush more quickly crushed particles, then by the fact that the input material having passed through the mechanical mill (6) passes through a centrifugal sorter (3), which makes it possible to separate from the remaining material any refined substance present in the input material before the latter is routed into the feeder (1) of the jet mill.

Description

Method and equipment for the production of particularly finely divided dry powders

The subject of the present invention is a method and an equipment for the production of particu¬ larly finely divided dry powders out of an input material consisting of coarser particles by means of a jet grinder provided with a mechanical feeder. In this method, the solids/working-gas jet rushing out of the jet grinder is passed into a centrifugal classifier, wherein the fine material and the coarse material are separated from each other in view of recirculating the coarse material into the feeder of the jet grinder and passing the fine material into the separation system for fine product. In jet grinding, the input material to be ground is fed by means of a mechanical feeder, such as a twin-valve feeder, to among the pressurized working gas so as to be fluidized. The working-gas/solids mix produced is divided into two or more component flows, and these component flows are accelerated through conically arranged accelerating nozzles to such a high velocity, preferably about 300 m/s, that a maximum amount of particles coming out of the different nozzles are broken into fine product when colliding against each other, which said fine product can be separated by a sharp classification from the coarse fraction to be recirculated to among the original input material of the jet grinder.

It is an essential problem of the jet grinder technology that the input material is highly unhomo- geneous, containing an abundance of oversize particles and also an abundance of very small particles. This is why it is very difficult to control the grinding pro¬ cess. Depending on the particle size, different par- tides, viz., require different quantities of energy in order to be accelerated to the desired velocity in the accelerating nozzles of the jet grinder. Since the grinding energy used in jet grinding is introduced in the form of pressurized working gas, such as compressed air, the quantity of energy to be used depends mainly on the working-gas/solids ratio fed into the grinder. Usually the input material contains some proportion of ready fine product right from the beginning, so that this proportion also requires its share of the energy contained in the compressed air in being acceler¬ ated to the velocity used in grinding and, moreover, the volume weight of this fine product proportion is low, so that this fact also makes it more difficult to produce a correct working-gas/solids ratio in the input of the jet grinder. The input material always also contains some amount of oversize particles, which require an un- reasonable amount of energy to be accelerated to the velocity required in the grinding. Since a sufficiently high velocity is mostly not achieved, these oversize particles are gathered in the circulation between the classifier and the jet grinder and hamper the feeding of new input material into the process.

The object of the present invention is to eliminate the problems described above and to provide an optimal particle size for the input material fed into the jet grinder, so that the overall energy consumption of the process is lowered at the same time as the grind¬ ing result is improved. This has been achieved by means of a method which is characterized in that the input material is passed from the feed silo into a mechanical crusher so as to produce microfissures in the particles of the input material and to grind more readily ground particles, and that the input material that has passed through the mechanical crusher is passed further into a centrifugal classifier so as to separate any ready fine material present in the input material from the rest of the material before the input material is fed into the feeder of the jet grinder. In the method in accordance with the invention, microfissures and cracks are formed by means of the mechanical crusher into the solid particles of the input material, the particles being ground readily at the said fissures and cracks in the grinding stage taking place in the jet grinder and based on collision. More¬ over, any oversize particles are crushed to the input particle size optimal for jet grinding. In the centri¬ fugal classifier following after the crusher, all fine material present in the input material is separated before the input material is fed into the jet grinder. Thus, the input material fed into the jet grinder con¬ sists of particles belonging to a very narrow range of particle size. The particle size aimed at is small enough so that it can be accelerated with good efficiency to the velocity required in jet grinding but, however, large enough so that it can no longer be retarded before the collision at the outlet side of the acceler¬ ating nozzles as the flow velocity of the working gas is changed.

The other characteristics of the invention come out from the attached claims 1 to 15.

In the following, the invention will be de¬ scribed in more detail with the aid of an example, reference being made to the attached drawing, wherein

Figure 1 illustrates the grinding of a par¬ ticle to fine product in accordance with a recommended embodiment of the invention,

Figure 2 shows the construction of principle of a pregrinding or autogenous pocket used in connection with pneumatic conveyance,

Figure 3 shows an example of a complete set of equipment used for carrying out the invention as a flow diagram, and Figure 4 shows a second example of an equip¬ ment used for carrying out the invention, wherein the pre-crushing and the fine-product separation are omitted. In the method in accordance with the invention, particularly finely divided powders are produced out of an input material consisting of coarser particles by means of a jet grinder 2 provided with a mechanical feeder 1. Preferably a jet grinder 2 provided with a twin-valve feeder 1 is used, such as a pressure chamber grinder. The material ground in the jet grinder 2 by means of working-gas/solids jets colliding against each other is passed along with the working-gas flow into a centrifugal classifier 3, wherein the coarse material and the fine material are separated from each other. The fine material is passed into the fine-product sepa¬ ration system 4, and the coarse material is passed back into the feeder 1 of the jet grinder. The input material is passed from a feed silo 5 of the equipment into a mechanical crusher 6 , wherein the largest and the most readily ground particles are crushed and microfissures are formed into harder particles, which remain uncrushed, the said particles being ground readily at the fissures in the treatment in the jet grinder. The input mate¬ rial which has passed through the mechanical crusher and which has been ground partly is passed further into the centrifugal classifier 3 so as to separate any ready fine material present in the input material from the rest of the material before the input material is passed into the feeder 1 of the jet grinder.

New input material is usually supplied to the equipment by means of a tank vehicle 17. The tank vehicle 17 is unloaded into the feed silo 5 of the equipment by means of a pneumatic conveyor line 12. According to a preferred embodiment, an accelerating nozzle 13 is provided at the outlet end of the pneumatic conveyor line 12, which said nozzle ends in an autogenous pocket 7 provided at the upper end of the feed silo 5. By means of this solution, input material can already be pre-crushed partly in connection with the unloading of the tank vehicle 17. The input material is acceler- ated in the accelerating nozzle 13 installed at the final end of the pneumatic conveyor line 12 so that a maximum proportion of the energy contained in the com¬ pressed air is converted to kinetic energy of the par- tides, whereupon the particles are made to collide against each other in the autogenous pocket 7 mounted after the accelerating nozzle 13. The velocity of the material-gas flow rushing into the autogenous pocket 7 is preferably of an order of 20 to 100 m/s. The rear or impact face 7a of the autogenous pocket 7 is preferably shaped so that it gives the material-gas flow rushing into the autogenous pocket 7 a loop-shaped flow path, as is indicated by an arrow in Fig. 2, whereby, on their way out of the autogenous pocket, the material particles are forced into the path of the material jet coming into the autogenous pocket 7. In this pre- crushing stage, a grinding on the macro level takes place, whereby any loose bonds in large particles are broken and any cracks and flaws in the particles become larger by the effect of collisions. The grinding taking place in the autogenous pocket 7 can be intensified by feeding additional material into the autogenous pocket into its collision zone from above the pocket, whereby the probability of collision is increased. The addi- tional material may, for example, consist of such oversize fraction as has been screened off the input material before the mechanical crusher because of its size that is excessively large for the crusher.

In connection with the pneumatic conveyance, the feed material can be dried at the same time by means of the energy produced in the pressurization of the com¬ pressed air. If a sufficient amount of heat is not obtained from the compressing, additional heating of the compressed air must be used, e.g. by superheating it under pressure.

In the fine-product separation system 4, the fine material is separated from the working gas by means of a pneumatic cyclone (8) into two fractions of differ¬ ent types, one of which contains the particles smaller than the separation limit but, yet, close to the said limit, and the other one contains the superfine par- tides, which have a large surface area in relation to their weight.

In the preferred embodiment of the invention, the mechanical crusher 6 is a roll crusher, in which the speed of rotation of the rolls may be about 5 to 10 m/s. An equipment that includes a roll crusher 6 is shown in Fig. 3. The input material introduced into the feed silo 5 is fed at a uniform speed into the roll crusher 6, e.g., by means of a closing feeder installed at the outlet opening 5b of the feed silo. By the effect of the rolls of the roll crusher 6, the oversize particles in the input material are broken, and micro- fissures are formed in the particles that are not broken. After the crushing treatment, the input material is passed along the outlet duct 6a of the roll crusher into the centrifugal classifier 3, wherein the fine material and the coarse material contained in the input material are separated from each other. The coarse material is passed along the duct 10 into a multicyclone 15, wherein the coarse material is separated from the working gas. The working gas, usually compressed air, is passed along the duct 15a to the outlet duct 11 for the fine- product fraction coming from the centrifugal classifier 3, which said duct ends in the fine-product separation system 4, and the coarse product is fed into the hydraulically operated twin-valve feeder 1 of the jet grinder, e.g., by means of a closing feeder 18 mounted at the bottom of the multicyclone 15. Thus, the multi¬ cyclone 15 must be dimensioned so that fractions coarser than the separation limit of the classification cannot pass along with the working gas into the fine product. The operation of the twin valve 1 is described, e.g. in the published International Patent Application WO86/02287. In the twin-valve feeder 1 , the input material is pressurized and dropped batchwise into the equalizing tank 19 of the jet grinder equipment, from where it is passed by means of a hydraulically operated screw feeder at a controlled speed into the fluidization space 20. In the fluidization space 20 the input material to be ground is mixed with the compressed air coming from the compressor 21 along the duct 22. The fluidized solids- working-gas mixture under high pressure rushes through at least one bisecting device 23 into the substantially conically arranged grinding nozzles in the jet grinder 2, in which said nozzles the material particles are, owing to an expansion of the working gas, accelerated to the velocity (about 300 m/s) required for the col- lision producing the grinding. The material/working-gas mix rushing out of the jet grinder 2 is passed along the outlet duct 9 into the centrifugal classifier 3, from which the fine product produced is passed into the fine-product separation system 4 along the duct 11, and the coarse material remaining after the jet grinding is recirculated into the jet grinder 2 through the multi¬ cyclone 15. The outlet duct 11 ends in the vortex chamber cyclone 8 of the fine-product separation system, in which cyclone there is a vortex tube bottom closed by an intermediate bottom and an adjustable fine-product opening 8a placed at the side of the vortex tube. The vortex chamber cyclone 8 is preferably also provided with tangentially directed openings 8b for additional air, by means of which said openings the classification taking place in the cyclone can be adjusted and intensi¬ fied. The working gas that has been made substantially free from solid matter is passed into a textile filter 16, where the working gas is made free from any super¬ fine product that is remaining in it. The "coarser" proportion of the fine product is passed from the bottom part of the vortex chamber cyclone 8 into a storage silo 24, and its superfine proportion into a storage silo 25, from which said silos 24, 25 the products formed can be measured by means of adjustable feeders to final pro¬ ducts of different properties. All the operations of the equipment are controlled from the control centre 26 of the equipment, and the hydraulically operated members 1 , 19 of the equipment receive their drive power from the hydraulic power source 27.

In the case of some materials, it may be pre¬ ferable to use a two-stage roll crushing, whereat the space between the rolls is larger in the first roll crusher than in the second roll crusher.

If a rotor crusher is used as the mechanical crusher 6, as is shown in Fig. 4, the input material is passed onto the breaking disc 6b of the rotor crusher through the duct 5a. The breaking disc 6b is driven by and electric motor 6c. The breaking disc 6b flings the particles of the input material against the surrounding casing 6d. During the operation of the equipment, -a material bed 6e consisting of the particles to be crushed is gathered .inthe casing 6d, from which bed the particles flung by the breaking disc 4 bounce first diagonally upwards and thereupon, following the face of the bed and of the casing, downwards so that the crushing of the material takes place mainly as the particles collide against each other in the air. The material that re¬ mains coarser in the crusher is lowered by the effect of the force of gravity into the recirculation duct 6f, which recirculates it back into the crusher for repeated crushing treatment. On the contrary, the more finely divided material produced by the crusher rises along with the air flow produced by the crusher up into the duct 6a starting above the breaking disc 6b, which said duct 6a passes into the centrifugal classifier 3, from which the coarse material is passed into the twin-valve feeder 1 of the jet grinder. The outlet duct of the jet grinder 2 is provided with a filter for the sepa¬ ration of the solid matter from the working gas to be passed into the rotor crusher 6, by means of which said working gas the more finely divided material is trans¬ ferred into the centrifugal classifier and the input material is dried. The invention is suitable for the production of almost all powders that are used as fine, of which the most important ones are the binder agents used by the construction industry, paper and plastic fillers, coatings and pigments, as well as various foodstuffs, such as grain and spices. Refining of minerals is also possible by means of the equipment of the invention. Thus, as the input material it is possible to use, for example, blast-furnace slag used for the production of finely divided and very finely divided products which have a large specific area and which are used in the way of cement, the composition of the said slag being close to the burnt clinker used for the manufacture of cement, as well as burnt cement clinker, which is required for the manufacture of cement products used for special purposes. As two fine finished products of highly differ¬ ent types are produced in the apparatus in accordance with the invention, by varying the ratios of these two products, e.g. in the preparation of concrete, it is possible to act upon various properties of the concrete produced in the desired way, such as upon initial and ultimate strength, workability, and water retaining capacity.

Water-granulated slag is also moist after the granulation, so that in connection with its treatment it is suitable to make use of the drying possibility in accordance with the invention in connection with the pneumatic conveyance of the material.

It comes out from the sketch of principle in

Fig. 1 that a large initial particle almost always has cracks, inclusions, pores, and border faces resulting from unhomogeneity of the material, produced either in nature or in earlier processes. It is typical of such sections of discontinuity that the particle is readily broken by the effect of an impact-type strain which is produced in a collision of particles against a solid face or against other particles, as takes place in the autogenous pocket in the equipment of the invention. The remaining parts are either more elastic and more homogeneous or stronger than the particle of starting material. This is why further grinding based on a grinding mechanism of the same type would consume a lot of energy, because the particles concerned have already proved resistant to impacts produced in the pre-crushing. Thus, in the method of the present invention, the next stage in the process is an intermediate crushing based on a compression taking place in an autogenous bed and on the strains produced therein, in which said crushing all oversize particles are forced to be broken into particles not exceeding a certain size, whereby the material is ground partly to completely finished product and partly receives new microfissures into the particles. Owing to these microfissures, the energy consumption in the next stage, which is the jet grinding, is lowered by up to 30 per cent. This has a great importance for the grinding economy in view of the fact that the consumption of energy in the pre-crushing and intermedi- ate crushing is only 1 to 10 kWh/t, whereas the con¬ sumption of energy in the final grinding proper is 50 to 250 kWh/t, in conventional jet grinders even 500 to 1500 kWh/t.

Claims

WHAT IS CLAIMED IS:

1. Method for the production of particularly finely divided dry powders out of an input material con- sisting of coarser particles by means of a jet grinder (2) provided with a mechanical feeder (1), in which said method the solids/working-gas jet rushing out of the jet grinder (2) is passed into a centrifugal classifier (3) , wherein the fine material and the coarse material are separated from each other in view of recirculating the coarse material into the feeder (1) of the jet grinder and passing the fine material into the separation system (4) for fine product, c h a r a c t e r i z e d in that the input material is passed from the feed silo (5) into a mechanical crusher (6) so as to produce micro¬ fissures in the particles of the input material and to grind more readily ground particles, and that the input material that has passed through the .mechanical crusher (6) is passed further into a centrifugal classifier (3) so as to separate any ready fine material present in the input material from the rest of the material before the input material is fed into the feeder (1) of the jet grinder.

2. Method as claimed in claim 1 , c h a r - a c t e r i z e d in that the input material is pre-crushed in connection with the filling of the feed silo (5) in an autogenous pocket (7) by means of the kinetic energy produced in connection with the pneumatic conveyance.

3. Method as claimed in claim 2, c h a r - a c t.e r i z e d in that the input material is dried in connection with the pneumatic conveyance by means of energy produced in the compressing of the compressed air.

4. Method as claimed in claim 3, c h a r - a c t e r i z e d in that in the fine-product separation system (4) , the fine material is separated from the working gas by means of a pneumatic cyclone (8) into two fractions of different types, one of which contains the particles smaller than the separation limit but, yet, close to the said limit, and the other one contains the superfine particles, which have a large surface area in relation to their weight.

5. Method as claimed in any of the preceding claims, c h a r a c t e r i z e d in that by means of the method, binder agents used by the construction industry, paper and plastic fillers, coatings and pigments are manufactured and grain and spices are treated.

6. Equipment for carrying out the method as claimed in claim 1 , which said equipment comprises a jet grinder (2) provided with a mechanical feeder (1) and a centrifugal classifier (3) provided in the outlet duct (9) of the said jet grinder, the duct (10) of the said classifier for the coarse material terminating in the feeder (1) of• the jet grinder and the duct ( 1) for the fine material terminating in the fine-product sepa¬ ration system (4), c h a r a c t e r i z e d in that the equipment further comprises a feed silo (5) and a mechanical crusher (6) connected to the outlet opening (5b) of the said silo, the outlet duct (6a) of the said crusher (6) being directly connected to the centri¬ fugal classifier (3) .

7. Equipment as claimed in claim 6, c h a r a c t e r i z e d in that at the outlet end of the pneumatic conveyor line (12), which operates as the filling system of the feed silo (5) , an accelerating nozzle (13) is provided, which ends in an autogenous pocket (7) provided at the top end of the feed silo (5) .

8. Equipment as claimed in claim 7, c h a r a c t e r i z e d in that the rear or impact face (7a) of the autogenous pocket (7) is shaped so as to give the material-gas flow rushing into the auto- genous pocket (7) a loop-shaped flow path.

9. Equipment as claimed in claim 8, c h a r a c t e r i z e d in that the top wall of the autogenous pocket (7) is provided with an inlet opening (7b) for additional material.

10. Equipment as claimed in claim 9, c h a r a c t e r i z e d in that the mechanical crusher (6) is a roll crusher, in which the speed of rotation of the rolls is about 5 to 10 m/s.

11. Equipment as claimed in claim 9, c h a r a c t e r i z e d in that the mechanical crusher (6) is a rotor crusher, from which the crushed material is arranged so as to pass along with the working-gas flow into the centrifugal classifier (3) .

12. Equipment as claimed in claim 11 , c h a r a c t e r i z e d in that the outlet duct (9) of the jet grinder (2) is provided with a filter (14) for the separation of solid matter from the working gas to be passed into the rotor crusher (6) .

13. Equipment as claimed in claim 10 or 12, c h a r a c t e r i z e d in that a multicyclone (15) is provided in the outlet duct (10) for the coarse-product fraction in the centrifugal classifier (3) for the sepa¬ ration of the air from the coarse product.

14. Equipment as claimed in claim 13, c h a r a c t e r i z e d in that the fine-product separation system (4) provided in the duct (11) for the fine product in the centrifugal classifier (3) comprises a vortex chamber cyclone (8) , which has a vortex-tube bottom closed by an intermediate bottom and an opening for fine product, located at the side of the vortex tube, as well as a textile filter (16) provided in the air exhaust duct of the vortex chamber cyclone (8) .

15. Equipment as claimed in claim 14, c h a r a c t e r i z e d in that the vortex chamber cyclone (8) is provided with tangentially directed openings (8a) for additional air for the purpose of con- trolling and intensifying the classification taking place in the cyclone.