EP0327559A1 - Titanium and zirconium complexes, and fuel compositions. - Google Patents
Titanium and zirconium complexes, and fuel compositions.Info
- Publication number
- EP0327559A1 EP0327559A1 EP87906884A EP87906884A EP0327559A1 EP 0327559 A1 EP0327559 A1 EP 0327559A1 EP 87906884 A EP87906884 A EP 87906884A EP 87906884 A EP87906884 A EP 87906884A EP 0327559 A1 EP0327559 A1 EP 0327559A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- carbon atoms
- formula
- hydrocarbyl
- fuel composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 46
- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 23
- 239000010936 titanium Substances 0.000 title claims abstract description 23
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 150000003754 zirconium Chemical class 0.000 title claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 47
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
- 150000003755 zirconium compounds Chemical class 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 49
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 45
- 229910052739 hydrogen Inorganic materials 0.000 claims 32
- 239000001257 hydrogen Substances 0.000 claims 32
- 125000003118 aryl group Chemical group 0.000 claims 28
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 26
- 125000000217 alkyl group Chemical group 0.000 claims 19
- 150000001412 amines Chemical class 0.000 claims 17
- -1 basic metal salts Chemical class 0.000 claims 17
- 239000002738 chelating agent Substances 0.000 claims 11
- 229920000768 polyamine Polymers 0.000 claims 10
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 10
- 125000002252 acyl group Chemical group 0.000 claims 9
- 125000001931 aliphatic group Chemical group 0.000 claims 9
- 229910052751 metal Inorganic materials 0.000 claims 9
- 239000002184 metal Substances 0.000 claims 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 8
- 125000000753 cycloalkyl group Chemical group 0.000 claims 7
- 150000002576 ketones Chemical class 0.000 claims 7
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 claims 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 6
- 125000001797 benzyl group Chemical class [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 6
- 125000005594 diketone group Chemical group 0.000 claims 6
- 125000000524 functional group Chemical group 0.000 claims 6
- 150000002989 phenols Chemical class 0.000 claims 6
- 229920001281 polyalkylene Chemical group 0.000 claims 6
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 6
- 150000001299 aldehydes Chemical class 0.000 claims 5
- 239000007795 chemical reaction product Substances 0.000 claims 5
- 239000007788 liquid Substances 0.000 claims 5
- 239000002243 precursor Substances 0.000 claims 5
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 5
- 239000004215 Carbon black (E152) Substances 0.000 claims 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical group CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims 4
- 125000003342 alkenyl group Chemical group 0.000 claims 4
- 125000002947 alkylene group Chemical group 0.000 claims 4
- 239000012141 concentrate Substances 0.000 claims 4
- 239000003085 diluting agent Substances 0.000 claims 4
- 239000002816 fuel additive Substances 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 150000002430 hydrocarbons Chemical class 0.000 claims 4
- RMVRSNDYEFQCLF-UHFFFAOYSA-N phenyl mercaptan Natural products SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 claims 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 3
- 150000003573 thiols Chemical class 0.000 claims 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 150000001414 amino alcohols Chemical class 0.000 claims 2
- 125000003277 amino group Chemical group 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 2
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 239000007822 coupling agent Substances 0.000 claims 2
- 150000004985 diamines Chemical class 0.000 claims 2
- 150000002009 diols Chemical class 0.000 claims 2
- 150000004662 dithiols Chemical class 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 150000003460 sulfonic acids Chemical class 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- RSPCKAHMRANGJZ-UHFFFAOYSA-N thiohydroxylamine Chemical compound SN RSPCKAHMRANGJZ-UHFFFAOYSA-N 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 1
- 229910052728 basic metal Inorganic materials 0.000 claims 1
- 239000002283 diesel fuel Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 150000003608 titanium Chemical class 0.000 claims 1
- 101150076749 C10L gene Proteins 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
- C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Definitions
- Priority Country US tent
- NL European patent
- SE European pat
- a method of operating a diesel engine equipped with an exhaust system particulate trap to reduce the build-up o haust particles collected in said trap comprises operating said diesel engine with a fuel containing at least compound selected from titanium or zirconium compounds effective to lower the ignition temperature of the exhaust ticulates collected in said trap.
- Fuel compositions which are useful particularly in the operation of diesel engines equi with exhaust particluate traps wherein the fuel contains at least one titanium or zirconium complex, and certain novel nium and zirconium complexes are described and claimed.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87906884T ATE80175T1 (en) | 1986-10-02 | 1987-09-25 | TATANIUM AND ZIRCONIUM COMPLEXES AND FUEL COMPOSITIONS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US91438286A | 1986-10-02 | 1986-10-02 | |
US914382 | 1992-07-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0327559A1 true EP0327559A1 (en) | 1989-08-16 |
EP0327559B1 EP0327559B1 (en) | 1992-09-02 |
Family
ID=25434285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87906884A Expired - Lifetime EP0327559B1 (en) | 1986-10-02 | 1987-09-25 | Titanium and zirconium complexes, and fuel compositions |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0327559B1 (en) |
JP (1) | JPH02504645A (en) |
AT (1) | ATE80175T1 (en) |
AU (1) | AU605193B2 (en) |
CA (1) | CA1324151C (en) |
DE (1) | DE3781557T2 (en) |
WO (1) | WO1988002392A2 (en) |
ZA (1) | ZA877370B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL100669A0 (en) * | 1991-05-13 | 1992-09-06 | Lubrizol Corp | Low-sulfur diesel fuel containing organometallic complexes |
US5344467A (en) * | 1991-05-13 | 1994-09-06 | The Lubrizol Corporation | Organometallic complex-antioxidant combinations, and concentrates and diesel fuels containing same |
US5360459A (en) * | 1991-05-13 | 1994-11-01 | The Lubrizol Corporation | Copper-containing organometallic complexes and concentrates and diesel fuels containing same |
US5279627A (en) * | 1992-11-06 | 1994-01-18 | The Lubrizol Corporation | Copper-containing aromatic mannich complexes and concentrates and diesel fuels containing same |
US5372613A (en) * | 1993-04-19 | 1994-12-13 | Mekonen; Kenneth | Fuel compositions |
GB9321370D0 (en) * | 1993-10-13 | 1993-12-08 | Exxon Chemical Patents Inc | Fuel additives |
US10100246B2 (en) | 2013-12-11 | 2018-10-16 | Halliburton Energy Services, Inc. | Polysaccharides and metal complexes for viscosity |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2151432A (en) * | 1937-07-03 | 1939-03-21 | Leo Corp | Method of operating internal combustion engines |
FR1159705A (en) * | 1955-08-17 | 1958-07-01 | Titan Gmbh | Organic titanium compounds |
FR1179418A (en) * | 1956-08-07 | 1959-05-25 | Titan Gmbh | Fuel composition and process for obtaining it |
FR1194036A (en) * | 1957-04-01 | 1959-11-06 | Sinclair Refining Co | Improved fuel oils |
US3134737A (en) * | 1960-08-24 | 1964-05-26 | Texaco Inc | Novel titanium compound and lubricating composition containing said compound |
FR1341731A (en) * | 1961-10-05 | 1963-11-02 | Ciba Geigy | Improvements to epoxy resin-based compositions |
US3355270A (en) * | 1963-06-03 | 1967-11-28 | Standard Oil Co | Metal chelate combustion improver for fuel oil |
US3993835A (en) * | 1971-12-15 | 1976-11-23 | Ppg Industries, Inc. | Transition metal oxide complex coupling agents coated on siliceous substrates |
SE7502286L (en) * | 1974-03-11 | 1975-09-12 | Ciba Geigy Ag | |
US3945933A (en) * | 1974-07-31 | 1976-03-23 | Mobil Oil Corporation | Metal complexes of nitrogen compounds in fluids |
US4067698A (en) * | 1975-08-27 | 1978-01-10 | The Lubrizol Corporation | Bridged phenol metal salt-halo carboxylic acid condensate additives for fuels |
DE3008193C2 (en) * | 1980-03-04 | 1982-07-08 | Dynamit Nobel Ag, 5210 Troisdorf | Cold-stable, catalytically effective solution of diisopropoxy-bis (2,4-pentanedionato) -titanium (IV) |
US4505718A (en) * | 1981-01-22 | 1985-03-19 | The Lubrizol Corporation | Organo transition metal salt/ashless detergent-dispersant combinations |
CA1187285A (en) * | 1981-08-25 | 1985-05-21 | Nicholas Feldman | Zirconium additives for residual fuel oil |
NO824020L (en) * | 1982-04-22 | 1983-10-24 | Key Fries Inc | ZIRKONATFORTYKNINGSMIDLER. |
NO824042L (en) * | 1982-04-22 | 1983-10-24 | Key Fries Inc | BISALKYL-BIS (trialkanolamine) zirconate. |
EP0167857B1 (en) * | 1984-06-30 | 1988-09-28 | Hüls Aktiengesellschaft | Titan(iv)-acetyl acetonates |
-
1987
- 1987-09-25 DE DE8787906884T patent/DE3781557T2/en not_active Expired - Fee Related
- 1987-09-25 AT AT87906884T patent/ATE80175T1/en active
- 1987-09-25 WO PCT/US1987/002495 patent/WO1988002392A2/en active IP Right Grant
- 1987-09-25 EP EP87906884A patent/EP0327559B1/en not_active Expired - Lifetime
- 1987-09-25 AU AU80786/87A patent/AU605193B2/en not_active Ceased
- 1987-09-25 JP JP62506218A patent/JPH02504645A/en active Pending
- 1987-09-30 CA CA000548283A patent/CA1324151C/en not_active Expired - Fee Related
- 1987-09-30 ZA ZA877370A patent/ZA877370B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO8802392A3 * |
Also Published As
Publication number | Publication date |
---|---|
EP0327559B1 (en) | 1992-09-02 |
WO1988002392A3 (en) | 1988-04-21 |
WO1988002392A2 (en) | 1988-04-07 |
DE3781557T2 (en) | 1993-03-18 |
ZA877370B (en) | 1988-06-29 |
JPH02504645A (en) | 1990-12-27 |
ATE80175T1 (en) | 1992-09-15 |
AU605193B2 (en) | 1991-01-10 |
CA1324151C (en) | 1993-11-09 |
DE3781557D1 (en) | 1992-10-08 |
AU8078687A (en) | 1988-04-21 |
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