EP0317008A1 - Drum with sealed folded seam - Google Patents
Drum with sealed folded seam Download PDFInfo
- Publication number
- EP0317008A1 EP0317008A1 EP88202533A EP88202533A EP0317008A1 EP 0317008 A1 EP0317008 A1 EP 0317008A1 EP 88202533 A EP88202533 A EP 88202533A EP 88202533 A EP88202533 A EP 88202533A EP 0317008 A1 EP0317008 A1 EP 0317008A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filament
- drum
- curvature
- preliminary
- flange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004033 plastic Substances 0.000 claims abstract description 12
- 229920003023 plastic Polymers 0.000 claims abstract description 12
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000007789 sealing Methods 0.000 claims abstract description 8
- 239000010959 steel Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000003566 sealing material Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 238000004826 seaming Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 4
- 238000003780 insertion Methods 0.000 description 4
- 230000037431 insertion Effects 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 230000032258 transport Effects 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D7/00—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal
- B65D7/12—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by wall construction or by connections between walls
- B65D7/34—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by wall construction or by connections between walls with permanent connections between walls
- B65D7/36—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by wall construction or by connections between walls with permanent connections between walls formed by rolling, or by rolling and pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/38—Making inlet or outlet arrangements of cans, tins, baths, bottles, or other vessels; Making can ends; Making closures
- B21D51/44—Making closures, e.g. caps
- B21D51/46—Placing sealings or sealing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D53/00—Sealing or packing elements; Sealings formed by liquid or plastics material
Definitions
- the invention relates to a drum comprising a steel body and steel end walls which are joined together by means of a folded seam which is provided with a seal in the core.
- the folded seam joint between body and end wall can consist of a flat, so-called double folded seam or a more or less rounded triple folded seam.
- the latter folded seam is preferable.
- the object of the invention is then to produce a solution to this sealing problem
- the seal comprises a filament made of a deformable plastic, which can adhere with its surface to the steel surface of the folded seam parts, and is chemically resistant as regards the contents of the drum.
- Chemically resistant is understood to mean an acceptable resistance and/or a material which does not breach any regulations concerning the packaging of foodstuffs.
- the length of the filament is not found to be critical. It can be equal to the peripheral length of the preliminary curvature, but it is preferivelyably shorter.
- a plastic ring which is closed all the way round and has no opening at all now is obtained. This can be explained by the fact that during the folding locally, as a result of the deformation of the material a temperature and pressure are produced which are sufficiently high to cause the deformable plastic material to flow, so that said material not only adjusts to the developing cross section of the cavity intended for the seal and situated in the core of the folded seam, but also undergoes a displacement in the peripheral direction, during which the ends grow towards each other and are united to form one unit.
- the filament which in fact has to form the seal, is chemically resistant as regards the contents of the drum.
- “Chemically resistant” can be understood to mean that the filament is completely inert in its behaviour relative to the contents, but also that the material of the filament undergoes an extraction which remains well below the limit which is set for it when an effort is made to dissolve it in the material which can form the contents of the drum. It is also important for the filament to be made of a material which meets all regulations concerning the packaging of foodstuffs.
- the adhesion of the plastic filament to the steel surface of the folded seam parts is another essential condition.
- Heat is necessary for optimum adhesion. It can arise during folding, but is fed in particularly after folding during heating to higher temperatures, for example during stoving of the coat of paint which is applied to the outside of the drum.
- the effect achieved by this adhesion is that, even if the folded seam is deformed due to damage to the drum, the seal remains in place even at the so difficult intersection of the lengthwise seam of the drum body with the folded seams. It has also been found in falling tests that the good adhesion makes an essential contribution to the strength of the folded seam. If the drum is damaged, unfolding of the folded seam now occurs less quickly, which also helps the seal.
- thermoplastics such as polyamides, polyesters and polyolefins.
- a copolymer of polyethylene is preferred, having a melt index of less than 300 and particularly preferable is a copolymer with vinyl acetate or (met)acrylic acid.
- the invention also comprises a process for the production of the drum, which is characterized in that the filament to be placed in the preliminary curvature is made of a length that is shorter than the peripheral length of the preliminary curvature, which gives the effect of the closed plastic sealing ring already described.
- This filament can be placed in the preliminary curvature after the end wall in the folding machine is placed on the drum body.
- the body with the end wall or cover placed thereon is then set in rotation; the preliminary curvature is provided if it has not already been carried out in an earlier operation, and the filament to be guided by suitable means into the preliminary curvature then remains in position therein as a result of the centri fugal action.
- This is preferably carried out just before the edge of the body flange goes into the preliminary curvature, so that the opening of the preliminary curvature, which opening is facing said body flange, is closed immediately after introduction during the further folding operation.
- the filament can also be placed in the preliminary curvature before the end wall is placed on the body of the drum.
- the end wall is set in rotation, the preliminary curvature is provided, and during or after this operation the filament is guided into the preliminary curvature.
- a slight adhesion of the filament in the precurl can be obtained by heating the end wall but, it is preferable, after the application of the filament, to make the opening of the preliminary curvature of a size which is slightly smaller than the diameter of the filament.
- the filament can be placed by mechanical means, but the best solution with the most rapid effect is obtained if the filament is fed into the preliminary curvature by means of a stream of air which guides and transports the filament.
- the filament can be a solid filament, but can also have a cellular structure. Some rigidity is desirable, so that the filament is not only easily guided to bridge the distance between the insertion means, such as the air jet nozzle, and the preliminary curvature, but also so that the filament can be held with some tension in the preliminary curvature, for the filament is in fact bent according to the curvature of the periphery.
- the drawings show schematically two means for introducing the filament into the preliminary curvature of the end wall flange.
- the filament 1 is pressed into the preliminary curvature 2, which has an opening which is slightly smaller than the diameter of the filament, from the end wall flange 3 by means of a rotary roller 4. This operation is preferably carried out before the end wall 3 is joined to the body.
- end wall flange 3 and body flange 5 have already been placed on each other, and the end wall flange is already provided with a preliminary curvature.
- Reference number 6 indicates a compressed air nozzle through which the filament 1 is conveyed and is, as it were, sprayed into the preliminary curvature 2 of the end wall flange, and takes up the position there indicated by solid lines. This can be carried out just before the folding rollers of the folding machine fold the curvature 2 further and finish the folded joint.
- the end wall is already provided with a preliminary curvature 7 and filament 9 fed in by means of a compressed air nozzle 8 before the end wall is placed on the body of the drum.
- the opening of the preliminary curvature is reduced to a size which is slightly smaller than the diameter of the filament as indicated by 10.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Rigid Containers With Two Or More Constituent Elements (AREA)
Abstract
Description
- The invention relates to a drum comprising a steel body and steel end walls which are joined together by means of a folded seam which is provided with a seal in the core.
- Such a drum is generally known. The folded seam joint between body and end wall can consist of a flat, so-called double folded seam or a more or less rounded triple folded seam. The latter folded seam is preferable.
- It is known here to inject a liquid sealing material into the folded seam in the process of formation just before or during folding, said sealing material subsequently drying or hardening during a subsequent heating process, such as, for example, during stoving of the lacquered drum.
- It is also known here to make a folded joint between the radially projecting flange of the drum body and the radially projecting edge or flange of an end wall by first of all giving the outside edge of the edge or flange of the end wall a 180° preliminary curvature opening inwards and subsequently injecting the sealing material into this preliminary curvature, then possibly allowing the sealing agent to dry or hardening it in an oven before the folding operation is carried out. Drying or hardening before the folding operation is carried out has advantages because it benefits the integrity of the seal, but it has the disadvantage that the production process has to be interrupted and additional energy has to be supplied for rapid drying or hardening.
- All these seals have the disadvantage that they sometimes do not seal properly, particularly if the sealing material is not injected very accurately, they are not always resistant to the contents of the drum, and in particular in the event of damage, for example if the drum falls, can give rise to leaks. Another disadvantage is that some sealing means are unsuitable for packaging of foodstuffs.
- Attempts have been made to solve this problem by fitting a prefabricated rubber ring in the preliminary curvature beforehand, but this did not give a satisfactory result, quite apart from the problem that placing such a rubber ring is difficult, because the diameter of a drum of, say, 55-gallon capacity is large, so that the ring is unwieldy.
- An attempt was also made to place a vulcanised rubber filament in the preliminary curvature, but the problem then was that the ends could not be joined in sealing fashion.
- An endeavour was also made to extrude vulcanisable rubber or a plastic into the preliminary curvature, but this again was without satisfactory results.
- The object of the invention is then to produce a solution to this sealing problem
- This object is achieved according to the invention in that the seal comprises a filament made of a deformable plastic, which can adhere with its surface to the steel surface of the folded seam parts, and is chemically resistant as regards the contents of the drum. Chemically resistant is understood to mean an acceptable resistance and/or a material which does not breach any regulations concerning the packaging of foodstuffs.
- When a filament of a deformable plastic is used the length of the filament is not found to be critical. It can be equal to the peripheral length of the preliminary curvature, but it is preferably shorter. After folding, it is found that a plastic ring which is closed all the way round and has no opening at all now is obtained. This can be explained by the fact that during the folding locally, as a result of the deformation of the material a temperature and pressure are produced which are sufficiently high to cause the deformable plastic material to flow, so that said material not only adjusts to the developing cross section of the cavity intended for the seal and situated in the core of the folded seam, but also undergoes a displacement in the peripheral direction, during which the ends grow towards each other and are united to form one unit.
- It is, of course, also important that the filament, which in fact has to form the seal, is chemically resistant as regards the contents of the drum. "Chemically resistant" can be understood to mean that the filament is completely inert in its behaviour relative to the contents, but also that the material of the filament undergoes an extraction which remains well below the limit which is set for it when an effort is made to dissolve it in the material which can form the contents of the drum. It is also important for the filament to be made of a material which meets all regulations concerning the packaging of foodstuffs.
- The adhesion of the plastic filament to the steel surface of the folded seam parts is another essential condition. Heat is necessary for optimum adhesion. It can arise during folding, but is fed in particularly after folding during heating to higher temperatures, for example during stoving of the coat of paint which is applied to the outside of the drum. The effect achieved by this adhesion is that, even if the folded seam is deformed due to damage to the drum, the seal remains in place even at the so difficult intersection of the lengthwise seam of the drum body with the folded seams. It has also been found in falling tests that the good adhesion makes an essential contribution to the strength of the folded seam. If the drum is damaged, unfolding of the folded seam now occurs less quickly, which also helps the seal.
- There are different deformable plastics which can meet the condition set. For example, various thermoplastics are conceivable, such as polyamides, polyesters and polyolefins. A copolymer of polyethylene is preferred, having a melt index of less than 300 and particularly preferable is a copolymer with vinyl acetate or (met)acrylic acid.
- The invention also comprises a process for the production of the drum, which is characterized in that the filament to be placed in the preliminary curvature is made of a length that is shorter than the peripheral length of the preliminary curvature, which gives the effect of the closed plastic sealing ring already described.
- This filament can be placed in the preliminary curvature after the end wall in the folding machine is placed on the drum body. The body with the end wall or cover placed thereon is then set in rotation; the preliminary curvature is provided if it has not already been carried out in an earlier operation, and the filament to be guided by suitable means into the preliminary curvature then remains in position therein as a result of the centri fugal action. This is preferably carried out just before the edge of the body flange goes into the preliminary curvature, so that the opening of the preliminary curvature, which opening is facing said body flange, is closed immediately after introduction during the further folding operation.
- The filament can also be placed in the preliminary curvature before the end wall is placed on the body of the drum. The end wall is set in rotation, the preliminary curvature is provided, and during or after this operation the filament is guided into the preliminary curvature. In order to hold the filament in place during storage and transport of the end walls a slight adhesion of the filament in the precurl can be obtained by heating the end wall but, it is preferable, after the application of the filament, to make the opening of the preliminary curvature of a size which is slightly smaller than the diameter of the filament.
- The filament can be placed by mechanical means, but the best solution with the most rapid effect is obtained if the filament is fed into the preliminary curvature by means of a stream of air which guides and transports the filament.
- The filament can be a solid filament, but can also have a cellular structure. Some rigidity is desirable, so that the filament is not only easily guided to bridge the distance between the insertion means, such as the air jet nozzle, and the preliminary curvature, but also so that the filament can be held with some tension in the preliminary curvature, for the filament is in fact bent according to the curvature of the periphery.
- The drawings show schematically two means for introducing the filament into the preliminary curvature of the end wall flange.
- Fig. 1 shows a mechanical insertion device;
- Fig. 2 shows a pneumatic insertion device;
- Fig. 3 also shows a pneumatic insertion device.
- In the embodiment shown in Fig. 1 the filament 1 is pressed into the
preliminary curvature 2, which has an opening which is slightly smaller than the diameter of the filament, from theend wall flange 3 by means of a rotary roller 4. This operation is preferably carried out before theend wall 3 is joined to the body. - In the embodiment shown in Fig. 2,
end wall flange 3 and body flange 5 have already been placed on each other, and the end wall flange is already provided with a preliminary curvature. - Reference number 6 indicates a compressed air nozzle through which the filament 1 is conveyed and is, as it were, sprayed into the
preliminary curvature 2 of the end wall flange, and takes up the position there indicated by solid lines. This can be carried out just before the folding rollers of the folding machine fold thecurvature 2 further and finish the folded joint. - In the embodiment shown in Fig. 3 the end wall is already provided with a preliminary curvature 7 and filament 9 fed in by means of a compressed air nozzle 8 before the end wall is placed on the body of the drum. Immediately after the filament is guided into the preliminary curvature, the opening of the preliminary curvature is reduced to a size which is slightly smaller than the diameter of the filament as indicated by 10.
- Drums obtained with the invention and subjected to all the usual tightness and strength tests remained completely tight. This can be explained by the fact that the plastic filament completely fills the core of the folded seam during the folding, and the heating occurring during stoving ensures adhesion and thus sealing in all circumstances.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88202533T ATE61777T1 (en) | 1987-11-20 | 1988-11-11 | BARREL WITH SEALED SEAM. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8702793A NL8702793A (en) | 1987-11-20 | 1987-11-20 | BARREL WITH SEALED Seam. |
NL8702793 | 1987-11-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0317008A1 true EP0317008A1 (en) | 1989-05-24 |
EP0317008B1 EP0317008B1 (en) | 1991-03-20 |
Family
ID=19850953
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88202533A Expired - Lifetime EP0317008B1 (en) | 1987-11-20 | 1988-11-11 | Drum with sealed folded seam |
Country Status (19)
Country | Link |
---|---|
EP (1) | EP0317008B1 (en) |
JP (1) | JPH03501011A (en) |
KR (1) | KR890701442A (en) |
CN (1) | CN1015247B (en) |
AR (1) | AR244159A1 (en) |
AT (1) | ATE61777T1 (en) |
BR (1) | BR8807807A (en) |
DE (1) | DE3862101D1 (en) |
DK (1) | DK115590D0 (en) |
ES (1) | ES2021424B3 (en) |
FI (1) | FI89344B (en) |
GR (1) | GR3001637T3 (en) |
IN (1) | IN168908B (en) |
NL (1) | NL8702793A (en) |
PT (1) | PT89037B (en) |
SG (1) | SG52592G (en) |
TR (1) | TR24249A (en) |
WO (1) | WO1989004799A1 (en) |
ZA (1) | ZA888563B (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE412448C (en) * | 1923-10-26 | 1925-04-18 | Felten & Guilleaume Carlswerk | Process for sealing the gaps, seams, grooves, etc. that occur when the walls of the vessel are made of non-weldable material |
DE1214956B (en) * | 1962-04-14 | 1966-04-21 | Lechler Bautenschutzchemie K G | Preparations for sealing and preserving gas pipes |
CH437020A (en) * | 1964-06-03 | 1967-05-31 | Catalytic Gas Pack Limited | End device of a container and use of this device |
FR2056925A1 (en) * | 1969-08-01 | 1971-05-07 | Koninkl Emballage In | |
EP0065842A1 (en) * | 1981-05-14 | 1982-12-01 | Büdenbender, Bernd | Securing end covers to rotationally symmetric bodies |
EP0129310A1 (en) * | 1983-04-25 | 1984-12-27 | W.R. Grace & Co. | Sealing gaskets |
-
1987
- 1987-11-20 NL NL8702793A patent/NL8702793A/en not_active Application Discontinuation
-
1988
- 1988-11-11 AT AT88202533T patent/ATE61777T1/en not_active IP Right Cessation
- 1988-11-11 WO PCT/NL1988/000049 patent/WO1989004799A1/en active Application Filing
- 1988-11-11 EP EP88202533A patent/EP0317008B1/en not_active Expired - Lifetime
- 1988-11-11 JP JP63509478A patent/JPH03501011A/en active Pending
- 1988-11-11 ES ES88202533T patent/ES2021424B3/en not_active Expired - Lifetime
- 1988-11-11 DE DE8888202533T patent/DE3862101D1/en not_active Expired - Fee Related
- 1988-11-11 BR BR888807807A patent/BR8807807A/en unknown
- 1988-11-16 TR TR88/0838A patent/TR24249A/en unknown
- 1988-11-16 ZA ZA888563A patent/ZA888563B/en unknown
- 1988-11-18 IN IN958/CAL/88A patent/IN168908B/en unknown
- 1988-11-18 AR AR88312501A patent/AR244159A1/en active
- 1988-11-18 PT PT89037A patent/PT89037B/en not_active IP Right Cessation
- 1988-11-19 CN CN88107948A patent/CN1015247B/en not_active Expired
-
1989
- 1989-07-20 KR KR1019890701373A patent/KR890701442A/en not_active Application Discontinuation
-
1990
- 1990-05-09 DK DK115590A patent/DK115590D0/en not_active Application Discontinuation
- 1990-05-18 FI FI902476A patent/FI89344B/en not_active Application Discontinuation
-
1991
- 1991-03-21 GR GR91400226T patent/GR3001637T3/en unknown
-
1992
- 1992-05-11 SG SG52592A patent/SG52592G/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE412448C (en) * | 1923-10-26 | 1925-04-18 | Felten & Guilleaume Carlswerk | Process for sealing the gaps, seams, grooves, etc. that occur when the walls of the vessel are made of non-weldable material |
DE1214956B (en) * | 1962-04-14 | 1966-04-21 | Lechler Bautenschutzchemie K G | Preparations for sealing and preserving gas pipes |
CH437020A (en) * | 1964-06-03 | 1967-05-31 | Catalytic Gas Pack Limited | End device of a container and use of this device |
FR2056925A1 (en) * | 1969-08-01 | 1971-05-07 | Koninkl Emballage In | |
EP0065842A1 (en) * | 1981-05-14 | 1982-12-01 | Büdenbender, Bernd | Securing end covers to rotationally symmetric bodies |
EP0129310A1 (en) * | 1983-04-25 | 1984-12-27 | W.R. Grace & Co. | Sealing gaskets |
Also Published As
Publication number | Publication date |
---|---|
DK115590A (en) | 1990-05-09 |
EP0317008B1 (en) | 1991-03-20 |
NL8702793A (en) | 1989-06-16 |
IN168908B (en) | 1991-07-06 |
GR3001637T3 (en) | 1992-11-23 |
DK115590D0 (en) | 1990-05-09 |
CN1034176A (en) | 1989-07-26 |
PT89037A (en) | 1989-09-14 |
WO1989004799A1 (en) | 1989-06-01 |
ZA888563B (en) | 1989-08-30 |
ATE61777T1 (en) | 1991-04-15 |
KR890701442A (en) | 1989-12-20 |
BR8807807A (en) | 1990-09-25 |
PT89037B (en) | 1993-12-31 |
TR24249A (en) | 1991-07-04 |
AR244159A1 (en) | 1993-10-29 |
FI902476A0 (en) | 1990-05-18 |
JPH03501011A (en) | 1991-03-07 |
FI89344B (en) | 1993-06-15 |
SG52592G (en) | 1992-09-04 |
CN1015247B (en) | 1992-01-01 |
ES2021424B3 (en) | 1991-11-01 |
DE3862101D1 (en) | 1991-04-25 |
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Legal Events
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