EP0314232A2 - Verdickende Gele - Google Patents

Verdickende Gele Download PDF

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Publication number
EP0314232A2
EP0314232A2 EP88202299A EP88202299A EP0314232A2 EP 0314232 A2 EP0314232 A2 EP 0314232A2 EP 88202299 A EP88202299 A EP 88202299A EP 88202299 A EP88202299 A EP 88202299A EP 0314232 A2 EP0314232 A2 EP 0314232A2
Authority
EP
European Patent Office
Prior art keywords
composition according
component
weight
surfactant
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP88202299A
Other languages
English (en)
French (fr)
Other versions
EP0314232A3 (de
Inventor
Thomas Bruce Neil
David James Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB878725132A external-priority patent/GB8725132D0/en
Priority claimed from GB878728383A external-priority patent/GB8728383D0/en
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP0314232A2 publication Critical patent/EP0314232A2/de
Publication of EP0314232A3 publication Critical patent/EP0314232A3/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/40—Monoamines or polyamines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the present invention is concerned with liquid detergent compositions.
  • compositions according to the invention are shear thinning, enabling convenient application by suitable means, e.g. a post-pump injector (which can bring about the required dilution of the concentrated product) together with a lance. That enables the diluted product to be sprayed over a wide area; yet it starts to thicken upon contact with the surface or object to be cleaned.
  • suitable means e.g. a post-pump injector (which can bring about the required dilution of the concentrated product) together with a lance. That enables the diluted product to be sprayed over a wide area; yet it starts to thicken upon contact with the surface or object to be cleaned.
  • Typical working dilutions are from about 5 to about 15% by weight of the composition in water, especially from about 7.5 to about 10%.
  • the present invention further comprises a method of diluting a composition of the invention according to any definition or described embodiment herein, with water or an aqueous vehicle, to a concentration at which the viscosity thereof is increased, and applying the composition thus diluted to a target surface.
  • target surface means a surface of any article, a working surface, or surface (internal or external) of any equipment or any other surface intended to be contacted by said diluted composition.
  • the diluted composition in the form of a foam, i.e. gassified with air or any other suitable gas. Conveniently, this may be effected by injecting the air or other gas into a lance or post-pump injector through which the diluted composition is administered.
  • Application in the form of a foam has the advantage of enabling the areas of the surface contacted to be seen better, thus obviating the need for inclusion of a dye for this purpose. It has also been found that in some instances, application as a foam enhances cleaning performance and rinsability.
  • compositions according to the present invention are brought about by use of appropriate surfactant blends.
  • any category of surfactant described herein for use in compositions of the present invention may be selected from any of the classes, sub-classes and specific materials described in "Surface Active Agents” Vol. I, by Schwartz & Perry, Interscience 1949 "Surface Active Agents” Vol.
  • compositions having the required properties may be formulated using
  • compositions comprise from about 0.1 to about 10% by weight of component (a), from about 0.05 to about 5% by weight of component (b) and from about 0.01 to about 30% by weight of component (c), preferably from about 0.5 to about 5% by weight of component (a), from about 0.5 to about 3% by weight of component (b) and from about l to about 25% by weight of component (c).
  • auxillary surfactant material which is other than the materials defined above for components (a) and (b), i.e. not significantly contributing to the required rheological properties.
  • auxillary surfactant material is present from about l to about 10% by weight of the total composition.
  • suitable auxillary surfactant materials comprise nonionic or anionic surfactants, most preferably a blend of both.
  • primary surfactant materials most suitable are those surfactants which are capable of forming addition compounds, especially those having a tri- or tetra­valent nitrogen atom. Suitable examples of these are amine or amine oxide surfactant materials in which the nitrogen atom is substituted by two independently selected C1 ⁇ 4 alkyl or C2 ⁇ 4 hydroxyalkyl groups and by a fatty residue having from 12 to 18 carbon atoms.
  • the fatty residue in such compounds has from 14 to 16 carbon atoms.
  • the HLB value of the primary surfactant material (averaged for all constituent surfactants therein, proportionally by weight) is from about 8 to about 12, most preferably around 10.
  • HLB value refers to the figure for hydrophilic lipophilic balance and is well known in the art, for example as described in "Nonionic Surfactants” Vol.I, Schick (Ed), Arnold, London 1967.
  • all or part of the primary surfactant material consists of an amine oxide surfactant which has an HLB value from about I4 to about 18, most preferably 16.
  • anionic surfactant compounds are generally preferred. Especially suitable are those selected from :
  • polyalkoxylated co-surfactants compounds (i) those containing from 3 to 7 ethylene oxide groups are normally the most suitable.
  • compositions according to the present invention may be formulated over a very wide pH range, from the highly acidic, through the mild acid, substantially neutral, mild and very alkaline.
  • acid compositions are most useful where descaling is required, for example the cleaning-in-place of dairy of brewery equipment.
  • alkaline compositions are most useful where fatty soil is to be emulsified, for example in the food industry.
  • the highly acidic compositions normally contain from about 15 to about 25% by weight, most preferably from about 18 to about 22% by weight of acidic material selected from one or more organic and/or inorganic acids.
  • the inorganic mineral acids are the most preferred, for example nitric, sulphuric, hydrochloric and phosphoric acids.
  • the more mildly acidic compositions will normally contain from about 5 to about 15% by weight of acid material, most preferably from about 8 to about 12%.
  • Substantially neutral compositions of the invention will contain substantially neutral, or perhaps mildly alkaline salts.
  • Suitable neutral salts are alkali metal sulphates, in particular sodium or potassium sulphate.
  • Suitable mildly alkaline salts are alkali metal carbonates or bicarbonates such as sodium carbonate, potassium carbonate, sodium bicarbonate and potassium bicarbonate or phosphates such as potassium tripolyphosphate or sodium tripolyphosphate, and tetrasodium pyrophosphate or potassium pyrophosphate.
  • Such mildly alkaline material is preferably used together with other neutral salts or in combination with more alkaline compounds. Generally, it is present at about from 1 to about 10% by weight of the total composition, for example to about 5 to about 6%. When used in combination with more alkaline material, for example as described further hereinbelow, the latter is generally present at from about 1 to about 5% by weight of the composition, typically about 3 to about 4%.
  • Stronger alkaline materials which may be used are, for example, selected from one or more alkali metal hydroxides and/or alkaline salts of alkali metals.
  • Preferred alkali metal hydroxides are sodium hydroxides (caustic soda) and potassium hydroxide (caustic potash).
  • Preferred alkaline salts are sodium metasilicate, trisodium phosphate, and sodium orthosilicate.
  • ferric ion impurities can catalyse the decomposition of any amine oxides present to the corresponding amine, resulting in a deterioration of the thickening effect upon dilution.
  • a chelating agent capable of chelating ferric ions at a pH above 8.
  • alkali metal gluconates such as sodium gluconate.
  • Typical materials herein described for components (a), (b), (c) are frequently used together in other compositions which do not possess the rheological properties presented here as defining the scope of the present invention in its broadest sense.
  • two known proprietory liquid bleach products have a weight ratio of components of type (a) to those of type (b) of, respectively, 0.35:I and 1.11:1.
  • the same products have a weight ratio of components of type (a) to those of type (c) of, respectively, I:10 and 1:16.3.
  • a known proprietory vehicle cleaner has, on the other hand, a weight ratio of components of type (a) to type (b) of 4.42:1 and a weight ratio of components of type (a) to type (c) of 1:0.36.
  • compositions according to the present invention have a weight ratio of component (a) to component (b) of from 1.25:1 to 4.25:1, and a weight ratio of component (a) to component (c) of from 1:0.5 to 1:9, preferably from 1:1.75 to 1:7.5.
  • compositions of the present invention contain no more than 7.5% by weight of bleach compounds, and it is especially preferred that they contain substantially no bleach compounds.
  • soil removal is greatly enhanced by incorporating one or more agents comprising a fatty acid esterified with a polyethylene glycol, for example where the fatty acid is oleic acid.
  • agents comprising a fatty acid esterified with a polyethylene glycol, for example where the fatty acid is oleic acid.
  • esters are preferably incorporated at from about 1 to about 10% by weight, most preferably from about 2.5 to 7.5% by weight of the total composition.
  • the component (b) hereinbefore defined is co-surfactant material capable of acting as a hydrotrope for the primary surfactant material.
  • a water-miscible, organic solvent especially one which is a hydrotrope for soaps and surfactants, such as an alkanol, e.g. ethanol or methanol or an appropriate amine such as triethanol­amine.
  • such solvents are incorporated at from about l to about 10% by weight, typically from about 2 to about 7.5% by weight of the total composition.
  • Suitable builders are well known in the art and preferably comprise tripolyphosphate salts of sodium and/or potassium.
  • compositions according to the present invention comprises one or more suitable enzymes, for example selected from proteolytic and amylolytic enzymes.
  • microbiocides for example selected from substituted guanidines (e.g. biguanides), halo-phenylalkanols, p-­hydroxybenzoic acid esters and their salts, halo­bisphenols, benzoic acid and its salts, and phenyl­phenol and derivatives thereof.
  • substituted guanidines e.g. biguanides
  • halo-phenylalkanols e.g. biguanides
  • halo-phenylalkanols e.g. biguanides
  • halo-phenylalkanols e.g. biguanides
  • halo-phenylalkanols e.g. biguanides
  • halo-phenylalkanols e.g. biguanides
  • p-­hydroxybenzoic acid esters and their salts e.g. biguanides
  • halo­bisphenols e.
  • compositions according to the invention may also be included in compositions according to the invention.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
EP88202299A 1987-10-27 1988-10-14 Verdickende Gele Withdrawn EP0314232A3 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB878725132A GB8725132D0 (en) 1987-10-27 1987-10-27 Gel products
GB8725132 1987-10-27
GB878728383A GB8728383D0 (en) 1987-12-04 1987-12-04 Gel products
GB8728383 1987-12-04

Publications (2)

Publication Number Publication Date
EP0314232A2 true EP0314232A2 (de) 1989-05-03
EP0314232A3 EP0314232A3 (de) 1990-07-04

Family

ID=26292957

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88202299A Withdrawn EP0314232A3 (de) 1987-10-27 1988-10-14 Verdickende Gele

Country Status (6)

Country Link
EP (1) EP0314232A3 (de)
AU (1) AU609532B2 (de)
FI (1) FI884895A (de)
NO (1) NO884747L (de)
NZ (1) NZ226662A (de)
ZA (1) ZA888020B (de)

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0474117A1 (de) * 1990-09-04 1992-03-11 IBC Manufacturing Company Zubereitungen
WO1993002175A1 (en) * 1991-07-15 1993-02-04 The Clorox Company Phase stable viscoelastic cleaning compositions
US5312558A (en) * 1991-04-04 1994-05-17 Ibc Manufacturing Company Pesticide composition
WO1994025561A1 (en) * 1993-05-05 1994-11-10 Novo Nordisk A/S Cleaning gel
WO1994028108A1 (en) * 1993-06-01 1994-12-08 Ecolab Inc. Thickened hard surface cleaner
TR27379A (tr) * 1992-07-29 1995-02-01 Clorox Co Faz dengeli viskoelastik temizleme bilesimleri.
US5399285A (en) * 1992-10-30 1995-03-21 Diversey Corporation Non-chlorinated low alkalinity high retention cleaners
WO1996003483A1 (en) * 1994-07-21 1996-02-08 Minnesota Mining And Manufacturing Company Concentrated cleaner compositions capable of viscosity increase upon dilution
WO1996012787A1 (en) * 1994-10-21 1996-05-02 Jeyes Group Plc Concentrated liquid surfactant-containing compositions
WO1996021721A1 (en) * 1995-01-12 1996-07-18 Jeyes Group Plc Concentrated, aqueous, surfactant-containing compositions
EP0724013A1 (de) * 1995-01-30 1996-07-31 Colgate-Palmolive Company Giessfähige Waschmittelkonzentrate, die nach Verdünnung mit Wasser gleiche oder erhöhte Viskosität zeigen
WO1996024654A1 (de) * 1995-02-09 1996-08-15 Henkel-Ecolab Gmbh & Co. Ohg Verdickende wässrige reinigungsmittel für harte oberflächen
US5612372A (en) * 1990-09-04 1997-03-18 Ibc Manufacturing Company Liquid dispersants for pesticides
US5698505A (en) * 1994-01-25 1997-12-16 The Procter & Gamble Company High sudsing light duty liquid or gel dishwashing detergent compositions containing long chain amine oxide
WO1998017776A2 (de) * 1996-10-24 1998-04-30 Henkel-Ecolab Gmbh & Co. Ohg Reinigung von rohrleitungen und behältern in der lebensmittelindustrie
US5816446A (en) * 1995-02-23 1998-10-06 Ecolab Inc. Dispensing a viscous use solution by diluting a less viscous concentrate
EP0872542A2 (de) * 1997-04-15 1998-10-21 Th. Goldschmidt AG Niedrigviskose alkalische Reinigeremulsion
WO1998050520A1 (en) * 1997-05-06 1998-11-12 Colgate-Palmolive Company Detergent concentrates which increase in viscosity after dilution
US6271187B1 (en) 1999-12-01 2001-08-07 Ecolab Inc. Hand soap concentrate, use solution and method for modifying a hand soap concentrate
WO2001085896A1 (de) * 2000-05-12 2001-11-15 Henkel Kommanditgesellschaft Auf Aktien Konzentrat zur verdünnung unter viskositätserhalt oder -erhöhung
US6564813B1 (en) 1997-07-22 2003-05-20 Ecolab Gmbh & Co. Ohg Use of solutions containing enzymes for cleaning fermentation or storage tanks
US6617293B2 (en) 2001-08-06 2003-09-09 3M Innovative Properties Company Thickening on dilution liquid soap
EP1362908A1 (de) * 2001-01-23 2003-11-19 Kao Corporation Flüssiges waschmittel
FR2855973A1 (fr) * 2003-06-12 2004-12-17 Bernard Mariotti Composition liquide detergente/predesinfectante, concentree et diluable, contre les biofilms bacteriens.
EP1820843A1 (de) * 2006-02-16 2007-08-22 Witty-Chemie GmbH & Co. KG Saures Reinigungsmittelkonzentrat zur Reinigung glatter, nicht-horizontaler Oberflächen
EP1939274A1 (de) 2006-12-20 2008-07-02 Unilever N.V. Geschirrspülzusammensetzung
EP2617805A1 (de) 2012-01-23 2013-07-24 Kao Corporation, S.A. Alkalihaltige Reinigungszusammensetzung für nichthorizontale Oberflächen
WO2017011158A1 (en) * 2015-07-14 2017-01-19 Ecolab Usa Inc. Controlled rate of foam breakage in hard surface cleaners
US10253277B2 (en) 2015-09-28 2019-04-09 Ecolab Usa Inc. DEA-free pot and pan cleaner for hard water use

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0151678A1 (de) * 1983-08-12 1985-08-21 THE PROCTER & GAMBLE COMPANY Stabile flüssige Detergenszusammensetzungen
GB2179054A (en) * 1985-08-16 1987-02-25 Unilever Plc Detergent gel compositions
GB2188058A (en) * 1986-03-22 1987-09-23 Abster Company Limited The Liquid hand cleaner containing solid phase

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PH25826A (en) * 1986-03-14 1991-11-05 Johnson & Son Inc S C Prespotter laundry detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0151678A1 (de) * 1983-08-12 1985-08-21 THE PROCTER & GAMBLE COMPANY Stabile flüssige Detergenszusammensetzungen
GB2179054A (en) * 1985-08-16 1987-02-25 Unilever Plc Detergent gel compositions
GB2188058A (en) * 1986-03-22 1987-09-23 Abster Company Limited The Liquid hand cleaner containing solid phase

Cited By (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5612372A (en) * 1990-09-04 1997-03-18 Ibc Manufacturing Company Liquid dispersants for pesticides
EP0474117A1 (de) * 1990-09-04 1992-03-11 IBC Manufacturing Company Zubereitungen
US5312558A (en) * 1991-04-04 1994-05-17 Ibc Manufacturing Company Pesticide composition
WO1993002175A1 (en) * 1991-07-15 1993-02-04 The Clorox Company Phase stable viscoelastic cleaning compositions
TR27379A (tr) * 1992-07-29 1995-02-01 Clorox Co Faz dengeli viskoelastik temizleme bilesimleri.
US5399285A (en) * 1992-10-30 1995-03-21 Diversey Corporation Non-chlorinated low alkalinity high retention cleaners
EP0595590A3 (de) * 1992-10-30 1995-04-26 Diversey Corp Nichtchlorierte Reinigungsmittel mit niedriger Alkalinität und hohem Zurückhalten.
US5965503A (en) * 1993-05-04 1999-10-12 Novo Nordisk A/S Cleaning gel for hard surfaces containing one or more surfactants, an electrolyte, and an enzyme
WO1994025561A1 (en) * 1993-05-05 1994-11-10 Novo Nordisk A/S Cleaning gel
AU676066B2 (en) * 1993-06-01 1997-02-27 Ecolab Inc. Thickened hard surface cleaner
US6630434B2 (en) 1993-06-01 2003-10-07 Ecolab Inc. Thickened hard surface cleaner
WO1994028108A1 (en) * 1993-06-01 1994-12-08 Ecolab Inc. Thickened hard surface cleaner
US6268324B1 (en) 1993-06-01 2001-07-31 Ecolab Inc. Thickened hard surface cleaner
US5698505A (en) * 1994-01-25 1997-12-16 The Procter & Gamble Company High sudsing light duty liquid or gel dishwashing detergent compositions containing long chain amine oxide
JPH10503235A (ja) * 1994-07-21 1998-03-24 ミネソタ マイニング アンド マニュファクチャリング カンパニー 希釈時に粘度増加しうる濃縮洗浄剤組成物
AU689624B2 (en) * 1994-07-21 1998-04-02 Minnesota Mining And Manufacturing Company Concentrated cleaner compositions capable of viscosity increase upon dilution
US6150320A (en) * 1994-07-21 2000-11-21 3M Innovative Properties Company Concentrated cleaner compositions capable of viscosity increase upon dilution
WO1996003483A1 (en) * 1994-07-21 1996-02-08 Minnesota Mining And Manufacturing Company Concentrated cleaner compositions capable of viscosity increase upon dilution
WO1996012787A1 (en) * 1994-10-21 1996-05-02 Jeyes Group Plc Concentrated liquid surfactant-containing compositions
WO1996021721A1 (en) * 1995-01-12 1996-07-18 Jeyes Group Plc Concentrated, aqueous, surfactant-containing compositions
EP0724013A1 (de) * 1995-01-30 1996-07-31 Colgate-Palmolive Company Giessfähige Waschmittelkonzentrate, die nach Verdünnung mit Wasser gleiche oder erhöhte Viskosität zeigen
WO1996024654A1 (de) * 1995-02-09 1996-08-15 Henkel-Ecolab Gmbh & Co. Ohg Verdickende wässrige reinigungsmittel für harte oberflächen
US5906973A (en) * 1995-02-09 1999-05-25 Henkel-Ecolab Gmbh & Co. Ohg Process for cleaning vertical or inclined hard surfaces
US5816446A (en) * 1995-02-23 1998-10-06 Ecolab Inc. Dispensing a viscous use solution by diluting a less viscous concentrate
WO1998017776A3 (de) * 1996-10-24 1999-01-21 Henkel Ecolab Gmbh & Co Ohg Reinigung von rohrleitungen und behältern in der lebensmittelindustrie
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Also Published As

Publication number Publication date
NO884747D0 (no) 1988-10-25
ZA888020B (en) 1990-06-27
AU609532B2 (en) 1991-05-02
NZ226662A (en) 1991-03-26
EP0314232A3 (de) 1990-07-04
FI884895A (fi) 1989-04-28
AU2418988A (en) 1989-04-27
FI884895A0 (fi) 1988-10-24
NO884747L (no) 1989-04-28

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